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PODAR INTERNATIONAL SCHOOL

IGCSE – CHEMISTRY 0620


WORKSHEET ON ENERGY CHANGE

The energy level diagram for the reaction between sodium hydrogen carbonate and dilute
hydrochloric acid is shown.

sodium chloride + water +


carbon dioxide

energy
sodium hydrogen carbonate +
dilute hydrochloric acid

Which row correctly describes the type of reaction and the energy of the reactants and products?

energy of the reactants


type of reaction and products

A endothermic the products have more


energy than the reactants

B endothermic the reactants have more


energy than the products

C exothermic the products have more


energy than the reactants

D exothermic the reactants have more


energy than the products

The energy level diagram for the reaction between magnesium and hydrochloric acid is shown.

Mg + 2HCl

energy

MgCl 2 + H2

Which statement about the reaction is not correct?

A Energy is given out during the reaction.


B The products are at a lower energy level than the reactants.
C The reaction is endothermic.
D The temperature increases during the reaction.
The energy level diagram shows the energy of the reactants and products in a chemical reaction.

reactants

energy

products

Which row correctly describes the energy change and the type of reaction shown?

energy change type of reaction

A energy is given out endothermic


to the surroundings
B energy is given out exothermic
to the surroundings
C energy is taken in from endothermic
the surroundings
D energy is taken in from exothermic
the surroundings

Which reaction is endothermic?

A acid neutralising alkali causing a temperature increase

B adding magnesium to hydrochloric acid

C calcium carbonate decomposing when heated

D combustion of fossil fuels


S o l i d h y d r a t e d s o d i u m c a r b o n a t e w a s a d d e d to so l i d citric a c i d .

T h e mi x t u r e w a s stirred a n d t h e t e m p e r a t u r e r e c o r d e d e v e r y 1 0 s e c o n d s .

T h e results are s h o w n o n the gr a ph:

25

20

15
te mp er atu re
/ °C
10

0
0 20 40 60 80 100
tim e / s

W h i c h r ow d e s c r i b e s t h e r e a c t i o n ?

6.
T h e d i a g r a m s s h o w f o u r c h e m i c a l r e a c ti o n s .

W h i c h r e a c ti o n i s e n d o t h e r m i c ?

A B

steam flame

water

natural g as
calcium oxide

addition of water to calcium oxide combust ion of natural g as

C D

final t e m p e r a t u r e
initial t e m p e r a t u r e

alkali

heat acid

thermal decomposit ion of limestone reaction of acid with alkali


7.
What occurs when a fuel burns?

fuel reacts energy


with oxygen change

A no endothermic
B no exothermic
C yes endothermic
D yes exothermic

8.
Some reactions are endothermic.

How does the temperature and energy change in an endothermic reaction?

temperature change energy change

A decreases energy taken in


B decreases energy given out
C increases energy taken in
D increases energy given out
9.
When anhydrous copper(II ) sulfate is added to water a solution is formed and heat is given out.

thermometer
anhydrous
copper(II) sulfate

water

Which row correctly shows the temperature change and the type of reaction taking place?

temperature change type of reaction

A decreases endothermic
B decreases exothermic
C increases endothermic
D increases exothermic

10.
The diagrams show the difference in energies of the reactants and products in two types of
reaction.

diagram 1 diagram 2
heat taken in heat given out

products

energy energy
reactants
reactants

products

Which diagram and which type of energy change apply to a fuel burning in air?
diagram type of energy change

A 1 endothermic
B 1 exothermic
C 2 endothermic
D 2 exothermic
11.
Bond breaking is an endothermic change and bond
forming is an exothermic change. Bond energy is the
amount of energy in kJ/mol needed to break one mole of
the specified bond.

H H H H H H

H C C C H + C l Cl → H C C C Cl + H Cl
H
H H H H H

Use the following bond energies to determine whether this reaction is exothermic or
endothermic. You must show your reasoning.

bond energies in
bond kJ / mol

C–Cl 338

C–H 412

Cl –Cl 242

H–Cl 431

C–C 348

Before- [(412*8)+(242)]= 3538


After- [(412*7)+(338)+(431)]= 3653
This reaction is endothermic because the product has more energy then the reactant.

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12.
–1
Approximate values of the average bond enthalpies, in kJ mol , of three substances
are:

H–H 430
F–F 155
H–F 565

What is the enthalpy change, in kJ, for this reaction?

2HF ® H2 + F2

A. +545

B. +20

C. –20

D. –545

13.
But–1–ene gas, burns in oxygen to produce carbon dioxide and water vapour according
to the following equation.

C4H8 + 6O2 ® 4CO2 + 4H2O

Ө
(a) Use the data below to calculate the value of DH for the combustion of
but-1-ene.

Bond C−C C=C C−H O=O C=O O–H


Average bond
– 348 612 412 496 743 463
enthalpy / kJ mol
1
14.
Ammonia is used to make nitrogen trifluoride, NF3 .
Nitrogen trifluoride is essential to the electronics industry. It is made by the following reaction.

F F H F
H N H + F F ® F N F + H
F
F F H F
H F

Determine if the above reaction is exothermic or endothermic using the following bond
energies and by completing the following table. The first line has been done as an example.
Bond energy is the amount of energy, in kJ / mole, needed to break or make one mole of the
bond.

bond bond energy in kJ / mole


N–H 390
F–F 155
N–F 280
H–F 565

15.

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