1 ‘Skema Jawapan Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 ‘Chapter 3 ~ Chemical Formulae and Equations MRSME: Question 9 No Mark Scheme Mark ‘Sub Total vay @ PI, Molecular formula: CoFiOe 2, Empirical formula : CH:0 iw Relative molecular mass (206) + 112) + 166) = 180 Oo PI. Volume of gas = G0 ea P2, Number of mol of gas= 60 /24000 = 0.0025 mol P3, Mass of gas = 0.0025 4= 001g @ PI. Helium gas consists of tiny and discrete particles 2, The particles helium atoms move freely and randomly P3. The atoms/particles diffuse / move in between the air /move through the air / through the empty space of the balloon’ wall 4. From the higher concentration area to a lower concentration area Procedure PL. A crucible and its lid is weighed and its mass is recorded, P2, Clean [5-10 em of metal ¥ by using sand paper Coiled and placed in the erucible P3. The crucible with its lid and content is weighed again and the mass is recorded, PA, The crucible is heated strongly without its lid 5. When metal Y starts to bum, close immediately with it lid. 6, Using a pair of tongs, the lid is lifted at intervals. P7. When the burning has completed, the lid is removed and the erucible is heated strongly for 2 minutes, 8, The crucible is allowed to coo! to room temperature, weighed again and its mass is recorded, 9, The heating, cooling and weighing provess are repeated until a constant ‘mass is obtained Result Description Masia) Crucible + lid a Crucible + lid + Metal Y > Crucible + lid + ¥ oxide c [Calculation] Element ¥ 0 Mass (g) bea Number of moles boa=m anol) 24 Simplest ratio of moles Empirical formula is Y,0, 4: reasonable value Max 10 dd WS pzeyn6y102 ‘Skema Tawopan Modul Sukses Kimia Kertas 2 ‘Soalan Percubaan Negeri 2016 Chapter 4 Periodie Table of Element MRSM: Question 7 No ‘Mark Scheme Mark ‘Sub Total Taw) PL P2, PR Pa PS The electron arangement of Na= 2.8.1, C1= 2.87. Both atoms have 3 shells occupied with electrons, Naand Cl belongs to Period 3 ‘The number of valence electrons of Na is I so it belongs to Group 1 The number of valence eleetrons of Cl is 7 s0 it belongs to Group 17, @ PS To achieve the stable octet cloctron arrangement Sodium / Na atom donate/release /lose | electron to form Na ions Chlorine / Cl atom accept / gain /receive | electron to form CI ions Na’ ion and CI ion attract each other with strong electrostatic Force forms ionic bond with the formula NaCl [Diagram} Po, P7. ED Correct number of electrons Label nucleus shown and correct charge Nav ct ‘P2 and P3 is not complete, infer from the half equation i) PL PR Pa Mating point for the compound formed / {etrachoromethane/CCIs is lower than compound in (a)ii) NaCl Weak intermoleculer force f! Van der Waals force between molecules ! Weak attraction force between molecules in the compound formed tetrachloromethane (CCl, Less heat energy needed to overcome the forces ‘The ions of compound in (ai) are held together by strong electrostatic fore ‘More heat energy is needed to overcome the fore. o) PL P2. PB, ‘Argon atom has achieved stable ovtet electron arrangement ‘Argon atom does not reat with tungsten/ atom doesnot donate, receive or. sharing electron ‘inert Oxygen atom ean aeeept electron from tungsten atom /reacts with tungsten * adlp atom for P2 Total 2 dd WS pzeyn6y103 ‘Skema Jawopan Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Pulau Pinang: Question 7 Question Mak Schane Sib) Toul 7@ @ _ | Group 17, Period 3 fn th Kumpulan 17, Kala 3 Atom Z,has 7 valence electrons. So atom Z. isin Group 17. Atom Z mempunyai 7 elektron valens, Jadi, atom Z dalam Kumpulan 17 Atom Z has 3 shells filled with electrons, So atom Z is in Period 3, Atom Z mempunyai 3 petala herist elekiron. Jad, atom Z dalam Kala 3. Brown solid is formed // Burn vigorously to form brown solid Pepejal perang terbentuk / Terbakar cergas untuk membentuk pepejal perang o oO @ DY +250 5 DVO HT Mol ¥ 3/23 170.1 2 mol Y produce | mol He 2 mol ¥ menghasifkan I mol I> 0.1 mol ¥ produce 0.05 mol He /0.Imol ¥ menghasitkan 0.05 mol Is ‘Volume = 0.05 x 24 dm’ //1.2.dmn* Isipadu © Tonic Compound Electron arrangement of atom Y is 2.8.1 ‘Susunan elekiron atom ¥ ialah 2.8.1 Electron arrangement of atom Z.is 28.7 Sustnan elekiron atom Z ialah 28.7 Atom Y has 1 valenee elevtron, Atom ¥ mempunyai 1 elektron valens. ‘Atom Z has 7 valence electrons. Atom Z mempunyai 7 elektron valens. To achieve a stable octet electron arrangement, atom Y loses I electron to form Y* Unauk mencapai sustman elekaron oktet yang stabil, atom ¥ melepaskan 1 elektron untuk membenauk ion Y" To achieve a stable octet electron arrangement, atom Z gains | electron to form Zion. Untuk mencapai susunan elektron oktet yang stabil, atom Z menerima I elekiron untuk membentuk ion Z Jon Y" and ion Z> are attracted by strong electrostatic force Ton Y'dan ion Z-tertarik dengan day elektrostatik yang kuat Tonie bond is formed Hatan ion terbentuk Tonie compound with formula YZ. is produced Sebatian ion dengan formula YZ dibasilkan. +1 mark is awarded to the correct pairs of electron arrangements +] mark is awarded for the correct pairs of valence electrons, Max 5 dd WS pzeyn6y104 ‘Skema Jawopan Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 ‘Question Mark Scheme Sub) Tout Mark | Mark ‘ovalent compound Electron arrangement of atom X is 2.4 Susan elekiron atom X ialah 24 Electron arrangement of atom Z is 287 Susunan elekiron atom Z ialah 28.7 ‘Atom X has 4 valence electrons. Atom X mempunvai 4 elekiron valens. ‘Atom Z has 7 valence electrons. Atom Z mempunyai 7 elektron valens. To achieve a stable octet electron arrangement, atom X needs 4 electrons. So atom. X contributes 4 electrons for sharing. Untuk mencapai susuonan elektron oktet yang stabil, atom X memertukan 4 elektron. Jad, atom X mensumbangkan 4 elektron untuk dikongsi To achieve a stable ovtet electron arrangement, atom Z needs | electron, So atom Z, ‘contributes electron for sharing, Untuk mencapai susunan elektron oktet yang stabil, atom Z memertukan 1 elekiron. Jadi, atom X menyumbanghan 1 elekron untuk dikongsi 1 atom X shares 4 pairs of electrons with 4 atom Z 1 atom X berkongsi 4 pasang elekiron dengan 4 atom Z Single covalent bonds is formed. Fkaian kovaten wnggal terbentuk Covalent compound with the formula X7 is producod. ‘Sebatian kovalen dengan formula XZedihasilkan. *| mark is awarded to the comect pairs of electron arrangements +] mark is awarded for the correct pairs of valence electrons, + description of sharing pairs of electrons can be replaced with diagram of electron ‘wrangement Max 5 dd WS pzeyn6y105 ‘Skema Jawopan Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 ‘Chapter $ ~ Chemical Bond ‘Negeri Sembilan: Question 7 ‘Question ‘Mark scheme ‘Sub | TotalM Mark | ark T@)@ | Able to edentify compounds P and O Answer 1 : Covalent compound 1 Q¢ lonie compound. w ‘Able to give an example for each compounds P and O ‘Sample answer : Any suitable covalent compound 1 Q: Any suitable ionie compound. 1 rr) “Able to explain why the melting and boiling point oT compounds P and O are different ‘Sample answer Pismolecules 1 Attracted together by weak intermolecular forcesivan de Waals forces 1 Required less heat energy fo overcome the forces Qisions Attracted together by strong electrostatic forces Required more heat energy fo overcome the forces o Able fo explain the formation of ionic compound and covalent compound. ple Answer Tonic compound 1. Theelectron arrangement of atom Z is 2.8.2 and atom Y is 2.7 2. To achieve octet electron arrangement 3. Atom Z.donate 2 electrons to form 2° 4 5 ‘Atom Y accept I electron to form Y ‘The ions are attracted together by strong electrostatic forces 6 OneZ and two Y-to form ZY2/! Diagram Covalent compound Atom X has electron arrangement of 2.4 To achieve octet electvon arrangement Atom X contribute 4 electrons. ‘Atom Y contribute | electron One atom of X and four atoms of Y share four pairs of electron to formed XY.// Diagram lo Total 20 dd WS pzeyn6y106 ‘Skema Jawopan Modul Sukses Kimia Kertas 2 Soalan Pereubaan Negeri 2016 Perlis: Question 9 ‘Question Answer Mak 9 [ea ‘Compound formed between X | Molecule formed between Z and Y and Y Typesof | Tonicbond is fomned because | Covalent bond is formed because Z 2 chemical | X atom donates electrons and_| and Y atoms share the eletrons to bonds Yatom reeivesclettons10 | gchieve able leon arrangement a eee agg | Yai ate nonnetal Y¥ is non-metal Boiling point | High because aTotofenergy | Low because less energy is needed a andmeliing | necdod to overcome the to overcome the weak forces of point strong electrostatic forces | attraction between molecules, between ions ©) _| Conver eleciron arrangement of fons Correct charges and miclel are shown 2+ f y +X atom with an elocton arrangement of 2.8.2 donates 2 valence electrons to achieve 1 the stable octet electron arrangement, 2.8, X* ion is formal /X 2 + Je = Y-atom with an electon arrangement of 26 aocept 2 electrons o achieve the stable 1 octet eloctron arangement,2.8. Y"ion is formed / Y +26 > Y> - The oppositely-charged ions, X** and Y* are attracted to each other by a strong. 1 electrostatic force = Anionic compound XY is formed 1 © [L Aerwoible is led with sofa P units hall Tall 7 2. Two.arbon eleetrodes are dipped in the solid P and eonneeted tothe batteries, 1 3. Switch istumed on and observation is recorded ‘4 The solid P is then heated uni it melts completely 1 5, The switch is tumed on again and observation is recorded 1 6. Steps Ito 5 are repeated using solid Q to replace solid P 1 7. Observations 1 P doesnot light up the bulb in both solid and molten states 1 Q lights up the bulb in molten state only. 1 naphthalene // any suitable answer 1 Q: lead(II) bromide // any suitable answer 1 Toul | 30 dd WS pzeyn6y107 ‘Skema Jawopan Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 SBP: Question 7 Question Answer Sub | Total 7 [(@) | [ableto give explanation on given situation correct) Sample answers Pl: Ice cube has low melting and point molecules in ice eube are held by weak intermolecular force of attraction 2: Less heat energy needed to overcome the weak force of attraction. 3: Salts has high melting point! ions in salt are attracted by a strong electrostatic force of attraction, P4: Lots of heat energy needed to overcome the strong force of attraction, wo) [able to name the type of bond for the compounds in Diagram 7 and explain the formation of the compound correetly| Sample answer; PI: Ice cube: covalent bond 2: Salt: ionic bond P3: Electron arrangement of hydrogen atom is 1, PA; Electron arrangement of oxygen atom is 2.6 PS: Two hydrogen atoms share a pair of electron with one oxygen stom one ‘oxygen atom shares two pairs of electron with two hydrogen atoms P6; to achieve stable duplev/ octet electron arrangement 7; Sodium atom has the electron arrangement of 2.8.1 8: Electron arrangement of chlorine stom is 287 9; Sodium atom releases one electron to form sodium ion/ Na’ P10: Chlorine atom reoeives one electton to form chloride ion! Cl PI: to achieve sable octet electron arrangement P12: Sodium ion/ Na" and chloride ion/ Cl are attracted by a strong electrostatic force of attraction, Max: 10 o | [able to suggest solvent W and solvent X correct] Sample answer; Solvent W: water Solvent X: tetrachloromethane/ methylbenzene/ diethyl eter/eyelohexane [ar suitable organic solvent] ii | [able to explain the differences in the properties of the salt in solvent W and solvent Xx] Sample ane PI Tabi sl sodium chloride can cont lettin solvent W con eer re ey | 3: Table sal sodium corde insolvent X canot conde lec 4 Tale sal sodium chloride insolent X has no Ste moving on ons in afx postion Table salt cannot diol insolvent X Total dd WS pzeyn6y10‘Skema Jawopan Modul Sukses Kimia Kertas 2 Soalan ercubaan Negeri 2016 Chapter 6 -Bletrochemistry Terengganu : Question 7 7] te) ElecirodeP: Concentration of ostohte 7 lecrode Q Poston ofthe ins nthe electrochemical series i} 2 (b) Electrode P Electrode Q Tons attracted to ‘Cl and OH ‘Na’ and H* I Names the fons ; : selectively discharged cr a M1 Reason why the ions a] Concentration of Fs | 1 Ton is placed Tower selectively discharged higher than OH ‘than Na® in the electrochemical seies_| | 141 Observation Grecnish yellow gas 8 | Colorless gas is releas released i 8 © aX caly Type of cell Electrolytic cell ‘Voltaic cell 1 The energy change Electrical energy to ‘Chemical energy t0 chemical enazy elecrical energy 1 The terminal ofthe call] Posive terminal Positive terminal 7 anode: Copper ‘cathode: copper 1 Negatveterminal / | Negative terminal / cathode: copper sxe! aun 1 Tons piesa he learalye cu SO# . OH 1 Observation Anode ‘Negative Thier temina/Aluminium plate: thinner 1 Cathode Positive terminal/Copper brown deposivtbown | plate: brown solid is deposivbrown solid is 1 deposited/Ahicker | deposited thicker Tlalf equation for both | Anode: “Alplate/- terminal: 1 electrodes cu c+2e [AID AP te Cathode: Cu plate//* terminal: Cu* Re > Cu Cut He> Cu 1 ‘Name of the process occurred at ‘Anode/A] plate: Oxidation both electrodes! terminal Cathode/Copper plate//negative terminal: 1 Reduction. 10 dd WS pzeyn6y109 ‘Skema Tawopan Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Pulau Pinang: Question 8(¢) 8(@) | @_ | Solvent X: Methyl benzene’ propanone [any organie solvent] T Pelarut X: Met benzene /propanon [sebarang pelarut organik] Solvent Y> Water 1 2 Pelarut ¥: Air G_ | Ammonia in solvent X exist as molecule T Ammonia dalam pelarat X wujud sebagat molekul Ammonia in solvent ¥ ean ionizes 1 Ammonia dalam pelarut ¥ boleh mengion Prexluce free moving ions 1 3 ‘Menghasilkan ion-ion yang bergerak bebas Perlis: Question 8 8 [@ | - Hydrogen gos 1 + 2H #20 1 2 (b) | The ions present in both cell are Cu*> SO, H? ad OH 1 In Cell M At anode, Copper atom ionises //Copper atom ionises fo Atcathode, Cu discharge and form copper atom (Cu discharge because the position is lower than Hin ECS ‘equation Anode: Cu> Cu +2e Cathode: Cu®+2e > Cu InCellN Atnegative terminal/Anode Mg stom ionises// Mg atom ionises and form Mg * “Ma atom is more clectropositve than copper i the po inEcs 1% equation Mg —>Mg?#2e jon of Mg is higher than Copper © “Materials: Iron key, copper plate, copper(I) sulphate solution (0.5 mol dm®) and sand Paper Apparatus: battery, connecting wires, beaker, ammeter Procedur: 1 ‘The irom key is cleaned with sand paper 2 ‘The iron key is then connected (o the negative terminal ofthe battery while the copper plate is connected to the positive terminal of the battery, Both are Jmmersod in the copper(I) sulphate solution 3 A.0.5 A current is supplied for about 30 minutes. 4 ‘The iron key is rotated slowly while the experiment is conducted. Hi Copper plate Plat kuprum Fi tronkey Copper() sulphate ron key a Kunci besi Larutan kuprum()) sulfat 41 dd WS pzeyn6y1010 ‘Skema Jowapan Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Half equation Anode Culs) —+ Cu*aq) +26 1 Cathode: Cu(aq) +20 + Cvs) L 10 TOrAL | 20 Kedah: Question 9 9 Ta) Spoon suc Nickel (ID nitrate solution Larwan nikel (1M) nitrat 1 functional diagram ‘node and cathode correct. solution shaded, whole spoon immersed 2 label: nickel spoon nickel(ID nitrate solution 1 gambarajah berfungsi: anod dan katod betuJaruan dilorek sud direndam sepenulva 2abel : Nikel.suu farutan nied (1) nivar {ecany solution with nickel) /niekel(I]) ion} Baanode: Ni—> Ni?" +2e//Ni— Ni #3e [refer solution) cathode : Ni*+2e— Ni fl Ni** 43e— Ni Arjuk larutan] (b) Experiment [ I produet = oxygen Hasil -oksigen 2 hydroxide ion is discharged Ton hidvoksida dinyaheaskan 3.hydroxide ion is lower than iodide ion in the electrochemical series on hidroksida di bawahs ion iodida dalam sirielektrokimia, Experiment II 4. produet = iodine Hasil =iodin Suiodide ion is discharged Ton iodida dinyahoaskan 6 iodide ion is more concentrated Jon iodida lebih pekat (©) TZn 2Cu 3.CuSO; solution Procedure 4, Zine strip and copper stip are cleaned with sand paper Jal zink dan jatur kuprum digosok dengan kertas pasir| dd WS pzeyn6y10rr ‘Skema Jawopan Modul Sukses Kimia Kertos 2 Soalan Percubaan Negeri 2016 S.A beaker is filed with 0.1 mol dm of eopper(If sulphate solution until hal full Sebuah bikar disi dengan larutan kuprum({h sulfat 0.1 mol dn? sehingga separuh bikar 6.Zine stip and copper strip are dipped into the solution Jalur ink dan kuprum dicelup ke dalam larwtan “both strips are connected to voltmeter via eonnecting wire kedua-dua jalur disambungkan ke voltmeter melalui wavar penyambung '8.Zine release electron to form zine ion zink menderma elekiron dan membentuk ion zink 9, copper ion receive electron to form copper Jon kuprum({1) menerina elekaron dan membentuk kuprum 1 10 0.Wwhen electron move from zine to copper pointer of voltmeter deflect H> 1 4 \Persamaan seiengah: 211° + 2e-—»Hs o Cal XT SeEN Cal Vise Eneray change ‘Chemical energy to | Electrical energy to chemical Perubahantenaga | Sees energy energy Tenaga kimia kepada | Tenaga elektrik kepada tenaga elekirik tenaga kimia Terminal Posilive: copper Positive: copper Terminal Positif: kuprum Positif: kuprum rel Negative: zine Negative: capper Negatifzink Negaaif: kuprum Half equation atthe | Cu #2 Cu Cas OF Fe positive terminal Persamaan setengah 11 di terminal posiaf dd WS pzeyn6y102 ‘Skema Jowapan Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Tal equation atthe | Zn Za +32‘ Cw Fe > Ow negative terminal i Persamaan setengah ‘di terminal negatip Observation atthe | Brown solid Copper plate becomes positive terminal | deposited// copper | thinner LH Pemerhatian di Plate becomes thicker | Kp ingan kuprum menjadi terminal positf Pepetal perang mipis terenap’/kepingan kuprum menjadi tebal Obsewvation athe | zine plate becomes | Brown solid deposed? bt negative terminal | thinner copper plate becomes thicker Pemerhatian di Kepingan zink Pepejal perang terminal negaiif | menjadi nipis terenap/kepingankuprum ‘menjadi tebal Max 6 (]__|[Name oft more electopostive metal and name of a Tes elecropostive metal] T [Nama satu fogam yang lebih elektropositf dan nama satu logan yang kurang lefektroposinf] [Name of one suitable salt solution] 1 [;Nama sane larutan garam yang seswai] Procedure! prosedir: 1. Clean {named metal] with sandpaper 1 Bersihkan flogam yang dinamakan] dengan kertas pas. : 2. Pourlbout 5 em of named salt solution} into atest tube Tuangkan lebih kurang 5 om (larwan garam yang dinamakan] ke dalam sara tabung ui B. Place [named metal] into the solution, I Letakkan {legam yang dinamakan) ke dalam larwan itu 14. Record the observation in a table, Catarkan pemerhatian ai dalam satu jadual. [5. Repeat the experiment by using [another named metal]. 1 5 lang eksperimen dengan flogam fain yang dinamakan) [Expected results! Keputusan yang djanghat ‘Metall Logam “Observation! Pemerhatian [Namne ofa more eleciropesitive | Deposit formed I metal] Enapan terbentuk {Nama satu logam yang lebih elektroposit TName of a less electropostive | No change metal] Tiada perubahan {Nama satu logam yang kurang elektroposi , A [Balanced equation] T T Persamaan seimban Toul) 20 dd WS pzeyn6y1013 ‘Skema Jowapan Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Kelantan: Question 9 SOALAN PENERANGAN MARKAH| 9] (@) | Regunaan sel elektolsis 1. Penyaduran logam i 2. Penulenan logam 3. Pengektrakan logam 3 © Aspe Sax SAY ElektrodP | ElektrodQ | ElektrodR__| lektrod S (Terminal bagi Positif! ano Negatitf Katod- Positif katod | Negatif/anod res) eclua-dua sel Ton-ion yang GF 1F, SOP, OFF Ga IF, SOF, OFF hadi dalam 1 elektroit Pemerhatian | menipis menebal menebal ‘menipis 1 Setengah | CudCu*42e, Cut2e>Cu | Cut2edCu | AMSAT +30 persamgan oa Bahan dan radas Kunei, kepingan kuprum/argentum, larutan kuprum(l) sulfavlarutan argentums nitrat, wayar | 1 penyambung dan klip buaya, bateri, bikar dan kertas pasir. Susunan Radas : Radas berfungsi 1 Label 1 Prosedur 1. Bersibkan kunci dan kepingan kuprun/argentums dengan kertas pas 2. Masukkan larutan kuprum({l) sulfa/argentums nitrat kedalam bikar schingga separuh i penuh 3, Sambungkan kunci kepada katod bateri manakala kepingan kuprum kepada anod bateri ‘dengan wayar penyambung dank lip buaya, 4. Kediu-dua elektrod dicelup ke dalam larutan di dalam bikar 5. Pemerhatian dirckodkan 1 Pentti vised Peta Aad Glenn a aaa es 1 Kated Fendalperang reap " JUMLAH | 20 dd MWS Ipzeyn6y10Pulau Pinang: 14 ‘Skema Jowapan Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Chapter 7 — Acid and Base lestion 8 ‘Question | ‘Mark Scheme Total 8@ |] @ ‘Acid A Hydrochlorie acid (aevept any strong avid) Asid A + Asid hidroklorik(terima sebarang asidkuat) ‘Acid B : Ethanoic acid (accept any weak acid) Asid B : Asid etanoik (terima sebarang asid lemah) wo “Ae A is strong acid, acid Bis weak acid Asid A tala asid kuat, asid B ialah asid femal ‘Acid ionizes completely in water, acid B ionizes partially in water Asid mengion lengkap dalam air, asid B mengion separe dalam air Acid A. produces high concentration of H’ ions, acid B produees low concentration of HP ions Asid A menghasitkan kepekatan ion H” yang tinggi, asid B menghasilkan kepekatan ion H” yang rendah. BO) Hydrochloric acid can react with magnesium fo form sall and hydrogen gas _Asid hidrokiork boleh bertindak balas dengan magnesium untuk menghasilkan garam dan gas hidrogen 2QHCL +Mg > MgCk + H: Hydrochloric acid ean react with calcium carbonate to form salt and carbon dioxide and water ‘sid hidroklonk boleh bertindak balas dengan kalsium Karbonat untuk menghasian ‘garam, karbon dioksida dan air 2HCI + CaCO; > — CaCh + CO; + HO so | oO Solvent X Methyl benzenei/ propanone [any organic solvent] PelarutX: Metil benzene / propanon [sebarang pelarut organik} Solvent ¥: Water PelanutY: Air wo "Ammonia in solvent X exist as molecule Ammonia dalam pelarut X wujud sebagai molekal ‘Ammonia in solvent Y can ionizes Ammonia dalam pelarut ¥ boleh mengion Produce free moving ions _Menghasilkan ion-ion yang bergerak bebas 8O®] @ Nitrogen wo % Nin (NH)SO, prars x 100=21.21% JAH) %N in CO(NES) 2x Md [DH6+ 2020) ‘Urea is the better fertiliser because it has higher percentage of nitrogen element, Urea adalah baja yang lebih baik kerana menpunyer pereaaus unsur nitrogen yang lebih tinggi Total 20 dd WS pzeyn6y1058 ‘Skema Jowapan Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 i | [able to state the name of acid X and alkali ¥ correctly] Sample answer; ‘Acid X: Sulphuric acid 1 Alkali Y: Sodium hydroxide // potassium hydroxide 1 2 ii | [able to explain why at the end point of titration, ammeter still give the reading correctly| Sample answers I: still have free moving ions in the beaker 1 2: the ions carried the electric current 1 2 ® i. | [able to write the chemical equation for the reaction correctly| Answers NaOH +NH-Cl> NaCl-+H:0+NHs + Correct formula of reactants 1 + Correct formula of products 1 2 i, | [able to caleulate the mass of ammonium chloride correctly| ‘Sample answer; 1 PI: mol NaQH == 0.0025 mol 2: Mol of NH.CI = = 0.056 mol 1 3: From the equation: 1 mol NaOH react with 1 mol NH.CI 1 0.0025 mol mol NaOH react with 0.0025 mol NH.CI 1 3: Mol of NH.CI that has not been reacted: 0,056 — 0.0025 = 0.0535 mol P4: Mass of NH,CI that has not been reacted: 1 0.0535 x 53.5 = 2.862 gram Max4 © i | [able to state the name of acid P and acid @ correctly] Sample answers 1 Acid P : ethanoie acid (any name of weak acid) 1 Acid Q : hydrochloric acid // nitric acid // sulphuric acid (any name of strong acid) 216 ‘Skema Jowapan Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Melaka: Question 10 0. [@ @o ‘Solvent X7 terachloromethane 7/methylbenzene 7 (bame any organie Sven) Solvent ¥ : water LX pelarut: tetraklorometana // metlbenzena // (nama apa-apa pelarut organik) Pelarut¥: air w Procedure 1. Add | spatula of zine/ magnesium aluminium( solid metal carbonate can be used fo replace metals above) into the two beakers containing hydrogen chloride in solvent X and solvent ¥ respectively 2. No changes in beaker A 3. Gas bubbles formed in beaker B 4 Hydrogen chloride in solvent X / tetrachloromethane / methylbenzene does not show acidie property/ HI is absent 5. Hydrogen chloride in water shows acidic property/ H” is present Prosedur 1. Tambah I spatula zink/ magnesium / aluminium (pepejat karbonat logam) boleh digunakan untuk menggantikan logam di atas) ke dalam dua Bikar mengandungi hhidrogen klorida dalam pelarut X dan pelarut ¥ masing-masing 2. Tiada perubahan data bikar A 3. Gelembung gas terhentuk dalam bikar B 4. Hidrogen Korida dalam larutan X/tetraklorometana / methytbenzene tidak ‘menunjubkan berasid harta/ HL tidak dir 5. Midrogen Korida dalam air menunjukkan sifat berasid /H + hadi HL Max 6 i) Oo T Hydrogen chloride in solvent Y/ water 2 Dissociales! ionised to form H’ //show acid properties 1. Hidrogen klorida dalam larutan Y ‘air 2. Mengion di dalam air membentuk H" // 7) ‘Able to describe an experiment to prepare Zine chloride Salt from hydrochloric acid and a suitable substance Procedure 1. Measure [20-100Jem’[0.1- 2.0 mol dnr?I of hydrochloric acid by using measuring eylinder Pour the solution into a beaker and heat it Add zine oxide / zine carbonate / excessively Stir the mixture Filter the mixture ‘The filtrate is heated until saturated / 1/3 from the initial volume The saturated solution is cool at room temperature Filter the sat formed 10. Rinse the salt with distilled water 11. Dry the salt with filter paper Dapat menjelaskan eksperimen untuk menyediakan garam larut dari larutan shidrogen klorida dan sebatian yang seswai Prosedu: 1. Skat (20-100 fem! [.1-1.0moldne'} asi hidroklorik menggunakan silinder pensukat dan 2. Tuangkan ke datam bikar Tambahs zinkohsida /zink Karbonat/ zink ke dalam bikar tad sehingga berlebihan 4. Kacau campuran tersebut 5. Turas 6 Hasil surasan dipanaskan sehingga 13 daripada ispadi asal 7. Keringkan hasil turasan tersebut pada sult bilik 8 9 Turas pepejal yang terbentuk Bilas dengan air suling 10. Keringkan pepejal tersebut dengan kertas turas. 10 TOTAL. dd WS pzeyn6y107 ‘Skema Jowapan Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Kelantan: Question 10(a) SOALAN PENERANGAN MARKAH 10 /(@) | 1 Dengan menggunakan pipet, sebanyak 25 cm natrium hidroksida 1.0 mol dm-3 disukat. | — 1 2. Larutan natrium hidroksida dituang dengan berhati-hati ke dalam kelalang volumetrik 100 em* 3 Air suling ditambahkan kepada sehingga tanda sengatan. 4 Kelalang volumetrik ditutup dengan ketat dan goneang beberapa kali untuk memastikan Jrutan bereampur sekata 1 1 1 Chapter 8 Salts MRSM: Question 8 (b) and (e) Mark No Mark Scheme Sab [Total 8b) | PL. Carbon dioxide CO: 1 2. Bubble’ flow / channel /pass the gas through lime water i PS. Lime water turns milky / chalky / cloudy 1 3 wo PI. Add 2 em’ dilute sulphuric acid followed by 2 em® iron(II) sulphate sofution into [1 test tube containing solution $ and shake: i P2, Add concentrated sulphuric acid slowly/earefully PS. A brown ring is formed, 1 3 8©@O | PL Barium chloride /Barium nitrate T P2, Soaium sulphate / Potassium sulphate / Ammonium sulphate 1 2 wo PI. Filter the misture and rinse T 2. Dry between two filter papers /using oven ‘i A Total 20 ‘Terengganu Question 10 10 | (@) | @ | Leadcnitate Acid reacts with base/ metal oxide! metal hydrowide/ metal carbonate metal 1 Lead(ID sulphate Double decomposition //Previpitation reaction 1 2 Gi_| Lead(tD nitrate sotution and 1 sodium sulphate* 1 2 [any suitable solution which contains sulphate ion, SO#] o T Pour [20-100] em nitric acid [0.1 = 2.0] mol dn to a beaker T 2. Add PoOIPCOs. 1 3. Stir the mixture. 1 4. Until some solid remains unreacted / excess. 1 5. Filter off the excess solid 1 6. Evaporate until ¢ 1/3 of volume of solution / saturate. 1 7. Leave to coo! until crystal formed. 1 8. Filter and dried between filter paper. 1 9. PbO + 2HNOs > Ph(NOs: + HOM PbCOs + 2HINOs > Pb(NO3): + CO: + HO HH 10 dd WS pzeyn6y1018 ‘Skema Jowapan Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 oO ‘Sample Answer Pout the solutions into two different test tubes Add barium nitrate® solution into the test tubes, White precipitate formed. Suiphate ton, SO.* present the solution is sodium sulphate No precipitate formed. No sulphate ion, $0,° the solution is sodium chloride *[Aecept other methods that can be used to detect chloride ion] Kelantan: Question 10(b) dan (¢) T 1 TotaL[ 20) SOALAN PENERANGAN MARKAH b) R= Kuprumill) kerbonat S=Gaskarbon dioksida Kuprum(l oksida Kuprumdl) itrat U CuO +2HN0s > CutNOs): +H20 © 1. [25 -200] em asid nitrik eair [0.5 — 1.0] mol dm- disukat dan dimasukkan ke dalam bikar dan dipanaskan, Serbuk plumbumd(l) oksida ditambahkan sedikit demi sedikit sehingga berlebihan sambil dikacau, CCampuran larutan dituras untuk mengasingkan baki turasan, PbO + 2HINOs > Pb(NOs)2. +H: [25 -150] em'larutan plumbum() nitrat (0.5 — 1.01 mol dm-3 disukat dan + NasSOi> PSO; ++ 2NaNOs ulfat [0.5 1.0] mol dm-3 disukat dan dimasukkan ke JUMLAH. 20 10 dd WS pzeyn6y109 ‘Skema Jawopan Modul Sukses Kimia Kertas 2 ‘SoalanPercubaan Negeri 2016 Chapter Manufactured substance in Industry Melaka: Question 8(a) No Rubric Total marks o Tw [O | Xrwphurieaetd T YY sulphur diovide 1 2 @ | Astetlizer 1 H:SO, + 2NHs — (NH,):S04 [Comrect formula of reactans& produet 1 [Balanced equation) 1 3 Ga] Nitrogen gas and hydrogen gs Mix wih ratio 1-3 7 Nz + 3H: — 2NH3 1 [Comet chemical formula of reactants and balanced) Temperature 400 300% 1 Pressure 200 atm Caulyst =Iron amy nv0] 11 4 GH | Seal become sic Taco rain T lof lkeriver decreases, 1 aquatic life die//Building damag 1 3 Pahang: Question 7a) Sub- Question Number Answer Mey | Mak 7 a ‘Natural polymer Synthetic polymers Rubber Polythene deal mil 4 Starch pyc (a) H CHsH H jelagien! ; H—c=C—C=C—-H 1) 2 isoprene f2-methylbu-l3-diene Pulau Pinang: Question 8(d) 8@ (@) | Nitrogen T Gi) | % Nin (NHy)SO, = 2x14 x 100=21.21% I 2[14+4(1) 4324416), %NinCOMH: =_2x 14 x 100= 46.67% 1 12+16+ 2[1442(1)] Urea is the better fertiliser because it has higher percentage of nitrogen element. Urea alah baja yng lebih Ba kerana menpuryelperamsunsurnirogen yang | iebih nga 1’ Toal | 20 dd WS pzeyn6y10Kedah : Question 8 8 @ @ iy o @ iy 20 ‘Skeme Jawapon Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Chapter 10 - Rate of Reaction Rate of reaction i the change in the volume of hydrogen gas released per unit time taken Concentration 1 Comreet formula of reactants and products 2.Balanoed chemical equation Zn+2HC1 ZnCl; +H: Experiment [= $0 2,5 en's"! 20 Eyperiment I= 30 //1.0 cn?s" 50 - Rate of reaction in experiment I is higher than higher Experiment II = The concentration of aeid in Experiment [higher than in Experiment IL / ‘Number of hydrogen ions per unit volume in Experiment I bigger than in Experiment IL ~ Frequency of collision between hydrogen ions and zine atoms in Experiment I ishigher ~ Frequency of effective collision betwoen particles in Experiment I is higher than in Experiment I. = kadar tindak balas dalam eksperimen I lebih tinggi daripada eksperimen IT = kepekatan asid dalam eksperimen I lebih tinggi daripada eksperimen IL bilangan ion hidrogen per unit isipadu dalam eksperimen I lebih tinggi daripada eksperimen IT ~ _frekuensi perlanggaran di antara ion hidrogen dengan atom logam zink dalam eksperimen I lebih tinggi daripada eksperimen Il ~ _frekuensi perlanggaran berkesan di artara zarah dalam eksperimen I lebih tinggi daripada eksperimen IT A Manganese (IV) oxidevlead (II) oxidevlead (IV) oxide Mangan (IVjoksida’ plumbum (1D oksida’ plumbum (IV)oksida | Label of energy on vertical axis 2.The position of the energy level of the reactants is higher than the energy level of the product, 3.Comteet position for Ey 4.Correet position for E Label ‘Tenaga’ pada paksi menegak 2kedudukan aras tenaga bagi balan lebih tinggi davipada aras tenaga hasil 3.kedudukan yang betul bagi Ey “Lkedudukan yang betul bagi F's dd WS pzeyn6y10at ‘Skema Jawopan Modul Sukses Kimia Kertas 2 ‘Soalan Percubaan Negeri 2016 ZnCk + Ha Reaction the presence of catalyst provide an alternative pathway 2. with a lower activation energy in ereated. 3. number of colliding particles which are able to overvome the lower aetivation ‘energy increases 4. frequency of effective collision increase 4 1. dengan kehadiran mangkin, sats latwan aliernatif 2. dengan renaga pengakifan lebih rendah rerbentuk 3. maka, bilangan zarah berlangear yang dapat mengatasi tenage pengaktifan yang lebih renal int bertambah 4. kadar tindak batas bertambah Total 20 Melaka : Question 9 9 [(@) | |. The smaller the size of best the larger the total surface arca of beet exposad to heat 2. More heat absorbed DO] P (Name of suitable metal carbonate Example CCaleium carbonate // Magnesium earbonate(/ Zine carbonate / Q: [Name of suitable acid} Example Hydrochloric acid // Sulphurie acid // Nitric acid [Chemical equation) Sample Answer CaCO; + BHC] > CaCl: + HO + CO: {Correct formula of reactants and products] [Balanced chemical equation] 4 dd WS pzeyn6y1022 ‘Skeme Jawapon Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Experiment = T wi) 5 1 Experiment = 1 1 4 oO Procipitate : Sulphur T T Materials: (0.2 mol dm-3 sogium thiosulphate, 1.0 mol da-3 sulphuric acid, a piece of white paper marked *X’ at the centre. Apparatus: 150 cm3 conical flask, stopwatch, 50 em3 measuring cylinder, 10 em3 measuring cylinder, thermometer, Bunsen bumer, wire gauze. Procedure: Using a measuring cylinder. 50 em3 of 0.2 mol dm-3 sodium thiosulphate solution is measured and poured into-a conical flask The conical flask is placed on top of a piece of white paper marked “X’ at the centre, Sem3 of 1.0 mol dm-3 sulphuric acid is measured using nother measuring evlinder ‘The sulphurie acid is poured immediately and carefully into the conical ask, AL the same time, the stop watch is satarted ‘The misture ina conical flask is swirled Phe ‘X” mark is observed vertically from the top of the con solution, cal flask through the ‘Phe stopwatch is stopped once the *X" mark disappears from view. ‘Step | ~7 are repeated using $0 em3 of 0.2 mol dim-3 sodium thiosulphate solution at 400C, 500C, 60 oC by heating the solution before 5 em3 of sulphuric acid is added in Conclusion ‘The increase of temperature, increase the rate of reaction Max 9 20 dd WS pzeyn6y1023 ‘Skeme Jawapon Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 ‘Negeri Sembilan : Question 8 Question ‘Mark scheme ‘Sub | Total Mark _| Mark Bla) | Able to state te four factors that afer the rate of reaction “Answer 1 Size ofthe reactant /he total surface area of the reactant 2. Concentration of the reactant 3. Temperature of the reactant 4. Catalyst 5. Pressure [any four correctly] @®)__| Able to state the condition or the contact process ‘Answer: 1. Temperature: 450 "C-550"C 1 3 2. Pressure: Jat 1 3. Catalyst :vanadium(V) oxide 1 (OW _ | Able 1 plot the graph correctly ‘Sample answer I. The axes are labelled together with unit 2. The uniform seale and occupied 50% graph paper 3. All the points are transferred correctly 4. Draw smooth curves and labeled for experiment I / I [Refer to page 14] TWD | Able o calculate the average rate of reaction ‘Sample answer: I. Average rate of reaction for experiment | = 32.00 1 210 = 0.15 ems! 1 2. Average rate of reaction for experiment II = 32,00 4 150 1 =0.21em! s! (MD) | Able to explain the differences inthe rate of reaction ample answer: The rate of reaction of Experiment ITs higher 2. Experiment IL is using zine carbonate powder/ smaller size 3, The smaller size of zine carbonate has larger total surface area 4. The collision frequency between H” and ZnCOs in Experiment Il is higher 5cThe effective collision frequeney in Experiment IL is higher Total 20 dd WS pzeyn6y10Pahang: Question 9 24 ‘Skeme Jawapon Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Question Number ‘Answer Sub- Mark ‘Mark a Tw | 1 Correet formulae of reactants and product 2.Balanced equation 2HCI+CaCOs > CaCl +H:0+ CO: 3, n= 20x40 / 0.08 mol 1000 4, mole ratio 2 mol HCI produce I mol COs 0.08 mol HCI produce 0.04 mol CO; 5. volume = 0,04 x 24 dm*= 0.96 dent 7 1 ® 1. Rate of reaction in Experiment Il is higher than Experiment I 2, The kinetic energy of particles in Experiment IL is higher 3. Froquency of collision between H” and CaCOs in Experiment Il is higher 4, Frequeney of effective collision in Experiment Il is higher ©) Copper (ID sulphate solution Procedure 1. [25-50] em'of[0.1-1.0] mold? of hydrochloric acid is measured and poured into the eonical flask About 5.0 g of zine granules is weigh A burette is filled with water and inverted into a basin containing water ‘The granulated zine is added into the conical flask Sem3 of 0.5 mokim-3 copper (ID sulphate solution is added into the conical flask Immediately the conical flask is closed and connect it using delivery tube to the burette ‘The stopwateh is started ‘The conical flask is shaken steadily Record volume of hydrogen gas produced every 30see interval for $ minutes eer aneen Concentration // size of reactant TOTAL 20 dd WS pzeyn6y10Perlis: Question 10 25 ‘Skeme Jawapon Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Question Number ‘Answer Mark ow X: (Name of any metal Siuated above Cuin the clectrochemical series) Y: (Name of any acid) Sample answer Xt Magnesium //Zine / Aluminium [Rejeet: Sodium / Potassium] Hydrochloric acid // Sulphurie acid // Nitric acid [Accept: weak acid] Chemical equation: Correct formula of reactants and prexlucts Balanced. Sample answer Mg +2HCI— MgCl: + Hs 1 1 wo Experiment 1 Average Rate of Reaction Experiment I Average Rate of Reaction 300 = Oem's! 3020 = 1S5em\ [With correet unit) Gi, 1 Rate of reaction in Experiment I is higher than Experiment IT The concentration of acid in Experiment Lis higher than Experiment Il The numberof hydrogen ions per unityolume in Experiment I higher than Experiment I Frequency of collision between hydrogen ions and atoms of Xin Experiment lis higher than in Experiment I Frequeney of effective collision between the particles in Experiment [ her than in Experiment I dd WS pzeyn6y1026 ‘Skema Jawopon Modul Sukses Kimia Kertas 2 ‘Soalan Percubaan Negeri 2016 SBP: Question 10 10 |@ [i | [ableto identify metal O correctly] (Q: Magnesium’ Mgi! Zine/ Zni/ Aluminium / AM! Iron! Fe ii, | lable to explain the difference in rate of reaction for Experiment Tand Experiment II based on collision theory correctly] Sample answers PL: Experiment in set I has higher rate of reaction than sot 2: The concentration of nitric acid is higher. 3: The number of hydrogen ions per unit volume of acil is higher. 4: The frequency of collision between hydrogen ions and Q atoms is higher PS: The frequency of effeetive collision is higher. [or vice-versa] iit_| [able to describe the experiment to compare the rate of reaction of Experiment I and Experiment II correetly] Sample answer; Procedure: 1. Fill water half-full in a basin, Fill water in a burette and invert it over water in a basin 1 Record the initial burete reading Measure 25 em’ of 0.5 mol dm nitric acid and pour into a conical flask Weigh 5 g of metal Q powder and quickly put in « eonical flask, Connect the stopper with a delivery tube immediately into the burette. Atthe same time start the stopwatch and shake the conical flask. Record the burette reading at interval of 30 seconds until the reaction complete 8. The experiment is repeated by using 25 em of 1.0 mol dm? nitric acid. 1 MawEEN Interpreting data: Graph of volume of hydrogen gas against time Volume of Ho/ em® aan OD / Exp Time/s Pl: Correct label of axes with unit, 1 2; Correet curve for Se Experiment I and Se Experiment II with label I 0 dd WS pzeyn6y107 ‘Skeme Jawapon Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 (Chapter 11- Carbon compounds Melaka — Question 7(a) 7 | (a) | (| (Able to state the correct name of the aleohol] Answer: Ethanol Able to state 3 correct propertis of ethanol Sample answer Miseible in waier Colouriess liquid Low melting/ boiling point easy to evaporate Cannot conduct electricity/non electrolyte [Max 3 marks: 3 answer for physical | 14141 | 4 @ | [Abie t name the reaction comreally] T Answer: Esterification [Able to write the correct chemical equation Tor the reaction] 2 1. Comeet formula of reactants 2. Correet formula of products ‘Sample answer (G:H:OH + C:HsCOOH ~ C:H:COO G:He + 120 [Abie to write the correct name of the ester] T Ethyl propanoate [Able to draw correct Siructaral formula of the substance] T HH ¢-¢-H Aa [Able to write the correct general formula of ester] T 3S Answer CsHaps1 COOC Han dd WS pzeyn6y1028 ‘Skeme Jawapon Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Pahang: Question 7(b) Question Number “Answer ‘Sub- Mark Mark o @ 1. Becieria fiom the air enter the latex 2. Bacteria will produce lactic acid / H’ ions which neutralize negatives charge of the protein membrane /rubber molecules 3. The rubber molecates will be collide with each other and cause protein membrane broken 4, Rubber polymer are released and lump together /eoagulate wo 1. Membrane protein of latex are negatively charge Ethanoie Acid “Amnmonia Contains H'/ positive ions | contains OH /negative ions FF ions neutralized the ‘OFT does not neutralize ‘negative charge on the protein | negative charge/ remain ‘membrane negative/ OH from alkali neutralise any acids that may bbe produced by bacteria The membranefrubber ‘The rubber particle repel each pparticles collide with each | other other Membrane burstoreak // Membrane does not Rubber coagulate bursvbreak/? polymer does not coagulate © oO Reaction X : Neutralisation ‘Compound Z.: Ammonium sulphate wo 1. MoLELSO; = MV / 1000 = 2.0.x 100/ 1000 =0.2 mol 2 Ratio between 11,804 and compound Z/ (NH):SO, Tmol > I mol 0.2 mol : 02 mol 3. Mass of compound Z,= mol x molar mass = 0.2132 = 264g TOTAL dd MWS Ipzeyn6y1029 ‘Skeme Jawapon Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 ‘Terengganu — Question 9 9 @ H- 2-methylpropene Hn ne Wesel C-C=C-C-H | i H H But-2-ene © Reaction: Oxidation Reaction II: Dehydration Reaction IIT: Esterification Ethanol ‘Aleohol OH HCHO © 10, ‘Alcohol Carboxylic acid Procedure Pour 2 ~ 10] em’ of glacial ethanoie acid into boiling tube. ‘Add [2 ~ 10] em of absolute ethanol into the acid ‘Add [1 ~ 2] em’ /a few drops of concentrated sulphur acid to the misture ‘Heat the mixture Equation CH;COOH + CHOH > CH;COOCH; + HO [Functional diagram) [Labelled] Pour fadd bromine water /aciified potassium —manganate( VII solution into test tube containing the gas ‘The brown / purple of bromine water /eeidified potassium ‘manganate VI) solution is decolourised TOTAL Max 10 20 dd MWS Ipzeyn6y10Kedah: Question 7 7 @ ob) © 30 ‘Skeme Jawapon Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Fidroearbon A | Hydrocarbon B Hidrokarbon A_|_Hidrokarbon B Functional group Single bond | Double bond Kumpulan befungsi_|_Matan ungeal | Tkatan ganda dua Chemical formula Cis CoH Formula Kimia Homologous series “Alkane ‘Alkene Siri homolog Alana Alkena General formula Colas CHa Formula am Molecular formula / formula mofekul Homologous series = alkene / alkene Because it contains double bond / mengandungi ikatan ganda dua CH, +1202 €; Ethanol / ezanol OH CH,COOH -COOH, carboxyl group L= ethanoic acid /asid etanoik X= hydrogen gas / gas hidrogen K= ethyl ethanoate /e! etanoat ‘Y= carbon dioxide gas / gas karhon dioksida Esterification / pengesteran L. Correct formula of reactant and product 2, Balance equation CHsCOOH + CHOH 9CHCOOC:Hs + H:0 Catalyst / mangkin : concentrated sulphuric acid / asi sulfurik pekat Total 10 20 dd WS pzeyn6y1031 ‘Skema Jawopan Modul Sukses Kimia Kertas 2 ‘Soalan Percubaan Negeri 2016 ‘Chapter 12— Oxidation and Reduetiom Kelantan : Question 7 SOALAN PENERANGAN MARKAH @ [a 1 ‘Air lat mengandungi garam 1 Garam merupaksn suatu elektrolit 1 3 © Oksigen Air ‘Oksigen Karat. iS Karat oan WA x Lj Katod :02+H,0+4e> 40H — Anod:Fe > Fe” + 2e Gambar rajah berlabel: Titisan air, besi, anod, Katod Setengah persamaan di nod 1 engaliranelektron 1 3 © XX Kuprum 1 1 Y Zink Pengaratan berlaku kerana besi lebih elektropositif berbanding kuprum, Pengaratan tidak } berlaku kerana Zink lebih elcktropositif berbanding besi U @ ‘A: Air bomin /klorin//Tarutan KMnO4 berasic Be Zink ‘Tindak balas I Fe mengalami pengoksidaan kerana kehilangan elektron, Air bromin mengalami penurunan kerana menerima elektron Fe > Fete Brs+2e 2Br Larutan hija kepada kuning/perang ‘Tindak balas I Fe mengulami penurunan kerana menerima elekton, ‘Zink + mengalami pengoksidaan kerana kehilanganelektron, Fe" te 9 F Zn > Za 26 Kuning/perang kepada hiju 1 1 1 Il 1 may 10 JUMLAH 20 dd WS pzeyn6y1032 ‘Skeme Jawapon Modul Sukses Kimia Kertas 2 Soalan Pereubaan Negeri 2018 Pahang: Question 10 ‘Question ‘Answer Sub- | Mark Number Mark 10 | @) | 1. Zine ismore electropositive than iron 1 2. Zine oxidise! zine release electron to form Zn" i 3. Fe does not present so the roof of Maimun’s house does not rust 4, Zine isthe sacrificial metal 1 4 (@) Suitable example: Zine and Copper(ID nitrate solution TH *any suitable answer 1. Oxidation number of zine increases fiom 0 to +2 1 2. Zine undergoes oxidation i 3. Oxidation number of eopper decreases from +2 10.0 i E 4. Copper undergoes reduction \: Question 10 Question Mark scheme Sub Total mark | _ mark TO) _ | ABle to Weniifrsolution-X and ¥, and give explanation comely Sample answer 1, X= Iron(l) sulphate/eSOy/soluble salt solution containing 1 Fe ion 2. Y= Potassium iodide // K/soluble salt solution containing 1 ion Br ion 1 3. Oxidation number ofiron increases from +2 043 1 4 Oxidation number ofbromine/iodine inereases from -1 10.0 1 5. X= Oxidation, Y = Oxidation 1 6 Fekete 1 7.2 > ke 20 Br -> Br. +20 1 8. MnO + 8H + Se > Mn 4F:0 1 For Y 1 9. Add starch solution 1 I-trichloroethane 1 2 10, Dark blue formed/forown layer formed ForX TT Addl potassium hexacyanoferrateID solution/K Fe(CN)d/ potassium thiocyanate solution/KSCN 12, Dark blue precipitate formedBlood red colouration “Able 1o explain the experiment by including all the aspeot required correctly ample answer Carbon Karbon Acidic posi manganat(¥) i acid SO, — ta at ego) 1, Funetional diagram 4 2. Comet label: Any reducing agent, any owidising agent and dilute sulphuricacid |! dd WS pzeyn6y1033 ‘Skeme Jawapon Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Procedure I 3. Dilute sulphurie acd is poured into a U-tube until half full, 4, Fill one arm of the U-tube with iron(ID sulphate solution and another arm with 1 acidified potassium manganate( VII) solution slowly/earefully/drop by drop. I 5, Immerse carbon electrode into both solutions and connect to galvanomoter/ ‘voltmeter! ammeter/ bulb. 1 6, Record the observation, Observation I 7. The green colour of iron(I}) sulphate solution changes to brown! The purple colour of potassium manganate(VIl) solution changes to @ cotourless // The needle of | galvanometer/ voltmeter deflectodi/bulb lights up 8 8, Correct flow of electron. Toul 20 Chapter 13 ~ Thermochemistry Melaka: Question 7 (b) 7 |(b) | @ | Haba yang dibebaskan apabila 1 mol mendakan argentum Klorida terbentuk TY] o @ Tenaga KC1+AgNOs AH=-655 kImol" AgCl+KNOs ‘gambar rajah yang menunjukkan aras tenaga bagi tindak balas eksotermik 1 label — Tenaga, persamaan kimia atau persamaan ion yang betul, AH/=-.63.5 kkmol* | 1 Gi Pengiraan bil mol AgCl terbentuk Pmarkah Perkaitan antara AH dan haba yang dibebaskan 1 markah Pengiraan perubahan suhu seria unit 2 mark Contoh Jawapan 1, Bil. mol AgCI= Bil mol AgNOs// KCL 1 MV/ 1000 05x20 0.01 mol 1 T000 2. 1 mol AgCl membebaskan 65: 0.01 mol AgCl membebaskan 01 1 0.01 x 63500 3. Haba yang dibebaskan =moO 1 655) (20420) 42 x X x 655_°Ci! 389°C 1 40x42 Nilai perubahan suhu ialah sama //- 3.89°C 1 5. Bilmol mendakan AgC1 tetap sama 1 TOTAL 20 dd WS pzeyn6y1034 ‘Skeme Jawapon Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 ‘Terengganu — Question 8 8] @) | @ | Temperature increase 7 Zine dissolve i! Brown solid formed // Blue solution turn colourless [any ovo} | 141 2 Gi. | EXothermic reaction / Heat released 77 When 1 mol of copper is displaced, 240 kI heat released // Energy content of reactant is higher than product [Any to} | 141 2 Gil) | Mg* CuSO, MgSO, + Cu [Correet chemical formula] 1 [Balanced equation] 1 2 * 20/1000 = 0.04 mol L Heat change 200 4.2 « 15.5 1 13020 IL 13020 « 190.04 /1 325500 17 325.5 L Heat of displacement = - 325.5 kJ mol" L a ©] o TCL 77 FINO T Q=CHCOOH 1 R=NE) solution 1 HCI // HNOs is a srong acid /fionised completely in water L CHACOOH is a weak acid 1 ionised partially in water 1 some of heat release during the reaction is absorb to ionise completely 1 a (i). | Heat of neutralisation is heat released when T mol of water formed, 1 In the reaction, 2 mol of water is formed: Heat of neutralisation — = 1142 1/57 KI mot? 1 2 TOTAL 20 Pahang: Question 8 8 | @) |G | Heat released when 1 mole of water is formed from the neutralisation between hydrochloric acid and sodium hydroxide solution// Heat released when 1 mol of water is formed from the neutralisation betwoen ethanoie acid and sodium hydroxide | solution, dd WS pzeyn6y1035 ‘Skema Jawopon Modul Sukses Kimia Kertas 2 ‘Soalan Percubaan Negeri 2016 i HCI+NaOH> NaCl=H.0 AH * balanced equation 70H ‘Okimol™ i) Hydrochloric avidin Experiment Is a strong acid which ionizes completely in water while efhanoic acid is a weak acid ‘which ionises partially in water 2, Most of ethanoie acid exist as molecules. 3. Some of the heat releases in Experiment Ili used to ionise the cthanoic acid molecules completely 4. Therefore, Heat of neutralisation for Experiment | is higher than Experiment I @) 0 ii) To reduce heat loss to the surrounding! plastic is @ good heat insulator [Temperature change, ‘Het given out, H ‘Heat given out when I mol of water produced 2730 = “oa =273001 4H=273 KImot" © iil) ‘Unchanged INitvie acid is also a strong acid hence the amount of heat given out ‘will be the same. _ Reaction is exothermie!/ heat released (o the surrounding = Temperature increases = Total energy of reactants is higher than the total energy of the! products + When 1 mol of hydrochloric acid reacts with 1 mol of sodium) hydroxide to produce I mol of sodium chloride and water, 57 kJ heat released = The heat released during bond formation is higher than heat absorbed during bond breaking. TOTAL 2 dd WS pzeyn6y1036 ‘Skema Jawopon Modul Sukses Kimia Kertas 2 ‘Soalan Percubaan Negeri 2016 Negeri Sembilan: Question 9 Question Mark scheme ae Mark |_Mark ‘WAND —_| Able to compare A of set and set Hand explain the answer 1. Hof set is lower // AH of set Il is higher 1 12. Acid X ionises partially in water 1 5. Acid Y ionises completely in water 1 ]4. Some ofthe heat release is used by acid X molecule to ionise completely 1 4 Ad) | Able to sketch energy level diagram of either set Tor set and give two information Sample answer 1. y-avis labelled with Energy and two parallel lines 1 2. Correct enengy level with reactants and products 1 3. Comect AH with unit 1 4, Two correct information correspondent tothe energy level diagram Hi Example ofthe energy level diagram: 5 Energy KOH+HX AH=-54 kJ mol! KX4+H,0, Example of information: 1. Thereaction releases heat energy t surounding 2. Temperature ofthe surrounding increases 3. Total eneray of products is lower than total energy of reactants (Any 2 correctly) Db) | Able to suggest metal Z “Answer: 1 MgiZn i! Fe 1 reject: Pb /Bal/ Ca Able to list the procedure of the experiment 2. Pour [20.0 - 100.0] em of 0.1 - 1.0] mol dm copper(I sulphate into a polystyrene | 1 cup Record initial temperature ofthe solution Add fexcess] metal [2 quickly Stir the mixture using thermometer 6. Revord the highest temperature Able to show the tabulation of results Sample answer: Initial temperature of CuSO. solution NC x Tlighest temperature of the mixture AC y 1 Able to show calculation steps to show how the heat of neutralisation is determined Sample answer 1. Temperature increase = y—x 2. Heat released = (100% 4.2xp = EI 3. Correet substitution of n= MV. 1 1000 1 4, Heat of neutralisation, Q= _E KJ mot! nx 1000 1 | Mast ect Total 20 dd WS pzeyn6y107 ‘Skeme Jawapon Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 Perlis: Question 7 Question ‘Answer Mark Number 7 | @) | Able to-state the ype of reaction and explain ‘Set I: Exothemie ‘The sign of *heat of reaction, 4 His negative 141 Set I: Endothemic ‘The sign of *heat of reaetion, \ H is positive 141 @ Energy NH + No* NHNOs ~ Label Energy comet level of reactants & product = correct chemical equations = AH with positive symbol and unit 1. Heat absorbed from the surrounding 2. The quantity of heat energy absorbed for bond breaking inthe reactants is higher than enerey than heat energy released from the formation of bonds in the products 3. The total energy content of reactants is lower than the product. i (XD | Able fo state hwo errors in the apparanis sebup correctly 1, Metal container and not beaker 2. replace wire gauze with pipe clay triangle w ble to cateulare the leat released correcily Heat released = meO 2004.2 30 1 25200 J/25.2 ki (must show unit, J/ 1) 1 Gil) | Able to calculate the heat of combustion correctly 1 mol= 172 Hf 0.02 1 86 2 aH= 252 1 002 3 =-1260 kimol- I negative sign & unit (kImok 1) 1 (WD | Able to calculate the fuel value correctly 1, Fuel value of ethanol is 1376/46 2. Fuel value of butan-1-ol 2675/7. wo “Able to choose which isthe better fuel correct Butan-|-ol is the better fuel as | g of it releases 36.1 KI 1 Total | 20 dd WS pzeyn6y10Kedah : Question 10 10 @ ©) © @ ai o co) 38 ‘Skema Jawopon Modul Sukses Kimia Kertas 2 ‘Soalan Percubaan Negeri 2016 energy PD* oy + SO AH = -S0 kJmot* PbSO, Y-aves : energy Two different level of energy Pasi ¥ : naga Dua aras tenaga berbeza 1 energy content of reactants is higher // products have less energy content Balen mempunyai tenaga yang lebih banyak’ hasil mempunyai fenaga yang sedikit 2 heat is released during the experiment // this is exothermic reaction haba dibebaskan semasa eksperimen int ialah tindak balas eksotermik 1. Heat of neutralization of exp. Lis higher than exp. IL Haba peneutralan eks.1 lebih tinggi daripada eks. IL 2. HClis strong acid and CHsCOOH is weak acid HClialah asi kuat dan CH COOHialah asid lemah 3. Strong acid / HCl ionized completely and weak acid/CHsCOOH ionized partially in water Asid kuat FICI mengion dengan lengkap dalam air dan asid lemah’ CH.COOK mengion separa dalam air 4, Some of the heat released are absorbed to ionizes ethanoie acid inthe ‘molecules completely sebahagian haba dibebaskan akan diserap wink mengion molekul asid cetanoik dengan lengkap 1, Value of Heat of neutralization is same 2 both experiments contain same number of hydrogen ion 1. Nilai Haba peneuaralan adalah sama Ini kerana kedua-dua eksperimen mengandungi kepekatan ion drogen yang sama banyak Apparatus : Polystyrene cup, thermometer, measuring eylinder, spatula, Radas : cawan polisierin, termometer, silinder penyukat, spatula “Materials: 0.2 mol div® copper(I) sulphate solution, zine powder. Bahan kimia : 0.2 mol dn laruuan kuprum (i) sulfa, serbuk zink Procedure Raedah 1. Measure 25 om3 of 0.2 mol dm copper (It) sulphate solution and pour it into a polystyrene eup. Sukat 25 em? larutan kuprum (I) sulfat 0.2 mol dn dan tuangkan ke dalam cawan polisterin 2. Putthe thermometer in the polystyrene cup and record the initial temperature ofthe solution Letakkan thermometer ke dalam cawan potisterin dan rekodan shu ‘wal larwtan dd WS pzeyn6y1039. ‘Skeme Jawapon Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 3. Add half'a spatula of zine powder quickly and carefully into the 1 polystyrene cup, Dengan cepat dan berhati-hari sambakan setengah spatula serbuk Zink ke dalam cawan polisterin 4. Stirthe reaction mixture with the thermometer to mix the reactants. 1 Kacau campuran tindak balas dengan mengzgunakan termometer untuk memastikannya bereampur 5. Revord the highest temperature reached, 1 Sulu tertinggi yang dieapai direkodkan. ‘Tabulation of date: 5 Tatil temperature of CuSO, solution CC) a Shu aval laruian CuSOs CC) Highest temperature ofthe reaction mixture CC) c Suhu tering cmpuran tidak balas CC “Temperature change °C) Perubahan subs ( Calculation’ pengiraan 1 Number of mole of CuSO: Bilangan mol CuSO; = MV/1000 = (0.2)(25)/1000 = 0.005 mol 1 Heat change! perubahan haba = me(@2-1)=x J Heat of displacement/FTaba penvesaran =x/ 0.005 kJ moll =ykImoll 1 Total 20 dd WS pzeyn6y1040 ‘Skema Jawopon Modul Sukses Kimia Kertas 2 ‘Soalan Percubaan Negeri 2016 MRSME: Question 10 Mark No Mark Scheme Sab] Tort Dao pence Zaemere T PI, Number of mole of butanol = 4G2)+9G)+16+2 _//0.05 mol 2, Heat released = med | = 5004260 Mf 126000 3/126 KI P3. 0:05 mol of butanol burnt completely to release 126000 J 1 mol of butanol released = 126000 J 1 PA. [value is correct 2520kI PS. [Negative sign with correct unit] AH =~ 2520 kJ mot eof, P3 & PS Gi | PI. Some heat is lost to the surrounding/Iheat is absorbed by the apparalus/ Wipod T stand! windshield/copper ean 2, Butanol undergoes incomplete combustion // does not undergo complete A combustion Git) | PT. Butanol//Propanot T 2. Correct structural formula of any isomers 1 3. Name based on isomer in P2 1 3 Sample answer Structural formula Name Propan-1-ol Propan-2-01 Butan-1-ol Butan-2-ol, 2-methylpropan-I-ol 2-methylpropan-2-01 dd WS pzeyn6y10aL ‘Skema Jowapan Modul Sukses Kimia Kertas 2 Soalan Pereubaan Negeri 2018 Ne Mark Sch Mark ° “ee Sub | Total @ | PL. Named metal V 1 P2. Measure [25.0 - 50.0] em’ of [0.1-1.0}mol dm’ copper(II) sulphate solution 1 3, Pour the solution ino aplastic! polystyrene cup i P4, Record the initial temperature of the solution PS. Add quickly excess/ I spatula of metal V powder into copper) sulphate 1 solution 6, Stir the mixture ' PT, Record the highest/masimum temperature reached P8. Data 1 Initial temperature of copper (II) sulphate solution = T)"C Highest temperature = T2 'C 1 PO, Heat given out = 25 x 4.2 (T;~Th)= XJ 1 P10, Number of mole of copper(II) sulphate = MV = ¥ mol 1 1000 1 1 i Max 10 ‘Total 20 Pulau Pinang: Question 10 Question ‘Mark Scheme ‘Sub ‘Total Mark | Mark 10 (a) | @ Hydrogen gas // Natural gas 1 Gas hidrogen Gas asli Hydrogen pas ‘Natural gas Patol Gas hidrogen Gas asl Petrol Environmental | 1. Clean buming? | T.Less earbon | 1. Produee soot 7 impact ero emission’! | emission. carbon emission Kesan terhadap | Pembakaran bersih | Kurang Menghasilkan 141 clam sekitar pembebasan | jelaga/karbon karbon. 2,Doesnotrelease | 2.Less 2. Release greenhouse /earbon | greenhouse! greenhouse! dioxide gas. carbon dioside | carbon dioxide Tidak as as membebasan gas | Kurang Membebaskan rumah hijaw membebaskan gas | gas rumah hijan || 1+1 Karbon dioksida | rumals hija ‘harbon dioksida ‘karbon dioksida GH Saniple answer 7 Sampel jawaparr = Useelectrical appliances that use energy efficiently (energy saving model) Menggunakan peralatan yang cekap tenaga (model jimat tenaga) ~ Unplug appliances that are notin used. 1 Mencabutplag peralatan yang tak digumaken = Replace regular bulb with LED bulb, Menggantian mentol biasa dengan mentol LED. = Allow natural Kighting 6 Membenarkan pencahayaan semulajadi * accept any relevant answer Terima mana-mana jawapan yang refeven dd WS pzeyn6y10a2 ‘Skeme Jawapon Modul Sukses Kimia Kertas 2 Soalan Percubaan Negeri 2016 @) | @ Ethanol has higher heat of combustion than methanol T Etanol mempursai haba pembakaran lebih tinggi daripada methanol (i) 1. Heat of combustion of ethanol is higher than methanol Haba pembakaran etanol lebih tinggi daripada metanol. 2. More carbon atoms per ethanol molecule // Bigger molecular size ofethanol. | 1 Lebih banyak atom karbon per molekul etanol / Saiz molekul etanol yang lebih besar 1 3. More heat is released // Produce more earbon dioxide and water. Lebih banyak haba dibebaskan ‘/ Menghasitkan lebih banyak gas karbon dioksida dan air I © | Sample answer ‘Sampel jawapan Materials and apparatus: Bahan dan radas: 1. spirit lamp filled with [propan-1-ol], water, ‘copper tin, thermometer, tripod stand, pipe-clay triangle, wind shield, measuring cylinder, balance, I Pelita berisi [propan-I-ol}, air, tn kuprum, termometer, tungku kaki tiga, segi ‘iga tanah lit, pengadang angin, silinder penyukat, penimbang. Procedure: Prosedur 2. [100- 250] em of water is measured and poured into a copper ean, 1 [100-250] em’ air disukat dan dituang ke dalam tin kuprum. 3. The initial temperature of water is recorded. 1 Sulu awal air direkodkan, 4. The mass of sprit lamp filled with [propan--ol] is recorded. 1 Jism pelita berisi [propan-1-ol] direkodlan. 5. The spirit lamp is placed under the copper can and the wick of the lamp is lighted | 1 up immediately Pelita itu diletakkan di bawah tin kuprum dan sumburya dinvalakan dengan segera 6. The water is stirred continuously 1 Air sentiasa dikacau 7. The flame is put off when the temperature of water inereases by 30°C. 1 Api dipadam apabila sul air meningkat sebanvak 30°C. 8. The mass of spirit lamp and its content is recorded l isin pelita beserta kandungannyadivekodkan Data: Data: Initial temperature of water = Ty Sun awat air Highest temperature of wat ‘Sun tertinggi air Change in temperature = Perubahan sub air Mass of lamp before burning = mig H:8:0; pembersihan logam // pewama Gi) | Pigmen cat /elektrolit dalam akumulator asid plumbum // detergen (7 agen oT ‘Mana - mana dua hhyjan asic 3, Penggunaan detergen menyebabkan pencemaran air Gi) | 1, Pembakaran polimer sintetik pembebasan gas sulfur dioksida menyebabkan 2. Penggunaan baja berlebihan menggalakan pertumbahan alga dan rumpai HL Mana-mana dua © |o ‘Daun pandan: pewarma i MSG = perisa 1 @) Aspirin: menyebabkan gastrik 77 pendarahan pada dinding usus T 1 Penisilin . menyebabkan alahan / menyebabkan koma / Kematian @ — Datergen ‘Berkesan dalam air Hat 'Boleh menanggalkan semua kotoran tidak membentuk kekat Sabun Tidak berkesan dalam air liat Tidak boleh menanggalkan semua kotoran Garam kalsium dan garam magnesium daripada detergen larut dalam air Hat 1 Jon - ion dalam air lat bergabung dengan ion sabun membentuk kekat, i JUMLAH | 20 dd WS pzeyn6y10