Modul Analisis Bertopik Tingkatan 5 2017 PDF

1 Modul Analisis Bertopik
Soalan SPM 2016 dan Soalan Percubaan SPM Negeri 2016
Modul Analisis Bertopik

Kimia Tingkatan 5
SPM 2017
ChEmisTrY
KerTAs 2
4541/2
Disusun oleh:
Cikgu Mohd Fazdli Bin Mohd Nor
SMK Pesisiran Perdana, Tangkak, Johor
Nama :
Sekolah :
Kelas :
To Excel in Chemistry is to Love Chemistry

©Mohd Fazdli Bin Mohd Nor, SMK Pesisiran Perdana,Tangkak SPM 2017, Kimia 4541 A+
Rate of Reaction … 3-7

Carbon Compounds … 8-25
Oxidation and Reduction …26-38
Chemical for Consumers …38-52
Terima kasih kepada semua guru guru Kimia Tulen Malaysia yang sudi
berkongsi bahan bahan untuk kejayaan pelajar kita. TQVM
Chapter 10 : Rate of Reaction
[Terengganu 2016, No 4]
4 A student carried out two experiments to investigate the factor that affects the rate of reaction.
Table 4 shows the results of the experiments.
Seorang pelajar telah menjalankan dua eksperimen untuk menyiasat faktor-faktor yang
menpengaruhi kadar sesuatu tindak balas. Jadual 4 menunjukkan keputusan bagi eksperimen-
eksperimen tersebut.
Volume of gas collected

when magnesium reacted
completely /cm3
Experiment Diagram
Isipadu gas yang
Eksperimen Rajah
dikumpul apabila
magnesium lengkap
bertindak balas /cm3
m g of magnesium ribbon
m g pita magnesium
I 50
5 minutes
5 minit
0.5 mol dm-3 hydrochloric acid in excess

asid hidroklorik 0.5 mol dm-3 berlebihan
m g of magnesium powder
m g serbuk magnesium
II 3 minutes 50
3 minit
0.5 mol dm-3 hydrochloric acid in excess

asid hidroklorik 0.5 mol dm-3 berlebihan
Table 4 / Jadual 4
(a) From this experiment, state the meaning of rate of reaction.

Daripada ekperimen ini, nyatakan maksud kadar tindak balas.
…………………………………………………………………………………….............
…………………………………………………………………………………….............
[1 mark]
(b) Write a chemical equation for the reaction between magnesium and hydrochloric acid.
Tuliskan persamaan kimia bagi tindak balas antara magnesium dengan asid hidroklorik.
…………………………………………………………………………………….............
[2 marks]
(c) State the factor that affects the rate of reaction in this experiment.
Nyatakan faktor yang mempengaruhi kadar tindak balas dalam eksperimen ini :
…………………………………………………………………………………….............
[1 mark]
(d) (i) From the information in Table 4, calculate the average rate of reaction for Experiment
I and Experiment II.
Daripada maklumat dalam Jadual 4 hitungkan kadar tindak balas purata untuk
Eksperimen I dan Eksperiment II.
[2 marks]
(ii) Rate of reaction in Experiment II is higher than Experiment I.

By referring to the Collision Theory, explain why there are differences in the rate of
reaction in both experiments.
Kadar tindak balas dalam Eksperimen II lebih tinggi daripada Eksperimen I.
Dengan merujuk kepada Teori Perlanggaran, terangkan mengapa terdapat perbezaan
dalam kadar tindak balas bagi kedua-dua eksperimen itu.
……………………………………………………………………………………....
……………………………………………………………………………………....
……………………………………………………………………………………....
……………………………………………………………………………………....
[3 marks]
(e) Give one reason why the final volume of gas obtained in all experiments are the same.
Beri satu sebab mengapa isipadu akhir gas yang diperolehi dalam semua eksperimen adalah
sama.
…………………………………………………………………………………….............
[1 mark]
[MRSM 2016, No 5]
5 An experiment is carried out to investigate the rate of reaction of magnesium with sulphuric acid. Excess
magnesium powder is added to 20 cm3 of 0.1 mol dm-3 sulphuric acid. Table 5.1 shows the volume of gas collected
at intervals of 30 seconds.
Satu eksperimen dijalankan untuk mengkaji kadar tindak balas antara magnesium dengan asid sulfurik. Serbuk
magnesium berlebihan ditambahkan kepada 20 cm3 asid sulfurik 0.1 mol dm-3.
Jadual 5.1 menunjukkan isipadu gas yang terkumpul pada setiap sela masa 30 saat.
Time/s
0 30 60 90 120 150 180 210 240
Masa/s
Volume of gas/cm3
0.00 12.00 22.00 31.00 38.00 42.00 44.00 45.00 45.00
Isipadu gas/cm3
Table 5.1/Jadual 5.1

(a) Name the gas released from the above reaction.
Namakan gas yang terbebas daripada tindak balas di atas.
………….………….…………………………………………………………………………….………..
[1 mark]
(b) Based on Table 5.1, plot a graph of the volume of gas collected against time.
Berdasarkan Jadual 5.1, plotkan graf isipadu gas yang terkumpul melawan masa.
[3 marks]
(c) Based on graph plotted in 5(b), calculate:
Berdasarkan pada graf yang diplotkan di 5(b), hitung :
(i) the rate of reaction at 120 s.

kadar tindak balas pada masa 120 s.
[2 marks]
(ii) the overall rate of reaction.

kadar tindak balas purata keseluruhan.
[1 mark]
(d) Another experiment is carried out to investigate the factors affecting the rate of reaction. Diagram 5.2 shows
the results of the experiment. Curve L represents the result of the experiment using excess magnesium
powder and 50 cm3 of 1.0 mol dm-3 hydrochloric acid.
Suatu eksperimen berasingan dijalankan untuk mengkaji faktor-faktor yang mempengaruhi kadar tindak
balas. Rajah 5.2 menunjukkan keputusan eksperimen. Lengkung L mewakili keputusan eksperimen yang
menggunakan serbuk magnesium berlebihan dan 50 cm3 asid hidroklorik 1.0 mol dm-3.
Volume of gas/cm3
Isipadu gas/cm3
Time/s
Masa/s
Diagram 5.2/ Rajah 5.2
(i) Suggest the factor that influence the rate of reaction to obtain the curve K.
Cadangkan faktor yang mempengaruhi kadar tindak balas untuk memperoleh lengkung K.
………….………….…………………………………………………………………………….………..
[1 mark]
(ii) Rate of reaction of curve K is higher than L. Explain your answer based on the Collision Theory.
Kadar tindak balas lengkung K lebih tinggi dari L. Terangkan jawapan anda berdasarkan Teori
Perlanggaran.
………………………………………………………………………………………………..……
……………………………………………………………………………………………………
[2 marks]
(iii) The final volume of gas obtained in curve M is half the final volume of gas obtained in curve L.
Give one reason for this.
Isipadu akhir gas yang diperolehi dalam lengkung M adalah separuh daripada isipadu akhir gas yang
diperolehi dalam lengkung L. Berikan satu sebab bagi keadaan ini.
………….………….…………………………………………………………………………….………..
[1 mark]
Chapter 11 : Carbon Compound
[Pahang 2016, No 6]
6. Diagram 6 shows the flow chart for the conversion of carbon compound.
Rajah 6 menunjukkan carta alir bagi penukaran sebatian karbon.
Gas X + water
Gas X + air
Combustion
Pembakaran
Compund R Dehydration I Propanoic acid

Sebatian R Pendehidratan Propanol, C3H8O
Asid propanoik
Propanol
Diagram 6/Rajah 6
Based on Diagram 6,
Berdasarkan Rajah 6,
(a) State the name of gas X.

Nyatakan nama gas X.
.......................................................................................................................................
[1 mark]
(b) (i) State the functional group of propanol

Nyatakan kumpulan berfungsi bagi propanol.
...............................................................................................................................
[1 mark]
(ii) Draw the structural formula for isomers of propanol
Lukis formula struktur untuk isomer-isomer bagi propanol.
[2 marks]
(c) (i) State the process at I
Nyatakan proses di I
..............................................................................................................................
[1 mark]
(ii) What is the substance that needs to be added in process I to produce propanoic acid?
Apakah bahan yang perlu ditambahkan dalam proses I untuk menghasilkan asid
propanoik?
..............................................................................................................................
[1 mark]
(d) (i) State the name of compound R
Nyatakan nama bagi sebatian R
...............................................................................................................................
[1 mark]
(ii) Draw a labelled diagram how the dehydration reaction can be carried out in the
laboratory.
Lukis rajah berlabel bagaimana tindak balas pendehidratan boleh dijalankan dalam
makmal.
[2 marks]
(e) Aliya mother sells pineapple cookies for last Eid. Aliya want to expand her mother business. The
problem faced by Aliya is the pineapple is not enough. Aliya thought
of using pineapple flavors to produce pineapple cookies. The chemical flavor formula for
pineapple is C3H7COOC2H5. Can you help Aliya to name two carbon compounds that can be used
to produce pineapple flavor?
Emak Aliya menjual biskut nanas untuk sambutan hari raya yang lepas. Aliya ingin
mengembangkan perniagaan emaknya. Masalah yang dihadapi oleh Aliya ialah nanas tidak
mencukupi. Aliya terfikir untuk menggunakan perisa nanas untuk
menghasilkan biskut nanas. Formula kimia bagi perisa nanas adalah C3H7COOC2H5. Bolehkah
anda membantu Aliya untuk menamakan dua sebatian karbon yang digunakan untuk
menghasilkan perisa nanas?
.....................................................................................................................................
[2 marks]
[Negeri Sembilan 2016, No 6]
6 Table 6 shows the structural formulae of three carbon compounds.

Jadual 6 menunjukkan formula struktur bagi tiga sebatian karbon.
Substance Structural Formula Name

Bahan Formula Struktur Name
X ......................................................
Y ......................................................
Z .......................................................
Table 6/Jadual 6
(a) What is the meaning of carbon compounds?

Apakah maksud sebatian karbon?
..................................................................................................................................................
[1 mark]
(b) State the name of substance X, Y and Z based on IUPAC nomenclature.

Write your answer in Table 6.
Nyatakan nama bagi bahan X, Y dan Z berpandukan sistem penamaan IUPAC.
Tuliskan jawapan anda dalam Jadual 6.
[3 marks]
(c) Draw the structural formula for isomer of substance Y.

Lukiskan formula struktur bagi isomer bagi bahan Y.
[1 mark]
(d) Substance Y can be converted to substance Z through dehydration reaction.

Draw a labelled diagram how the reaction can be carried out in the school laboratory.
Bahan Y boleh ditukarkan kepada bahan Z melalui tindak balas pendehidratan.
Lukiskan gambar rajah berlabel susunan radas yang digunakan untuk menjalankan tindak balas itu
di makmal sekolah.
[2 marks]
(e) Diagram 6 shows the apparatus set-up for the reaction between bromine water with X
and Z.
Rajah 6 menunjukkan susunan radas bagi tindak balas antara air bromin dengan X dan Z.
X Z
Bromine water
Air bromin
Diagram 6/Rajah 6
(i) State the observations for both test tube.

Nyatakan pemerhatian bagi kedua-dua tindak balas.
..........................................................................................................................................
[1 mark]
(ii) Explain the observation.

Terangkan pemerhatian itu.
..........................................................................................................................................
[2 marks]
[SPM 2016, No 4]
4 Diagram 4.1 shows a bottle of hand sanitizer. Compound X is the main component found in the hand
sanitizer.
Rajah 4.1 menunjukkan sebotol pembasmi kuman tangan. Sebatian X merupakan komponen utama yang
terdapat dalam pembasmi kuman tangan itu.
Diagram 4.1/Rajah 4.1
(a) State the type of bond in compound X.

Nyatakan jenis ikatan dalam sebatian X.
..................................................................................................................................................
[1 mark]
(b) (i) Is compound X able to conduct electricity?

Adakah sebatian X dapat mengkonduksikan arus elektrik?
..................................................................................................................................................
[1 mark]
(ii) Explain your answer in 4(b)(i).

Terangkan jawapan anda di 4(b)(i).
..................................................................................................................................................
..................................................................................................................................................
..................................................................................................................................................
[2 marks]
(c) Compound X is known as a clean fuel. The combustion of compound X produces blue flame without
soot. Write a chemical equation for the combustion of compound X.
Sebatian X dikenali sebagai bahan api bersih. Pembakaran sebatian X menghasilkan nyalaan biru
tanpa jelaga. Tulis persamaan kimia bagi pembakaran sebatian X.
..................................................................................................................................................
[2 marks]
(d) Compound X is also used s a main substance in the production of acetone. Diagram 4.2 shows a woman
is removing her nail varnish.
Sebatian X juga digunakan sebagai bahan utama dalam penghasilan aseton. Rajah 4.2 menunjukkan
seorang wanita sedang menanggalkan varnish kuku.
Based on Diagram 4.2,

Berdasarkan Rajah 4.2,
(i) explain why acetone is suitable to be used to remove the nail varnish.
terangkan mengapa aseton sesuai digunakan untuk menanggalkan varnish kuku.
..........................................................................................................................................
..........................................................................................................................................
[2 marks]
(ii) can water replace acetone to remove the nail varnish? Give your reason.
bolehkah air menggantikan aseton untuk menanggalkan varnish kuku? Berikan alasan anda.
..........................................................................................................................................
..........................................................................................................................................
[2 marks]
[Perlis 2016, No 4]
4 Diagram 4 shows a flow chart of conversion of compound P to compound Q and R.

Rajah 4 menunjukkan carta alir bagi penukaran sebatian P kepada sebatian Q dan R.
Porcelain chips Reagent X

Compound R Serpihan Compound P Reagen X Compound Q
Sebatian R Sebatian P Sebatian Q
porselin C4H9OH
Hot/panas
Diagram 4/ Rajah 4
Based on Diagram 4, answer the following questions:

Berdasarkan Rajah 4, jawab soalan-soalan berikut:
(a) (i) Write the general formula of the homologous series of compound P.
Tuliskan formula umum bagi siri homolog sebatian P.
........................................................................................................................
[1 mark]
(ii) State the functional group for compound P.

Nyatakan kumpulan berfungsi bagi sebatian P.
........................................................................................................................
[1 mark]
(b) When bromine water is added to compound R, the brown bromine water is decolourised.
Apabila air bromin ditambah kepada sebatian R, warna perang air bromin diyahwarnakan.
(i) Name a compound R.

Namakan sebatian R.
...........................................................................................................................
[1 mark]
(ii) Draw a structural formula for compound R

Lukiskan formula struktur bagi sebatian R
[1 mark]
(c) (i) When the mixture of compound P, reagent X and concentrated sulfuric acid is gently
heated it will produced compound Q. Compound Q also turns the colour of blue
litmus paper to red.
Apabila campuran sebatian P, reagen X dan asid sulfurik dipanaskan secara
perlahan-lahan ia akan menghasilkan sebatian Q. Sebatian Q juga dapat
menukarkan warna kertas litmus biru kepada merah.
Name the Reagent X

Namakan Reagent X
..........................................................................................................................
[1 mark]
(ii) State the colour change of the reagent at 4(c)(i) during the reaction.
Nyatakan perubahan warna bagi reagen di 4(c)(i) semasa tindakbalas berlaku.
..........................................................................................................................
[1 mark]
(d) (i) Propanic acid react with compound P with the presence of the concentrated
sulphuric acid to form a compound.
Asid propanoik bertindak balas dengan sebatian P dengan kehadiran asid sulfurik
pekat bagi menghasilkan suatu sebatian.
Name the compound formed.

Namakan sebatian yang terbentuk.
……………………………………………………….……………………….......
[1 mark]
(ii) Write a balanced chemical reaction at 4(d)(i)

Tuliskan persamaan kimia yang seimbang bagi tindakbalas di 4(d)(i)
…………….………………………………….………………………….........…
[1 mark]
(e) Compound R burns in excess oxygen to produce carbon dioxide and water.
Sebatian R terbakar dalam oksigen berlebihan menghasilkan carbon dioksida dan air.
Calculate the numbers of carbon dioxide molecules are formed when 11.2 g of
compound R burned in excess oxygen.
Hitungkan bilangan molekul carbon dioksida yang terbentuk apabila 11.2 g sebatian R
terbakar dalam oksigen berlebihan,
[Relative atomic mass C = 12, O = 16 ; Avogadro number = 6.03 x 1023]

[Jisim atom relatif C = 12, O = 16; Nombor Avogadro = 6.03 x 1023]
[2 marks]
[Pulau Pinang 2016, No 5]
5. Diagram 5.1 shows a preparation of ethanol and some of the reactions involving ethanol.
Rajah 5.1 menunjukkan penyediaan etanol dan beberapa tindak balas yang melibatkan etanol.
+ Acidified potassium manganate

(VII) solution.
Process 1 + Larutan kalium manganat(VII)
Proses 1 berasid
Glucose Ethanol Compound R
Glukosa Etanol Sebatian R
Dehydration
Pendehidratan
Gas X
(a) Ethanol can be prepared from glucose in a laboratory through process 1. Name process 1.
Etanol boleh disediakan daripada glukosa dalam makmal melalui proses 1. Namakan proses 1.
…...…..………………………………………………………………………………………………
[1 mark]
(b) Ethanol undergoes dehydration to produce gas X.

Etanol mengalami pendehidratan untuk menghasilkan gas X.
Name gas X and describe a chemical test to determine the presence of gas X.
Namakan gas X dan huraikan satu ujian kimia untuk menentukan kehadiran gas X.
…...…..……………………………………………………………………………………………
…...…..……………………………………………………………………………………………
…...…..……………………………………………………………………………………………
[3 marks]
(c) Compound R is produced through oxidation of ethanol in the presence of acidified potassium
manganate (VII) solution.
Sebatian R terhasil daripada tindak balas pengoksidaan ke atas etanol dengan kehadiran larutan
kalium manganat(VII) berasid.
(i) Name compound R.

Namakan sebatian R.
..…..………………………………………………………………………………………………
[1 mark]
(ii) Draw the structural formula of compound R.
Lukis formula struktur bagi sebatian R.
[1 mark]
(d) Diagram 5.2 shows the compound S prepared in the laboratory through the reaction between
ethanol and compound R.
Rajah 5.2 menunjukkan sebatian S yang disediakan dalam makmal melalui tindak balas antara
etanol dengan sebatian R.
Thermometer
Termometer
Liebig Condenser
Kondenser Liebig
Water bath
Kukus Air
Compound S
Sebatian S
Ethanol + Compound R
Heat Etanol + Sebatian R
Panaskan
(i) Label water in as 'X' and water out as 'Y' in Diagram 5.2.
Label air masuk sebagai 'X' dan air keluar sebagai 'Y' pada Rajah 5.2.
[1 mark]
(ii) Compound S is the product of this experiment. Name the compound S?

Sebatian S ialah hasil bagi eksperimen ini. Namakan sebatian S?
..……………………………………………………………………………………………..
[1 mark]
(iii) Write a chemical equation for this reaction.

Tulis persamaan kimia untuk tindak balas ini.
…...…..…………………………………………………………………………………………
[2 marks]
(iv) State one use of compound S in everyday life.

Nyatakan satu kegunaan sebatian S dalam kehidupan seharian.
………..…………………………………………………………………………………………
[1 mark]
[MRSM 2016, No 2(d)]
(d) Diagram 2.3 shows the conversion of glucose to another substance.

Rajah 2.3 menunjukkan penukaran glukosa kepada bahan lain.

(i) name Reaction I.

namakan Tindak balas I.
………….………….……………………………………………………………………………..
[1 mark]
(ii) state the homologous series for liquid H.

nyatakan siri homolog bagi cecair H.
………….………….……………………………………………………………………………..
[1 mark]
(iii) write the chemical equation in Reaction II.

tuliskan persamaan kimia dalam Tindak balas II.
………….………….……………………………………………………………………………..
[1 mark]
(iv) state a substance that can be used to replace porous pot chips in Reaction II.
nyatakan satu bahan yang boleh menggantikan serpihan pasu berliang dalam Tindak balas II.
………….………….……………………………………………………………………………..
[1 mark]
[SBP 2016, No 5]
5 Diagram 5 shows the structural formulae of compound P and compound Q. Both compound P and
compound Q are isomers.
Rajah 5 menunjukkan formula struktur bagi sebatian P dan sebatian Q. Kedua-dua sebatian P dan
sebatian Q adalah isomer.
Diagram 5/ Rajah 5
a) (i) State the meaning of isomer.

Nyatakan maksud isomer.
………………………………………………………………………………….
[1 mark]
(ii) State the name of the compounds by using IUPAC nomenclature.

Nyatakan nama sebatian-sebatian itu dengan menggunakan penamaan
IUPAC.
Compound P: ………………………………………………………………….
Sebatian P
Compound Q: ………………………………………………………………….
Sebatian Q
[2 marks]
(iii) Draw the structural formula for another isomer of the compound.
Lukiskan formula struktur untuk satu lagi isomer bagi sebatian itu.
[1 mark]
b) Compound P burns in excess oxygen to form a gas and water.

Sebatian P terbakar di dalam oksigen berlebihan menghasilkan sejenis gas dan air.
(i) Write a balance chemical equation for the reaction involve.

Tuliskan persamaan seimbang bagi tindak balas yang terlibat.
………………………………………………………………………………….
[2 marks]
(ii) Describe briefly a confirmatory test for the gas released.

Huraikan dengan ringkas ujian pengesahan bagi gas yang terbebas.
………………………………………………………………………………….
………………………………………………………………………………….
[2 marks]
c) Compound Q undergoes a reaction to form compound R. Compound R contains 85.7% carbon

and the rest is hydrogen. Find the empirical formula of the compound R.
Sebatian Q mengalami tindak balas membentuk sebatian R. Sebatian R mengandungi 85.7%
karbon dan selebihnya adalah hydrogen. Tentukan formula empirik bagi sebatian R.
[Relative atomic mass: H =1, C =12] [Jisim atom relatif: H =1, C =12]
[3 mark]
[JUJ Pahang 2016, No 6]
6. Diagram 6 shows the conversions of organic compound P to compound Q, compound R and

compound S.
Rajah 6 menunjukkan penukaran sebatian organik P kepada sebatian Q, sebatian R dan sebatian
S.
Oxidation reaction
Tindak balas pengoksidaan Compound R
Sebatian R
Compound P + Ethanol
Sebatian P Etanol
Dehydration reaction Compound S

Tindak balas pendehidratan Sebatian S
Compound Q
Diagram 6
Sebatian Q
Rajah 6
(a) What is the general formula of compound P?

Apakah formula am bagi sebatian P?
…………………………………………………………………………………
[1 mark]
(b) State the name of compound Q, compound R and compound S

Nyatakan nama bagi sebatian Q, sebatian R dan sebation S.
Compound Q :…………………………………………………..
Sebatian Q
Compound R : ……………………………………………………..
Sebatian R
Compound S : …………………………………………………………..
Sebatian S
[3 marks]
(c) Compound P undergoes dehydration reaction to form compound Q.
Draw a labelled diagram to show how to prepare and collect compound Q from
compound P.
Sebatian P menjalani tindak balas pendehidratan.
Lukiskan rajah berlabel menunjukkan bagaimana menyediakan dan mengumpul sebatian
Q daripada sebatian P.
[2 marks]
(d) Compound P can undergoes oxidation reaction.

Sebatian P boleh mengalami tindak balas pengoksidaan.
(i) State one suitable oxidising agent for the conversion of compound P to compound
R
Nyatakan satu agen pengoksidaan yang sesuai bagi penukaran sebatian P
kepada sebatian R
…………….……………………………………………………………
[1 mark]
(ii) Write the chemical equation for the oxidation reaction of compound P.
Tuliskan persamaan kimia untuk tindak balas pengoksidaan sebatian P.
……..………………………………..…………………………………
[2 marks]
(e) Compound R reacts with ethanol to form compound S.

Sebatian R bertindak balas dengan etanol membentuk sebatian S.
(i) State the functional group of compound S

Nyatakan kumpulan berfungsi bagi sebatian S
…………………………………………………………………………
[1 mark]
(ii) Draw the structural formula of compound S.
Lukiskan formula struktur sebatian S.
[1 mark]
[Kedah 2016, No 5]
5. Diagram 5.1 shows the structural formula of monomer of natural rubber.

Rajah 5.1 menunujukkan formula struktur bagi monomer getah asli.
H CH3 H H
H C C
C Diagram 5.1 C H
Rajah 5.1
(a) State the name of the monomer of natural rubber.

Nyatakan nama bagi monomer getah asli.
[1 mark]
(b) (i) The monomers react each other to form a long-chain molecule, P through process Q.
Name process Q.
Monomer bertindak balas antara satu sama lain untuk membentuk satu molekul rantai
panjang, P melalui prosesQ. Namakan proses Q.
[1 mark]
(ii) Draw the structural formula of P.

Lukiskan formula struktur bagi P.
[1 mark]
(c) An experiment is carried out to studythe effect of solution A and solution B when added to
latex. Table 5 shows the results of the experiment.
Suatu eksperimen telah dijalankan untuk mengkaji kesan larutan A dan larutan B apabila
ditambah kepada lateks. Jadual 5menunjukkan keputusan eksperimen itu.
Mixture Observation
Campuran Pemerhatian
Latex + solution A Latex coagulate
Lateks + larutan A Getah menggumpal
Latex + solution B Latex does not coagulate
Lateks + larutan B Getah tidak menggumpal
Table 5/Jadual 5
Based on Table 5,
Berdasarkan Jadual 5,
(i) Name the solutions.
Namakan larutan-larutan tersebut.
Solution A:
Larutan A :
Solution B:
Larutan B :
[ 2 marks]
(ii) Latex can also coagulate after being left overnight.

Explain how the process occurs.
Lateks juga boleh menggumpal apabila dibiarkan semalaman. Terangkan bagaimana
proses ini berlaku.
[2 marks]
(d) Vulcanisation is a process used to enhance the quality of natural rubber.
Diagram 5.2 below shows two products K and L made of rubber.
Pemvulkanan adalah satu proses dijalankan untuk meningkatkan kualiti getah.
Rajah 5.2 menunjukkan dua produk K dan Lyang dihasilkan daripada getah.
Material K Material L
Bahan K Bahan L
(i) Choose the product that is made of vulcanised rubber.

Pilih produk yang dibuat menggunakan getah tervulkan.
[1 mark]
(ii) Explain your choice in term of their properties.

Terangkan pilihan anda dari segi sifatnya.
[2 marks]
(iii) Draw the structural formula of vulcanised rubber.

Lukiskan formulastruktur bagi getah tervulkan.
[1 mark]
Chapter 12 : Oxidation and Reduction
[Terengganu 2016, No 6]
6 (a) Table 6.1 shows the set-up of apparatus and observation for two experiments, I and II.
Jadual 6.1 menunjukkan susunan radas dan pemerhatian bagi dua eksperimen, I dan II.
Experiment
I II
Eksperimen
Copper(II) sulphate solution Magnesium sulphate solution

Larutan kuprum(II) sulfat Larutan magnesium sulfat
Test tube
Tabung uji
Magnesium powder Copper powder
Serbuk magnesium Serbuk kuprum
Observation Brown solid formed.

Pemerhatian Blue solution becomes paler. No change.
Pepejal perang terbentuk. Tiada perubahan.
Larutan biru menjadi pucat.
Table 6.1 / Jadual 6.1
Based on Table 6.1,

Berdasarkan Jadual 6.1,
(i) State the name of the brown solid formed.

Nyatakan nama bagi pepejal perang yang terbentuk.
.......................................................................................................................
[1 mark]
(ii) Give a reason for the observation on the solution in Experiment I.

Berikan satu sebab bagi pemerhatian ke atas larutan dalam Eksperimen I.
.......................................................................................................................
[1 mark]
(iii) The reaction is a redox reaction. Explain in term of change in oxidation number.
Tindak balas itu ialah suatu tindak balas redoks. Terangkan dari segi perubahan
nombor pengoksidaan.
.......................................................................................................................
.......................................................................................................................
.......................................................................................................................
[2 marks]
(iv) Write the chemical equation for the reaction occurred.
Tuliskan persamaan kimia bagi tindak balas yang berlaku.
.......................................................................................................................
[1 mark]
(v) Explain the observation in Experiment II

Terangkan pemerhatian dalam Eksperimen II.
.......................................................................................................................
.......................................................................................................................
[2 marks]
(b) Iron is a metal that rusts easily.

Besi adalah sejenis logam yang mudah berkarat.
(i) State the conditions for the rusting of iron

Nyatakan syarat-syarat untuk pengaratan besi.
......................................................................................................................
[1 mark]
(ii) Draw a labelled diagram to show how the conditions for the rusting of iron involve the
ionization of iron and the flow of electron.
Lukis satu gambar rajah berlabel untuk menunjukkan bagaimana syarat untuk
pengaratan melibatkan pengionan besi dan pengaliran elektron.
[3 marks]
[Perlis 2016, No 5]
5 Diagram 5 shows the set up of the apparatus of an experiment to investigate the transfer of
electrons at a distance. Solution X is an oxidising agent and turns colour from purple to colourless
after a few minutes reacted.
Rajah 5 menunjukkan susunan radas eksperimen bagi mengkaji pemindahan elektron pada satu
jarak. Larutan X ialah agen pengoksidaan dan bertukar warna dari ungu kepada tidak berwarna
selepas beberapa minit bertindak balas.
Carbon Carbon
Karbon Karbon
X Potassium iodide solution

Larutan kalium iodida
Dilute sulphuric acid

Asid sulfurik cair
Diagram 5/Rajah 5
The overall ionic equation that occurs at electrodes A and B is,

Persamaan ion keseluruhan bagi tindak balas yang berlaku pada elektod A dan B adalah,
2MnO4- + 16H+ + 10I- → 2Mn2+ + 8H2O + 5I2
(a) Name the solution X.

Namakan larutan X.
……………………………………………………………………………………..
[1 mark]
(b) Calculate the oxidation number of manganese in MnO4- ion.

Hitungkan nombor pengoksidaan bagi mangan dalam ion MnO4-.
[1 mark]
(c) State the type of reaction that occurs at electrode A.
Nyatakan jenis tindakbalas yang berlaku pada elektod A.
...................................................................................................................................
[1 mark]
(d) Referring to the reaction that takes place at electrode B.

Merujuk kepada tindak balas yang berlaku pada elektrod B.
(i) State the observation?
Nyatakan pemerhatian?
……………………………………………………………………………...
[1 mark]
(ii) Write the half equation for the reaction.
Tulis setengah persamaan bagi tindakbalas.
.......................................................................................................................
[2 marks]
(iii) Explain the reaction that occurs in term of transfer of electron.

Terangkan tindak balas yang berlaku dari segi pemindahan elektron.
.......................................................................................................................
[1 mark]
(e) State the function of the dilute sulphuric acid in this experiment.
Nyatakan fungsi bagi asid sulfurik cair dalam eksperimen ini.
...................................................................................................................................
[1 mark]
(f) In other experiment you are given zinc strip, copper strip, copper (II) sulphate solution
and all apparatus required.
Draw a labelled diagram to show another set up of apparatus to investigate the transfer of
electron at a distance. In your diagram show the direction of electron flow.
Di dalam eksperimen lain anda dibekalkan dengan kepingan zink, kepingan kuprum,
larutan kuprum(II) sulfat dan semua radas yang diperlukan.
Lukiskan satu gambarajah berlabel untuk menunjukkan susunan radas bagi menyiasat
pemindahan elektron pada satu jarak. Tunjukkan arah pergerakan elektron pada rajah
anda.
[3 marks]
[Kedah 2016, No 6]
6. Diagram 6.1 shows the apparatus set-up to investigate the transfer of electrons at a distance in a redox
reaction.
Rajah 6.1menunjukkan susunan radas untuk mengkaji pemindahan elektron pada suatu jarak dalam
tindak balas redoks.
Carbon electrode Y
Carbon electrode X Elektrod karbonY
Elektrod karbonX
Iron(II) sulphate solution Acidified potassium dichromate (VI) solution

Larutan ferum(II)sulfat Larutan kalium dikromat(VI) berasid
Dilute sulphuric acid

Asid sulfurik cair

(a) State the function of dilute sulphuric acid.
Nyatakan fungsi asid sulfurik cair.
...................................................................................................................................
[1 mark]
(b) The following equation shows the reaction that takes place at carbon electrode Y.
Persamaanberikutmenunjukkantindakbalas yangberlakupadaelektrod karbon Y.
Cr2O72-- + 14H+ + 6e-→ 2Cr3+ + 7H2O
(i) State the change ofoxidation number for chromium.

Nyatakan perubahan nombor pengoksidaan bagi kromium.
...................................................................................................................................
[1 mark]
(ii) State the type of reaction that occurs.

Nyatakan jenis tindakbalas yang berlaku.
...................................................................................................................................
[1 mark]
(c) Based on the reaction that takes place at carbon electrode X,

Berdasarkan tindak balas yang berlaku pada elektrod karbon X,
(i) write the half equation for the reaction
tuliskan persamaan setengah bagi tindak balas itu.
...................................................................................................................................
[1 mark]
(ii) describe briefly a chemical test to identify the cation formed in (c)(i)
huraikan secara ringkas ujian kimia untuk mengenal pasti kation yang terbentuk di
c(i).
...................................................................................................................................
...................................................................................................................................
[2 marks]
(d) Table 6 shows the results of four sets of experiment to determine the position of hydrogen in the
reactivity series.
Jadual 6 menunjukkan keputusan bagi empat set eksperimen untuk mengkaji kedudukan
hidrogen dalam siri kereaktifan.
Set Reaction Observation

Set Tindak balas Pemerhatian
Burns quickly with bright flame
Hydrogen + oxide P Terbakar cepat dengan nyalaan terang
I
Hidrogen + oksida P Black powder turns to brown
Serbuk hitam bertukar menjadi perang
Burns with bright flame
Hydrogen + oxide Q Terbakar dengan nyalaan terang
II
Hidrogen + oksida Q Yellow powder turns to shiny grey
Serbuk kuning bertukar menjadi kelabu berkilat
Hydrogen + oxide R No change
III
Hidrogen + oksida R Tiada perubahan
Glow dimly
Hydrogen + oxide S Berbara malap
IV
Hidrogen + oksida S Brown powder turns to shiny grey
Serbuk perang bertukar menjadi kelabu berkilat
Table 6/Jadual 6
Based on the results in Table 6,

Berdasarkan keputusan di dalam Jadual 6,
(i) Arrange P, Q, R, S and hydrogen in ascending order of reactivity.

Susun P, Q, R, S dan hidrogen mengikut tertib kereaktifan menaik.
...................................................................................................................................
[1 mark]
(ii) Based on experiment I, identify P. State the role of oxide P in term of redox reaction.
Berdasarkan eksperimen I, kenal pastikan P. Nyatakan peranan oksida P dari segi tindak
balas redoks.
...................................................................................................................................
...................................................................................................................................
[2 marks]
(iii) Diagram 6.2 for the apparatus set-up used to determine the position of hydrogen in
reactivity series. Complete the apparatus set-up in Diagram 6.2.
Rajah 6.2 bagi susunan radas yang digunakan untuk menentukan kedudukan hidrogen
dalam siri kereaktifan. Lengkapkan susunan radas dalam Rajah 6.2.
Oxide P
Oksida P
H2
Heat
Haba
Anhydrous calcium chloride

Kalsium klorida kontang

[2 marks]
[Pulau Pinang 2016, No 6]
6. Diagram 6 shows an experiment that involves the transfer of electrons through a distance. The
reactions that occur is a redox reaction.
Rajah 6 menunjukkan satu eksperimen yang melibatkan pemindahan elektron pada suatu jarak.
Tindak balas yang berlaku ialah tindak balas redoks
Diagram 6/Rajah 6
(a) What is a redox reaction?

Apakah itu tindak balas redoks?
…...…..……………………………………………………………………………………………..
[1 mark]
(b) (i) Write the half equation for the reaction occurred at electrode P and Q.
Tuliskan persamaan setengah bagi tindak balas yang berlaku di elektrod P dan Q.
Electrode P / Elektrod P : ………………………………………………
Electrode Q / Elektrod Q: ………………………………………………

[2 marks]
(ii) Write a complete ionic equation for the reaction occurred in this experiment.
Tuliskan satu persamaan ion bagi tindak balas yang berlaku dalam eksperimen ini.
…..………………………………………………………………………………………………
[1 mark]
(c) Show the direction of electron flow in Diagram 6 by using an arrow.

Tunjukkan arah aliran elektron pada Rajah 6 dengan menggunakan anak panah.
[1 mark]
(d) State the observation at:

Nyatakan pemerhatian pada:
Electrode P / Elektrod P : ………………………………………………
Electrode Q / Elektrod Q: ………………………………………………

[2 marks]
(e) Identify the reducing agent.

Kenal pasti agen penurunan.
…...…..………………………………………………………………………………………………
[1 mark]
(f) Suggest a chemical test to identify the product formed at electrode Q

Cadangkan satu ujian kimia untuk mengenal pasti hasil yang terbentuk di elektrod Q.
…...…..………………………………………………………………………………………………
…...…..………………………………………………………………………………………………
[2 marks]
(g) Suggest another substance that can be used to replace the oxidising agent in Diagram 6.
Cadangkan satu bahan lain yang dapat digunakan untuk menggantikan agen pengoksidaan
dalam Rajah 6.
…...…..………………………………………………………………………………………………
[1 mark]
[SBP 2016, No 6]
6 Diagram 6 shows the apparatus set-up constructed by a student. As the circuit is completed, the needle
of galvanometer deflected.
Rajah 6 menunjukkan susunan radas yang dibina oleh seorang pelajar. Apabila litar
dilengkapkan, jarum galvanometer telah terpesong.
Diagram 6/Rajah 6
a) Based on Diagram 6;
Berdasarkan Rajah 6;
(i) State the negative terminal.

Nyatakan terminal negatif.
………………………………………………………………………………......
[1 mark]
(ii) State the role of bromine water.
Nyatakan peranan air bromin.
………………………………………………………………………………......
[1 mark]
(iii) Explain your answer in (a)(ii).

Terangkan jawapan anda di (a)(ii).
………………………………………………………………………………......
………………………………………………………………………………......
[2 marks]
(b) On Diagram 6, draw the arrows to show the direction of electron flow.
Pada Rajah 6, lukiskan anak panah bagi menunjukkan arah pengaliran elektron.
[1 mark]
(c) The colour of iron(II) sulphate solution change from green to brown. Describe briefly a chemical test
to identify the cation present.
Warna larutan ferum(II) sulfat berubah dari hijau ke perang. Huraikan dengan ringkas ujian kimia
untuk mengenalpasti kation yang hadir.
………………………………………………………………………………..................
………………………………………………………………………………..................
[2 marks]
(d) Write the overall ionic equation for the reaction occured.
Tuliskan persamaan ion keseluruhan bagi tindak balas yang berlaku.
………………………………………………………………………………..................
[2 marks]
(e) Draw a labelled diagram for the apparatus set-up used to show the electron tra nsfer at a distance by
using another suitable material.
Lukiskan satu gambarajah berlabel bagi susunan radas untuk menunjukkan pemindahan elektron
pada suatu jarak dengan menggunakan bahan-bahan lain yang sesuai.
[2 marks]
[MRSM 2016, No 6]
6 Diagram 6.1 shows a match head has been struck.

Rajah 6.1 menunjukkan satu kepala mancis yang telah digeserkan.
The chemical equation for the reaction is as follow:

Persamaan kimia untuk tindak balas adalah seperti berikut:
3 P4 + 10 KClO3 3 P4O10 + 10 KCl
(a) (i) Determine the oxidation number of chlorine, Cl in KClO3.

Tentukan nombor pengoksidaan bagi klorin, Cl dalam KClO3.
………….………….…………………………………………………………………………….………..
[1 mark]
(ii) State the substance that undergoes oxidation.

Nyatakan bahan yang mengalami pengoksidaan.
………….………….…………………………………………………………………………….………..
[1 mark]
(iii) Explain the answer in (a)(ii) in terms of the change in the oxidation number.
Terangkan jawapan di (a)(ii) dari segi perubahan nombor pengoksidaan.
………….………….…………………………………………………………………………….………..
[1 mark]
(b)
(i) State the colour of copper(II) sulphate solution in test tube I.

Nyatakan warna larutan kuprum(II) sulfat di dalam tabung uji I.
………….………….…………………………………………………………………………….………..
[1 mark]
(ii) Based on Diagram 6.2, explain the change in colour of copper(II) sulphate solution.
Berdasarkan Rajah 6.2, terangkan perubahan warna larutan kuprum(II) sulfat.
………………………………………………………………………………………………..……
……………………………………………………………………………………………………
[2 marks]
(iii) Suggest a suitable metal G. Write the ionic equation for the reaction in Diagram 6.2.
Cadangkan logam G yang sesuai. Tuliskan persamaan ion bagi tindak balas dalam Rajah 6.2.
………………………………………………………………………………………………..……
…………………………………………………………………………………………………......
[2 marks]
(c) Diagram 6.3 shows zinc plate attached to the hull of the ship to prevent rusting.
Rajah 6.3 menunjukkan kepingan zink yang dilekatkan pada badan kapal bagi mengelakkan pengaratan.
Hull
Zinc plate Badan kapal
Kepingan zink

(i) Explain how zinc plate protect the ship’s hull from rusting.
Terangkan bagaimana kepingan zink dapat melindungi badan kapal daripada berkarat.
………………………………………………………………………………………………..……
…………………………………………………………………………………………………......
[2 marks]
(ii) Write the half equation for the reaction in 6 (c)(i).
Tulis setengah persamaan bagi tindak balas di 6(c)(i).
………….………….…………………………………………………………………………….………..
[1 mark]
Chapter 13 : Chemical For Consumer

[Perlis 2016, No 1]
1. Table 1 shows information of the different types of medicine P, Q and R.

Jadual 1 menunjukkan maklumat tentang jenis-jenis ubat berbeza P, Q dan R.
Type of medicine Function Example

Jenis ubatan Fungsi Contoh
Analgesic To relief pain Aspirin
Analgesik Mengurangkan kesakitan Aspirin
Antibiotic Penicilin
Antibiotik ………………………………………… Penisilin
R To reduce tension and anxiety Tranquilizer
Mengurangkan tekanan dan kegelisahan Tranquilizer
Table 1/Jadual 1
(a) (i) State the type of medicine R.

Nyatakan jenis ubat R.
.....................................................................................................................
[1 mark]
(ii) What is the function of penicillin.

Apakah fungsi penisilin.
.....................................................................................................................
[1 mark]
(iii) En. Azlan who has gastric problems is suffering toothache for a few days.
Suggest one medicine that must be taken by him.
En. Azlan yang mempunyai masalah gastrik telah mengalami sakit gigi sejak
beberapa lain. Cadangkan satu ubat yang perlu diambil oleh beliau.
....................................................................................................................
[1 mark]
b) The following equation shows the reaction that take place in the preparation of soap.
Persamaan berikut menunjukkan tindak balas yang berlaku dalam penyediaan sabun.
Palm oil + Concentrated Boil Soap X + Gliserol

Potassium hydroxide
Minyak + Kalium hidroksida Pendidihan Sabun X + Gliserol
sawit pekat
(i) Name soap X.
Namakan sabun X.
..............................................................................................................................
[1 mark]
(ii) Diagram 1.2 shows the structural formula of a soap anion.

Rajah 1.2 menunjukkan struktur formula bagi suatu anion sabun.
CH3 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 C O-
O
Part P Part Q
Bahagian P Bahagian Q
CH2 CH2 CH2 CH 2 CH
Diagram CH2 1.2
2 Rajah
1.2/ CH2 CH2 C – O-
State the property of part P and Q of soap anion. O

Nyatakan sifat bagi bahagian P dan Q dalam anion sabun.
CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 C – O-

..............................................................................................................................
……………………………………………………………………………………
O
[2 mark]
(c) Diagram 1.3 shows the label on a pack of food.

Rajah 1.3 menunjukkan label bagi satu bungkusan makanan.
Ingrediants:
Non-dairy milk, sugar, ethyl butanoate , Sunset Yellow and ascorbic
acid
Bahan-bahan:
Susu bukan tenusu , gula, etil butanoat, Sunset Yellow dan
asid askobik
(i) State one type of food additives found on the label and state the function.
Nyatakan satu jenis bahan tambah yang terdapat pada label itu dan nyatakan
fungsinya.
..............................................................................................................................
..............................................................................................................................
[2 marks]
(ii) Sugar is not suitable for diabetic patient. Suggest another food additive that
can give the same sweetness but has a lower calorie content.
Gula tidak sesuai bagi pesakit diabetik. Cadangkan bahan tambah makanan
lain yang dapat memberi kemanisan yang sama tetapi mempunyai kandungan
kalori yang lebih rendah.
..............................................................................................................................
[1 mark]
Disusun oleh:
Cikgu Mohd Fazdli Bin Mohd Nor
SMK Pesisiran Perdana, Tangkak, Johor
Dan jutaan terima kasih kepada semua guru guru kumpulan Telegram Kimia Tulen Malaysia
yang sudi berkongsi bahan dan sumber untuk kejayaan semua anak didik kita.

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1 Modul Analisis Bertopik

Soalan SPM 2016 dan Soalan Percubaan SPM Negeri 2016

Modul Analisis Bertopik

To Excel in Chemistry is to Love Chemistry

Rate of Reaction … 3-7

Volume of gas collected

0.5 mol dm-3 hydrochloric acid in excess

0.5 mol dm-3 hydrochloric acid in excess

(a) From this experiment, state the meaning of rate of reaction.

(ii) Rate of reaction in Experiment II is higher than Experiment I.

Table 5.1/Jadual 5.1

(i) the rate of reaction at 120 s.

(ii) the overall rate of reaction.

Compund R Dehydration I Propanoic acid

(a) State the name of gas X.

(b) (i) State the functional group of propanol

[Negeri Sembilan 2016, No 6]

6 Table 6 shows the structural formulae of three carbon compounds.

Substance Structural Formula Name

(a) What is the meaning of carbon compounds?

(b) State the name of substance X, Y and Z based on IUPAC nomenclature.

(c) Draw the structural formula for isomer of substance Y.

(d) Substance Y can be converted to substance Z through dehydration reaction.

(i) State the observations for both test tube.

(ii) Explain the observation.

Diagram 4.1/Rajah 4.1

(a) State the type of bond in compound X.

(b) (i) Is compound X able to conduct electricity?

(ii) Explain your answer in 4(b)(i).

Diagram 4.2/ Rajah 4.2

Based on Diagram 4.2,

4 Diagram 4 shows a flow chart of conversion of compound P to compound Q and R.

Porcelain chips Reagent X

Based on Diagram 4, answer the following questions:

(ii) State the functional group for compound P.

(i) Name a compound R.

(ii) Draw a structural formula for compound R

Name the Reagent X

Name the compound formed.

(ii) Write a balanced chemical reaction at 4(d)(i)

[Relative atomic mass C = 12, O = 16 ; Avogadro number = 6.03 x 1023]

+ Acidified potassium manganate

(b) Ethanol undergoes dehydration to produce gas X.

(i) Name compound R.

(ii) Compound S is the product of this experiment. Name the compound S?

(iii) Write a chemical equation for this reaction.

(iv) State one use of compound S in everyday life.

(d) Diagram 2.3 shows the conversion of glucose to another substance.

Diagram 2.3/ Rajah 2.3

Based on Diagram 2.3,

(i) name Reaction I.

(ii) state the homologous series for liquid H.

(iii) write the chemical equation in Reaction II.

a) (i) State the meaning of isomer.

(ii) State the name of the compounds by using IUPAC nomenclature.

b) Compound P burns in excess oxygen to form a gas and water.

(i) Write a balance chemical equation for the reaction involve.

(ii) Describe briefly a confirmatory test for the gas released.

c) Compound Q undergoes a reaction to form compound R. Compound R contains 85.7% carbon

[JUJ Pahang 2016, No 6]

6. Diagram 6 shows the conversions of organic compound P to compound Q, compound R and

Dehydration reaction Compound S

(a) What is the general formula of compound P?