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Quantum Mechanics
– anics in Ph
Quantum Mech in Phase
– ase Space Space
Thomas
Thomas L. L. Curtright
Curtright Cosmas K. Zachos
Department
Department of
of Physics,
Physics, University
Universityof
ofMiami
Miami High Energy Physics Division, Argonne National Laboratory
Coral Gables, FL 33124-8046, USA
Coral Gables, FL 33124-8046, USA Argonne, IL 60439-4815, USA
Cosmas K. Zachos
High Energy Physics Division, Argonne National Laboratory
Argonne, IL 60439-4815, USA
DOI: 10.1142/S2251159812500030
Abstract: Ever since Werner Heisenberg’s 1927 paper on uncer- with c-number position and momentum variables simul-
tainty, there has been considerable hesitancy in simultaneously taneously placed on an equal footing, in a way that fully
considering positions and momenta in quantum contexts, since
Asia Pac. Phys. Newslett. 2012.01:37-46. Downloaded from www.worldscientific.com
formalism for quantum mechanics in phase space was wholly cast provides still more insight and understanding.
at that time, it was not completely understood nor widely known What follows is the somewhat er-
— much less generally accepted — until the late 20th century.
ratic story of this third formulation.
The foundations of this remarkable
When Feynman first unlocked the
picture of quantum mechanics were
secrets of the path integral formalism
laid out by H. Weyl and E. Wigner
and presented them to the world, he
around 1930. But the full, self-standing
was publicly rebuked [8]. “It was obvi-
theory was put together in a crowning
ous,” Bohr said, “that such trajectories
violated the uncertainty principle.” H. Weyl achievement by two unknowns, at the
very beginning of their physics careers,
However, in this case,1 Bohr was
independent of each other, during World War II: H. Groe-
wrong. Today path integrals are uni-
R. Feynman newold in Holland and J. Moyal in England (see Appendix
versally recognized and widely used as
Groenewold and Moyal). Their theory was only published
an alternative framework to describe quantum behavior,
after the end of the war under considerable adversity and
equivalent to — although conceptually distinct from — the
in the face of opposition by established physicists; and it
usual Hilbert space framework, and therefore completely
took quite some time for this uncommon achievement to
in accord with Heisenberg’s uncertainty principle. The dif-
be appreciated and utilized by the community.2
ferent points of view offered by the Hilbert space and path
The net result is that quantum mechanics works
integral frameworks combine to provide greater insight
smoothly and consistently in phase space, where posi-
and depth of understanding.
tion coordinates and momenta blend together closely and
Similarly, many physicists hold the
symmetrically. Thus, sharing a common arena and lan-
conviction that classical-valued posi-
guage with classical mechanics [14], QMPS connects to its
tion and momentum variables should
classical limit more naturally and intuitively than in the
not be simultaneously employed in
other two familiar alternate pictures, namely, the standard
any meaningful formula expressing
formulation through operators in Hilbert space, or the path
quantum behavior, simply because this
integral formulation.
would also seem to violate the uncer-
Still, as every physics undergraduate learns early on,
tainty principle (see Appendix Dirac).
classical phase space is built out of “c-number” position
However, they are also wrong. N. Bohr coordinates and momenta, x and p, ordinary commuting
Quantum mechanics (QM) can be con-
sistently and autonomously formulated in phase space, 2Perhaps this is because it emerged nearly simultaneously with the
path integral and associated diagrammatic methods of Feynman,
1 Unlikethe more famous cases (http://en.wikipedia.org/wiki/Bohr- whose flamboyant application of those methods to the field theory
Einstein debates) where Bohr criticised thought experiments proposed problems of the day captured the attention of physicists worldwide,
by Einstein at the 1927 and 1930 Solvay Conferences. and thus overshadowed other theoretical developments.
variables characterizing physical particles; whereas such now bears his name, is “the” quantization prescription —
observables are usually represented in quantum theory superior to other prescriptions — the elusive bridge ex-
by operators that do not commute. How then can the tending classical mechanics to the operators of the broader
two be reconciled? The ingenious technical solution to quantum theory containing it; effectively, then, some ex-
this problem was provided by Groenewold in 1946, and traordinary “right way” to a “correct” quantum theory.
consists of a special binary operation, the ⋆-product (see However, Weyl’s correspondence fails to transform the
Appendix Star Product), which enables x and p to maintain square of the classical angular momentum to its accepted
their conventional classical interpretation, and permits x quantum analog; and therefore it was soon recognized to
and p to combine more subtly than conventional classical be an elegant, but not intrinsically special quantization
variables; in fact to combine in a way that is equivalent prescription. As physicists slowly became familiar with the
to the familiar operator algebra of Hilbert space quantum existence of different quantum systems sharing a common
theory. classical limit, the quest for the right way to quantization
Nonetheless, expectation values of quantities measured was partially mooted.
in the lab (observables) are computed in this picture of In 1931, in establishing the essential uniqueness of
quantum mechanics by simply taking integrals of conven- Schrödinger’s representation in Hilbert space, von Neu-
Asia Pac. Phys. Newslett. 2012.01:37-46. Downloaded from www.worldscientific.com
tional functions of x and p with a quasi-probability density mann utilized the Weyl correspondence as an equiva-
in phase space, the Wigner function (WF) — essentially lent abstract representation of the Heisenberg group in
the density matrix in this picture. But, unlike a Liouville the Hilbert space operator formulation. For completeness’
probability density of classical statistical mechanics, this sake, ever the curious mathematician’s foible, he worked
density can take provocative negative values, and indeed
by Mr uday singh on 01/18/18. For personal use only.
Wigner also noticed the WF would assume negative erated out of a classical-valued characteristic function in
values, which complicated its conventional interpretation phase space, which he only much later identified with the
as a probability density function. However, perhaps unlike Fourier transform of the very function introduced previ-
his sister’s husband, in time Wigner grew to appreciate that ously by Wigner. He then appreciated that many familiar
the negative values of his function were an asset, and not operations of standard quantum mechanics could be ap-
a liability, in ensuring the orthogonality properties of the parently bypassed. He reassured himself the uncertainty
formulation’s building blocks, the “stargenfunctions” (see principle was incorporated in the structure of this charac-
Appendix Simple Harmonic Oscillator). teristic function, and that it indeed constrained expectation
Wigner further worked out the dynamical evolution values of “incompatible observables”. He interpreted sub-
law of the WF, which exhibited the nonlocal convolu- tleties in the diffusion of the probability fluid and the “neg-
tion features of ⋆-product operations, and violations of ative probability” aspects of it, appreciating that negative
Liouville’s theorem. But, perhaps motivated by practical probability is a microscopic phenomenon.
considerations, he did not pursue the formal and physical Today, students of QMPS routinely demonstrate as
implications of such operations, at least not at the time. an exercise that, in 2n-dimensional phase space, domains
Those and other decisive steps in the formulation were where the WF is solidly negative cannot be significantly
larger than the minimum uncertainty volume, (/2)n , and
Asia Pac. Phys. Newslett. 2012.01:37-46. Downloaded from www.worldscientific.com
decisive paper, in which he explored the consistency of the quantum time evolution of the WF through a deforma-
the classical-quantum correspondences envisioned by von tion of the Poisson bracket into the Moyal bracket, and thus
Neumann. His tool was a fully mastered formulation of opened up the way for a direct study of the semiclassical
the Weyl correspondence as an invertible transform, rather limit → 0 as an asymptotic expansion in powers of
than as a consistent quantization rule. The crux of this — “direct” in contrast to the methods of taking the limit
isomorphism is the celebrated ⋆-product in its modern of large occupation numbers, or of computing expecta-
form. tions of coherent states (see Appendix Classical Limit). The
Use of this product helped Groenewold demonstrate subsequent applications paper of Moyal with the eminent
how Poisson brackets contrast crucially to quantum com- statistician Maurice Bartlett also appeared in 1949, almost
mutators (“Groenewold’s Theorem”). In effect, the Wigner simultaneously with Moyal’s fundamental general paper.
map of quantum commutators is a generalization of Pois- There, Moyal and Bartlett calculated propagators and
son brackets, today called Moyal brackets (perhaps un- transition probabilities for oscillators perturbed by time-
fairly, given that Groenewold’s work appeared first), which dependent potentials, to demonstrate the power of the
contains Poisson brackets as their classical limit (techni- phase-space picture.
cally, a Wigner-Inonü Lie-algebra contraction). By way By 1949 the formulation had been
of illustration, Groenewold further worked out the har- completed, although few took note of
monic oscillator WFs. Remarkably, the basic polynomials Moyal’s and especially Groenewold’s
involved turned out to be those of Laguerre, and not the work. And in fact, at the end of the
Hermite polynomials utilized in the standard Schrödinger war in 1945, a number of researchers
formulation! Groenewold had crossed over to a different in Paris, such as J. Yvon and J. Bass,
continent. were also rediscovering the Weyl corre-
At the very same time, in England, Joe Moyal was spondence and converging towards the
M. Bartlett
developing effectively the same theory from a yet different same picture, albeit in smaller, hesitant,
point of view, landing at virtually the opposite coast of discursive, and considerably less explicit steps (see [20] for
the same continent. He argued with Dirac on its validity a guide to this and related literature).
(see Appendix Dirac) and only succeeded in publishing Important additional steps were subsequently carried
it, much delayed, in 1949. With his strong statistics back- out by T. Takabayasi (1954), G. Baker (1958, his thesis),
ground, Moyal focused on all expectation values of quan- D. Fairlie (1964), and R. Kubo (1964) (again, see [20]).
tum operator monomials, Xn Pm , symmetrized by Weyl or- These researchers provided imaginative applications and
dering, expectations which are themselves the numerically filled-in the logical autonomy of the picture — the op-
valued (c-number) building blocks of every quantum ob- tion, in principle, to derive the Hilbert-space picture from
servable measurement. it, and not vice versa. The completeness and orthog-
Moyal saw that these expectation values could be gen- onality structure of the eigenfunctions in standard QM
yet another sort of uncertainty principle — but we are led Hilbrand Johannes Groenewold
to wonder if it had to do with some key features of Moyal’s
29 June 1910–23 November 1996 7
theory at that time. First, in sharp contrast to Dirac’s own
Hip Groenewold was born in Muntendam, Nether-
operator methods, in its initial stages QMPS theory was
lands. He studied at the University of Groningen, from
definitely not a pretty formalism! And, as is well known,
which he graduated in physics with subsidiaries in mathe-
beauty was one of Dirac’s guiding principles in theoretical
matics and mechanics in 1934.
physics.
In that same year, he went of his
Moreover, the logic of the early formalism was not easy
own accord to Cambridge, drawn by
to penetrate. It is clear from his correspondence with Moyal
the presence there of the mathematician
that Dirac did not succeed in cutting away the formal
John von Neumann, who had given a
undergrowth to clear a precise conceptual path through the
solid mathematical foundation to quan-
theory behind QMPS, or at least not one that he was eager
tum mechanics with his book Mathema-
to travel again.3
tische Grundlagen der Quantenmechanik.
One of the main reasons the early formalism was not
This period had a decisive influence on
pleasing to the eye, and nearly impenetrable, may have had H. Groenewold Groenewold’s scientific thinking. Dur-
Asia Pac. Phys. Newslett. 2012.01:37-46. Downloaded from www.worldscientific.com
In 1971 Groenewold decided to resign as a professor in That same year, Moyal’s first academic appointment
theoretical physics in order to accept a position in the Cen- was in Mathematical Physics at Queen’s University Belfast.
tral Interfaculty for teaching Science and Society. However, He was later a lecturer and senior lecturer with M.S.
he remained affiliated with the theoretical institute as an Bartlett in the Statistical Laboratory at the University of
extraordinary professor. In 1975 he retired. Manchester, where he honed and applied his version of
In his younger years, Hip was a passionate pup- quantum mechanics [2].
pet player, having brought happiness to many children’s In 1958, he became a Reader in the Department of Statis-
hearts with beautiful puppets he made himself. Later, he tics, Institute of Advanced Studies, Australian National
was especially interested in painting. He personally knew University, for a period of 6 years. There he trained several
several painters, and owned many of their works. He was graduate students, now eminent professors in Australia
a great lover of the after-war CoBrA art. This love gave him and the USA. In 1964, he returned to his earlier interest in
much comfort during his last years. mathematical physics at the Argonne National Laboratory
near Chicago, coming back to Macquarie University as
Professor of Mathematics before retiring in 1978.
José Enrique Moyal
Joe’s interests were broad. He was an engineer who
1 October 1910–22 May 1998 8
Asia Pac. Phys. Newslett. 2012.01:37-46. Downloaded from www.worldscientific.com
bounds
with commutators of operators, e.g.
1 1
− ≤ F x, p ≤ .
x, p ⋆ = i.
π π
E. Wigner Such normalized states therefore cannot give probability
by Mr uday singh on 01/18/18. For personal use only.
Wigner Functions spikes (e.g. Dirac deltas) without taking the classical limit
Wigner’s original definition of his eponymous function → 0. The corresponding bound in 2n phase-space dimen-
was (Eqn (5) in [19]) sions is given by the same argument applied to Wigner’s
1 n
original definition: P x1 , · · · , xn ; p1 , · · · , pn ≤ π .
P x1 , · · · , xn ; p1 , · · · , pn
n ∞
1
· · · dy1 · · · dyn ψ x1 + y1 · · · xn + yn ∗
= Pure States and Star Products
π −∞
0.4
0.3
0.3
0.2
0.2
0.1
F(x,p) 0.1 F(x,p)
0.0
0.0
−0.1
−0.1
−0.2
−2 −2
0 −2
0 −2
p 0
p
2 x 0
2
2 x
2
n=0 n=2
0.2 0.2
0.1 0.1
0.0 0.0
Asia Pac. Phys. Newslett. 2012.01:37-46. Downloaded from www.worldscientific.com
−2 −2
0 −2 0 −2
by Mr uday singh on 01/18/18. For personal use only.
p p
0 0
2 x 2 x
2 2
n=1 n=3
H ⋆ F = EF = F ⋆ H.
Exercise 2 Associativity.
� � To illustrate this, consider the simple harmonic oscillator
eax+bp ⋆ eAx+Bp ⋆ eαx+βp (SHO) with (m = 1, ω = 1)
= e(a+A+α)x+(b+B+β)p e(aB−bA+aβ−bα+Aβ−Bα)i/2 1� 2 �
H= p + x2 .
� � 2
= eax+bp ⋆ eAx+Bp ⋆ eαx+βp
The above equations are now second-order partial differ-
Exercise 3 Trace properties. (a.k.a. “Lone Star Lemma”) ential equations,
� � � � � �2 ��2
dxdp f ⋆ g = dxdp f g = dxdp g f = dxdp g ⋆ f 1 1 1
H ⋆ F = p − i ∂x + x + i ∂p F = EF ,
2 2 2
So H⋆F = EF = F⋆H reduces to a single ordinary differential even if F becomes negative. (Note this� is� not true if the ⋆
2
equation (Laguerre, not Hermite!), namely, the real part of is removed! If g∗ ⋆ g is supplanted by ��g�� , then integrated
either of the previous second-order equations. with a WF, the result could be negative.)
There are integrable solutions if and only if E = To show this, first suppose the system is in a
(n + 1/2) , n = 0, 1, · · · for which pure state. Then use F = (2π) F ⋆ F (see Appendix
Pure States and Star Products), and the associativity and
� � (−1)n x + p2 −(x2 +p2 )/
� 2 �
Fn x, p = Ln e , trace properties (see Appendix Exercises), to write 11 :
π /2 � �
dxdp g∗ ⋆ g F = (2π) dxdp g∗ ⋆ g (F ⋆ F)
� � � �
1 z dn � n −z �
Ln (z) = e z e .
n! dzn
�
= (2π) dxdp g∗ ⋆ g ⋆ (F ⋆ F)
� �
The
+∞ normalization is chosen to be the standard one �
= (2π) dxdp g∗ ⋆ g ⋆ F ⋆ F
� �
−∞
dxdp F n x, p = 1. Except for the n = 0 ground state � �
(Gaussian) WF, these F’s change sign on the xp-plane. For
example: L0 (z) = 1, L1 (z) = 1 − z, L2 (z) = 1 − 2z + 12 z2 , etc.
�
= (2π) dxdp F ⋆ g∗ ⋆ g ⋆ F
� �
Using the integral form of the ⋆ product, it is now easy �
= (2π) dxdp F ⋆ g∗ ⋆ g ⋆ F
Asia Pac. Phys. Newslett. 2012.01:37-46. Downloaded from www.worldscientific.com
� � � �
to check these pure states are ⋆ orthogonal:
(2π) Fn ⋆ Fk = δnk Fn .
�
= (2π) dxdp F ⋆ g∗ g ⋆ F
� �� �
�
This becomes more transparent by using ⋆ = (2π) dxdp |g ⋆ F|2
by Mr uday singh on 01/18/18. For personal use only.
These always have non-negative expectation values for any 11 By essentially the same argument, if F and F are two distinct
1 2
g and any WF, pure state WFs, the phase-space overlap integral between the two is
�g∗ ⋆ g� ≥ 0 , also manifestly non-negative and thus admits interpretation as the
transition probability between the respective states:
� �
10 Note that the earlier exercise giving the star composition law of
dxdp F1 F2 = (2π)2 dxdp |F1 ⋆ F2 |2 ≥ 0 .
Gaussians immediately yields the projection property of the SHO
ground state WF, F0 = (2π) F0 ⋆ F0 .
allowed to evolve
Mechanics”, in 12,
Physica, time, its (1946).
405–460 peak follows a classical 1–33
vanishes (i.e. x and p statistically independent, ashappens [10] N. Hugenholtz, “Hip12 Groenewold, 29 juni 1910-23 does
november [19] E. W
exp − x2 + p2 / ).
1
trajectory (see Movies ... this simple behavior not
for a Gaussian pure state, F = π 1996”, Nederlands Tijdschrift voor Natuurkunde, 2, 31 (1997). rium
hold for less trivial potentials). The classical
[11] D. Leibfried, T. Pfau, and C. Monroe, “Shadows and Mirrors: limit of this [20] C. Z
Reconstructing
evolving Quantum States
WF is therefore just aofDirac
Atom Motion”,
delta whose Physicsspike
Today, in Ph
A Classical Limit 22–28 (April 1998). tific,
by Mr uday singh on 01/18/18. For personal use only.
follows
[12] J. E. the trajectory
Moyal, “Quantum of Mechanics
a classicalas point particle
a Statistical moving
Theory”, Proc. http:
The simplest illustration of the classical limit, by far, is in theCamb.
harmonic
Phil. Soc.potential:
45, 99-124 (1949).
provided by the SHO ground state WF. In the limit → 0, a [13] J. v. Neumann, Mathematical Foundations of Quantum Mechanics,
1 University
limNolte,exp − x − x0 cos t − p0 sin t 2
Princeton Press, (1955, 1983).
completely localized phase-space distribution is obtained, [14] D.
→0 π “The tangled tale of phase space”, Physics Today, 33–38
namely, a Dirac delta at the origin of the phase space: (April 2010).
− p0 cosDecoherence:
t + x0 sin t 2 The
+ p“Battling
[15] J. Preskill, / Fault-Tolerant Quantum
1
lim exp − x2 + p2 / = δ (x) δ p . Computer”, Physics Today, (June 1999).
[16] S. Saunders, cos t − A.
= δ x − xJ.0 Barrett, p0 sin
Kent,
t δand cos t + xMany
p −D.p0Wallace, 0 sin tWorlds?
→0 π .
Oxford University Press, (2010).
Moreover, if the ground state Gaussian is uniformly dis- [17] R. J. Szabo, “Quantum field theory on noncommutative spaces”,
Physics Reports, 378, 207–299 (2003).
placed from the origin by an amount x0 , p0 and then
[18] H. Weyl, “Quantenmechanik und Gruppentheorie”, Z. Phys. 46,
allowed to evolve in time, its peak follows a classical 1–33 (1927).
trajectory (see Movies12 ... this simple behavior does not [19] E. Wigner, “Quantum Corrections for Thermodynamic Equilib-
rium”, Phys. Rev. 40, 749–759 (1932).
hold for less trivial potentials). The classical limit of this [20] C. Zachos, D. Fairlie, and T. Curtright, Quantum Mechanics
evolving WF is therefore just a Dirac delta whose spike in Phase Space: An Overview with Selected Papers, World Scien-
tific, 2005. (A revised and updated first chapter is online at
follows the trajectory of a classical point particle moving http://gate.hep.anl.gov/czachos/a.pdf).
in the harmonic potential:
1
lim exp − x − x0 cos t − p0 sin t 2
→0 π
+ p − p0 cos t + x0 sin t 2 /
12 http://server.physics.miami.edu/curtright/
World Scientific Series in 20th Wigner's quasi-probability distribution function in phase space is a
Century Physics - Vol. 34 special (Weyl) representation of the density matrix. In this logically
QUANTUM MECHANICS IN complete and self-standing formulation, one need not choose sides —
coordinate or momentum space. It works in full phase space, accom-
PHASE SPACE modating the uncertainty principle, and it offers unique insights into the
An Overview with classical limit of quantum theory. This invaluable book is a collection of
Selected Papers the seminal papers on the formulation, with an introductory overview
edited by Cosmas K Zachos which provides a trail map for those papers; an extensive bibliography;
(Argonne National Laboratory, and simple illustrations, suitable for applications to a broad range of
USA), David B Fairlie (University of physics problems.
Durham, UK), & Thomas L Curtright 560pp Dec 2005
(University of Miami, USA) 978-981-238-384-6 US$180 £119
12 http://server.physics.miami.edu/curtright/
TimeDependentWignerFunctions.html