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Journal of Food Engineering 106 (2011) 298–305

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Journal of Food Engineering


journal homepage: www.elsevier.com/locate/jfoodeng

Effects of vacuum frying on structural changes of bananas


Ram Yamsaengsung ⇑, Thaworn Ariyapuchai, Kulchanat Prasertsit
Department of Chemical Engineering, Faculty of Engineering, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand

a r t i c l e i n f o a b s t r a c t

Article history: Effects of oil temperature, frying time, and ripeness on dimensional changes of vacuum fried bananas
Received 21 May 2010 were studied. Banana slices with cross section diameters of 25–30 mm and a thickness of 3.5–4.5 mm
Received in revised form 8 May 2011 were fried at temperatures of 100, 110, and 120 °C and 8 kPa for 20 min to determine which temperature
Accepted 11 May 2011
produced the highest degree of expansion. Using this temperature, the width and thickness of the prod-
Available online 19 May 2011
uct were measured at 0, 5, 10, 15, and 20 min to model the dimensional changes as a function of moisture
ratio. Sensory evaluation was conducted using a 7-point hedonic scale test to determine the effect of ripe-
Keywords:
ness on acceptability of the product. Scanning electron microscopy (SEM) was used to analyze the struc-
Vacuum frying
Modeling
ture of the vacuum fried bananas.
Structure The experimental results under this vacuum pressure revealed that frying temperature of 110 °C on
Expansion bananas at the second day of ripeness yielded the highest volume expansion. Sensory evaluations did
Heywood shape factor not unveil any significant difference (p > 0.05) in acceptability of the products based on ripeness. Results
Banana ripeness from SEM exhibited, as a function of frying time, a dramatic increase in the pore size of the bananas, while
the Heywood shape factor indicated an overall increase in the product volume.
Ó 2011 Elsevier Ltd. All rights reserved.

1. Introduction and Okos, 2000; Panyawong and Devahastin, 2007). At the same
time, casehardening may also retard the degree of shrinkage due
Besides drying and atmospheric frying, a popular technique for to formations of rigid layers in the product perimeter (Nimmol
snack food processing is vacuum frying. Due to associated lower et al., 2007). Many researchers have investigated the influence of
frying temperature, vacuum frying has many advantages compared the initial moisture content of the material and various drying pro-
to typical deep-fat frying, such as reduced oil absorption, preserva- cesses on the shrinkage of food products (Ratti, 1994; Maskan,
tion of natural color and flavor of fresh fruits, as well as loss min- 2001; Kraisheh et al., 2004; Panyawong and Devahastin, 2007;
imization of vitamins and minerals (Garayo and Moreira, 2002; Nimmol et al., 2007; Sawasdisevi et al., 2009). Mostly, shrinkage
Yamsaengsung and Rungsee, 2003; Yamsaengsung et al., 2008). of the product is reported as the change as a function of the mois-
Consequently, a number of researchers have investigated optimum ture content of the material. While many quantify shrinkage in
vacuum frying conditions and quality of snack products in recent terms of the change in volume at any instant to its original volume
years. These include apples (Shyu and Hwang, 2001), potato chips (V/V0), drying causes changes in the shape of the product as well as
(Garayo and Moreira, 2002), and other types of fruits and vegeta- the volume. Therefore, the change in volume alone does not
bles (Da Silva and Moreira, 2008). adequately represent the overall deformation of the product
During drying and frying processes, heat from ambient media is (Panyawong and Devahastin, 2007). Porous media has uneven pore
convected to the product surface and then conducted to its interior, sizes, so when moisture is removed from these pores, the material
increasing its temperature. Moisture evaporates as the product shrinks non-uniformly, resulting in an uneven product surface and
reaches its boiling-point temperature. This process is generally irregular thickness and diameter. Ratti (1994) proposed shrinkage
considered a Stefan-type heat transfer problem which is character- to be a function of moisture content, geometry of the product and
ized by the presence of a moving interface that divides two regions the drying conditions imposed. Various drying conditions such as
of physical and thermal properties (Farkas et al., 1996a). During low pressure superheated steam drying (LPSSD) and vacuum dry-
drying and the early stages of frying, there is shrinkage of the prod- ing result in different degrees of shrinkage (Panyawong and
uct due to microstructural stresses induced by migration of free Devahastin, 2007).
water from the porous region to the surface of the food material However, unlike drying, frying causes the product to undergo
and hence collapsing of the skin surface (Ratti, 1994; Achanta significant chemical and physical changes (Moreira et al., 1995;
Farkas et al., 1996a,b; Yamsaengsung and Moreira, 2002a,b). For
⇑ Corresponding author. Tel.: +66 7 428 7291; fax +66 7 455 8833. example, a soft piece of tortilla flour becomes hard and crispy
E-mail address: ram.y@psu.ac.th (R. Yamsaengsung). and a soggy piece of potato slice becomes a dried, crunchy potato

0260-8774/$ - see front matter Ó 2011 Elsevier Ltd. All rights reserved.
doi:10.1016/j.jfoodeng.2011.05.016
R. Yamsaengsung et al. / Journal of Food Engineering 106 (2011) 298–305 299

chip. While a product is being fried, many physical changes take 2.2. Methods
place, such as hardening, shrinkage, and puffing. The puffing phe-
nomenon can be described as followed. As the crust region is being Gros Michel banana (Musa sapientum L.), or ‘kluauyhomtong’ in
formed in the latter stages of frying, diffusion of air and water va- Thai, was used as the tested material in this study. A commercial
por from the product interior becomes limited due to caseharden- peel color scale (ChiquitaÒ, Brand, Inc.) was employed to assess
ing and closing of the pores at the product surface. At the same ripeness of the bananas and to ensure homogeneous samples for
period, pressure buildups from gaseous expansion inside the visco- each test. Ripe bananas with a color index of 6 (completely yellow
elastic material create insurmountable internal stresses, causing peel and tip) were peeled and cut into 3.5–4.5 mm slices. The cross
the material to expand in axial direction. The increase in the pore section diameter of the slices ranged from 25 to 30 mm. The bana-
size and the porosity of the final product created by this expansion nas were fried at 100, 110, and 120 °C and 8.0 kPa for 20 min. Each
is directly related to crispness and acceptability of the fried snack batch consisted of 600–700 g of the products and was deep-fried in
foods. For example, potato chips and tortilla chips have very por- 13.7 L of soybean oil. The soybean oil was replaced after 10 batches
ous and crispy structures after undergoing the frying process. of frying to keep the oil fresh although previous research by Oph-
While previous researchers investigated the effects of vacuum ithakorn and Yamsaengsung (2003) found that cooking oil could be
frying on final product characteristics such as hardness and crisp- used to vacuum fry up to 30 batches of fish tofu (each batch con-
ness, none have investigated dimensional changes in terms of vol- taining approx. 500 g of product) without exceeding the free-fatty
umetric expansion of the product during the vacuum frying acids (FFA), peroxide value (PV), and the Thiobarbaturic Acid (TBA)
process. Therefore, this research was aimed to investigate various limits. The thickness, average diameter, and moisture content of
factors that may influence expansion of the fried materials, such the bananas were measured at 0, 5, 10, 15, and 20 min of frying.
as starch content and frying conditions. Prediction of such changes After each frying time interval, the samples were discarded and
as a function of moisture content and temperature during vacuum new samples were used for each set of experiments. An average va-
frying would be useful in predicting the final product quality for lue of the thickness and diameter were obtained from a set of 10
snack food manufacturers worldwide. random samples using a Vernier Caliper (0.05 mm precision). The
Baik and Mittal (2005) studied the effects of temperature and percent shrinkage and percent expansion are described by Eqs.
moisture content on the thickness of tofu during deep fat frying (1) and (2):
at 147, 160, and 172 °C. The researchers developed a model based  
D0  D
on convective heat and mass transfer that yielded good results for %shrinkage ¼  100 ð1Þ
D0
changes in temperature, moisture content, and shrinkage of the
product.  
L  L0
Mayor and Sereno (2004) also investigated shrinkage and %expansion ¼  100 ð2Þ
dimensional changes of dried foods and concluded that these phys- L0
ical changes imposed a significant effect on the product quality. In where D and D0 are respectively the end-of-each-test and the origi-
addition, they also used a set of empirical models from previous nal diameters (mm); and L and L0 are respectively the end-of-each-
researchers to describe the dimensional changes of food products, test and the original thicknesses (mm).
including apples, carrots, potatoes, and garlic. The following equations by Panyawong and Devahastin (2007)
Panyawong and Devahastin (2007) described shrinkage of food were used in this study.
products using Heywood shape factor. They dried carrots that have
been diced into cubes using low-pressure superheated steam dry- V
ks ¼ 3
ð3Þ
ing (LPSSD) and vacuum drying. From their study, the researchers da
concluded that the Heywood shape factor corresponded reasonably
where ks is the Heywood shape factor, V is the volume of the sample
well with deformation kinetics of the carrot cube as observed visu-
(m3) at the end of each test, da is the equivalent projected area
ally. If the value of the Heywood shape factor remains near its initial
diameter, and
value, the change in shape of the material can be considered uni-
form; however, a value much lower than its initial value indicates  2  
V X X
that there is more shrinkage in the overall volume of the material ¼a þb ¼c ð4Þ
V0 X0 X0
compared to shrinkage in the equivalent diameter of the material.
where V is the volume of the sample (m3) at the end of each test, V0
is the original volume of the sample (m3), X is the moisture content
2. Materials and methods (dry basis), and a, b, c are the empirical coefficients.
If the value of the Heywood shape factor remains near its initial
2.1. Vacuum Frying Equipment value, the change in shape of the material can be considered uni-
form; however, a value much lower than its initial value will indi-
Fig. 1 depicts the experimental setup consisting of a vacuum cate that there is more shrinkage in the overall volume of the
fryer, a condenser, a liquid ring vacuum pump (Model ET32030, material compared to shrinkage in the equivalent diameter of the
Nash, Trumbull, CT), and a centrifuge. The vacuum fryer was con- material. The moisture content at each time interval was obtained
structed from stainless steel with a diameter of 400 mm, a height by drying the sample in a vacuum oven (Model VOS-300VD, EYELA,
of 300 mm, and a wall thickness of 6 mm. The stainless steel lid Tokyo) at 70 °C and 4.0 kPa for 24 h (AOAC, 1990).
of the fryer had a thickness of 8 mm. The condenser and the centri-
fuge were fabricated and assembled by the Department of Chemi- 2.3. Texture analysis
cal Engineering, Prince of Songkla University, Hat Yai, Thailand. The
condenser consisted of a 9425 mm long stainless steel tube with an Textural properties of the bananas were analyzed using a Tex-
internal diameter of 19.0 mm coiled inside a stainless steel con- ture Analyzer (Model TA-XT2i, Stable Micro Systems™ Co., Eng-
tainer circulated with cooling water. The vacuum pump was pur- land). The sample was placed on a hollow planar base (Bourne
chased from Kinetics Engineering Co. (Thailand). After frying, the et al., 1978). For fresh samples, a 2 mm spherical probe was set
products were centrifuged for 5 min at 450 rpm to remove excess to travel at a speed of 2 mm/s and a traveling distance of 10 mm.
surface oil and to minimize oil absorption. For fried samples, a 1=4 in. (approx. 6 mm) diameter probe was used
300 R. Yamsaengsung et al. / Journal of Food Engineering 106 (2011) 298–305

Fig. 1. Schematic of the vacuum frying operation (Yamsaengsung and Rungsee, 2003).

at a speed of 1 mm/s and a traveling distance of 4 mm or until the Pilgrim, 1957; Meilgarrd et al., 1999). Since hedonic scales can be
sample cracked. The maximum compression force from the force– considered as interval scales, they can be statistically analyzed
deformation curve of each sample was considered as an indication using ANOVA (analysis of variance). Even though some researchers
of hardness. A total of ten samples were used for each test run. have argued that the hedonic scales should be best considered as
Data were evaluated using the Texture Expert Software (SMS ordinal scales (Jones et al., 1955; Stroh, 1998), Peryam and Girardot
Ltd., Version 1.19, Stable Micro Systems™ Co., England). (1952) and Peryam et al. (1960) suggested that parametric analysis
was a viable approach on practical grounds (Nicolas et al., 2010). A
2.4. Structural analysis taste panel consisting of 30 random students and staffs from the
campus of the Prince of Songkla University (Thailand) was used.
An SEM (Scanning Electron Microscope, JEOL Model JSM 5800 LV, Since Thai people are brought up to display modest emotions in
Tokyo, Japan) was used to observe changes in the pore size and the public, words such as ‘like extremely’ and ‘dislike extremely’ are
pore size distribution within the product during vacuum frying. often avoided and seldom used. The 7-point hedonic scale test,
The applied voltage was 10 kV and the magnification was 100. rather than the 9-point hedonic scale test, was used to reduce
The ImageJ 1.42 Software (National Institutes of Health) was used the difficulty in differentiating of terms ‘like very much’ (a ‘7’
to determine the number of pore counts along with the average pore score) and ‘like extremely’ (a ‘9’ score) by this particular group of
size for a particular SEM image. The minimum and maximum pore Thai participants. Both 7-point scale and 9-point scale are widely
sizes were also determined along with the standard deviations. used, and in many instances, a 9-point scale test may be more
appropriate (especially for a pre-trained panel). The definition of
2.5. Effect of ripeness (sugar and starch content) each score for the 7-point hedonic scale test was ‘1’ = ‘dislike very
much’, ‘2’ = ‘dislike moderately’, ‘3’ = ‘dislike slightly’, ‘4’ = ‘neither
Effect of ripeness, or the amount of sugar content, on the degree like nor dislike’, ‘5’ = ‘like slightly’, ‘6’ = ‘like moderately’, and
of shrinkage and expansion was also studied to determine if there ‘7’ = ‘like very much’. The parameters tested were color, texture,
was an optimum sugar content level (which correlates to the taste, crispness, and overall likeness.
amount of starch content) that is necessary for the maximum
expansion of the product. High degree of expansion may be related
2.7. Statistical analysis
to the crispness of the product. Samples were allowed to ripen for 1,
2, 3, and 4 days at room temperature of 26 ± 2 °C and RH of
All experiments were performed in duplicate and the mean val-
45 ± 10%. Day 2 was used as the reference ripeness when merchants
ues with standard deviations were reported. The experimental data
market their bananas. This is the time when the peel and the stem
were analyzed using ANOVA. Duncan’s multiple range test was
of the banana bunch were completely yellow (ChiquitaÒ peel color
used to establish multiple comparisons of the mean values; mean
index of 6). Day 1 corresponds to the color index of 5 (mostly yellow
values were considered at 95% confidence level (p = 0.05). A statis-
with green tip), while Day 4 corresponds to peel color level of 7
tical program SPSS (Version 12) was used to perform all statistical
(overripe with dark spots on peel). Fresh samples were submitted
calculations.
to the Agro-Industry Development Center for Export (ADCET, Prince
of Songkla University, Thailand) to obtain total carbohydrate (prox-
imate analysis) and total sugar content (Lane and Eynon). Total car- 3. Results and discussion
bohydrate (percent) was calculated by subtracting the percentage
of moisture content, fat, protein, and ash from 100. The total sugar 3.1. Shrinkage and expansion
content was determined in terms of % sucrose of the original sample
and was calibrated using a glucose standard curve. The starch con- Table 1 presents the experimental results for shrinkage and
tent was obtained by subtracting the total amount of carbohydrate expansion as a function of frying time for bananas slices fried at
by the amount of total sugar content. 110 °C under 8 kPa up to 20 min and Fig. 2 plots the results as a
function of frying time. Even though the total frying time for a
2.6. Sensory evaluation product can take as short as 90 s for potato chips and as long as
20 min for fried pork meat (Sosa-Morales et al., 2006), these pro-
To evaluate the acceptability of the product, a hedonic scale test cesses take place at 160–190 °C, while the vacuum frying temper-
for likeness was used (Peryam and Girardot, 1952; Peryam and ature is from 100 to 120 °C. Therefore, the frying conditions, the
R. Yamsaengsung et al. / Journal of Food Engineering 106 (2011) 298–305 301

Table 1
Dimensional changes as a function of frying time and moisture ratio for T = 110 °C and p = 8 kPa.

Time % Shrinkage % Expansion X/X0 V/V0 L/L0


a b d b
0 0.00 ± 0.00 0.00 ± 0.00 1.000 ± 0.000 1.000 ± 0.000 1.000 ± 0.000b
5 10.15 ± 1.49c 20.98 ± 2.14a 0.278 ± 0.022c 0.636 ± 0.038a 0.790 ± 0.021a
10 2.98 ± 2.53b 1. 92 ± 9.11b 0.047 ± 0.012b 0.922 ± 0.134b 0.980 ± 0.091b
15 1.80 ± 1.25b 12.80 ± 6.92c 0.023 ± 0.015a 1.088 ± 0.094c 1.128 ± 0.069c
20 1.32 ± 2.91b 20.50 ± 9.24d 0.019 ± 0.008a 1.173 ± 0.159c 1.205 ± 0.092d

Values in the same column with different superscripts mean that the values are significantly different (p < 0.05).

thickness of the product, the property of the foodstuffs, and the de- 3.2. Model fitting
sired final characteristics of the product all directly influence the
total frying time of the product. In this case, frying was carried The empirical models for Mayor and Sereno (2004) and Panya-
out for 20 min until the product banana chips were completely wong and Devahastin (2007) were used to fit the results for the
crispy (no soft, mushy texture). Additional frying time resulted in vacuum frying of bananas. Changes in thickness (L) and volume
undesirable dark colorations of the product. (V) can be described by a second order equation using ratios L/L0
From Table 1, for banana slices fried at 110 °C, there is a signif- and V/V 0 versus moisture content ratio, X/X0. Even though previous
icant shrinkage in the product diameter during the first 5 min of results for plantain bananas slices dried at 40 °C (Johnson et al.,
frying, indicating a rapid water loss. The moisture content in the 1998) and whole bananas dried at 50 and 70 °C (Queiroz and Ne-
product decreased dramatically from 74% (w.b.) to 44% (w.b.). This bra, 2001) indicated a linear shrinkage in the diameter of the prod-
results correlates with a typical drying process in which water is uct, Demirel and Turhan (2003) observed a second order
removed from the porous structure and the cell walls collapse un- relationship between diameter shrinkage and volume shrinkage
der compressive stress (Demirel and Turhan, 2003; Kraisheh et al., for the air-drying of Cavendish bananas at 40 and 70 °C. They con-
2004; Panyawong and Devahastin, 2007; Nimmol et al., 2007). cluded that the degree of shrinkage depended on specific drying
However, after approx. 5 min of frying, the degree of shrinkage de- condition. Results for this study are shown in Table 2. While the
creased. Nimmol et al. (2007) suggested that the effect of casehar- second order model fitted well (R2 of 0.8964 and 0.8406 for L/L0
dening (rigid layer) at the product perimeter may retard the degree and V/V0, respectively), the Heywood shape factor model gave an
of shrinkage. In addition, once a crust region began to form at the even better representation of the changes in deformation as a func-
product surface and its perimeter, the product may have expanded tion of time (R2 of 0.9881). From Fig. 3, there is a slight decrease in
in the axial and radial direction as gaseous vapor expanded, caus- the Heywood shape factor during the first 10 min of frying – indi-
ing a pressure buildup. Similar results can be seen for the thickness cating an overall volume decrease, followed by a striking increase
expansion of the product. The thickness of the banana chips de- in the Heywood shape factor to 0.15 after 20 min of frying – repre-
creases by nearly 20% after 5 min of frying. Once the crust had been senting the product expansion. Even though the value of the
formed and gas pressure buildup occurred inside the product, the Heywood shape factor was low compared to previous work
product expanded by as much as 20% at the end of the frying pro- (Panyawong and Devahastin, 2007), there was still a significant in-
cess. Yamsaengsung and Moreira (2002b) observed similar effects crease in the Heywood shape factor from 0.112 (at t = 0 min.) to
of puffing due to pressure buildup inside the product for super- 0.153 (at t = 20 min.) or a 35.8% increase. In the previous work by
heated steam drying of tortilla chips. Panyawong and Devahastin (2007), the samples were cut into
Moreover, from Fig. 2, a frying temperature of 110 °C produced cubes, which meant that both the numerator and the denominator
the highest degree of expansion. Since there was no significant dif- equaled 1.0 before drying. In this work, the samples were cut into
ference in the degree of expansion between 110 and 120 °C, higher thin discs, so the numerator term (V) was small compared to the
frying temperature would not be necessary for increasing the denominator term (d3). Still, the changes in the values of the Hey-
expansion or the crispness of the product. At the same time, lower wood shape factor reflected actual deformation of the structure in
frying temperature would also reduce the energy cost of the frying both axial and radial directions. The models fitted above only apply
process, as well as minimizing nutritional loss from higher temper- to vacuum frying of bananas at 110 °C and does not hold true for
ature treatment. other frying conditions. Similar procedures may be conducted to
obtain a correlation between water content and deformation of
the product.
During drying, the product does not undergo a uniform change
in dimensions nor volume; therefore, the Heywood shape factor
was developed to account for this irregularity. Porous media has
uneven size pores, so when water is removed from these pores,
the material shrinks non-uniformly, resulting in uneven product

Table 2
Empirical models used and their coefficients for vacuum fried bananas at T = 110 °C
and p = 8 kPa.

Equation⁄ k1 k2 k3 R2
2
L/L0 = k1  k2(X/X0) + k3 (X/X0) 1.1616 1.8584 1.6977 0.8406
V/V0 = k1  k2(X/X0) + k3 (X/X0)2 1.1377 2.5208 2.3841 0.8964
ks = k1  k2 t + k3 t2 0.1132 0.0036 0.0003 0.9881
Fig. 2. Percent thickness expansion and hardness of vacuum fried banana slices at

100, 110, and 120 °C and 8.0 kPa after 20 min of frying. Values in the same data Modified from Mayor and Sereno (2004) and Panyawong and Devahastin (2007).
series with different superscripts mean that the values are significantly different L = thickness (mm), V = volume (m3), X = water content (wet basis), t = time (min),
(p < 0.05). and ki = coefficients, ks = Heywood shape factor.
302 R. Yamsaengsung et al. / Journal of Food Engineering 106 (2011) 298–305

perature (25 °C) and product remained in a rubbery state. However,


after 15 min of frying, the lowered moisture content inside the
product (X/X0 = 0.023 ± 0.015 or about 6.0% w.b.) helped to increase
the Tg above the room temperature, allowing the product to be in a
glassy state and become harder as indicated in Fig. 4. Boudhrioua
et al. (2002) also observed an increase in hardness (Fp, maximum
force applied until perforation) as a function of drying time for
air-drying at 40, 60 and 80 °C. From Table 3, the effect of tempera-
ture on the hardness of the product was not significant (p > 0.05) as
the hardness of the final product at 100, 110, and 120 °C were
10.93 ± 1.28, 12.17 ± 2.29, and 11.27 ± 1.82 N, respectively. In addi-
tion, Nimmol et al. (2007) also did not find any significant effect of
drying temperatures (70, 80, and 90 °C) using low-pressure super-
heated steam drying (LPSSD), low-pressure superheated steam and
far-infrared radiation (LPSSD-FIR), and far-infrared radiation under
vacuum (VACUUM-FIR) drying on the hardness of dried banana
Fig. 3. The Heywood shape factor for vacuum fried banana slices at 110 °C and
slices (3 mm thick and 30 mm in diameter). The maximum forces
8.0 kPa as a function of time. required to break the products for the above processes ranged from
16.39 to 24.09 N which were much higher than that found for vac-
uum frying. Hence, it can be inferred that hardness and crispness of
surface, thickness, and diameter. Both ratios of L/L0 and V/V 0 make the product are also process dependent. Since samples from the
reference to the original thickness (L0) and the original volume (V0) previous research had slightly different geometry compared to this
while the Heywood shape factor, in contrast, makes reference to its research (3.5–4.5 mm thick and 25–30 mm in diameter), a separate
volume at time t versus its projected equivalent diameter at the investigation involving these techniques must be made to posi-
same time t. Hence, the change in dimension as a function of time tively identify significant differences in the hardness of the
for this particular product corresponds better to the equation using samples.
the Heywood shape factor.

3.4. Effect of ripeness on physical and textural changes of the product


3.3. Textural changes: hardness of the product
As banana ripens, the amount of starch decreases as it is hydro-
Fig. 4 depicts the changes in the hardness of the product as a lyzed into small sugar molecules of sucrose and maltose (Bou-
function of frying time (decreasing moisture content). As can be dhrioua et al., 2002). The effect of total sugar content on thickness
seen, the hardness of the product decreased substantially from expansion and diameter shrinkage (based on the ripeness of the
6.14 ± 0.85 to 1.29 ± 0.23 N during the first 10 min of frying and in- product) is shown in Table 3. From Table 3, the highest degree of
creased significantly as the product changed from a rubbery, soggy thickness expansion of 20.54 ± 7.24% occurred for products from
material to a hard and crispy product after 20 min of frying Day 2. This may indicate the optimum value of starch to sugar con-
(12.17 ± 2.29 N). During the first 10 min of frying, there was a rapid tent required to produce the highest degree of puffing. Yet, if the
movement of water from within the product toward the product product becomes too ripened (may contain some bruises and be-
surface. This water mobility caused the product to become rubbery come mushy), the extent of starch gelatinization and crust forma-
and soggy. At the same time, as the starch granules within the prod- tion during the initial stages of frying may be slow, causing lower
uct were exposed to heat, water, and shear stress, they begin to pressure buildups during the frying process. In addition, Day 3 and
gelatinize, giving structure and a more solid texture to the product. Day 4 products also had more shrinkage compared to those of Day
However, after this 10 min of frying, there were still some water in- 2. This result correlated with previous studies of having higher
side the product, as indicated in Table 1 (X/X0 = 0.047 ± 0.012 or shrinkage with slower drying rate and slower crust formation of
about 12% w.b.). As a result, even after cooling, the glass transition the product (Nimmol et al., 2007).
temperature (Tg) of the product remained lower than the room tem- Moreover, with Day 1 representing the least ripened bananas
and containing the lowest sugar to starch ratio of 2.90 ± 0.20, its
hardness value of 16.51 ± 1.40 N was significantly higher than
those of other days of ripeness. At the same time, it showed less
expansion than Day 2 products, indicating a more compact and
harder structure as opposed to a crispier, porous structure. This ef-
fect can be observed from the SEM pictures. In general, this result
corresponded to that of Boudhrioua et al. (2002) who also found
that bananas ripened for up to 16 days has a much lower peak
force (Fp) or hardness compared to freshly ripened bananas
(2 days). From Table 3, even though the % total sugar for Days 2,
3 and 4 products were slightly higher than Day 1 products, these
values were not significantly different from each other. Even
though the bananas were all taken from a local banana distributor
at the same time with the same extent of ripeness (green tip), there
may still have been variations in the chemical compositions of ba-
nanas purchased. As a result, the banana samples from Day 3 actu-
ally had higher sugar content than those from Day 4. Nonetheless,
Fig. 4. Hardness of vacuum fried banana slices at 110 °C and 8.0 kPa as a function of although no direct correlation could be obtained from this result, a
frying time. general conclusion could be made that factors such as sugar to
R. Yamsaengsung et al. / Journal of Food Engineering 106 (2011) 298–305 303

Table 3
Effect of days of ripeness on the percent shrinkage, percent expansion, total sugar content and hardness of vacuum fried bananas fried at T = 110 °C and p = 8 kPa.

Day % Shrinkage % Expansion % Carbohydrate % Total sugar Sugar to starch ratio Hardness (N)
a ab b a a
1 3.91 ± 3.63 13.04 ± 7.95 26.44 ± 0.30 19.75 ± 0.51 2.95 ± 0.20 16.51 ± 1.40d
2 2.88 ± 3.73a 20.54 ± 7.24b 24.18 ± 1.23a 21.70 ± 0.63b 8.75 ± 2.33c 13.36 ± 1.31c
3 1.25 ± 3.33a 9.64 ± 11.98ab 25.16 ± 0.41a 20.18 ± 1.54ab 4.05 ± 1.69b 9.94 ± 1.04a
4 2.81 ± 2.02a 5.61 ± 7.64a 26.06 ± 0.85b 22.04 ± 0.42b 5.48 ± 0.42b 11.79 ± 1.05b

Values in the same column with different superscripts mean that the values are significantly different (p < 0.05).

Fig. 5. SEM images of vacuum fried banana slices as a function of frying time at 110 °C and 8.0 kPa (100).

starch content can influence the degree of expansion and crispiness structure (smaller and less pores) product has a slightly lower
of the product. hardness value than those with large pores.

3.5. Structural changes 3.6. Sensory evaluation

In Figs. 5 and 6, SEM images were taken to study the internal Table 5 shows the result of the sensory evaluation performed
structure of the banana slices. Fig. 5 presents the change in the for vacuum fried bananas at 110 °C under 8 kPa for different days
structure of the vacuum fried product as a function of time of ripeness. From the results, Day 2 products scored the highest
(T = 110 °C). After 5 min of frying, the pores within the product be- for taste (5.9 ± 0.6), crispness (6.0 ± 0.8), and overall impression
came more compressed and distorted. Previous researchers (Ratti, (6.0 ± 0.7). However, from statistical analysis, there were no signif-
1994; Achanta and Okos, 2000; Panyawong and Devahastin, 2007) icant difference (p > 0.05) in the scores obtained for color, texture,
have contributed this observation to the removal of free water taste, crispness, and overall impression. Since all products were
from the cellular structure and the microstructural stresses devel- fried under the same conditions and for the same duration of time
oped inside the product. However, as frying time increased, there (20 min.), the sensory panel did not observe any significant differ-
was a gradual increase in the size of pores within the product. This ence (p > 0.05) in the color of the product. This result indicated that
strongly supports the gas vapor expansion inside the product, lead- fresh bananas can be stored for up to 4 days after reaching a color
ing to thickness expansion and puffing. From Table 4 the average index of 5 without showing any significant difference in the
pore diameter increased significantly from 37.84 ± 20.08 lm after acceptability of the products by this particular group of consumers.
10 min of frying to 84.92 ± 70.16 lm after 15 min of frying. Finally, In addition, from Table 3, Day 2 products have a lower hardness va-
in Fig. 6 and Table 4, the effects of ripeness on the structure of the lue than Day 3 and Day 4 products, while it has the highest degree
fried bananas were compared. Results showed that there were no of expansion. These two factors agree with the sensory evaluation
significant differences in the average pore diameter for vacuum of Day 2 products of being the crispiest. The harder the final prod-
frying at different temperatures. Moreover, from Table 4, Day 1 uct, the more it is associated to being stiff and brittle (Boudhrioua
products had the highest hardness value because it had the fewest et al., 2002), rather than crispy. Still, a conclusion cannot be made
number of pores (less porous than the others), while Day 3 and Day based on that the sensory evaluation that Day 2 product was the
4 had the lowest hardness values because it had very small, com- most preferred. It is clear that once the bananas have ripened
pacted pores. Nimmol et al. (2007) also observed that a dense (Day 1), consumers’ preference for the vacuum fried products leans
304 R. Yamsaengsung et al. / Journal of Food Engineering 106 (2011) 298–305

Fig. 6. SEM images of vacuum fried banana slices at 110 °C and 8.0 kPa as a function of ripeness (30).

Table 4 more toward ‘like slightly’ to ‘like moderately’ as opposed to ‘nei-


Number of pores and average diameter for vacuum fried bananas at various ther like nor dislike’ or ‘dislike slightly’. Investigations using bana-
conditions. nas more ripened than those in this study may provide a better
Samples Number of pores Diameter of pores conclusion on the effect of sugar to starch ratio on the final product
characteristics and acceptability.
Average (lm) Min (lm) Max (lm)
Effect of frying time*
Fresh Bananas 348 33.84 ± 17.06a 19.54 148.46 4. Conclusions
5 min. 405 32.14 ± 14.36a 19.54 129.09
10 min. 275 37.84 ± 20.08a 19.54 181.01 In this study, dimensional changes of vacuum fried bananas
15 min. 53 84.92 ± 70.16b 19.90 312.84 were modeled using empirical equations and the Heywood shape
20 min. 57 73.53 ± 61.69b 19.90 260.78
factor. The thickness and volume ratio of the fried bananas fol-
25 min. 72 62.64 ± 61.33b 19.54 307.27
lowed a second order model while the Heywood shape factor of
Effect of Temperature**
the product initially decreased then increased substantially indi-
100 °C* 493 58.47 ± 47.72b 21.72 378.21
110 °C* 347 79.77 ± 106.58b 21.72 809.91 cating significant volume expansion. SEM images clearly verify
120 °C* 384 58.48 ± 68.25b 21.72 666.26 the increase in the pore size of the products due to gas vapor
Effect of Ripeness*** expansion during the frying process. Products ripened for 2 days
Day 1 465 61.57 ± 59.35b 21.72 464.90 and fried at 110 °C under 8 kPa pressures produced the highest de-
Day 2 430 76.70 ± 84.61b 21.72 549.22 gree of expansion, but sensory evaluations showed that there was
Day 3 615 65.73 ± 56.28b 21.72 431.23
no significant difference in the overall acceptability of the product
Day 4 460 69.36 ± 76.60b 21.72 549.94
based on the number of ripened days.
Day = day of ripeness, Min = minimum diameter; Max = maximum diameter. Values
in the same column with different superscripts mean that the values are signifi-
Acknowledgement
cantly different (p < 0.05).
*
p = 8 kPa, T = 110 °C.
**
p = 8 kPa, t = 20 min. This research was conducted through the auspicious grant of
***
p = 8 kPa, T = 110 °C, t = 20 min. the Graduate School Research Fund from the Prince of Songkla
University.
Table 5
Sensory evaluation based on bananas fried at 110 °C and 8 kPa at different days of
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