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Organic

Geochemistry
Organic Geochemistry 37 (2006) 1–11
www.elsevier.com/locate/orggeochem

Review
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Organic geochemistry – A retrospective of its first 70 years
Keith A. Kvenvolden *

U.S. Geological Survey, 345 Middlefield Road, MS 999, Menlo Park, CA 94025, USA
Institute of Marine Sciences, University of California, Santa Cruz, CA 95064, USA

Received 1 September 2005; accepted 1 September 2005


Available online 18 October 2005

Abstract

Organic geochemistry had its origin in the early part of the 20th century when organic chemists and geologists realized
that detailed information on the organic materials in sediments and rocks was scientifically interesting and of practical
importance. The generally acknowledged ‘‘father’’ of organic geochemistry is Alfred E. Treibs (1899–1983), who discov-
ered and described, in 1936, porphyrin pigments in shale, coal, and crude oil, and traced the source of these molecules to
their biological precursors. Thus, the year 1936 marks the beginning of organic geochemistry. However, formal organiza-
tion of organic geochemistry dates from 1959 when the Organic Geochemistry Division (OGD) of The Geochemical Soci-
ety was founded in the United States, followed 22 years later (1981) by the establishment of the European Association of
Organic Geochemists (EAOG). Organic geochemistry (1) has its own journal, Organic Geochemistry (beginning in 1979)
which, since 1988, is the official journal of the EAOG, (2) convenes two major conferences [International Meeting on
Organic Geochemistry (IMOG), since 1962, and Gordon Research Conferences on Organic Geochemistry (GRC), since
1968] in alternate years, and (3) is the subject matter of several textbooks. Organic geochemistry is now a widely recognized
geoscience in which organic chemistry has contributed significantly not only to geology (i.e., petroleum geochemistry,
molecular stratigraphy) and biology (i.e., biogeochemistry), but also to other disciplines, such as chemical oceanography,
environmental science, hydrology, biochemical ecology, archaeology, and cosmochemistry.
Published by Elsevier Ltd.

1. Introduction latter half of the 18th century saw the independent


rise of each of these basic disciplines. Geology be-
Organic geochemistry is a modern geoscience gan in the 50 years between 1775 and 1825 with
that results from the amalgamation of many aspects the musings of James Hutton (see McIntyre,
from the two fundamental, but disparate, scientific 1963); organic chemistry, during approximately
disciplines of geology and organic chemistry. The the same time interval, grew out of the recognition
of the basic difference between organic and inor-
q
ganic chemical compounds – organic compounds al-
Material in this paper was presented orally at the 229th ways contain carbon (see Noller, 1957). Geology
American Chemical Society National Meeting, San Diego, CA,
March 2005 in a symposium ‘‘History of Organic Geochemistry’’.
and organic chemistry continued to evolve indepen-
*
Tel.: +1 650 329 4196. dently until the early part of the 20th century
E-mail address: kkvenvolden@usgs.gov. when geologists realized the scientific and practical

0146-6380/$ - see front matter. Published by Elsevier Ltd.


doi:10.1016/j.orggeochem.2005.09.001
2 K.A. Kvenvolden / Organic Geochemistry 37 (2006) 1–11

importance of organic matter in rocks, and organic stances (chlorophyll and hemin), thus linking geo-
chemists discovered that rocks contain an abun- molecules to biomolecules. These men were
dance of organic compounds of fundamental and contemporaries, both born in 1899, but it is unlikely
applied interest. The purpose of this paper is to that their paths ever crossed.
(1) update information about the formal organiza-
tion of organic geochemistry, (2) summarize the 2.1. Parker D. Trask
lives of early practitioners in the field, (3) gauge
the content of the subject matter, and (4) acknowl- Parker Trask (Fig. 2A) came from New England
edge those who organized organic geochemistry in the United States, and was educated in Califor-
and those who have helped sustain the field through nia, obtaining an advanced degree in geology from
their editorships of Organic Geochemistry. Fig. 1 the University of California at Berkeley. From
shows a timeline of events in the development of 1926 to 1931 he was a research associate with the
the history of organic geochemistry. American Petroleum Institute (API), working on
studies related to petroleum source rocks. In 1931
2. Origins and awards the source-bed project became a joint undertaking
with the API and the U.S. Geological Survey
Two individuals can be identified who success- (USGS), and Trask became a USGS employee, a
fully merged geology and organic chemistry in the connection he retained full time for 15 years and
1930s. From the geologic side, Parker D. Trask part time thereafter until his death in 1961. The
(Fig. 2A) related the organic materials in sediments joint API/USGS project, which he led, continued
(Trask, 1932) and sedimentary rocks (Trask and for 10 years during which time the chemical and
Patnode, 1942) to an understanding of the source physical properties of more than 25,000 samples
beds of petroleum. From the organic chemistry side, from many geological formations from most parts
Alfred E. Treibs (Fig. 2B) discovered organic (por- of the United States were studied. The goal was to
phyrin) pigments in shale, crude oil, and coal (Tre- determine possible relationships between these sam-
ibs, 1936), and demonstrated that these pigments ples and oil reservoirs in a search for clues to the
were degradation products from biological sub- recognition of true petroleum source beds. During

ORGANIC GEOCHEMISTRY TIMELINE

Treibs
(Organic Chemistry) Organic Geochemistry

Trask (Geology)
Petroleum
Geochemistry
Organic Geochemistry Division,
The Geochemical Society

European Association of Organic Geochemists

Journal Organic Geochemistry

Gordon Research Conferences


on Organic Geochemistry
International Meetings
on Organic Geochemistry
50
40

00

10
30

90
60

70

80
19
19

20

20
19

19
19

19

19

Fig. 1. Timeline showing the history of the development of organic geochemistry.


K.A. Kvenvolden / Organic Geochemistry 37 (2006) 1–11 3

Fig. 2. Early practitioners of organic geochemistry: (A) Parker D. Trask (!1960), a geological organic geochemist; (B) Alfred E. Treibs
(1979), a chemical organic geochemist, and the ‘‘Father of Organic Geochemistry’’; (C) G.T. Philippi (!1979), first recipient of the A.E.
Treibs Award.

Fig. 3. The organizers of organic geochemistry as a geoscience discipline: (A) Bart Nagy, founder of OGD; (B) Pieter Schenck, founder of
EAOG.

Fig. 4. The Editors of the journal Organic Geochemistry: Irving Breger, Earl Baker, Pieter Schenck, Archie Douglas, Joe Curiale, James
Maxwell, and Lloyd Snowdon.
4 K.A. Kvenvolden / Organic Geochemistry 37 (2006) 1–11

much of his later life (after 1941) Trask devoted his ning of the geoscience of organic geochemistry, 70
attention to engineering geology, and he is better years ago. A tribute to Treibs has been provided
remembered as an engineering geologist than an or- by Seifert (1977), who was one of Treibs! many
ganic geochemist (Bailey, 1962; Gilluly, 1963). He students.
probably did not even consider himself an organic
geochemist, and perhaps did not even know that 2.3. Awards
he was, in essence, an early practitioner of organic
geochemistry on a grand scale, emphasizing the In recognition of the pioneering work of Alfred
‘‘geo’’ aspects of the subject. Treibs, an award was established in his name. The
Alfred E. Treibs Award (consisting of a Medal and
2.2. Alfred E. Treibs Certificate) is given for ‘‘outstanding contributions
to Organic Geochemistry’’, and was presented as
In contrast to Trask, Alfred Treibs (Fig. 2B) was an honorary award to A.E. Treibs in 1979. In
well recognized during his lifetime as an organic the same year, the first designated recipient was
geochemist. His scientific research on porphyrin pig- G.T. (Ted) Philippi (Fig. 2C) for his pioneering
ments in various geological materials, spanning al- work in petroleum geochemistry, a major part of
most five decades, set the stage and the standard organic geochemistry. Much of his research was
for the new geoscience of organic geochemistry. conducted from 1936 to 1968 in various laborato-
His pioneering body of work is internationally rec- ries of Shell Oil Company. His publications,
ognized, and he was acclaimed and honored on though not numerous, were recognized by the or-
his 80th birthday in 1979 by the symposium entitled ganic geochemical community as conceptually
‘‘The Impact of the Treibs! Porphyrin Concept on important and very stimulating. Appearing late in
the Modern Organic Geochemistry’’ (Prashnowsky, his professional career, after a lifetime of experi-
1980). In 1999, 16 years after his death, a sympo- ence, his publications, beginning about 1957, dealt
sium was ‘‘Dedicated to the Memory of Alfred Tre- with (1) the chemical recognition of petroleum
ibs, the Father of Organic Geochemistry on the source rocks, (2) the importance of subsurface tem-
100th Anniversary of his Birthday’’ (Prashnowsky, peratures on the formation and composition of
2002). petroleum, (3) the roles of marine and terrestrial
Treibs was born in the German village of Idar- plants as the ultimate sources of petroleum, and
Oberstein; his home is now marked with a bronze (4) the nature and extent of bacterial affects on
plaque [GEBURTSHAUS VON PROF. DR. petroleum. His active life as a petroleum geochem-
ALFRED TREIBS (1899–1983) BEGRÜNDER ist continued unabated after his retirement in 1968,
DER ORGANISCHEN GEOCHEMIE]. He stud- and many of his publications appeared after that
ied chemistry in Aachen and later in Munich where date. His early contributions to petroleum geo-
he obtained advanced academic degrees at the chemistry have been outstanding.
Technical University (TU). He continued on the From 1979 through 2002, 17 organic geochemists
staff at the TU for most of his career, except for have received the Treibs Award (Kvenvolden,
the time from 1936 to 1945 when he worked at 2002). Since 2002 this award has been presented to
Wacker-Chemie, an industrial research institute. Roger Summons (2003), Eric Galimov (2004), and
During his 50-year association with the TU, he Jaap Sinninghe Damsté (2005). Two other awards
was involved with research on porphyrins, first as are given to recognize organic geochemists – the Pi-
a student supervised by Han Fischer (awarded a eter A. Schenck Award and the Australian Organic
Nobel Prize for the utilization of physico-chemical Geochemistry Medal. The Schenck Award is given
methods applied to pyrroles, the basic structures of every second year to a scientist under 35 years of
porphyrins), and later as Fischer!s colleague, as a age who has made a major contribution to any spe-
research leader, and as a teacher. At the TU, Treibs cific area of organic geochemistry or related field.
laid the foundations of the science of Organic Geo- The awardees have been J. Sinninghe Damsté
chemistry with his fundamental research leading to (1993), Mark McCaffrey (1995), Kate Freeman
an understanding of the significance of porphyrin (1997), Stefan Schouten (1999), and Kliti Grice
pigments in shale, oil, and coal (Treibs, 1936). With (2001). The Australian Organic Geochemistry
the recognition of Treibs as the ‘‘father’’ of organic Medal for lifetime achievement in organic geochem-
geochemistry, the date 1936 represents the begin- istry has been awarded to John Smith (1991).
K.A. Kvenvolden / Organic Geochemistry 37 (2006) 1–11 5

Basil Johns (1993), Trevor Powell (1995), Dave the subject matter of these conferences. The idea of
McKirdy (1996), Bob Alexander (1998), Barry Batts a GRC on organic geochemistry seems to have
(2000), Roger Summons (2002), and John Volkman originated in 1963 with a conference entitled
(2004). ‘‘Origin of Petroleum’’. For the next six years,
GRCs were convened and dealt with broad issues
3. Organizations and conferences in geochemistry, including organic geochemistry,
but it was not until 1968 and thereafter that GRCs
Organic geochemistry was formally organized focused specifically on organic geochemistry. A
and recognized as a geoscience about 30 years after tabulation of GRCs (from 1968 to 2002) is given
Treibs and Trask set the stage (Fig. 1). In 1959 Bart in Kvenvolden (2002). One GRC has met since in
Nagy (Fig. 3A) established the Organic Geochemis- 2004 with S. Wakeham as Chairperson.
try Division (OGD) of The Geochemical Society
(GS), which met for the first time in 1960 at the an- 4. The journal Organic Geochemistry
nual meeting of the Geological Society of America.
By early 1961, OGD was recognized as an integral Responding to the proliferation of technical pa-
part of GS. Pieter Schenck (Fig. 3B) organized the pers addressing organic geochemical topics, Irving
European Association of Organic Geochemists Breger established the journal Organic Geochemistry
(EAOG) in 1981, and EAOG met at the 11th Inter- in 1977, published by Pergamon Press. He served as
national Meeting on Organic Geochemistry at The Editor-in-Chief until the time of his death in 1982.
Hague, The Netherlands in 1983. The officers In volume 1, number 1 (1977) of the journal, Breger
(Chairperson and Secretary) through 2003 for both wrote the FORWARD which read:
organizations were tabulated in Kvenvolden (2002).
Organic Geochemistry has been established in
Since this compilation the 2003–2005 officers for
response to the need for a specialized medium
OGD are M. Whiticar, Chairperson, and T. Dickne-
for the publication of research in this highly
ider, Secretary. For EAOG the officers since 2002
interdisciplinary field. At present papers con-
are R. Patience, Chairperson, and S. Derenne,
cerned with interrelated fields such as organic
Secretary.
chemistry, inorganic chemistry, geology, mineral-
After OGD was formally organized in 1959, two
ogy, biogeochemistry, oceanography, hydrology,
series of conferences have been devoted specifically
atmospherics and extraterrestrial subjects are
to organic geochemistry for more than 40 years
published in many scattered journals. It is
(Fig. 1) – International Meetings on Organic
intended that Organic Geochemistry serve as a
Geochemistry (IMOG) and Gordon Research
medium for the publication of reports on all
Conferences (GRC) on Organic Geochemistry.
phases of geochemistry in which organic sub-
IMOG began in 1962 with a gathering in Milan,
stances play a role. Interpretation of this policy
Italy, and has met consistently every other year (ex-
will be liberal to permit the broadest possible
cept for a three-year hiatus between 1968 and
exchange of ideas. Among others, papers related
1971) since 1962. A tabulation of the first 20
to crude oils, coals, natural gas and shales and
IMOGs (from 1962 to 2001) appears in Kvenv-
their associated substances will be welcome, as
olden (2002). The 21st IMOG (2003) took place in
will reports of studies on the roles of organic sub-
Kraków, Poland, with M. Kotarba (Chairperson)
stances in the geochemical cycles of various ele-
and B. Stankiewicz & M. Kotarba (Proceedings
ments. Reports of paleontological and coal
Editors). The 22nd IMOG (2005) took place in
petrographic studies will be considered favorably
Seville, Spain, with F. González-Vila as Chair-
if they are geochemically oriented. Letters to the
person.
Editor, relevant news and book reviews will be
GRCs on Organic Geochemistry have been held
published. Individual issues of Organic Geochem-
every other year at Holderness School, New
istry may be devoted to papers at Symposia.
Hampshire, since 1968. The 1968 conference was
titled ‘‘Organic Geochemistry’’, but in 1970 and This statement became the Aims and Scope of
1972 the conferences were titled ‘‘Geochemistry’’, the journal through v. 20, n. 3 (1993); in the next
although the main topic of discussion was organic issue [v. 20, n. 4 (1993)] the Aims and Scope were
geochemistry. From 1974 to the present, the name expanded and have appeared in most issues of
‘‘Organic Geochemistry’’ has been used to identify the journal to the present. The expanded version
6 K.A. Kvenvolden / Organic Geochemistry 37 (2006) 1–11

can be found at the frontmatter of this issue of Or- Organic Geochemistry became ‘‘The Official Journal
ganic Geochemistry. In addition to the major points of EAOG’’ with co-editors Earl Baker and Pieter
of the original statement, the current version in- Schenck. To date seven individuals have served as
cludes several more specific aspects of organic Editors of Organic Geochemistry (Fig. 4).
geochemistry, such as molecular and isotope geo-
chemistry (including compound-specific isotope 5. Textbooks in Organic Geochemistry
techniques), environmental geochemistry, organic
matter in marine and non-marine sediments, organic- In addition to the journal Organic Geochemistry,
rich rocks and soils, archaeological chemistry, bio- several books and compilations of papers have been
geochemical ecology, biomolecular paleontology, prepared which serve as textbooks on the subject.
and molecular stratigraphy. The journal seeks pa- Table 1 lists the Proceedings of IMOG. Each of
pers covering the full range of research activities these 21 (as of 2005) compilations of papers is
in organic geochemistry. Earl W. Baker assumed assembled under the title ‘‘Advances in Organic
editorship of the journal in 1983 with v. 5, n. 1 Geochemistry’’ and presents an up-to-date view of
(1983). Also this issue noted the journal!s official organic geochemistry as of the date of each IMOG
affiliation with EAOG. With v. 12, n. 1 (1988) conference. Examples of textbooks containing

Table 1
Advances in Organic Geochemistry. Proceedings of the International Meetings on Organic Geochemistry (IMOG)
IMOG Year Publication details
1st 1962 International Series of Monographs on Earth Sciences, No. 15, Pergamon Press, distributed by The Macmillan
Company, USA (1964), 488p
2nd 1964 International Series of Monographs on Earth Sciences, No. 24, Pergamon Press, UK (1966), 330p
3rd 1966 International Series of Monographs in Earth Sciences, No. 32, Pergamon Press, UK (1970), 577p
4th 1968 International Series of Monographs in Earth Sciences, No. 31, Pergamon Press, UK (1969), 617p
5th 1971 International Series of Monographs in Earth Sciences, No. 33, Pergamon Press, UK (1972), 736p
6th 1973 Éditions Technip, France (1974), 1080p
7th 1975 Empresa National Adaro de Investigaciones Mineras, S.A. (ENADIMSA), Spain (1977), 911p
8th 1977 Abstracts only published in meeting program. Index to Abstracts in Organic Geochemistry, 1, 115–121 (1978)
9th 1979 Physics and Chemistry of the Earth, vol. 12, Pergamon Press, UK (1980), 784p
10th 1981 Organized by EAOG, John Wiley & Sons, Ltd., UK, (1983), 880p
11th 1983 Organized by EAOG, Organic Geochemistry 6, 1–892 (1984)
12th 1985 Organized by EAOG, Part I, Petroleum Geochemistry. Organic Geochemistry 10(1–3), 1–648 (1986); Part II,
Molecular and General Organic Geochemistry. Organic Geochemistry 10(4–6), 649–1142 (1986)
13th 1987 Part I, Organic Geochemistry in Petroleum Exploration. Organic Geochemistry 13(1–3), 1–572 (1988); Part II,
Analytical Geochemistry. Organic Geochemistry 13(4–6), 573–1168 (1988)
14th 1989 Part I, Organic Geochemistry in Petroleum Exploration. Organic Geochemistry 16(1–3), 1–640 (1990); Part II,
Molecular Geochemistry. Organic Geochemistry 16(4–6), 641–1237 (1990)
15th 1991 Part I & Part II, Advances and Applications in Energy and the Natural Environment. Organic Geochemistry 19(1–6),
1–556 (1992)
16th 1993 Organic Geochemistry 22(3–5), 355–884 (1994)
17th 1995 Part I, Paleoclimate and Palaeoceanography. Organic Geochemistry 24(4), 399–472 (1996); Part II, Biopolymers and
Macromolecules. Organic Geochemistry 24(6/7), 593–750 (1996); Part III, Origin of Natural Gas; Petroleum
Geochemistry; Impact of Organic Geochemistry on Exploration; Migration and Expulsion of Oil and Gas. Organic
Geochemistry 24(10/11), 947–1096 (1996); Part IV, Reservoir and Production Geochemistry. Organic Geochemistry
24(12), 1097–1198 (1966); Part V, Environmental Organic Geochemistry; Microbial Geochemistry. Organic
Geochemistry 25(1/2), 1–130, (1996); Part VI, Palaeoenvironmental and Source Rock Occurrence; Biogeochemical
Cycling of Sulphur and Other Elements. Organic Geochemistry 25(5–7), 265–626 (1996); Part VII, Analytical
Developments in Organic Geochemistry; Archaeological and Palaeontological Organic Geochemistry. Organic
Geochemistry 26(1/2), 1–154 (1997)
18th 1997 Part I, Petroleum Geochemistry. Organic Geochemistry 29(1–3), 1–810 (1998); Part II, Biogeochemistry. Organic
Geochemistry 29(5–7), 1025–1835 (1998)
19th 1999 Petroleum Geochemistry; Biogeochemistry. Organic Geochemistry 31(12), 1263–1804 (2000)
20th 2001 Petroleum Geochemistry; Organic Matter Structure and Reactivity; Depositional Environments and
Biogeochemistry; Soil and Environmental Geochemistry. Organic Geochemistry 33(12), 1273–1770 (2002)
21st 2003 Diagenesis of Molecules and Sediments; Environmental and Soil Geochemistry; Petroleum Geochemistry. Organic
Geochemistry 35(11–12), 1197–1634 (2004)
K.A. Kvenvolden / Organic Geochemistry 37 (2006) 1–11 7

Table 2
Examples of Organic Geochemistry textbooks that contain papers by many authors, assembled by an Editor or Editors
Breger, I.A., 1963. Organic Geochemistry, International Series of Monographs on Earth Sciences, vol. 16. The Macmillan Co., New York,
USA, 658p
Nagy, B., Colombo, U., 1967. Fundamental Aspects of Petroleum Geochemistry. Elsevier, The Netherlands, 388p
Eglinton, G., Murphy, M.T.J., 1969. Organic Geochemistry – Methods and Results. Springer-Verlag, Germany, 828p
Durand, B., 1980. Kerogen – Insoluble Organic Matter from Sedimentary Rocks. Editions Technip, France, 519p
Kvenvolden, K.A., 1980. Geochemistry of Organic Molecules, Benchmark Papers in Geology, vol. 52. Dowden, Hutchinson and Ross,
Inc., USA, 357p
Brooks, J., 1981. Organic Maturation Studies and Fossil Fuel Exploration. Academic Press, UK, 441p
Atkinson, G., Zuckerman, J.J., 1981. Origin and Chemistry of Petroleum. Pergamon, UK, 116p
Brooks, J., 1983. Petroleum Geochemistry and Exploration of Europe, The Geological Society Special Publication No. 12. Blackwell
Scientific Publications, UK, 379p
Isaacs, C.M., Garrison, R.E., 1983. Petroleum Generation and Occurrence in the Miocene Monterey Formation, CA. Pacific Section,
Society of Economic Paleontologists and Mineralogists, USA, 228p
Miknis, F.P., McKay, J.F., 1983. Geochemistry and Chemistry of Oil Shales, ACS Symposium Series 230. American Chemical Society,
USA, 565p
Palacas, J.G., 1984. Petroleum Geochemistry and Source Rock Potential of Carbonate Rocks, AAPG Studies in Geology, No. 18.
American Association of Petroleum Geologists, USA, 208p
Brooks, J., Welte, D., 1984. Advances in Petroleum Geochemistry, vol. 1. Academic Press, UK, 344p
Demaison, G., Murris, R.J., 1984. Petroleum Geochemistry and Basin Evaluation, AAPG Memoir 35. American Association of
Petroleum Geologists, USA, 426p
Johns, R.B., 1986. Biological Markers in the Sedimentary Record. Elsevier, The Netherlands, 364
Magoon, L.B., Claypool, G.E., 1986. Alaska North Slope Oil/Rock Correlation Study – Analysis of North Slope Crude, AAPG Studies in
Geology No. 20. American Association of Petroleum Geologists, USA, 682p
Beaumont, E.A., Foster, N.H., 1988. Geochemistry, Treatise of Petroleum Geology, Reprint Series No. 8. American Association of
Petroleum Geologists, USA, 660p
Degens, E.T., 1989. Perspectives on Biogeochemistry. Springer-Verlag, Germany, 423p
Moldowan, R.M., Albrecht, P., Philp, R.P., 1992. Biological Markers in Sediments and Petroleum, Prentice-Hall, USA, 411p
Whelan, J.K., Farrington, J.W., 1992. Organic Matter: Productivity, Accumulation, and Preservation in Recent and Ancient Sediments.
Columbia University Press, USA, 533p
Engel, M.H., Macko, S.A., 1993. Organic Geochemistry – Principles and Applications. Plenum Press, USA, 861p

Table 3
Examples of Organic Geochemistry textbooks in which the content has been prepared by the listed textbook authors
Swain, F.G., 1970. Non-marine Organic Geochemistry. Cambridge University Press, UK, 445p
Tissot, B.F., Welte, D.H., 1978. Petroleum Formation and Occurrence. Springer-Verlag, Germany, 538p
Hunt, J.M., 1979. Petroleum Geochemistry and Geology. Freeman, USA, 617p
Waples, D., 1981. Organic Geochemistry for Exploration Geologists. Burgess, USA, 151p
Tissot, B.F., Welte, D.H., 1984. Petroleum Formation and Occurrence. second ed. Springer-Verlag, Germany, 699p
Philp, R.P., 1985. Fossil Fuel Biomarkers – Applications and Spectra. Elsevier, The Netherlands, 294p
Waples, D.W., 1985. Geochemistry in Petroleum Exploration. International Human Resources Development Corporation (IHRDC),
USA, 232p
Waples, E.W., Machihara, T., 1991. Biomarkers for Geologists – A Practical Guide to the Application of Steranes and Triterpanes in
Petroleum Geology, AAPG Methods in Exploration No. 9, American Association of Petroleum Geologists, USA, 91p
Killops, S.D., Killops V.J., 1993. An Introduction to Organic Geochemistry. Longman Group, UK, 265p
Peters, K.E., Moldowan, J.M., 1993. The Biomarker Guide – Interpreting Molecular Fossils in Petroleum and Ancient Sediments.
Prentice-Hall, USA, 363p
Hunt, J.M., 1996. Petroleum Geochemistry and Geology, second ed. Freeman, USA, 743p
Killops, S.D., Killops, V.J., 2005. Introduction to Organic Geochemistry, second ed., Blackwell, USA, 393p
Peters, K.E., Walters, C.C., Moldowan, J.M., 2005. The Biomarker Guide, second ed. Cambridge University Press, UK, 1155p

papers in organic geochemistry by many different in subject matter from general organic geochemistry
authors are listed in Table 2, and textbooks in which to specialties such as petroleum geochemistry and
the entire content was prepared by one to three the organic geochemistry of non-marine sediments,
authors are listed in Table 3. These textbooks range oil shales, and carbonate rocks.
8 K.A. Kvenvolden / Organic Geochemistry 37 (2006) 1–11

Table 4
Organic Geochemistry Division, Best Paper Award Winners
Award year Title Authors Source
Molecular Organic Geochemistry
1971 Nonprotein amino acids in the Murchison K. Kvenvolden, J. Lawless, C. Proceedings, National Academy
meteorite Ponnamperuma of Sciences (U.S.) 68 (2), 486–490
(1971)
1972 Proof of structure of steroid carboxylic acids in a W. Seifert, E. Gallegos, R. Teeter Journal American Chemical
California petroleum by deuterium labeling, Society 94, 5880–5887 (1972)
Synthesis and mass spectrometry
1974 Tri- and tetraterpenoid hydrocarbons in the B. Kimble, J. Maxwell, P. Philp, GCA 38, 1165–1181 (1974)
Messel shale G. Eglinton, P. Albrecht, A.
Ensminger, P. Arpino, G.
Ourisson
1975 Rearranged steranes in shale: occurrence and I. Rubinstein, D. Sieskind, P. Journal Chemical Society 1975,
simulated formation Albrecht 1833–1836 (1975)
1977 Diterpenoid compounds in other lipids in deep-sea B. Simoneit GCA 41, 463–476 (1977)
sediments and their geochemical significance
1987 Identification of aryl isoprenoids in source rocks R. Summons, T. Powell GCA 51, 557–566 (1987)
and crude oils: biological markers in the green
sulphur bacteria
1989 Quenching of labile functionalized lipids by J. Sinninghe Damsté, W. GCA 53, 1343–1355 (1989)
inorganic sulphur species: evidence for the Rijpstra, A. Kock-van Dalen, J.
formation or sedimentary organic sulphur de Leeuw, P. Schenck
compounds at the early stages of diagenesis
1998 Variability in radiocarbon ages of individual T. Eglinton, B. Benitez-Nelson, Science 277, 796–799 (1997)
compounds from marine sediments A. Pearson, A. McNichol, V.
Bauer, E. Druffel
Biogeochemistry
1977 Biogeochemistry of Mono Lake, California W. Reed GCA 41, 1231–1245 (1977)
1979 Sterol geochemistry of sediments from the western C. Lee, J. Farrington, R. GCA 43, 35–46 (1979)
North Atlantic Ocean and adjacent coastal areas Gagosian
1982 Volatile fatty acid cycling in organic-rich marine F. Sansone, C. Martens GCA 46, 1575–1589 (1982)
sediments
1986 Biogenic methane formation in marine and M. Whiticar, E. Faber, M. GCA 50, 693–709 (1986)
freshwater environments: CO2 reduction vs. Schoell
acetate fermentation – Isotope evidence
1989 The occurrence and identification of series of J. Sinninghe Damsté, W. GCA 53, 1323–1341 (1989)
organic sulphur compounds in oils and sediment Rijpstra, J. de Leeuw, P. Schenck
extracts: II. Their presence in samples from
hypersaline and non-hypersaline
palaeoenvironments and possible application as
source, palaeoenvironmental and maturity
indicators
1996 Dependence of phytoplankton carbon isotopic E. Laws, B. Popp, R. Bidigare, GCA 59, 1131–1138 (1995)
composition on growth rate and [CO2]aq: M. Kennicutt, S. Macko
theoretical considerations and experimental
results
1997 Reactivity of recently deposited organic matter: E. Canuel C. Martens GCA 60, 193–1806 (1996)
degradation of lipid compounds near the
sediment–water interface

Petroleum Geochemistry
1973 Bacterial degradation of crude oil: comparison of N. Bailey, A. Jobson, M. Rogers Chemical Geology 11, 203–221
field and experimental data (1973)
1973 Alteration of crude oil by waters and bacteria – N. Bailey, H. Krouse C. Evans American Association of
evidence from geochemical and isotope studies M. Rogers Petroleum Geologists Bulletin 57,
1276–1290 (1973)
1974 Origine et migration des hydrocarbures dans le B. Tissot, J. Espitalié, G. Deroo, In Advances in Organic
Sahara Oriental (Algérie) C. Tempere, D. Jonathan Geochemistry, 1973, Editions
Technip, France, 315–334 (1974)
K.A. Kvenvolden / Organic Geochemistry 37 (2006) 1–11 9

Table 4 (continued)
Award year Title Authors Source
1978 Applications of steranes, terpanes and W. Seifert, M. Moldowan GCA 42, 77–95 (1978)
monoaromatics to the maturation, migration and
source of crude oils
1980 Molecular parameters of maturation in the A. Mackenzie, R. Patience, GCA 44, 1709–1721 (1980)
Toarcian shales, Paris Basin, France – I. Changes J. Maxwell, M. Vandenbroucke,
in the configurations of acyclic isoprenoid alkanes, B. Durand
steranes and triterpanes
1983 Isomerization and aromatization of hydrocarbons A. Mackenzie, D. McKenzie Geology Magazine 120, 417–
in sedimentary basins formed by extension 470 (1983)
1990 Origin of Beatrice oil by co-sourcing from K. Peters, M. Moldowan, A. American Association of
Devonian and Middle Jurassic source rocks, Inner Driscole, G. Demaison Petroleum Geologists
Firth, United Kingdom Bulletin 73, 455–471 (1989)
1991 The origin of light hydrocarbons in petroleum: a F. Mango GCA 54, 1315–1323 (1990)
kinetic test of the steady-state catalytic hypothesis
1993 Extraction of whole versus ground source rocks: L. Price, J. Clayton GCA 56, 1213–1222 (1992)
fundamental petroleum geochemical implications
including oil-source rock correlations
1994 Hydrocarbon composition of authigenic D. Karlsen, T. Nedkvitne, S. GCA 57, 3641–3659 (1993)
inclusions: application to elucidation of petroleum Larter, K. Bjørlykke
reservoir filling history
Miscellaneous
1976 Land-derived organic matter in surface sediments J. Hedges P. Parker GCA 40, 1019–1029 (1976)
from the Gulf of Mexico
1976 Thermal alteration of young kerogen in relation to R. Ishiwatari, M. Ishiwatari, I. Nature 264, 347–349 (1976)
petroleum genesis Kaplan, B. Rohrback
1981 Thermal alteration of Cretaceous black shale by B. Simoneit, S. Brenner, K. GCA 45, 1581–1602 (1981)
diabase intrusions in the eastern Atlantic – II. Peters, I. Kaplan
Effects on bitumen and kerogen
1984 Thermal reactions of kerogen with added water, T. Hoering Organic Geochemistry 5,
heavy water and pure organic substances 267–278 (1984)
1985 Evaluation of petroleum generation by hydrous M. Lewan Philosophical Transactions,
pyrolysis experimentation Royal Society, London,
Series A, 315, 123–134 (1985)
1992 Chemical evidence of kerogen formation in source S. Derenne, C. Largeau, E. GCA 55, 1041–1050 (1991)
rocks and oil shales via selective preservation of Casadevall, C. Berkaloff, B.
thin resistant outer walls of microalgae: origin of Rousseau
ultralaminae
1995 Evidence for metastable equilibrium between J. Seewald Nature 370, 285–287 (1994)
hydrocarbons under hydrothermal conditions

6. Content Papers in Organic Geochemistry. To date, 32 Best


Paper Awards and 4 Best Student Paper Awards
Organic geochemistry is highly interdisciplinary, have been presented. Best Papers were first selected
as outlined above in the Aims and Scope of its jour- starting in 1971 and have been identified every year
nal Organic Geochemistry. An understanding of the (except 1988) thereafter until 1998. The 32 Best Pa-
breadth and depth of the subject matter can be pers have been organized here under four categories
gained by perusing the numerous papers within each (Table 4), although some papers could fit under
volume (Table 1) published for the twenty-one more than one category: Molecular Organic Geo-
IMOG conferences that have been held since 1962. chemistry (8 papers); Biogeochemistry (7 papers);
Also the textbooks in Tables 2 and 3 contain a vari- Petroleum Geochemistry (10 papers); and Miscella-
ety of papers on subjects dealing with the multiple neous (7 papers). Nineteen of these papers were pub-
aspects of organic geochemistry. lished in Geochimica et Cosmochimica Acta (GCA,
Another way to judge the content of this field is 1974–1986).
to review the published papers that have been se- The papers classified under Molecular Organic
lected by committee as Best Papers and Best Student Geochemistry deal with the discovery and
10 K.A. Kvenvolden / Organic Geochemistry 37 (2006) 1–11

Table 5
Organic Geochemistry Division, Best Student Paper Award Winners
Award year Title Authors Source
1994 Laboratory studies of oxic and anoxic M-Y. Sun, C. Lee, R. Aller GCA 57, 147–157 (1993)
degradation of chlorophyll-a in Long Island
sediments
1995 The geochemical evolution of low-molecular- L. Cozzarelli, M. Baedecker, GCA 58, 863–877 (1994)
weight organic acids derived from the degradation R. Eganhouse, D. Goerlitz
of petroleum contaminants in groundwater
1996 A novel triterpenoid carbon skeleton in immature S. Schouten GCA 59, 953–958 (1995)
sulfur-rich sediments
1998 Hydrolysis of peptides in seawater and sediment S. Pantoja Marine Chemistry 57,
25–40 (1997)

structural determination of several classes of or- Environmental Science and Technology, [notably the
ganic molecules found in geological materials. Best Papers (Table 4) and the Best Student Papers
These molecules include di-, tri-, and tetraterpe- (Table 5)], and general journals, such as Science
noid hydrocarbons, aryl isoprenoid hydrocarbons, and Nature, attest to the rich content of the field
steranes, carboxylic and amino acids, and sulfur- of organic geochemistry.
containing lipids. In addition, the radiocarbon
ages of individual organic compounds have been 7. Summary
measured. Biogeochemistry papers are concerned
mainly with organic geochemical processes medi- In 70 years, organic geochemistry, an amalgama-
ated by organisms. For example, papers address tion of aspects of organic chemistry and geology,
the biogeochemistry of lacustrine and marine sedi- has become a mature and widely recognized geosci-
ments, lipid cycling, microbial generation of meth- ence. The beginnings can be traced back to the early
ane, including the use of carbon and hydrogen part of the 20th century when Alfred E. Treibs, an
isotopes, and palaeoenvironmental implications of organic chemist, turned his attention to geological
organic sulfur compounds. The category Petroleum materials and discovered the presence of significant
Geochemistry has papers on both bacterial and organic molecules in shale, coal, and crude oil. Not
thermal processes as applied to petroleum occur- only did he find complex organic molecules but, per-
rence, including studies of isomerization and aro- haps more important, he traced the source of these
matization of petroleum molecules during basin molecules to their biological precursors. For his
development. Organic molecules such as steranes, visionary and pioneering work, he is generally re-
terpanes, and monoaromatic and isoprenoid garded as the ‘‘father’’ of organic geochemistry.
hydrocarbons are used in the identification of Formal recognition of organic geochemistry came
petroleum source rocks, in oil-rock correlations, about in 1959, when an organization was estab-
in assessment of organic matter maturity, and in lished to promote organic geochemical research,
understanding the origin and migration of petro- and conferences focusing on organic geochemical
leum. Papers in the Miscellaneous category treat topics have been convened and have met regularly
the geochemistry of bulk organic carbon (kerogen) since 1962. Because of the proliferation of scientific
and include thermal alteration experiments. The papers on organic geochemistry, a need was identi-
four Best Student Papers were identified for the fied for a journal, and Organic Geochemistry was
years 1994–1998, and they also reflect some of founded in 1977. Outstanding contributions to the
the content of organic geochemistry (Table 5). subject have been acknowledged with the presenta-
Thus, the numerous publications in the IMOG tion of various awards starting two years after the
conference proceedings (Table 1), in organic geo- journal was founded. Organic geochemistry is a
chemical textbooks (Tables 2 and 3), in GCA, Or- highly interdisciplinary field, comprising fundamen-
ganic Geochemistry, specialty journals, such as tal and applied research, and it is now an important
Chemical Geology, Applied Geochemistry, Marine component of many studies in geology and in other
Chemistry, Marine and Petroleum Geology, Bulletin fields such as oceanography, hydrology, archaeol-
of the American Association of Petroleum Geologists, ogy, and cosmochemistry.
K.A. Kvenvolden / Organic Geochemistry 37 (2006) 1–11 11

Acknowledgements Kvenvolden, K.A., 2002. History of the recognition of organic


geochemistry in geoscience. Organic Geochemistry 33, 517–521.
McIntyre, D.B., 1963. James Hutton and the philosophy of
Many thanks go to B.R.T Simoneit for providing geology. In: Albritton, C.C. (Ed.), The Fabric of Geology.
encouragement for the preparation of this paper Addison-Wesley, Reading, MA, pp. 1–11.
and for valuable information on A.E. Treibs from Noller, C.R., 1957. Chemistry of Organic Compounds. W.B.
the comprehensive ‘‘Alfred Treibs Memorial Vol- Saunders, Philadelphia, PA, pp. 1–4.
ume’’, which unfortunately has had very limited dis- Prashnowsky, A.A., 1980. The Impact of the Treibs! Porphyrin
Concept on the Modern Organic Geochemistry. HALBIGd-
tribution. Thanks also go to B.W. Rogers, who ruck, Wirtzburg, Germany, 358p.
prepared the figures for this paper. Critical reviews Prashnowsky, A.A., 2002. Alfred Treibs Memorial Volume.
by Joe Curiale and James Maxwell are gratefully HALBIGdruck, Wirtzburg, Germany, 631p.
acknowledged. Seifert, W.K., 1977. Alfred Treibs. In: In Campos, R., Goñi, J.
(Eds.), Advances in Organic Geochemistry, 1975. ENAD-
IMSA, Madrid, Spain, pp. vii–viii.
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Gilluly, J., 1963. Memorial to Parker Davies Trask. Geological Treibs, A.E., 1936. Chlorophyll- und Häminderivate in organis-
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