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Expert Answer
Study... Experiment...

Aditya answered this 8th Edition 11th Edition


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1,027 answers

Hi
We can consider the given deactivation of pores in the following manner

P --BP
Here P is pore and BP is the blocked pore.
Unit...
We can see in that part 1 that the unit of the decay constant is given as S^-1 . 7th Edition

View all solutions


We know that for a nth order reaction the unit of the rate constant is given by
(S^-1)*M^(1-n)
Since, the molarity term is not appearing, we can say that n=1 .

So the rate of disappearance of Pores Top Chegg tutors who can


-dp/dt = K*P
Here P is the concentration of P at any time
help right now
-dp/P = kdt
Integrating between time t=t1 , P1 and time =t2 and pressure P2 gives Omar M.
61
ln(P2/P1) = -K(t2-t1) equation 1 University of Pennsy…
We can take any two data points and then substitute the values in the above equation.
Erin S.
For simplicity I am taking rst two data points Yale University
1

P2 = 4.23*10^9 /m3
P1 =8.5*10^10 /me Lorenzo L.
4
t1 = 0 S Columbia University
t2 = 300 S

ln(0.423/8.5)=-k*300 Find me a tutor


K= 0.01 S^-1 .

Part b and C

At t=40 minutes we can use the equation 1 with the following values.

P2=unknown
P1 =8.5*10^10 /m^3
t1=0
t2 = 40*60=2400 S

ln(P2/8.5*10^10)= - 0.01*2400=24
P2=3.20/m^3

Inactivation factor is nothing but the fraction of pores inactivated.

This can be written as = 1 - fraction of pores survived


= 1-3.2/8.5*10^10
= 1 (approximately)

Survival factor =fraction of pores that survived


=3.2/8.5*10^10
=3.77*10^-11

Hope this helps


Feel free to comment in the case of any doubt.
Thank you

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