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Student Name:

#12 Potential Energy Diagram


1. Based on the following reaction profile:

B
D
A

Reaction Coordinate

a. How many steps are in the reaction going from A to D?

b. How many transition states are there?

c. Which step is the slowest?

d. Which step is the fastest?

e. Identify the following as exothermic or endothermic.

A B B C C D

A C A D B D
2. A key organic reaction is

C3H7Br + NaNH2 C3H6 + NH3 + NaBr

The reaction occurs by a single step mechanism and is exothermic overall. Draw a
potential energy diagram for this reaction. Be sure to include all necessary identities such
as Ea, H, TS, reactants, products, etc.

3. Consider the three step mechanism for a reaction is proposed for the synthesis of
formaldehyde:
Step 1 H2 2H fast endothermic
Step 2 H + CO HCO slow, endothermic
Step 3 H + HCO H2CO fast, exothermic

The reaction is overall exothermic.


a. What is the overall reaction?

Draw a potential energy diagram for this reaction. Be sure to include all necessary
identities such as Ea, H, TS, reactants, products, etc.

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