SCES3123 Organic Chemistry

SCES3123: W1 - Tutorial 1

1. Give the IUPAC names of the following alkyl halides:

CH3

(a) CH3CH2CH2CH2I (b) CH3CHCH2CH2Cl

Iodobutane 4-chloro-2-methylbutane

CH3 CH3

(c)BrCH2CH2CH2CCH2Br (d) CH3 CCH2CH2Cl

CH3 Cl
1,5-dibromo-2,2-dimethylpentane 2,4-dichloro-2-methylbutane

I CH2CH2Cl Br Cl

(e) CH3 CHCHCH2CH3 (f)CH3CHCH2CH2CHCH3

2-bromo-5-chlorohexane
1-chloro-4-iodoethylpentane

2. Draw structures corresponding to the following IUPAC names:

(a) 2-Chloro-3,3-dimethylhexane

Cl CH3
I I
CH3CHCCH2CH2CH3
I
CH3

(b)3,3-Dichloro-2-methylhexane

CH3 Cl
I I
CH3CHCCH2CH2CH3
I
Cl

(c) 3-Bromo-3-ethylpentane

CH3CH2CH2CH2CH3

(d) 1,1-Dibromo-4-isopropylcyclohexane

(e) 4-sec-Butyl-2-chlorononane(f)1,1-Dibromo-4-tert-butylcyclohexane
SCES3123: W1 - Tutorial 2

Elaborate how would you prepare 2-Chloropropane from the appropriate (a)
alcohol or (b) alkene

IPGKTI/TCS/SCES3123/W1T1&2