Hydrateinfo With TEG

Spreadsheet for calculating hydrate dissociation
In general:
Cells with text or numbers in red can be changed by the user.
TIPS
The spreadsheet can be set for automatic recalculation of all worksheets using Tools\Options\Calculation\Automatic
However, this can be slow. Setting Tools\Options\Calculation to manual allows user to determine which worksheets are recalc
F9 updates all
Shift F9 only updates the current worksheet
To see effect of fluids giving different hydrate structures copy and paste the following into the hydrocarbon composition in "Co
TEST compositions
Hydrate2 Hydrate1 Mixed
2.1202 0 2.1202
0.65007 0 0.65007
92.369 100 2000
3.4103 0 3.4103
0.86009 0 0.86009
0.14001 0 0.14001
0.21002 0 0.21002
7.00E-02 0 7.00E-02
6.00E-02 0 6.00E-02
0 0 0
0 0 0
0 0 0
0 0 0
0.11001 0 0.11001
10 10 10
ation\Automatic
hich worksheets are recalculated
arbon composition in "Composition" worksheet

Hydrate calculations with no inhibitor present
remove all; puredata infodata ;
bipdata OILANDGAS4 ;
bipset RKSABIP3 3 linear ;
model MRKSANRTL RKSA PSAT LDEN NRTL RKSABIP3;
model MDH LRELECTROLYTE DH BORN VIRIAL;
model MTEST LREPHCHECK;
model MADDMRKSANRTLMDH ADD ZANAL MTEST MRKSANRTL MDH;
model MPDVISC PDVISC LFIT;
model MCLSMRKSANRTL CLS MRKSANRTL;
model MMCSMRKSANRTL MCS MRKSANRTL;
model MHYD1MRKSANRTL HYDRATE I MRKSANRTL;
model MHYD2MRKSANRTL HYDRATE II MRKSANRTL;
model MICEMRKSANRTL FREEZEOUT WATER MRKSANRTL;
pd GAS gas MADDMRKSANRTLMDH MADDMRKSANRTLMDH MADDMRKSANRTLMDH MPDVISC
MCLSMRKSANRTL;
pd LIQUID1 liquid MADDMRKSANRTLMDH MADDMRKSANRTLMDH MADDMRKSANRTLMDH MPDVISC
MCLSMRKSANRTL MMCSMRKSANRTL;
key LIQUID1 not WATER;
pd WATER liquid MADDMRKSANRTLMDH MADDMRKSANRTLMDH MADDMRKSANRTLMDH MPDVISC
key WATER WATER;
pd HYDRATE1 hydrate MHYD1MRKSANRTL;
pd ICE condensed MICEMRKSANRTL;
units
temp
DegC
press
Bar
;
components nitrogen CO2 methane ethane propane isobutane butane isopentane pentane
hexane heptane octane nonane;
petrofracs PF data cnumber
7
;;
components water Na+ Cl- K+ Ca++;
Salt model Electrolyte
Fluid composition Hydrate dissociation temperature for given pressu

Moles Hydrate2
1 #ADDIN? 2.1202 Pressure #ADDIN? 90
2 #ADDIN? 0.65007 Temperature #ADDIN? #ADDIN?
3 #ADDIN? 92.369
4 #ADDIN? 3.4103 If result is # followed by text then that hydrate structure is not present
5 #ADDIN? 0.86009 Hydrate dissociation pressure for given temperatu
6 #ADDIN? 0.14001 Hydrate2
7 #ADDIN? 0.21002 Pressure #ADDIN? #ADDIN?
8 #ADDIN? 0.070007 Temperature #ADDIN? 4
9 #ADDIN? 0.060006
10 #ADDIN? 0 If result is # followed by text then that hydrate structure is not present
11 #ADDIN? 0
12 #ADDIN? 0 Amount of hydrate formed at given conditions
13 #ADDIN? 0 Hydrate2
14 #ADDIN? 0.11001 #ADDIN?
15 #ADDIN? 10 Temperature #ADDIN? 1 #ADDIN?
16 #ADDIN? #ADDIN? Pressure #ADDIN? 40
17 #ADDIN? #ADDIN?
18 #ADDIN? #ADDIN?
19 #ADDIN? #ADDIN?
Total #ADDIN?
Hydrate Curve
Calculation of dissociation temperature as a function of pressure Plot Specification
Pressure Hydrate2 Hydrate1 Starting pressure 1
#ADDIN? #ADDIN? #ADDIN? Step 20
1 #ADDIN? #ADDIN?
21 #ADDIN? #ADDIN?
41 #ADDIN? #ADDIN?
Hydrate dissociation
61 #ADDIN? #ADDIN?
no inhibition
81 #ADDIN? #ADDIN?
500
101 #ADDIN? #ADDIN?
Pressure bar
121 #ADDIN? #ADDIN? 450

Hydr
141 #ADDIN? #ADDIN? ate2
400
161 #ADDIN? #ADDIN?
201 #ADDIN? #ADDIN?
300
221 #ADDIN? #ADDIN?
281 #ADDIN? #ADDIN?
341 #ADDIN? #ADDIN?
50
361 #ADDIN? #ADDIN?
401 #ADDIN? #ADDIN? 0 5 10 15 20
421 #ADDIN? #ADDIN? Temperature degC
441 #ADDIN? #ADDIN?
If result is # followed by text then that hydrate structure is not present

MDH MPDVISC
MDH MPDVISC
MDH MPDVISC
rature for given pressure

Hydrate1
#ADDIN?
e structure is not present

ure for given temperature
Hydrate1
#ADDIN?
at given conditions
Hydrate1
#ADDIN?
#ADDIN?
PLOT
#ADDIN? Hydrate2 Hydrate1
#ADDIN? #ADDIN?
#N/A #N/A
#N/A #N/A
#N/A #N/A
ciation
#N/A #N/A
#N/A #N/A
#N/A #N/A
#N/A #N/A
#N/A #N/A
#N/A #N/A
#N/A #N/A
#N/A #N/A
#N/A #N/A
#N/A #N/A
#N/A #N/A
#N/A #N/A
#N/A #N/A
#N/A #N/A
#N/A #N/A
#N/A #N/A
#N/A #N/A
15 20 25 #N/A #N/A
egC #N/A #N/A
#N/A #N/A
Hydrate calculations with methanol present
MCLSMRKSANRTL;
key WATER WATER;
units
temp
DegC
press
Bar
;
7
;;
Components methanol;
Fluid composition Concentration of methanol in aqueous stream

moles Methanol MW #ADDIN?
1 #ADDIN? 2.12020000 Methanol 15 wt% #ADDIN?
2 #ADDIN? 0.65007000
3 #ADDIN? 92.36900000 Hydrate dissociation temperature for a given pr
8 #ADDIN? 0.07000700 Hydrate dissociation pressure for given temper
10 #ADDIN? 0.00000000 Pressure #ADDIN? #ADDIN?
11 #ADDIN? 0.00000000 Temperature #ADDIN? 5
13 #ADDIN? 0.00000000 Amount of hydrate formed at given conditions
15 #ADDIN? 10.00000000 mol
16 #ADDIN? #ADDIN? Temperature DegC 0 #ADDIN?
17 #ADDIN? #ADDIN? Pressure Bar 80
18 #ADDIN? #ADDIN?
19 #ADDIN? #ADDIN?
20 #ADDIN? #ADDIN?
Total #ADDIN?
Hydrate Curve
Hydrate dissociation temperature calculated as a function of pressure
No MeoH MeOH No MeOH MeOH

Pressure Hydrate2 Hydrate2 Hydrate1 Hydrate1
#ADDIN? #ADDIN? #ADDIN? #ADDIN? #ADDIN?
1 #N/A #ADDIN? #N/A #ADDIN? Hydrate dis
21 #N/A #ADDIN? #N/A #ADDIN? with methan
41 #N/A #ADDIN? #N/A #ADDIN? 500
Pressure Bar
61 #N/A #ADDIN? #N/A #ADDIN?
101 #N/A #ADDIN? #N/A #ADDIN? Hydrate2
121 #N/A #ADDIN? #N/A #ADDIN? 400 Hydrate2 with
350
Hydrate1 with
150
421 #N/A #ADDIN? #N/A #ADDIN? -50 -40 -30 -20
441 #N/A #ADDIN? #N/A #ADDIN? Temperatu
in aqueous stream
mol%
rature for a given pressure

Hydrate1
#ADDIN?
Hydrate1
#ADDIN?

at given conditions
Hydrate1
mol
#ADDIN?
with methanol
Hydrate2
Hydrate2 with MeOH
Hydrate1
Hydrate1 with MeOH
-30 -20 -10 0 10 20 30

Temperature DegC
Hydrate calculations to determine the amount of methanol required to suppress h
MCLSMRKSANRTL;
key WATER WATER;
units
temp
DegC
press
Bar
;
7
;;
components methanol;
salt model Electrolyte

Input stream
mol% Tol feed Hydrate2 suppression
1 #ADDIN? 2.1202 0 2.1202
2 #ADDIN? 0.65007 0 0.65007
3 #ADDIN? 92.369 0 92.369
4 #ADDIN? 3.4103 0 3.4103
5 #ADDIN? 0.86009 0 0.86009
6 #ADDIN? 0.14001 0 0.14001
7 #ADDIN? 0.21002 0 0.21002
8 #ADDIN? 0.070007 0 0.070007
9 #ADDIN? 0.060006 0 0.060006
10 #ADDIN? 0 0 0
11 #ADDIN? 0 0 0
12 #ADDIN? 0 0 0
13 #ADDIN? 0 0 0
14 #ADDIN? 0.11001 0 0.11001
15 #ADDIN? 10 0 10
16 #ADDIN? #ADDIN? 0 #ADDIN?
20 #ADDIN? 0 1 #ADDIN?
Hydrate Curve
hydrate dissociation temperature as a function of pressure with sufficient methanol to suppress hydrate formation at given
CALC CALC
No MeoH MeOH No MeOH MeOH
21 #N/A #ADDIN? #N/A #ADDIN? Hydrate dissociation
41 #N/A #ADDIN? #N/A #ADDIN? with methanol inhibition fo
500
101 #N/A #ADDIN? #N/A #ADDIN? 450 Hydrate2
121 #N/A #ADDIN? #N/A #ADDIN? Hydrate2 with
Press/bar
141 #N/A #ADDIN? #N/A #ADDIN? 400 MeOH

201 #N/A #ADDIN? #N/A #ADDIN? MeOH
300
100
441 #N/A #ADDIN? #N/A #ADDIN? -50 -40 -30 -20 -10
Temp/Deg
quired to suppress hydrates at given conditions
MDH MPDVISC
MDH MPDVISC
MDH MPDVISC
Input stream MW methanol #ADDIN?

Hydrate1 suppression Amount of methanol to suppress hydrate2 Amount of methanol to su
2.1202
0.65007 Conditions Conditions
92.369 Temperature DegC 5 Temperatu
3.4103 Pressure Bar 80 Pressure
0.86009
0.14001 Methanol mole #ADDIN? to total stream Methanol
0.21002
0.070007 Methanol to be added in relation to water Methanol to be added in r
0.060006 (Mass MeOH/Mass H20+Mass MeOH)*100 (Mass MeOH/Mass H20+M
0 #ADDIN? wt% #ADDIN?
0
0 If the result of calculating the amount of methanol to suppress a hydrate is #NULL
0 this indicates that particular hydrate structure is not formed
0.11001
10
#ADDIN?
#ADDIN?
#ADDIN?
#ADDIN?
#ADDIN?
ess hydrate formation at given conditions
ydrate dissociation
th methanol inhibition for set conditions
Hydrate2
Hydrate2 with
MeOH
Hydrate1
Hydrate1 with
MeOH
-30 -20 -10 0 10 20 30

Temp/DegC
Amount of methanol to suppress hydrate1
Conditions
DegC 12
Bar 90
mole #ADDIN? to total stream
Methanol to be added in relation to water

(Mass MeOH/Mass H20+Mass MeOH)*100
wt%
Hydrate calculations with MEG present
MCLSMRKSANRTL;
key WATER WATER;
units
temp
DegC
press
Bar
;
7
;;
Components MEG;
Fluid composition Concentration of MEG in aqueous stream

moles MEG MW #ADDIN?
1 #ADDIN? 2.1202 MEG 25 wt% #ADDIN?
2 #ADDIN? 0.65007
3 #ADDIN? 92.369 Hydrate dissociation temperature for a given press
8 #ADDIN? 0.070007 Hydrate dissociation pressure for given temperatu
10 #ADDIN? 0 Pressure #ADDIN? #ADDIN?
11 #ADDIN? 0 Temperature #ADDIN? 10
12 #ADDIN? 0 If result is # followed by text then that hydrate structure is not present
13 #ADDIN? 0 Amount of hydrate formed at given conditions
15 #ADDIN? 10 mol
16 #ADDIN? #ADDIN? Temperature DegC -5 #ADDIN?
17 #ADDIN? #ADDIN? Pressure Bar 80
18 #ADDIN? #ADDIN?
19 #ADDIN? #ADDIN?
20 #ADDIN? #ADDIN?
Hydrate Curve
Hydrate dissociation temperature calculated as a function of pressure
No MEG MEG No MEG MEG

#ADDIN? #ADDIN? #ADDIN? #ADDIN? #ADDIN? Hydrate dissocia
1 #N/A #ADDIN? #N/A #ADDIN? with MEG
500
41 #N/A #ADDIN? #N/A #ADDIN? Pressure Bar
101 #N/A #ADDIN? #N/A #ADDIN? 400 Hydrate2 with MeOH
350 Hydrate1
161 #N/A #ADDIN? #N/A #ADDIN? Hydrate1 with MeOH
300
100
401 #N/A #ADDIN? #N/A #ADDIN? -50 -40 -30 -20 -10
421 #N/A #ADDIN? #N/A #ADDIN? Temperature De
MDH MPDVISC
MDH MPDVISC
MDH MPDVISC
ueous stream
mol%
rature for a given pressure

Hydrate1
#ADDIN?
Hydrate1
#ADDIN?

at given conditions
Hydrate1
mol
#ADDIN?
with MEG
Hydrate2
Hydrate2 with MeOH
Hydrate1
Hydrate1 with MeOH
-30 -20 -10 0 10 20 30

Temperature DegC
Hydrate calculations to determine the amount of MEG required to suppress hydra
MCLSMRKSANRTL;
key WATER WATER;
units
temp
DegC
press
Bar
;
7
;;
components MEG;

Input stream
1 #ADDIN? 2.1202 0 2.1202
2 #ADDIN? 0.65007 0 0.65007
3 #ADDIN? 92.369 0 92.369
4 #ADDIN? 3.4103 0 3.4103
5 #ADDIN? 0.86009 0 0.86009
6 #ADDIN? 0.14001 0 0.14001
7 #ADDIN? 0.21002 0 0.21002
8 #ADDIN? 0.070007 0 0.070007
9 #ADDIN? 0.060006 0 0.060006
10 #ADDIN? 0 0 0
11 #ADDIN? 0 0 0
12 #ADDIN? 0 0 0
13 #ADDIN? 0 0 0
14 #ADDIN? 0.11001 0 0.11001
15 #ADDIN? 10 0 10
Hydrate Curve
hydrate dissociation temperature as a function of pressure with sufficient MEG to suppress hydrate formation at given cond
CALC CALC
No MEG MEG No MEG MEG
with MEG inhibition fo
450 Hydrate2
Press/bar Hydrate2 with
400
Hydrate1
200
0
401 #N/A #ADDIN? #N/A #ADDIN? -50 -40 -30 -20 -1
421 #N/A #ADDIN? #N/A #ADDIN? Temp/D

ed to suppress hydrates at given conditions
MDH MPDVISC
MDH MPDVISC
MDH MPDVISC
Input stream MW MEG #ADDIN?

Hydrate1 suppression Amount of MEG to suppress hydrate2 Amount of MEG to suppre
2.1202
0.86009
0.14001 MEG mole #ADDIN? to total stream MEG
0.21002
0.070007 MEG to be added in relation to water MEG to be added in relati
0.060006 (Mass MEG/Mass H20+Mass MEG)*100 (Mass MEG/Mass H20+Ma
0 #ADDIN? % #ADDIN?
0
0 If the result of calculating the amount of MEG to suppress a hydrate is #NULL
0.11001
10
#ADDIN?
#ADDIN?
#ADDIN?
#ADDIN?
#ADDIN?
hydrate formation at given conditions
with MEG inhibition for set conditions
Hydrate2
Hydrate2 with
MeOH
Hydrate1
Hydrate1 with
MeOH
-30 -20 -10 0 10 20 30

Temp/DegC
Amount of MEG to suppress hydrate1
Conditions
DegC 12
Bar 90
MEG to be added in relation to water

(Mass MEG/Mass H20+Mass MEG)*100
%
Hydrate calculations to determine the amount of TEG required to suppress hydra
MCLSMRKSANRTL;
key WATER WATER;
units
temp
DegC
press
Bar
;
7
;;
components TEG;

Input stream
1 #ADDIN? 2.1202 0 2.1202
2 #ADDIN? 0.65007 0 0.65007
3 #ADDIN? 92.369 0 92.369
4 #ADDIN? 3.4103 0 3.4103
5 #ADDIN? 0.86009 0 0.86009
6 #ADDIN? 0.14001 0 0.14001
7 #ADDIN? 0.21002 0 0.21002
8 #ADDIN? 0.070007 0 0.070007
9 #ADDIN? 0.060006 0 0.060006
10 #ADDIN? 0 0 0
11 #ADDIN? 0 0 0
12 #ADDIN? 0 0 0
13 #ADDIN? 0 0 0
14 #ADDIN? 0.11001 0 0.11001
15 #ADDIN? 10 0 10
Hydrate Curve
hydrate dissociation temperature as a function of pressure with sufficient TEG to suppress hydrate formation at given cond
CALC CALC
No TEG TEG No TEG TEG
with TEG inhibition fo
450 Hydrate2
Press/bar Hydrate2 with
81 #N/A #ADDIN? #N/A #ADDIN? TEG
400
Hydrate1
141 #N/A #ADDIN? #N/A #ADDIN? TEG
200
0
401 #N/A #ADDIN? #N/A #ADDIN? -50 -40 -30 -20 -1
421 #N/A #ADDIN? #N/A #ADDIN? Temp/D

d to suppress hydrates at given conditions
MDH MPDVISC
MDH MPDVISC
MDH MPDVISC
Input stream MW TEG #ADDIN?

Hydrate1 suppression Amount of TEG to suppress hydrate2 Amount of TEG to suppre
2.1202
0.86009
0.14001 TEG mole #ADDIN? to total stream TEG
0.21002
0.070007 TEG to be added in relation to water TEG to be added in relatio
0.060006 (Mass TEG/Mass H20+Mass TEG)*100 (Mass TEG/Mass H20+Ma
0 #ADDIN? % #ADDIN?
0
0 If the result of calculating the amount of TEG to suppress a hydrate is #NULL
0.11001
10
#ADDIN?
#ADDIN?
#ADDIN?
#ADDIN?
#ADDIN?
ydrate formation at given conditions
with TEG inhibition for set conditions
Hydrate2
Hydrate2 with
TEG
Hydrate1
Hydrate1 with
TEG
-30 -20 -10 0 10 20 30

Temp/DegC
Amount of TEG to suppress hydrate1
Conditions
DegC 12
Bar 90
TEG to be added in relation to water

(Mass TEG/Mass H20+Mass TEG)*100
%

Hydrateinfo With TEG

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Hydrateinfo With TEG

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Spreadsheet for calculating hydrate dissociation

arbon composition in "Composition" worksheet

Salt model Electrolyte

Fluid composition Hydrate dissociation temperature for given pressu

121 #ADDIN? #ADDIN? 450

If result is # followed by text then that hydrate structure is not present

rature for given pressure

e structure is not present

Salt model Electrolyte

Fluid composition Concentration of methanol in aqueous stream

No MeoH MeOH No MeOH MeOH

rature for a given pressure

e structure is not present

-30 -20 -10 0 10 20 30

salt model Electrolyte

141 #N/A #ADDIN? #N/A #ADDIN? 400 MeOH

Input stream MW methanol #ADDIN?

ess hydrate formation at given conditions

-30 -20 -10 0 10 20 30

mole #ADDIN? to total stream

Methanol to be added in relation to water

Salt model Electrolyte

Fluid composition Concentration of MEG in aqueous stream

No MEG MEG No MEG MEG

rature for a given pressure

e structure is not present

-30 -20 -10 0 10 20 30

Salt model Electrolyte

If result is # followed by text then that hydrate structure is not present

Input stream MW MEG #ADDIN?

hydrate formation at given conditions

-30 -20 -10 0 10 20 30

mole #ADDIN? to total stream

MEG to be added in relation to water

Salt model Electrolyte

If result is # followed by text then that hydrate structure is not present

Input stream MW TEG #ADDIN?

ydrate formation at given conditions

-30 -20 -10 0 10 20 30

mole #ADDIN? to total stream

TEG to be added in relation to water

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