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Article history: The analysis of the process of frost formation on a cold surface exposed to humid air yields a system of
Received 17 November 2018 differential equations. In this study, the orthogonal collocation method is used to help solve the system of
Received in revised form 1 January 2019 equations resulting from the flow of humid air over heat exchanger fins maintained at a temperature
Accepted 2 February 2019
below both the dew-point temperature of water vapor in air and the freezing point. The temporal
dependence of the frost growth creates a moving boundary that is addressed using a front-fixing method.
This proposed method allows solving for important variables such as frost thickness, temperature
Keywords:
distribution, and heat flux through the frost layer. Model results were found to agree closely with
Frost formation
Rectangular fin
available experimental data. In all data sets modeled, it was found that super saturation at the
Annular fin frost-air interface must be included in the model to accurately predict frost growth.
Moving boundary Ó 2019 Elsevier Ltd. All rights reserved.
Orthogonal collocation
Heat transfer
Mass transfer
Super saturation
1. Introduction investigate, due to the unstable and brittle nature of the deposited
frost [24].
Frost formation on cold surfaces in heat exchanger and refriger- Chen et al. [5,6] studied frost formation on rectangular fins,
ation applications has considerable practical relevance. The frost experimentally and analytically. They developed a test facility to
layer acts as a thermal insulator between the cooling surface and characterize frost growth on heat exchanger fins where the cold
the air, decreasing the efficiency of the cooling process. It also surfaces and the air supply conditions were similar to those expe-
reduces the size of the air channels, therefore increasing the gener- rienced in freezers. This facility included a test section with remov-
ated pressure drop This was reported by many researchers such as able fins to measure the frost height and mass concentration. They
Emery and Siegel [11] who found a 50–75% decrease in heat trans- presented results for typical operating conditions with frost
fer and a substantial increase in pressure drop on the surface of a growth on fins. They presented data for frost height on fins,
compact heat exchanger. Results obtained by Chen et al. [6] and increase in pressure loss, frost mass accumulation, and heat trans-
Su [31] show a comparable trend. Therefore, an accurate and fer rate. Kim et al. [20] proposed a mathematical model for predict-
robust analysis of the frost formation process is essential to ing frost behavior on a heat exchanger fin under frosting
characterize the aforementioned problems. conditions, considering fin heat conduction. Their model reflected
Analyzing the structure and properties of a frost layer is chal- the change in the three-dimensional airside flow caused by frost
lenging to do. The frost formation process is three-dimensional, growth. Kim et al. [18] conducted frosting experiments to analyze
non-linear, transient, and involves coupled heat and mass transfer the characteristics of frost formation on a two-dimensional fin
with a moving boundary. The structure within the frost varies with a non-uniform temperature distribution. The temperature
continuously [21], and as recently as 2015, a detailed physical distribution and the characteristics of frost formation were ana-
description of the unsteady frost formation process was not clear lyzed perpendicular and parallel to the airflow for different values
[19]. In terms of experimental data acquired, it is also difficult to of fin thickness and other frosting parameters.
Lenic et al. [25] developed a PDE-based model to describe tran-
sient two-dimensional frost formation on a fin-and-tube heat
⇑ Corresponding author.
exchanger. The governing equations were discretized using the
E-mail addresses: teresa.benitez@upr.edu (T. Benítez), sasherif@ufl.edu
(S.A. Sherif), jaime.benitez@ufl.edu (J. Benítez). control volume method. The convection-diffusion terms were
https://doi.org/10.1016/j.ijheatmasstransfer.2019.02.005
0017-9310/Ó 2019 Elsevier Ltd. All rights reserved.
100 T. Benítez et al. / International Journal of Heat and Mass Transfer 136 (2019) 99–115
Nomenclature
treated using a power-law scheme. An iterative procedure was This paper uses a methodology, first suggested by Benítez and
used to solve the resulting set of linearized discretization equa- Sherif [3] with regards to frost formation on a flat plate, to approx-
tions. Lee et al. [23] provided experimental data to be used to pre- imate the solution to the system of PDEs that describe the frost for-
dict frost growth and frost performance of a round plate fin-tube mation process on heat exchanger fins. First, the front-fixing
heat exchanger for low temperature heat pumps used in zero emis- method [8] is used to determine a suitable set of new coordinates
sion vehicles under cold weather conditions. Round plate fin-tube that deal with the moving boundary. Then, with the orthogonal
heat exchangers were tested with variation of the fin space, airflow collocation method [1,4,10,29,33] the transformed system of dif-
rate, relative humidity, and inlet air temperature. Frost height was ferential equations is converted to an initial value problem. The
measured. The variation of the blockage ratio with fin space was solution to this problem is carried out using an ODE solver from
determined to be an important parameter when designing MATLAB. The results obtained from the model are compared to
advanced heat exchangers that operate in cold weather conditions. available data in the literature.
Mahdavi and Yaghoubi [27] experimentally measured the natu- While the previous work by Benítez and Sherif [3] was limited
ral convection heat transfer and frost deposition over a horizontal to the simple one-dimensional geometry of a flat plate with uni-
fin-tube. The fins were annular, with a small fin pitch (2 mm), com- form wall temperature, this paper extends the analysis to more
mon in air-cooled heat exchangers and some refrigerated evapora- complex geometries such as rectangular and annular fins. In these
tors. Hirbodi and Yaghoubi [14] experimentally investigated heat applications, heat and mass transfer considerations are by nature
and mass transfer during natural condensation of humid air over two-dimensional, adding a significant level of complexity to the
a horizontal annular finned-tube. The fins were circular with rect- problem. From the point of view of practical application of the
angular cross-section. The test results showed that condensation results, analysis of rectangular and annular fins is much more
and heat transfer rate depend mainly on the temperature and rel- attractive due to their widespread use in refrigeration applications
ative humidity of the surrounding air and fin base temperature. where frost formation is a very important drawback.
Correlations were developed for heat and mass transfer during nat- Analysis of the dynamics of frost formation over extended sur-
ural dehumidification over compact annular finned-tubes. Their faces have gone from the simple quasi steady-state approximation
correlations, expressed in terms of the Rayleigh number, were [26] to the use of sophisticated computational fluid dynamics
based on those of Chen and Hsu [7] modified by Mahdavi and (CFD) models using grid sizes of over 100,000 points [19]. The
Yaghoubi [27]. methodology presented in this paper fills the gap between those
T. Benítez et al. / International Journal of Heat and Mass Transfer 136 (2019) 99–115 101
1 eb DAB
Deff ¼ ð8Þ
described by the following governing equations: s 1 þ DAB =DK
Energy equation (frost)
Here, DAB is the molecular diffusivity of water vapor in air, DK is the
@T f
C f qf _ sg
¼ r keff rT f þ mh ð2Þ Knudsen diffusivity of water vapor inside the pores, and s is the tor-
@t tuosity of the pores. The Knudsen diffusivity depends on the charac-
Continuity equation for ice in the frost teristic pore diameter, a parameter not known for frost. The
102 T. Benítez et al. / International Journal of Heat and Mass Transfer 136 (2019) 99–115
tortuosity can be estimated in terms of the frost porosity, according T f ðx; z; t ¼ 0Þ ¼ T F ðx; t ¼ 0Þ ð14Þ
to Na and Webb [28]. The following expression is obtained
df ðt ¼ 0Þ ¼ d0 ð15Þ
1 eb 2 eb DAB
Deff ¼ ð9Þ
2 1 þ DAB =DK eb ðt ¼ 0Þ ¼ eb0 ð16Þ
The ratio DAB/DK is approximately 8.0, a value typical of porous
media [2,3] The value of DAB was calculated as suggested by Mago qv ðx; z; t ¼ 0Þ ¼ qv sat ðT F Þ ð17Þ
and Sherif [26].
In Eq. (14), it is assumed that the initial frost layer is in thermal
equilibrium with the fin. The initial values for frost layer thickness
3. Analysis of rectangular fin and density, shown in Eqs. (15) and (16), were investigated by
Jones and Parker [16] who determined that these values were
Fig. 1 is a schematic diagram of a rectangular fin with a frost around 0.02 mm and 30 kg/m3, respectively. In Eq. (17), it is
layer of thickness df(t) growing on both sides of the extended assumed that the gas phase in the initial frost layer is saturated
surface. with water vapor at the local temperature.
For rectangular geometry, Eqs. (1), (2), and (4) can be written as
For the fin we can write
(assuming heat transfer only in the x direction for the fin, and in
the x and z directions for the frost layer): T F jx¼0 ¼ T b ð18Þ
@T F keff @T f kF @ 2 T F
¼ þ ð10Þ @T F
@t qF C F d @z z¼0 C F qF @x2 @x x¼L
¼0 ð19Þ
" #
_ sg
@T f mh 1 @ 2 T f @T f @keff @ 2 T f @T f @keff At the interface between the fin and the frost layer we have
¼ þ k þ þ keff þ
@t qf C f qf C f eff @z2 @z @z @x2 @x @x T f bx;z¼0 ¼ T F ðxÞ ð20Þ
ð11Þ
@ eb
¼0 ð21Þ
@ @2q @ q @D @2q @ q @D @z x;z¼0
q 1 eb ¼ Deff 2v þ v eff þ Deff 2v þ v eff m_
@t v @z @z @z @x @x @x
ð12Þ @ qv
¼0 ð22Þ
@z x;z¼0
3.2. Initial conditions At the interface between the frost layer and the air we have
@T f ddf
Assuming that the temperature profile in the fin reaches steady keff ¼ h T 1 T f x;z¼d þ hsg qf ð23Þ
state before frost formation begins, we have [15], @x x;z¼df f x;z¼df dt
cosh½mF ðL xÞ h
T F ðx; t ¼ 0Þ ¼ T 1 ðT b T 1 Þ m2F ¼ ð13Þ @ eb
coshðmF LÞ kF d b ¼0 ð24Þ
@z x;z¼df
i
@ qv ddf
Deff ;s þ qf ¼ hm qv ;1 qv x;z¼d ð25Þ
@z z¼df z¼df dt f
qv x;z¼df ¼ ð1 þ SÞqv sat T f x;z¼df ð26Þ
Eq. (23) is an energy balance at the interface and states the fact
that the energy transferred to the frost layer from the humid air by
convection, plus the latent energy released when the water vapor
deposits as ice on the surface, move toward the inside of the frost
layer by conduction. Eq. (25) is a water vapor mass balance at the
interface. Part of the water vapor transferred from the humid air to
the frost layer by convection diffuses into the layer contributing to
its densification, while the rest deposits as ice on the surface, thus
increasing the frost layer thickness. Therefore, the boundary
between the frost layer and the air will be moving as the frost layer
thickness increases.
Eq. (26) introduces the possibility of super saturation at the
interface between frost and air. Most researchers assume that the
water vapor density at the interface corresponds to saturation con-
ditions at the frost surface temperature. If that were the case, once
the surface temperature is calculated, the corresponding water
vapor density would be fixed. However, Na and Webb [28] demon-
strated that a certain degree of super saturation at the solid-vapor
Fig. 1. Rectangular fin covered by a uniform frost layer. interface is required for ice crystal growth.
T. Benítez et al. / International Journal of Heat and Mass Transfer 136 (2019) 99–115 103
T f ðt; n; gÞ T b T F ðt; nÞ T b The rate of increase of the frost layer thickness is obtained from
hf ðt; n; gÞ ¼ hF ðt; nÞ ¼ ð37Þ Eq. (25), written in terms of the dimensionless variables:
T1 Tb T1 Tb
ddf hm qv ;1 qv g¼1 Deff ;s @ qv
3.5. Rate of ice deposition ¼ ð44Þ
dt qf
df qf @ g g¼1
g¼1 g¼1
The rate of ice deposition can be expressed as proportional to
the water vapor density in the frost layer, as mentioned in assump- Eqs. (40)–(44) form a set of nonlinear, coupled PDEs whose
tion (f). For the pseudo-steady-state case, Lee et al. [21] found that solution must be obtained by a suitable numerical method.
104 T. Benítez et al. / International Journal of Heat and Mass Transfer 136 (2019) 99–115
spatial dimensions are discretized using N internal collocation at Deff ði;kÞqv ði; kÞ 1
þ
points. With rectangular geometry and no symmetry, both bound- d2f 1 eb ði; kÞ 1 eb ði; kÞ d2f
aries are included as additional collocation points for a total of N !
X
M þ2 X
M þ2 X
M þ2
+ 2 discretization points for each dimension, chosen specifically Azðk; lÞqv ði; lÞ Azðk; lÞDeff ði;lÞ þ Deff ði;kÞ Bzðk; lÞqv ði; lÞ
as the roots of the (N + 2) degree Jacobi orthogonal polynomial l¼1 l¼1 l¼1
[10]. Benítez and Sherif [3] effectively used this method to describe 1
the frost formation process on flat plates. þ
1 eb ði; kÞ L2
The spatial derivatives are discretized as follows (illustrated !
here with the dimensionless temperature, but applicable to other X
N þ2 X
N þ2 X
N þ2
Axði; jÞqv ð j;kÞ Axði; jÞDeff ð j; kÞ þ Deff ði; kÞ Bxði; jÞqv ð j; kÞ
properties) j¼1 j¼1 j¼1
@h X
Nþ2
@ 2 h X
Nþ2 ð51Þ
¼ Ax ð i; jÞh ð j; k Þ ¼ Bxði; jÞhð j; kÞ ð45Þ
@n i;k j¼1 @n i;k
2
j¼1 Eq. (44) is written in terms of orthogonal collocation as:
PNþ2
ddf hm qv ;1 i¼1 wi qv ði; N þ 2Þ
@h X
Mþ2
@ 2 h X
Mþ2 ¼ P
¼ Az ð k; l Þhð i; lÞ ¼ Bzðk; lÞhði; lÞ ð46Þ dt qb Nþ2
i¼1 wi eb ði; N þ 2Þ
@ gi;k @ g2
l¼1 i;k l¼1
Deff ;s XNþ2 X
N þ2
PNþ2 wi AzðN þ 2; jÞqv ði; N þ 2Þ
where i ¼ 1; 2; ; M þ 2 k ¼ 1; 2; ; M þ 2 qb df i¼1 wi eb ði; N þ 2Þ i¼1 j¼1
Matrices Ax, Az, Bx, and Bz are readily calculated once the value ð52Þ
of N, the geometry of the problem, and whether one or two of the
In Eq. (52), the frost density at any point is approximated with
boundaries are included as collocation points are specified [3]. Do
the product of the ice density and the ice volume fraction, as justi-
[10] gives MATLAB programs to calculate the roots, and the matri-
fied above. The boundary conditions must also be expressed in
ces Ax, Az, Bx, and Bz. The results obtained through the orthogonal
terms of the collocation points.
can be used directly to accurately estimate spatial integrals by
Eqs. (48)–(52), with initial conditions given by Eqs. (13)–(17),
means of a quadrature formula. This is very useful for estimating
constitute an initial value problem (IVP) that can be approximately
average properties of the frost layer, such as temperature, and den-
solved using the ode15s program of MATLAB.
sity, as follows
Z df Z 1 X
Nþ2
1 4. Analysis of annular fin
qf ðtÞ ¼ qf ðt; zÞdz ¼ qf ðt; gÞdg wj qf t; gj ð47Þ
df 0 0 j¼1
Fig. 2 is a schematic diagram of an annular fin with a frost layer
In this equation, wj is the quadrature weight corresponding to of thickness df(t) growing on both sides of the extended surface.
the root gj. The weights are obtained from the MATLAB program
given by Do [10]. 4.1. Governing equations
The governing Eqs. (40)–(43) must be satisfied at each of the N
internal collocation points. They become: For cylindrical geometry, Eqs. (1), (2), and (4) can be written as
(assuming heat transfer only in the r direction for the fin, and in the
dhF ðiÞ keff g¼0 X Nþ2
kF X Nþ2
¼ Azð1; lÞhf ði; lÞ þ Bxði; jÞhF ð jÞ ð48Þ r and z directions for the frost layer):
dt df qF C F d l¼1 2
qF C F L j¼1 " #
@T F keff @T f kF @ 2 T F 1 @T F
¼ þ þ ð53Þ
X
dhf ði; kÞ gk ddf Mþ2 at Deff ði; kÞhsg qv ði; kÞ @t qF C F d @z z¼0 qF C F @r2 r @r
¼ Azðk; lÞhf ði; lÞ þ
dt df dt l¼1 df C f d2f ðT 1 T b Þ
_ sg
@T f mh 1 @ @T f 1 @ @T f
¼ þ keff þ keff r ð54Þ
1 X
M þ2 X
M þ2 @t qf C f qf C f @z @z r @r @r
þ Azðk; lÞhf ði; lÞ Azðk; lÞkeff ði; lÞ
df C f d2f
@
l¼1 l¼1
@ @ qv 1 @ @q
! qv 1 eb ¼ Deff þ Deff r v m_ ð55Þ
X
M þ2 @t @z @z r @r @r
þkeff ði; kÞ Bzðk; lÞhf ði; lÞ
l¼1
4.2. Initial conditions
1 X
Nþ2 X
Nþ2
þ Axði; jÞhf ð j; kÞ Axði; jÞkeff ð j; kÞ
df C f L2 j¼1 j¼1 Assuming that the temperature profile in the fin reaches steady
! state before frost formation begins, we have [15]
X
Nþ2
þkeff ði; kÞ Bxði; jÞhf ð j; kÞ ð49Þ T F ðr; t ¼ 0Þ ¼ T 1 ðT 1 T b Þ
j¼1
K 1 ðmF r 2 ÞI0 ðmF r Þ þ K 0 ðmF r ÞI1 ðmF r 2 Þ
ð56Þ
K 1 ðmF r2 ÞI0 ðmF r1 Þ þ K 0 ðmF r 1 ÞI1 ðmF r 2 Þ
deb ði; kÞ at Deff ði; kÞqv ði; kÞ gk ddf X
Mþ2
¼ þ Azðk; lÞeb ði; lÞ ð50Þ
dt d2f qb df dt l¼1 T f ðr; z; t ¼ 0Þ ¼ T F ðr; t ¼ 0Þ ð57Þ
T. Benítez et al. / International Journal of Heat and Mass Transfer 136 (2019) 99–115 105
@q ddf
Deff ;s v þ qf ¼ hm qv ;1 qv r;z¼d ð68Þ
@z r;z¼df r;z¼df dt f
qv r;z¼df ¼ ð1 þ SÞqv sat T f r;z¼df ð69Þ
qv r¼r2 ;z ¼ ð1 þ SÞqv sat T f r¼r2 ;z ð75Þ
4.3. Boundary conditions Applying the above, the governing equations become as
follows:
For the fin we can write
4.5.1. Energy equation on the fin
T F jr¼r1 ¼ T b ð61Þ
@T F @ HF 1 @ Hf kF
¼0 ð62Þ ¼ keff þ
@r r¼r2 @t df qF C F d @ g g¼0 qF C F ðr 2 r 1 Þ2
" #
At the interface between the fin and the frost layer we have @ 2 HF r2 r1 @ HF
þ ð78Þ
@ c2 ðr 2 r 1 Þc þ r 1 @ c
Tf r;z¼0
¼ T F ðr Þ ð63Þ
@ eb 4.5.2. Energy equation in the frost
¼0 ð64Þ
@z r;z¼0
1 @ @ Hf
At the interface between the frost layer and the air we have þ keff
qf C f ðr2 r1 Þ2 @ c @c
@T f
ddf @ Hf
keff ¼ h T 1 T f r;z¼d þ hsg qf ð66Þ keff
@z r;z¼df f r;z¼df dt þ
qf C f ðr2 r1 Þ½ðr2 r1 Þc þ r1 @ c
ð79Þ
@ eb
¼0 ð67Þ
@z r;z¼df 4.5.3. Continuity equation for ice in the frost
Remains as before, regardless of the change in geometry:
106 T. Benítez et al. / International Journal of Heat and Mass Transfer 136 (2019) 99–115
ð86Þ
at Deff qv 1 @ @ qv
2 þ 2 Deff
df 1 eb df 1 e b @ g @g
1 @ @ qv X
dHf ði; kÞ gk ddf Mþ2 at Deff ði; kÞhsg qv ði; kÞ
þ Deff ¼ Azðk; lÞHf ði; lÞ
1 eb ðr 2 r 1 Þ2 @ c @c dt df dt l¼1 qf C f d2f ðT 1 T b Þ
Deff @ qv X
þ ð81Þ keff ði; kÞ Mþ2
1 eb fcðr 2 r1 Þ þ r 1 gðr2 r1 Þ @ c þ Bzðk; lÞHf ði; lÞ
qf C f d2f l¼1
The time rate of increase of frost layer thickness remains as X
Mþ2 X
Mþ2
1
before: þ 2
Azðk; lÞHf ði; lÞ Azðk; lÞkeff ði; lÞ
q f C f df l¼1 l¼1
qv ;1 qv g¼1
ddf hm Deff ;s @ qv keff ði; jÞ X
Nþ2
¼ ð82Þ þ Br ði; jÞHf ð j; kÞ
dt qf
df qf @ g g¼1 qf C f ðr2 r1 Þ 2
j¼1
g¼1 g¼1
1 X
Nþ2 X
Nþ2
Eqs. (78)–(82) form a set of nonlinear, coupled PDEs whose þ Arði; jÞHf ð j; kÞ Ar ði; jÞkeff ð j; kÞ
2
solution must be obtained by a suitable numerical method. qf C f ðr2 r1 Þ j¼1 j¼1
keff ði; jÞ X
N þ2
For cylindrical coordinates, when the radial domain includes dqv ði; kÞ X
q ði;kÞ @ eb ði; kÞ gk ddf Mþ2
¼ v þ Azðk;lÞqv ði; lÞ
the origin, there are different equations to calculate the position dt 1 eb ði; kÞ @t df dt l¼1
of the internal collocation points and the derivative matrices Ar
X
g q ði; kÞ ddf Mþ2
and Br instead of those used for rectangular coordinates for those k v Azðk;lÞeb ði; lÞ
purposes. However, they do not apply to an annular region such as df 1 eb ði; kÞ dt l¼1
the one considered in this case. To circumvent this restriction, we at Deff ði;kÞqv ði;kÞ 1
defined a dimensionless radial position (c) in Eq. (76) with a þ
1 eb ði;kÞ d2f 1 eb ði; kÞ d2f
domain from 0 to 1.0; and used the position of the internal collo- !
cation points and matrices A and B corresponding to rectangular X
M þ2 X
M þ2 X
M þ2
Azðk; lÞqv ði;lÞ Azðk;lÞDeff ði; lÞ þ Deff ði; kÞ Bzðk; lÞqv ði;lÞ
coordinates [12]. A quadrature formula to estimate the value of l¼1 l¼1 l¼1
average properties in the radial direction is as follows:
1 X
N þ2 X
N þ2
R r2 þ Arði;jÞqv ð j; kÞ Ar ði; jÞDeff ð j; kÞ
2pr Hf ðt; g; r Þdr
r1
2
1 eb ði;kÞ ðr2 r1 Þ j¼1 j¼1
Hf ðt; gÞ ¼ R r2
r1
2prdr Deff ði;kÞ X
Nþ2
Z þ 2
Brði;jÞqv ð j;kÞ
2ðr 2 r 1 Þ 1 2r 1 1 eb ði;kÞ ðr2 r1 Þ j¼1
¼ cHf ðt; g; cÞdc þ
ðr 2 þ r 1 Þ 0 ðr 2 þ r 1 Þ X
Nþ2
Z 1 1
þ h 2
i Ar ði;jÞqv ð j; kÞ
Hf ðt; g; cÞdc ð84Þ 1 eb ði;kÞ ci ðr 2 r 1 Þ þ r 1 ðr 2 r 1 Þ j¼1
0
ð89Þ
2ðr 2 r 1 Þ X
Nþ2
Hf ðt; gÞ wj cj Hf t; g; cj Eq. (82) is written in terms of orthogonal collocation as:
ðr 2 þ r 1 Þ j¼1
h i
2r 1 X Nþ2
þ wj Hf t; g; cj ð85Þ @df hm qv ;1 qv ðN þ 2Þ
ðr 2 þ r 1 Þ j¼1 ¼
@t qb eb ðN þ 2Þ
In Eq. (85), wj is the quadrature weight corresponding to the Deff ;s XN þ2
root cj. The weights are obtained from the MATLAB program given AzðN þ 2; jÞqv ði; N þ 2Þ ð90Þ
df qb eb ðN þ 2Þ j¼1
by Do [10].
T. Benítez et al. / International Journal of Heat and Mass Transfer 136 (2019) 99–115 107
The average values in Eq. (90) are evaluated using Eq. (85). The To fix the domain of the space coordinates between zero and
frost density at any point is approximated with the product of the one, we use the front-fixing method. Then, the space-discretized
ice density and the ice volume fraction, as justified above. The set of equations is integrated in time to follow the changing posi-
boundary conditions must also be expressed in terms of the collo- tion of the moving boundary. This procedure eliminates the need
cation points. to use a pseudo-steady-state approximation frequently used by
Eqs. (86)–(90), with initial conditions given by Eqs. (56)–(60), researchers in this area. The method presented here can be used
constitute an initial value problem (IVP) that can be approximately for many problems in which a boundary is moving.
solved using the ode15s program of MATLAB. The degree of super saturation (S) required for frost formation is
a very important parameter in our formulation. Fig. 4 shows the
5. Results and discussion importance of the value of S when trying to simulate the experi-
mental results on the variation of the frost layer thickness with
5.1. Rectangular fins time obtained by Chen et al. [6]. The experimental conditions used
by these researchers are summarized in Table 2. The experimental
In order to calculate the convective mass- and heat-transfer values of frost thickness at the end of 4 h, shown in Fig. 4, corre-
coefficients, details about the geometric configuration of the fin spond to 91 measurements taken at different positions on the rect-
arrangement must be specified. Since we will test our model with angular fin. Assuming saturation at the interface (S = 0), the model
the experimental data obtained by Chen et al. [6] and Kim et al. significantly overestimates the frost layer development at all
[20], a similar configuration will be used, as shown in Fig. 3. The times. This can be explained from a mass transfer point of view.
air will flow through a rectangular channel formed by two succes- The driving force for water-vapor transfer rate from the humid
sive fins, the cold base wall, and an insulated lid. The flow through air surrounding the frost to the air inside the porous solid layer
the channel is turbulent with Reynolds numbers between 3000 and is the difference between the water-vapor partial pressure in the
10,000. The Gnielinski [13] correlation applies under these condi- bulk of the humid air and the corresponding partial pressure in
tions, and is used to estimate the heat-transfer coefficient: the air filling the pores at the air-frost interface. Assuming that
the air in the pores at the interface is saturated results in overesti-
ð f =8ÞðReD 1000ÞPr mating this driving force. As mentioned before—as far as we
NuD ¼ ð91Þ
1 þ 12:7ð f =8Þ
1=2
Pr2=3 1 know—there is no way of predicting the value of S; therefore, it
must be estimated by comparing the model predictions for differ-
Assuming heat and mass transfer similarity (jD = jH) for this ent values of S to experimental results. For the set of experimental
slowly varying heat and mass transfer process allows calculation conditions used by Chen et al. [6], simulations with a value of
of the mass-transfer coefficient [2]. S = 15% agree well with the average value of the experimental data.
The orthogonal collocation method usually achieves great accu- Fig. 5 shows the variation of the frost layer thickness with time
racy with a small number of collocation points. For dependent vari- obtained by Kim et al. [20]. The experimental conditions used by
ables that change smoothly with position, N = 2, (where N is the these researchers are also summarized in Table 2. Simulations with
number of internal collocation points) is usually sufficient. The col- a value of S = 8.0% agree well with the experimental data, as Fig. 5
location roots, quadrature weights, and the first- and second-order shows. Fig. 6 shows the temperature distribution on the surface of
derivative matrices are easily obtained from the literature for a the fin at the end of a frost formation period of 4 h for the experi-
given geometry and N value. Table 1 shows the results obtained mental conditions described by Chen et al. [6]. The final distribu-
for N = 2 obtained using in this case the MATLAB program given tion predicted by the model (with S = 15%) agrees well with the
by Do [10]. experimental data. Fig. 7 shows the temperature distribution on
Fig. 3. Schematic diagram of frost-covered rectangular heat exchanger fins, elevation and plan views.
108 T. Benítez et al. / International Journal of Heat and Mass Transfer 136 (2019) 99–115
Table 1
Roots, weights, and matrices for N = 2, rectangular geometry [10].
i gia wib Ac Bd
1 0.0 0.044 6.0 8.090 3.090 1.0 20.0 38.54 28.54 10.0
2 0.276 0.435 1.618 0.0 2.236 0.618 11.71 20.0 10.0 1.71
3 0.724 0.435 0.618 2.236 0.0 1.618 1.71 10.0 20.0 11.71
4 1.0 0.087 1.0 3.090 8.090 6.0 10.0 28.54 38.54 20.0
a
Roots of the (N + 2) degree Jacobi orthogonal polynomial.
b
Weights used in quadrature formula, Eq. (47).
c
Discretization first-derivative matrix, Eqs. (45) and (46).
d
Discretization second-derivative matrix, Eqs. (45) and (46).
Fig. 4. Variation of frost thickness with time. Experimental result shown is the average of 91 measurements of frost thickness at different points on the fin surface after 4 h
[6].
Table 2 [20]. The final distribution predicted by the model (with S = 8.0%)
Experimental test conditions used for rectangular fins. agrees well with the experimental data.
Parameter Chen et al. [6] Kim et al. [20] The effect of frost growth on the rate of heat transfer through
Fins material Aluminum alloy Aluminum alloy
the fin can be ascertained using the model results to calculate
Fins length, L (mm) 40.0 70.0 the variation with time of a dimensionless heat flux, Q(t), defined
Fins half-thickness, d (mm) 0.15 0.5 for a rectangular fin as
Fins spacing, tfin (mm) 9.2 40a
Air dry-bulb temperature, °C 15.0 7.0 PNþ2
Cold plate temperature, °C 35.0 20.0 qðx ¼ 0; tÞ j¼1 Axð1; jÞhF ð jÞ
Average air velocity, m s1 Q ðt Þ ¼ ¼ ð92Þ
4.4 1.0 qðx ¼ 0; t ¼ 0Þ mF LtanhðmF LÞ
Humidity of the air 92% RH 0.00464 kg kg1
Time of frost growth, min 240 90 This is the ratio of the heat flux from the fin to the cold wall at
a
Estimated from schematic diagram of Kim et al. [20]. any time during the frost formation period divided by the corre-
sponding heat flux before frost formation starts.
Fig. 8 shows the variation of the dimensionless heat flux with
the surface of the fin at the end of a frost formation period of time for the experimental conditions used by Chen et al. [6]. The
90 min for the experimental conditions described by Kim et al. model predicts the general trend displayed by the experimental
T. Benítez et al. / International Journal of Heat and Mass Transfer 136 (2019) 99–115 109
Fig. 5. Variation of frost thickness with time. Experimental results are from Kim et al. [20]. Each point corresponds to the average of 4 measurements at different points on the
fin.
Fig. 6. Temperature distribution on the surface of the fin. The experimental data from Chen et al. [6] were measured at the end of 4 h.
110 T. Benítez et al. / International Journal of Heat and Mass Transfer 136 (2019) 99–115
Fig. 7. Temperature distribution on the surface of the fin. The experimental data from Kim et al. [20] were measured at the end of 90 min.
Fig. 8. Dimensionless heat transfer rate as a function of time. Experimental data are from Chen et al. [6].
T. Benítez et al. / International Journal of Heat and Mass Transfer 136 (2019) 99–115 111
assumes constant values of the convective heat- and mass-transfer Parameter Forced convectiona Natural convectionb
coefficients. Actually, these coefficients will tend to increase as Fins material Aluminum Aluminum
frost accumulation partially blocks the airflow path and, for a con- Fins diameter, (mm) 23.0 56.0
stant airflow rate, the gas velocity increases. The increase in con- Tube outside diameter, (mm) 8.0 25.4
vective heat and mass flow at the air-frost interface partially Fins half-thickness, (mm) 0.075 0.2
Fins spacing, (mm) 10.0 2.0
offsets the insulating effect of the frost layer. However, as Fig. 8 Air dry-bulb temperature, °C 5.0 18.0/22.0
shows, the net effect of frost formation is a significant heat flux Cold plate temperature, °C 15.0 9.0
reduction over time. [Kim et al. [20] did not measure the heat flux Humidity of the air, % 50/60/70/80 35/45
variation with time in their experimental setup.] a
Lee et al. [23].
b
Mahdavi and Yaghoubi [27].
5.2. Annular fins data. (In all simulations of annular fins we used N = 2 in both the
radial and axial coordinates.)
In order to calculate the convective mass- and heat-transfer The concept of a dimensionless heat flux introduced in Eq. (92)
coefficients, details about the geometric configuration of the is modified here for an annular fin as
finned-tubes arrangement must be specified. Since we will test P
our model with the experimental data obtained by Lee et al. [23] qðr ¼ r 1 ; tÞ Nþ2 i¼1 Ar ð1; iÞHF ðiÞ
Q ðt Þ ¼ ¼
and Mahdavi and Yaghoubi [27], a similar configuration will be qðr ¼ r 1 ; t ¼ 0Þ mF ðr 2 r1 Þ K 1 ðmF r1 ÞI1 ðmF r2 ÞK 1 ðmF r2 ÞI1 ðmF r1 Þ
K 1 ðmF r 2 ÞI0 ðmF r1 ÞþK 0 ðmF r 1 ÞI1 ðmF r 2 Þ
used, as shown in Fig. 9. Lee et al. [23] worked under forced con-
ð93Þ
vection conditions, while Mahdavi and Yaghoubi [27] did it under
natural convection conditions. Table 3 summarizes the experimen- Fig. 11 shows the variation of the dimensionless heat flux with
tal conditions used in both works. time for the experimental conditions used by Lee et al. [23] at a rel-
Forced Convection ative humidity of 80% as predicted by our model. It shows that ini-
Lee et al. [23] studied experimentally frost growth on a large- tially the latent heat transfer due to ice deposition makes Q much
pitch fin-tube heat exchanger for low temperature heat pumps. higher than 1.0, but then it decreases monotonically as the frost
They worked with fin separations ranging from 4.0 to 12.0 mm. layer thickness increases. Eventually, the insulating effect of the
These are significantly larger than the fin pitch of heat exchangers presence of the frost layer becomes more pronounced and the heat
used for residential and commercial systems (usually in the range flux is reduced by more than 40%. Lee et al. [23] did not measure
of 1.4–2.0 mm). This is because the frosting problem is very impor- the heat flux; therefore, there are no experimental data in this case
tant in this case since frost growth blocks the air path, decreasing to corroborate the model predictions.
the airflow rate if the fin separation is not large enough.
Lee et al. [22] developed a heat-transfer coefficient correlation 5.2.1. Natural convection
for an inline finned-tube alignment, for fin pitches of 7.5– Mahdavi and Yaghoubi [27] studied experimentally frost depo-
15.0 mm. We used their correlation to estimate the heat-transfer sition over a compact finned-tube by natural convection. The fins
coefficient for the experimental conditions of Lee et al. [23] sum- were annular, with a small fin pitch (2 mm), common in air-
marized in Table 3. Assuming heat and mass transfer similarity cooled heat exchangers and some refrigerated evaporators. Chen
for this slowly varying heat and mass transfer process allows calcu- and Hsu [7] presented various correlations to estimate the heat
lation of the mass-transfer coefficient [2]. transfer coefficient on annular-finned tube heat exchangers in nat-
Fig. 10 shows the variation of the frost layer thickness with time ural convection. We used their correlation to estimate the heat-
obtained by Lee et al. [23] at a relative humidity of 70%. Simula- transfer coefficient for the experimental conditions of Mahdavi
tions with a value of S = 11.0% agree well with the experimental and Yaghoubi [27] summarized in Table 3. Assuming heat and
Fig. 9. Schematic diagram of an annular finned-tube showing frost formation on the fin surfaces.
112 T. Benítez et al. / International Journal of Heat and Mass Transfer 136 (2019) 99–115
Fig. 10. Variation of frost thickness with time under forced convection. Data are from Lee et al. [23].
Fig. 11. Variation with time of the dimensionless heat flux at the fin base for the experimental conditions of Lee et al. [23].
T. Benítez et al. / International Journal of Heat and Mass Transfer 136 (2019) 99–115 113
Fig. 12. Variation of frost thickness with time, under natural convection conditions, relative humidity of 45%. Data are from Mahdavi and Yaghoubi [27].
Fig. 13. Variation of frost thickness with time, under natural convection conditions, relative humidity of 35%. Data are from Mahdavi and Yaghoubi [27].
114 T. Benítez et al. / International Journal of Heat and Mass Transfer 136 (2019) 99–115
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Wesley, Reading, MA, 1963. media: a theory of drying, in: J.P. Hartnett, T.F. Irvine (Eds.), Advances in Heat
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And-Tube Heat Exchangers under Frosting Conditions Master Thesis, Huafan
University, Taipei, Taiwan, 2001.