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This paper was prepared for presentation at the SPE International Conference on CO2 Capture, Storage, and Utilization held in New Orleans, Louisiana, USA, 10–12 November 2010.
This paper was selected for presentation by an SPE program committee following review of information contained in an abstract submitted by the author(s). Contents of the paper have not been
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reproduce in print is restricted to an abstract of not more than 300 words; illustrations may not be copied. The abstract must contain conspicuous acknowledgment of SPE copyright.
This paper describes further the results from simulations is chosen which can represent part of the flank of an
of CO2 injection into conceptual reservoir models that are anticline, part of a fault block or part of the side of a salt
constructed to represent water flooded oil fields in the diapir by changing the dip of the model. Different
North Sea. The majority of North Sea oil reservoirs have conceptual models are realised by changing the
been subject to massive strategic and efficient water petrophysical properties of the model. The two main
flooding resulting in high recoveries for most of the cases. geologies of shallow marine deposit and fluvial deposits
Still residual oil is left after this either as bypassed oil are considered. Definition of base case North Sea
sones or as capillary trapped residual oil after water conceptual EOR model properties for the three main types
flooding leaving tertiary recovery methods as future of geology are based on the hydrocarbon pore volume
options to to increase the recovery. The reservior oil in (HCPV) weighted average values for field data in the
many candidate reservoirs in the North Sea, will obtain North Sea taken from SINTEF’s database (Holt and
misciblity with CO2 at reservoir conditions that will Lindeberg 2003). The HCPV weighted average values for
enable efficient displacement of capillary trapped oil after field data including reservoir fluid properties of the
water flooding. The density of CO2 at reservoir conditions conceptual model are presented in TABLE 1.
is in most cases lesser than the injected water and may
therefore reach other parts of the reservoir and TABLE 1 - Average values for field data in the North Sea
consequently improve the sweep efficiency. (from SINTEF’s database)
Average Values, Weighted
In order to cover the range of different geological classes, on HCPV
traps and recovery strategies for the great variation in type Norwegian All North
of North Sea oil reservoirs, a large number of scenarios Field/Input data Units Fields Sea Fields
have been simulated on conceptual sector models. PV Rm3 4.82E+08 2.73E+08
Conceptual live reservoir oil is composed to represent HCPV Sm3 2.48E+08 1.65E+08
fluid properties of a selection of 55 water flooded oil Reservoir °C 104 101
reservoirs (30 reservoirs in the UK sector, 20 in the temperature
Norwegian sector and 5 in the Danish sector) that are Reservoir bar 306 317
considered potential candidates for CO2 injection in the pressure
North Sea. The conceptual fluid model is composed and Depth m 2456 2462
tuned to reflect the hydrocarbon pore volume (HCPV) Oil viscosity cp 0.438 0.545
weighted average properties of these 55 oil reservoirs. Water viscosity cp 0.343 0.365
Density of STO Kg/Sm3 820 816
Reservoir simulation results are presented for GOR 197 145
representative petrophysical properties and fluid
Bo 1.58 1.39
compositions of North Sea oil reservoir in order to
Gas density kg/Sm3 0.99 0.99
schematically account for heterogeneities and phase
behavior of the different reservoir types. Conceptual
North Sea oil reservoir models in this context means Geometry and grid resolution of the North Sea
reservoir simulation models build to represent a selection conceptual models
of North Sea oil reservoirs candidates for CO2 injection The geometry of the North Sea conceptual reservoir
where the geological, fluid, static and dynamic properties models, the grid, the depth and the well positions are
of the fields are preserved in making the reservoir shown in Fig. 1. The area extent of the model is 1450 m
simulation models by average weighting of the properties. in length and 790 m in width. The thickness of the
reservoir model is 46 ± 1.2 m. The reservoir model is
Definition of base case North Sea representative penetrated by two wells, one injector (I1, water and gas)
conceptual model and one producer (P1). One well is located down-flank
Conceptual North Sea reservoir models representing the below the oil-water-contact (OWC), the other well at the
productive upper Brent-type sandstone oil reservoir have crest or top of the model. The distance between the wells
been constructed. The selected Brent sands represent is 1000 m. Both wells can be used as injector or producer
shallow marine deposition from Jurassic age (Johannessen and can be connected to the grid either in the entire height
and Nøttvedt 2008). The upper sequence is the Tarbert of the well or in selected layers of the grid. The depth of
Formation which is the final event of the Brent delta the reservoir model extends from 2940 m to 3040 m in
system and shows large variations in the different fields. true vertical depth sub surface (TVDSS). The average tilt
The Ness Formation represents the fluvial deposition of the model is varied between 2 and 10 degrees.
environment of the delta (Nystuen, Mørk, Müller, and
Nøttvedt 2008). The porosity and permeability fields for The model is initialized for reservoir simulation with
the two Brent sequences are taken from the 10th SPE under-saturated oil (no gas-cap) and enclosed aquifer with
comparative solution project (Christie and Blunt 2001). the OWC at 2990 m TVDSS as illustrated in Fig. 1.
Reservoir simulation grids with 2, 5 and 10° dip with 46
In order to construct conceptual sector models by 48 metre grid blocks and 30 layers are made and
representative of North Sea oil fields, one simulation grid illustrated in Fig. 2. The resolution of the simulation grid
SPE 139765 3
has been varied from a very fine mesh with grid block try to improve the CO2 sweep efficiency with 1 km wide
size in horizontal direction equal to 10 m to a coarser well spacing. If the reservoir is strongly tilted, it would be
mesh with grid block size up to 50 m and grid cell hight interesting to study different injection strategies like
from 1.0 m in the top layers and gradually increasing cell injection down flank or up flank. Horizontal well versus
hights towards deeper layers in the simulation grid. vertical well is another issue.
Type of geology
Definition of the shallow marine North Sea conceptual
EOR model is based on the geology of the Tarbert
Formation. The horizontal permeability for the shallow
marine conceptual model is illustrated on the fine scale
sector model in Fig. 3. The reservoir properties represent
a relatively homogenous shallow marine Brent deposit
with a high sand content, generally good reservoir
characteristics and a kv/kh ratio in the range of 10-3 to 1.0.
Flow parameters
The relative permeability functions are derived by use of
Corey relative permeability correlations. The oil, water
Fig. 9 - Density of CO2 and reservoir live oil at and gas relative permeability curves with hystersis in non-
reservoir temeprature and pressure of selected North wetting and wetting phases are presented in Fig. 10.
Sea oil reservoirs. Simulation runs have been performed using a commercial
black oil simulator (Eclipse 2009) with hysteresis options
The composition, the mol-fraction and the molecular and Todd-Langstaff miscibility options available in the
weight (MW) of each component, and the density of the software package.
liquid components of the conceptual live reservoir oil are
presented in TABLE 2. 1.0
0.9
krw imb
Krow
TABLE 2 - Composition, mol-fraction and molecular weight 0.8
0.2
CO2 0.311 44,010
0.1
C1 44,013 16,043
0.0
C2 3,843 30,070 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
iC4 0.606 58,124 Fig. 10 - Hysteresis in oil, water and gas relative
nC4 0,717 58,124 permeability curves for the North Sea conceptual
iC5 0,687 72,151 reservoir model.
nC5 0,349 72,151
C6 1,037 86,178 0,6640
Overview of reservoir simulation cases
A total of 1134 cases have been simulated for each of the
C7 2,365 96,000 0,7380
two geological types. The parameter sensitivity matrix for
C8 4,489 107,000 0,7650
the CO2-WAG injections is listed in TABLE 4 resulting
C9 3,514 121,000 0,7810 in a total of 648 cases. The CO2 injection cases counts
C10+ 36,461 246,300 0,8280 half of the WAG cases (no WAG-cycle parameter) and
the water injection cases counts to half of that again (no
The minimum miscibility pressure (MMP) between the onset parameter). Changing the gas-oil ratio effectively
conceptual live reservoir oil and CO2 was calculated by changes the density and viscosity of the oil to account for
PVTsim (Calsep 2010) by use of available methods. The the main variation in the field data.
parameters for combined condensing and vaporizing drive
MMP calculation are used. The result of the slim-tube TABLE 4 - Overview of reservoir simulation cases with
simulations for calculation of MMP showed that MMP parameter sensitivities
between the conceptual live reservoir oil and CO2 is far Parameter Values Units # of cases
below all the resevoir pressure regimes relevant for all the Model dip 2, 5, 10 degrees 3
reservoir simulation runs. Injection rate 300, 600, 1200 Rm3/day 9
Stauration
The density and viscosity of the conceptual live reservoir end point
0.1, 0.2, 0.3 27
oil as a function of increasing pressure are presented in
kv/kh 0.1, 1.0 Fraction 54
TABLE 3 -. The density, viscosity and surface tension at
Gas-oil ratio 40, 120, 150 Sm3/Sm3 162
1.01 bara pressure and 15.0 °C are 0.8161 g/cm³, 17.1 cP
and 20.6 mN/m, respectively. Onset of
0.6, 1.2 PV injected 324
CO2
WAG cycle
3, 12 Months 648
length
6 SPE 139765
Oil recovery efficiency by water injection Frequency plot of EOR by CO2 injection in shallow
The oil recovery profiles from the water injection runs on marine and fluvial deposits are presented in Fig. 15.
the conseptual North Sea shallow marine and fluvial
deposite reservoir models are presented in Fig. 11and Fig. 0,2
fraction of total HCPV. The initial stock tank oil in place 0,14
Min
EOR, fraction of HCPV
Average ‐
0,12 STDEV
with an oil formation volume factor, Bo = 1.36. Average +
STDEV
0,1
0,6 0,08
0,06
Oil recovery, fraction of HCPV
0,5
0,04
0,02
0,4
0
0 0,5 1 1,5 2 2,5
0,3 Injected volume, fraction of HCPV
0
0 0,5 1 1,5 2 2,5
Injected water volume, fraction of HCPV
0,45
0,4
0,35
Oil recovery, fraction of HCPV
0,3
0,25
Fig. 14 - EOR by CO2 injection in North Sea fluvial
0,2 deposits beyond water flooding.
0,15
16
EOR frequency, Fluvial
0,1 14
0,05 12
Frequency, %
EOR frequency, Shallow
0
10 Marine
0 0,5 1 1,5 2 2,5
8
Injected water volume, fraction of HCPV
6
Fig. 12 - Oil recovery by water injection in North Sea 4
fluvial deposits.
2
Frequency, %
10
simulation CO2 injection cases with on-set of CO2
injection at 0.6 HCPV of water injection. 8
0,25
6
4
0,2
Average
2
Max
EOR, fraction of HCPV
Min 0
0,5
1,5
2,5
3,5
4,5
5,5
6,5
7,5
8,5
9,5
10,5
11,5
12,5
13,5
14,5
15,5
16,5
17,5
18,5
19,5
20,5
21,5
22,5
0,15
Average ‐
EOR % of HCPV, (1% intervals)
0,1
0
0 0,5 1 1,5 2 2,5
Injected volume, fraction of HCPV Effect of injection of recirculated hydrocarbon
Fig. 16 - EOR by CO2-WAG injection in North Sea gas topped with CO2 on oil recovery efficiency
shallow marine deposits beyond water flooding. Associated gas contaminated with increasing amounts of
CO2 after CO2 break-through into production wells may
0,25
be re-circulated through the reservoir without further
processing. This will result in an injection gas with other
0,2
Average
properties compared to pure CO2 and this may affect the
Max oil recovery efficiency. Such potential impact is addressed
EOR, fraction of HCPV
0,15
Min by use of compositional reservoir simulations on
Average ‐ conceptual North Sea oil reservoir models.
0,1
The oil recovery profiles by water injection followed by
continuous CO2 injection and mixture of associated gas
0,05 topped with CO2 are shown in Fig. 19. The results are
from compositional reservoir simulation runs of
0 continuous CO2 injection after waterinjection and
0 0,5 1 1,5
Injected volume, fraction of HCPV
2 2,5
injection of CO2/hydrocarbon gas mixtures (CO2 break-
through gas) as make-up gas in a recirculatio process in
Fig. 17 - EOR by CO2-WAG injection in North Sea
the oil reservoir. The breakthrough gas is re-circulated
fluvial deposits beyond water flooding.
without further processing. The cases shown are runs on
the conceptual North Sea shallow marine reservoir model
Frequency plot of EOR by CO2 WAG injection in shallow
with onset of CO2 injection after about ten years of water
marine and fluvial deposits are presented in Fig. 18.
injection and with the residual oil saturaion after water
flooding set to Sorw = 0.3.
8 SPE 139765
0,30
Associated gas contaminated with increasing amounts of
Oil recovery efficiency; CO2 injected CO2 after CO2 break-through into production wells may
continuously after water injection
0,20
be re-circulated through the reservoir without further
processing. This will result in an injection gas with other
Oil recovery efficiency; CO2 injected
continuously after water injection
properties compared to pure CO2 and this may affect the
0,10
until CO2 breakthrough, then oil recovery efficiency. Such potential impact is addressed
breakthrough gas topped with CO2
by use of compositional reservoir simulations on
0,00
0 10 20 30 40 50
conceptual North Sea oil reservoir models.
Years
Results from compositional reservoir simulation runs of
Fig. 19 - Oil recovery by water injection followed by injection of CO2/hydrocarbon gas mixtures (CO2 break-
continuous CO2 injection and mixture of associated through gas) as make-up gas in a recirculation mode in oil
gas topped with CO2. reservoirs after about ten years of water injection revealed
that the EOR contribution was very similar or compareble
Discussions to the cases run without recirculation for the first 20 years
The performance of the continuous water injection in the of recirculation. Beyond 20 years the EOR contribution
conceptual North Sea shallow marine and fluvial deposite from continuous injection is somewhat higher and reaches
reservoir models as presented in Fig. 11and Fig. 12 as a 1.9% of HCPV at 50 years of injection (water and CO2
fraction of cumulative produced oil expressed as fraction injection in total).
of HCPV versus injected water volumes as a fraction of
HCPV until injection 2.5 HCPV in total. The initial stock The compositional reservoir simulation runs incorporate
tank oil in place in the model is 5.78·106 Sm3. The HCPV recirculation of a mixture of breakthrough gas
is 7.87·106 Rm3 with an oil formation volume factor, Bo = contaminated with increasing amounts of CO2 after CO2
1.36. The oil recovery profiles are within a range of breakthrough. The breakthrough gas is re-circulated
0.325– 0.514 fraction of HCPV and in a range of 0.258– without further processing which will result in an
0.417 fraction of HCPV for shallow marine and fluvial injection gas with other properties compared to pure CO2
deposits, respectively. and this may affect the oil recovery. After breakthrough
of CO2 into the production well, the mole fraction of CO2
The better performance with respect to the oil recovery in the separator gas phase will increase. This separator gas
profiles for the North Sea shallow marine deposits will be re-circulated and topped with CO2 and will
compared to fluvial deposits under otherwise comparable constitute the always changing mixture of CO2 and
fluid properties and dynamic flow properties is hydrocarbon gas for re-circulation. With a relative low
anticipated to be caused by the better volumetric sweep of GOR of the reservoir oil this gas mixture will after years
CO2 of the shallow marine deposit compared to fluvial of recirculation not deviate enough from CO2 itself to
deposit, please refer to the river flow channel system in influence the oil recovery efficiency markedly.
fluvial deposits shown in Fig. 5.
Conclusions
The EOR profiles presented are the average profile, The conclusions are as follows:
maximum profile, minimum profile, average profile • The CO2 EOR from North Sea shallow marine
minus standard deviation of all profiles and average conceptual reservoir models is in the range of
profile plus standard deviation of all profiles for all 3.75– 17.4 % with average of 10.0% of HCPV
simulation. The onset of CO2 injection is at 0.5 HCPV of after continuous injection of 2.5 HCPV of CO2.
water injection applies for all cases of both CO2 injection
• The CO2 EOR from North Sea fluvial deposits
and CO2 WAG injection. The EOR is within a range of
conceptual reservoir models is in the range of
0.038– 0.174 fraction of HCPV and in a range of 0.264–
2.64– 16 % of HCPV with an average of 9.0%
0.160 fraction of HCPV after injection of 2.5 HCPV for
after injection of 2.5 HCPV of CO2.
shallow marine and fluvial depostis, respectively.
• The CO2 WAG EOR from North Sea shallow
marine conceptual reservoir models is in the
The CO2 WAG EOR profiles are even more promising
range of 6.9– 23.8 % with an average of 16.6%
compared to above. The CO2 WAG EOR is within a
of HCPV after injection of 2.5 HCPV of CO2
range of 0.069– 0.238 fraction of HCPV and in a range of
WAG.
0.068–0.207 fraction of HCPV after injection of 2.5
SPE 139765 9
• The CO2 WAG EOR from North Sea fluvial Johannessen, J.P. and Nøttvedt, A., 2008: Norway
deposits conceptual reservoir models is in the encircled by coastal plains and deltas. In: Ramberg, I.B.,
range of 6.8– 20.7 with average of 13.4% of Bryhni, I., Nøttvedt, A. and Rangnes, K. (eds.) 2008, The
HCPV after injection of 2.5 HCPV of CO2 Making of a Land – Geology of Norway, Trondheim,
WAG. Norsk Geologisk Forening, pp. 356–383.
• The EOR contribution from CO2/hydrocarbon
mixture injection with recirculation of Nystuen, J.P., Mørk, A., Müller, R. and Nøttvedt, A.,
breakthrough gas contaminated with CO2 beyond 2008: From desert to alluvial plain – from land to sea. In:
that of water injection, is very similar or Ramberg, I.B., Bryhni, I., Nøttvedt, A. and Rangnes, K.
comparable to the cases run without (eds.) 2008, The Making of a Land – Geology of Norway,
recirculation. Trondheim, Norsk Geologisk Forening, pp. 330–355.
Subscripts
h, v = horizontal, vertical
g, o, w = gas, oil, water
r imb = relative permeability during imbibition
Acknowledgments
We acknowledge the ECCO–European Value Chain for
CO2 project for the financial support for this research
work. ECCO is a European research project funded by the
European Commission under the 7th framework
programme for research (7FP) and by industial companies
within power generation and oil and gas production
(http://www.sintef.no/Projectweb/ecco/).
References
Holt, T., Lindeberg, E. and Taber, J.J., 2000:
Technologies and possibilities for large scale CO2
separation and underground storage, paper SPE 63103
presented at the SPE Annual Technical Conference and
Exhibition, Dallas, Tx., 1–4 Oct.