PART-A : PHYSICS

SECTION-I : Single Correct Type

This section contains 20 multiple choice questions. Each question has four choices (1), (2), (3) and (4)
out of which ONLY ONE is correct. You will be awarded 4 marks if only the correct option is chosen
and zero mark if none of the option is chosen. (–1) marks will be awarded for incorrect answers in this
section.
1. Ice at 0ºC is added to 200gm of water initially at 70°C in a vacuum flask. When 50 gm of ice has
been added and has all melted, the temperature of flask and contents is 40ºC, When a further 80
gm of ice is added and has all melted, the temperature of whole becomes 10ºC. Neglecting heat
lost to surroundings the latent heat of fusion of ice is :
(1) 80 cal/gm (2) 90 cal/gm (3) 70 cal/gm (4) 540 cal/gm

2. A gas is expanded from volume V0 to 2V0 under three different processes. Process 1 is isobaric,
process 2 is isothermal and process 3 is isothermal and process 3 is adiabatic. Let U1, U2 and
U3 be the change in internal energy of the gas in these three processes. Then –
P

1
P0
2
3

V
V0 2V0

(1) U1 > U2 > U3 (2) U1 < U2 < U3
(3) U2 < U1 < U3 (4) U2 < U3 < U1

P0
3. One mole of an ideal gas undergoes a process P = 2
.
V 
1  0 
 V
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Here, P0 and V0 are constants. Change in temperature of the gas when volume is changed from V
= V0 to V = 2V0 is –
2P V 11P0 V0 5P V
(1) – 0 0 (2) (3) – 0 0 (4) P0V0
5R 10R 4R

4. Bulk modulus of water is 2 × 10 9 Nm–2. The change in pressure required to increase the density of
water by 0.1% is -
(1) 2 × 109 Nm–2 (2) 2 × 108 Nm–2 (3) 2 × 10 6 Nm–2 (4) 2 × 104 Nm–2

5. A gas is expanded to double its volume by two different processes. One is isobaric and the other is
isothermal. Let W1 and W2 be the respective work done, then –
W1 W
(1) W2 = W1 ln (2) (2) W2 = (3) W2 = 1 (4) data is insufficient
ln (2) 2

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 6. A gas undergoes process ABCDAC. Work done by gas is –

A C
200 kPa
P

100 kPa
D B

100 cc 200 cc
V
(1) 5 kJ (2) 2.5 kJ (3) – 5 kJ (4) 7.5 kJ

R 
7. The molar heat capacity for a process is : C = + , then process equation is -
 1 T
(1) Ve–(/R)T = constant (2) Ve(/R)T = constant
(3) VT = constant (4) Ve/RT = constant

8. The internal energy of a diatomic gas is given as U = U 0V, where U0 is a constant. Molar heat
capacity of gas is -
5 7 9 3
(1) R (2) R (3) R (4) R
2 2 2 2

9. A container has N molecules at absolute temperature T. If the number of molecules is doubled but
kinetic energy in the box remains the same as before, the absolute temperature of the gas is -
(1) T (2) T/2 (3) 2T (4) zero

10. An ideal gas whose adiabatic exponent is  is expanded so that the amount of heat transferred to
the gas is equal to the decrease of its internal energy. Molar heat capacity of the gas for this
process is -
R R
(1) (2) (3) R (4) R/2
1   1
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11. The highest temperature of the gas, attained if the pressure of an ideal gas varies according to the
law P = P0 – aV2, where P0 and a are constants, is (number of moles-n)
1/2 1/ 2
2P0  P0  2 P0  P0 
(1) T max =   (2) Tmax =  
2nR  3a  3 nR  3a 
1/2
P0  P0 
(3) T max = (4) none of these
3nR  3a 

12. Consider 1 cc sample of air at absolute temperature T0 at sea level and another 1 cc sample of air at a
height where pressure is one-third atmosphere. The absolute temperature T of the sample at the
height is-
(A) equal to (T0/3)
(B) equal to (3/T0)
(C) equal to T 0
(D) cannot be determined in terms of T0 from the above data
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 13. A metal ball immersed in water weighs w1 at 0ºC and w2 at 50ºC. The coefficient of cubical
expansion of metal is less than that of water. Then –
(1) w1 > w2 (2) w1 < w2 (3) w1 = w2 (4) data is insufficient

14. The height of mercury column measured with brass scale at temperature T0 is H0. What height H'
will the mercury column have at T = 0ºC. Coefficient of volume expansion of mercury is .
Coefficient of linear expansion of brass is  -
H (1  3T0 ) H (1  3T0 ) H (1  T0 )
(1) H0(1 + T0) (2) 0 (3) 0 (4) 0
1  T0 (1   / 3)T0 1  T0

Q
15. The molar heat capacity in a process of a diatomic gas if it does a work of when a heat of Q is
4
supplied to it is -
2 5 10 6
(1) R (2) R (3) R (4) R
5 2 3 7

16. Three discs, A, B and C having radii 2 m, 4 m and 6 m respectively are coated with carbon black
on their outer surfaces. The wavelengths corresponding to maximum intensity are 300 nm, 400 nm
and 500 nm, respectively. The power radiated by them are QA, QB and QC respectively –
(1) QA is maximum (2) QB is maximum (3) QC is maximum (4) QA = QB = QC

17. A ring consisting of two parts ADB and ACB of same conductivity K carries an amount of heat H.
The ADB part is now replaced with another metal keeping the temperatures T1 and T2 constant.
The heat carried increases to 2H. What should be the conductivity of the new ADB part ?
ACB
(Given =3)
ADB
C
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T1 A B T2
D
7 5
(1) K (2) 2 K (3) K (4) 3 K
3 2

18. P-V diagram of a diatomic gas is a straight line passing through origin. The molar heat capacity of
the gas in the process will be -
4R
(1) 4R (2) 2.5 R (3) 3 R (4)
3

19. Wein's constant is 2892 × 10–6 SI unit and the value of m for moon is 14.46 micron. The surface
temperature of moon is –
(1) 100 K (2) 300 K (3) 400 K (4) 200 K
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 20. A students performs cooling experiment with a solid sphere and hollow sphere of same material
and size which are heated to the same temperature. If the temperature difference between each
sphere and surroundings is around 30°C , then -
(1) The hollow sphere will cool at a faster rate
(2) The solid sphere will cool at a faster rate
(3) Both spheres will cool at the same rate
(4) Both spheres will cool at the same rate if temp. difference more than 30°C

SECTION-II : Integer Value Correct Type

This section contains 5 questions. For each question, enter the correct numerical value (in decimal
notation, truncated / rounded off to the second decimal place; e.g. 6.25, 7.00, –0.33, –0.30, 30.27,
–127.30) using the mouse and the on screen virtual numeric keypad in the place designated to enter the
answer. You will be awarded 4 marks if correct numerical value is entered as answer. No negative
marks will be awarded for incorrect answers in this section.
21. Given the following values for an elastic material: Young's modulus = 7 × 1010 Nm–2 and Bulk
modulus = 11 × 1010 Nm–2 . The Poisson's ratio of the material is -

1
22. A gas expands adiabatically at constant pressure such that its temperature T  , The value of
V
Cp/CV of gas is 

23. Figure shows a parabolic graph between T and 1 for a mixture of a gas undergoing an adiabatic
V
process. What is the ratio of Vrms of molecules and speed of sound in mixture -
T

2T 0
T0
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24. A and B are two points on a uniform metal ring whose centre is C. The angle ACB = . A and B
are maintained at two different constant temperatures. When  = 180º, the rate of total heat flow
from A to B is 1.2 W. When  = 90º, this rate(in watt) will be -

25. One gram of ice is mixed with one gram of steam. After thermal equilibrium, the temperature(in °C)
of the mixture is

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 PART-B : MATHEMATICS
SECTION-I : Single Correct Type
This section contains 20 multiple choice questions. Each question has four choices (1), (2), (3) and (4)
out of which ONLY ONE is correct. You will be awarded 4 marks if only the correct option is chosen
and zero mark if none of the option is chosen. (–1) marks will be awarded for incorrect answers in this
section.
26. If 270º < < 360º, then 2  2  2cos  is equal to

   

(1) 2sin   (2) 2sin   (3) 2 cos   (4) 2 cos  
4 4 4 4

27. The expression sin x – cos2x – 1 assumes the least value for the set of real values of x given by
 
(1) x = n + (–1)n+1   (2) x = n + (–1)n  
6 6

 
(3) x = n + (–1)n   (4) x = n – (–1)n  
3 3
where n  I

28. Number of real roots of the equation x  x  (1  x)  1 is

(1) 0 (2) 1 (3) 2 (4) 3

2 3 1
29. A triangle has sides a = 1, b = and c = . The angle opposite to side c, is
3 6
(1) 18° (2) 15° (3) 36° (4) 75°
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30. The value of sin 47° + sin 61° – sin 11° – sin 25° is equal to
(1) sin 36° (2) cos 36° (3) sin 7° (4) cos 7°

sin(m )
31. If (3 – 4 sin221°) (3 – 4 sin 27°) = (where mº, nº are acute angle) then (m + n) is
sin(n )
(1) 50° (2) 65° (3) 70° (4) 59°

32. The vertex of ABC are A(0, –6), B(–6, 0) and C(1, 1). Then co-ordinate of excentre opposite to
vertex A is given by -
 3 3   3  3 3 
(1)  ,  (2)  4,  (3)  ,  (4) (–4, 6)
 2 2   2  2 2

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 33 Which of the following trigonometric statement does not hold good ?
      1  tan x
(1) tan   x   cot   x  (2) tan   x  
4  4  4  1  tan x
    cos 2x
(3) tan   x   sec 2x  tan 2x (4) tan   x  
4  4  1  sin 2x

C A
34. In a triangle ABC, 2  a sin 2  c sin 2  
 2 2
(1) a + b + c (2) b + c – a (3) a + b – c (4) a + c – b

3
35. If A + B + C = , then cos2A + cos2B + cos2C is equal to
2
(1) 1 – 4cosA cosB cosC (2) 4sinA sinB sinC
(3) 1 + 2cosA cosB cosC (4) 1 – 4sinA sinB sinC

sin(   )  sin(   )  n 
36. If  +  = , (), then the value of is    ,nI
sin(    )  sin(    )  2 
(1) sin (2) sin (3) sin (4) –1

37. Find largest angle if the sides of triangle are 3  3 , 2 3 and 6.

 2 7 5
(1) (2) (3) (4)
2 3 12 12

38. If ƒ(x, y) = 3x2 + 4xy + ay2 + 6x – 8y – 7 can be factorised into two linear factors then 'a' is equal to
29 29 34 34
(1) (2)  (3) (4)
15 15 15 15

39. The angle A of the ABC is obtuse. Then the value of [6 – tanB tanC] is equal to
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(where [x] denotes the greatest integer function)

(1) 2 (2) 3 (3) 4 (4) 5

 
40. cot  cos 2x   3 , then the general solution of the equation is (where n  I)
3 
1 1 1 1
(1) x = n ± (2) x = n ± (3) x = n ± (4) x = n ±
2 3 6 4

41. For all pairs of angles (A, B), measured in degrees such that sin A+sin B = 2 and
cos A + cos B = 2 ,both hold simultaneously. The smallest possible value of |A – B| in degrees
is
(1) 15° (2) 30° (3) 45° (4) 60°

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 42. If (q + r) = 0, then the equation (x2 + px + q) (x2 +px + r) = 0, (p, q, r  R) has
(1) at least 2 real roots (2) at least 2 imaginary roots
(3) at most 2 real roots (4) all roots real
89
43. Value of   cos(2r)º  tan(2r  1)º  is equal to :
r 1

(1) 0 (2) cos178º + tan179º

(3) –tan1º (4) tan179º – cos2º

x2  x  7
44. The smallest positive integral value of expression , x  R is
x2
(1) 1 (2) 2 (3) 3 (4) 4

 
45. Consider following figure  R – (2n  1)  ; n  I, then
 2

 

(1) tan+ tan+ tan = tan. tan. tan (2) tan– tan– tan = tan. tan. tan
(3) tan– tan– tan = tan. tan. tan (4) tan– tan– tan = tan. tan. tan

SECTION-II : Integer Value Correct Type

This section contains 5 questions. For each question, enter the correct numerical value (in decimal
notation, truncated / rounded off to the second decimal place; e.g. 6.25, 7.00, –0.33, –0.30, 30.27,
–127.30) using the mouse and the on screen virtual numeric keypad in the place designated to enter the
answer. You will be awarded 4 marks if correct numerical value is entered as answer. No negative
marks will be awarded for incorrect answers in this section.
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(d  a)(b c) (d  b)(c a) (d  c)(a  b)

46. Given A + B + C = 2 and cosA = , cosB = and cosC = ,
(d  a)(b c) (d  b)(c a) (d  c)(a  b)
A B C
then the value of tan  tan  tan is equal to-
2 2 2

47. The value of x satisfying the equation 2cos2(x3 + x) = 2x + 2–x is

48. Number of roots of the equation sin2x + 2 sinx – cosx – 1 = 0 in the range 0 x  2 is


49. If ,  are roots of equation 9x2 – 11x + 3 = 0, then 
r 0
r
 r  is equal to

b
50. In a ABC, with usual notation if sinB = 2 sinC·cosA, then equals
ccos C
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 PART-C : CHEMISTRY
SECTION-I : Single Correct Type
This section contains 20 multiple choice questions. Each question has four choices (1), (2), (3) and (4)
out of which ONLY ONE is correct. You will be awarded 4 marks if only the correct option is chosen and
zero mark if none of the option is chosen. (–1) marks will be awarded for incorrect answers in this section.

51. Which of the following species has maximum thermal stability ?

(1) H–F (2) H–I (3) H–Cl (4) H–Br

52. Which of the following statements is INCORRECT

(1) For reversible isothermal expansion Suniverse is zero
(2) Ssystem for irreversible adiabatic compression is greater than zero
H
(3) Change in entropy for phase change is always equal to at any temperature and pressure
T
(4) Ssystem for free expension is greater then zero

53. Which of the following statement is CORRECT ?

(1) All non-aromatic compounds are stable at room temperature.
(2) –OH group when attached with benzene increases net electron density
(3) Ethenol and ethanol are resonating structures
(4) 1,3,5,7-cyclooctatetraene is anti-aromatic compound

54. Which of the following has CORRECT order of bond length of their indicated bond(s) ?
(1) d O–O ; H2O2 < O2F2 (2) dC–O ; CO32– > CO2 > CO
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(3) d O–O ; O3 < O2 (4) dC–C ; H3C–CH3 < CF3–CF3

55. Which of the following is least reactive for electrophilic attack than Benzene ?

(1) (2) (3) (4)

56. When 16gm O2 is expanded isothermally and reversibly at 300K to double of its initial volume,
then work done by the gas is (ln2 =0.7 & R = 2cal/mol-K)
(1) 210 cal (2) –210 cal (3) 420 cal (4) –420 cal

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 57. Which of the following species, contains maximum number of l.p.–b.p. repulsions w.r.t. central

atom is :-

(1) XeF4 (2) XeF5 (3) XeO3 (4) SO2

58. Identify the binary mixture(s) that can be separated into individual compounds, by differential
extraction, as shown in the given scheme. ‘

(1) C6H5NH2 , PhCH2COOH (2) C6H5(CH)2COOH, C6H5OH

(3) (COOH)2 , CH3SO3H (4) C6H5OH, CH3(CH2)5OH

59. For the real gas reaction,

2SO2(g) + O2(g) 2SO3(g) ; H = –440 kJ/mol
If the reaction is carried out in 10 litre rigid vessel the initial pressure is 50 bar which decreases to
20 bar in the course of reaction. The change in internal energy for the reaction is :
(Given: 1 bar-L = 100 J)
(1) –437 kJ (2) –410 kJ (3) –443 kJ (4) –470 kJ

60. Which of the following overlapping is CORRECT regarding -bond formation ?

(1) 2px + 2p x, when y-axis is inter nuclear axis
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(2) 1s + 2px, when x-axis is inter nuclear axis

(3) 2py + 2p y, when z-axis is inter nuclear axis
(4) 2py + 2p z, when x-axis is inter nuclear axis

61. Most stable resonating structure of p-methoxybenzylcarbocation ( )

(1) (2) (3) (4)

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 62. Which of the following statement is INCORRECT ?

(1) Only a state function may be expressed as difference in its value at two states in any process

(2) A process cannot be defined on the basis of initial and final states of the system.

(3) In a cyclic process, the internal energy of the system remains throughout constant.

(4) During irreversible process, the equation PV = nRT is not applicable to ideal gas

63. Which of the following specie does not contain p  – d bond(s) ?

(1) SO2Cl2 (2) N2O (3) H2PO3 (4) SO32–

64. Which of the following methyl substituted aniline is least basic?

(1) Ortho (2) Meta (3) Para (4) N-substituted

65. Which of the following is INCORRECT for the phase change,

H2O (l, 373 K, 1 atm)  H2O (g, 373 K, 1 atm)

(1) w = –ve (2) H = +ve (3) U < H (4) Ssys = 0

66. If internulear axis is z-axis, then, in which of the following cases  and  bonds are not possible ?

(1) d xy + d xz (2) p y + py (3) d z 2  d z 2 (4) pz + pz

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67. Tenormin, a member of the group of drugs known as beta-blockers, is used to treat high blood

pressure and improve survival after a heart attack, It works by slowing down the heart to reduce its

workload. Which atom in Tenormin is the most basic?

O OCH2CHCH2NHCH(CH3)2
C OH
H2N CH2

(1) Acid amide (2) Ether (3) Alcohol (4) Secondary amine

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 68. An ideal diatomic gas undergoing the following process as shown :

8P1 B
P
2P1

V1 4V1
V
The value of q for the process is :
(1) 37 P1V1 (2) 43 P1V1 (3) 96 P1V1 (4) 90 P1V1

69. Which of the following statement is INCORRECT about PCl3F2.

(1) Molecule is non polar

(2) P–F bond length is greater than P–Cl bond length

(3) Axial hybrid orbital length is greater than that of equitorial hybrid orbital length

(4) All F – Pˆ – Cl bond angles are equal

70. Which of the following compounds can’t show all types of permanent electronic displacement

effect?

(1) 3-methyl benzaldehyde (2) 2-Hexenoic acid

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(3) Buta-1,3-diene (4) Prop-1-en-1-amine

SECTION-II : Integer Value Correct Type

This section contains 5 questions. For each question, enter the correct numerical value (in decimal
notation, truncated/rounded off to the second decimal place; e.g. 6.25, 7.00, –0.33, –0.30, 30.27,
–127.30) using the mouse and the on screen virtual numeric keypad in the place designated to enter the
answer. You will be awarded 4 marks if correct numerical value is entered as answer. No negative
marks will be awarded for incorrect answers in this section.
71. A monoatomic ideal gas undergoing irreversible adiabatic compression from 4L to 1L against
1 bar pressure. Calculate enthalpy change in Joules. (Given: 1 bar-L = 100 J)

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 72. Which of the following compounds/species are non-aromatic in nature?
O
 
(1) (2) (3) (4)

NH O
(5) (6) (7) (8)

(9)

N
H H

73. An ideal gas undergoes expansion from A(10 atm, 1 litre) to B(1 atm, 10 litre), first against
5 atm and then against 1 atm isothermally. Calculate heat involved in process (in L-atm)

74. Find the maximum number of identical bond angle in ClO3–.

75. Expansion of 1 mole of ideal gas is taking place from 2 litre to 8 litre at 300K against 1 atm
pressure. Calculate Stotal in JK–1mol–1
1 1
(Given R = 8.3Jmol K ,1L-atm=100 J, ln2 = 0.7)
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