2020 2019

: ‫ خالل تحول كيميائي يحدث تفاعل نمذجته بالمعادلة التالية‬

Cr2o72- (aq) +3H2C2O4 (aq) + 8 H+ (aq) = 2Cr3+ (aq) +6 CO2 (g) + 7 H2O (l)
OX/Red 1
2
- +
H2O2 (aq) + 2I (aq) +2 H (aq) = I2 (aq) + 2 H2O (l)
Zn (s) + 2 H+ (aq) = Zn2+ (aq) + H2 (g)
2MnO4 (aq) + 5 SO2 (aq) + 2 H2O (l) = 2 Mn2+ (aq) + 5 SO42-(aq) + 4 H+ (aq)
-

A +2B=c+3D
B 5125 mol A 5110 mol t=0
1
2
3
n0(B)= 0.30mol n0(A)= 0.10mol 4
n0(B)=0.20mol n0(A) = 0.10mol

V1 = 20 ml C1
C2= 0.1mol/L
1
( ox/Red ) 2
O2 (g) /H2O2(l) ; MnO4-(aq) 2+
/Mn (aq)
3
V2E C1 ,V1 , C2 , V2E ? 4
V2E 50ml C1 0

0.5mol/L V= 100ml m=1.0 g

380ml 5min
560 ml 10 min
1
( ) 2
3
10min 4
-1 -1
M(Mg) = 24.0 g.mol VM= 24 L.mol

C= 100 m mol/L VS= 100ml CaCO3 (S) m0=2.0 g

CaCO3(S) + 2 H3O+ (aq) = Ca2+ (aq) + CO2 (g) +3 H2O (l)

V = 51.2 ml CO2 46s 𝛉 20° P= 101.3 KPa
1
R V 𝛉 P x 2
t= 46s 3
-1
M(Ca) = 40 g.mol R= 8.31 (SI)
2020/2019
2

2H2O2 (aq) = 2 H2O (l) + O2 (g)

1
2

H2O2 5 1.0 mol/L V=20ml t=0 3

t(h) 0.5 1 1.5 2 2.5 3 4 5 6 7 8 10
V(O2)(ml) 50.2 90.6 117.2 147.4 167.2 183.2 206.0 220.0 228.0 232.0 236.0 238.0
n(O2)(mmol)
VM = 24 L/mol

( ) V n(O2) H2O2 5

H2O2 f(t)
t= 4h t=2h t=0

1ml c1= 5 ,6 .10-2mol/L V1= 50 ml

c2 = 0.2 mol/L V2= 50ml
15 ml t= 0
V= 100ml
40ml t= 60s
trempe c= 4 ,0 .10-2 mol/L

t(s) 60 180 270 360 510 720 900 1080 1440

VE(ml) 2.2 4.8 6.3 7.3 9.0 10.6 11.7 12.7 13.7
1
1 2
VE c 2 2
V=100ml n(I2)T 3 2
4 2
t(s) 60 180 270 360 510 720 900 1080 1440
n(I2)T(mol) ……… ……… ……11 ………1 ………1 ………11 ………1 ………1 ………
1 3
2 3
x n(I2) T 3 3
x= f(t) 4 3
t1= 900s t0= 0

t1/2
c2= 0.5 V2= 20 ml c1= 0.2 mol/L V1= 20ml
c t=0 mol/L
t(min) 0 1 2 3 4 5 6 7 8
C(mmol/L) C0 96 93 60 30 12 5 3 2
1

c0 2
3
4
V c0 c x 0
t= 3min 6

CaCO3(S) + 2 H3O+ (aq) = Ca2+ (aq) + CO2 (g) +3 H2O (l)

VA= 100ml
V= 1L c= 0.1mol/L
25C°
t(s) 10 20 30 40 50 60 70 80 90 100
P(CO2)x102(Pa) 12.5 22.8 33.2 41.2 48.8 55.6 60.9 65.4 69.4 71.47
X(mol)
R=8.31 SI n(CO2) 1
n(CO2) X 2
3
t X 4
t = 50s t=0 0
+
H3O 6

CH3-Cl (aq) + H2O(l) = CH3OH(aq) + H+(aq) + Cl-(aq)

+
H Cl- H+ Cl-
0.1mol/L v= 60ml t=0

t(min) 0 2 4 6 8 10 12
𝝈 0 0.012 0.020 0.025 0.028 0.030 0.030
X(mol)
1
𝝈 (t) 2
3
𝝈 (t) Xmax X(t) 4
X=f(t) 0
t=4min 6