DATOS

LOG
[Hg+2] 0.01 -2
[HS-] 0.01 -2
[SO4-2] 0.01 -2
F 96500 (aqu eous species only)
R 8.314 [ S O 4 2 ] T O T = 1 0 .0 0 m M [P b4
[ H S ] = 1 0 .0 0 m M [P b2
2.303 TOT

T1 2
25°C 298.15

/ V
DATOS: MEDUSA 0 H 2S HS S

S H E
E
Compuesto Log K
H2 -3.15 -1
H2S 6.994
Hg 22.301
Hg(HS)2 37.5 -2
2 Hg(OH)2 -6.097 0 5 10 15
3 Hg(OH)3- -21.1 pH

4 HgOH+ -3.4
HgS 26.5 Especie log K
5 HgSO4 1.394 * H2S(a) 6.994
HSO4- 1.98 ** S 2- 12.864
O2 -86.08
O2(g) -83.12
OH- -14
S 2- -12.864
1 Hg(l) 28.854
6 HgS(s) 39.092
S(s) 2.145
REACCIONES BRIN

Sistema
1
2
3
4
5
6
 7

REACC

Sistema
2

(1-6)
 DIAGRAMAS DE POURRBAIX ELA

) (aq ueou s sp eci es o n ly )

mM [P b4 + ] = 0 .1 0 m M [ S O 4 2 ] T O T = 10.00 m M
TOT
mM [P b2 + ] = 0 .1 0 m M
TOT 2

ESHE / V
0 H SO 4 S O 42
H 2S HS S 2

-1

-2
0 5 10 15 20 2 4 6 8
pH t = 2 5 C pH

Reacción Especie log K

H(+a) + HS(-a)=H2S *** HSO4(-a) 1.98
H(+a) + S(-2a)=HS(-a)

REACCIONES BRINDADAS POR MEDUSA

Sistema Hg-S-H2O LOG K

Hg(+2a) + 2e- = Hg(l) 28.854
Hg(+2a) + 2H2O = 2H(+a) + Hg(OH)2 -6.097
Hg(+2a) + 3H2O = 3H(+a) + Hg(OH)3(-a) -21.1
Hg(+2a) + H2O = H(+a) + Hg(OH)(+a) -3.4
Hg(+2a) + SO4(-2a) = HgSO4 1.394
Hg(+2a) + HS(-a) = HgS + H(+a) 39.092
 2Hg(+2a) + 2H2O + 2e- = Hg2(OH)2 + 2H(+a) 25.538

REACCIONES FORMADAS

Sistema Hg-S-H2O LOG K

Hg(+2a) + 2H2O = 2H(+a) + Hg(OH)2 -6.097 L
Hg(OH)2 + H2O = H(+a) + Hg(OH)3(-a) -15.003
Hg(l) + HSO4(-a) + 7H(+a) + 6e- = HgS + 4H2O 42.793 LogK = Log[HgS] + 7pH + 8pe - Log[HSO4
8e- + Hg(OH)2 + SO4(-2a) + 10H(+a) = HgS + 6H2O 46.910 LogK = Log[HgS] + 10pH +8pe - Log[Hg(OH)2] - L
Hg(OH)3(-a) + SO4(-2a) + 11H(+a) + 8e- = HgS + 7H2O 59.933 LogK = Log[HgS] + 8pe + 11pH- Log[(Hg(OH)3)-] - L
SO4(-2a) + Hg(l) + 8H(+a) + 6e- = HgS + 4H2O 9.979 LogK = Log[HgS] + 6pe + 8pH - L
HgS + 2H(+a) + 2e- = H2S(a) + Hg(l) -3.244 LogK = 8pe + 11pH- Log[(Hg(OH)3)-] - L
HgS + H(+a) + 2e- = HS(-a) + Hg(l) -10.238 LogK = Log[H2S(a)] - Log[HgS]
HgS + 2e- = S(-2a) + Hg(l) -23.102 LogK = Log[HS-] - Log[HgS
LogK = Log[S(-2)] - Log
S DE POURRBAIX ELABORADOS CON MEDUSA

y)
0 mM [ H S ] T O T = 10.00 m M

SO 4 S O 4 2

2 4 6 8 10 12
pH t = 2 5 C

Reacción
HSO4(-a)=H(+a)+SO4(-2a)

HSO4(-a) + 9H(+a) + 8e-= H2S(a) + 4H2O

 pe ph
LogK = -2pH 0 3.0485
LogK = -pH 0 15.003
HgS] + 7pH + 8pe - Log[HSO4-] - Log[Hg] LogK = 7pH + 8pe - Log[HSO4-]
0pH +8pe - Log[Hg(OH)2] - Log[SO4(-2)] LogK = 10pH +8pe - Log[SO4(-2)]
+ 11pH- Log[(Hg(OH)3)-] - Log[SO4(-2)] LogK = 8pe + 11pH- Log[SO4(-2)]
= Log[HgS] + 6pe + 8pH - Log[SO4(-2)] LogK = 6pe + 8pH
+ 11pH- Log[(Hg(OH)3)-] - Log[SO4(-2)] LogK = 8pe + 11pH- Log[SO4(-2)]
ogK = Log[H2S(a)] - Log[HgS] + 2pH + 2pe LogK =2pH + 2pe
LogK = Log[HS-] - Log[HgS] + pH + 2pe LogK = pH + 2pe
LogK = Log[S(-2)] - Log[HgS] + 2pe LogK =2pe
 Eh (Volts) S - H2O - System at 25.00 C
2.0

1.5

HSO4(-a) SO4(-2a)
1.0

0.5
S
0.0

-0.5

-1.0 H2S(a)
HS(-a)

-1.5 S(-2a)

H 2 O L im it s
-2.0
0 2 4 6 8 10 12 14 16 18 20

C:\HSC6\EpH\S25595.iep pH

ELEMENTS Molality Pressure

S 1.000E-02 1.000E+00

[ S O 4 2 ] T O T = 10.00 m M
[ H S ] T O T = 10.00 m M [H g2+]T OT = 0.10 m M

H g 2+
H g (O H ) 2

1 H g (O H ) 3 
E SHE / V

0 H g S (s )

-1
H g (l)

-2
0 5 10 15 20
pH t = 2 5 C
-2
0 5 10 15 20
pH t = 2 5 C