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ECOCERA
The Best Chimney Lining Maker

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For making the environment better
For making the earth clean
For promising future to following generations

Ⅱ. Application Information
(GI-180 Block Lining System)

Many well-known plants in the world are equipped with ECOCERA


GI-180 Block Lining System, of which quality is recognized by our
world-wide customers and clients.

ECOCERA CO., LTD.


II. Application Information – Record of Revision

Record of Revision

II. Application Information

Rev. No. Date Revised Section Revised Contents Confirmed

Rev.1 Aug 26, 2019 I. EAS1 Temperatures, Application

Rev.1 Aug 26, 2019 Detail Drawings Update image

ii. Inspection &


Rev.2 Mar 02, 2020 Product Shelf Life
Test Plan at Site

Rev.2 Mar 02, 2020 MSDS (Epoxy Primer) Health Hazard Identification

Document Code, Product


Rev.3 Mar 24, 2020 Overall
Name, outline, product color
i.EIS & ii.EIP
Recommended mixing
Rev.4 May 06, 2020 GI-200 Adhesive Membrane
temperature
GI-181 Epoxy Primer
[EIS-0] General Information
clean-up procedures and
Rev.5 June 19, 2020 for Surface Preparation,
Pysical of Epoxy Primer
MSDS(Epoxy primer)
Revised the format of EIP30,
Rev.6 Aug 10, 2020 EIP30, EIP31
EIP31

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II. Application Information – Description of the Terms

Description of the Terms

II. Application Information


Terms Description
GI-180 /
1 Borosilicate Cellular Glass Block
GI-180 Block
GI-200 /
2 GI-200 Adhesive Membrane / Adhesive Membrane
GI-200 Ad/Membrane
GI-200A /
3 Adhesive Membrane (Resin)
GI-200 Part A
GI-200B /
4 Adhesive Membrane (Hardener)
GI-200 Part B
GI-181 /
5 Epoxy Primer
GI-181 Epoxy Primer
GI-181A /
6 Epoxy Primer (Resin)
GI-181 Part A
GI-181B /
7 Epoxy Primer (Hardener)
GI-181 Part B

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II. Application Information – Document Code

Document Code
II.Application Information
Document
Chapter Name Description
Code
General Information for surface preparation EIS-0

EIS Instructions for GI-181 Epoxy Primer EIS-1


(Ecocera Installation
Specfication) Instructions for GI-200 Adhesive Membrane EIS-2

Detail Drawings of GI-180 Block Application EIS-3

Inspection of Materials at Jobsite EIP-1

Inspection of Substrate after Flue Can Set-up & Welding EIP-2

Inspection of Surface Preparation in Sand Blasting Process EIP-30

EIP Inspection of Ceramic (Cement Concrete, Refractory) Surface EIP-31


(Ecocera Inspection
Procedure at site) Application & Inspection of GI-181 Epoxy Primer EIP-4

Application & Inspection of GI-180 Block Lining System EIP-5

Procedure for Final Report EIP-6

Final Report EIP-7

GI-180 Block (Borosilicate Cellular Glass Block) EMSDS-1

GI-200A Adhesive Membrane (Resin) EMSDS-21


EMSDS
(Ecocera Material GI-200B Adhesive Membrane (Hardener) EMSDS-22
Safety Data Sheet)
GI-181A Epoxy Primer (Resin) EMSDS-31

GI-181B Epoxy Primer (Hardener) EMSDS-32

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GI-180 Block Lining System - Contents

CONTENTS

ⅰ. EIS (ECOCERA Installation Specification) ---------------------------------------------------- 2


1. [EIS-0] General Information for surface preparation ----------------------------------- 3
2. [EIS-1] Instructions for GI-181 Epoxy Primer ----------------------------------- 15
3. [EIS-2] Instruction for GI-200 Adhesive Membrane (Mixing) --------------------- 20
4. [EIS-3] Detail Drawings of GI-180 Block Application ----------------------------- 21

ⅱ. EIP (Ecocera Inspection Procedure at site) ----------------------------------------------- 38


1. [EIP-1] Inspection of Materials at Jobsite --------------------------------------------- 39
2. [EIP-2] Inspection of Substrate after Flue Can Set-up & Welding --------------- 48
3. [EIP-3] Inspection for Surface Preparation in Sand Blasting Process -------------- 54
[EIP-31] Inspection of Ceramic(Cement Concrete, Refractory) Surface ------------- 60
4. [EIP-4] Application & Inspection of GI-181 Epoxy Primer ------------------------ 64
5. [EIP-5] Application & Inspection of GI-180 Block & GI-200 Ad/Membrane -- 71
6. [EIP-6] Procedure for Final Report --------------------------------------------------- 79
7. [EIP-7] Final Report ---------------------------------------------------------- 83

ⅲ. EMSDS (Ecocera Material Safety Data Sheets) ----------------------------------- 92


1. [EMSDS-1] GI-180 Block (Borosilicate Cellular Glass Block) ------------------ 93

2. [EMSDS-21] GI-200A (Adhesive Membrane, Resin) ---------------------------------- 98


3. [EMSDS-22] GI-200B (Adhesive Membrane, Hardener) ------------------------------ 106
4. [EMSDS-31] GI-181A (Epoxy Primer, Resin) ------------------------------------------ 114
5. [EMSDS-32] GI-181B (Epoxy Primer, Hardener) -------------------------------------- 124

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GI-180 Block Lining System

[EIS] Ecocera Installation Specification

ⅰ. EIS
(Ecocera Installation Specification)

1. EIS-0 : General Information for surface preparation ---------------- 3

2. EIS-1 : Instructions for GI-181 Epoxy Primer ------------------------ 15

3. EIS-2 : Instructions for GI-200 Adhesive Membrane –Mixing -- 20

4. EIS-3 : Detail Drawings of GI-180 Block Application -------------- 21

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GI-180 Block Lining system - Ecocera Installation Specification
[EIS-0] General Information for Surface Preparation

[EIS-0] General Information for Surface Preparation

For a good installation of the GI-180 Block Lining System, all workers have to learn and
practice enough how to work prior to the installation. For actual field inspection, the
affiliated EIP (Ecocera Inspection Procedure at site) with this EIS is applied.

1. Application filed

1.1 This specification covers the recommended installation, quality control, and inspection guidance
for the successful installation of the GI-180 Block Lining System on metal, concrete, brick, and
FRP surfaces.
1.2 At coal power plants, the GI-180 Block Lining System is used to protect carbon steel liners,
heat recovery equipment, and inlet/outlet duct work of wet FGD scrubbers from condensate
permeation and acid corrosion. It is used in flue gas conveying equipment such as stacks and
ductwork serving the power, chemical, metallurgical, petrochemical, pulp & paper and municipal
waste incineration/sludge burning industries, to protect the substrate structures from acid
corrosion.
1.3 FRP-constructed stacks, ducts, and other equipment, when lined with the GI-180 Block Lining
System, can operate at higher temperatures due the insulation characteristics of this lining
system.
1.4 The GI-180 Block Lining System offers an acid corrosion resistant, light-weight, highly
insulation lining for steel and concrete tanks and vessels including the covers of molten sulfur
its, acid pickling tanks, and acid storage tanks.
1.5 The GI-180 Block Lining System may be used as a chemical resistant backup to refractories
and chemically resistant masonry/monolithic linings in such areas as hot gas inlets to chemical
vessels, petrochemical heaters and furnaces.

2. General

2.1 This specification is organized to first cover steps that are the same independent of the
substrate type or design. The later sections provide information specific to a particular substrate
design or component.
2.2 The GI-180 Block Lining System can be applied to many different surfaces. The system has
been used successfully in power plant applications in flue gas ducts and chimneys that are
constructed of many types of materials with varying designs.
2.3 Care in handling and storage of GI-180 Block made by glasses, therefore can be susceptible to

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GI-180 Block Lining system - Ecocera Installation Specification
[EIS-0] General Information for Surface Preparation

damage if care is not taken to prevent such damage during handling and installation.
2.4 The lining system when properly installed and cured is quite strong. However, excessive particulate loading,
gas velocities exceeding 24-30m/s and potential for unexpected mechanical damage, (i.e. routine outages and
inspections) must be designed with ECOCERA for specific applications.
2.5 When construction and maintenance activities will take place near or on a lined surface, efforts
shall be made to cover the surface to prevent mechanical damage. Areas of known risk of
mechanical damage such as near routine maintenance activities should be covered with a
permanent layer to prevent damage to the liner. Coverings such as gunite, cement concrete
have been used effectively for such areas.
2.6 When appropriate, the following sign shall be posted on the exterior of the structure during and
after lining application. "Lined equipment, no welding or burning".
2.7 Do not impale the installed GI-180 Block Lining System with welding rods or other sharp or
pointed devices as a convenient way to hang cords or wires for temporary lighting during
outages or other maintenance activities.

3. Equipment / etc, Supplies

3.1 Heavy duty variable speed drills, having 16-18mm chucks with sufficient torque to deliver a
minimum speed of 230rpm under load. For mixing, ECOCERA recommends the use of a Jiffler
mix blade-Model DC312 with 2x165mm propeller blades to mix the Adhesive Membrane. Blades
shall be set with dimensions of 125mm from the base of the bottom of the blade (sitting on a
flat surface) to the top of the ferrule on the top blade. Use of other mixing equipment may
adversely affect mix results and product performance. Use of any other equipment shall only be
authorized following consultation and written approval of ECOCERA.

3.2 Can use wood saws and rasps, to cut and sculpt the glass block.
3.3 Masons' trowels of a size approximately 200mm long x 383mm at the heel with end blunt to
approximately 20mm radius to apply the Adhesive Membrane.

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[EIS-0] General Information for Surface Preparation

3.4 Before working, recommend to use skin protector for workers.


3.5 100 mm wide stiff bristled paint brushes, paper coveralls, Playtex dishwashing gloves, rags,
wire brushes.
3.6 Use mineral spirits, like the thinner, for cleaning and soaking trowels, etc., for loosening cured
GI-200 Adhesive Membrane.
3.7 Set of installation specifications, and latest product information sheets for all lining materials of
construction.
3.8 etc, Supplies: Portable psychrometer or dew-point meter, calibrated electronic temperature meter,
lights, surface thermometers, white(non-wax) marking chalk or white spray paint.

4. Temperatures

4.1 The product and substrate temperatures are very important factor for a good installed GI-180
Lining System. In cold winter conditions it is recommended that the product storage and
construction area be heated to achieve and maintain the temperatures identified in sections 4.2
and 4.3.
4.2 Recommended mixing temperature of Main material (GI-200A, Resin) and the curing agent
(GI-200B, Hardener) is more than 10°C.
4.3 The temperature of the prepared surface shall be at least 3℃ above the moisture dew point and
at a temperature between 4℃ and 36℃ at the time the GI-180 Block Lining System is
applied.
4.4 Be aware of the temperature of the substrate to be sure that the GI-200 Adhesive Membrane
does not set up too quickly and, hence, lose its wet tack. Wet tack is if Membrane comes off
onto the finger when touched. When properly mixed and applied GI-200 Adhesive Membrane
will remain tacky for approximately 4(four) hours at an ambient air temperature and no more
than one hour at 32℃.
4.5 Weather protection of the work site is necessary. The prepared substrate must be protected from
the elements until the lining work is completed.
4.6 In addition to protection the work area from the elements, the cartons of GI-180 Block and
containers of GI-200 Adhesive Membrane and GI-181 Epoxy Primer shall be protected.

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[EIS-0] General Information for Surface Preparation

5. Mixing

5.1 Remove the lid from the GI-200 Adhesive Membrane steel can. Inspect for damage incurred
during transit.
5.2 Insure that there are no leaks in the Component B container and that there is no water present
on or in Component A.
5.3 Utilizing a drill, delivering sufficient torque to achieve a shaft rotation of a minimum 300rpm,
and the proper mixer blade as specified in section 3.1, premix for homogeneous, Component A
by itself for a minimum of one minute. If temperatures are below 10℃, mix component A for
a minimum of 5 minute.
5.3.1 A good manual mixing technique involves movement of the rotating blade within the pail.
Move the blade around the base of the pail in a circular motion and also lift the blade from
the base above the surface of the compound and continue the circular motion around the side of
the pail. During mixing also hold the mix blade occasionally at a 30 to 45 degree angle within
the mixture, to insure all contents of the pail are thoroughly mixed, paying close attention to
contact all surfaces of the sides of the pail with the mix blade.
5.3.2 For mass mixing per once or more a good mix, automated mixing machines specifically
designed for this purpose can also be used to mix GI-200 Adhesive Membrane. Consult
ECOCERA for more details. (Refer to GI-200 Mixing Machine)
5.4 Open Component B. Continue to mix Component A at the recommended speed. Begin pouring
Component B into the vortex created by the mixer in Component A. Total elapsed time for the
addition of the component B should be 15 to 20 seconds while mixing.
5.5 Mix components both A and B for 5 minutes using a good mixing technique to yield an
uniform mix. When the ambient temperature is lower than 5℃, mix for more than 10 minutes
using a good mixing technique to yield an uniform mix. After mixing, leave it for approx. 5
minutes for its stability to remove bubble gas in mixed Membrane. This mixing and mixing time
is very important and will not harden for a very long time if not properly mixed.
5.6 The GI-200 Adhesive Membrane is a thixotrope i.e. It will thicken if allowed to sit after the
components have been mixed together. Material is generally ready for use immediately after
mixing.
5.7 Improper mix techniques and/or use of mixing equipment other than recommended in section
3.1 may adversely affect mix results and products performance. Use of any other equipment or
mixing techniques shall only be authorized following consultation with and written approval of
ECOCERA. Note carefully sections 5.3.1 and 5.3.2.

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[EIS-0] General Information for Surface Preparation

6. Installation

6.1 Substrate or cut the standard size block being used which, in turn, will minimize the effect of
the substrate variation and allow a full bond of the block to the substrate surface using the
GI-200 Adhesive Membrane. A comparable check shall also be applicable to lining curved
surfaces.
6.2 Trowel apply a minimum 1.5 mm thickness of Adhesive Membrane onto the substrate with a
suitable trowel carrying the coverage to approximately 50mm beyond the area of the GI-180
Block will cover when it is placed in position. The size of the area to which the Adhesive
Membrane is applied at any one time shall be no greater than will allow the area to be lined
with the GI-180 Block before the Adhesive Membrane on the substrate loses its tackiness. Do
not trowel to less than 1.5 mm thickness. The substrate must be fully lined.
6.3 Trowel a minimum of 1.5mm thickness of the Adhesive Membrane onto the back, and all sides
of the GI-180 Block to be installed. In positioning the GI-180 Block against the GI-200
Adhesive Membrane applied to the substrate surface, move the block back and forth at least
50mm a couple of times as it is being slid into place against the adjacent block so as to
remove voids between the block and the surface. The recommended film thickness between the
block and steel surface shall be 3mm ~ 5mm, between the block and block shall be 2mm ~
5mm but install as close to 2 mm as possible. GI-200 Adhesive Membrane shall totally fill side
joints, and shall be seen to 'bead' along edges. Strike clean the surfaces of joints of GI-200
Adhesive Membrane squeezed out during placement of the block. Listen for the sound of block
scraping against GI-180 Block or the substrate. This is a sure indication of insufficiently filled
side joints.
6.4 In placing successive GI-180 Blocks, it is acceptable to leave one or more sides without
Adhesive Membrane and subsequently apply the Adhesive Membrane to these sides when they
are on the substrate prior to placing the next block up against this block edge. The intent is to
utilize a double buttering technique. No block surface is to be put into final position without
Adhesive Membrane applied with a trowel on that surface first.

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[EIS-0] General Information for Surface Preparation

6.5 It is very important that the GI-180 Block, coated with GI-200 Adhesive Membrane, has full
contact with the Adhesive Membrane applied to the substrate surface, whether it be flat floors,
side walls, overhead areas, curved surfaces, nozzles, etc. No voids shall be left between the
block and the substrate. Cut the block and create an extra joint when necessary and/or increase
thickness of the Adhesive Membrane back joint. Back joint must be full joints, and shall not be
less than 3 mm thick.
6.6 Installer shall exhibit care in the handling and placement of the blocks so as to minimize the
presence of excess Adhesive Membrane on the face of the block. Side joints shall be struck
clean after installation, with attention to removing excess material from the face of the block.
Before moving to a new work area or at appropriate times such as shift changes or
scaffold/platform movements, inspectors shall thoroughly inspect surface to detect presence of any
excess Adhesive and direct that it is to be removed promptly.
6.7 If the applied Adhesive Membrane is still tacky to the degree that when touched it blackens a
gloved finger, additional Adhesive Membrane can be applied over it, to continue installing
GI-180 Block. However, If it has cured to the point of not staining a glove when touched, it
must be removed. This can be accomplished by using scrapers to remove as much remaining
GI-200 Adhesive Membrane as practical. Use care to confirm scraping does not damage the
block. This procedure is critical since wet GI-200 Adhesive Membrane will not bond well to
cured Adhesive Membrane.
6.8 As noted in section 6.7, wet Adhesive Membrane does not bond well to cured Adhesive
Membrane. The gloved finger tack test outlined in section 6.7 should be utilized to determine if
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[EIS-0] General Information for Surface Preparation

work can carry on after a work stoppage without further treatment. Cured Adhesive Membrane
that does not pass the gloved finger wet tack test must be abraded to roughen the surface and
remove surface gloss. Dry remnants of cured Adhesive Membrane remaining on a block surface
at the end of a shift shall be dealt with by cutting back the block surface to expose a clean
cell structure on the leading edge of the block.
6.9 When work stoppage is anticipated, remove as much of the Adhesive Membrane as practical
from the substrate and edges of the completed lining that will have additional lining when the
stoppage ends.
6.10 Do not install blocks that are cracked, have gouges, or other imperfections in them. Also, do
not install blocks with cracked corners, etc.
6.11 Staggered or broken bond construction is recommended to minimize four corners meeting and
the possibility of a corner void. Running bond may be more desirable for gas flow purposes.
Contact ECOCERA if this is a concern.
6.12 If partial Blocks are used, the minimum size shall be a one third piece of block. If the
remaining gap is less than a half block, adjust the dimension of the final two blocks.

7. Stop bars, Man hole, Expansion joint etc.

7.1 The GI-180 Block Lining System should not be finished to a free edge. It is recommended to
install proper retaining (stopper) angles or flat bars to ensure proper installation. The height of
the stopper should be the full lining thickness. The stop bar shall be of an alloy grade suitable
for the anticipated service. Stop bars should be used if the GI-180 Block Lining System is to
be installed immediate to man way openings, expansion joints, dampers, pipe stubs, sample
ports, gunites, or castable linings.
7.2 To see detail drawings of Ⅰ.products information.

8. Curing

8.1 Intended operating service conditions of the lined component may contribute to the cure of the
system. It most important thing is “Mixing”.
8.2 In general the lining may be placed into service after curing for 2 days at 32℃ or for 72
hours at 21℃, or for 7 days at 10℃.
8.3 GI-200 Adhesive Membrane cures by chemical reaction. At a curing temperature of 21℃, the
applied Adhesive Membrane will develop full strength at 14 days at 21℃.
8.4 Contact ECOCERA for special cure schedules if down time does not allow sufficient curing of
the lining as outlined in section 8.2 above.
8.5 Consult ECOCERA if initial start up temperatures may exceed 120℃.
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GI-180 Block Lining system - Ecocera Installation Specification
[EIS-0] General Information for Surface Preparation

9. Inspection / Qualification

9.1 The mixing, curing, and adhesion characteristics of GI-200 Adhesive Membrane shall be
evaluated by applying it onto a test area of the same material and surface preparation of the
production substrate. Work life and initial set time may be visually observed. Work life is the
maximum time the Adhesive Membrane remains trowel. Initial set time is defined as the time
between mixing Adhesive Membrane and when it begins to exhibit cohesiveness, i.e. the time
when the surface of the Adhesive Membrane is no longer wet to the touch. Cure must be
uniform.
9.2 The installation procedure of the lining system shall be verified by using Inspection cards as
supplied for the project. Cards should be retained throughout the duration of the project to
insure cure of all applied batches.
9.3 Inspectors shall determine the frequency of random site checks to determine back joints have
complete contact by pulling random Blocks while the Adhesive Membrane is still wet and
visually verifying the back joint and side joints are completely full.

10. Records

10.1 Inspection cards as outlined in section 9.2 should be retained throughout the duration of the
project to insure cure of all applied batches.
10.2 Inspector shall sketch areas lined and which he inspected, and note his observations.
10.3 A photographic history of surface preparation, primer application, Adhesive Membrane
application, and block installation is suggested.

11. Repair of mechanically damaged areas

11.1 Experience indicates that repair of an area smaller than a standard size block requires more
effort than a larger area.
11.2 Cut out a minimum of a full block down to membrane on substrate. Remove remaining
membrane on substrate as best as possible to expose underlying substrate. Clean the GI-200
Adhesive Membrane per Section 6.8 and 6.9. Install block(s) per Section 6.2 and 6.3.

12. Specific substrate 1 - metal, carbon steel, stainless steel, nickel alloys
12.1 Surface Preparation

12.1.1 All welds shall be continuous. Intermittent or spot welding shall not be permitted.

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GI-180 Block Lining system - Ecocera Installation Specification
[EIS-0] General Information for Surface Preparation

12.1.2 All weld spatter slag and old anchor welds shall be removed from the substrate, and the
area ground flush with the parent metal.
12.1.3 Gross pinholes, pits, blind holes, porosity, undercutting, or similar depressions should not
exist in the finished surface of the weld before or after blast cleaning.
12.1.4 All edges and fillets and similar abrupt contours shall be rounded off smoothly by grinding
or machining. A 3mm radius is preferable. Smooth ripple finished welds are acceptable.
12.1.5 Plates welded together shall be properly aligned; butt welded joints are preferred.
12.1.6 Lap welded joints should be avoided wherever possible. If lap welded joints are used, they
must be fully welded on the inside.
12.1.7 All connections to the equipment being lined shall be flange.
12.1.8 Structural reinforcement members should be installed on the vessel exterior, if possible.
However, if such members are installed internally, they should be fabricated of simple shapes
such as smooth round bars or pipe for ease of applying the lining material. The use of
angles, channels, l-beams, and other complex shapes should be avoided. If they must be
installed internally, these members shall be fully seal welded and edges ground.

12.2 Surface Cleaning

12.2.1 Unless otherwise specified in writing by ECOCERA, a near white metal blast finish (as
specified by most current revisions of ISO 8501-1 or SA 2.5) is required for preparing
carbon steel surfaces to receive the Lining.

12.2.2 New stainless titanium and nickel alloys (metal surfaces) must be abrasive blast cleaned to
achieve a minimum profile of 35㎛ and to remove any oxidation layer. Deteriorated, pitted,
corroded stainless and nickel alloys must be cleaned and prepared to a sound base. All
surfaces must be dust, dirt, and grease free. Any foreign material which will interfere with
adhesion must be removed.

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[EIS-0] General Information for Surface Preparation

12.3 Priming for steel substrates – GI-181 Epoxy Primer

12.3.1 To prohibit the formation of re-rusting after blasting and rust bloom, carbon steel should be
primed with GI-181 Epoxy Primer. All stainless titanium and nickel alloys shall also use
Primer for best adhesion.
12.3.2 Mixing instructions: GI-181 Epoxy Primer is mixed in a normal ratio of 1 Part "A" to 1
Part "B". It is packaged in pre measured containers.
12.3.3 Thoroughly mix the contents of the Part "A" (4 kgs) component. Thoroughly mix the
contents of the Part "B" (1.6 kgs) component.
12.3.4 Pour the entire contents of the Part "B" container into the Part "A" component. Thoroughly
mix the combined Part A/B mixture and allow it to stand for 15 minutes.
12.3.5 Thoroughly stir the mixture before starting application.
12.3.6 A pot-life of primer (ref, I. Products information).
12.3.7 All abrasives and dust must be removed from the substrate in accordance with the most
recent revision of ISO 8502-3 prior to priming. The use of a power vacuum is recommended.

12.3.8 Spray application is preferred, although brush or roller application is acceptable. Consult
ECOCERA if temperatures during spraying are over 32℃.
12.3.9 Application should be accomplished in a single wet pass with a 50% overlap.
12.3.10 Hold the spray gun at right angles to the surfaces and about 8-12" away from the
substrate.
12.3.11 Make even, parallel passes applying Primer at a rate of 0.1~0.2Kg/sqm insuring substrate is
uniformly covered. WFT(Wet Film Thickness) testing is not practical with GI-181 Epoxy
Primer. A visual check along with consumption monitoring is the best method to determine
correct coverage.

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[EIS-0] General Information for Surface Preparation

12.4 GI-181 Epoxy Primer Clean-up procedures

Equipment should be thoroughly cleaned with : MEK, Xylene, or Toluene after use. Read
and follow manufacturer's MSDS's and safety precautions when handling these chemicals.
12.4.1 High velocity air and good ventilation help to remove solvents and accelerate drying.
High humidity slows curing. The Primer dries in about 8 hours at 22℃ and 6.5 hours
at 32℃. Use a fingernail scratch test to insure Primer is cured hard before proceeding.
12.4.2 The Primer must dry hard before application of the GI-200 Adhesive Membrane is allowed
to begin, as any solvents remaining in the uncured primer will affect the cure of the GI-200
Adhesive Membrane.
12.4.3 The detailed Installation of Epoxy Primer reference to "IGI-181"

13. Specific substrate 2 - Concrete & brick substrates

13.1 Surface Preparation

13.1.1 The surface condition of new and/or existing concrete and brick liners can vary greatly. The
surface should be thoroughly inspected to identify the condition and suitability of the surface
to accept the GI-180 Block Lining System. An assessment and evaluation of the suitability
of the surface and the unique circumstances found for the specific concrete or brick lining
should precede quotations, procurement, or mobilization of installation worker. Any buildup,
deposits, carry over, or mortar on concrete or brick must be removed.
13.1.2 When forms have been used for placing the concrete, they should be designed so as to yield
a smooth continuous concrete surface to which the lining will be applied. See also section
13.1.6.
13.1.3 Concrete floors should have a single pass trowelled finish with special care being taken to
avoid bringing laitance to the surface.
13.1.4 New concrete shall reach a minimum compressive strength of 20 MPa and a surface tensile
strength of 2.0 MPa before the lining is applied. Curing compounds must either be removed
or tested for compatibility before proceeding.
13.1.5 Before acceptance for lining, all form marks and protrusions, such as prominent aggregate
exposure, tie wires, reinforcing wire, stirrups, etc. must be cut off and ground flush with the
surface.
13.1.6 All cavities, stone pockets, honeycombing, and bug holes greater than 6 mm depth shall be
filled by repairing with appropriate materials.
13.1.7 Damage to the existing structure such as cracks or other structural damage is to be suitably
repaired prior to the application of the GI-180 Block Lining System.
13.1.8 Existing concrete surfaces to be lined with the GI-180 Block Lining System shall be tested

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for suitable strength and verified to be structurally sound.


13.1.9 For installations onto brick liners, if the offset between adjacent bricks is greater than 3 mm,
the nature and size of the surface irregularity will dictate the actions to properly prepare the
surface. For a corbeled area where individual brick courses are intentionally offset consult
ECOCERA for specific details.
13.1.10 If mortar joints exist in brick substrates that are not completely filled, but brickwork is
structurally sound and joints are not greater than 6mm then Adhesive Membrane can be used
to fill those areas. Joints wider than 6mm shall be appropriately addressed before glass block
application.
13.1.11 Attachments to the brick substrate (i.e. liquid condensate collection (LC) systems and
stop-bars) shall be installed without leaving any gaps in between the brick substrate and the
attachment to be used to level the area behind attachments prior to final installation of such
attachments. The leveled area behind LC systems shall have a vertical dimension greater than
the width of the condensate collection plate to be bolted to the substrate.

13.2 Surface Cleaning

13.2.1 A brick liner surface to which the lining is to be applied shall be suitably high pressure
water cleaned and abrasive blasted in order to clean the brick faces and mortar to provide a
sound hard clean surface. Contaminants must be removed and the surface shall be pH
neutral. Consult ASTM D4258 and D4262. The intent is to remove sufficient material to
achieve a sound surface free of contaminants.
13.2.2 A concrete surface to which the lining is to be applied shall generally be prepared in
accordance with ASTM D4259(most current revision) "Abrading Concrete". The surface shall
have a non-glazed appearance. The intent is to remove sufficient material in order to achieve
a sound concrete surface free of laitance, glaze, efflorescence, and incompatible concrete
curing agents or form release agents.
13.2.3 All surfaces must be dust, dirt, and grease-free. Any foreign material which will interfere
with adhesion must be removed. All abrasives and dust must be removed from the substrate
in accordance with the most recent revision of ISO8502-3 prior to priming. The use of a
power vacuum is recommended.

13.3 Priming for Concrete and Brick Substrates

13.3.1 GI-181 Epoxy Primer serves to seal and promote adhesion of GI-200 Adhesive Membrane.
Consult Product Data Sheet GI-181 and IGI-181 for complete product details.

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GI-180 Blcok Lining System - ECOCERA Installation Specification
[EIS-1] Information for GI-181 Epoxy Primer

[EIS-1]
Information for GI-181 Epoxy Primer

Carbon Steel Ceramic surface

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GI-180 Blcok Lining System - ECOCERA Installation Specification
[EIS-1] Information for GI-181 Epoxy Primer

[EIS-1] Information for GI-181 Epoxy Primer

1. Scope

1.1 This specification is about installation of the GI-181 Epoxy Primer.


1.2 GI-181 Epoxy Primer is an industrial lining system most typically used as one of the
components of the GI-180 Block Lining System. The EIS (Ecocera Installation Specification) :
Construction Specifications, covers the installation of the GI-180 Block Lining System for
further details on the installation of the other components of the system.

2. Surface preparation

2.1 All welds shall be continuous. Intermittent or spot welding shall not be permitted.
2.2 All weld spatter, slag and old anchor welds shall be removed from the substrate, and the area
ground flush with the parent metal.
2.3 Gross pinholes, pits, blind holes, porosity, undercutting, or similar depressions should not exist
in the finished surface of the weld before or after blast cleaning.
2.4 All edges and fillets and similar abrupt contours shall be rounded off smoothly by grinding or
machining. A 3mm radius is preferable. Smooth ripple finished welds are acceptable.
2.5 Plates welded together shall be properly aligned; butt welded joints are preferred.
2.6 Plates welded joints should be avoided wherever possible. If lap-welded joints are used, they
must be fully welded on the inside.
2.7 All connections to the equipment being lined shall be flange.
2.8 Structural reinforcement members should be installed on the substrate exterior. If such members
are installed internally, they should be fabricated of simple shapes such as smooth round bars
or pipe for ease of applying the lining material. The use of angles, channels, l-beams, and
other complex shapes should be avoided. If they must be installed internally, these members
shall be fully seal welded and edges ground.
2.9 Unless otherwise specified in writing by ECOCERA or its representative, a near-white metal
finish (as specified by most current revisions of, ISO8501-1 or SA 2.5) is required for
preparing carbon steel surfaces to receive the lining. The resultant surface profile after grit
blasting to achieve the near-white finish typically falls in the range of 35~50㎛, but this is not
a hard and fast specification requirement. Variability with the size, shape, and composition of
available local blast media may result in the achievement of the required cleanliness standard,
while simultaneously producing a blast profile that may fall outside of this range.
2.10 New stainless steel, titanium, and nickel alloys (metal surfaces) must be abrasive blast cleaned
to achieve a minimum profile of 35㎛ and to remove any oxidation layer. Deteriorated, pitted,
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GI-180 Blcok Lining System - ECOCERA Installation Specification
[EIS-1] Information for GI-181 Epoxy Primer

corroded stainless and nickel alloys must be cleaned and prepared to a sound base. All surfaces
must be dust, dirt, and grease free. Any foreign material which will interfere with adhesion must
be removed.
2.11 All abrasives and dust must be removed from the substrate in accordance with the most recent
revision of ISO 8502-3 prior to priming. The use of a power vacuum is recommended.

3. Mixing instructions (Part A, Resin & Part B, Hardener)

3.1 Mixing instructions: GI–181 Epoxy Primer packaged with pre-measure containers. It is the part
"A" component is packaged in 4 kgs steel container, and the Hardener Part "B" component is
packaged in 1.6 kgs steel container. i.e, Mixing ratio is GI-181A(4 kgs) : GI-181B(1.6kgs) by
weight. Use one container each.
3.2 Recommended mixing temperature of Main material (GI-200A, Resin) and the curing agent
(GI-200B, Hardener) is more than 10°C. Mix Part A by itself for at least one minute. Shake
Part B well and add entire contents to Part A. Mix them for at least three minute, at 21°C,
using a heavy-duty electric, or air operated drill. At cooler temperatures, mix material for a
longer period of time period of time. (up to 3-4minutes at upper 15°C-300rpm/min, more than 5
minutes at below 5°C-300rpm.)
Never mix the amount more than can be applied in 40minutes. Work life is 40-50 minutes at
25°C. Work life will vary depending on temperature. (Refer to the I. Product Information -
GI-181 Epoxy Primer)
3.3 Smaller quantities may be mixing ratio is part A (4 kgs), part B (1.6 kgs) by weight.
3.4 Allow mixed material to stand for and induction period of 15 minutes.
3.5 Thoroughly re-stir the mixture before starting application.
3.6 Never add water or other materials to the mix.
3.7 Spray application is preferred, although brush or roller application is acceptable. When installing
by brush, use a nylon/polyester or natural bristle. When applying by roller, use a 9.0 mm
woven roller with a phenolic core.
3.8 Clean tools with MEK immediately after use and Keep containers tightly sealed. Store in a cool
dry place out of direct sunlight.

4. Application

4.1 Application shall be performed within a recommended substrate temperature range of 4~35℃.
Temperatures must be maintained at least 4℃ above the moisture dew point, and relative
humidity must be maintained below 90%. Work environment of the job site shall be controlled

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GI-180 Blcok Lining System - ECOCERA Installation Specification
[EIS-1] Information for GI-181 Epoxy Primer

within this range.


4.2 Application should be accomplished in a single wet pass with a 50% overlap.
4.3 Hold the spray gun at right angled to the surface.
4.4 Primer can be applied at varying covering rates, varying from a rate of 150㎛ Wet Film
Thickness (WFT) to 75㎛ WFT. For most applications where a minimum 35-50㎛ blast profile
has been achieved, it is suggested primer be installed at a nominal thickness of 75~150㎛ WFT.
4.4.1 The ratio of the Wet Film Thickness and Dry Film Thickness (DFT) of the applied primer
has a relationship to its performance and cost. Variables such as the profile of the prepared
steel can be impacted by the blast media used, regardless of the cleanliness standard specified.
All of these factors must be considered in advance of the commencement of work to establish
agreed QA standards and methodologies.
4.5 WFT testing should be performed to monitor specified thicknesses as the job progresses. Film
reduction during curing will reduce the DFT thicknesses of the cured lining when applied at
the thicknesses above by a factor of approximately 50%.
4.6 Suggested- spray equipment : You can choice spray gun and air pressure by viscosity of Epoxy
primer.
4.6.1 Changes in pressure and tip sizes may be needed for proper automation.
4.7 GI-181 Epoxy Primer is pre-thinned and further thinning is typically not required. If
circumstances and the expertise of the painter deem that thinning may aid in the spraying of
the material, GI-181 Epoxy Primer can be thinned up to 10% by volume with MEK to assist in
spraying if needed. Do not recommend more than 10%.

5. Curing and recoat

5.1 GI-180 Epoxy Primer cures quickly at temperatures between 18~24℃. High velocity air and
good ventilation help to remove solvents and accelerate drying. High humidity slows curing. The
Primer should dry to the touch in about 1 hour at 18℃ and will dry hard in 1.5 to 2 hours
depending on humidity and substrate temperature. Use a fingernail scratch test to insure Primer
is cured hard before proceeding.
5.2 Recoat : GI-181 Epoxy Primer is designed to be installed in a single step to the desired
thickness. In the event it becomes necessary to perform re-coating or touch-ups, GI-181 Epoxy
Primer may require surface preparation before these operations can be completed. Material will
reach approximately 80% of its full cure within 72 hours of application, with the remaining
20% attained over a period of 7~14 days. Recoating within the initial 72 hour period does not
require any surface preparation. Once the initial 72 hour period has passed, the coated surface
shall be sanded with a 150~200 grit sandpaper to roughen the coating surface; thus providing a
"tooth" that
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GI-180 Blcok Lining System - ECOCERA Installation Specification
[EIS-1] Information for GI-181 Epoxy Primer

will aid the adhesion of subsequent topcoats.


5.3 The Primer must dry hard to touch before commencing application of the GI-180 Block Lining
System. Do not apply the GI-180 Block Lining System on wet or tacky Primer.
5.4 Primed components that remain exposed to the elements for excessive lengths of time require
the resultant surface marking i.e. chalk to be removed before commencement of re-priming or
subsequent lining work. Wash affected components with clean water and allow to dry before
proceeding with installation of other components of the GI-180 Block Lining System. Pressure
washing may be more efficient to achieve this for larger areas and is acceptable.

6. Sags and runs

6.1 Sags and runs can occasionally be encountered during the installation of GI-181 Epoxy Primer.
While sags and runs are aesthetically unpleasing, they are not necessarily detrimental to the
purpose of the Primer, which is to protect the steel form re-rusting before subsequent Block
lining work. A sag/run however with a thickness > 200㎛ could develop curing shrinkage
stresses that minimizes bond in that area and shall be dealt with.
6.2 To assist in defining a standard for pass/fail for sags and runs the following is noted:
6.2.1 A sag is defined as having a width greater than its height and a height not exceeding 200㎛.
A run is defined as singular bubble-shaped slumps of nominal 3mm width or less and height
of 200㎛ or greater.
6.2.2 Sags and run shall be permitted, provided the DFT thickness is less than 200㎛. Runs should
ideally be "worked out" during installation while the primer is still wet by using a paint brush
or roller to knock down the peaks.
6.2.3 In the event sags or runs in excess of 200㎛ are discovered after the Primer has dried, they
shall be sanded down so they are below 200㎛.

7. Clean up

7.1 Equipment should be thoroughly cleaned with MEK. Read and follow manufacturer's MSDS's
and safety precautions when hand-ling this chemical.

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GI-180 Block Lining System - ECOCERA Installation Specification
[EIS-2] Information for GI-200 Adhesive Membrane - Mixing

[EIS-2] Information for GI-200 Adhesive Membrane - Mixing

1) GI-200 Adhesive Membrane: Part A, Resin & Part B, Hardener

① Recommended mixing temperature of Main material (GI-200A, Resin) and the curing agent
(GI-200B, Hardener) is more than 10°C. Mix Part A by itself for at least one minute. Shake
Part B well and add entire contents to Part A. Mix for five minutes at or above 20°C, using a
heavy-duty electric, or air operated drill. At cooler temperatures, mix material for a longer
period of time period of time (more than 5 minutes at or below 18°C-300rpm/min, up to 10
minutes at or below 5°C-300rpm.)
② Smaller quantities may be mixed at a ratio of part A (17 kgs), part B (0.55 kgs) by weight.
③ Never mix the amount more than can be applied in 40 minutes. Work life is 30-40 minutes at
30°C. Work life will vary depending on temperature.
④ Never add water or other materials to the mix.
⑤ Keep containers tightly sealed. It is recommended to use the curing agent immediately after
opening. But when it is not possible, be aware that Part B has a shelf life of 15 days when
opened. Store in a cool dry place out of direct sunlight.
⑥ GI-200 Adhesive Membrane which has passed its work life cannot be recovered.
⑦ If the material has cured beyond tackiness (beyond 4 hours, around 25°C), surface must be
wiped with MEK to promote bond of next coat.
⑧ Clean tools with MEK immediately after use.

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

[EIS-3] Detail Drawings of GI-180 Block Application

(Appendix File of the Construction Specification)

Materials of GI-180 Block Lining System

Materials of GI-180 Block Document No. TD-ECO-010


TITLE
Lining System Issue date 13/11/06
Revision Number Rev.1 (20/03/13)
Drawn by S.M.Gyo Approved by B.I.Kim
Page 1 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

CROSS SECTION

FRONT VIEW

TITLE
Typical GI-180 Block Document No. TD-ECO-010
Lining System for Application Issue date 13/11/06
Revision Number Rev.1 (20/03/13)
Drawn by M.G.SUNG Approved by B.I.KIM
Page 2 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

NOTES:

1. Stop bar shall be constructed of suitable metal to withstand the design operating environment.

2. Stop bar shall be fully seal welded to the duct plate.

3. Height of stop bar shall be equal to that of the thickness of Glass block lining installed.

4. Surface of stop bar to which Glass block lining to be bonded, shall be cleaned by solvent
wiping with methylene chloride or methyl ketone(MEK) prior to lining.

5. The Glass block shall be fully bonded to the stop bar.

6. Thickness of Glass block shall be as specified above.

Typical Detail-Stop Bar at Document No. TD-ECO-010


TITLE
all Termin. of Glass Block Lining Issue date 13/11/06
Revision Number Rev.1 (20/03/13)
Drawn by M.G.SUNG Approved by B.I.KIM
Page 3 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

NOTES:
1. For proper installation, floor blocks in corner are laid first followed by wall blocks.
All other floor blocks except corner are laid last after walls and ceilings have been completed.

2. First course of wall block lays on top of floor block.

3. Thickness of Glass block shall be as specified as a above.

4. Thickness of GI-200 Ad/Membrane should be from typical ⅛″ to maximum ⅕″.

Typical Detail-Block at Document No. TD-ECO-010


TITLE
Floor Corner in Sect of Outlet Duct Issue date 13/11/06
Revision Number Rev.1 (20/03/13)
Drawn by M.G.SUNG Approved by B.I.KIM
Page 4 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

NOTES:

1. Blocks are to be "hand notched" with knife or rasp to fit snugly over corner angle to minimize
offset. "Dry fit" blocks over corner angles to check seating.

2. Apply adhesive/membrane to block and to corner angle as to carbon steel substrate.


Thickness of glass block shall be as specified.

Typical Block Installation Document No. TD-ECO-010


TITLE
over Inside Corner Angles Issue date 13/11/06
Revision Number Rev.1 (20/03/13)
Drawn by M.G.SUNG Approved by B.I.KIM
Page 5 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

NOTES:

1. Blocks hand-cut with metered angles if necessary to fit snugly against substrate and each other
on corners.
2. Use insulation saw to cut block and rasp to shape or make minor adjustments.
3. No block installed shall be less than 18 square inch surface area.
4. Thickness of glass block shall be as specified.

Typical Layout of Block Document No. TD-ECO-010


TITLE
in Angled Inside Corners Issue date 13/11/06
Revision Number Rev.1 (20/03/13)
Drawn by M.G.SUNG Approved by B.I.KIM
Page 6 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

Typical Layout of Block on Document No. TD-ECO-010


TITLE
Angled Outside Corners Issue date 13/11/06
Revision Number Rev.1 (20/03/13)
Drawn by M.G.SUNG Approved by B.I.KIM
Page 7 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

NOTES:
1. Nozzle(pipe tube) is to be of suitable alloy steel to withstand design operating environment.
2. Nozzle is to be located and fully seal-welded both inside and outside of the steel duct plate.
The inside weld shall be ground smooth.
3. Nozzle shall be flanged rather than threaded.
4. Nozzle is extended inside equipment a minimum distance equal to the thickness of the GI-180
Block system lining specified.
5. The exterior surfaces of the nozzle which will be intimate to the lining system shall be cleaned
by solvent-wiping with methylene chloride or methyl ethyl ketone(MEK) prior to lining.
6. Cut and shape the Glass blocks as required to fit. Fully bond the block to the exterior surface
of the nozzle with GI-200 Adhesive Membrane.

Sample point Document No. TD-ECO-010


TITLE (Nozzle inserts on walls or overhead
Issue date 13/11/06
surfaces of ductwork)
Revision Number Rev.1 (20/03/13)
Drawn by M.G.SUNG Approved by B.I.KIM
Page 8 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

Document No. TD-ECO-010


TITLE Drain
Issue date 13/11/06
Revision Number
Drawn by M.G.SUNG Approved by B.I.KIM
Page 9 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

Document No. TD-ECO-010


TITLE Manhole
Issue date 13/11/06
Revision Number
Drawn by M.G.SUNG Approved by B.I.KIM
Page 10 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

Document No. TD-ECO-010


TITLE Manhole (New Project)
Issue date 18/03/28
Revision Number
Drawn by M.G.SUNG Approved by B.I.KIM
Page 11 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

Document No. TD-ECO-010


TITLE Collection gutter layout
Issue date 13/11/06
Revision Number
Drawn by M.G.SUNG Approved by B.I.KIM
Page 12 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

Document No. TD-ECO-010


TITLE Collection gutter Detail
Issue date 13/11/06
Revision Number
Drawn by M.G.SUNG Approved by B.I.KIM
Page 13 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

Document No. TD-ECO-010


TITLE Expansion joint typical existing
Issue date 13/11/06
Revision Number
Drawn by M.G.SUNG Approved by B.I.KIM
Page 14 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

Document No. TD-ECO-010


TITLE Expansion joint New project
Issue date 13/11/06
Revision Number
Drawn by M.G.SUNG Approved by B.I.KIM
Page 15 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

Document No. TD-ECO-010


TITLE Expansion joint New project 2
Issue date 13/11/06
Revision Number
Drawn by M.G.SUNG Approved by B.I.KIM
Page 16 OF 17

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GI-180 Block Lining System - Ecocera Installation Specification
[EIS-3] Detail Drawings of GI-180 Block Application

Document No. TD-ECO-010


TITLE Expansion joint Bellow (New project)
Issue date 18/03/28
Revision Number
Drawn by M.G.SUNG Approved by B.I.KIM
Page 17 OF 17

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GI-180 Block Lining System

[EIP] Ecocera Inspection Procedure at site

ii. EIP
(Ecocera Inspection Procedure at site)

1. [EIP-1] Inspection of Materials at Jobsite -------------------------------------- 39

2. [EIP-2] Inspection of Substrate after Flue Can Set-up & Welding ---------- 48

3. [EIP-30] Inspection of Surface Preparation in Sand Blasting Process ------- 54

[EIP-31] Inspection of Ceramic(Cement Concrete, Refractory) Surface ----- 60

4. [EIP-4] Application & Inspection of GI-181 Epoxy Primer ------------------ 64

5. [EIP-5] Application & Inspection of GI-180 Block & GI-200 Ad/Membrane 71

6. [EIP-6] Procedure for Final Report ---------------------------------------------- 79

7. [EIP-7] Final Report – Overall Assessment ---------------------------------- 83

Final Report – Project Progress -------------------------------------- 84

Final Report – Data Measurement Summarization ------------------ 88

Final Report – Detail Data Measurement -------------------------- 90

Final Report – Additional Note ----------------------- 91

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GI-180 Block Lining System - Ecocera Inspection Procedure at site

[EIP-1] Inspection of Materials at Jobsite

[EIP-1] Inspection of materials at Jobsite

Client name Project name

Document no. ECO-EIP-PC-1


Date
Revision no.
Inspector Author by Approved by

Verification by Inspection Reference/ Form of Inspection


Item Activity
Frequency Standard Reporting Method
Supervisor Client

Import Inspection 100% Spot Before start Daily Check


1.1 Attached 1-1
: packing/quantity/status check Inspection check of lining Report List
Material Storage Check
100% Spot Before start Daily Check
1.2 : temperature/humidity, storage Attached 1-2
Inspection check of lining Report List
status check

Work environment check 100% Spot Before start Daily Check


1.3 Attached 1-3
: items listed in "attached 1-3" Inspection check of lining Report List

All the equipment which is


related to working at heights As per Site
is installed in accordance with 100% Spot Before start Safety Daily Check
1.4
the safety requirement and Inspection check of lining Conditions Report List
safety standards which are Required (HSE)
applicable within the industry.

All supervisors have to be


acquainted with required Train the Before start
1.5 - Ref 1-1 - -
temperatures of substrate & workers of lining
materials.

The contractor MUST use


certain amount of Primer and Train the Before start
1.6 - Ref 1-1 - -
Membrane per sqm according workers of lining
to regulated consumption

ATTACHED FILE
Attached 1-1 Check List for Material Inspection
Attached 1-2 Check List for Material Storage
Attached 1-3 Check List for Work Safety Environment
Attached 1-4 Daily Report
Ref 1-1 Recommended consumption amount and conditions of products

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GI-180 Block Lining System - Ecocera Inspection Procedure at site

[EIP-1] Inspection of Materials at Jobsite

[Attached 1-1]
Check List for Material Inspection

Supervisor : Date:

(O) Satisfactory, (X) Requires Action

ITEMS O / X Details and Actions

GI-180 Borosilicate Cellular Glass Block

Quantity of Boxes
- Actual quantity / Ordered quantity (Invoice)

Quantity of Blocks (44ea/ box, 51mm)

Outer Box conditions


- Label, Appearance, etc.
Products conditions
- Damage, Quantity, etc.

GI-200 Adhesive Membrane

Quantity of Cans
- Actual quantity / Ordered quantity (Invoice)
Package (17.55kg/set)
- Appearance of pallets, steel cans, leakage etc.

GI-181 Epoxy Primer

A
Quantity of Cans (Part A + Part B = 1 Set)
- Actual quantity / Ordered quantity (Invoice)
B

Package (A: 4kg, B: 1.6kg)


- Appearance of pallets, steel cans, leakage etc.

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GI-180 Block Lining System - Ecocera Inspection Procedure at site

[EIP-1] Inspection of Materials at Jobsite

[Attached 1-2]
Check List for Material Storage

Supervisor : Date:

(O) Satisfactory, (X) Requires Action

ITEMS O / X Details and Actions

GI-180 Borosilicate Cellular Glass Block

Recommended Temp. : -15 ~ 45°C (Max. 50°C)

Recommended Humidity : 90%↓

Recommended Storage :
- 5 stages stacked on each palette

GI-200 Adhesive Membrane

Recommended Temp. : -18 ~ 45°C (Max. 50°C)

Recommended Humidity : 90%↓

Recommended Storage :
- No more than 5 stages stacked on each palette
- In dry areas, do not store near sources of heat of flame

GI-181 Epoxy Primer

Recommended Temp. : -18 ~ 35°C (Max. 40°C)

Recommended Humidity : 90%↓

- No more than 5 stages stacked on each palette


- In dry areas, do not store near sources of heat of flame

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GI-180 Block Lining System - Ecocera Inspection Procedure at site

[EIP-1] Inspection of Materials at Jobsite

[Attached 1-3]
Checklist for Work Safety Environment
Supervisor : Date:
(O) Satisfactory, (X) Requires Action
O / X Details and Actions
1. Environment
Are resources available to deal with very hot or very cold
conditions (drinking water, lined gloves, insulated boots)?
Is the rain/cold weather gear that is provided comfortable and
light enough?
Are work surfaces and grip surfaces safe when wet?
Do workers know the symptoms of heat cramps/heatstroke, or frost
bite/hypothermia?
2. Work Process
Are repetitive motion tasks properly paced and kept to a minimum?
Are the material safety data sheets(MSDS) placed in locations
accessible to all employees?
Are hazards signalled by signs and tags?
Have all trucks, fork lifts and other equipment been inspected
and maintained?
Are lockout or tagout procedures in place and followed?
Is ventilation equipment working effectively?
Is the fume and dust collection hood working effectively?
Are the safety showers and eye wash stations in the proper
locations and in good working condition?
3. Fire Emergency Procedures
Is there a clear fire response plan posted for each work area?
Do all workers know the plan?
Are drills held regularly?
Are fire extinguishers chosen for the type of fire most likely in
that area?
Are there enough extinguishers present to do the job?
Are extinguisher locations conspicuously marked?
Are extinguishers properly mounted and easily accessible?
Are all extinguishers fully charged and operable?
Are special purpose extinguishers clearly marked?
4. Means of Exit
Are there enough exits to allow prompt escape?
Do employees have easy access to exits?
Are exits unlocked to allow egress?
Are exits clearly marked?
Are exits and exit routes equipped with emergency lighting?

page 1 of 3

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GI-180 Block Lining System - Ecocera Inspection Procedure at site

[EIP-1] Inspection of Materials at Jobsite

5. Lighting
Is the level of light adequate for safe and comfortable
performance of work?
Does lighting produce glare on work surfaces, monitors,
screens and keyboards?
Is emergency lighting adequate and regularly tested?

6. Machine Guards
Are all dangerous machine parts adequately guarded?
Do machine guards meet standards?
Are lockout procedures followed when performing
maintenance with guards removed?
7. Electrical
Are all machines properly grounded?
Are portable hand tools grounded or double insulated?
Are junction boxes closed?
Are extension cords out of the aisles where they can be
abused by heavy traffic?
Is permanent wiring used instead of extension cords?
8. Tools and Machinery
Are manufacturers' manuals kept for all tools and machinery?
Do power tools conform to standards?
Are tools properly designed for use by employees?
Are defective tools tagged and removed from service as part
of a regular maintenance program?
Are tools and machinery used so as to avoid electrical
hazards?
Is proper training given in the safe use of tools and
machinery?
9. Confined Spaces
Are the confined space procedures and training available and
followed by all involved?
Are entry and exit procedures adequate?
Are emergency and rescue procedures in place (e.g. trained
safety watchers)?
10. Housekeeping
Is the work area clean and orderly?
Are floors free from protruding nails, splinters, holes and loose
boards?
Are aisles and passageways kept clear of obstructions?
Are permanent aisles and passageways clearly marked?
Are covers or guard rails in place around open pits, tanks and
ditches?
page 2 of 3
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GI-180 Block Lining System - Ecocera Inspection Procedure at site

[EIP-1] Inspection of Materials at Jobsite

11. Stairs, Ladders and Platforms


Are stairs and handrails in good condition?

Are ladders free of defects?

Are ladders set up properly before use?


Are the elevated platforms properly secured and do they have
handrails?

12. Sound Level/Noise


Are regular noise surveys conducted?

Is hearing protection available and used properly?

13. Employee Facilities


Are facilities kept clean and sanitary?

Are facilities in good repair?

Are cafeteria facilities provided away from toxic chemicals?

Are hand washing facilities available?

14. Medical and First Aid


Do all employees know how to get first aid assistance when
needed?
Do the first-aiders know when and to which hospital or clinic
an injured person should be taken?
Are there employees trained as first-aid practitioners on each
shift worked?
Are first-aid kits provided as per jurisdiction’s first-aid
regulations?
Are first-aid supplies replenished as they are used?

15. Personal Protective Equipment (PPE)


Is required equipment provided, maintained and used?

Does equipment meet requirements?

Is it reliable?
Is personal protection utilized only when it is not reasonably
practicable to eliminate or control the hazardous substance or
process?

Are the areas requiring PPE usage properly identified by


warning signs?

page 3 of 3
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GI-180 Block Lining System - Ecocera Inspection Procedure at site

[EIP-1] Inspection of Materials at Jobsite

[Attached 1-4]
Daily Report
Subject Inspection of Materials at Jobsite
Customer Project
Document no. ECO-EIP-DR-1
Date
Revision no.
Inspector Author by Approved by

Sr Done
Item Overview and Comments
No. (Y/N)

Material
1
Inspection

Material
2
Storage

Work
3 Safety
Environment

Page 1 of 2
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GI-180 Block Lining System - Ecocera Inspection Procedure at site

[EIP-1] Inspection of Materials at Jobsite

Sr
Item Category Details
No.

GI-180
Block

Material GI-200
1 Inspection Ad/Membrane

GI-181
Epoxy Primer

AM AM AM PM PM PM PM
Temp.
(°C)

AM AM AM PM PM PM PM

Material Humidity
2 (%)
Storage

AM AM AM PM PM PM PM

Status

Work Attached1-3
3 Safety List no.
Environment 1~15

Page 2 of 2

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GI-180 Block Lining System - Ecocera Inspection Procedure at site

[EIP-1] Inspection of Materials at Jobsite

[ Ref 1-1 ] Recommended consumption amount and conditions of products


1. Storage and Working conditions
Storage Storage
Product Temp. Humidity Mixing Substrate
GI-180 Recommend : -15~45°c
Max. 90% n/a
Block Maximum : 50°c
Recommend : 4~36°c
GI-200 Maximum : 40°c
Recommend : -18~45°c Recommend : 4~40°c
Ad/ Max. 90%
Maximum : 50°c Maximum : 45°c
Membrane
GI-181
Recommend : -18~35°c Recommend : 4~35°c Recommend : 4~35°c
Epoxy Max. 90%
Maximum : 40°c Maximum : 40°c Maximum : 40°c
Primer
※ Storage : The storage temperature can be allowed over Max temp. But the shelf life will be shorter than
that of recommendation temp. It should be stored in roofed indoor where is also well ventilated without direct
sunlight and heat.
※ Mixing & Substrate : The temperature can be allowed over Max temp. But the pot-time will be shorter
than that of recommendation temp. Further details, Refer to product information.
※ The cartons of GI-180 Block and containers of GI-200 Adhesive Membrane and Primer shall be protected.
※ The prepared substrate must be protected from the elements until the lining work is completed.
※ Be aware of the temperature of the substrate to be sure that GI-200 Adhesive Membrane does not set up
too quickly and, hence, lose its wet tack. Wet tack is if Membrane comes off onto the finger when touched.
※ Products DO NOT get affected by outside temperature.

2. Product Shelf Life


Product Shelf Life Conditions
Meets all the storage and working conditions above.
GI-180 Block Indefinite
Stored in cardboard cartons with spacers.
Meets all the storage and working conditions above.
GI-200 3 years from manufactured date
Do not store near resources of heat or frame.
Ad/ Membrane (unopened units)
Do not store under the direct sunlight.
2 years from manufactured date Meets all the storage and working conditions above.
GI-181

(unopened units) Do not store near resources of heat or frame.
Epoxy Primer
5 months under the max 40°c. Do not store under the direct sunlight.

3. Recommended Consumption and information


Product Consumption Package Applicable Area
GI-180 Block 28 ea / m2 60ea / box (38mm) approx. 2.5 m2/ box (38mm)
44ea / box (51mm) approx. 1.5 m2/ box (51mm)
GI-200 38mm : 6.5 ± 2% Kg/m2 17.55 kg / set approx. 2.7 m2 /set (38mm)
Ad/Membrane 51mm : 7.0 ± 3% Kg/m2 approx. 2.5 m2 /set (51mm)
GI-181 0.15 kg / m2 (Steel)
0.2 kg / m2 5.6 kg / set approx. 37 m2 / set
Epoxy Primer (Concrete, Refractory)*
*In case of Ceramic (Concrete, Refractory) surface application, please skip EIP-2 & EIP-30 and go to
EIP-31.

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GI-180 Block Lining System Ecocera Inspection Procedure at site
[EIP-2] Inspection of Substrate after Flue Can Set-up & Welding

[EIP-2] Inspection of Substrate after Flue Can Set-up & Welding

Client name Project name

Document no. ECO-EIP-PC-2


Date
Revision no.
Inspector Author by Approved by

Verification by Inspection Reference/ Form of Inspection


Item Activity
Supervisor Client Frequency Standard Reporting Method

Check welding status.


100% Spot Before Daily Check
2.1 - All surface defects should Attached 2-1
Inspection check Blasting Report List
be removed.
ISO8501:1988
100% Spot Before Daily Check
2.2 Check Rust grade Attached 2-1
Inspection check Blasting Report List
Ref 2-1
Installation of Stop bars
Ecocera
-All leading edges of the
Application
GI-180 Block Lining Information
System (manholes pipe
100% Spot Before (EIS-3 Daily Check
2.3 stubs, expansion joints) are
Inspection check Blasting Detail Report List
protected from undercutting
Drawings of
by the gas stream through
Block
the use of properly
Application)
designed “Stop bars”.
Acceptance of the steel
substrate - attached hereto
and incorporated, which
applies to the specific area,
will be signed by
Before Attached Check
2.4 ECOCERA(Supervisor) Submission Approval Attached 2-2
Blasting 2-2 List
and clients.
Note: grit blasting may
uncover steel defects, which
need to be addressed
afterwards.
ATTACHED FILE
Attached 2-1 Check List for Substrate after Flue Can Set-up & Welding
Attached 2-2 Acceptance of the steel substrate
Attached 2-3 Daily Report
Ref 2-1 The Rust grade A to D - ISO8501

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GI-180 Block Lining System Ecocera Inspection Procedure at site
[EIP-2] Inspection of Substrate after Flue Can Set-up & Welding

[Attached 2-1]
Check List for Substrate after Flue Can Set-up & Welding

Supervisor : Date:

(O) Satisfactory, (X) Requires Action

ITEMS O / X Details and Actions

1. Substrate Surface Conditions

Welds must be free of pinholes, undercutting, etc.

Smooth ripple welds are acceptable.


Weld spatter, slag and old anchor welds must be removed.
Rust grade A and B are acceptable.
Rust grade C and pitting(D) is subject to agreement.

2. Installation of Stop bars

The stop bars shall be fabricated of or protected by corrosion


resistant material.

Stop bars must be installed using continuous welds.

3. Acceptance of Steel Substrate

Preparation and Submission of Documents

Approval of Documents

[Ref. 2-1] The Rust grade A to D – ISO8501

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GI-180 Block Lining System Ecocera Inspection Procedure at site
[EIP-2] Inspection of Substrate after Flue Can Set-up & Welding

[Attached 2-2]
Acceptance of the steel substrate

Client :
Project :
Date :

The undersigned declare, that the quality of the steel substrate of the internal surface of the above
mentioned object is in accordance with the requirements which are described in item 2 (Inspection
of substrate of Flue Can) of the EIP (Ecocera Inspection Procedure at site).
This Attached 2-2 is subject to the terms and the conditions of the Inspection and Test Plan in its
entirety.
Remarks :
1) Welding Status

2) Rust Grade

Inspector (Ecocera) Authority Approval (Client)

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GI-180 Block Lining System Ecocera Inspection Procedure at site
[EIP-2] Inspection of Substrate after Flue Can Set-up & Welding

[Attached 2-3]
Daily Report

Subject Inspection of Substrate after Flue Can Set-up & Welding


Customer Project
Document no. ECO-EIP-DR-2
Date
Revision no.
Inspector Author by Approved by

Sr Done
Item Overview and Comments
No. (Y/N)

Substrate
1 Surface
Conditions

Installation
2 of
Stop Bars

Acceptance
of
3
Steel
Substrate

Page 1 of 2

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GI-180 Block Lining System Ecocera Inspection Procedure at site
[EIP-2] Inspection of Substrate after Flue Can Set-up & Welding

Sr
Item Details
No.

Substrate
1 Surface
Conditions

Installation
2 of
Stop Bars

Acceptance
of
3
Steel
Substrate

Page 2 of 2

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GI-180 Block Lining System Ecocera Inspection Procedure at site
[EIP-2] Inspection of Substrate after Flue Can Set-up & Welding

[ Ref 2-1 ] The Rust grade A to D - ISO8501

※ Description

Grade A : Steel surface largely covered with adhering mill scale but little, if any, rust.

Grade B : Steel surface which has begun to rust and from which the mill scale has begun to flake.

Grade C : Steel surface on which the mill scale has rusted away or from which it can be scraped,
but with slight pitting visible under normal vision.

Grade D : Steel surface on which the mill scale has rusted away and on which general pitting is
visible under normal vision.
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GI-180 Block Lining System Ecocera Inspection Procedure at site

[EIP-30] Inspection of Surface Preparation in Sand Blasting Process

[EIP-30] Inspection of Surface Preparation in Sand Blasting Process

Client name Project name

Document no. ECO-EIP-PC-3


Date
Revision no.
Inspector Author by Approved by

Verification by Inspection Reference/ Form of Inspection


Item Activity
Frequency Standard Reporting Method
Supervisor Client
Examine abrasive for
Before Daily
30.1 cleanliness and proper Spot check - - Visual
blasting Report
grade size.
Every
Cleanliness of the
time Daily
30.2 pressure air and the Spot check - - Visual
during Report
MPa at the nozzle.
blasting
Check surface
100% Spot Before Attached Daily Check
30.3 conditions before
Inspection check blasting 30-1 Report List
blasting.
Check
After Attached List/
Check the blast quality 100% Spot blasting 30-1 Daily surface
30.4
after blasting. Inspection check and rough Report profile
cleaning Ref 30-1 gauge
Elco-meter
Remove all abrasive After Attached Check
and dust from the 100% Spot blasting 30-1 Daily List/
30.5
surface. Inspection check and rough Report Elco-meter
Check dust grade. cleaning Ref 30-2 (Dust Kit)
Acceptance of surface
preparation- Attached Attached
hereto and incorporated Before 30-3
Attached Check
30.6 herein, which applies to Submission Approval Primer (Dust Kit
30-3 List
the specific area, will work
be signed by Ecocera Report)
(Supervisor) and Client.

Attached File
Attached 30-1 Checklist for Surface Preparation in Sand Blasting Process
Attached 30-2 Daily Report
Attached 30-3 Dust Assessment in Accordance with ISO 8502-3
Ref 30-1 ISO8501-1, Sa2.5 / Ref 30-2 ISO8502-3, Dust classes

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GI-180 Block Lining System Ecocera Inspection Procedure at site

[EIP-30] Inspection of Surface Preparation in Sand Blasting Process

[Attached 30-1]
Check List for Surface Preparation in Sand Blasting Process

Supervisor : Date:

(O) Satisfactory, (X) Requires Action

ITEMS O / X Details and Actions

1. Check surface conditions before blasting

Before blasting the substrate is free of oil, grease and other


penetrating contaminants.

2. Check the blast quality after blasting

Blast quality shall be Sa 2.5,


referring to Ref 30-1 / ISO 8501-1

Minimum surface profile (Rz) shall be 35~50 µm.

3. Check the Dust Class

Remove all abrasive and dust from the surface.

Check the dust class in accordance with class no.2,


referring to Ref 30-2 / ISO 8502-3.

Preparation and submission of Documents

Approval of Documents

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GI-180 Block Lining System Ecocera Inspection Procedure at site

[EIP-30] Inspection of Surface Preparation in Sand Blasting Process

[Attached 30-2]
Daily Repot

Subject Inspection of Surface Preparation in Sand Blasting Process


Customer Project
Document no. ECO-EIP-DR-3
Date
Revision no.
Inspector Author by Approved by

Sr Done
Item Overview and Comments
No. (Y/N)
Abrasive
cleanliness
&grade size
1
Nozzle
cleanliness
&pressure
Surface
condition
(free of
2 contaminants)
before
sand
blasting
Blast quality
after sand
blasting
3 - Sa 2.5
- Roughness
-Surface
Cleaning
Dust assessment
- Determination

Dust assessment
4
- Submission

Dust assessment
- Approval
Page 1 of 2
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GI-180 Block Lining System Ecocera Inspection Procedure at site

[EIP-30] Inspection of Surface Preparation in Sand Blasting Process

Sr
Item Details
No.

Abrasive
cleanliness
&grade size
1
Nozzle
cleanliness
&pressure

Surface
condition
(free of
2 contaminants)
before
sand
blasting

Blast quality
after sand
blasting
3 - Sa 2.5
- Roughness
-Surface
Cleaning

Dust
assessment -
Determination

4
Dust
assessment -
Submission

Dust
assessment -
Approval

Page 2 of 2

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GI-180 Block Lining System Ecocera Inspection Procedure at site

[EIP-30] Inspection of Surface Preparation in Sand Blasting Process

[Attached 30-3] Dust Assessment in Accordance with ISO 8502-3

Client :
Project :
Date :

Dust Quantity Rating (Mean)


Test 1
Test 2
Test 3
Test 4
Test 5

Dust Quantity Rating

1 2 3 4 5

Surface identification :
Substrate backing used :
Nature of surface tested :
Inspector (Ecocera) Authority Approval (Client)

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GI-180 Block Lining System Ecocera Inspection Procedure at site

[EIP-30] Inspection of Surface Preparation in Sand Blasting Process

[Ref 30-1] ISO 8501-1, Sa 2.5

[Ref 30-2] ISO 8502-3, Dust Classes

Acceptable

Acceptable

Cleaning and Re-test

Cleaning and Re-test

Cleaning and Re-test

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-31] Inspection of Ceramic (Cement Concrete, Refractory) Surface

[EIP-31] Inspection of Ceramic (Cement Concrete, Refractory) Surface

Verification by Reference
Inspection Form of Inspection
Item Activity /
Frequency Reporting Method
Supervisor Client Standard
Surface Preparation of
Concrete by ASTM D
4259.

※ Proper Cleaning
Method shall be
determined by ASTM D
Client/Erection Agent. 4258 & Approval
31.1 Submission Approval - -
ASTM D by Client
- Mechanical Abrading 4259
Procedure

- Water Blast Cleaning

- Abrasive Blast Cleaning


Procedure

Attached
Acceptable surface by 100% spot After Check
31.2 31-1 &
Inspection Inspection check Cleaning List
Ref 31-1

Acceptance of surface
preparation- Attached
hereto and incorporated Before
Attached Check
31.3 herein, which applies to Submission Approval Primer
31-2 List
the specific area, will be work
signed by Ecocera
(Supervisor) and Client.

Attached File
Attached 31-1 Checklist of acceptable Ceramic(Cement Concrete, Refractory) Surface
Attached 31-2 Daily Report (Inspection of Surface Preparation)
Ref 31-1 Acceptable Grade of Concrete Surface by ICRI Technical Guide Line

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-31] Inspection of Ceramic (Cement Concrete, Refractory) Surface

[Attached 31-1]
Checklist of acceptable Ceramic (Cement Concrete, Refractory) Surface

Supervisor : Date:

(O) Satisfactory, (X) Required Action

ITEMS O / X Details and Actions

Check surface conditions before priming

Acceptable surfaces shall be free of laitance, oil. grease, and


other materials incompatible with the coating. The surface
shall also be free of fins, projections and loosely adhering
concrete, dirt, and dust particles

The surface shall have a roughened, textured appearance.


Aggregate may be exposed, Bug holes shall be opened.

The roughened textured appearance shall be similar to the


roughness standard established by mutual agreement.

If specified, the treated surface shall meet the surface strength


requirements.

The concrete surface is in accordance with ICRI grade.


Recommeded grade : CSP 1 ~ CSP 6.

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-31] Inspection of Ceramic (Cement Concrete, Refractory) Surface

[Attached 31-2]
Daily Report

Subject Inspection of Ceramic (Cement Concrete, Refractory) Surface


Customer Project
Document no. ECO-EIP-DR-3
Date
Revision no.
Inspector Author by Approved by

Sr Done
Item Overview and Comments
No. (Y/N)
Free of laitance, oil. grease
other materials incompatible
with the coating
1
Free of fins, projections and
loosely adhering concrete, dirt,
and dust particles

The surface shall have a


roughened, textured appearance.
2
Aggregate may be exposed,
Bug holes shall be opened.
The roughened textured
appearance shall be similar to
3 the roughness standard
established by mutual
agreement.
The concrete surface is in
accordance with ICRI grade.
4
Recommeded grade
: CSP 1 ~ CSP 6.

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-31] Inspection of Ceramic (Cement Concrete, Refractory) Surface

[Ref 31-1] Acceptable Grade of Concrete Surface by ICRI Technical Guide Line

These Concrete Surface Profiles were developed by the International Concrete Repair Institute (ICRI), are
divided in to ten classifications 9CSP1-10) of surface textures based on the average distance from the peaks
of the surface to the valleys. They are accepted industry standards to help guide the installer achieve the
proper texture for successful bonding of the overlay or coating. The lower number profiles are smoother(CSP
1 is nearly flat), and the higher numbers have more “tooth” and get progressively rougher.

Before priming, recommended grade of concrete surface is from CSP 1 to CSP 6. However, other grades
required shall be mutually discussed with related agency.

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-4] Application & Inspection of GI-181 Epoxy Primer

[EIP-4] Application & Inspection of GI-181 Epoxy Primer

Client name Project name


Document no. ECO-EIP-PC-4
Date
Revision no.
Inspector Author by Approved by

Verification by
Inspection Reference/ Form of Inspection
Item Activity
Frequency Standard Reporting Method
Supervisor Client

Inspect the temperature Before Check


100% Spot Daily
4.1 of the substrate and the Applicatio Attached 4-1 List/
Inspection check Report
Relative Humidity n Tester

Before
Inspect equipment Spot Daily Check
4.2 Spot check Applicatio Attached 4-1
management throughly check Report List
n

Before
Inspect the mixing of Daily Check
4.3 Spot check - Applicatio Attached 4-1
the GI-181 Epoxy Report List
n

PRE-application of the Each


100% Daily Check
4.4 GI-181 Epoxy Primer - Applicatio Attached 4-1
Inspection Report List
(10% diluted) n

Check WFT Check


(Wet film Thickness) Each Attached 4-1
Spot Daily List/
4.5 The right application Spot check Applicatio
check Report WFT
technique.(Spraying) n Ref 4-1
gauge

Page 1 of 2

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-4] Application & Inspection of GI-181 Epoxy Primer

Verification by Inspection Reference/ Form of Inspection


Item Activity
Supervisor Client Frequency Standard Reporting Method

Record the consumed


amount and information Daily Check
100% Each
4.6 of the GI-181 Epoxy - Attached 4-1
Inspection Application Report List
Primer applied to each
working area.

Result of spray and Spot Daily Check


4.7 100% After
application after drying Attached 4-1
Inspection check Application Report List
on the surface.

Check
Attached 4-1
Check DFT Spot After Daily List
4.8 Spot check
(Dry film Thickness) check Application Report /Elcomet-
Ref 4-1
er

Acceptance of the
primed substrate
-attached hereto and
incorporated herein, After Attached Check
4.9 Submission Approval Attached 4-3
which applies to the Application 4-3 List
specific area, will be
signed by Ecocera
(Supervisor) and Client.

Attached File
Attached 4-1 Check List for Application of GI-181 Epoxy Primer
Attached 4-2 Daily Report
Attached 4-3 Acceptance of the primed substrate
Ref 4-1 Measuring Spot of Wet&Dry film thickness (WFT, DFT) on Ferrous substrates

Page 2 of 2

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-4] Application & Inspection of GI-181 Epoxy Primer

[Attached 4-1]
Check List for Application of GI-181 Epoxy Primer
Supervisor : Date:
(O) Satisfactory, (X) Required Action
ITEMS O / X Details and Actions
1. Temperature measurement
Relative temperature: 4℃~35℃

Relative Humidity: R.H. ≤90%


Substrate temperature: 4℃~35℃
It shall be at least 3℃ higher than the dew point temperature.
2. Equipment management
Hoses, mixer and other equipment, which come into contact
with the components or the mixed material are clean.
3. Mixing of the GI-181 Epoxy Primer
Mix part A by itself for at least one minute.
Shake Part B well and add entire contents to Part A
(Part A: Part B = 4kg:1.6kg) by weight. (300rpm./min.)
Mixing time : at least 3~4minutes at upper 15°c
more than 5minutes at below 5°c
Never mix more than can be applied in 40minutes.
Work life is 40-50 minutes at 25°c.
Shorter work life in higher temperature. (Product Information)
Never add water or other materials to the mix.
Keep containers tightly sealed, and in
Stored in a cool dry place out of direct sunlight.
Clean tools with MEK immediately after use.
4. PRE-application of the GI-181 Epoxy Primer
All welds, corners stop bars and other protuberances are being
coated with a 10% diluted “stripe-coat” (paint brush only) of
the GI-181 Epoxy primer. (solvent: MEK or Gasoline)
5. Check WFT (Wet film Thickness)
Spraying : single wet pass and 50% overlap.
Acceptable WFT : 75~150㎛. (direct after spraying)
6. Record product information per each working area
Record the consumed amount and information of Epoxy Primer
as per applied area (ex: The upper, bottom part of Flue can)
7. Result of spray and application after drying
Film must be flat without vacancy, drips or sagging.
8. Check DFT (Dry film Thickness)
Acceptable DFT : 40~120 ㎛

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-4] Application & Inspection of GI-181 Epoxy Primer

[Attached 4-2]
Daily Report
Subject Application & Inspection of GI-181 Epoxy Primer
Customer Project
Document no. ECO-EIP-DR-4
Date
Revision no.
Inspector Author by Approved by

Sr Done
Item Overview and Comments
No. (Y/N)
Temp &Humidity
1
Check
Equipment
2
Management
Mixing
3
of Primer

Pre-application of
4
Primer

5 WFT

Record product
6 info. per each
working area

7 Result of Spray

8 DFT

Preparation-
Acceptance of
primed substrate
Submission-
9 Acceptance of
primed substrate
Approval-
Acceptance of
primed substrate
Page 1 of 2

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-4] Application & Inspection of GI-181 Epoxy Primer

Sr
Item Details
No.

Temp &Humidity
1
Check

Equipment
2
Management

Mixing
3
of Primer

Pre-application of
4
Primer

5 WFT

Record product
6 info. per each
working area

7 Result of Spray

8 DFT

Preparation-
Acceptance of
primed substrate

Submission-
9 Acceptance of
primed substrate

Approval-
Acceptance of
primed substrate

Page 2 of 2
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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-4] Application & Inspection of GI-181 Epoxy Primer

[Attached 4-3]
Acceptance of the primed substrate

Client :
Project :
Date :
The undersigned declare, that the quality of the steel substrate of the internal surface of the above
mentioned object is in accordance with the requirements which are described in item 4 (Inspection
of substrate) of the EIP (Ecocera Inspection Procedure at site).
This Attached 4-3 is subject to the terms and the conditions of the Inspection and Test Plan in its
entirety.
Remarks :
1) WFT

2) DFT

3) Result of Application

Inspector (Ecocera) Authority Approval (Client)

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-4] Application & Inspection of GI-181 Epoxy Primer

[ Ref 4-1 ] Measuring Spot of Wet&Dry film thickness(WFT, DFT) on


Ferrous substrates

Objective : Coating thickness is an important variable that plays a role in product quality,
process control and cost control. These particular spots describe the use of gauges to measure
the WFT&DFT of GI-181 Epoxy Primer range.

* The measuring spots can be chosen at random by supervisors and measured intensively.

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-5] Application & Inspection of GI-180 Block & GI-20 Ad/Membrane

[EIP-5] Application & Inspection of GI-180 Block & GI-200 Ad/Membrane

Verification by Inspection Reference/ Form of Inspection


Item Activity
Supervisor Client Frequency Standard Reporting Method

Inspect the First-Mid- Check


temperature of the Spot
5.1 Spot check Last Attached 5-1 Daily Report List/
substrate and the check
/Each shift Tester
Relative Humidity.

First-Mid-
Mixing of GI-200 Check
5.2 Spot check - Last Attached 5-1 Daily Report
Adhesive Membrane List
/Each shift

First-Mid-
Equipment Check
5.3 Spot check - Last Attached 5-1 Daily Report
management List
/Each shift

Inspect glass block During Check


5.4 Spot check - Attached 5-1 Daily Report
condition. installation List
The right application
technique for GI-200 100% Spot During Check
5.5 Ref 5-1 Daily Report
Ad/Membrane and Inspection check installation List
GI-180 Block
Record the consumed
amount and
information of the 100% During Check
5.6 GI-200 Ad/Membrane - Attached 5-1 Daily Report
and GI-180 Block Inspection installation List
applied to each
working area.
During/
100% Spot Check
5.7 Inspect of Defects After Attached 5-2 Daily Report
Inspection check List
Installation

Attached File
Attached 5-1 Checklist for Installation of the GI-180 Block & GI-200 Ad/Membrane
Attached 5-2 Daily Report
Ref 5-1 Bad Cases for Final Inspection and corresponding actions

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-5] Application & Inspection of GI-180 Block & GI-20 Ad/Membrane

[Attached 5-1]
Check List for Installation of the GI-180 Block & GI-200 Ad/Membrane
Supervisor : Date:

(O) Satisfactory, (X) Requires Action

ITEMS O / X Details and Actions

1. Temperature measurement
Relative Temperature : 4℃~40℃

Relative Humidity : R.H. ≤90%


Substrate temperature : 4℃~36℃
The substrate temperature shall be at least 3℃ higher than
then the dew point temperature.
2. Mixing of GI-200 Adhesive Membrane
Mix part A by itself for at least one minute.

Mix part A(Main Resin) and B(Hardener) together.


(Part A: Part B = 100:3.2 by weight (300rpm./min.)
Mixing time : at least 5minutes at upper 18°c
more than 10minutes at below 5°c
Leave the mixed Ad/M for about 5 minutes for suitable
viscosity. Work life is 60~70 minutes at 30°c.
Not hardness Mixing time

If Bad Cases Early hardness Temp(°c)/Humidity(


%)
Swelling after Considered failure
mixing in storage
3. Equipment Management
Mixers and tools are kept clean.

4. Glass Block Pre-visual inspection


Damaged or Not

5. The right application technique for GI-200 Ad/Membrane and GI-180 Block
The minimum thickness of the back joint : Minimum 3mm.
The minimum thickness of the side joint : Minimum 2mm.
All blocks are well aligned with the joints struck smooth.
(Alignment : lower than 3mm)

Remove over-flowed adhesive from the surface of blocks.

Page 1 of 2

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-5] Application & Inspection of GI-180 Block & GI-20 Ad/Membrane

ITEMS O / X Details and Actions

6. Record product information per each working area

Record the consumed amount and information of GI-180 Block


as per applied area.
(ex: The upper, bottom part of Flue can)
Record the consumed amount and information of GI-200
Adhesive Membrane as per applied area.
(ex: The upper, bottom part of Flue can)

7. Inspect of Defects
The GI-180 Block Lining System is free of defects and that
GI-200 Ad/Membrane in the joints is without craters.

8. Final Inspection for each bad case


Space on upper block : Incomplete block laying with
insufficient membrane
Vertical space in-between blocks : Incomplete block laying
with insufficient membrane
Horizontal Space : Incomplete block laying with insufficient
membrane
Space between block and substrate (Test by tapping with
rubber tool) : Incomplete block laying with insufficient
membrane

Page 2 of 2
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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-5] Application & Inspection of GI-180 Block & GI-20 Ad/Membrane

[Attached 5-2]
Daily Report
Subject 5. Application & Inspection of the GI-180 Block Lining System
Customer Project
Document no. ECO-EIP-DR-5
Date
Revision no.
Inspector Author by Approved by

Sr Done
Item Overview and Comments
No. (Y/N)

Temperature
1
measurement

Mixing of
2 GI-200
Ad/Membrane

Equipment
3
Management

GI-180 Block
4 Pre-visual
inspection
The right
application
5 technique for
GI-200 and
GI-180 Block
Record product
information per
6
each working
area

Inspect of
7
Defects

Final Inspection
8 for each bad
case
Page 1 of 2

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-5] Application & Inspection of GI-180 Block & GI-20 Ad/Membrane

Sr
Item Details
No.

Temperature
1
measurement

Mixing of
2 GI-200
Ad/Membrane

Equipment
3
Management

GI-180 Block
4 Pre-visual
inspection

The right
application
5 technique for
GI-200 and
Gl-180 Block

Record product
information per
6
each working
area

Inspect of
7
Defects

Final Inspection
8 for each bad
case

Page 2 of 2

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-5] Application & Inspection of GI-180 Block & GI-20 Ad/Membrane

[ Ref 5-1 ] Bad Cases for Final Inspection and corresponding actions
(1) Space on upper block : Incomplete block laying with insufficient membrane

Page 1 of 3

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-5] Application & Inspection of GI-180 Block & GI-20 Ad/Membrane

(2) Vertical space in-between blocks : Incomplete block laying with insufficient membrane

Page 2 of 3

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-5] Application & Inspection of GI-180 Block & GI-20 Ad/Membrane

(3) Horizontal Space : Incomplete block laying with insufficient membrane

(4) Space between block and substrate (Test by tapping with rubber tool) : Incomplete block
laying with insufficient membrane

Page 3 of 3

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-6] Procedure for Final Report

[EIP-6] Procedure for Final Report

Client name Project name

Document no. ECO-EIP-PC-6


Date
Revision no.
Inspector Author by Approved by

Verification by Inspection Reference/ Form of Inspection


Item Activity
Supervisor Client Frequency Standard Reporting Method

Verify, count of 100% Spot After


6.1 Attached 6-1 Daily Report -
bad case Inspection Check Installation

Actions taken for


100% Spot After
6.2 bad case and the Attached 6-1 Daily Report -
Inspection Check Installation
results

Draft Report After II II


6.3 Preparation - -
Preparation Installation Final Report Final Report

Draft Report Review II II


6.4 Submission - -
Submission Approval Final Report Final Report

Draft Report II II
6.5 Improvement Improvement - - -
(when required) Final Report Final Report

Improved Report Review II II


6.6 Submission - -
Submission Approval Final Report Final Report

Final Report
Acceptance
(To be signed II II
6.7 Signature Signature
after completion Final Report Final Report
of the flue by
Ecocera and Client)

Attached File
Attached 6-1 Checklist for Final Report
Attached 6-2 Daily Report

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-6] Procedure for Final Report

[Attached 6-1]
Check List for Final Report
Supervisor : Date:

(O) Satisfactory, (X) Requires Action

ITEMS O / X Details and Actions

1. Verify, count of bad case


The lining on the total inside of the object is free from
defects and mechanical damages. This shall be indicated in the
final report.

2. Actions taken for bad case and the results

This shall be indicated in the final report.

3. Draft Report Preparation

All inspection contents/items shall be inserted without missing.

4. Draft Report Submission

Submit the draft report to the client for approval.

5. Draft Report Improvement (When required)

Improve the draft report by the client’s requests.

6. Improved Report Submission

Submit the improved report to the client for approval.

7. Final Report Acceptance

Must be signed by both Ecocera and the Client.

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-6] Procedure for Final Report

[Attached 6-2]
Daily Report

Subject 6. Procedure for Final Report


Customer Project
Document no. ECO-EIP-DR-6
Date
Revision no.
Inspector Author by Approved by

Sr Done
Item Overview and Comments
No. (Y/N)

Verify, count
1
of bad case

Actions taken
2 for bad case
and the results

Draft Report
3
Preparation

Draft Report
4
Submission

Draft Report
Improvement
5
(When
required)
Improved
6 Report
Submission

Final Report
7
Acceptance

Page 1 of 2
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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-6] Procedure for Final Report

Sr
Item Details
No.

Verify, count
1
of bad case

Actions taken
2 for bad case
and the results

Draft Report
3
Preparation

Draft Report
4
Submission

Draft Report
Improvement
5
(When
required)

Improved
6 Report
Submission

Final Report
7
Acceptance

Page 2 of 2

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-7] Final Report

[EIP-7] Final Report


7.1 Overall Assessment
• Total Project Duration : 202 . . ~ 202 . . (Days : )
• Purpose of Project : Application of GI-180 Block Lining System
• Number of Participants : _______ Persons
• Total consumption of Material
Used Order
S/N DESCRIPTION Comments
Quantity Quantity
GI-180 Block (229x152x51mm)
Total Area (sqm)
Consumption (plates/sqm)
1 Total Consumption (plates)
Total Package (Carton boxes)
40ft Container
Total Volume
20ft Container
GI-200 Adhesive Membrane
Total Area (sqm)
2 Consumption (kg/sqm)
Total Consumption (kg)
Total Package (Can(set))
Total Volume (20ft Container)
GI-181 Epoxy Primer
Total Area (sqm)
3 Consumption (kg/sqm)
Total Consumption (kg)
Total Package (Can(set))
Calculated Area :
• Overall Comments:

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-7] Final Report

7.2 Project progress for Flue no.1


Target working period Actual working period
Project Inspection of Materials at Inspection for
Inspection of Substrate
Day Jobsite Surface Preparation
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40

Comment

Page 1 of 2
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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-7] Final Report

Project Application of the Application o f th e


Procedure for Final Report
Day GI-181 Epoxy Primer GI-180 Block Lining System
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79

Comment

Page 2 of 2

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-7] Final Report

7.2 Project progress for Flue no.2


Target working period Actual working period
Project Inspection of Materials at Inspection for
Inspection of Substrate
Day Jobsite Surface Preparation
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40

Comment

Page 1 of 2
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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-7] Final Report

Project Application of the Application o f the


Procedure for Final Report
Day GI-181 Epoxy Primer GI-180 Block Lining System
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79

Comment

Page 2 of 2
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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-7] Final Report

7.3 Data Measurement Summarization


Accept(O)
Part Item Comment
Reject(X)
GI-180 Block
1. Inspection
GI-200
of Materials at
Ad/Membrane
Jobsite
GI-181 Epoxy Primer

Substrate Surface
2. Inspection Conditions
of Substrate Installation
Stop Bars
Check surface
conditions before
blasting
3. Inspection Check the blast
for Surface quality after
blasting
Preparation
Remove all
abrasive and dust
Dust Grade
The temperature of
the substrate
The temperature of the
GI-181 Epoxy Primer
Equipment
management
Mixing of the
GI-181 Epoxy
Primer
PRE-application of
the GI-181 Epoxy
4. Application
Primer
of the GI-181 The right pplication
Epoxy Primer technique.
(Check WFT)
Record the consumed
amount and information
of the GI-181 Epoxy
primer per area
Result of spray and
application after
drying on the
surface

Check DFT

Page 1 of 2

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-7] Final Report

Accept(O)
Part Item Comment
Reject(X)
The temperature of
the substrate

The status of GI-200


Adhesive Membrane

Equipment
management

Mixing of GI-200
Adhesive Membrane

Inspect glass block


5. Application
condition
of the
The right
GI-180 Block application
Lining System technique for
GI-200 and GI-180
Block
Check GI-200
Ad/Membrane

Record the consumed


amount and
information of the
GI-180 Block and
GI-200 Ad/Membrane

Inspect of Defects

Verify, count of
bad case

6. Procedure Draft Submission


for Final
Report Approval

Final Report
Acceptance

Page 2 of 2

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-7] Final Report

7.4 Detail Data Measurement


Part Step ITEM Reference Actual Value MAX Value MIN Value
GI-180 Block ea ea
GI-200
Quality Ad/Membrane set set
GI-181 set set
Epoxy Primer
Recommended
GI-180 Block -15~40°c °c °c °c
Max 50°c
1. Inspection Recommended
of Materials at GI-200
Storage Ad/Membrane -18~45°c °c °c °c
Jobsite Air temp. Max 50°c
Humidity Recommended
GI-181 -18~35°c °c °c °c
Epoxy Primer
Max 40°c
Humidity 90% % % %
Recommended
Substrate
Application 4~36°c °c °c °c
Temperature
Max 40°c
2. Inspection Before Accept: A/B
Rust Grade Agreement:
of Substrate Application C/D
3. Inspection After Sa 2.5
Blast Quality ㎛ ㎛ ㎛
Rz=35~50㎛
for Surface Sand
Preparation Blasting Dust class Class 2
Recommended
Mixing temp. 4~35°c °c °c °c
Before Max 40°c
4. Application Humidity 90% % % %
Application
of the GI-181 Recommended
Substrate 4~35°c °c °c °c
Epoxy primer Temp
Max 40°c
After WFT 75~150㎛ ㎛ ㎛ ㎛
Application DFT 40~120㎛ ㎛ ㎛ ㎛
GI-200 Recommended
Ad/Membrane 4~40°c °c °c °c
Mixing temp. Max 45°c
Before
5. Application Humidity 90% % % %
of the Application
Recommended
GI-180 Block Substrate
4~36°c °c °c °c
Temp.
Lining System Max 40°c
After Alignment ≤ 3mm mm mm mm

Application Width of ≥ 2mm mm mm mm


Ad/Membrane

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GI-180 Block Lining System – Ecocera Inspection Procedure at site
[EIP-7] Final Report

7.5 Additional Note

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GI-180 Block Lining System
[EMSDS] Ecocera Material Safety Data Sheet

ⅲ. EMSDS
(Ecocera Material Safety Data Sheet)

1. [EMSDS-1] GI-180 Block (Borosilicate Cellular Glass Block) ----- 93

2. [EMSDS-21] GI-200A (Adesive Membrane, Resin) ---------------- 98

3. [EMSDS-22] GI-200B (Adesive Membrane, Hardener) ------------ 106

4. [EMSDS-31] GI-181A (Epoxy Primer, Resin) -------------------------- 114

5. [EMSDS-32] GI-181B (Epoxy Primer, Hardener) -------------------- 124

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GI-180 Block Lining System - Ecocera Material Safety Data Sheet
[EMSDS-1] GI-180 Block (Borosilicate Cellular Glass Block)

GI-180 Block (Borosilicate Cellular Glass Block)

------------------------------------------------------------------------
1. INFORMATION OF PRODUCT AND COMPANY
------------------------------------------------------------------------

1) Product Name : GI-180 Block (Borosilicate Cellular Glass Block)


2) General Characteristics : Chemical resistance, Low thermal conductivity etc.
3) Handle with care : storage at room temperature
4) Product Applications : Chimney lining for anti-corrosion
5) Manufacturer Information
(1) Manufacturing Company Name : ECOCERA CO., LTD.
(2) Address : #1812, 298, Beotkkot-ro, Geumcheon-gu, Seoul, 08510 Republic of Korea.
(3) Emergency contact phone number : +82-2-2083-8311
6) Supplier / distributor information : same as manufacturer
7) Written by department and name : Technical team
8) Create Date : January 10, 2002
9) Last revision date and revision number : January, 3rd , 2017

------------------------------------------------------------------------
2. NAME AND COMPOSITION OF COMPONENTS
------------------------------------------------------------------------

Composition(wt %) ----------------- Borosilicate glass


SiO2 ------------------ 65 ~75
B2O3 ------------------ Min. 10
etc.
Not indicated contents are confidential.

-----------------------------------
3. RISK AND HAZARD
-----------------------------------

1) Urgent danger, hazard information : None


2) Effect on eyes : None
3) Effect on the skin : None
4) Effect on Inhalation or Ingestion : None
5) Signs and symptoms of chronic : None

----------------------------------------------------------
4. EMERGENCY HANDLING MEASURE
----------------------------------------------------------
1) Eye contact : No data
2) When in contact with the skin : No data

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GI-180 Block Lining System - Ecocera Material Safety Data Sheet
[EMSDS-1] GI-180 Block (Borosilicate Cellular Glass Block)

3) Inhalation : No data
4) Ingestion : No data
5) Shelf : over 10(ten) years

----------------------------------------------
5. FIRE FIGHTING MEASURES
----------------------------------------------

1) Flash point : Not Applicable


2) Auto ignition : Not Applicable
3) Lowest explosion limit, up to the explosion limit (VOL.%) : N / A
4) By the category for the fire department regulations, and regulatory information : a flame-retardant solid.
5) Extinguishing Media : Non-combustible and non-flammable.
6) Ways to quell the fire, and equipment : N / A
7) Hazardous in case of fire : N / A
8) Extinguishing media not available : N / A

----------------------------------------------------------
6. ACCIDENTAL RELEASE MEASURES
----------------------------------------------------------

1) Measures to protect the body :


Mask & Wear the respiratory and protective clothes.
When a lot of dust blow, avoid continued inhalation.
2) Measures needed to protect the environment : N / A
3) Methods for cleaning : N / A

----------------------------------------------
7. HANDLING AND STORAGE
----------------------------------------------

1) Safe handling : When a lot of dust blow, avoid continued inhalation.


After handling, wash hands and face. Keep the kids from eating.
2) Storage : Keep the kids away from it.

-------------------------------------------------------------------------------------
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
-------------------------------------------------------------------------------------

1) Engineering measures : Existing storage methods such as the aggregates.


2) Respiratory protection : Frequent use or heavy exposure cases, breathing protection is needed.
3) Eyes protection : Safety goggles prevent dust particles entering the eye and can be used.
Washing facilities must be near from working site.
4) Hand protection : Wear a general gloves for working.
5) Body protection : Wear a general workwear, wash the face and hands after handling.
6) Hygiene precautions : Comply with the regulations of the government and local government.
7) Exposure limits : N / A

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GI-180 Block Lining System - Ecocera Material Safety Data Sheet
[EMSDS-1] GI-180 Block (Borosilicate Cellular Glass Block)

------------------------------------------------------------------
9. PHYSICAL AND CHEMICAL PROPERTIES
------------------------------------------------------------------

1) Appearance : Black colored solid


2) Smell : None.
3) pH : neutral or weak alkaline in water.
4) Water Solubility : None.
5) Boiling point : N / A
6) Melting point / Melting range : over 700 ℃
7) Explosive : None.
8) Oxidative : None.
9) Vapor Pressure : N / A
10) Specific Gravity : 0.17 ~ 0.21 (volume ratio)
11) Partition coefficient : N / A
12) Vapor Density : N / A
13) Viscosity : N / A
14) Molecular Weight : N / A
15) Chemical Resistance : Not soluble

---------------------------------------------------
10. STABILITY AND REACTIVITY
---------------------------------------------------

1) Chemical Stability : Stable


2) Materials to avoid : HF
3) Harmful decomposition substance : N / A
4) Chemical reaction stability : Under normal temperature and pressure conditions, harmful reactions are not
reported.

Acid Condensate Solutions & Gases Resistant Non-Resistant


*
Sulfuric Acid H2SO4 •
*
Nitric Acid, HNO3 •
*
Hydrochloric Acid, HCl •
*
Phosphoric Acid, H3PO4 •
*
Acetic Acid •
*
Hydrofluoric Acid, HF •
Steam Impingement •
BASE AND SALT SOLUTIONS
Ammonium Hydroxide, NH4OH •
Magnesium Hydroxide, Mg(OH)2 •
Calcium Hydroxide, Ca(OH)2 •
Potassium Hydroxide, KOH •
Sodium Hydroxide, NaOH •
Sodium Carbonate, Na2CO3 •
Sodium Chloride, NaCl •

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GI-180 Block Lining System - Ecocera Material Safety Data Sheet
[EMSDS-1] GI-180 Block (Borosilicate Cellular Glass Block)

*
Sodium Sulfate, Na2SO4 •
Sodium Sulfite, Na2SO3 •
Ammonium Nitrate, NH4NO •
ORGANICS
Heptane •
Kerosene •
Benzene •
Toluene •
Carbon Tetrachloride •
Methylene Chloride •
Acetone •
Methyl Ethyl Ketone •
Methanol •
Diethyl Ether •
Ethyl Acetate •

---------------------------------------------------------
11. TOXICOLOGICAL INFORMATION
---------------------------------------------------------

1) Acute oral toxicity : N / A


2) Acute dermal toxicity : N / A
3) Acute Inhalation Toxicity : N / A
4) Second rank acute toxicity : N / A
5) Chronic toxicity : N / A
6) Mutagenicity : N / A
7) Generation effect (teratogenetic) : N / A
8) Carcinogenic effects : N / A
9) Additional information, especially strange : N / A
---------------------------------------------------------
12. IMPACT ON THE ENVIRONMENT
---------------------------------------------------------

1) Ecological information : N / A
2) Soil mobility : N / A
3) Persistent and biodegradable : N / A
4) The possibility of biological accumulation : N / A

------------------------------------------------
13. DISPOSAL CONSIDERATION
------------------------------------------------

1) Waste Management Act Status : N / A (treated in a similar way like an aggregate)


2) Disposal method : To be handled by licensed waste disposal contractor.
3) Disposal Considerations : Comply with the regulations of the government and local government.

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[EMSDS-1] GI-180 Block (Borosilicate Cellular Glass Block)

------------------------------------------------
14. TRANSPORT INFORMATION
------------------------------------------------

1) Marine transport and marine safety regulations for hazardous materials rules and regulations by category :
N / A
2) Transport Precautions : Comply with the regulations of the government and local government.

-----------------------------------------
15. REGULATORY STATUS
-----------------------------------------

1) Regulations by occupational Safety and Health Act : N / A


2) Regulations by Hazardous Chemicals Control Act and other administrative departments of the chemical
substances : N / A
3) Other foreign Regulations : N / A

------------------------------
16. OTHER NOTES
------------------------------

* Source of data
1) Based on Material Safety Data Sheet for the creation and storage.
(The Korea Ministry of Labor Notification No.97-27)
2) Practical Affairs for Material Safety Data.
(Department of Labor, The Korea Occupational Safety and Health Agency, 1996.2)
3) Practical Affairs for Material Safety Data for a mixture.
(The Korea Occupational Safety and Health Agency)

* This MSDS was referred to MSDS of base materials in the website (www.kosha.net ) of the Korea
Occupational Safety and Health Agency.
* More information : ECOCERA CO., LTD. (www.ecocera.co.kr )

http://www.ecocera.co.kr

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[EMSDS-21] GI-200A (Adhesive Membrane, Resin)

GI-200A (Adhesive Membrane, Resin)

--------------------------------------------------------------------------------------------
1. INFORMATION OF CHEMICAL PRODUCTS AND COMPANY
--------------------------------------------------------------------------------------------

1) Product Name : GI-200A (Adhesive Membrane, Resin)


2) Hazard Classification : Hazard matters
3) Use of Product : Adhesive for Cellular Glass Block
4) Manufacturer Information
(1) Manufacturing Company Name : ECOCERA CO., LTD.
(2) Address : #1812, 298, Beotkkot-ro, Geumcheon-gu, Seoul, 08510 Republic of Korea.
(3) Emergency contact phone number : +82-2-2083-8311
5) Post in Charge : R & D
Person in Charge : Mr. Kim
6) Supplier / distributor information : same as manufacturer
7) Create Date : January 6th, 2002
8) Last revision date and revision number : January 3rd, 2017

---------------------------------------------------------------
2. NAME AND CONTENTS OF ELEMENTS
---------------------------------------------------------------

■ REGULAR CLASSIFICATION : Poly Glycol type urethane resin & Asphalt mastic

NAME OF CHEMICAL MATERIALS CAS NO CONTENT (%)

POLYPROPYLENE GLYCOL 25322-69-4 40∼60

ASPHALT 64742-93-4 30∼40

FILLER(Ceramics Powder) 14807-96-9 15∼25

CATALYST 3648-18-8 0.1∼1

----------------------------------------------------------
3. HEALTH HAZARD IDENTIFICATION
----------------------------------------------------------

1) CHEMICAL NAME : Does not classification.


a) Hazard-Risk Classification :
- Eye irritation : Category 2
- Respiratory sensitization : Category 1
- skin irritation : Category 2

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GI-180 Block Lining System - Ecocera Material Safety Data Sheet
[EMSDS-21] GI-200A (Adhesive Membrane, Resin)

b) Label elements including precautionary statements

- Symbol :

- Signal Word : Danger


- Hazard-Risk statements
H319 : Causes serious eye irritation
H332 : Harmful if inhaled.
H335 : May cause respiratory irritation
H336 : May cause drowsiness or dizziness
- Precautionary statements
• Prevention
P201 : Obtain special instructions before use
P202 : Do not handle until all safety precautions have been read and understood
P264 : Wash hands thoroughly after handling
P270 : Do not eat, drink or smoke when using this product
P280 : Wear protective gloves/protective clothing/eye protection/face protection
P285 : In case of inadequate ventilation wear respiratory protection
• Response
P303+P361+P353 : IF ON SKIN(or hair) :
Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340 : IF INHALED :
Remove victim to fresh air and keep at rest in a position comfortable for breathing
P307+P311 : IF exposed : Call a POISON CENTER or doctor/physician
P312 : Call a POISON CENTER or doctor/physician if you feel unwell
• Storage
P403+P233 : Store in a well-ventilated place. Keep container tightly closed.
P405 : Store locked up
• Disposal
P501 : Dispose the contents/container in accordance with local/regional/national
International regulations
c) Other hazard-risk which are not included in the classification criteria :
- NO information available.

-------------------------------------
4. FIRST AID MEASURE
-------------------------------------

1) Eye contact :
Irrigate with clean water, holding the eyelids apart, for at least 15 minutes.
Obtain medical attention if ill effects occur.

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[EMSDS-21] GI-200A (Adhesive Membrane, Resin)

2) Skin contact : Wash skin with water. If symptoms develop, obtain medical attention.
3) Inhalation : Remove patient from exposure, keep warm and at rest. Obtain medical attention if ill effects.
Get prompt medical attention.

4) Ingestion : Wash out mouth with water. Obtain medical attention if ill effects occur. Get prompt medical
attention.
5) Indication of immediate medical attention and notes for physician : Symptomatic treatment and supportive
therapy as indicated.

----------------------------------------------
5. FIRE-FIGHTING MEASURES
----------------------------------------------

1) Explosion Characteristics : No data.


2) Available Fire Extinguished : CO2, extinguisher, powder extinguisher, sand, soil, and sufficient water.
a) Suitable (and unsuitable) extinguishing media :
- Suitable extinguishing media : Foam, CO₂, Dry powder, water spray
- Unsuitable extinguishing media : -
b) Specific hazards arising from the chemical : nitrogen oxide
3) Way of Fire Fighting : With positive air supply, use regulated fire extinguishing equipment
a) Special protective equipment and precautions for fire-fighters :
Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing
(includes fire fighting helmet, coat, trousers, boots and gloves). If protective equipment is not available or
not used, fight fire from a protected location or safe distance.

------------------------------------------
6. LEAKAGE ACCIDENT
------------------------------------------

1) If a little: Wipe thoroughly with organic solvent. Spray the suction materials such as sawdust which has
strong absorptiveness, to abolish them all.
2) If overmeasure : Construct the spread prevention wall not to spread anymore, and pay attention to inflow
to the pipe. After mixing the major material portion to metalize, then remove it.

------------------------------------------------------------
7. ACCIDENTAL RELEASE MEASURES
------------------------------------------------------------
1) Personal precautions, protective equipment and emergency procedures :
Wear suitable protective clothing, protective gloves and protective goggles/mask.
2) Environmental precautions and protective procedures :
- Prevent product spill from entering sewers, streams, or drinking water supplies.
- Collect liquid or soak up with inert filler or an absorbent, such as dry earth, sand, or oil
absorbent(sweeping) compound
- Collect material into suitable containers for disposal.
3) Methods and materials for containment and cleaning up :

- Contain and absorb large spills on to an inert, non-flammable absorbent carrier (such as earth or

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[EMSDS-21] GI-200A (Adhesive Membrane, Resin)

sand)
- Shovel into open-top drums or plastic bags for further decontamination.
- Wash the spill area clean with a liquid decontaminant.
- Remove and properly dispose of residues.
----------------------------------------------
8. HANDLING AND STORAGE
----------------------------------------------
1-1) Handling : Wear appropriate chemical resistant clothing.
- Pay a special attention to contact with skin or eyes or steam inhalation, ingestion.
- Close the tube air-tight for spread protection.
- When use this product, keep storing place being well ventilated.
- Try to press down the steam spread and keep it below working environmental density to handle.

1-2) Precautions for safe handling :


- Ensure adequate ventilation or exhaust ventilation in the working area.
- Exhaust ventilation necessary if product is sprayed.
- Ensure proper electrical grounding procedures are in place.

2-1) Storing : Shut tube tightly using by 2 step caps, inside and outside.
- Keep away from sunlight and keep safe distance from a heat source.
- As possible, store it sheltered place at the normal temperature.
- Shelf : 3(three) years

2-2) Conditions for safe storage (including any incompatibilities) :


- Store in a cool, dry place, away from excessive heat, in original or similar container.
- Avoid unnecessary contact.
- Protect from freezing.
- Containers should be tightly sealed to prevent contamination with foreign materials.

-----------------------------------------------------------------------------------------------------------------------------------
9. INFORMATION OF EXPOSURE PROTECTION AND CHEMICAL RESISTANT CLOTHING
-----------------------------------------------------------------------------------------------------------------------------------
1) Exposure Protection : When using, estimate the consumption for rapid application, and have residual
quantity shut tightly in tube and store it in specified cool sheltered place.
2) PERSONAL PROTECTION EQUIPMENTS :
Respiration protection - Use officially recognized mask which installed cleaning filter.
Eyes protection – Wear protection glasses in order to avoid steam and liquid contact.
Hands protection – Wear rubber gloves or PVC coated protection gloves.
Body protection – Wear the impermeable protection clothing and shoes.

-----------------------------------------------------------------------------------
10. EXPOSURE CONTROLS & PERSONAL PROTECTION
-----------------------------------------------------------------------------------
1) Control parameters :

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[EMSDS-21] GI-200A (Adhesive Membrane, Resin)

Occupation Safety & Health Agency (OSHA)


Chemical name TWA STEL
ppm mg/m3 ppm mg/m3
Polypropylene glycol - - - -
Asphalt - 0.5 - -
Ceramic powder 2 - -

2) Appropriate engineering controls :


Use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels
below recommended exposure limit.

3) Personal protective equipment :


- Respiratory protection : An organic vapor cartridge or fresh air supplied respirator is recommended in
closed rooms or areas.
- Eye protection : Safety goggles or glasses are recommended.
- Hands protection : Use suitable protective gloves.
- Body protection : Wear suitable protective clothing.

-----------------------------------------------------------------------------
11. PHYSICAL AND CHEMICAL CHARACTERISTICS
-----------------------------------------------------------------------------

1) Appearance (physical state, color etc) : Asphalt Urethane Mastic, Black (when mixed with Part B : Black
elastomeric rubber )
2) Odor : smell of Asphalt
3) Odor threshold : Not available
4) pH : Not available
5) Melting point/Freezing point : Not available
6) Initial boiling point and boiling range : above 200℃
7) Flash point : Not available
8) Evaporation rate : Not available
9) Flammability (solid, gas) : Not available
10) Upper/lower flammability or explosive limits : -(upper)/-(lower) %
11) Vapor pressure : Not available
12) Solubility : - Not available
13) Vapor density : - Not available
14) Relative density (25℃) : 1.05~1.1 Kg/Liter
15) Partition coefficient : n-octanol/water : Not applicable
16) Auto-ignition temperature : Not available
17) Decomposition temperature : Not available
18) Viscosity : Paste
19) Molecular weight : Not available
20) Smell : Asphalt & Tar
21) Melting Rate : Melted by many organic solvents.
22) Ignition Temperature : min. 204℃

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[EMSDS-21] GI-200A (Adhesive Membrane, Resin)

---------------------------------------------------
12. STABILITY AND REACTIVITY
---------------------------------------------------
1) Stability : Safe at recommended cool sheltered place.
Become when react with polyisocyanate.
Exposure in high temperature for a long time, makes tube expand due to steam pressure.
a) Chemical stability and possibility of hazardous reaction :
- Chemical stability : Stable at normal temperatures and pressures
- Possibility of hazardous reaction : Not available

2) Incompatible Materials and Conditions to avoid : Polyisocyanate, Lighter, Spark, Over heating, Strong
oxidation materials, Steel oxide.

a) Conditions to avoid (e.g. static discharge, shock or vibration, etc) :


isocyanate, Heat, sparks, open flame, and other ignition sources.
b) Incompatible materials : -

3) HAZARD MATTERS WHEN DISJOINTING : C2 compounds.


a) Hazardous decomposition products : Not available

---------------------------------------------------------------------------------------------------------------
13. INFORMATION OF VIRULENCE & ITOXICOLOGICAL INFORMATION
---------------------------------------------------------------------------------------------------------------
1) Oral Virulence : May cause irritation to mouth and stomach. May cause difficulty in breathing, diarrhea,
abdominal spasm.
2) Inhalation Virulence : Difficulty in breathing, irritation to respiratory organ.
3) Skin Contact Virulence : Contacting skin for a long time may cause skin damage and a foam.

a) Information on the likely routes of exposure : Not available


b) Health hazards information :
- Acute toxic :
• Oral : Polypropylene - Not available
Asphalt - LD50 5,000mg/kg Rat
Ceramic powder - Not applicable
• Dermal : Polypropylene - Not available
Asphalt LD50 2,000mg/kg Rabbit
Ceramic powder - Not applicable
• Inhalation : Polypropylene - Not available
Asphalt - LC50 5.28mg/ℓ4hr Rat
Ceramic powder - Not applicable

- Skin corrosive/irritant : Not available


- Serious eye damage/eye irritation : Not available
- Respiratory sensitization : Not available
- Skin sensitization : Not available

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[EMSDS-21] GI-200A (Adhesive Membrane, Resin)

- Carcinogenicity : Not available


- Germ Cell Mutagenicity : Not available
- Reproductive toxicity : Not available
- Specific target organ toxicity (single exposure) : Not available
- Specific target organ toxicity (repeated exposure) : Not available
- Aspiration hazard : Not available

-----------------------------------------------------------------------------------------------------------------------------------
14. INFORMATION OF ENVIRONMENTAL EFFECTS & ECOLOGICAL INFORMATION
-----------------------------------------------------------------------------------------------------------------------------------
1) Characteristic of Water, Plants and Ecology :
Decline the growth promotion.
Plants will wither to death.
2) Remaining and Resolvability : No data.
3) Liquid has viscosity, so does not depart without artificiality.
Make a C2 compounds.
a) Aquatic and terrestrial ecotoxicity :
- Fishes : Not available
- Crustacean : Not available
- Birds : Not available
b) Persistence and degradability :
- Persistence : Not available
- degradability : Not available
c) Bioaccumulative potential :
- Bioaccumulation : Not available
- Biodegradation : Not available
d) Mobility in soil : Not available
e) Other adverse effects : Not available

---------------------------------------------
15. CAUTION AT ABOLITION
---------------------------------------------
Way to Abolition : Classify it as special scrapped material to be scrapped only by licensed disposal
company as industrial waste.
When destruction, it is desirable to mix the material to metalize.
---------------------------------------------------------
16. TRANSPORTATION INFORMATION
---------------------------------------------------------
1) Receptacle : Use the recommended receptacles.
2) Loading : Use steel can and shut tightly using by 2 step caps, inner and outer.
After closing tightly each container and check it, oad with three plies and shield outside
with vinyl wrap for preventing them from dropping or collapsing.
3) Carrying : Carry the emergency equipment and absorbent materials and instruct the carrying agent to
pay special attention.

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[EMSDS-21] GI-200A (Adhesive Membrane, Resin)

-------------------------------------------------
17. DISPOSAL CONSIDERATIONS
-------------------------------------------------
1) Disposal method : Waste must be disposed of accordance with federal, state and local environmental
control regulations.
2) Disposal precaution (including the disposal method of contaminated container and packaging) :
Consider the require attentions in accordance with waste treatment management regulation.

------------------------------------------------
18. TRANSPORT INFORMATION
------------------------------------------------

1) UN number : none
2) UN proper shipping name : ADHESIVES
3) Transport hazard class : Not applicable
4) Packing group : Not applicable
5) Marine pollution(yes/no) : No
6) Special safety response for transportation or transportation measures : Not applicable

---------------------------------------------------
19. REGULATORY INFORMATION
---------------------------------------------------
1) Industrial Safety and Health Act : Korea Occupational Safety and Health Regulation
2) Toxic Chemical Control Act : Not listed
3) Dangerous Material Safety Control Act : Not applicable
4) Wastes Management Act : Not applicable
5) Other requirements in domestic and other countries : Not applicable

-------------------------------------------
20. INFORMATION OF LAW
-------------------------------------------
1) Observe government laws and regulations, or self-governing body's rules.

----------------------------------------
21. OTHER INFORMATION
----------------------------------------
1) Information source and references :
- Asphalt MSDS, Polypropylene MSDS, ceramic powder MSDS.
- KOSHA (Korea Occupational Safety & Health Agency : www.kosha.or.kr

---------------------
22. REMARK
---------------------
Data Source : Urethan resin Handbook, Chemical products Dictionary
More Information : ECOCERA CO., LTD. (www.ecocera.co.kr)

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[EMSDS-22] GI-200B (Adhesive Membrane, Hardener)

GI-200B (Adhesive Membrane, Hardener)

--------------------------------------------------------------------------------------------
1. INFORMATION OF CHEMICAL PRODUCTS AND COMPANY
--------------------------------------------------------------------------------------------

1) Product Name : GI-200B (Adhesive Membrane, Hardener)


2) Hazard Classification : Hazard matters
3) Use of Product : Adhesive Hardener
4) Manufacturer Information
(1) Manufacturing Company Name : ECOCERA CO., LTD.
(2) Address : #1812, 298, Beotkkot-ro, Geumcheon-gu, Seoul, 08510 Republic of Korea.
(3) Emergency contact phone number : +82-2-2083-8311
5) Post in Charge : R & D
Person in Charge : Mr. Kim
6) Supplier / distributor information : same as manufacturer
7) Create Date : September 16th, 2002
8) Last revision date and revision number : January 3rd, 2017

-----------------------------------------------------------------
2. NAME AND CONTENTS OF ELEMENTS
-----------------------------------------------------------------

■ REGULAR CLASSFICATION : Isocyanate

NAME OF CHEMICAL MATERIALS CAS NO CONTENT (%)


Diphenylmethane Diisocyanate, isomers and
916-87-9 100
homologues

----------------------------------------------------------
3. HEALTH HAZARD IDENTIFICATION
----------------------------------------------------------

1) Chemical Name : Isocyanate Prepolymer


a) Hazard-Risk Classification :
- Skin Irritation
- Eye irritation
b) Label elements including precautionary statements
- Symbol :

- Signal Word : Danger

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[EMSDS-22] GI-200B (Adhesive Membrane, Hardener)

- Hazard-Risk statements
Harmful if swallowed (H302)
Causes skin irritation (H315)
Causes severe eye irritation (H319)
May cause respiratory irritation (H335)
Prolonged or repeated exposure Causes damage to organs (H372)
- Precautionary statements
• Prevention
Obtain special instructions before use (P201)
Do not handle until all safety precautions have been read and understood (P202)
Do not breathe dust/fume/gas/mist/vapours/spray (P260)
Wash hands thoroughly after handling (P264)
Do not eat, drink or smoke when using this product (P270)
Use only outdoors or in a well-ventilated area (P271)
Avoid release to the environment (P273)
Wear protective gloves/protective clothing/eye protection/face protection (P280)
Please wear appropriate personal protective equipment (P281)
• Response
If you feel uncomfortable swallowed : Call a medical assistance (doctor) (P301 + P312)
If on skin : Wash with plenty of soap and water Do (P302 + P352)
Inhalation: Remove victim to fresh air and comfortable for breathing
Please take a stable (P304 + P340)
If in eyes : Remove contact lenses, please Rinse cautiously with water for several
minutes, if possible. Continue Wash (P305 + P351 + P338)
Exposure : Call for medical assistance (doctor) (P307 + P311)
• Storage
Tightly closed in a well-ventilated place Keep container store (P403 + P233)
Store in sealed (P405)
• Disposal
P501 : Dispose the contents/container in accordance with local/regional/national
International regulations
c) Other hazard-risk which are not included in the classification criteria : Not available

-------------------------------------
4. FIRST AID MEASURE
-------------------------------------
1) Eye contact :
Rinse with plenty of water, also under the eyelids, for at least 15 minutes.
Obtain medical attention.
Get medical attention.
2) Skin contact :
Wash off immediately with soap and plenty of water. Obtain medical attention.
3) Inhalation :

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[EMSDS-22] GI-200B (Adhesive Membrane, Hardener)

Move to fresh air in case of accidental inhalation of vapours. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen, provided a qualified operator is available. Call a physician immediately.
Get prompt medical attention.
4) Ingestion : Immediately rinse mouth and provide fresh air. Get medical attention immediately.
5) Indication of any immediate medical attention and notes to physician : Treat symptomatically and
supportively.

----------------------------------------------
5. FIRE-FIGHTING MEASURES
----------------------------------------------

1) Explore Characteristics : No data


2) Fire Extinguishers : Large amount of water, dry sand, CO2, powder extinguisher, etc.
a) Suitable (and unsuitable) extinguishing media :
- Suitable extinguishing media : Foam, CO₂, Dry powder, Water spray
- Unsuitable extinguishing media : -
3) Way of Fire Fighting : With positive air supply and spray extinguishers.
4) Hazard Matters when Firing : Generates heavy soot, smokes and hazardous oxide.
a) Special hazards arising from the chemical : Carbon monoxide, Carbon dioxide, Halogenated compound
b) Special protective equipment and precautions for fire-fighters :
As in any fire, wear a self-contained breathing apparatus (SCBA) in pressure-demand, and protective
fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective
equipment is not available, fight fire in a protected location or safe distance.

----------------------------------------------------
6. WAY OF LEAKAGE ACCIDENT
----------------------------------------------------

1) If a Little : Wipes clearly by rag.


2) If Over-measure : Construct the spread prevention wall to prevent more spread.
Put into airtight box and treat it as industrial abolition waste to be treated only by
licensed scrapping company.

------------------------------------------------------------
7. ACCIDENTAL RELEASE MEASURES
------------------------------------------------------------

1) Personal precautions, protective equipment and emergency procedures :


Wear suitable protective clothing, protective gloves and protective goggles/mask.
2) Environmental precautions and protective procedures :
- Prevent product spill from entering sewers, streams, or drinking water supplies.
- Collect liquid or soak up with inert filler or an absorbent, such as dry earth, sand, or oil
absorbent(sweeping) compound.
- Collect material into suitable containers for disposal.
3) Methods and materials for containment and cleaning up :
- Contain and absorb large spills on to an inert, non-flammable absorbent carrier such as earth or sand.

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[EMSDS-22] GI-200B (Adhesive Membrane, Hardener)

- Shovel into open-top drums or plastic bags for further decontamination.


- Wash the spill area clean with a liquid decontaminant.
- Remove and properly dispose of residues.

------------------------------------------------------------
8. HANDLING AND STORING METHOD
------------------------------------------------------------

1) Handling : Wear appropriate chemical resistant clothing.


Pay a special attention not to contact with skin or eyes or steam inhalation, ingestion.
a) Precautions for safe handling :
- Ensure adequate ventilation.
- Exhaust ventilation necessary if product is sprayed.

2) Storing : Use airtight box and keep from direct sun and keep safe distance from heat source.
a) Conditions for safe storage (including any incompatibilities) :
- Store in a cool, dry, well-ventilated area away from incompatible substances.
- Avoid unnecessary contact.
- Containers which are opened must be carefully resealed.
- Protect from extremes of temperature and direct sunlight.

-----------------------------------------------------------------------------------------------------------------------------------
9. INFORMATION OF EXPOSURE PROTECTION AND CHEMICAL RESISTANT CLOTHING
-----------------------------------------------------------------------------------------------------------------------------------
1) Exposure Protection : Keep in airtight box and avoid loading over three plies while carrying or
loading.
a) the chemical exposure limits and biological exposure limits
- Domestic Regulation: TWA - 50ppm 175mg /m³ (Methylene Chloride)
- ACGIH American Policy: No data
- Biological Exposure limits: No data
b) Engineering Controls: Use local exhaust ventilation, or closed

2) PERSONAL PROTECTION EQUIPMENTS :


Respiration protection - Use officially recognized mask which installed cleaning filter.
Eyes protection – Wear the protection glasses in order to avoid steam and liquid contact.
Hands protection - Wear the rubber gloves or PVC coated protection gloves.
Body protection - Wear the impermeable protection clothing and shoes.
a) Personal Protection
- Respiratory protection: Gas mask (organic gas for)
- Eye protection: safety glasses
- Protection of hands: Protective gloves (rubber oil resistant type)
- body protection: the protection (of the anti-war), protective aprons, protective Chemistry (Chemistry
antistatic)

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-----------------------------------------------------------------------------
10. PHYSICAL AND CHEMICAL CHARACTERISTICS
-----------------------------------------------------------------------------

1) Appearance (physical state, color, etc.): Dark Amber liquid


2) Odor : Musty
3) Odor threshold : Not available
4) pH : Not available
5) Melting point/Freezing point : <0℃
6) Initial boiling point and boiling range : <200 ℃
7) Flash point : >204℃
8) Evaporation rate : No data
9) Flammability (solid, gas) : No data
10) Flammable Range High / Low : No data
11) Vapor Pressure : <0.1Pa (25 ℃)
12) Solubility : Reacts with water
13) Vapor Density (25℃) : 2.9 Kg/Liter
14) Specific gravity : 8.5
15) n- octanol / water partition coefficient : Not applicable
16) Self-ignition temperature : > 600℃
17) Decomposition Temperature : >230℃
18) Viscosity : 100 - 250 cps / 25 ℃
19) Molecular weight : Not available
20) SMELL : Odor-free
21) MELTING RATE : Melted by many organic solvents.

---------------------------------------------------
11. STABILITY AND REACTIVITY
---------------------------------------------------

1) Chemical Stability : Safe at recommended cool sheltered place.


Become active when react with the air.
a) Chemical stability and possibility of hazardous reaction :
- Chemical stability : Refer to <Section 7. Handling and storage>.
- Possibility of hazardous reaction : Exposure to high temperature may cause decomposition and gases.
b) Conditions to avoid (e.g. static discharge, shock or vibration, etc) :
Heat, sparks, open flame, and other ignition sources.
2) Physical Stability : If not contacting with air, it is safe.
3) Incompatible Materials and Conditions to Avoid :
Conditions - High temperature, direct sunlight, flammable materials, and moisture.
a) Incompatible materials : High pressure gas
b) Hazardous decomposition products : Does not cause hazardous decomposition products in normal
conditions of storage and use, hazardous decomposition products.

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---------------------------------------------------------------------------------------------------------
12. INFORMATION OF VIRULENCE & TOXICOLOGICAL INFORMATION
---------------------------------------------------------------------------------------------------------

1) Skin Contact : Skin irritation.


2) Ingestion : Vomiting, stomachache.
a) Information on the likely routes of exposure : Not available
b) Health hazards information
- Acute toxic :
• Oral : LD50 10,000mg/kg Rat
• Dermal : LD50 > 10,000mg/kg Rabbit
• Inhalation : LC50 0.49mg/ℓ 4hr Rat
- Skin corrosive/irritant : Causes skin irritation.
- Serious eye damage/eye irritation : Causes severe eye irritation
- Respiratory sensitization : May cause respiratory reactions alreuregi
- Skin sensitization : May cause reaction on contact with skin alreuregi
- Carcinogenicity : Not available
- Germ Cell Mutagenicity : Not available
- Reproductive toxicity : Not available
- Specific target organ toxicity (single exposure) : respiratory tract irritation
- Specific target organ toxicity (repeated exposure) : respiratory system and lung tissue injury possibility
- Aspiration Hazard : Not available:

-----------------------------------------------------------------------------
13. INFORMATION OF ENVIRONMENTAL EFFECTS
-----------------------------------------------------------------------------

1) The condition out of metalizing reactivity by moisture, it has no material change.


2) Difficult to destruct by fire, and there is no disjointing reactivity alone.
So it remains permanently and causes the environmental pollution.
3) When firing for destruction, it generates heavy soot and causing the air pollution.

-------------------------------------------------
14. ECOLOGICAL INFORMATION
-------------------------------------------------
1) Ecotoxicity
- Fishes : LC50 > 10,000㎎/l 96Hr
- Crustacean : EC50 >10,000㎎/l 24Hr
- Birds : Not available
2) Persistence and degradability : Not nearly biodegradable
3) Bioaccumulation : No possibility of accumulation within the organism
4) Mobility : Not available
5) Other adverse effects : Not available

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[EMSDS-22] GI-200B (Adhesive Membrane, Hardener)

---------------------------------------------
15. CAUTION AT ABOLITION
---------------------------------------------

Way to Abolition : Classify it as special scrapped material to be scrapped only by licensed disposal
company as industrial waste. When destruction, it is desirable to mix the material
to metalize.

----------------------------------------------------------
16. TRANSPORTATION INFORMATION
----------------------------------------------------------

1) Receptacle : Use the recommended receptacles.


2) Loading : Use steel can and shut tightly using by 2 step caps, inner and outer.
After closing tightly each container and check it, load with three plies and shield outside
with vinyl wrap for preventing them from dropping or collapsing.
3) CARRYING : Carry the emergency equipment and absorbent materials and instruct the carrying agent to
pay special attention.

-------------------------------------------------
17. DISPOSAL CONSIDERATIONS
-------------------------------------------------

1) Disposal method : Waste must be disposed of accordance with federal, state and local environmental
control regulations.
2) Disposal precaution (including the disposal method of contaminated container and packaging) :
Consider the require attentions in accordance with waste treatment management regulation.

------------------------------------------------
18. TRANSPORT INFORMATION
------------------------------------------------

1) Receptacle : Use the recommended receptacles.


2) Loading : Use steel can and shut tightly by 2 step caps, inner and outer.
After closing tightly each container and check it, load with three plies and shield outside
with vinyl wrap for preventing them from dropping or collapsing.
3) CARRYING : Carry the emergency equipment and absorbent materials and instruct the carrying agent to
pay special attention.

a) UN number : No
b) UN proper shipping name : No
c) Transport hazard class : No
d) Packing group : No
e) Marine pollution(yes/no) : No
f) Special safety response for transportation or transportation measures : Not available

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[EMSDS-22] GI-200B (Adhesive Membrane, Hardener)

---------------------------------------------------
19. REGULATORY INFORMATION
---------------------------------------------------

1) Industrial Safety and Health Act : Creating a Material Safety Data Sheet, Beach and warning signs by
Article 41 Occupational Applies to attach
2) Regulated by TCCA :
Pursuant to Article 2 Section 3 of the law corresponds to the toxic
Diphenylmethane-4,4'-diisocyanate (MDI), CAS No: 101-68-8
Content limit of 25%
3) Dangerous Material Safety Control Act : The four kinds of petroleum fourth / Hazard Class Ⅲ /
non-aqueous
4) Wastes Management Act : Designated Waste
5) Other requirements in domestic and other countries : Not applicable

-------------------------------------------
20. INFORMATION OF LAW
-------------------------------------------

- Observe government laws and regulations, or self-governing body's rules.

-------------------------------------------
21. OTHER INFORMATION
-------------------------------------------

1) Information source and references :


- PAPI 135 Polymeric MDI MSDS
- LUPRANATE M20S MSDS

---------------------
22. REMARK
---------------------

Data Source : Urethan resin Handbook, Chemical products Dictionary


More Information : ECOCERA CO., LTD. (www.ecocera.co.kr)

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[EMSDS-31] GI-181A (Epoxy Primer, Resin)

GI-181A (Epoxy Primer, Resin)

--------------------------------------------------------------------------------------------
1. INFORMATION OF CHEMICAL PRODUCTS AND COMPANY
--------------------------------------------------------------------------------------------

1) Product Name : GI-181A (Epoxy Primer, Resin)


2) Hazard Classification : Hazard matters
3) Use of Product : PRIMER
4) Manufacturer Information
(1) Manufacturing Company Name : ECOCERA CO., LTD.
(2) Address : #1812, 298, Beotkkot-ro, Geumcheon-gu, Seoul, 08510 Republic of Korea.
(3) Emergency contact phone number : +82-2-2083-8311
5) Post in Charge : R & D
Person in Charge : Mr. Kim
6) Supplier / distributor information : same as manufacturer
7) Create Date : 28 JAN, 2002
8) Last revision date and revision number : 6th JAN, 2017

---------------------------------------------------------------
2. NAME AND CONTENTS OF ELEMENTS
---------------------------------------------------------------

■ REGULAR CLASSIFICATION : 2 Liquid type epoxy primer

NAME OF CHEMICAL MATERIALS CAS NO CONTENT (%)

4.4’-bisphenol polymer with oxirane 9002-98-6 80 ~ 90

Butyl glycidyl ether 67-56-1 10 ~ 20

-----------------------------------------------------------------------------------
3. HEALTH HAZARD IDENTIFICATION
------------------------------------------------------------------------------------

1) Hazard-Risk Classification :
- Flammable liquid : Category 3
- Eye irritation : Category 2
- Skin irritation : Category 2
- Chronic aquatic toxicity : Category2

2) Label elements including precautionary statements

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[EMSDS-31] GI-181A (Epoxy Primer, Resin)

- Symbol :

- Signal Word : Danger


- Hazard-Risk statements
H302 : Harmful if swallowed
H311 : Toxic in contact with skin
H315 : Cause skin irritation
H317 : May cause an allergic skin reaction
H319 : Causes serious eye irritation
H332 : (gas)Harmful if inhaled
H341 : Suspected of causing genetic defects
H351 : Suspected of cancer
H441 : Toxic to aquatic life with long lasting effects
- Precautionary statements
• Prevention
P201 : Obtain special instructions before use
P202 : Do not handle until all safety precautions have been read and understood
P261 : Avoid breathing dust/fume/gas/mist/vapours/spray
P264 : Wash hands thoroughly after handling
P270 : Do not eat, drink or smoke when using this product
P271 : Use only outdoors or in a well-ventilated area
P272 : Contaminated work clothing should not be allowed out of the workplace
P273 : Avoid release to the environment
P280 : Wear protective gloves/protective clothing/eye protection/face protection
P281 : Use personal protective equipment as required
• Response
P301+P312 : IF SWALLOWED : Call a POISON CENTER or doctor/physician if you feel
P302+P352 : IF ON SKIN : Wash with plenty of soap and water
P304+P340 : IF INHALED : Remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 : IF IN EYE : Resin cautiously with water for several minutes.
Remove contact lenses, if present and easy to go
Continue rinsing
P308+P313 : IF exposed or concerned : Get medical advice/attention
P363 : Wash contaminated clothing before reuse.
• Storage
P405 : Store locked up
• Disposal
P501 : Dispose the contents/container in accordance with local/regional/national/International regulations.

3) Other hazard-risk which are not included in the classification criteria :

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GI-180 Block Lining System - Ecocera Material Safety Data Sheet
[EMSDS-31] GI-181A (Epoxy Primer, Resin)

NFPA ratings (Scale 0~4)


- Health : 2, Flammability : 2, Reactivity : 0

-------------------------------------
4. FIRST AID MEASURE
-------------------------------------

1) EYE CONTACT : Flush eyes with large amount of water or isotonic saline until irritation subsides.
Get medical attention.
a) Eye contact :
- Do not rub your eyes
- Immediately flush eye with plenty of water for at least 15 minutes and call a.
- go to the hospital immediately if symptoms(flare, irritate) occur.
- Remove contact lenses if worn.

2) SKIN CONTACT : Wash with ethyle alcohol and flush enough with large amount of water.
a) Skin contact :
- Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing.
- go to the hospital immediately if symptoms(flare, irritate) occur.
- Laundering enough contaminated clothing before reuse.
- Prevent the spread of the skin.

3) INGESTION : Move the victim to air fresh place and keep at rest.
Get prompt medical attention.
a) Inhalation :
- when exposed to large amounts of steam and mist, move to fresh air.
- Take specific treatment if needed.
- Get medical attention immediately.
- If breathing is stopped or irregular, give artificial respiration and supply oxygen.

b) Ingestion
- About whether I should induce vomiting Take the advice of a doctor.
- Rinse your mouth with water immediately.
- Get medical attention immediately.
- Take the doctor's examination.
- Wash thoroughly after handling.

c) Delayed and immediate effects and also chronic effects from short and long term exposure
- Not available
d) Notes to Physician
- Notify medical personnel of contaminated situations and have them take appropriate protective
- IF exposed or concerned, get medical attention/advice.

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[EMSDS-31] GI-181A (Epoxy Primer, Resin)

---------------------------------------------------------
5. FIRE AND EXPLOSION & FIRE-FIGHTING MEASURES
---------------------------------------------------------
1) EXPLOSION CHARACTERISTICS : No data.

2) FIRE EXTINGUISHERS : Large amount of water, dry sand, CO2, powder extinguisher, etc.
a) Suitable (and unsuitable) extinguishing media :
- Avoid use of water jet for extinguishing.
b) Specific hazards arising from the chemical : nitrogen oxide
- Not available
3) FIRE FIGHTING : With positive air supply and spray extinguishers.
a) Special protective equipment and precautions for fire-fighters :
- Move containers from fire area, if you can do without the risk.
- Keep unauthorized personnel out.
- Withdraw immediately in case of rising sound from venting safety devices or discoloration
- Using a unattended and water devices in case of large fire and leave alone to burn if you do not
imperative.
- Do not access if the tank on fire.
- Vapor or gas is burned at distant ignition sources can be spread quickly.

4) HAZARD MATTERS WHEN FIRING : Generates heavy soot and smoke and hazardous oxide.

----------------------------------------------------
6. WAY OF LEAKAGE ACCIDENT
----------------------------------------------------

1) IF A LITTLE : Wipes clearly by rag.


2) IF OVER-MEASURE : Construct the spread prevention wall to prevent more spread.
Put into airtight box and treat it as industrial waste to be treated and processed by
licensed scrapping company. After mixing the main material to metalize, remove it.

------------------------------------------------------------
7. ACCIDENTAL RELEASE MEASURES
------------------------------------------------------------

1) Personal precautions, protective equipment and emergency procedures :


- Wear proper personal protective apparatus as indicated in section 8 and avoid skin contact and inhalation.
- Must work against the wind let the upwind people to evacuate..

2) Environmental precautions and protective procedures :


- Prevent runoff and contact with waterways, drains or sewers.
- if large amounts have been spilled, inform the relevant authorities.
3) Methods and materials for containment and cleaning up :
- Large spill : Stay upwind and keep out of low areas. Dike for later disposal.
- Notification to central government, local government. When emissions at least of the standard

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[EMSDS-31] GI-181A (Epoxy Primer, Resin)

- Dispose of waste in accordance with local regulation.


- Appropriate container for disposal of spilled material collected.
- Small leak: sand or other non-combustible material, please let use absorption.
- Wipe off the solvent.
- Dike for later disposal.
- Prevent the influx to waterways, sewers, basements or confined spaces.

------------------------------------------------------------
8. HANDLING AND STORING METHOD
------------------------------------------------------------

1) HANDLING : Wear appropriate chemical resistant clothing.


Pay a special attention NOT TO contact with skin or eyes or steam inhalation and
ingestion.

a) Precautions for safe handling :


- Avoid contact with incompatible materials.
- Dealing only with a well-ventilated place.
- Do not handle until all safety precautions have been read and understood.
- Operators should wear antistatic footwear and clothing.
- Do not inhale the steam prolonged or repeated.
- Contaminated work clothing should not be allowed out of the workplace.

2) STORING : Use airtight can and keep out from sunlight and keep a safe distance from a heat source.
- Shelf : 2 (two) years

a) Conditions for safe storage (including any incompatibilities) :


- Save in cool, dry and well ventilated place.
- Save applicable laws and regulations.
- Avoid direct sunlight.
- No open fire.
- Prevent static electricity and keep away from combustible materials or heat sources.
- By specifying a storage area for carcinogenic substances.
- Collected them in sealed containers.
- Do not eat, drink or smoke when using this product.
- Store away from water and sewer.

-----------------------------------------------------------------------------------------------------------------------------------
9. INFORMATION OF EXPOSURE PROTECTION AND CHEMICAL RESISTANT CLOTHING
-----------------------------------------------------------------------------------------------------------------------------------

1) EXPOSURE PROTECTION : Keep in airtight box and avoid loading over three piles while carrying or
loading.
2) PERSONAL PROTECTION EQUIPMENTS :
Apnea protection - Use the officially recognized mask which installed cleaning filter.

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GI-180 Block Lining System - Ecocera Material Safety Data Sheet
[EMSDS-31] GI-181A (Epoxy Primer, Resin)

Eyes protection - Wear protection glasses in order to avoid steam and liquid contact.
Hands protection – Wear rubber gloves or PVC coated protection gloves.
Body protection - Wear the impermeable protection clothing and shoes.

-----------------------------------------------------------------------------------
10. EXPOSURE CONTROLS & PERSONAL PROTECTION
-----------------------------------------------------------------------------------

1) Control parameters : ACGIH TLV : Butyl glycidyl ether] : TWA 3 ppm

2) Appropriate engineering controls :


- A system of local and/or general exhaust is recommended to keep employee exposures above the
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of
the contaminant at its source, preventing dispersion of it into the general work area.
The use of local exhaust ventilation is recommended to control emissions near the source.

3) Personal protective equipment


- Respiratory protection :
• Under conditions of frequent use or heavy exposure, Respiratory protection may be needed.
• Respiratory protection is ranked in order from minimum to maximum.
• Consider warning properties before use.
• Any chemical cartridge respirator with organic vapor cartridge(s).
• Any chemical cartridge respirator with a full facepiece and organic vaporcartridge(s).
• Any air-purifying respirator with a full facepiece and an organic vapor canister.
• For Unknown Concentration or Immediately Dangerous to Life or Health :
Any supplied-air respirator with full facepiece and operated in a pressure-demand or other
positive-pressure mode in combination with a separate escape supply.
Any self-contained breathing apparatus

-----------------------------------------------------------------------------
11. PHYSICAL AND CHEMICAL CHARACTERISTICS
-----------------------------------------------------------------------------
1) Appearance (physical state, color etc) : Clear color liquid (when mixed with Part B : Light Amber color,
Rigid)
2) Odor : smell of resin
3) Odor threshold : Not available
4) pH : Not available
5) Melting point/Freezing point : Not available
6) Initial boiling point and boiling range : above 170℃
7) Flash point : 120℃
8) Evaporation rate : Not available
9) Flammability (solid, gas) : Not available
10) Upper/lower flammability or explosive limits : Not available
11) Vapor pressure : 0.43KPa at 25℃

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12) Solubility : Negligible


13) Vapor density : 3.78
14) Relative density (25℃) : 1.14 Kg/Liter
15) Partition coefficient : n-octanol/water : Not available
16) Auto-ignition temperature : Not available
17) Decomposition temperature : Not available
18) Viscosity : 1,100~2,000 cps at 25℃
19) Molecular weight : Not available
20) SMELL : Butyl Glycidyl Ether
21) MELTING RATE : Melted by a little water or many organic solvents.

---------------------------------------------------
12. STABILITY AND REACTIVITY
---------------------------------------------------

1) CHEMICAL STABILITY : Safe at cool sheltered storage place. Become feverish when react with amine.

a) Chemical stability and possibility of hazardous reaction :


This material is stable under recommended storage and handling conditions.
b) Possibility of hazardous reaction : Hazardous polymerization will not occur.
2) PHYSICAL STABILITY : Safe at recommended keeping place.
3) INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID :
Conditions - High temperature, direct sunlight, flammable materials - Amine type
a) Incompatible materials : Not available
b) Hazardous decomposition products : Not available

-------------------------------------------------------
13. TOXICOLOGICAL INFORMATION
-------------------------------------------------------
1) Information on the likely routes of exposure : Not available
2) Health hazards information :
- Acute toxic :
• Oral : 4,4'-bisphenol polymer with oxirane : LD50 1001
Butyl glycidyl ether : LD50 1660 ㎎/㎏ Rat
• Dermal : 4,4'-bisphenol polymer with oxirane] : LD50
Butyl glycidyl ether : LD50 788 ㎎/㎏ Rabbit
• Inhalation : Butyl glycidyl ether : LC50 2590 ppm 4 hr Rat
- Skin corrosive/irritant : Cause skin irritant
- Serious eye damage/eye irritation : Cause serious eye irritation
- Respiratory sensitization : Not available
- Skin sensitization : May cause an allergic skin reaction.
- Carcinogenicity : Not available
- Germ Cell Mutagenicity : Suspected of causing genetic defects.
- Reproductive toxicity : Not available
- Specific target organ toxicity (single exposure) : Not available

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GI-180 Block Lining System - Ecocera Material Safety Data Sheet
[EMSDS-31] GI-181A (Epoxy Primer, Resin)

- Specific target organ toxicity (repeated exposure) : Not available


- Aspiration hazard : Not available
-------------------------------------------------
14. ECOLOGICAL INFORMATION
-------------------------------------------------

1) Aquatic and terrestrial ecotoxicity :


- Fish : 4,4'-bisphenol polymer with oxirane : LC50 1.41mg/ℓ
- Crustaceans : 4,4'-bisphenol polymer with oxirane : EC50 1.7mg/ℓ
- Birds : Not available
2) Persistence and degradability :
- Persistence : 4,4'-bisphenol polymer with oxirane : log Kow 2.821
- degradability : Not available
3) Bioaccumulative potential :
- Bioaccumulation : 4,4'-bisphenol polymer with oxirane : BCF0.56~0.67
- Biodegradation : 4,4'-bisphenol polymer with oxirane : 0%, 28Day
4) Mobility in soil : Not available
5) Other adverse effects : Not available

----------------------------------------------------
15. INFORMATION OF VIRULENCE
----------------------------------------------------

1) SKIN CONTACT : Skin irritation.


2) INGESTION : Vomiting, stomachache.

-----------------------------------------------------------------------------
16. INFORMATION OF ENVIRONMENTAL EFFECTS
-----------------------------------------------------------------------------

1) Except metalizing reaction with amine, it has no material change.


2) Difficult to destruct by fire and there is no disjointing reactivity alone.
So it remains permanently and causing the environmental pollution.
3) When firing for destruction, it generates heavy soot and causing the air pollution.

---------------------------------------------
17. CAUTION AT ABOLITION
---------------------------------------------

WAY TO ABOLITION : Classify it as special industrial waste material to be scrapped only by licensed
disposal company for proper processing. When firing for destruction, it is desirable
to mix the material for metalizing.
---------------------------------------------------------
18. TRANSPORTATION INFORMATION
---------------------------------------------------------

1) RECEPTACLE : Use the recommended receptacles.

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[EMSDS-31] GI-181A (Epoxy Primer, Resin)

2) LOADING : Use steel can and shut tightly using by 2 step caps, inner and outer.
After closing tightly each container and check it, oad with three plies and shield outside
with vinyl wrap for preventing them from dropping or collapsing.
3) CARRYING : Carry the emergency equipment and absorbent materials and instruct the carrying agent to
pay special attention.

-------------------------------------------------
19. DISPOSAL CONSIDERATIONS
-------------------------------------------------

1) Disposal method :
- Since more than two kinds of designaed waste is mixed, it is difficult to treat seperatly, then can be
reduction or stabilization by incineration or similar process.
- if water separation is possible, pre-process with Water separation process.
- Dispose by incineration.
2) Disposal precaution for disposal :
- The user of this product must disposal by oneself or entrust to waste disposer or person who other’s
waste recycle and dispose, person who establish and operate waste disposal facilities.
- Dispose of waste in accordance with all applicable laws and regulations.

------------------------------------------------
20. TRANSPORT INFORMATION
------------------------------------------------

1) UN number : 3082
2) UN proper shipping name : Environmentally hazardous substances, Liquid, n.o.s
3) Transport hazard class : Class 9
4) Packing group : Ⅲ
5) Marine pollution : Subsidiary risk : MP
6) Special safety response for transport or transportation measures :
- Local transport follows in accordance with Dangerous goods Safety Management Law.
- Package and transport follow in accordance with Department of Transportation (DOT) and other
regulatory agency requirements.
- EMS FIRE SCHEDULE : F-A (General fire schedule)
- EMS SPILLAGE SCHEDULE : S-F (Water-soluble marine pollutants)

---------------------------------------------------
21. REGULATORY INFORMATION
---------------------------------------------------
1) National and/or international regulatory information
- POPs Management Law : Not applicable
- Information of EU Classification :
• Classification : - 4,4-'bisphenol polymer with oxirane : Xi;
- Butyl glycidyl ether : R10 Carc. Cat. 3; R40 Muta. Cat.

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GI-180 Block Lining System - Ecocera Material Safety Data Sheet
[EMSDS-31] GI-181A (Epoxy Primer, Resin)

3; R68 Xn; R20/22 Xi; R37 R43 R52-53


• Risk Phrases : - 4,4'-bisphenol polymer with oxirane : R36/38,
- Butyl glycidyl ether : R10, R20/22, R37, R40, R43,
• Safety Phrase : - 4,4'-bisphenol polymer with oxirane : S2, S28,
- Butyl glycidyl ether : S2, S24/25, S36/37, S61
- U.S. Federal regulations
• OSHA PROCESS SAFETY (29CFR1910.119) : Not applicable
• CERCLA Section 103 (40CFR302.4) : Not applicable
• EPCRA Section 302 (40CFR355.30) : Not applicable
• EPCRA Section 304 (40CFR355.40) : Not applicable
• EPCRA Section 313 (40CFR372.65) : Not applicable
- Rotterdam Convention listed ingredients : Not applicable
- Stockholm Convention listed ingredients : Not applicable
- Montreal Protocol listed ingredients : Not applicable

-------------------------------------------
22. INFORMATION OF LAW
-------------------------------------------
- Observe government laws and regulations, or self-governing body's rules.

-------------------------------------------
23. OTHER INFORMATION
-------------------------------------------

1) Information source and references :


- KOSHA (Korea Occupational Safety & Health Agency : www.kosha.or.kr
- SIDS
- NLM
- IPCS
- ESIS

---------------------
24. REMARK
---------------------

Data Source : Urethan resin Handbook, Chemical products Dictionary


More Information : ECOCERA CO., LTD. (www.ecocera.co.kr)

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[EMSDS-32] GI-181B (Epoxy Primer, Hardener)

GI-181B (Epoxy Primer, Hardener)

--------------------------------------------------------------------------------------------
1. INFORMATION OF CHEMICAL PRODUCTS AND COMPANY
--------------------------------------------------------------------------------------------

1) Product Name : GI-181B (Epoxy Primer, Hardner)


2) Hazard Classification : Hazard matters
3) Use of Product : PRIMER
4) Manufacturer Information
(1) Manufacturing Company Name : ECOCERA CO., LTD.
(2) Address : #1812, 298, Beotkkot-ro, Geumcheon-gu, Seoul, 08510 Republic of Korea.
(3) Emergency contact phone number : +82-2-2083-8311
5) Post in Charge : R & D
Person in Charge : Mr. Kim
6) Supplier / distributor information : same as manufacturer
7) Create Date : January 28th, 2002
8) Last revision date and revision number : January 6th, 2017

-----------------------------------------------------------------
2. NAME AND CONTENTS OF ELEMENTS
-----------------------------------------------------------------

Chemical Name Other Name CAS NO CONTENT (%)

Fatty acids, tall-oil, reaction products


Amidoamine resin 68953-36-6 80
with etraethylene pentamine

Tetra ethylene pentamine


3,6,9-triazaundeca methylene diamine 112-57-2 20
(TEPA)

----------------------------------------------------------
3. HEALTH HAZARD IDENTIFICATION
----------------------------------------------------------

1) Hazard-Risk Classification :
- Acute Toxicity - Oral : Category 4
- Acute Toxicity - Dermal : Category 4
- Skin Corrosion/Irritation : Category 1
- Skin Sensitization : Category 1

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[EMSDS-32] GI-181B (Epoxy Primer, Hardener)
- Chronic hazards to the aquatic environment : Category 3

2) Label elements including precautionary statements

- Symbol :

- Signal Word : Danger


- Hazard-Risk statements
H302 Harmful if swallowed
H312 Harmful in contact with skin/dermal
H314 Causes severe skin burns and eye damage
H317 May cause allergic skin reaction
H412 Harmful to aquatic life with long lasting effects

- Precautionary statements
• Prevention
P264 Wash... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P261 Avoid breathing dust/fumes/gas/mist/vapors/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
• Response
P301+P312 IF SWALLOWED : Call a POISON CENTER or doctor/physician if you feel unwell.
P330 Rinse mouth.
P302+P352 IF ON SKIN : Wash with plenty of soap and water.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P322 Specific measures (see... on this label).
P363 Wash contaminated clothing before reuse.
P301+P330+P331 IF SWALLOWED : Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON Skin (or hair) : Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P304+P340 IF INHALED : Remove victim to fresh air and keep at rest a position comfortable for
breathing.
P305+P351+P338 IF IN EYES : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do.
Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P321 Specific treatment (see ... on this label).
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

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[EMSDS-32] GI-181B (Epoxy Primer, Hardener)
• Storage
P405 Store locked up.
• Disposal
P501 Dispose of contents/container to...

3) Other hazard-risk which are not included in the classification criteria :


NFPA ratings (Scale 0~4)
- Health : 2, Flammability : 1, Reactivity : 0

-------------------------------------
4. FIRST AID MEASURE
-------------------------------------

1) Eye contact :
- Flush eyes with plenty of water for at least 15 minutes while holding eyelids open.
- Consult a physician immediately.
2) Skin contact :
- Immediately remove contaminated clothing or shoes, wash skin w plenty of water for at least 15
minutes.
3) Inhalation :
- Move person to fresh air area and provide oxygen if breathing is difficult.
- Consult a physician immediately.
4) Ingestion :
- Do not induce vomiting.
- Provide oxygen if breathing is difficult.
5) Acute and delayed symptoms/effects
- Inhalation
• Short-term exposure : Irritation, vomiting, difficult breathing, headache, sleepiness, vertigo
• Long-term exposure : No data for side effect.
- Ingestion
• Short-term : exposure vomiting, difficult breathing, irregular heartbeat, headache, vertigo, blood-flow
disorder
• Prolonged exposure : No data for side effect.
- Skin contact
• Short-term exposure : Irritation, allergic reaction
• Prolonged exposure : Irritation, allergic reaction
- Eye contact
• Short-term exposure Irritation, allergic reaction
• Prolonged exposure Irritation, allergic reaction

6) Notes to Physician
- Get adequate measure with the symptoms.
- Ensure that medical personnel are aware of the material(s) involved and take
- precautions to protect themselves.

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----------------------------------------------
5. FIRE-FIGHTING MEASURES
----------------------------------------------

1) Suitable (and unsuitable) extinguishing media :


- Suitable extinguishing media : Dry chemical, carbon dioxide, foam in use, water
- Unsuitable extinguishing media : No data
- Conflagration : Use foaming agent in use or water spray.
2) Specific hazards arising from the chemical :
- Combustion product : May cause hazardous and toxic product such as chloride and carbon oxide.
- Fire-fighting hazard : May cause fire or explosion.
3) Special protective equipment and precautions for fire-fighters :
- Isolate from heat, electrical equipment, sparks and opened flame.
- Were self-contained breathing apparatus.
- Keep unauthorized personnel away.

------------------------------------------------------------
6. ACCIDENTAL RELEASE MEASURES
------------------------------------------------------------

1) Personal precautions, protective equipment and emergency procedures :


- Wear suitable protective equipments (heat- resistant clothes/respiratory protective equipment etc.).

2) Environmental precautions and protective procedures :


• Air : A vapor suppressing foam may be used to reduce vapors.
- Water spray may reduce vapor; but may not prevent ignition in closed paces
• Soil : No data
• Underwater : Store away from water supply and drainage.

3) Methods and materials for containment and cleaning up :


• Little leakage : Absorpt with sand or nonflammable material.
- Store in an airtight container.
• Enormous leakage : All disposal methods must be in compliance with applicable local
regulations.

----------------------------------------------
7. HANDLING AND STORAGE
----------------------------------------------

1) Precautions for safe handling :


- avoid direct sunlight.
2) Conditions for safe storage (including any incompatibilities) :
- store at good place of ventilation

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GI-180 Block Lining System - Ecocera Material Safety Data Sheet
[EMSDS-32] GI-181B (Epoxy Primer, Hardener)
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8. EXPOSURE CONTROLS & PERSONAL PROTECTION
---------------------------------------------------------------------------------
1) Control parameters : No data.
2) Appropriate engineering controls :
- Good general ventilation sufficient under most conditions, but local exhaust ventilation may be necessary
for some operations.
3) Personal protective equipment
- Respiratory protection : No data
- Eye protection : Wear protective goggle.
- Hands protection : Wear chemical resistant gloves.
- Body protection : Wear chemical resistant clothing.

-----------------------------------------------------------------------------
9. PHYSICAL AND CHEMICAL CHARACTERISTICS
-----------------------------------------------------------------------------

1) Appearance (physical state, color etc) : Amber color liquid (when mixed with Part A : Light Amber color)
2) Odor : Irritating odor
3) Odor threshold : Not available
4) pH : Not available
5) Melting point/Freezing point : 30℃
6) Initial boiling point and boiling range : Not available
7) Flash point : 105℃
8) Evaporation rate : Not available
9) Flammability (solid, gas) : Not available
10) Upper/lower flammability or explosive limits : 4.6%(Upper)/0.8%(lower)
11) Vapor pressure : 0.0000008mmHg at 25℃
12) Solubility : Insoulble
13) Vapor density : Not available
14) Relative density (25℃) : 1 Kg/Liter
15) Partition coefficient : n-octanol/water : 3.16
16) Auto-ignition temperature : 300℃
17) Decomposition temperature : Not available
18) Viscosity : 500~1,000cps at 25℃
19) Molecular weight : Not available

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10. STABILITY AND REACTIVITY
---------------------------------------------------
1) Chemical stability : Stable at normal temperature and pressure.
2) Possibility of hazardous reactions : No data
3) Conditions to avoid : Avoid to contact with strong oxidizing agent, heat, spark and flame.
4) Incompatible materials : Acid, amine. anhydride, epoxy, oxidizing agent
5) Hazardous decomposition products : May cause hazardous and toxic product such as chloride and carbon
oxide.
http://www.ecocera.co.kr

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GI-180 Block Lining System - Ecocera Material Safety Data Sheet
[EMSDS-32] GI-181B (Epoxy Primer, Hardener)

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11. TOXICOLOGICAL INFORMATION
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1) Information on the likely routes of exposure :
- by respiratory organ : No data

- by mouth : No data
- by skin and contact : In Occupational settings
- by eye and contact : In Occupational settings
2) Health hazards information :
- Acute toxic :
• Oral : LD50 3,250mg/kg, 3,990mg/kg Rat
• Derma l: LD50 660 - 1,260mg/kg Rabbit
• Inhalation : LC50 > 9.9ppm 8hr Rat
• Skin corrosive/irritant : - 495mg skin - rabbit serious irritation
- 5mg/24hr skin - rabbit serious irritation
- Corrosive (4hr Exposure, Rabbit)
- Not irritating (4hr Exposure, 10% solution, Rabbit)
• Serious eye damage/eye irritation :
- 100mg/24hr eye : rabbit moderate irritation
- 5mg eye - rabbit moderate irritation
- Moderately irritating (Single Exposure, Rabbit)
- Corrosive irritating (Repeated Exposure, Rabbit)
• Respiratory sensitization : No data
• Skin sensitization : Sensitizing (Maximization study, Guinea pig)
• Germ Cell Mutagenicity : Not classifiable
• Reproductive toxicity : No data
• Specific target organ toxicity (single exposure) : No data
• Specific target organ toxicity (repeated exposure)
- Dermal (Rabbit, Dose : 50,100,200mg/kg/day, OEDC 410)
- NOEL : 50mg/kg/day (skin)
200mg/kg/day (systemic) - No systemic effects.
- LOAEL : 100mg/kg/day
• Aspiration hazard : No data

3) Numerical measures of toxicity : i.p. LD50 205mg/kg Rat


i.v. LD50 320mg/kg Mouse

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12. ECOLOGICAL INFORMATION
-------------------------------------------------

1) Aquatic and terrestrial ecotoxicity :


- fish : LC50 420mg/L 96hr OECD 203
LC50 310, > 1000mg/L 96hr

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GI-180 Block Lining System - Ecocera Material Safety Data Sheet
[EMSDS-32] GI-181B (Epoxy Primer, Hardener)
- crustacean : EC50 14.6mg/L, 24.1mg/L 48hr OECD 202

- aquatic plant : EC50 2.1 - 6.8mg/L 72hr OECD 201


2) Persistence and degradability
- Persistence No data
- Resolvability : Atmospheric Half life 1.2hr.
Hydrolysis would not be expected under environmental conditions.

3) Bioaccumulative potential
- Concentration : log Kow -3.16 (Estimated) ; it is not expected to bioconcentrate.
BCF 4.2 (Estimated)
It would not bioconcentrate in aquatic organism.
- Bio resolvability : 28days Aerobic, Activated sludge, Domestic waste.
Did not be decomposed.
4) Mobility in soil : log Koc 1098 (Estimated), Koc 3.6 (Estimated)
Highly mobile in soil and leaching may occur.
5) Other adverse effects : No data

---------------------------------------------
13. CAUTION AT ABOLITION
---------------------------------------------

WAY TO ABOLITION : Classify it as special industrial waste material to be scrapped only by licensed
disposal company for proper processing.
When firing for destruction, it is desirable to mix the material for metalizing.

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14. TRANSPORTATION INFORMATION
----------------------------------------------------------

1) RECEPTACLE : Use the recommended receptacles.

2) LOADING : Use steel can and shut tightly using by 2 step caps, inner and outer.
After closing tightly each container and check it, oad with three plies and shield outside with
vinyl wrap for preventing them from dropping or collapsing.
3) CARRYING : Carry the emergency equipment and absorbent materials and instruct the carrying agent to
pay special attention.

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15. DISPOSAL CONSIDERATIONS
-------------------------------------------------

1) Disposal method :
- Dispose of contents/container to the regulations
2) Disposal precaution : No data

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GI-180 Block Lining System - Ecocera Material Safety Data Sheet
[EMSDS-32] GI-181B (Epoxy Primer, Hardener)

------------------------------------------------
16. TRANSPORT INFORMATION
------------------------------------------------
1) UN number : 2735
2) UN proper shipping name : Amines, liquid, corrosive, n.o.s. or Polyamines, liquid, corrosive, n.o.s.
Tetraethylenepentamine (TEPA)
3) Transport hazard class : Class 8
4) Packing group : Ⅲ

5) Marine pollution : No data


6) Special safety response for transport or transportation measures :
- Emergency procedure at fire : F - A
- Emergency procedure at leakage : S - B

---------------------------------------------------
17. REGULATORY INFORMATION
---------------------------------------------------

1) Occupational Safety and Health Act : No data


2) Toxic Chemical Control Act : No data
3) Safety Control Dangerous Substance Act : Class4, Class4 Petroleum
4) Wastes Control Act : Specific Waste
5) Other requirements in domestic and other countries : No data

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18. INFORMATION OF LAW
-------------------------------------------

- Observe government laws and regulations, or self-governing body's rules.

-------------------------------------------
19. OTHER INFORMATION
-------------------------------------------

1) Information source and references :


- KECL - TSCA
- ENCS - MITI

---------------------
20. REMARK
---------------------

Data Source : Urethane resin Handbook, Chemical products Dictionary


More Information : ECOCERA CO.,LTD. (www.ecocera.co.kr)

http://www.ecocera.co.kr

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