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Wigner D-Matrix PDF
Wigner D-Matrix PDF
The Wigner D-matrix is a unitary matrix in an irreducible representation of the groups SU(2) and SO(3). The complex
conjugate of the D-matrix is an eigenfunction of the Hamiltonian of spherical and symmetric rigid rotors. The matrix was
introduced in 1927 by Eugene Wigner. D stands for Darstellung, which means "representation" in German.
Contents
Definition of the Wigner D-matrix
Wigner (small) d-matrix
Properties of the Wigner D-matrix
Orthogonality relations
Kronecker product of Wigner D-matrices, Clebsch-Gordan series
Relation to spherical harmonics and Legendre polynomials
Relation to Bessel functions
List of d-matrix elements
Symmetries and special cases
See also
References
External links
In all cases, the three operators satisfy the following commutation relations,
where i is the purely imaginary number and Planck's constant ħ has been set equal to one. The Casimir operator
commutes with all generators of the Lie algebra. Hence, it may be diagonalized together with Jz.
This defines the spherical basis used here. That is, in this basis, there is a complete set of kets with
where j = 0, 1/2, 1, 3/2, 2, ... for SU(2), and j = 0, 1, 2, ... for SO(3). In both cases, m = −j, −j + 1, ..., j.
where α, β, γ are Euler angles (characterized by the keywords: z-y-z convention, right-handed frame, right-hand screw rule,
active interpretation).
The Wigner D-matrix is a unitary square matrix of dimension 2j + 1 in this spherical basis with elements
where
is diagonal, like the γ matrix factor, but unlike the above β factor.
The sum over s is over such values that the factorials are nonnegative.
Note: The d-matrix elements defined here are real. In the often-used z-x-z convention of Euler angles, the factor
in this formula is replaced by causing half of the functions to be purely imaginary. The realness of the d-matrix
elements is one of the reasons that the z-y-z convention, used in this article, is usually preferred in quantum mechanical
applications.
The d-matrix elements are related to Jacobi polynomials with nonnegative and [2] Let
If
where
Further,
which have quantum mechanical meaning: they are body-fixed rigid rotor angular momentum operators.
and the corresponding relations with the indices permuted cyclically. The satisfy anomalous commutation relations (have a
minus sign on the right hand side).
and because of the anomalous commutation relation the raising/lowering operators are defined with reversed signs,
Finally,
In other words, the rows and columns of the (complex conjugate) Wigner D-matrix span irreducible representations of the
isomorphic Lie algebras generated by and .
An important property of the Wigner D-matrix follows from the commutation of with the time reversal operator
or
Here we used that is anti-unitary (hence the complex conjugation after moving from ket to bra),
and .
Orthogonality relations
The Wigner D-matrix elements form a set of orthogonal functions of the Euler angles and :
The group characters for SU(2) only depend on the rotation angle β, being class functions, so, then, independent of the axes of
rotation,
and consequently satisfy simpler orthogonality relations, through the Haar measure of the group,[3]
whence, for
forms a reducible matrix representation of the groups SO(3) and SU(2). Reduction into irreducible components is by the
following equation:[4]
The symbol is a Clebsch-Gordan coefficient.
When both indices are set to zero, the Wigner D-matrix elements are given by ordinary Legendre polynomials:
In the present convention of Euler angles, is a longitudinal angle and is a colatitudinal angle (spherical polar angles in the
physical definition of such angles). This is one of the reasons that the z-y-z convention is used frequently in molecular physics.
From the time-reversal property of the Wigner D-matrix follows immediately
[5]
for j = 1/2
for j = 1
for j = 3/2
for j = 2[6]
Wigner d-matrix elements with swapped lower indices are found with the relation:
See also
Clebsch–Gordan coefficients
Tensor operator
Symmetries in quantum mechanics
References
1. Wigner, E. P. (1931). Gruppentheorie und ihre Anwendungen auf die Quantenmechanik der Atomspektren.
Braunschweig: Vieweg Verlag. Translated into English by Griffin, J. J. (1959). Group Theory and its
Application to the Quantum Mechanics of Atomic Spectra. New York: Academic Press.
2. Biedenharn, L. C.; Louck, J. D. (1981). Angular Momentum in Quantum Physics. Reading: Addison-Wesley.
ISBN 0-201-13507-8.
3. Schwinger, J. "On Angular Momentum" (https://www.osti.gov/biblio/4389568-angular-momentum), Harvard
University, Nuclear Development Associates, Inc., United States Department of Energy (through predecessor
agency the Atomic Energy Commission) (January 26, 1952)
4. Rose, M. E. Elementary Theory of Angular Momentum. New York, JOHN WILEY & SONS, 1957.
5. https://link.springer.com/content/pdf/bbm%3A978-4-431-54180-6%2F1.pdf
6. Edén, M. (2003). "Computer simulations in solid-state NMR. I. Spin dynamics theory". Concepts in Magnetic
Resonance Part A. 17A (1): 117–154. doi:10.1002/cmr.a.10061 (https://doi.org/10.1002%2Fcmr.a.10061).
External links
PDG Table of Clebsch-Gordan Coefficients, Spherical Harmonics, and d-Functions (http://pdg.lbl.gov/2008/rev
iews/clebrpp.pdf)
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