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NAME M S Ravcend8a Phatriap

NOYI8CHO34
Sub CREI
QUiz-
shoiking-Coe m fos cymesicol
ROstickes OF UChanging Size
Te COGtjor i

A 9) +b B(s)- solid PolcE


fo a pastide
Dfisiotiagh
o s fIm contsolS

dNe
SexCE b_dNA-balay
dE bg a)
Cxtcanl soface
axca is
hexe

= 2Tn2zh

-b_
ONA=bko Ag=Corstam
dt

of B in tne
et be moas density
ard v be t e volue of Paaticle
SOb in
t
iTHe
c omoont bf B p
Pobtice
Ng- gV
T e c c a l e i n volue
onbcactcd coe accomponyi19 t
disapreaNaNCE of dNg moes of Solid
Cactamt

dNg=bdNA z
(Rolv-bdNa
-Pal7 an)=-bdNa
C1 2hde= - bdN4-
foor G 0

LONg
dcbh
dE

e dc b
-
hg CAg -
intcgpate ()
t

bis bh ng (t0)
bky Cng(i)
2

2 bka t )

R1-(
2R
bKglt)
1-/R=bk g) (
ct time fox conrplet ConveSiOV
of a Rrsticle be T. ren by
takking Y=d
Sives
T R -
2b Kg CAg
pt i n
R)=E
f s a c t i o r c a ConEBSIOV)

I-X VOlume Of nsccctcd


total Olume of pstit

fom cualion 6)
2

u)=Ke
Diffusion thogh ash layes contxos

dNA(anish)Qh=411RhA
dt

dNA
dE
41&,hnr Cornstam'
t flo2 of A
ui' tin ash layCS
be expoessed by ffcks lau fo
cufmoa8 covrle diffusior
tnern
DeDe da-
whcse
De is effcctive dilosioe) coetMicic

dl=(2mh) (e da Con
dt

CAc-O
dNA
dt d 211Deh dCA
K
CAg CAS
dNA
dtIn
211Deh o-Ag)
-dNa (In - IníR)= -21nACag)
NG- BV V=Tn
bM-dNB fdv-CB (min)2% O
ooNA
LONB
N A b dNA
dE bKgao
cauation Put in
dNA TIT128 de

-g mhe) de)(me}-nf
-b(211h) De Caqot
s d (m(o)-nR))--b
intcgartC (cwith timits

dv Inv) -In)Yd
R R 4b
b Using byPaxts ule

In(R) bo.Cag
B in(c) ( ¥-n(RE 2
4
= blCagt
vtiply wth 4'
2 in( )- In)(
2

AbDCAgt
2(in( e- AboCagt
in
B(nAÝ-RO)+R)-Ab
R-+n( 4beCAgb Cng

R1-(+(K){¥-E
fo cormpltc Conve.son, EO
T ER2
AbDeCag
Put in

(4n
volume af Un&nctcalt
Tota volue of Palt

fK/RK=(/R
=(s)
(B)+(1-g) m(l-g
chemical eactian nto|
ONa b
271h JtdNAbK
whcse k is fikst oxoes
ale cEBant Ao Svfare ex
p27e)
2 Tho
de - , d
dt dE
Pe debr'ag
dt

dbK'a dt

-n bkaalt-o
-R)= brcagt
t B(R-C)/br"ag-
fo complete corvetson, dc-0
tsR/orlGg
Pot Put m(2)
C-

Hence ue calculated for


cylinalsicza paticlein sheink
.ong coC metioo
ase
fim oiffsion
Xg-1-)
T (R 2bkgla9
th-e
osh diffusion

TER4beag
Reactio
T
gR/xCa9
t/T1-(1Ye2

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