Challenges For GHG Reduction in Steel Industry

2007 RITE International Symposium
-Technologies for mitigating global warming and the role of Japan-
Challenges for GHG Reduction

鉄鋼業におけるエネルギー有効利用と
in Steel Industry
地球温暖化問題への取り組み
January 18, 2007

Toru Ono
Nippon Steel Corporation
Copyright (C) 2005 NIPPON STEEL Corporation All Rights Reserved. 0

Table of Contents
Contents
1) Introduction
2) Voluntary Action Plan
3) Energy-Saving Technologies
4) Utilization of Waste Materials
5) Challenges for the Future
6) International Collaborations
7) Conclusions

Introduction
Iron & Steel Making Process Flow

Cold Rolling
Raw Materials Iron Making Steel Making Hot Rolling Steel Products
& Finishing
Raw Materials Energy Plants

Iron Making
Power
Boiler Oxygen
Coal Plant
Plant
Coke Oven
Blast Steel Making
Iron Pig Iron
Furnace
Ore
BOF
Continuous Crude Steel
Sinter Plant Molten Caster
Steel
Scrap EAF Steel
Heating
Long Products Furnace
Heating
Continuous Galvanizing Plate Furnace
Heating
Furnace
Continuous Annealing Hot coil
Finishing Cold Rolling Hot Rolling
Steel Products
Process Boundary
Introduction
From the Point of View of Energy,

Waste
Plastics,
Highly Energy integrated process
etc.
Raw Materials Iron Making By-pro. Gas Energy Plants
Energy
Power
Coal Boiler
Conversion
Plant Oxygen
Plant
Coke Oven Energy Cascade
Blast Steel Making
Iron Pig Iron
Furnace
Ore
BOF
Continuous Crude Steel
Sinter Plant Molten Caster
Steel
Scrap EAF Steel
Waste
Waste Energy Heating
Heat Recovery Long Products Furnace
Heating
Continuous Galvanizing Plate Furnace
CO2
Heating
Furnace
Energy Continuous Annealing Hot coil
Cold Rolling Hot Rolling
Supply Finishing
Process Boundary

Introduction
Energetic CO2 Emission in Japan by Sectors

GDP 450Tyen 503(+11.9%)
Crude Steel
Production 112Mt 113(+0.9%) Total Energetic CO2 Emission :
1,206 +143Mt-CO2 (+13.9%)
1,059 Transportation :
257 +40Mt-CO2 (+18.4%)
217
House-H-holding & Business :
+ 118Mt-CO2 (+40.5%)
409
291 Industry Sector :
-16Mt-CO2 (-3.3%)
482 466 Steel Sector :

-13Mt-CO2 (-6.9%)
195 182
Energy Conversion :
68 74 + 6Mt-CO2 (+8.8%)
1990FY 2005FY *Grid power is distributed to each sector with national average
CO2 emission by power generation
Voluntary Action Plan
Voluntary Action Plan of JISF *JISF:Japan Iron and Steel Federation
In 1996 the Japan Iron and Steel Federation launched its voluntary
initiatives with the following action plans.
1) Challenge to save energy in the process by -10％
between 1990 and 2010
2) Challenge to use 1 million tons of waste materials
in the process under the condition of establishing
classification and collecting scheme by local
government. (equals to -1.5% of energy).
3) Further utilization of unused waste energy in the
local communities.
4) Contribution to energy-saving in the communities
through “Eco-products” and byproducts.
5) Contribution to world wide energy-saving through
technology transfer.
Achievement of the Activities

Energy-
Energy-Saving Contributions through Products
PJ Energy Consumption
2600
-7.6 Million ton-CO2
2519 -4.2% -7.1% -6.5%
2500
2400
2402
2354
2300 2340 ＣｏｎｔｒｉｂｕｔｉｎｓｔｈｒｏｕｇｈＢｙｐｒｏｄｕｃｔｓ
2010Target 2267PJ (-10%)
2200 -9.2 Million ton-CO2
Mt-CO 2 1990 1995 2000 2005
CO 2 Emission t-CO2 Assumption of Calculation
-6.9%
Conversion from Cement to Slag : 450kg-slag/t-cement
200 195.3
1000 CO2 Reduction Effect : 312kg-CO2/t-cement 924
-4.7% -7.4% 900
Domestic
800 Export 715
190 700 483
600 578
511 Domestic –4.8Mt
186.1 500
180 181.9 400
550
180.9 525
300 464
2010Target 177.7Mt (-9%) 200 441
Export –4.4Mt
170 100 165
0 47 53
1990 1995 2000 2005
160 -13.4 Million ton-CO2
150
1990 1995 2000 2005 Kyoto Mechanism
Crude Steel Production (Mt)
1990 1995 2000 2005
112 100 107 113
-5.6 Million ton-CO2

Keidanren’s Voluntary Action Plan

○Targeting no increase in CO2 emission in 2010 from that in 1990
○35 industrial sectors participants in the 2006FY follow-up.
○Covering 44% of the national total and 83% of industrial sector in Japan.
1990 2005 Change Rate
Industrial sector in Japan
Mt-CO2 Mt-CO2 Mt-CO2 %
1. Iron and Steel Federation 195.3 182.0 -13.4 -6.9
2. Car manufacturing 7.6 5.7 -1.9 -24.4
3. Car parts 7.2 7.4 0.2 3.1
4. Petroleum Association 33.0 44.7 11.7 35.3
5. Chemical I. Association 68.3 75.2 6.8 10.0
6. Paper Association 25.4 25.1 -0.4 -1.4
7. Cement Association 27.4 21.8 -5.7 -20.6
8. Power companies (portion) 31.0 38.8 7.8 25.2
9. Electric appliances etc 11.8 18.7 6.9 58.0
10. Other sectors 39.0 33.4 -5.6 -14.4
11. Non-energy CO2 62.1 52.4 -9.6 -15.5
Keidanren Total 508.2 505.1 -3.1 -0.6

Energy-
Energy-Saving Technologies
Efforts to Energy Saving

’70s ’80s ’90s ’00s ’10s
１）Process Innovation CC, C.A.P.L etc. PCI, CMC etc. SCOPE-21 etc.
2）Process Optimization HCR, ACC etc. AI, SCN etc. never ending improvement
3）Enhancement of Bypro. Gas Recovery Gas Holder, ACC H2 Supply, CO2 Capture
4）Waste Heat Recovery TRT, CDQ, etc Regenerative Burner etc. Low Temp. Recovery and Use
5）Waste Material Utilization Plastics, Tires Biomass

Net Consumption
Gross Energy Consumption
Process Innovation
Process Optimization
Recovery
By-pro. Gas recovery
Waste heat recovery
Utilization of Wastes
‘73 ‘80 ‘90 ‘00 ‘10
Energy-
Coke Dry Quenching (CDQ)
Waste-heat recovery from hot coke

Improvement in coke quality
Cooling Chamber
Coke Basket Waste-heat boiler Turbine Generator

1050deg.C 860deg.C
High-pressure Steam
9MPa, 510 deg.C, 50t/H
Coke Oven
Coke Dust Collector
95t/H Cooling gas
130kNm3/H
HT LP G
130deg.C Pre heater

200deg.C Deairator
180deg.C
Cooling
Circulation Fan Water
Coke Carrier
Conveyer Process steam
Cooled Coke

Energy-
Energy Recovery System in BF

BFG
DC
Blast VS
Furnace To Gas holder
Blast Blower Hot Stove VS
ＭＢＬ
TRT Ｇ
195℃ 85℃
BFG
Air
Heat Medium Pump

Circulation
Tank
Hot Stove Waste-

Waste-heat Recovery System Top-
Top-pressure Recovery Turbine

Energy-
Energy Recovery System in BOF
BOF gas is collected

Recovered Steam by OG system.
OG System
Drum
Water
接触
Direct
伝熱部
Heat
Sensible heat of BOF Exchang
gas is recovered by a er
Dust Collector
waste-heat boiler
Primary BOF Gas
equipped in the OG Radiator
system.
Upper Hood
Pump Lower Hood

下部フー
ＩＤＦ
IDF
BOF

Energy-
Trends of Waste-heat Recovery

Results in Kimitsu Works of Nippon Steel
150 25
Power generated
Waste-heat power rate

over total demand (%)
排排
by waste-heat
熱 125 20 熱
回回
100 収
収 15
発発
75 電
電 10 比
量 50
率
25 5
(MW
(MW) (％)
) 0 0
200 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 00 01 02 03 120
180 年度
Steam generated
Waste-heat steam rate

over total demand (%)
排 160 100 排
by waste-heat
熱熱
140 80 回
回
収 120 収
蒸
蒸 100 60
気
気 80 比
量 60 40
率
40 20
(t/H)
(t/H) 20
0 0 (％)
79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 00 01 02 03
年度
Fiscal Year

Energy-
ACC for Byproduct Gas Advanced Combined Cycle
Capacity : 300MW
Fuel : mixed BFG (4.4MJ/Nm3)
Gas temp. : 1300deg.C
Efficiency : 47.5%
LP Steam
MP Steam
Waste-heat Recovery Boiler HP Steam
Gas Compressor
Air Filter
Steam Turbine Power to grid
Gas Turbine Generator
Combustion
Chamber
Cooling Water
BFG+COG
Gas Filter
Gas Cooler
From Kimitsu Cooperative Thermal Power Company

Energy-
Advanced Coke Oven (SCOPE-21)
Hot briquetting machine

Emission free
coal charging
Coal plug Dust collecting system
conveying system
Highly sealed oven door
Emission free
coke discharging
Pneumatic Emission free
preheater coke pushing
Emission free coke
Coking chamber travelling system
・Medium temp. carbonization

Coke upgrading
・Super denced brick & thin wall chamber
Fine Coarse ・Pressure control
Coal coal coal CDQ
Coke Blast
Fluidized bed dryer Coke quenching car furnace
High performance Coke Treatment

Coal Pre-treatment
Coke Oven

Utilization of Waste Materials
Cross Sector Approach

Civil Life Iron/steel making process
(Serious needs for waste disposal) (Big potential for effective uses of wastes)
Cost Incineration is the High temp./reducing …

major method for
PA Ideal reaction processes
waste disposal in
Japan.
NIMBY Products can be used by
CO2 Emissions present processes
Solution for social problems

Social system design
High economic performance
Rule establishment
Global Warming Problem
To realize a material recycling society system

across sectoral borders
Evaluation of Utilization of Waste Materials
Waste plastics Waste plastics

Coal, fuel (E) Waste tires Coal, fuel (E’) Waste tires
Steel mill System
Extension
Coke Oven Coke Oven
Incinerator Incinerator
Blast Furnace Blast Furnace
×
CO2 (A) + CO2 (B) CO2 (A’) + ZERO
Saving Natural Resources

Reduction of Total CO2 Emission
Methodology of Waste Plastic Utilization-1

Material Preparation Process
供給コンベア Magnetic
磁力選別機 selector
From local
自治体ヤードより
governments
積込・輸送
Pre-crusher
Waste plastic
廃プラ受入
Primary selector CB eliminator Secondary crusher Pelletizer

Pre-treatment
Compressed Package
1m x 1m x 1m
200 – 300 kg Secondary Crushed tips
20 x 20 mm
Plastic Pellets
25 mmD x 40 mmL

Methodology of Waste Plastic Utilization-2

Chemical Decomposition Process Products and Reuses
40% COG
Power Plant
Fuel Cell (in future)
40% Oils
Plastic Materials
Paints etc.
20% Coke
Reducing Agent for BF
Coke Oven

Trend of Utilization of Waste Plastics

kt
500
420 440
Packaging Materials Recycling Law
400
Stated Apr. 1, 2000 350
290
300 270
200
150
100 70
30 30
0
1997 1998 1999 2000 2001 2002 2003 2004 2005

Social System Design by Nippon Steel
Social System Design by Nippon Steel

Local Government
Gas(Fuel
Recovery ) Collection
Coal Waste
Plastic
Main Coke Sub

Products Products
Flow Oven Flow
Iron Making Raw Material

Coal+Iron ore Virgin Plastic
In 2002, Good Design Award was

granted to Nippon Steel for it’s Social
System Design of Waste Plastic
recycling.

Challenges for the Future
A Scenario for Hydrogen Based Society in Japan
Japanese government
disclosed a scenario for
establishing a hydrogen based 15million FCVs
society in the future.

In 2030, 15 million FCVs and
12.5 GW FCGs are planed to
be installed.
Hydrogen supply is one of the

major concerns.
12.5GW FCGs
Coke oven gas in steel plant
becomes a promising
candidate for hydrogen source.

Potential of COG as a Hydrogen Source

N2
CO2 3%
3%
CmHn Dehydrater
3% CO H2 Compressor
6% Off gas
H2 Gas Holder
PSA
COG
COG H2 H2
H2
CH4 Composition 55%

30% vol% 55％ Compressor Desulfurizer H2 Liquifier Liquified H2 Tank
Easy equipment
Wide spread of location

Huge amount of resource
FCV Demonstration in EXPO2005

Served from Nagoya Works
1) Number of FC bus 8
2) Total mileage 124,500km
3) Service term 185days
4) Total passengers 1million JHFC FCV Demonstration Project
5) Hydrogen consumption 11,430kg Served from Kimitsu Works
CO2 Capture from Blast Furnace Gas

BFG
Composition CO2 CO N2 H2 High concentration of CO2 in BFG
vol% 22 23 51 4
Improve efficiency of power plant
Power Plant
Reuse as a reducing agent in BF
CO2 absorbent
CO2 absorber
Blast Furnace
Steel Process
CO2 discharger Unused waste-heat
Potential of utilization of unused waste heat

Captured CO2

An Image of Future Iron/Steel Plant
Steel Plant Iron Ore

Wastes Coal Energy
Waste Plastics Power, Gas,
Waste Biomass Iron/Steel Making Process Steam etc
Byproduct Gases
Hydrogen Energy Saving CCS
＋
Unused Waste Energy
High Performance
Products
Byproducts
H2 Society Global Warming
Society with
High Energy Efficiency
Material Recycling
International Collaborations
Trend of World Steel Production

2005: China growth
Mt World Population 6.5Billion
1200 World Steel Production 1130Mt
1990: Base year of Kyoto

World Population 5.3Billion
1000 Steel Production 770Mt
China
1974: After the 1st Oil Crisis Growth
World Population 4.0Billion
800 Steel Production 710Mt
1950: After WW-II

World Population 2.5Billion Fall of the Berlin Wall
600 Steel Production 189.6Mt
Plaza Agreement
1913: A year before WW-I 2nd Oil Crisis
World Population 1.7Billion st
Steel Production 79.5Mt 1 Oil Crisis
400
WW-I Economic WW-II

Panic
200
0
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
00
05
19
19
19
19
19
19
19
19
19
19
19
19
19
19
19
19
19
19
20
20
Trend of National Steel Production

Mt
400
China Growth
Year Crude Steel Production (million t)
350
1996 101 Over 100 million tons
2000 127 End of 20th Century
2001 151 +24
300
2002 182 +31
2003 222 +40 Rapid Growth
250 2004 272 +50
2005 350 +78
200
CIS
150
USA China
Jpn
Japan
100
France
Germany
50 Korea
India
0
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
00
05
19
19
19
19
19
19
19
19
19
19
19
19
19
19
19
19
19
19
20
20
Economic Growth and Steel Consumption

Domestic steel consumption and GDP/capita between 2000 and 2005
Domestic Steel Consumption kg-steel/capita
1200 2000 2001 2002 2003 2004 2005
Korea 851 839 953 991 1018 1002
Japan 627 592 578 599 629 648
Korea EU15 430 415 406 408 423 406
1000
Domestic Steel Consumption
USA 484 402 410 362 419 378

China 109 133 159 198 228 264
CIS 161 173 162 189 200 207
India 30 30 32 33 35 38
800 World 151 151 159 168 183 189
(kg/capita)
Japan
600
Germany
OECD
EU15 USA
400
China France
CIS UK
200 World average
Real GDP is calculated based on the annual GDP and exchange rates of 2000.
India Domestic steel consumption is defined as “National production + import – export”.
0
0 10000 20000 30000 40000 50000
GDP ($/capita)
Energy-Saving Model Projects

Governmental Project
13 (500kt-CO2/year)
Private Project
7 (900kt-CO2/year) 580
290 310
Korea
China
20
India 7
Thai
10 Projects by Nippon Steel

Malaysia Technology Installed Host Country Year Compreted CO2 reduction
BF-HS Waste Heat Recovery China 1995 29.8
（unit: kt-CO2） Coal Moisture Control China 1995 18.6
Coke Dry Quenching China 2000 68.3
BOFG Recovery China 2001 40.0
BF-HS Waste Heat Recovery China 2001 17.8
BF-HS Waste Heat Recovery Indea 2003 22.4
Total 196.9
kt-CO2/year
Status of Major Energy-Saving Technologies
ｺｰｸｽ Top-
Top-pressure Recovery
Coke 乾式消火設備
Dry Quenching 高炉炉頂圧回転炉ガス回収設備
BOF Gas Recovery
（ＣＤＱ） Turbine
収設備（ＴＲＴ）
(％) 0 50 100 (％) 0 50 100 (％) 0 50 100
Japan
日本 8 5 Japan
日本 100 1 0 0Japan
日本 100
Korea
韓国 50 韓国
Korea 100 1 0 0Korea
韓国 25
米国
US 0 米国
US 2 米国
US 11
ｲｷﾞﾘｽｲｷﾞﾘｽ 00 ｲｷﾞﾘｽ

UK 0 UK UK 18
Germany
ﾄﾞｲﾂ 33 Germany
ﾄﾞｲﾂ 24 Germany
ﾄﾞｲﾂ 0
The data above were gathered in 1996.

Efforts for updating the data are intensely carried out by IISI, IEA and
APP to estimate potentials to be improved.

Future Potential of CO2 Reduction
Potential of CO2 Reduction researched by NEDO

CIS
2120 (2)
East Euro.
1240 (8)
Middle East Asia

27 (1) 3390 (17)
Africa
59 (2)
Latin America
73 (5)
JI Candidates：3370kt-CO2(10Projects)
CDM Candidates ：4970kt-CO2(25Projects)

kt-CO2/year (# of Project)

Japan-China Steel Industry

Advanced Technology Exchange Meeting in
Environmental Protection & Energy-Saving
July 4-5, 2005 :The first meeting held in Beijing, China
Nov. 1-2, 2006 :The second meeting held in Beppu, Japan
Common Understanding
Importance of technical exchanges in the area of environmental preservation and
energy-saving technologies, from the standpoint of the effective use of resources
and the preservation of the global environment.
Agreement
To realize the above, the Japan Iron and Steel
Federation and the China Iron and Steel
Association will continue exchanges of
information and experts on environmental
preservation and energy-saving.

Asia Pacific Partnership (APP)
Established in 2005
6 partners: Australia, China, India, Japan, Korea, US
To cope with both increasing energy needs and climate change
Focus on technology
To complement Kyoto Protocol
Cleaner fossil energy/ Renewable energy and distributed generation/ Power generation
and transmission / Steel / Aluminum/ Cement/ Coal mining/ Buildings and Appliances
Steel Task Force chaired by Japan

2nd Steel TF Meeting and 1st WS, Sep. 27-29, 2006, Tokyo, Japan
Project# Contents Chair
Pro.-1 APP Steel workshop Host Country Next meeting
Pro.-2 Status Review of Steel Industry Related Indicators for Energy Saving etc Japan
Pro.-3 Performance Indicators Setting Korea
Mar.14-16,2007
Pro.-4 Performance Diagnosis China, India
Pro.-5-1 State-of-the-art Clean Technology Handbook USA (co-chair JPN)
Calcutta, India
Pro.-5-2 Technology Deployment Australia

SOACT Handbook SOACT:State-of-Art Clean Technology)
SOACT Handbook is
under compiling to be
shared state-of-art
technologies relating
environmental
protection and
energy saving by the
member countries.
By the end of 2006,

53 of environmental protection technologies and 48 of energy
saving technologies are compiled. 63 technologies are
presented by Japan.

Appendix
Importance of International Sectoral Approach
1,130Mt/year
Others 130 650Mt/year 1,000Mt/year
Australia 10
India 40
Korea 50
USA 90 460Mt/year
ugh io n: n
l: thro a t tio P
e ra k l e n A c
r al: a : AP
a t a g r y e i es
lt i-l Br e
S in nta
y-la -Chin
t
n tr
Mu CO 2
V olu B an
p cou
I Ja 6
IIS
China 350 460Mt/year
Japan 110
CIS 110
Canada 20
Other EU 60
EU15 160
World Total Kyoto Japan-China APP Kyoto+APP

Coverage 100% 40% 40% 60% 90%

IISI’s CO2 Breakthrough Program

Phase-1: Seeds research and development（until 2008）
Phase-2: Pilot projectト（2～5years）
Phase-3: Demonstration Plant
EU
North
ULCOS
American
Program
*Ultra Low CO2 Steelmaking
Korea Japan
Program Program
JISF
CO2 separation
Hydrogen production etc.
South
American
Program

Conclusions
Future Directions
Past Present Future
Energy Saving through Performance Improvement
Steel Products and Byproducts
(eg.HITEN)
Process Innovation
Energy-Saving in Process
(eg.SCOPE-21)
APP, Bilateral etc.
International Collaboration
IISI CO2 Breakthrough
Waste Material Utilization
(Waste Plastics/Tires, Dust/Sludge)
Cross Sector Approach Hydrogen Supply
Low-Temp. Waste Heat Utilization

CCS

Toru Ono
Nippon Steel Corporation
Otemachi 2-chome, 6-3, Chiyoda-ku, Tokyo 100-8071, Japan
e-mail ono.tooru@hq.nsc.co.jp
+81-3-3275-5471 Wind farm in Hibikinada Coast

Challenges For GHG Reduction in Steel Industry

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2007 RITE International Symposium

-Technologies for mitigating global warming and the role of Japan-

Challenges for GHG Reduction

January 18, 2007

Copyright (C) 2005 NIPPON STEEL Corporation All Rights Reserved. 0

Copyright (C) 2005 NIPPON STEEL Corporation All Rights Reserved. 1

Iron & Steel Making Process Flow

Raw Materials Energy Plants

From the Point of View of Energy,

Copyright (C) 2005 NIPPON STEEL Corporation All Rights Reserved. 3

Energetic CO2 Emission in Japan by Sectors

482 466 Steel Sector :

Voluntary Action Plan of JISF *JISF:Japan Iron and Steel Federation

Achievement of the Activities

Copyright (C) 2005 NIPPON STEEL Corporation All Rights Reserved. 6

Keidanren’s Voluntary Action Plan

Copyright (C) 2005 NIPPON STEEL Corporation All Rights Reserved. 7

Efforts to Energy Saving

5）Waste Material Utilization Plastics, Tires Biomass

By-pro. Gas recovery

Waste heat recovery

Coke Dry Quenching (CDQ)

Waste-heat recovery from hot coke

Coke Basket Waste-heat boiler Turbine Generator

130deg.C Pre heater

Copyright (C) 2005 NIPPON STEEL Corporation All Rights Reserved. 9

Energy Recovery System in BF

Heat Medium Pump

Hot Stove Waste-

Copyright (C) 2005 NIPPON STEEL Corporation All Rights Reserved. 10

Energy Recovery System in BOF

BOF gas is collected

Pump Lower Hood

Copyright (C) 2005 NIPPON STEEL Corporation All Rights Reserved. 11

Trends of Waste-heat Recovery

Waste-heat power rate

Waste-heat steam rate

Copyright (C) 2005 NIPPON STEEL Corporation All Rights Reserved. 12

ACC for Byproduct Gas Advanced Combined Cycle

From Kimitsu Cooperative Thermal Power Company

Copyright (C) 2005 NIPPON STEEL Corporation All Rights Reserved. 13

Advanced Coke Oven (SCOPE-21)

Hot briquetting machine

・Medium temp. carbonization

High performance Coke Treatment

Copyright (C) 2005 NIPPON STEEL Corporation All Rights Reserved. 14

Cross Sector Approach

Cost Incineration is the High temp./reducing …

Solution for social problems

To realize a material recycling society system

Evaluation of Utilization of Waste Materials

Waste plastics Waste plastics

Saving Natural Resources

Methodology of Waste Plastic Utilization-1

Primary selector CB eliminator Secondary crusher Pelletizer

Copyright (C) 2005 NIPPON STEEL Corporation All Rights Reserved. 17

Methodology of Waste Plastic Utilization-2

Copyright (C) 2005 NIPPON STEEL Corporation All Rights Reserved. 18

Trend of Utilization of Waste Plastics

Copyright (C) 2005 NIPPON STEEL Corporation All Rights Reserved. 19

Social System Design by Nippon Steel

Social System Design by Nippon Steel

Main Coke Sub

ｲｷﾞﾘｽｲｷﾞﾘｽ 00 ｲｷﾞﾘｽ