Puntos 0 1 2 3

Vm(m3/kmol) 1.3228 0.6184 0.3799 0.257

P(bar)

a= 5.507
b= 0.0304
R= 0.08314
T= 673.15

a) (𝑃+𝑎/(𝑉_𝑚^2 ))(𝑉_𝑚−𝑏)=𝑅𝑇

𝑃=𝑅𝑇/((𝑉_𝑚−𝑏) )−𝑎/(𝑉_𝑚^2 )

Puntos 0 1 2 3
Vm(m3/kmol) 1.3228 0.6184 0.3799 0.257
P(bar) 40.1564745 80.7792949 121.973533 163.602609

b) Vm= 0.5

Polinomio interpolador de grado 2 (0,1,2)

40.156474469 = a0 + a1 1.3228 + a2
80.77929490508 = a0 + a1 0.6184 + a2
121.9735332674 = a0 + a1 0.3799 + a2

P* = 216.26 - Vm 294.53 + 122.02

𝜕𝑃/𝜕𝑉 -294.53 + 244.04 Vm

𝑚=

𝜕𝑃/𝜕𝑉 -172.51 %error 4.1268979

𝑚=

Polinomio interpolador de grado 2 (1,2,3)

80.77929490508 = a0 + a1 0.6184 + a2
121.9735332674 = a0 + a1 0.3799 + a2
163.6026090327 = a0 + a1 0.257 + a2

P* = 295.5 - Vm 631.27 + 459.33

𝜕𝑃/𝜕𝑉 -631.27 + 918.66 Vm

𝑚=
 𝜕𝑃/𝜕𝑉
𝑚=

𝜕𝑃/𝜕𝑉 -171.94 %error 3.78284636

𝑚=

Polinomio interpolador de grado 2 (0,1,3)

180

160 f(x) = 160.915207574921 x² − 370.038703778176 x + 248.074267358603

P*
140

120 𝜕𝑃/𝜕𝑉
𝑚=
100

80 𝜕𝑃/𝜕𝑉
𝑚=
60

40

20

0
0.2 0.4 0.6 0.8 1 1.2 1.4

Polinomio interpolador de grado 2 (0,2,3)

180

160 f(x) = 236.396538633173 x² − 489.284110584002 x + 273.734870472634

140
P*
120
𝜕𝑃/𝜕𝑉
100 𝑚=
80
𝜕𝑃/𝜕𝑉
60 𝑚=
40

20

0
0.2 0.4 0.6 0.8 1 1.2 1.4

c) 𝜕𝑃/𝜕𝑉𝑚=−𝑅𝑇/(𝑉𝑚−𝑏)^2 +2𝑎/ 〖𝑉𝑚〗 ^3

𝜕𝑃/𝜕𝑉
𝑚=

𝜕𝑃/𝜕𝑉 -165.672851
𝑚=
 140

120
1.74979984 f(x) = 122.019377021214 x² − 294.534117507321 x + 216.256718719059

0.38241856 100
0.14432401
80

Vm^2 60

40

20

0
0.2 0.4 0.6 0.8 1 1.2 1.4

180

160
f(x) = 459.327564198926 x² − 631.26888076683 x + 295.500585102028
0.38241856 140
0.14432401 120
0.066049
100

80
Vm^2
60

40

20

0
0.2 0.25 0.3 0.35 0.4 0.45 0.5 0.55 0.6 0.65
 80

60

40

20

0
0.2 0.25 0.3 0.35 0.4 0.45 0.5 0.55 0.6 0.65

= 248.07 - Vm 370.04 + 160.92 Vm^2

𝜕𝑃/𝜕𝑉 -370.04 + 321.84 Vm

𝑚=

𝜕𝑃/𝜕𝑉 -209.12 %error 26.2246646

𝑚=

= 273.73 - Vm 489.28 + 236.4 Vm^2

𝜕𝑃/𝜕𝑉 -489.28 + 472.8 Vm

𝑚=

𝜕𝑃/𝜕𝑉 -252.88 %error 52.6381656

𝑚=