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ChE 200 Chemical Engineering and Process Calculations

Description
Application of physico-chemical principles to problems of the chemical industry;
stoichiometry and material balance.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
two 48-min lectures, Chem 123, Eng Graph, ChE 201, Math
U 3 AU, W
one 108-min recitation 254, Physics 131 (concur)

Textbook
Felder, R. M. And Rousseau, R.W., Elementary Principles of Chemical Processes ,
John Wiley & Sons (1986), 2nd Ed.

Course Objectives
 Be exposed to ideas in dimensional analysis. Be familiar with different unit systems.
 Be familiar with processes and process variables
 Be familiar with chemical engineering unit operations and processes
 Master fundamentals of stoichiometry, material balances for reacting and non-
reacting systems.
 Be exposed to process data representation and analysis
 Be exposed to mathematical tools such as MAPLE and mathcad

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I-14
Detailed Schedule
Week Topics
Introduction to Chemical Engineering and Chemical Engineering
1
Calculations

2 Processes and process variables; introduction to computer facilities

3 Material balances on non-reactive systems

4 Material balances on non-reactive systems

5 Material balances on reactive systems

6 Material balances on reactive systems

7 Single-phase systems

8 Multi-phase systems

9 Multi-phase systems

10 Multi-phase systems and review

Evaluation
Homework (9): 15%
Exams (2): 40%
Final Exam: 30%
Quizzes (4) 15%

Preparation
Syllabus prepared by Professor Umit S. Ozkan
Last modified: January 1999

I-15
ChE 201 Chemical Engineering and Process Calculations

Description
Continuation of 200. Emphasis on applications of the energy balance to chemical
engineering processes.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
three 48-min lectures, ChE 200
U 3 WI, SP
one 48-min recitation concurrent: Math 255, Physics 132

Textbook
Felder, R.M., Rousseau, R.W. Elementary Principles of Chemical Processes, 2nd Ed.,
John WIley & Sons, New York, NY (1986).

Course Objectives
 Be familiar with various forms of energy including shaft and flow work, heat, kinetic
and potential energy, internal energy and enthalpy.
 Master methods of obtaining thermodynamic data from tables, psychrometric charts,
enthalpy-concentration diagrams.
 Be familiar with simple equations of state and how they are used to describe
volumetric properties of pure and mixed materials.
 Master application of the general energy balance equation to solve a variety of
problems of moderate complexity, including the simultaneous application of material
and energy balances and systems involving phase changes and chemical reactions.
 Be familiar with transient mass and energy balances and their general use.
 Master the used of transient mass balances to solve simple problems.

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I-16
Detailed Schedule
Week Topics
introduction and orientation; first law of thermodynamics; forms of energy;
1 heat and work; closed and open systems; the general energy balance
equation

2 tables of thermodynamic data; the mechanical energy balance

3 state properties; hypothetical paths; pressure and temperature changes

4 phase changes; mixing; solutions

5 heats of reaction and Hess's Law

6 heats of combustion reactions; the energy balance for reactive systems

7 reactive systems (cont.); fuels and combustions

reactive systems (cont.)


8
the general balance equation for unsteady-state (transient) processes

9 material balances on transient processes

10 energy balances on transient processes

Evaluation
Homework (10): 20%
Written Report: 4%
Quizzes (4): 16%
Exams (2): 40%
Final Exam: 20%

Preparation
Syllabus prepared by Professor James Rathman.
Last modified: May 14, 1999

I-17
ChE 420 Elements of Chemical Engineering - Transport Phenomena I

Description
Introduction to momentum, mass, and heat transfer with emphasis on the analogies
between them; practical applications of momentum transfer (fluid flow).

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
three 48-min lectures,
U 4 SP ChE 201, Math 255, Physics 133
one 108-min recitation

Textbook
Bird, R.B.; Stewart, W.E.; Lightfoot, E.N. Transport Phenomena, John Wiley & Sons
(1960)

Course Objectives
 Master basic vector and tensor mathematics relevant to transport phenomena.
 Master the application of the mass and momentum balances to a deforming body
and to a fixed volume of space.
 Be familiar with constitutive equations for Newtonian and non-Newtonian fluids.
 Be familiar with principals underlying and the derivation of the equation of continuity,
the Cauchy momentum equations, and the Navier-Stokes equations
 Master the solution of basic laminar flow problems.
 Be exposed to ideas in dimensional analysis and the rational design of engineering
experiments (including those involving turbulent flow).
 Be exposed to the general approach for the design of piping systems.
 Be generally familiar with fluid dynamical ideas and terminology that often appear in
the research literature.

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I-18
Detailed Schedule
Week Topics
vector algebra, tensor algebra: addition and multiplication, dot product,
1
heat flux
vector and tensor calculus: "del" operator, Divergence Theorem, Reynolds
2
Transport Theorem
Balance of Mass: deforming body, fixed volume of space, the Equation of
3
Continuity
Balance of Momentum: deforming body, fixed volume of space, the
4
Cauchy Momentum Equations

5 Constitutive equations: Newton's Law of Viscosity, non-Newtonian fluids

6 Navier-Stokes equations

7 laminar flow problems: inclined plane, circular tube, lubrication

dimensional analysis based on the equations of motion: scale-up and the


8 rational design of engineering experiments, friction factors for flow in
conduits, laminar and turbulent flow

9 macroscopic balances and their uses

10 design of piping systems

Evaluation
Homework (10): 15%
Exams (2): 60%
Final Exam: 25%

Preparation
Syllabus prepared by Professors Martin Feinberg and James Rathman.
Last modified: April 27, 1999

I-19
ChE 508 Chemical Engineering Thermodynamics I

Description
Application of the fundamental concepts and laws of thermodynamicsto problems of the
chemical industry
Weekly Class Time Quarters
Level Credits Distribution Offered Prerequisites
two 48-min lectures,
U 3 W ChE 201, ChE 420
one 108-min recitation

Textbook
Sandler, S. I., Chemical and Engineering Thermodynamics, John Wiley & Sons. 3rd Ed.
(1999)

Course Objectives
 Master the application of the energy balance equation
 Master the application of the entropy balance equation
 Be familiar with the concept of reversibility
 Be familiar with equations of state and property estimation of real substances
 Be exposed to mathematical tools such as MAPLE and Mathcad
 Be exposed to concepts of equilibrium and stability in one-component systems
 Be introduced to the thermodynamics of multi-component mixtures

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I-20
Detailed Schedule
Week Topics
Definition of thermodynamic concepts; energy, heat, work, intensive and
1
extensive variables; state properties, path functions.
General balance approach, mass and energy balance; thermodynamic
2 properties of matter; property charts and tables; application of mass and
energy balances.
Entropy and the 2nd law of thermodynamics; entropy balance and
3
reversibility.

4 Heat, work, engines and entropy; entropy changes of matter.

Applications of mass, energy and entropy balances; liquefaction, power


5
cycles, refrigeration.
Thermodynamic partial derivatives, property changes of real substances;
6
principle of corresponding states.

7 Criteria for equilibrium, stability, phase equilibria.

Molar Gibbs free energy, fugacity, VLE computations using equation of


8
state.

9 Gibbs phase rule; thermodynamic properties of phase transition.

10 Examples and applications; review.

Evaluation
Homework (6): 16%
Exams (2): 42%
Final Exam: 25%
Quizzes (4): 17%

Preparation
Syllabus prepared by Professor Umit S. Ozkan
Last modified: September 1998

I-21
ChE 509 Chemical Engineering Thermodynamics II

Description
Continuation of ChE 508. Application of the fundamental concepts and laws of
thermodynamics to problems of the chemical industry; stress on computational problem
work.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
two 48-min lectures,
UG 3 WI ChE 508
one 108-min recitation

Textbook
Sandler, Stanley I., Chemical and Engineering Thermodynamics, 3rd Ed., John Wiley &
Sons, Inc. (1998).

Course Objectives
 Develop skills in applying the material, energy, and entropy balances to
multicomponent systems.
 Be able to calculate fugacity in nonideal solutions.
 Be able to determine whether a system has attained equilibrium.
 Be able to use equations of state and activity coefficient models to describe
multicomponent phase equilibria (we'll focus primarily on vapor-liquid equilibrium)
 Determine reaction equilibrium constants and predict effects of temperature,
pressure, and composition on equilibrium conversion.

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I-22
Detailed Schedule
Week Topics
introduction to the thermodynamics of mixtures; partial molar properties;
1
Gibbs-Duhem equation.
material, energy, and entropy balances for mixtures; experimental
2
determination of partial molar properties
phase equilibrium in multicomponent systems; chemical equilibrium;
3
equilibrium criteria; Gibbs Phase Rule
ideal gas mixtures; partial molar Gibbs free energy and fugacity; ideal
4 mixtures and excess properties; fugacity of a component in gas, liquid and
solid mixtures
activity coefficients; Principle of Corresponding States for mixtures (Kay's
5
Rule)
describing vapor-liquid equilibrium using activity coefficient models and
6
equations of state;
solubility of a gas in a liquid; liquid-liquid and liquid-liquid vapor
7
equilbrium;
partition coefficients; colligative properties: effect of solutes on solvent
8
properties
notation for chemical reactions; heat of reaction; chemical equilibrium in a
9
single-phase system
heterogeneous chemical equilibrium; multiple reactions in a phase;
10
combined chemical and phase equilibrium

Evaluation
Homework (10): 17%
Quizzes: 19%
Exams (3): 45%
Final Exam: 19%

Preparation
Syllabus prepared by Professor David L. Tomasko.
Last modified: May 12, 1999

I-23
ChE 521 Elements of Chemical Engineering - Transport Phenomena II

Description
Continuation of transport theory with emphasis on heat transfer and introduction to
radiation; basic principles developed and illustrated with problems from chemical
engineering practice.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
three 48-min lectures,
UG 3 AU ChE 420, Math 512
one 48-min recitation

Textbook
Bird, R.B.; Stewart, W.E.; Lightfoot, E.N. Transport Phenomena, John Wiley & Sons
(1960)
Pitts, D.R.; Sissom, L.E. Heat Transfer, Schaum's Outlines Series, McGraw-Hill (1977)

Course Objectives
 Be familiar with derivation of partial differential equations of heat transfer from First
Law of Thermodynamics
 Master solution of steady state one-dimensional heat transfer problems (up to and
including the use of Bessel functions)
 Be familiar with the solution of transient heat transfer problems in one spatial
dimension
 Be familiar with the solution of steady state heat transfer problems in more than one
spatial dimension
 Master the solution of simple heat transfer problems involving viscous dissipation
 Be familiar with the dimensionless-analysis foundations of correlations for heat
transfer coefficients in the presence of fluid motion
 Master aspects of heat exchanger design

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I-24
Detailed Schedule
Week Topics
mathematical preliminaries: vector algebra (elementary vector operations,
1
dot product, application to heat flux and the heat flux vector)
vector calculus (derivatives with respect to time, spatial derivatives, the
2
del operator, volume and surface integrals, divergence theorem

3 first law of thermodynamics (body version)

basic equations of heat transfer in the absence of motion: differential


4 energy balance (limited version), constitutive equations, the "Heat
Equation"
heat conduction in rigid solids: steady-state heat conduction in one
5 dimension, transient heat conduction in one dimension, multidimensional
problems

6 math review: tensors, the stress tensor, Reynolds transport theorem

fluid mechanical background for heat transfer in the presence of motion:


the balance of mass and the equation of continuity, the balance of
7
momentum and the Cauchy momentum equations, constitutive equations:
Newton's "Law" of viscosity and the Navier-Stokes equations
heat transfer in the presence of motion: the general differential energy
8
balance, problems involving convection and viscous heating

9 dimensional analysis and the design of experiments

10 the macroscopic energy balance and the design of heat exchangers

Evaluation
Homework (10): 15%
Exams (2): 60%
Final Exam: 25%

Preparation
Syllabus prepared by Professors Martin Feinberg and James Rathman.
Last modified: May 27, 1999

I-25
ChE 522 Elements of Chemical Engineering - Transport Phenomena III

Description
Continuation of the study of transport theory. Emphasis on mass transfer and
stagewise operations with applied computational problems.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
two 48-min lectures,
U 3 Winter ChE 420 or ChE 520, Math 512
one 108-min recitation

Textbook
Treybal, R.E., Mass Transfer Operations, 3rd ed, McGraw-Hill (1980)

Course Objectives
 Master the application of the mass, heat, and momentum balances to engineering
problems involving mass transfer.
 Be familiar with equations describing molecular diffusion through gasses, liquids,
and solids.
 Be familiar with techniques used to estimate diffusivities in binary and multi-
component systems.
 Be familiar with techniques used to estimate mass transfer coefficients in laminar
and turbulent flows.
 Understand the analogies between heat, mass, and momentum transfer.
 Master the application of computational techniques to solve mass transfer problems.
 Be exposed to the general approach for the design of contiuous contact and
stagewise absorption towers.

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I-26
Detailed Schedule
Week Topics

1 Flux equations, diffusion in gasses and liquids

2 Diffusion in solids, unsteady-state diffusion

3 Unsteady-state diffusion, estimation of molecular diffusivities

4 Mass transfer coefficients in laminar flows

5 Mass transfer coefficients in turbulent flows

6 Analogies and correlations between heat, mass, and momentum transfer

7 Phase equilibrium, interphase mass transfer

Gas absorption, countercurrent multistage operations, continuous contact


8
equipment
Absorption in multicomponent systems, simultaneous heat and mass
9
transfer

10 Equipment for gas-liquid operations (gas and liquid dispersed systems)

Evaluation
Homework (10): 10%
Project: 10%
Quizzes (3): 15%
Exams (2): 40%
Final Exam: 25%

Preparation
Syllabus prepared by Professor Kurt Koelling.
Last modified: May 3, 1999

I-27
ChE 523 Chemical Engineering Operations

Description
The application of transport phenomena such as fluid, heat, and mass transfer to the
chemical engineering operations of evaporation, distillation, extraction, drying, etc.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
three 48-min lectures,
U 4 SP ChE 522, Chem 532
one 108-min recitation

Textbook
Christie J. Geankoplis, “Transport Processes and Unit Operations," Prentice Hall, 1993,
3rd edition.

Course Objectives
 Master basic design principles and applications relevant to stage-wise operations.
 Be familiar with material and energy balance equations for various unit operation
processes.
 Be familiar with principals underlying and the derivation of the design equations for
adsorption, extraction, distillation, leaching, evaporation, drying, membrane
processing (RO and UF), and filtration.
 Master the solution of various unit operation process design problems.
 Be exposed to process simulation software (e.g., HYSIS) and master their use in
process calculation and design.
 Be familiar with the process safety issues involved in various unit operation
processes.
 Be prepared to design and operate various unit operation equipment/processes in
the laboratory

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I-28
Detailed Schedule
Week Topics

1 Introduction; Stage-wise operation -Absorption

2 Phase Diagram; Liquid-Liquid Extraction

3 Liquid-solid Leaching; Differential Extractor; Fractional Extraction

4 Distillation – McCabe-Thiele Method; Enthalpy-Concentration Method

5 Distillation – Multicomponent Mixture; Distillation Column Design

6 Evaporation – Evaporator Design

7 Drying of Process Materials

8 Adsorption

9 Membrane Separation – reverse osmosis, ultrafiltration

10 Mechanical-Physical Separations – Filtration, Centrifugation, Sedimentation

Evaluation
Homework (10) - 10%
Exams (9) - 80%
Final Project - 10%

Preparation
Syllabus prepared by Professor Shang-Tian Yang.
Last modified: May 31, 1999

I-29
ChE 610 Chemical Engineering Kinetics

Description
Chemical and engineering principles for the design and operation of chemical reactors;
kinetics of simple homogeneous systems and introduction to heterogeneous catalysis.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
Two 48-min lectures,
U 3 SP ChE 509; 522; or Chem 532
one 108-min recitation

Textbook
Fogler, H. Scot. Elements of Chemical Reaction Engineering (1999)

Course Objectives
 Master the three basic design equations for chemical reactors.
 Master the ability to use reaction equations, rate laws, and stoichiometry to balance
elements in reaction vessels.
 Master the basic energy balance equation in a reacting system
 Master the ability to design simple isothermal and non-isothermal chemical reactors
 Be exposed to how to analyze multivariable data.
 Be exposed to complex to diffusional and reacting systems and approaches to
simply these systems.
 Be exposed to complex reaction systems and networks.

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I-30
Detailed Schedule
Week Topics

1 Introduction, Mole balances, Conversion and Reactor Sizing

2 Rate Laws and Stoichiometry

3 Isothermal Reactor Design

4 Collection and Analysis of Rate Data

5 Non-elementary Homogeneous Reactions

6 Isothermal Reactor Design

7 Isothermal Reactor Design, Example problems

8 Multiple Reactions

9 Introduction to Solid Catalyzed Reactions

10 Review

Evaluation
Homework (10): 20%
Exams (2): 40%
Final Exam: 40%

Preparation
Syllabus prepared by Professor Jeff Chalmers.
Last modified: May 11, 1999

I-31
ChE 624 Chemical Process Dynamics and Control

Description
Study of the dynamics and control of chemical processes; mathematical models of
simple processes, including feedback control, are derived, analyzed, and simulated.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
U 3 three 48-min lectures AU ChE 523, 610, 630 and Math 512

Textbook
T. E. Marlin, Process Control, McGraw-Hill, 1995

Course Objectives
 Introduction to the modeling and analysis of the dynamic behavior of chemical
processes.
 Introduction to the basic theory and practice of automatic process control.
 Become familiar with the principles of single-loop feedback control and its design
and analysis

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I-32
Detailed Schedule
Week Topics

1 Introduction to Process Control, Control objectives and benefits

Mathematical modeling, Dynamic modeling, linearization, Laplace


2
transform
Transfer functions and block diagrams, Frequency response, Process
3
dynamics.
Process dynamics, Process dynamics, model identification, Empirical
4
model identification

5 Empirical model identification, Elements of feedback loop

Block diagram, performance measures, variables selection, The PID


6
algorithm

7 The PID algorithm, PID controller tuning, Stability of control systems

8 Bode stability analysis, Veterans Day (no class), Nyquist stability analysis

Controller tuning methods, Review, Practical application of feedback


9
control
Performance of control systems, Enhancements to single-loop PID
10
control, Summary

Evaluation
Homework, Projects (10): 25%
Mini-Quizes (2): 5%
Exams (2): 40%
Final Exam: 30%

Preparation
Syllabus prepared by Professor Bhavik R. Bakshi.
Last modified: May 28, 1999

I-33
ChE 626 Digital Control Techniques in Chemical Engineering

Description
Study of real-time data acquisition and digital control techniques as applied to chemical
processes.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
ChE 624 and En Graph 167, or
U, G 3 three 48-min lectures SP
permission of instructor.

Textbook
T. E. Marlin, Process Control, McGraw-Hill, 1995

Course Objectives
 Introduce advanced techniques for process control.
 Become familiar with enhancements to single-loop control including, cascade, feed
forward, inferential and adaptive control.
 Learn the basics of single-variable model predictive control and multivariable control.
 Introduce the basic principles of digital control including z-transforms and signal
processing.

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I-34
Detailed Schedule
Week Topics
Introduction and Review, Enhancements to Single-Loop PID Control -
1
Cascade Control

2 Feedforward Control

3 Control of Nonlinear Processes, Inferential Control

4 Level and Inventory Control, Single-Variable MPC

5 Internal Model Control, Smith Predictor

6 Multivariable control - Effects of Interaction

7 Multivariable control - Performance Analysis

8 Centralized multivariable control

Digital Control - Motivation, digital to analog and analog to digital


9
conversion
Digital Control - z-transforms, pulse transfer function, zero-order hold
10
transfer function.

Evaluation
Homework, Projects (10): 25%
Mini-Quizes (2): 5%
Exams (2): 40%
Final Exam: 30%

Preparation
Syllabus prepared by Professor Bhavik R. Bakshi.
Last modified: May 28, 1999

I-35
ChE 630 Chemical Engineering Operations Laboratory

Description
The fundamental laboratory course in the chemical engineering operations; laboratory
investigation of the operating characteristics and efficiency of chemical engineering
equipment such as distillation, drying, filtration, etc.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
5 hrs conference
U 6 SU ChE 523
7-19 hrs in labs

Textbook
Course handout with description of all experiments and operation manuals for various
equipment items.

Course Objectives
 Master the application of fundamental concepts from stoichiometry,
thermodynamics, reaction kinetics, and transport phenomena to chemical
engineering unit operations.
 Be able to design and conduct experiments in the laboratory.
 Master the use of modern computational tools to analyze and interpret the collected
data.
 Work effectively as a member of a team. Learn skills needed to be a team leader,
including delegating duties and responsibilities.
 Prepare high quality written reports and oral presentations to summarize a project in
a professional and informative manner.
 Be familiar with safety issues important in the chemical industry, including laboratory
safety protocols, material safety data (MSD) sheets, and proper handling, storage,
and disposal of chemicals.
 Gain an appreciation for the complexity of chemical processes and the need for
continuous learning in a practicing engineer's career.

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I-36
Detailed Schedule
Students work in teams of four or five, performing a total of seven experiments during the
quarter. Each team must prepare a detailed written report for each experiment that includes: (1)
description of the experiments performed, materials and equipment used, and summary of data
collected; (2) analysis and interpretation of the data, with appropriate graphical and
computational results to support conclusions; (3) design extension. The design extension is an
additional problem posed by the instructor that requires each team to propose a modification of
their process to conditions or applications different than those studied in the lab.

There are a total of fourteen experiments currently available in the unit operations laboratory.
These are: (1) shell and tube heat exchanger; (2) plate heat exchanger; (3) continuous
distillation; (4) pulse liquid/liquid extraction; (5) CSTR reaction engineering; (6) plug-flow
reaction engineering; (7) gas-solid fluidization; (8) gas-solid-liquid fluidization; (9) absorption;
(10) adsorption: (11) reverse osmosis; (12) drum filtration; (13) conductive heat transfer; (14)
mixing dynamics.

For each experiment, one student is assigned the role as team leader. This position rotates
throughout the quarter so that all students are team leader at least once. One of the team
leader's responsibilities is to fairly and accurately evaluate the performance of other members of
the team.

Safety is stressed throughout the course. Each week a safety inspection/evaluation committee
is formed, comprised of one student from each team. This committee is responsible for assuring
that the laboratory activities of all teams during that week are done safely and responsibly. One
of these committees does a full safety inspection of the Chemical Engineering Department at
some time during the quarter. This inspection includes graduate research laboratories and the
committee issues a written report to all faculty and graduate students citing safety violations and
concerns. The Department Safety Committee performs the follow-up to insure that corrective
actions are taken. Students are penalized on their lab grades for minor safety violations or
professional misconduct. Intentional or malicious violation of safety rules results in immediate
dismissal from the course.

Evaluation
Lab performance (7): 23%
Written reports (7): 47%
Oral presentations (3): 10%
Safety inspection: 5%
Lecture exams: 5%
Final Exam: 10%

Preparation
Syllabus prepared by Professor James Rathman.
Last modified: May 30, 1999

I-37
ChE 666 Principles of Biochemical Engineering

Description
The application of biochemical engineering principles for modern bioprocesses and in the
area of industrial biotechnology.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites

U 3 three 48-min lectures AU ChE 523, ChE 610

Textbook
J. Bailey and D. Ollis, Biochemical Engineering Fundamentals, 2nd ed., McGraw Hill,
1986.

Course Objectives
 Master basic biochemical engineering principles and applications relevant to
bioprocesses and biotechnology operations.
 Be familiar with basic biochemistry and microbiology literature and terminology.
 Be familiar with principals underlying and the derivation of the design equations for
enzyme reactions and fermentation reactor operation and design.
 Master the solution of various biochemical engineering process design problems.
 Be exposed to bioprocess simulation software (e.g., BioProDesigner) for use in
process calculation and design.
 Be familiar with issues in biotechnology industry product/process development.
 Be prepared to design and operate bioreactor/fermentor in laboratory and pilot plant

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I-38
Detailed Schedule
Week Topics

1 Introduction; Biological Molecules

2 Enzyme Technology – Enzyme Kinetics

3 Immobilized Enzyme and Reactor

4 Introduction to Fermentation and General Microbiology

5 Fermentation Medium Formulation and Microbial Growth Requirement

6 Fermentation Kinetics and Modeling

7 Continuous Culture and Reactor

8 Thermal Death Kinetics of Cells; Medium Sterilization

9 Fermentor Operation – Agitation and Aeration

9 Reactor Scale up

10 Multiphase, Immobilized Cell Bioreactors

Evaluation
Homework (10) - 25%
Exams (2) - 50%
Final Exam/Project - 25%

Preparation
Syllabus prepared by Professor Shang-Tian Yang.
Last modified: May 31, 1999

I-39
ChE 694 Colloidal Dispersions

Description
Industrial production of colloids and their applications; fundamentals of interfaces;
analytical techniques for characterization of colloid systems; science of colloid stability;
formulation and design of colloidal dispersions; properties of emulsions and foams

Level Credits Weekly Class Time Quarters Prerequisites


Distribution Offered
UG 3 three 108-min lectures SU ChE 509 or Chem 531, Chem 253
(five-week course)

Textbook
Ross, S.; Morrison, I.D. Colloidal Systems and Interfaces, Wiley-Interscience (1988)

Course Objectives
 Review fundamental behavior of interfaces and surfaces.
 Develop a broad working knowledge of colloidal systems.
 Learn about the influence of surfactant microstructuring on the stability and
formation of emulsions and foams.
 Demonstate familiarity with the thermodynamic principles underlying colloid
stability.
 Become familiar with the electrostatic and polymeric approaches to colloidal
stability.
 Demonstrate familiarity with the analytical techniques for characterizing colloids
and the fundamental science behind them.
 Learn basic techniques and principles for demulsification and breaking of foams.
 Develop a working knowledge of how colloid systems are formulated and used in
industry.

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I-40
Detailed Schedule
Week Topics
1 Overview of Colloid Systems, Self-Assembly of Amphiphiles: definitions
and examples, making of mayonnaise, types of colloids, types of
surfactants, surfactant microstructures, analogy to molecular systems,
example applications of colloids, colloid-related phenomena
2 Interfacial Properties, Thermodynamic Basis for Colloid Stability:
capillarity, molecular theory of surface tension, dispersion force
contribution, Young-Laplace equation, Kelvin equation, nucleation,
Ostwald Ripening, Capillary Condensation, Gibbs adsorption model,
Langmuir equation
3 Analytical Techniques and Characterization: colligative properties, surface
tension, interfacial tension, zeta potential, spreading coefficients, pH, ionic
strength, sessile and pendant drops, contact angles

4 Interparticle Forces and Stabilization Mechanisms: Hamaker theory,


Lifshitz theory, measurement and estimation of Hamaker constants,
electrostatic stabilization, adsorption of polymers, polymeric stabilization,
Gouy-Chapman theory, Stern theory, Langmuir approximation, spherical
double layers, Derjaguin approximation, Debye-Hückel approximation,
DLVO theory
5 Colloids in Industry, Emulsions and Foams: making emulsions, phase
inversion techniques, nucleation methods, demulsification, Bancroft’s rule,
agglomeration, coalescence, stabilization by amphipathic particles,
selection of emulsifying agents, properties of foams, Gibbs theory of
foams, Maragoni effect, thermodynamics and phase formation in foam
stability, foam inhibition strategies, silicone foam inhibitors, mechanism of
particiculate foam inhibition, stabilization of solid suspensions

Evaluation
Homework (7): 15%
Exams (1): 40%
Final Exam: 45%

Preparation
Syllabus prepared by Professor Kenneth Cox.
Last modified: May 16, 1999

I-41
ChE 712 Catalysis and Catalytic Processes

Description
Introduction to catalytic phenomena and catalytic processes
Weekly Class Time Quarters
Level Credits Distribution Offered Prerequisites
Three 48-minute
U 3 W Che 610 or equivalent background
lectures

Textbook
Satterfield, C.N., Heterogeneous Catalysis in Industrial Practice, McGraw Hill. 2rd Ed.
(1991)

Course Objectives
 Be exposed to topics in catalysis, catalytic kinetics and catalytic reaction engineering
 Develop an understanding of the existing catalytic processes
 Be familiar with catalysis literature and terminology

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I-42
Detailed Schedule
Week Topics

1 Introduction to catalysis; adsorption.

2 Kinetics of catalytic reactions.

3 Transport phenomena in catalytic reactions.

4 Transport phenomena in catalytic reactions.

5 Catalyst preparation; catalyst supports.

6 Catalyst characterization.

Catalyst deactivation.
7

8 Catalytic reactors

9 Industrial catalytic processes

10 Industrial catalytic processes

Evaluation
Term paper and presentation : 30%
Exam(1): 35%
Final Exam: 35%

Preparation
Syllabus prepared by Professor Umit S. Ozkan
Last modified: January 1999

I-43
ChE 717 Colloids and Surfaces

Description
Introduction to various aspects of colloids and surfaces, including sedimentation,
diffusion, thermodynamics, light scattering, surface tension, contact angle, and
surfactants.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
Math 255, Chem 253, ChE 509 or Chem
U, G 3 two 78-min lectures, WI
531 or equivalent thermodynamics

Textbook
Hiemenz, P.C., Rajagopalan, R. Principles of Colloid and Surface Science, 3rd Ed.,
Marcel Dekker (1997).

Course Objectives
 Be familiar the mechanical, thermodynamic, and molecular interpretations of surface
tension.
 Understand the application of the Laplace equation, Kelvin equation, and Young-
Laplace equation to colloidal phenomena.
 Be familiar with methods of measuring interfacial tension and contact angle.
 Be familiar with preparation and applications of insoluble monolayers.
 Be familiar with theories describing adsorption of components from a bulk phase
onto a surface, including Gibbs monolayers and 2-D equations of state.
 Understand the importance of interfacial phenomena in diverse chemical processes.
 Be familiar with osmotic pressure and its role in natural systems and chemical
processes.
 Be familiar with thermodynamics of molecular self-assembly and related
phenomena, including micellar solubilization and catalysis.
 Be familiar with method used to characterize colloidal systems, including scattering
of radiation.

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I-44
Detailed Schedule
Week Topics

1 surface tension, contact angle, Laplace eq

Kelvin eq, Young eq, adhesion and wetting, molecular view of surface
2
tension
insoluble monolayers, surfactants and adsorption from solution, Gibbs eq,
3
surface excess quantities, Langmuir eq
adsorption at the gas/solid interface, Gibbs monolayers, 2-D equations of
4
state

5 Langmuir isotherm, BET isotherm

surfactant science and technology: catalysis, wetting agents and coatings,


6
foams, emulsions, dispersions, foods, biomedical applications

7 thermodynamics of colloids, osmotic pressure and dialysis

self-assembly of surfactants in solutions: micelle formation, counterion


8
binding, cloud points and Kraft points, mixtures, liquid crystals
surfactant science and technology: micellar catalysis, rheology of colloidal
9 solutions, detergency, surfactant-based separation processes, biomedical
applications
experimental techniques for characterizing colloids and surfaces:
10
spectroscopy, imaging, light and neutron scattering

Evaluation
Homework (5): 30%
Exam: 35%
Final Exam: 35%

Preparation
Syllabus prepared by Professor James Rathman.
Last modified: May 25, 1999

I-45
ChE 733 Novel Separation Processes

Description
Provides further depth beyond ChE 523 in the area of separations applied to chemical
processing and to introduce some novel techniques which are at the leading edge of
separations research.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
ChE 522 or 815.02 and 523, Math 512
UG 3 two 72-min lectures SU,SP
or permission of instructor

Textbook
No Required Text

Course Objectives
 Identify the multiple factors influencing the choice of separation techniques.
 Be able to both qualitatively and quantitatively address the fundamental aspects of
several specialty separation processes.
 Recognize the role of molecular structure and properties and intermolecular
interactions in determining the selectivity of separation
 Gain intimate knowledge of at least one novel process or application through
completion of a term project.

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I-46
Detailed Schedule
Week Topics
Introduction, Choosing a Separation Process, General Process
1
Considerations, Review of Phase Equilibria

2 Review of Mass Transfer, Chemical Complexation

Extraction based on Reversible Chemical Complexation; Membrane


3
Separations - Gases
Membrane Separations - Gases; Membrane Separations - Liquids,
4
Dialysis

5 Ion Exchange, Introduction to Chromatography

6 Large Scale Chromatography

7 Supercritical Fluid Processes

8 Supercritical Fluid Processes

9 Electric Field Based Separations

10 Magnetic Cell Separation, Electrodialysis, Electrophoresis

Evaluation
Homework (4): 10%
Exam(1): 30%
Project: 30%
Final Exam: 30%

Preparation
Syllabus prepared by Professor David L. Tomasko.
Last modified: May 12, 1999

I-47
ChE 750 Profession of Chemical Engineering

Description
The roles of professional activities performed by chemical engineers, code of ethics,
professional registration, professional societies, responsibilities to management and to
labor as an administrator.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
U 1 one 48-min lectures SP Junior standing

Textbook
none

Course Objectives
 Understand the importance of ethical conduct throughout one’s career.
 Be familiar with various career paths possible after graduation.
 Understand the importance of involvement in professional organizations and
professional registration.
 Prepared for successful transition from the university environment.

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I-48
Detailed Schedule
Week Topics

1 The engineering profession

2 Ethics

3 Graduate school

4 Career management

5 Pricing

6 Marketing

7 Professionalism and engineering registration

8 Balancing career and home

9 How to prepare for the on campus interview

10 no class

Evaluation
Ethics Assignment: 60%
Attendence: 40%

Preparation
Syllabus prepared by Professor L.S. Fan, Dr. David Miller and Professor James
Rathman
Last modified: May 8, 1999

I-49
ChE 760 Chemical Engineering Economy and Strategy

Description
Economic and strategy considerations in research, development, design, and
manufacturing in the chemical process industry; cost estimation and economic
optimization of chemical engineering operations and chemical processes.

Level Credits Weekly Class Time Quarters Prerequisites


Distribution Offered
UG 4 three 48-min lectures, AU ChE 610, ChE 630
one 108-min recitation

Textbook
Peters, M.S.; Timmerhaus, K.D. Plant Design and Economics for Chemical Engineers,
4th Edition, McGraw-Hill (1991)

Course Objectives
 Master the basic techniques of economic evaluation, including acounting
techniques, taxes, investment, interest and insurance.
 Demonstrate the ability to work effectively as a member of a team.
 Demonstate proficiency in presentation and writing techniques.
 Learn preliminary techniques for using computer-aided process simulation
including proficiency with a commercial simulation package, such as HYSYS.
 Master heuristic approaches to develop and evaluate solutions without extensive
computational support.
 Become familiar with the basic principles of finding an optimum solution.
 Learn how to deal with uncertainty both in market environment and final
solutions.
 Demonstrate proficiency in addressing open-ended design problems based on
ambiguous and incomplete data.
 Review and apply concepts learned in all previous chemical engineering courses.

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I-50
Detailed Schedule
Week Topics
1 Cost Estimation: process design development, general design considerations,
cash flow diagrams, cost indexes, factor method, basic definitions

2 Interest and Investments: simple interest, compound interest, effective interest,


continuous interest, annuities, present worth, perpetuities, capitalized costs,
discounted cash flows
3 Taxes, Insurance, and Depreciation: types of taxes, depreciation credit, types of
insurance, computation of depreciation, service life, salvage value, present
value, basic depreciation methods, MACRS
Alternative Investments: cost of capital, rate of return on investment, payout
period, discounted cash flow, net present worth, capitalized cost

4 Equipment Sizing: Guthrie diagrams, time factors, scale factors, refrigeration


equipment, pumps and compressors, separation equipment, tanks and columns,
mixers, reactors
5 Computer-Aided Process Design: rules of thumb, shortcut methods, process
synthesis, process flow diagrams, HYSYS techniques, degrees of freedom,
recycle streams
6 Physical Property Methods for Process Simulation: thermodynamic modesl,
conditions for phase equilibria, activity coefficient methods, equations of state
methods, electrolyte solutions, phase diagrams, azeotropes, liquid-liquid
immiscibility
7 Separation System Design: flash calculations, distillation column variables,
optimal column sequence, ideal systems, separating azeotropic systems

8 Presentation Techniques: effective presentation aids, analyzing an audience,


persuasion strategies, delivery skills, speech writing and organization, library
information resources
9 Team Activities: organization of teams, personality types, team behaviors,
stages of team evolution, company requirements for team effectiveness

10 Cost and Asset Accounting: basic accounting relationships, balance sheets,


accounting records, debits and credits, cost accounting methods

Evaluation
Homework (8): 10%
Team Activities: 15%
Exams (2): 50%
Final Exam: 25%

Preparation
Syllabus prepared by Professor Kenneth Cox.
Last modified: May 14, 1999

I-51
ChE 761 Chemical Engineering Processes

Description
Integration of fundamentals of chemistry, chemical engineering operations,
thermodynamics, reaction kinetics and economics for optimum design and operation of
chemical process plants

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
One 120-min lecture,
U/G 3 AU Senior standing in Chem Eng or Chem
two 60-min lectures

Textbook
Shreve’s Chemical Process Industries, 5th edition, Austin (1984)

Course Objectives
 To familiarize students with selected portions of the chemical process industry.
 To familiarize students with current issues, problems and trends in the chemical
process industry.
 To familiarize students with economics of the chemical process industry.
 To visit several plants to observe processes.

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I-52
Detailed Schedule
Week Topics
Introduction to chemical process industries, energy sources, water
1
treatment, waste water treatment
Industrial bioprocesses, overview of biotech industries, sulfur and sulfuric
2
acid

3 Nitrogen, ammonia and products of ammonia

4 Jackson Pike Water Treatment Plant, paper production, pulp production

5 Mead Paper Plant, household products, paper – energy

6 Iso-9000 Quality Systems, petroleum industry, petroleum refining

7 US Petrochemical Industry, petroleum industry

8 Chemical and dust explosions, PUREA Foliar Fertilizer

9 Anheuser Busch Plant Trip, beer products

Diamonds production, dust explosion hexagon video, batch vs.


10
continuous

Evaluation
Plant trip reports (3): 24%
Term paper: 30%
Exam: 23%
Final Exam: 23%

Preparation
Syllabus prepared by Professor Jacques Zakin.
Last modified: May 1999.

I-53
ChE 762 Chemical Engineering Process Development

Description
Library, laboratory, and pilot plant research and development of chemical processes of
industrial potential justified by preliminary economic studies; preparation of optimum
process flow sheets; process scale-up and plant design.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
11 hours group
U 4 SP ChE 610, ChE 630, ChE 760
laboratory study

Textbook
None

Course Objectives
 Master problem solving skills - to identify problems and to find logical approaches to
solving the problem.
 Be familiar with methods for information searching- library and internet on-line search
of database and journal publications.
 Master how to present information and ideas in a written proposal and oral
presentation using appropriate visual aids (slides and computer presentation).
 Be able to carry out independent thinking and research in the process (product)
development area.
 Be able to design experiments, collect, and analyze data in the laboratory, and
evaluate the process based on experimental outcomes (data interpretation).
 Be able to use process simulation software (e.g., HYSIS and BioProDesigner) in
process calculation, scale-up design, and cost estimation.
 Be familiar with the process safety issues involved in the laboratory environment.
 Be able to work in a team to apply/assemble individual special skills and knowledge to
a group project.

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I-54
Detailed Schedule
Week Topics

1 Introduction; group project, problem statement, and proposed approaches

2 Library and internet search of information

3 Proposal and creating group web page

4 Design experiments and laboratory set up

5 Experiment – collecting data and refining experimental procedures

6 Experiment – collecting data and refining experimental procedures

7 Experiment – collecting data and refining experimental procedures

8 Experimental data analysis and report

9 Oral project presentation

10 Final report

Evaluation
Report - 60%
Oral presentation - 30%
Web page - 10%

Preparation
Syllabus prepared by Professor Shang-Tian Yang.
Last modified: May 31, 1999

I-55
ChE 764 Chemical Engineering Process Design

Description
Process design studies on selected chemical processes encompassing a broad
spectrum of fundamental engineering principles; optimization studies utilizing economic
and technical simulation.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
Two 60-min lectures,
U 4 one 30 to 45-min group WI ChE 762
project meeting

Textbook
Biegler, L.T.; Grossmann, I.E.; Westerberg, A.W. Systematic Methods of Chemical
Process Design, Prentice Hall (1997)

Course Objectives
 Master the basic hierarchical approach to process design..
 Master the use of process simulation software for process analysis.
 Integrate material from previous courses to synthesize a complete chemical process
plant.
 Understand and integrate economic considerations in evaluating potential design
projects.
 Be familiar with the scale and scope of an engineering design project.
 Master and apply basic concepts of heat integration.
 Be generally familiar with the interaction between design and control.
 Be exposed to basic issues in batch scheduling and design (including Gannt charts,
multiple product plants, and transfer policies).
 Be exposed to the general approach for the geometric design of reactor networks.

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I-56
Detailed Schedule
Week Topics
Introduction to chemical engineering process design and overview of the
1 design process. Doulgas’s design hierarchy, levels 0, 1 and 2 (input
information, input-output structure of the flowsheet).

2 Design hierarchy, level 3 (recycle structure)

3 Design hierarchy, level 4 (separation system synthesis)

4 Heat and power integration

5 Heat integrated distillation processes

6 Interaction of design and control

7 Design and scheduling of batch plants

8 Geometric techniques for the synthesis of reactor networks

9 Review and exam

10 Group project presentations

Evaluation
Homework (5): 10%
Exam (1): 20%
Design Project: 70% made up of: Progress Reports (3): 30
Final Report: 20
Presentation: 10
Weekly meetings (9): 10

Preparation
Syllabus prepared by Dr. David Miller
Last modified: May 6, 1999

I-57
ChE 766 Biotechnology and Bioprocess Engineering

Description
Fundamentals of biotechnology and their applications to bioprocessing with emphasis
on fermentation and bioseparation.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
three 48-min lectures,
UG 3 W or SP ChE 666 or BioChem 511 or Micro 520

Textbook
Bailey, J.E., D.F. Ollis, "Biochemical Engineering Fundamentals or
Shuler, M.L., F. Kargi, "Bioprocess Engineering", Prentice Hall

Course Objectives
 Be exposed to the field of biotechnology and bioprocess engineering.
 Begin to understand what is involved in the development of a commercial bioprocess
 Be exposed to social/political/economic issues surrounding

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I-58
Detailed Schedule
Week Topics

1 Introduction to Biotechnology Industry, How do cell work?

2 How is cell information changed?

3 Types of Host-Vector systems and issues related to their use.

4 Genomics

5 Student Presentations

6 Student Presentations

7 Bioreactors

8 Downstream processing and separations

9 Student Presentations

Student Presentations
10

Evaluation
Final 15%
BioproDesigner Project 15%
1st oral presentation 10%
2nd oral presentation 15%
1st written paper 20%
2nd written paper 25%

Preparation
Syllabus prepared by Professors Jeff Chalmers
Last modified: May 13, 1999

I-59
ChE 771 Air Pollution

Description
Introduction to principal aspects of air pollution, including engineering control of
stationary sources, atmospheric chemistry, aerosol behavior, transport and dispersion
modeling, and an overview of relevant regulations
Weekly Class Time Quarters
Level Credits Distribution Offered Prerequisites
two 78-min lectures ChE 420, or permission from
U 3 SP
instr.

Textbook
Cooper, C.D., and Alley, F.C., Air Pollution Control, A Design Approach, 2nd ed.,
Waveland Press, Inc., Prospect Heights, IL, (1986)

Course Objectives
 Familiarity with key regulations
 Understand basics of aerosol mechanics and particulate control devices
 Understand basics of adsorption and absorption processes for gaseous emission
control
 Familiarity with air pollution meteorology and dispersion modeling fundamentals
 Familiarity with basic atmospheric chemistry and mobile sources of reactive
pollutants

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I-60
Detailed Schedule
Week Chapters Covered Topics Covered
1 1&2 Overview; Respiratory System; Regulations

2 3&6 Particulate Matter; Filtration; Baghouses

3 4, 5, & 7 Cyclones; Scrubbers; ESPs

4 10 & 12 Gas Properties; Adsorption; Respirators

5 11 VOC Control; MIDTERM EXAM

6 13, 14, & 15 Absorption; SOx Control; NOx Control

7 18 Air Pollution Meteorology

8 17 Atmospheric Chemistry; Mobile Sources

9 19 Dispersion Modeling; Review for Final

10 aux. Emissions Measurements; FINAL EXAM

Evaluation
Homework: 20%
Quizzes: 20%
Midterm: 25%
Final Exam: 35%

Preparation
Syllabus prepared by Dr. Michael Kuhlman
Last modified: May 30, 1999

I-61
ChE 773 Introduction to High Polymer Engineering

Description
Introduction to polymeric materials, polymerization methods and kinetics, polymer
solution properties, molecular weight determination and polymer physical/mechanical
properties

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
U/G 3 Two 90-min lectures AU ChE 610, Chem 251, Chem 252

Textbook
Billmeyer, W.R. Textbook of Polymer Science, 3rd edition, John Wiley & Sons (1984)

Course Objectives
 Be familiar with polymer structure, polymer type, average molecular weights and
polymer morphology.
 Be familiar with polymerization mechanism and reaction kinetics.
 Be familiar with principals underlying and the derivation of Flury-Huggins equation.
 Be familiar with various molecular weight determination methods.
 Be exposed to important polymer characterization methods.
 Be familiar with mechanical properties of polymers.

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I-62
Detailed Schedule
Week Topics
Definition of polymer, history of polymer science and the polymer industry,
polymers and petroleum, types of polymers and polymerization,
1
nomenclature of polymers, chain structures, molecular weights and
distribution, molecular forces, thermal and mechanical behavior
Step growth polymerization, kinetics, molecular weight control in linear
2
polymerization, molecular weight distribution in linear polymerization
Network formation, branching, crosslinking, gel point and statistics of
3
crosslinking, experimental gel points
Chain growth polymerization, structural arrangement of monomer units,
4
mechanism, type of initiation, kinetics
Degree of polymerization, molecular weight control and chain transfer,
5 thermochemistry of chain growth polymerization, comparison between
step and chain growth polymerization
Polymerization processes, types of polymerization process, changes of
6 emulsion polymerization, copolymerization, the copolymer equation, types
of copolymerization
Polymer solutions, physical chemistry review, ideal solution, polymer
7
solution theories
Molecular weight determination, end group analysis, colligative prop.
8
Measurement

9 Light scattering, intrinsic viscosity, GPC

Morphology and polymer science, semi-crystalline polymers, process


10 industry crystallinity, mechanical properties of polymers, polymer
rheology, viscoelasticity

Evaluation
Homework (7-8):20%
Exams (2): 40%
Final Exam: 40%

Preparation
Syllabus prepared by Professor James Lee.
Last modified: September 1998.

I-63
ChE 775 Rheology of Fluids

Description
Principles of rheology, including the characterization of non-Newtonian materials,
rheological equations of state, viscometric flows, measurements, and applications to the
flow of industrial materials. Practical examples, demonstrations, and group projects are
used to supplement lectures.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
two 78-min lectures
U/G 3 SP ChE 420 or ChE 520

Textbook
Macosko, C.W. Rheology: Principles, Measurements, and Applications, Wiley - VCH
(1994)

Course Objectives
 Understand the definitions of tensors used to describe the state of stress, strain,
and strain rate on a material element.
 Be familiar with the types of constitutive equations used to describe the behavior of
Newtonian liquids, elastic solids, and viscoelastic liquids.
 Master the application of the mass and momentum balance coupled with a proper
constitutive equation to solve engineering problems.
 Be generally familiar with experimental techniques used for rheological
characterization of liquids and solids.
 Be exposed to the rheological behavior of rubbers, polymers, suspensions,
emulsions, and foams.
 Be generally familiar with terminology used in the field of rheology.

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I-64
Detailed Schedule
Week Topics
Elastic solids, stress tensors, principal stresses, finite deformation tensor,
1
finger deformation tensor, neo-Hookean solids
Equations of motion, boundary conditions, velocity gradient tensor, rate of
2
strain tensor, definition of shear and extensional flows
Viscous liquids, constitutive models for general viscous fluids and plastic
3
behavior
Linear viscoelasticity, Maxwell model, stress relaxation, creep, and
4
sinusoidal oscillation
Nonlinear viscoelasticity, Deborah number, differential and integral
5
constitutive equations

6 Shear rheometry: drag flows and pressure driven flows

7 Extensional rheometry

8 Rheo-optical measurements

9 Rheology of suspensions, emulsions, and foams

10 Rheology of polymeric liquids (polymer melts and solutions)

Evaluation
Homework (10): 10%
Project: 10%
Exams (2): 50%
Final Exam: 30%

Preparation
Syllabus prepared by Professor Kurt Koelling.
Last modified: May 4, 1999

I-65
ChE 776 Principles of Polymer Conversion Operations

Description
Introduction to various polymer processing techniques; practical applications of
transport phenomena and polymer melt rheology

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
U/G 3 Two 90-min lectures WI or SP ChE 773, ChE 775

Textbook
Tadmor, Z., Gogos, C.G. Principles of Polymer Processing, John Wiley & Sons (1979)

Course Objectives
 Be familiar with transport phenomena relevant to polymer processing.
 Be familiar with constitutive equations for Newtonian and non-Newtonian fluids.
 Be familiar with principals underlying and the derivation of the equation of continuity,
the Navier-Stokes equations, and the energy equations.
 Be familiar with rheological measurement techniques.
 Be exposed to various thermoplastic processing operations such as extrusion,
injection molding and mixing.
 Be exposed to the general approach for modelling the processing operations.
 Be generally familiar with thermoset polymer processing techniques.

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I-66
Detailed Schedule
Week Topics

1 Introduction, review of transportation phenomena (lab tour)

2 Polymer melt rheology

3 Rheological measurement

4 Polymer melting

5 Polymer pumping

6 Extrusion

7 Die forming

8 Injection, molding

9 Compression molding, transfer molding, casting

10 Mixing and composite processing

Evaluation
Homework: 20%
Midterm: 40%
Final Exam: 40%

Preparation
Syllabus prepared by Professors James Lee and Kurt Koelling.
Last modified: January, 1999

I-67
ChE 779 Chemical Engineering Experimental Design

Description
Industrial and research experiments designed with special emphasis on reducing the
number of experiments, interpreting final results, and ensuring against unknown factors.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
En Graph 167 or equivalent or
U, G 3 three 48-min lectures SU
permission of instructor.

Textbook
W. A. Rosenkratz, Introduction to Probability and Statistics for Scientists and Engineers,
McGraw-Hill, 1997

Supplemented by handouts of technical papers and instructor's notes.

Course Objectives
 Introduce basic principles of statistics that are relevant to chemical process
operation.
 Become familiar with process operation tasks including, data rectification, process
monitoring (quality control), fault diagnosis, supervision, planning and scheduling.
 Learn the basic techniques for various operation tasks and the challenges for their
integration and efficient process operation.

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I-68
Detailed Schedule
Week Topics
Introduction to process operation tasks. Review basic principles of
1
statistics and regression. Filtering for noise reduction.
Linear and nonlinear regression. Common framework, representation as
2
sum of basis functions.
Noise removal by filtering. Fourier analysis, wavelet analysis, linear and
3
nonlinear filters.
Statistical process monitoring - univariate and multivariate. Control
4
charts, principal component analysis, T2 and Q tests.

5 Statistical process monitoring, fault diagnosis.

6 Fault diagnosis - linear and nonlinear statistical methods, neural networks.

Data rectification with process models - linear, steady-state, nonlinear,


7
dynamic models.

8 Principles of process optimization.

9 Design of Experiments.

10 Design of Experiments, summary.

Evaluation
Homework, Projects (10): 25%
Mini-Quizes (2): 5%
Exams (2): 40%
Final Exam: 30%

Preparation
Syllabus prepared by Professor Bhavik R. Bakshi.
Last modified: May 31, 1999

I-69
ENGINEERING 100 D: Engineering Survey

Description
Introduction to the University Community; strategies for successful transition to
participation in that community; institutional context of academic programs; education
and learning as lifelong processes; University resources and procedures.

Weekly Class Time Quarters


Level Credits Distribution Offered Prerequisites
one 48-min lecture,
U 1 AU Enrolled in the College of Engineering
one 48-min recitation

Textbooks and Additional Materials


Studying Engineering, R. Landis, Discovery Press, 1995
University Survey: A Guidebook and Readings for New Students
OSU Student Handbook
The Ohio State University Bulletin: Course Offerings
Master Schedule of Classes
Master Schedule Supplement

Course Objectives
 Provide guidance to engineering students regarding future course work.
 Teach OSU student rights and responsibilities including judicial affairs, university policies
and procedures, and academic misconduct.
 Educate students about personal safety issues on and off campus.
 Instruct students on how to schedule classes using phone or web service.
 Provide information about the availability and benefits of joining engineering student
organizations.
 Expose students to as many engineering majors as possible; provide information on all
engineering majors to facilitate students’ selections of majors.
 Provide information about library resources located on campus.
 Provide information about the employment opportunities of co-op and internships during
college and full-time positions upon graduation; emphasize the assistance provided by
Engineering Career Services.
 Provide information about academic support structures and resources to help students
improve study skills and test taking.
 Impress upon the students the importance of setting future goals, such as, graduate school,
or a career.
 Use texts to increase students’ understanding about what it means to be an engineer, how
to effectively prepare to become an engineer, how to study engineering subjects more
effectively, and what they can expect over the next several years.

I-70
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Detailed Schedule
Week Topics
1 welcome, introduction, overview of Chemical Engineering
2 high school vs. college, academic survival skills, student safety
3 BRUTUS and registration
4 ChE curriculum, GEC's, grading policies, probation, advising
5 code of conduct, student rights and responsibilities, misconduct
6 study skills, libraries and other information resources
7 tour of the ChE department, discussion of what chemical engineers do
8 student AIChE organization
9 co-op and internship opportunities, communicating across cultures
10 final exam

Evaluation
Lecture reports: 20%
Self-portrait: 10%
Six quarter projection: 10%
Department visit reports: 20%
Library assignment: 10%
Final Exam: 30%

Preparation
Syllabus prepared by Judith McDonald (COE) and Professor James Rathman.
Last modified: May 7, 1999

I-71

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