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CHEMISTRY 5070/11
Paper 1 Multiple Choice October/November 2016
1 hour
Additional Materials: Multiple Choice Answer Sheet
Soft clean eraser
*6497421817*
There are forty questions on this paper. Answer all questions. For each question there are four possible
answers A, B, C and D.
Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet.
Each correct answer will score one mark. A mark will not be deducted for a wrong answer.
Any rough working should be done in this booklet.
A copy of the Periodic Table is printed on page 16.
Electronic calculators may be used.
IB16 11_5070_11/6RP
© UCLES 2016 [Turn over
2
In each experiment, the gas evolved was tested with damp blue litmus paper and damp red
litmus paper.
dilute aqueous
hydrochloric acid sodium hydroxide
ammonium ammonium
carbonate carbonate
heat
experiment 1 experiment 2
Which row correctly shows the colour of both the pieces of litmus paper at the end of each
experiment?
experiment 1 experiment 2
A blue blue
B blue red
C red blue
D red red
3 A paper chromatography experiment is carried out to find an Rf value for Fe3+(aq). The result is
shown.
solvent front
Fe3+
y
x
starting line
To make the spot containing Fe3+(aq) more visible, the paper is sprayed with aqueous sodium
hydroxide so that a precipitate of iron(III) hydroxide forms.
Under the conditions of the experiment, the Rf of Fe3+(aq) is given by ......1...... and the colour of
the precipitate is ......2...... .
gap 1 gap 2
x
A red-brown
y
x
B green
y
y
C red-brown
x
y
D green
x
4 The graph gives the melting points (m.p.) of mixtures of lead and tin.
400 400
m.p. of
pure lead
300 300
100 100
0 50 100
% tin in the mixture
The graph shows that any mixture of lead and tin must have a melting point that is
5 Some students wrote three statements about the bonding in a molecule of ammonia, NH3.
1 A nitrogen atom has three outer electrons so all outer electrons are involved in
bonding.
2 A nitrogen atom has five outer electrons so two outer electrons are not involved in
bonding.
3 A nitrogen atom shares electrons with each of three hydrogen atoms.
6 Which diagram correctly shows the arrangement of the ions in solid sodium chloride?
A B
Na+ Cl – Na+ Na+
Cl – Na+ Cl – Cl –
Na+ Cl – Cl – Cl –
C D
Na+ Na+ Na+ Cl –
Cl – Cl – Cl – Na+
Cl – Cl – Cl – Na+
A good 97
B good 3550
C poor 113
D poor 4750
1 CH4
2 NH3
3 CO2
4 N2
What is the order of their rate of diffusion at room temperature and pressure?
slowest fastest
A 1 2 4 3
B 2 1 3 4
C 3 4 2 1
D 4 1 3 2
A B
–
– + + – + – + –
+ + + – + – + – + key
– – + –
+ + – + – + – – a negative ion
– + – – + – – + – + – +
+ + – + – + – + a positive ion
+ –
+
– + – + – an electron
–
C D
– – – –
+ + + + – – –
– –
– – – – + + + + –
+ + + + – + + + + –
– – – – – + + + + –
+ + + + – – – –
11 A compound containing only the elements carbon and hydrogen has 80.0% by mass of carbon.
14 Aqueous copper(II) sulfate is electrolysed using copper as the positive electrode and carbon as
the negative electrode.
The ions of which metal require the smallest number of electrons for one mole of atoms to be
liberated during electrolysis?
A aluminium
B calcium
C iron
D sodium
17 A student investigates how the concentration of a reagent affects the rate of a chemical reaction.
A balance
B gas syringe
C measuring cylinder
D stopwatch
A 1 B 2 C 3 D 4
What is X?
A calcium
B copper
C magnesium
D potassium
21 Which row shows the pH values for 0.1 mol / dm3 solutions of ammonia, hydrochloric acid,
sodium chloride and sodium hydroxide?
pH values
NH3 HCl NaCl NaOH
A 1 7 13 11
B 7 1 11 13
C 11 1 7 13
D 13 11 7 1
22 The diagram shows the apparatus used to extract aluminium from aluminium oxide.
aluminium
C The equation for the reaction at the positive electrode is Al 3+ + 3e– → Al.
D The positive carbon electrodes lose mass during the process and need regular replacement.
A 3 B 4 C 5 D 6
B 2C + O2 → 2CO
C C + CO2 → 2CO
25 Some properties which make elements different from each other are listed.
1 metallic character
2 number of electron shells in an atom
3 number of protons in an atom
4 total number of electrons in an atom
26 Aqueous copper(II) sulfate solution is placed in an iron container and left to stand for several
days.
A Atmospheric oxygen reacts with the copper(II) sulfate to give black copper(II) oxide.
B Some fine iron particles are formed in the solution.
C The part of the container in contact with the solution is coated with copper.
D The solution turns from green to blue.
27 Which equation shows a reaction that will occur at room temperature and pressure?
28 Attaching pieces of magnesium to underground iron pipes can protect the iron from corrosion.
A ammonium sulfate
B barium carbonate
C calcium hydroxide
D lead chloride
30 In the Haber process, hydrogen and nitrogen react to form ammonia in the presence of a catalyst.
Which of the two reactants is obtained by fractional distillation and what is the catalyst used in the
Haber process?
obtained by
fractional catalyst
distillation
A hydrogen iron
B hydrogen nickel
C nitrogen iron
D nitrogen nickel
31 An element, Z, from Group II of the Periodic Table reacts with chlorine, an element from
Group VII.
32 The table shows treatments used for drinking water supplies and reasons for using those
treatments.
33 The table shows some atmospheric pollutants and their possible effects.
pollutant effect
34 How many moles of ethanoic acid, CH3CO2H, react with one mole of magnesium?
A 1 B 2 C 3 D 4
35 With which substance will ethene react to form more than one product?
A argon
B hydrogen
C oxygen
D steam
H H
H H C H H C H H
H C C H C C
H H C H H C H H
H H
X Y
A both 1 and 2
B 1 only
C 2 only
D neither 1 nor 2
H H H O
H C C C C H H H
H H H O C C C H
H H H
A butyl butanoate
B butyl propanoate
C propyl butanoate
D propyl propanoate
38 An unsaturated hydrocarbon with six carbon atoms contains only three C=C double bonds. This
hydrocarbon is reacted with excess hydrogen at a high temperature.
What is R?
A a fat
B a nylon
C a polyester
D a protein
BLANK PAGE
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
International Examinations Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download at
www.cie.org.uk after the live examination series.
Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local
Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
© UCLES 2016
1 2
H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10
Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
16
55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
5070/11/O/N/16
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.)
Cambridge International Examinations
Cambridge Ordinary Level
CHEMISTRY 5070/12
Paper 1 Multiple Choice October/November 2016
1 hour
Additional Materials: Multiple Choice Answer Sheet
Soft clean eraser
*5229043977*
There are forty questions on this paper. Answer all questions. For each question there are four possible
answers A, B, C and D.
Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet.
Each correct answer will score one mark. A mark will not be deducted for a wrong answer.
Any rough working should be done in this booklet.
A copy of the Periodic Table is printed on page 16.
Electronic calculators may be used.
IB16 11_5070_12/5RP
© UCLES 2016 [Turn over
2
1 When measured under the same conditions, which gas diffuses at the same rate as nitrogen?
A ammonia, NH3
B carbon monoxide, CO
C ethane, C2H6
D oxygen, O2
2 When calcium carbonate is added to dilute hydrochloric acid, carbon dioxide gas is released.
tap
cotton wool
funnel
CaCO3(s)
+ HCl (aq)
CaCO3(s)
0100.02
+ HCl (aq) gas syringe
1 2
thistle
funnel
measuring
cylinder
CaCO3(s)
+ HCl (aq)
water
3
Which sets of apparatus are suitable, together with a stopwatch, for following the rate of this
reaction?
4 Benzene and cyclohexane are both flammable liquids. They are able to mix with each other
without separating into two layers. They have very similar boiling points. It is difficult to separate a
mixture of these two liquids by fractional distillation.
5 The graph gives the melting points (m.p.) of mixtures of lead and tin.
400 400
m.p. of
pure lead
300 300
100 100
0 50 100
% tin in the mixture
The graph shows that any mixture of lead and tin must have a melting point that is
7 When substance Q melts, only weak forces of attraction between its molecules are overcome.
electrical conduction
melting point / °C
of solid Q
A 44 non-conductor
B 98 conductor
C 660 conductor
D 714 non-conductor
8 A solution containing lead(II) ions is added to a solution containing iodide ions. A yellow
precipitate is formed.
A Pb+ + I – → PbI
B Pb+ + 2I – → PbI2
C Pb2+ + I– → PbI
carbon
atom
buckminsterfullerene
A a covalent compound
B an ionic compound
C a polymer
D molecular
10 Which diagram correctly shows the arrangement of the ions in solid sodium chloride?
A B
Na+ Cl – Na+ Na+
Cl – Na+ Cl – Cl –
Na+ Cl – Cl – Cl –
C D
Na+ Na+ Na+ Cl –
Cl – Cl – Cl – Na+
Cl – Cl – Cl – Na+
A aluminium
B calcium
C copper(II)
D zinc
A diamond
B magnesium
C pure ethanoic acid
D solid sodium chloride
The ions of which metal require the smallest number of electrons for one mole of atoms to be
liberated during electrolysis?
A aluminium
B calcium
C iron
D sodium
A B
products reactants
energy x energy x
reactants products
C D
x x
reactants products
energy energy
products reactants
17 In two experiments, 1 and 2, an excess of powdered calcium carbonate was reacted in a flask
with dilute hydrochloric acid.
In experiment 1, the carbon dioxide evolved was collected and the volume of gas measured at
regular intervals.
In experiment 2, the mass of the flask and its contents was measured at regular intervals.
W X Y Z
0 0 0 0
0 time 0 time 0 time 0 time
experiment 1 experiment 2
A W Y
B W Z
C X Y
D X Z
What is X?
A calcium
B copper
C magnesium
D potassium
melting density
point / °C in g / cm3
A 44 1.82
B 181 0.53
C 271 9.75
D 1244 7.20
The positions of four elements are shown on the outline of part of the Periodic Table.
Which is element Z?
A B
C
25 The table shows the observations made when an aqueous solution of salt Z has different
reagents added to it.
What is Z?
A copper(II) chloride
B copper(II) sulfate
C iron(II) chloride
D iron(II) sulfate
26 The diagram shows the apparatus used to extract aluminium from aluminium oxide.
aluminium
C The equation for the reaction at the positive electrode is Al 3+ + 3e– → Al.
D The positive carbon electrodes lose mass during the process and need regular replacement.
B 2C + O2 → 2CO
C C + CO2 → 2CO
28 Aqueous copper(II) sulfate solution is placed in an iron container and left to stand for several
days.
A Atmospheric oxygen reacts with the copper(II) sulfate to give black copper(II) oxide.
29 In the manufacture of paper, sulfur dioxide is used to remove the yellow colour from the wood
pulp.
A a bleach
B a catalyst
C an oxidising agent
D a solvent
A Helium is used in balloons because it is unreactive and less dense than air.
B Hydrogen is used in an addition reaction with saturated vegetable oils to form margarine.
C Nitrogen from the air is used in the manufacture of ammonia.
D Oxygen is used in making steel and welding.
metals
electrolyte
Which pair of metals, when used as electrodes, will give the largest reading on the voltmeter, V?
32 When reacted with an excess of dilute hydrochloric acid, 0.002 moles of a metal M liberated
48 cm3 of hydrogen measured at r.t.p.
A 2M + 2H+ → 2M + + H2
B M + H+ → M + + H
C M + 2H+ → M 2+ + H2
D M + 2H+ → M 2+ + 2H
H C 2H 5 H C 2H 5 H C 2H 5
C C C C C C
H H H H H H
A CH3CH=CH2
B CH3CH2CH=CH2
C CH3CH2CH=CHCH3
D CH3CH=CHCH3
34 The table shows some atmospheric pollutants and their possible effects.
pollutant effect
36 How many moles of ethanoic acid, CH3CO2H, react with one mole of magnesium?
A 1 B 2 C 3 D 4
37 With which substance will ethene react to form more than one product?
A argon
B hydrogen
C oxygen
D steam
A 1 B 2 C 3 D 4
A an addition polymer
B a carbohydrate
C a polyamide
D a polyester
BLANK PAGE
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
International Examinations Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download at
www.cie.org.uk after the live examination series.
Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local
Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
© UCLES 2016
1 2
H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10
Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
16
55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
5070/12/O/N/16
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.)
Cambridge International Examinations
Cambridge Ordinary Level
* 4 0 5 3 2 1 1 0 0 8 *
CHEMISTRY 5070/21
Paper 2 Theory October/November 2016
1 hour 30 minutes
Candidates answer on the Question Paper.
No Additional Materials are required.
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use an HB pencil for any diagrams or graphs.
Do not use staples, paper clips, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.
Section A
Answer all questions.
Write your answers in the spaces provided in the Question Paper.
Section B
Answer any three questions.
Write your answers in the spaces provided in the Question Paper.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part question.
DC (LEG/SG) 107872/3
© UCLES 2016 [Turn over
2
Section A
Ba(NO3)2
CaCO3
CaO
CH4
C3H8
Fe2O3
KMnO4
NaNO3
NO
SO2
V2O5
Zn(NO3)2
Each of these compounds can be used once, more than once or not at all.
Which compound
...............................................................................................................................................[1]
...............................................................................................................................................[1]
(c) dissolves in water to form an aqueous solution which gives a white precipitate on addition of
aqueous sodium sulfate,
...............................................................................................................................................[1]
(d) is a catalyst in the contact process for the manufacture of sulfuric acid,
...............................................................................................................................................[1]
...............................................................................................................................................[1]
[Total: 5]
.......................................................................................................................................[1]
(ii) Describe how you could measure the pH of dilute sulfuric acid.
...........................................................................................................................................
.......................................................................................................................................[1]
(b) Many plants cannot grow in soils which are too acidic.
Describe and explain how soils which are too acidic can be treated to reduce the acidity.
...................................................................................................................................................
...................................................................................................................................................
...............................................................................................................................................[2]
(c) The graph shows the effect of soil pH on the rate of uptake of potassium ions by plant roots.
rate of uptake
of potassium
ions
2 3 4 5 6 7 8 9 10
soil pH
Describe how the rate of uptake of potassium ions varies with soil pH.
...................................................................................................................................................
...............................................................................................................................................[1]
[Total: 5]
A3 The alcohols are a homologous series with the general formula CnH2n+1OH.
(a) Deduce the molecular formula of the alcohol having eight carbon atoms.
...............................................................................................................................................[1]
(i) Describe how the boiling point changes with the number of carbon atoms in the alcohol.
.......................................................................................................................................[1]
.......................................................................................................................................[1]
(iii) What is the physical state of pentanol at room temperature and pressure? Explain your
answer.
...........................................................................................................................................
...........................................................................................................................................
.......................................................................................................................................[1]
...................................................................................................................................................
...............................................................................................................................................[2]
...............................................................................................................................................[2]
(i) Suggest the oxidising agent and describe the conditions used for this reaction.
...........................................................................................................................................
.......................................................................................................................................[2]
© UCLES 2016 5070/21/O/N/16
5
(ii) Draw the structure of propanoic acid, showing all the atoms and all the bonds.
[1]
[Total: 11]
The table shows how the relative rate of this reaction changes when different concentrations of
peroxodisulfate ions and iodide ions are used.
(a) Use the information in the table to describe how increasing the concentration of each of these
ions affects the relative rate of reaction.
...................................................................................................................................................
...................................................................................................................................................
[2]
...................................................................................................................................................
...............................................................................................................................................[1]
(i) Explain how iron(III) ions are acting as an oxidising agent in this reaction.
...........................................................................................................................................
.......................................................................................................................................[1]
.......................................................................................................................................[1]
test ....................................................................................................................................
observation ........................................................................................................................
[2]
(d) Iron(II) ions react with peroxodisulfate ions. The products are iron(III) ions and sulfate ions.
...............................................................................................................................................[1]
[Total: 8]
A5 Potassium chlorate, KCl O3, decomposes to form potassium chloride and oxygen.
[2]
(b) Calculate the maximum volume of oxygen formed at room temperature and pressure when
12.25 g of potassium chlorate is completely decomposed.
[3]
(i) Explain in terms of gain and loss of electrons, how potassium ions and chloride ions are
formed when potassium reacts with chlorine.
...........................................................................................................................................
...........................................................................................................................................
...........................................................................................................................................
.......................................................................................................................................[3]
...........................................................................................................................................
.......................................................................................................................................[2]
[Total: 10]
(a) State the percentage compositions by volume of nitrogen and oxygen present in dry air.
nitrogen ................................ %
[1]
.......................................................................................................................................[1]
(c) Titanium is extracted from titanium(IV) chloride by reduction with molten sodium in an argon
atmosphere and not in air.
Suggest why this reaction is carried out in an argon atmosphere and not in air.
...................................................................................................................................................
...............................................................................................................................................[2]
...............................................................................................................................................[1]
[Total: 6]
Section B
(a) Draw an energy profile diagram for this reaction on the axes shown.
energy
reaction pathway
[3]
test ............................................................................................................................................
observation ...............................................................................................................................
[2]
(c) The catalyst used in the manufacture of ethenyl ethanoate contains copper.
COCH3
O H
C C
H H
Draw the structure of the addition polymer formed from ethenyl ethanoate.
[2]
...................................................................................................................................................
...............................................................................................................................................[2]
[Total: 10]
B8 Ethanol can be manufactured by reacting ethene with steam in a closed reaction vessel.
...................................................................................................................................................
...............................................................................................................................................[2]
(b) The graph shows the percentage yield of ethanol at different temperatures.
50
40
% yield 30
of ethanol
20
10
100 200 300 400
temperature / °C
(i) Describe how, and explain why, the percentage yield changes with temperature.
...........................................................................................................................................
...........................................................................................................................................
...........................................................................................................................................
.......................................................................................................................................[3]
(ii) Suggest why the reaction is carried out at 300 °C and not at 200 °C.
...........................................................................................................................................
...........................................................................................................................................
.......................................................................................................................................[2]
(c) Describe how, and explain why, the position of equilibrium changes when the pressure is
increased.
...................................................................................................................................................
...................................................................................................................................................
...............................................................................................................................................[2]
(d) Ethanol reacts with methanoic acid, HCO2H, to form ethyl methanoate and water.
...............................................................................................................................................[1]
[Total: 10]
...................................................................................................................................................
...............................................................................................................................................[2]
(b) Draw a labelled diagram to show how a tin rod can be electroplated with silver.
[3]
2SnO + O2 2SnO2
tin(II) oxide tin(IV) oxide
When a sample of 13.5 g of tin(II) oxide is reacted with oxygen, 12.7 g of tin(IV) oxide is
formed.
...................................................... % [3]
[Total: 10]
B10 A student prepared some crystals of hydrated lithium nitrate by reacting aqueous lithium hydroxide
with dilute nitric acid.
(a) Explain how you would carry out this procedure to obtain pure dry crystals of hydrated lithium
nitrate.
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
...............................................................................................................................................[4]
(b) The student used 20.0 cm3 of 0.500 mol / dm3 of lithium hydroxide to prepare the crystals.
Calculate the maximum mass of hydrated lithium nitrate crystals that could be made.
....................................................... g [3]
...............................................................................................................................................[1]
...............................................................................................................................................[1]
[Total: 10]
BLANK PAGE
BLANK PAGE
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable
effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will
be pleased to make amends at the earliest possible opportunity.
To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge International
Examinations Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download at www.cie.org.uk after
the live examination series.
Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local
Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
© UCLES 2016
I II III IV V VI VII VIII
1 2
H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10
Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
20
85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
5070/21/O/N/16
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.)
Cambridge International Examinations
Cambridge Ordinary Level
* 4 1 2 1 9 0 8 7 2 6 *
CHEMISTRY 5070/22
Paper 2 Theory October/November 2016
1 hour 30 minutes
Candidates answer on the Question Paper.
No Additional Materials are required.
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use an HB pencil for any diagrams or graphs.
Do not use staples, paper clips, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.
Section A
Answer all questions.
Write your answers in the spaces provided in the Question Paper.
Section B
Answer any three questions.
Write your answers in the spaces provided in the Question Paper.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part question.
DC (LEG/SG) 107871/4
© UCLES 2016 [Turn over
2
Section A
BaCl 2
C 2H 4
C 3H 4
C 3H 8
CO
CO2
K2SO4
Na3PO4
SO2
ZnSO4
Each of these compounds can be used once, more than once or not at all.
...............................................................................................................................................[1]
...............................................................................................................................................[1]
(c) dissolves in water to form an aqueous solution which gives a white precipitate on addition of
aqueous sodium hydroxide,
...............................................................................................................................................[1]
...............................................................................................................................................[1]
...............................................................................................................................................[1]
[Total: 5]
A2 Farmers add fertilisers such as ammonium sulfate to the soil to increase the rate of plant growth.
test ............................................................................................................................................
observation ...............................................................................................................................
[2]
(c) When ammonia dissolves in water, ammonium ions and hydroxide ions are formed.
Write the ionic equation for the reaction of aqueous ammonia with sulfuric acid.
...............................................................................................................................................[1]
[Total: 5]
...................................................................................................................................................
...............................................................................................................................................[2]
(b) Draw the structures of the branched and unbranched alkanes having four carbon atoms.
[2]
(c) The graph shows how the melting points of the first nine unbranched alkanes vary with the
number of carbon atoms per molecule.
–50
melting point
/ °C –100
–150
–200
1 2 3 4 5 6 7 8 9 10
number of carbon atoms per molecule
(i) Describe how the melting points of these alkanes change with the number of carbon
atoms.
...........................................................................................................................................
...........................................................................................................................................
.......................................................................................................................................[2]
(ii) Use the graph to estimate the melting point of the unbranched alkane which has ten
carbon atoms.
......................................................°C [1]
(d) (i) Construct the equation for the complete combustion of pentane, C5H12.
.......................................................................................................................................[2]
(ii) Name the products of the incomplete combustion of pentane and explain why the
incomplete combustion of hydrocarbons is hazardous to health.
...........................................................................................................................................
.......................................................................................................................................[2]
[Total: 11]
CH3COCH3 + I2 CH3COCH2I + HI
The table shows how the relative rate of this reaction changes when different concentrations of
propanone, iodine and hydrochloric acid are used.
(a) Describe how increasing the concentration of each of these substances affects the relative
rate of reaction.
propanone ................................................................................................................................
iodine ........................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
...............................................................................................................................................[2]
...................................................................................................................................................
...............................................................................................................................................[1]
Aqueous iodine reacts with aqueous astatide ions, At–, to produce astatine.
...............................................................................................................................................[1]
...................................................................................................................................................
...............................................................................................................................................[1]
[Total: 8]
...................................................... % [2]
(b) Calculate the maximum volume of gas formed at room temperature and pressure when 1.71 g
of nickel carbonyl reacts completely with hydrogen iodide.
CO
OC Ni CO
CO
...................................................................................................................................................
...............................................................................................................................................[2]
(d) The proton numbers and accurate relative atomic masses of cobalt and nickel are shown in
the table.
cobalt nickel
proton number 27 28
relative atomic mass 58.9 58.7
Suggest why cobalt has a higher relative atomic mass than nickel.
...................................................................................................................................................
...................................................................................................................................................
...............................................................................................................................................[2]
...................................................................................................................................................
...............................................................................................................................................[1]
[Total: 10]
...............................................................................................................................................[1]
...................................................................................................................................................
...............................................................................................................................................[2]
(c) Name the products formed when rubidium reacts with water.
(d) Titanium is extracted from titanium(IV) chloride by reduction with molten sodium.
...............................................................................................................................................[1]
[Total: 6]
BLANK PAGE
Section B
B7 In the contact process, sulfur trioxide is made by the catalytic oxidation of sulfur dioxide. In a
closed container the following equilibrium is set up.
...............................................................................................................................................[1]
[1]
(c) The graph shows the percentage yield of sulfur trioxide at different temperatures.
100
95
90
% yield
85
80
75
100 200 300 400 500 600
temperature / °C
(i) Describe how, and explain why, the percentage yield of sulfur trioxide changes with
temperature.
...........................................................................................................................................
...........................................................................................................................................
...........................................................................................................................................
.......................................................................................................................................[3]
(ii) Suggest why the reaction is carried out at 450 °C and not at 250 °C.
...........................................................................................................................................
...........................................................................................................................................
.......................................................................................................................................[2]
(d) Describe how, and explain why, the position of equilibrium changes when the pressure
increases.
...................................................................................................................................................
...................................................................................................................................................
...............................................................................................................................................[2]
(e) Sulfur trioxide oxidises hydrogen bromide to form sulfur dioxide, bromine and water.
...............................................................................................................................................[1]
[Total: 10]
B8 Propenenitrile, CH2=CHCN, is made by passing a mixture of propene, ammonia and oxygen over
a catalyst at 450 °C.
(a) Draw an energy profile diagram for this reaction on the axes shown.
energy
reaction pathway
[3]
Explain why.
...................................................................................................................................................
...............................................................................................................................................[1]
H CN
C C
H H
[2]
(d) The catalyst used in the reaction to make propenenitrile is molybdenum. Molybdenum is a
transition element.
...........................................................................................................................................
.......................................................................................................................................[2]
(ii) Molybdenum reacts with chlorine at room temperature to form molybdenum(VI) chloride,
MoCl6. Molybdenum(VI) chloride has a melting point of 254 °C.
.......................................................................................................................................[2]
[Total: 10]
(a) Explain why magnesium reacts with hydrochloric acid but copper does not.
...............................................................................................................................................[1]
(b) Brass is an alloy of copper and zinc. The table shows how the composition of brass influences
its relative strength.
composition of brass
relative strength
% copper % zinc
90 10 2.6
80 20 3.0
70 30 3.3
60 40 3.6
...................................................................................................................................................
...............................................................................................................................................[1]
(c) Use your knowledge of the structure of metals to explain why brass is stronger than pure
copper.
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
...............................................................................................................................................[3]
(d) Draw a labelled diagram to show how a steel rod can be electroplated with copper.
[3]
[Total: 10]
B10 A student prepared some crystals of hydrated copper(II) sulfate by reacting excess insoluble
copper(II) oxide with dilute sulfuric acid.
(a) Describe how you would obtain pure dry crystals of hydrated copper(II) sulfate from the
reaction mixture.
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
...............................................................................................................................................[3]
(b) The student used 15.0 cm3 of 2.00 mol / dm3 sulfuric acid to prepare the crystals.
Calculate the maximum mass of hydrated copper(II) sulfate crystals that could be made.
....................................................... g [3]
(c) Aqueous ammonia is added to aqueous copper(II) sulfate until the ammonia is in excess.
...................................................................................................................................................
...............................................................................................................................................[2]
[Total: 10]
© UCLES 2016 5070/22/O/N/16
19
BLANK PAGE
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge International
Examinations Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download at www.cie.org.uk after
the live examination series.
Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local
Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
© UCLES 2016
I II III IV V VI VII VIII
1 2
H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10
Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
20
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
5070/22/O/N/16
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.)
Cambridge International Examinations
Cambridge Ordinary Level
* 2 3 2 3 6 1 9 5 8 2 *
CHEMISTRY 5070/31
Paper 3 Practical Test October/November 2016
1 hour 30 minutes
Candidates answer on the Question Paper.
Additional Materials: As listed in the Confidential Instructions
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use an HB pencil for any diagrams or graphs.
Do not use staples, paper clips, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part question.
Total
DC (ST) 107576/2
© UCLES 2016 [Turn over
2
1 Mangalloy is made by alloying steel with manganese. The percentage by mass of manganese
in mangalloy can be determined by converting all the manganese in the alloy into aqueous
manganate(VII) ions and then using the solution to titrate aqueous iron(II) sulfate.
No indicator is needed for this titration as the products of the reaction are almost colourless and
one drop of aqueous manganate(VII) ions in excess produces a permanent pale pink colour.
P is an aqueous solution of manganate(VII) ions, MnO4–. The solution was prepared by converting
all the manganese in a 2.12 g sample of mangalloy into manganate(VII) ions and making the final
volume up to 250 cm3 by adding water.
The colour of P makes it difficult to see the bottom of the meniscus so you should take all your
readings using the top of the meniscus.
Add P from the burette. At first the purple colour disappears quickly but as more P is added
the colour disappears less quickly. At the end-point, one drop of P produces a pale pink colour
that does not disappear on swirling.
Record your results in the table, repeating the titration as many times as you consider
necessary to achieve consistent results.
Results
Burette readings
titration number 1 2
final reading / cm3
initial reading / cm3
volume of P used / cm3
best titration results (✓)
Summary
Using these results, the average volume of P required was ...................... cm3.
Calculate the number of moles of iron(II) sulfate present in the volume of Q used.
(c) Using your answer from (b), calculate the number of moles of manganate(VII) ions present in
the average volume of P required.
[Five moles of iron(II) sulfate react with one mole of manganate(VII) ions.]
(d) Using your answer from (c), calculate the number of moles of manganate(VII) ions in
250 cm3 of P.
(e) Using your answer from (d), calculate the mass of manganese in the 2.12 g sample of
mangalloy.
[The relative atomic mass of manganese is 55.]
(f) Using your answer from (e), calculate the percentage by mass of manganese in mangalloy.
[Total: 17]
[19]
Conclusions
[Total: 23]
BLANK PAGE
BLANK PAGE
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable
effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will
be pleased to make amends at the earliest possible opportunity.
To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge International
Examinations Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download at www.cie.org.uk after
the live examination series.
Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local
Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
CHEMISTRY 5070/32
Paper 3 Practical Test October/November 2016
1 hour 30 minutes
Candidates answer on the Question Paper.
Additional Materials: As listed in the Confidential Instructions
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use an HB pencil for any diagrams or graphs.
Do not use staples, paper clips, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part question.
Total
DC (RW) 107574/3
© UCLES 2016 [Turn over
2
1 The percentage by mass of iron in steel can be determined by converting all the iron in the
steel into aqueous iron(II) ions and titrating portions of the solution with aqueous potassium
manganate(VII).
No indicator is needed for this titration as the products of the reaction are almost colourless and
one drop of aqueous potassium manganate(VII) in excess produces a permanent pale pink colour.
P is an aqueous solution of iron(II) ions, Fe2+. The solution was prepared by converting all the iron
in a 3.12 g sample of steel into iron(II) ions and making the final volume up to 500 cm3 by adding
water.
The colour of Q makes it difficult to see the bottom of the meniscus so you should take all
your readings using the top of the meniscus.
Add Q from the burette. At first the purple colour disappears quickly but as more Q is added
the colour disappears less quickly. At the end-point, one drop of Q produces a pale pink
colour that does not disappear on swirling.
Record your results in the table, repeating the titration as many times as you consider
necessary to achieve consistent results.
Results
Burette readings
titration number 1 2
final reading / cm3
initial reading / cm3
volume of Q used / cm3
best titration results (✓)
Summary
Using these results, the average volume of Q required was ...................... cm3.
Calculate the number of moles of potassium manganate(VII) present in the average volume
of Q required.
(c) Using your answer from (b), calculate the number of moles of iron(II) ions present in the
volume of P used in each titration.
[Five moles of iron(II) ions react with one mole of potassium manganate(VII) ions].
(d) Using your answer from (c), calculate the number of moles of iron(II) ions in 500 cm3 of P.
(e) Using your answer from (d), calculate the mass of iron in the 3.12 g sample of steel.
[The relative atomic mass of iron is 56.]
(f) Using your answer from (e), calculate the percentage by mass of iron in the steel.
[Total: 17]
[19]
Conclusions
[Total: 23]
BLANK PAGE
BLANK PAGE
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable
effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will
be pleased to make amends at the earliest possible opportunity.
To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge International
Examinations Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download at www.cie.org.uk after
the live examination series.
Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local
Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
CHEMISTRY 5070/41
Paper 4 Alternative to Practical October/November 2016
1 hour
Candidates answer on the Question Paper.
No Additional Materials are required.
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use an HB pencil for any diagrams or graphs.
Do not use staples, paper clips, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part question.
DC (NF/FD) 107611/4
© UCLES 2016 [Turn over
2
1 A student separates a mixture of pentane and hexane using the apparatus shown. Pentane
collects in the conical flask.
thermometer
water in
A
water out
conical
flask
mixture of pentane
and hexane
heat
.......................................................................... [1]
...................................................................................................................................... [1]
.......................................................................... [1]
1. ..............................................................................................................................................
2. ..............................................................................................................................................
[2]
.............................................................................................................................................. [1]
(d) (i) State why a Bunsen burner should not be used to heat the mixture of pentane and
hexane.
...................................................................................................................................... [1]
...................................................................................................................................... [1]
(e) Suggest why pentane collects in the conical flask before hexane.
...................................................................................................................................................
.............................................................................................................................................. [2]
[Total: 10]
2 A student investigates the electrolysis of aqueous copper(II) sulfate using the apparatus shown.
+ –
anode cathode
aqueous
copper(II) sulfate
.............................................................................................................................................. [1]
.............................................................................................................................................. [1]
(c) Name the gas produced at the anode. Give a test and observation to identify this gas.
[Total: 4]
In questions 3 to 5 inclusive, place a tick (✓) in the box against the correct answer.
3 A student finds that a compound contains 4.8 g of carbon, 0.8 g of hydrogen and 6.4 g of oxygen.
(a) CH2O
(b) C2H2O
(c) C2HO2
(d) C4H8O4
[Total: 1]
4 Aqueous solutions of which of the following pairs of compounds will not react together to form a
precipitate?
[Total: 1]
5 A student adds the catalyst manganese(IV) oxide to aqueous hydrogen peroxide. The hydrogen
peroxide decomposes.
The student measures the volume of oxygen given off at regular time intervals. This is experiment 1.
The student repeats the experiment using one different condition. This is experiment 2.
volume
of experiment 1
oxygen
experiment 2
0
0 time
[Total: 1]
6 Copper(II) oxide and carbon are both black solids. Copper(II) oxide reacts with dilute sulfuric acid
forming aqueous copper(II) sulfate. Carbon does not react with dilute sulfuric acid.
Describe how you would obtain a pure, dry sample of carbon from a mixture of powdered
copper(II) oxide and powdered carbon.
You should give experimental details and the observations occurring at each stage of the
procedure.
..........................................................................................................................................................
..........................................................................................................................................................
..........................................................................................................................................................
..........................................................................................................................................................
..........................................................................................................................................................
..........................................................................................................................................................
[Total: 5]
7 Limestone is impure calcium carbonate. A student does an experiment to determine the percentage
by mass of calcium carbonate in a sample of limestone. The sample of limestone is placed in a
previously weighed container and reweighed.
....................................................... g [1]
The student transfers the sample of limestone into a beaker and adds 50.0 cm3 of 2.00 mol / dm3
hydrochloric acid, an excess. The calcium carbonate reacts with the hydrochloric acid.
The student transfers the contents of the beaker into another container and the volume is made
up to 250 cm3 with distilled water. This is solution T.
.............................................................................................................................................. [1]
25.0 cm3 of T is transferred to a conical flask and a few drops of methyl orange indicator are
added.
An aqueous solution of 0.100 mol / dm3 sodium hydroxide is put into a burette and run into the
conical flask until the end-point is reached.
(c) What is the colour change of the methyl orange at the end-point?
(d) Three titrations are done. The diagrams show parts of the burette with the liquid levels at the
beginning and end of each titration.
0 29 16 45 4 32
1 30 17 46 5 33
2 31 18 47 6 34
titration number 1 2 3
final burette
reading / cm3
initial burette
reading / cm3
volume of
0.100 mol / dm3
sodium
hydroxide / cm3
best titration results
(✓)
Summary
Using these results, the average volume of 0.100 mol / dm3 sodium hydroxide is
........................................................ cm3.
[4]
(e) Calculate the number of moles of sodium hydroxide in the average volume of 0.100 mol / dm3
sodium hydroxide in (d).
and your answer to (e), deduce the number of moles of hydrochloric acid in 25.0 cm3 of T.
(h) Calculate the number of moles of hydrochloric acid in the original 50.0 cm3 of 2.00 mol / dm3
hydrochloric acid.
(i) Using your answers to (h) and (g), calculate the number of moles of hydrochloric acid that
reacted with the calcium carbonate in the sample of limestone.
and your answer to (i), calculate the number of moles of calcium carbonate that reacted with
the hydrochloric acid.
.......................................................... [1]
(l) Using your answers to (j) and (k), calculate the mass of calcium carbonate in the sample of
limestone.
....................................................... g [1]
(m) Using your answers to (a) and (l), calculate the percentage by mass of calcium carbonate in
the sample of limestone.
.......................................................% [1]
[Total: 16]
Complete the table by adding the conclusion for (a), the observations for (b) (i), (ii) and (iii), the
conclusions for (c)(i) and (ii) and both the test and observation which lead to the conclusion for
test (d). Any gases produced should be identified by test, result and name.
[4]
(c) (i) To the second part, A green precipitate forms.
aqueous ammonia
is added until a
change is seen.
[3]
(e) The green precipitate that forms in test (c) turns brown at the surface after a few minutes.
Suggest why.
...................................................................................................................................................
.............................................................................................................................................. [2]
[Total: 11]
© UCLES 2016 5070/41/O/N/16 [Turn over
12
9 When magnesium powder is added to an excess of hydrochloric acid, the temperature rises.
(a) (i) What type of reaction does the temperature rise indicate?
............................................................ [1]
(ii) In addition to the temperature rise, give two observations that can be made as the
reaction takes place.
...........................................................................................................................................
...................................................................................................................................... [2]
(iii) Construct an equation for the reaction between magnesium powder and
hydrochloric acid.
...................................................................................................................................... [1]
(b) A student does an experiment to determine the amount of heat produced in the reaction. The
student transfers 50.0 cm3 of 2.0 mol / dm3 hydrochloric acid to a beaker. The temperature of
the solution is 20.0 °C. When 0.20 g of magnesium powder is added to the hydrochloric acid
the temperature rises rapidly.
magnesium thermometer
powder
The student records the temperature of the mixture at one minute intervals.
Plot the results on the grid. Draw a straight line through the points. Extend the line until it
intersects the y-axis.
40
35
temperature
of the mixture
/ °C
30
25
20
0 1 2 3 4 5 6
time / min
[3]
(c) (i) Use your graph to determine the temperature at 0 minutes. This gives the maximum
temperature of the mixture reached in the reaction.
..................................................... °C [1]
(ii) The initial temperature of the hydrochloric acid was 20.0 °C. Use your answer to (c)(i) to
calculate the maximum temperature rise.
..................................................... °C [1]
(d) 4.2 joules (J) of heat energy are required to raise the temperature of 1.0 cm3 of hydrochloric
acid by 1 °C.
(i) Calculate the amount of heat energy in joules (J) required to raise the temperature of
50.0 cm3 of hydrochloric acid by 1 °C.
........................................................ J [1]
(ii) Calculate the amount of heat energy in joules (J) required to raise the temperature of
50.0 cm3 of hydrochloric acid by the maximum temperature rise calculated in (c)(ii).
........................................................ J [1]
[Total: 11]
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publisher will be pleased to make amends at the earliest possible opportunity.
To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge International
Examinations Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download at www.cie.org.uk after
the live examination series.
Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local
Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
CHEMISTRY 5070/42
Paper 4 Alternative to Practical October/November 2016
1 hour
Candidates answer on the Question Paper.
No Additional Materials are required.
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use an HB pencil for any diagrams or graphs.
Do not use staples, paper clips, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part question.
DC (NF/FD) 107618/4
© UCLES 2016 [Turn over
2
1 A student uses acidified aqueous potassium manganate(VII) to oxidise ethanol to ethanoic acid.
bung
water in
A
water out
heat
...................................................................................................................................... [1]
...................................................................................................................................... [1]
1. ..............................................................................................................................................
2. ..............................................................................................................................................
[2]
(c) (i) State why a Bunsen burner should not be used to heat the mixture of ethanol and
potassium manganate(VII).
...................................................................................................................................... [1]
...................................................................................................................................... [1]
(d) Name the process that the student uses to separate ethanoic acid from the mixture after
heating.
.............................................................................................................................................. [1]
(e) The ethanoic acid is heated with another sample of ethanol and a catalyst of sulfuric acid.
.............................................................................................................................................. [1]
[Total: 8]
dilute
sulfuric acid
+ –
(a) Name the gas that collects at the anode. Give a test and observation to identify this gas.
(b) Name the gas that collects at the cathode. Give a test and observation to identify this gas.
(c) The student does three more experiments with different electrolytes, using the apparatus
shown.
+ –
electrolyte
concentrated
black solid bubbles of
aqueous sodium
/ brown solution colourless gas
iodide
concentrated
aqueous bubbles of
pink solid
copper(II) colourless gas
sulfate
concentrated
aqueous sodium chlorine hydrogen
chloride
[6]
[Total: 10]
In questions 3 to 6 inclusive, place a tick (✓) in the box against the correct answer.
3 A student burns 4.8 g of an element X in excess oxygen. The mass of the oxide produced is 8.0 g.
(a) XO
(b) X2O
(c) X2O2
(d) X3O5
[Total: 1]
4 The chromatogram shows the results of chromatography using mixture Z as well as individual
dyes labelled 1, 2, 3 and 4.
starting line
solvent
flow Z 1 2 3 4
(a) 1 only
(b) 2 and 3
(c) 1 and 4
(d) 4 only
[Total: 1]
5 A student adds excess zinc to hydrochloric acid and measures the volume of hydrogen gas given
off at regular time intervals. This is experiment 1.
The student makes a change to one of the conditions and then repeats the experiment. This is
experiment 2.
experiment 2
volume experiment 1
of
hydrogen
0
0 time
[Total: 1]
6 A student passes air backwards and forwards over heated copper using the apparatus shown.
The original volume of air in the apparatus is 50.0 cm3.
copper
The experiment continues until the volume of gas stops changing. Some unreacted copper
remains.
(a) 10 cm3
(b) 30 cm3
(c) 40 cm3
(d) 60 cm3
[Total: 1]
7 Vinegar contains dilute ethanoic acid. Different brands of vinegar contain different concentrations
of ethanoic acid.
You are provided with two different brands of colourless vinegar as well as the apparatus and
chemicals normally found in a laboratory.
Describe how you would carry out experiments to find out which of the two brands contains the
higher concentration of ethanoic acid.
You should give experimental details and the observations occurring at each stage of the
procedure.
..........................................................................................................................................................
..........................................................................................................................................................
..........................................................................................................................................................
..........................................................................................................................................................
..........................................................................................................................................................
..........................................................................................................................................................
..........................................................................................................................................................
..........................................................................................................................................................
..........................................................................................................................................................
..........................................................................................................................................................
[Total: 5]
....................................................... g [1]
The student transfers the sample of impure copper to a beaker, adds excess concentrated nitric
acid and stirs until all the solid has dissolved. The copper reacts with the nitric acid producing
aqueous copper nitrate as shown in equation 1.
An excess of aqueous potassium iodide and an excess of dilute hydrochloric acid are then added
to the beaker. A further reaction occurs as shown in equation 2.
The contents of the beaker are transferred to a suitable container and made up to 250 cm3 with
distilled water. This is solution J.
.............................................................................................................................................. [1]
The student transfers 25.0 cm3 of J to a conical flask and adds a few drops of a suitable indicator.
An aqueous solution of 0.100 mol / dm3 sodium thiosulfate, Na2S2O3, is put into a burette and run
into the conical flask until the end-point is reached. The reaction between sodium thiosulfate,
Na2S2O3, and iodine, I2, is shown in equation 3.
(c) Three titrations are done. The diagrams show parts of the burette with the liquid levels at the
beginning and end of each titration.
0 20 24 47 10 32
1 21 25 48 11 33
2 22 26 49 12 34
titration number 1 2 3
final burette
reading / cm3
initial burette
reading / cm3
volume of
0.100 mol / dm3
Na2S2O3 / cm3
best titration results
(✓)
Summary
Using these results, the average volume of 0.100 mol / dm3 Na2S2O3 is
........................................................ cm3.
[4]
(d) Calculate the number of moles of Na2S2O3 in the average volume of 0.100 mol / dm3 Na2S2O3.
(e) Use your answer to (d) and equation 3 to calculate the number of moles of I2 in 25.0 cm3
of J.
(f) Use your answer to (e) to calculate the number of moles of I2 in 250 cm3 of J.
(g) Use your answer to (f) and equation 2 to calculate the number of moles of Cu(NO3)2 that
produce the number of moles of I2 calculated in (f).
(h) Use your answer to (g) and equation 1 to deduce the number of moles of Cu that produce
the number of moles of Cu(NO3)2 calculated in (g).
(i) Use your answer to (h) to calculate the mass of copper in the sample of impure copper.
....................................................... g [1]
(j) Use your answers to (i) and (a) to calculate the percentage by mass of copper in the sample
of impure copper.
.......................................................% [1]
[Total: 13]
9 The following table shows the tests a student does on a mixture L, which contains two compounds.
Complete the table by adding the conclusion for (a), the observations for (b) (i), (ii) and (iii), the
conclusions for tests (c) (i) and (ii), and both the test and observation which lead to the conclusion
for test (d). Any gases produced should be identified by test, result and name.
[4]
(c) (i) To the second part, A white precipitate forms.
aqueous ammonia
is added until a
change is seen.
[3]
(e) Give the formulae of the two compounds which are present in mixture L.
[Total: 11]
.......................................................... [1]
M + CuSO4 MSO4 + Cu
A student transfers 25.0 cm3 of 2.7 mol / dm3 of aqueous copper(II) sulfate to a glass beaker.
A 0.4 g sample of metal M is added to the beaker and the mixture is stirred. The student records
the maximum temperature rise with a thermometer.
M thermometer
The student repeats the experiment using different masses of metal M and in each case calculates
and records the maximum temperature rise.
(b) Plot the maximum temperature rise against the mass of M on the grid and draw two
intersecting straight lines through the points.
10
maximum
temperature rise
/ °C
4
0
0.0 0.4 0.8 1.2 1.6 2.0 2.4
mass of M / g
[3]
(c) (i) Use your graph to determine the mass of M required to produce a maximum temperature
rise of 5.0 °C.
....................................................... g [1]
(ii) Use your graph to determine the maximum temperature rise which would occur if 1.5 g of
M is used in the experiment.
..................................................... °C [1]
(d) (i) Calculate the number of moles of copper(II) sulfate in 25.0 cm3 of 2.7 mol / dm3 aqueous
copper(II) sulfate.
(ii) Use your graph to deduce the mass of M that reacts completely with 25.0 cm3 of
2.7 mol / dm3 aqueous copper(II) sulfate.
....................................................... g [1]
M + CuSO4 MSO4 + Cu
and your answers to (d)(i) and (d)(ii) to calculate the relative atomic mass of metal M.
........................................................... [1]
[Total: 9]
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge International
Examinations Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download at www.cie.org.uk after
the live examination series.
Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local
Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.