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ALL INDIA TEST SERIES

OPEN TEST

JEE (Advanced)-2021
PAPER –1

TEST DATE: 24-01-2021

ANSWERS, HINTS & SOLUTIONS


Physics PART – I

SECTION – A
1. B
Sol. In a rotational equilibrium net torque about the CM must be zero i.e. F must pass through CM.

2. A
Sol. Coefficient of friction is small so there will be slipping between the blocks.
3. C
f
Sol. U  nR  T2  T1 
2
3
 Pf Vf  PV
i i
2
3
 
 105  4  105  6  3  105 J
2
4. B
Sol. Motion of Q with respect to P
  
v Q,P  v Q  v P
vQ,P
d d
 sin 60 60°
30 P
30 km 60° O
d  15 3 km 60°
60°
V
Q

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AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 2

5. B

Sol. E A  EB 
20D

6. A
Sol. d  r.dqE
d = r.(2r.dr) E
r dB dr
E r
2 dt
QR2 dB

4 dt
MR2
  dt    0
2
Q
 B0
2M

7. C, D
dT
Sol. H  K 0 x4x 2
dx
2R0 T0
H dx
4K 0 
R0
x3 2T

  dT , it will give H
0

x T
H dx
and
4K 0 R0
 x3 2T

  dT , it will give T = f(x).
0

8. B, C, D
D
Sol. Optical path length =  dy  2 D
0
0

20D
t
c

9. B, D
1
Sol. When the distance increases, intensity gets reduced as I 
r2
Kmax depends on the frequency of light.

10. A, D

Sol.
mdv
dt
 
 qE0 ˆI  q v x ˆi  v y ˆj  v zkˆ XB0 ˆj
Solving we get vy = 0
E02
and vx(max) = v 02 
B02

11. A, C
Sol. Conceptual

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3 AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021

12. B, C, D
mv 02 v0
Sol. T ,  decreases.

  2 R  R 
d v 0 d v0
    d
dt  dt 2R  R
2 t 
   2R  R  d  v  dt 0
0 0 

R

SECTION – C

13. 00007.70
2
1 R H
Sol. mg   w g
3  3  3
2
1 R  H 1
mg   g  R2Hw g
3  2  2 3

Solving these equation,  7.70
w

14. 00000.15
Sol. mg = R2P R
1 1 
Where P = S    r
r R
Since R >> r
 1
 P = S  
r 
S
 mg  R 2
r
Mg  mg  R 2 P

1 1 
P  S  ,  
 r R 
r
r   , R  r 
2
2
 P  S  
r
R .2r  R2 .2r 
2

 R  R 2
2
 Mg  mg   2R2 S    
r
S
4R2
r

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AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 4

= 4 mg
 M = 3m
= 3 × 0.050
= 0.15 Kg

15. 00002.49
Sol. Conservation of momentum
1
2  4K 1  2  12K 3 cos  K2 0n

and 2  1  K 2  2  12K 3 sin  K1


and Q = K3 + K2 – K1 
 5.80 = K2 + K3 – 5.32 
Solving it K3 = 2.49 MeV. 9
Be 12
C , K3

16. 00001.23
hc
Sol. K e max  

12400
  10  90 eV
124
Ke of fastest electron falling in collector is 10090 eV
hc
 C 
eV
12400
 1.23
10090

17. 00000.25
Sol. Power, P = mgv0
= 2  10  2.5
= 50W
dT
P  2H
dt
dT 50
  0.25 C/s
dt 200

18. 00019.60
Sol. If E = 0
Let particle strikes at point B. v0
z
 AB2 = OB2 OA2
3a2 3a2 a2
= r2  = a2  
4 4 4
a B
AB  a
2 r
a
O  A
AB 2 1 x
sin     (0, 0, 0)
OB a 2
 2  r
 m
 3 
Time taken to reach at B, t =
q0B (0, 0, a) v0
E  0, this time displacement along y-axis during

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5 AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021

2 2
1 qE  2  m 2 Em  2  a
y 0      
2 m  3  q20B 2 2q0B2  3  2
Co-ordinate of point of impact
 3a a a 
=  , ,
 2 2 2 
 
Velocity at point of impact
 E 2 ˆ 3v 0 ˆ a ˆ ˆ
v   v 0 cos 60iˆ  j ˆ
k  (  i  j  3k)
B 3 2 2
Angular momentum of particle before collision about O,
 a
L  1 ( 3iˆ  ˆj  k)ˆ  a (ˆi  ˆj  3k)
ˆ
2 2

= 4 ( 3  1)iˆ  4jˆ  ( 3  1)kˆ 

| L | 8 6 kg-m2/sec

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AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 6

Chemistry PART – II

SECTION – A

19. D
Sol. Possible isomers are
K 3 Fe  CN6  K 3 Fe NC 6 
K 3 Fe  CN5 NC   K 3 Fe NC 5  CN 
   
K 3 Fe  CN4  NC 2  K 3 Fe NC 4  CN2 
 cis and trans   cis and trans 
 
K 3 Fe  CN3  NC 3 
 fac and mer 

20. A
Sol.
Ph
N N N  N Ph  N N

Here phenyl group preferentially migrates due to its high migratory aptitude.

21. B
Sol. Ph Ph OH Ph
NH2OH
C O 
pH 5  C N  C N
Me Me Me OH
Ph OH O
H2SO4 / 
C N   Ph C N CH3
Beckman's rearrangement 
H3C H
N  methyl benzamide

22. B
Sol. 

H2  g  I2  g 
 2HI  g
Initial mol 1 1 0
mol at eqbm 1  x  1  x  2x
1  x  1  x 
2x
eqbm conc
V V V
Now, equivalents of hypo used = equivalents of I2 present at equilibrium
0.110  1  1  x   2
x = 0.5
1
2

So, K c  4
 1  1
  
2 2

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7 AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021

So, Kc for the reaction


1


 1 1  1 2 1
HI  g 
 H2  g   I2  g will be     0.5
2 2 4 2
Hence, (B)

23. D
Sol. qp  806  100  80600 J
80600
So, Hvap   40300 J mol1  40.3 kJmol1
2
n  Hvap 80600
S vap    216.08 J K 1
boiling point 373
Uvap  Hvap  ngRT
 80.6  2  8.314  373  103
 74.3 kJ
Since, the system is at equilibrium so G  0.
Hence, (D) is incorrect.

24. D
Sol. Correct reaction is
1.B H THF
CH2  CH2 
2 6
2. CH COOH
 CH3  CH3
3

25. B
Sol. (A) Highly pure dilute solution of sodium in liquid ammonia is blue and not red.
4NaNO3  s    2Na2 O  2N2  g  5O2  g
o
 800 C
(B)
Na  O2 
 Na2 O2  NaO2
(C)
 excess   traces 

(D) 

 B  OH 4  H
(i) H3BO3  H2 O   
…(i)
O OH
OH HO OH

ii B 
 B

OH OH
OH HO O
So, in accordance with Le Chatlier’s principle, Eq. (i) shifts in forward direction due to reaction (ii)
and hence pH decreases.

26. A, C, D
q
Sol. (A) S X  Z   0 reversible adiabatic change 
T
100
(B) SXZ Y  S XY  2.303  5  8.314log10  95.7 JK 1
10
(because ‘S’ is a state function).
(C) S X  Y  95.7 JK 1 Reversible isothermal expansion 
(D) Since ‘S’ is a state function, so S X  Y  S X  Z  SZ Y  95.7 JK 1
 0  S z  Y  95.7
So, A, C and D are correct.

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AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 8

27. A, B, C
Sol. (A) H
Me H
Me Et
Et Me
Me Et
Me Et H Me (S)
H Me Me2HC Et
Me
H Me H
H H
CHMe2
Me
Me
(B) H
H H
H Me
Et CHMe2
Me Me
Me2HC Me H H (S)
Me2HC H Et Me
CHMe2
H Me2HC H
H
Me H
Me
Me
(C) H
Et H
Et CHMe2
CHMe2 Et
H CHMe2
H CHMe2 H Et (S)
H Et Me CHMe2
H
H H H H
Me H
H
H
(D) Et
Et Et
Et Me

H Me
H Me Et Et
H
H H H
H
H
H

Me

Et Et

Me
(achiral)

28. A, C, D
Sol. Resonance effect of ester is less dominant than aldehydes and ketones.
29. A, B, C
Sol. O O O O

Si Si Cr Cr
O O O O O O

O O O O
(A) (B)

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9 AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021

O O

S S
. .
O O O

O .
O
(C) (D)
(Cyclic silicate)
30. A, B, D
Sol. (A) 1st excitation

Cl :
3s 3p 3d

So, x  5
(B) nd
2 excitation

1st excitation

He :
1s 2s  y  3
(C) nd
2 excitation

1st excitation

H:
1s 2s 2p 3s 3p 3d

degenarate
So, z = 9

SECTION – C

31. 00002.80
Sol. CH3 NO2

Si C
H3C CH3 Cl Cl

CH3 Cl
tetra methyl silane tear gas
(x = 6) (y = 14)

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AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 10

32. 00001.50
Sol. O O
N NH2

 4e  
Highly acidic condition
Electric current 

OH
O O
N NH2

 6e  
Mild acidic condition

Electric current 

So, n = 4 F, m = 6 F

33. 00001.80
Sol. Blue coloured compound Red coloured
compound
O2    , O3  g , Cu NH3 4  SO 4 , HgI2 ,Pb3 O 4 CuO  Black
III  II  II  III 
Ag2CrO 4 ,KO3 ,Cu2O  C2H5 3 BO3  colourless
K Fe Fe  CN6  , K Fe Fe  CN6  , y=5 CaC2O 4  white
   
z=3
N2 O3   
x=6

34. 00009.90
n2
Sol. t1/ 2 
k f  kb 
35. 00005.60
1.4  meqvts of acid used
Sol. % of N 
w
1.4  20
  5.60
5

36. 00002.50
Pb
Sol. Z  1
RT
b 
So, slope  
RT 492.6
 4
b  RT  4  r 3  NA
492.6 3
So, r  2.50A o

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11 AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021

Mathematics PART – III

SECTION – A
37. C
Sol.  x  2  x  2   x 2  4 3 tan x  16  0 
 
 x 2  4 3 tan x  16  0 must have at least one positive root

 
2
 4 3 tan   0  tan  > 0 and 4 3 tan   16  0  3 tan2   1
1
 tan  
3
   
   n  , n  ; n  z 
 6 2 
38. B
Sol. Required circles C1 and C2 are given by C1
(x – 1)2 + (y – 1)2 + k(3x + 4y – 7) = 0
 It touches x axis A(4, 5)
 x2 + (3k – 2)x + (2 – 7k) = 0 has equal roots
 k = –2, 2/9
C1 = x2 + y2 – 8x – 10y + 16 = 0
4 10 4 C2
C2 = x 2 + y 2 – x  y 0
3 8 9 6 5
B , 
4 6 5 3 5 5 4  1 1 9 9
Slope of AB  , Q     ,    i.e.  ,  Q
3  9 9 5 9 9 5  3 9
39. C

Sol.
dy


2x3  1
y
3x 
dx x 1  x 3  1  x3   
2

1
2x 
x 2 dx
2x3 1
 x1 x3  dx  1 2
 x  x
If = e e x  
1  x3
x 3x2 yx 1 1
Solution is y    1 x dx ,  c  y 
 
   
3 3 3 2
1 x 3 1 x 2 1  x3 2x 1  x 3

40. C
Sol. Equation of auxiliary circle (x – 1)2 + (y – 4)2 = a2
 a = 5  ae  5 2  e  2
S(6, 9)
 7 13 
Point on directrix LL   , 
2 2  Q
Equation of directrix is x + y – 10 = 0 (5, 7) P(h, k)
(1, 4)
Equation of tangent through (5, 7) is x + 2y – 19 = 0
Point Q(1, 9)  PSQ = 90 S(–4, –1)
 13 
 P(h, k) is  6, 
 2 

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AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 12

41. C
Sol. Use graph

42. C
 
Sol. r  xa  yb  z  a  b  ..... (1)
r  a  b   r  b a   r  a b
 r b  2, r a  3
3
Moreover x  , y  1
2
15 1
Also, r   z
2 2
 r a b   2

43. A, B, D
a b 
Sol. A  ; ad – bc  0
c d 
a + b + c + d = 5, aij  {0, 1, 2, 3, 4, 5}
(A) (i) Exactly one zero
4! 4!
Number of matrices =   24
2! 2!
(ii) Exactly 2 zeros
Number of matrices = 2  5 1C2 1  8
 Total matrices = 32
2
(B) Number of symmetric matrices =   6  2b   12
b0
(C) Det A = ad – bc is odd
a b 
A  if A = A then b = c
T

c d 
 Det A = ad – b2, a + d = 5 – 2b
(i) b = 0, a + d = 5 not possible
(ii) b = 1, a + d = 3 4 cases
(iii) b = 2, a + d = 1 not possible

44. A, B, D
1
Sol. 
P  n   1  P  n  1  4
P(2) = 0


P  3   1  P  2  41  41
 1 1 3
P  4   1    
 4  4 16
 3  1 13
P  5   1   
 16  4 64
 13  1 51
P  6  1   4  256
 64 

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13 AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021

45. B, C, D
Sol. Foot of perpendicular P  (–6, –9)
Q  12,  36  (0, 8)
S(48, 72)

and R   24, 18 
R
 S1  y 2  108x  0
(27, 0)
S2  x 2  32y  0
P

46. A, B, C
Sol. z  z 1 z 1
1
 (2x + 1)2 = (x – 1)2 ; x  
2
 x  1
2
y2
 3x2 + 6x – y2 = 0  
1
1 3
branch of
hyperbola
(–1, 0) (–1, 0)
y = –2

 x  1
2
y2
|z – 1| + |z + 3| = 6  z lies on an ellipse  1
9 5
Re z > 0, Im (z)  –2
Let ax + by = 1 be a chord of curve S1 = 0
3(x)2 – y2 + 6x(ax + by) = 0
If angle subtended is 90, then
1 x
3(1 + 2a) – 1 = 0  a   . Chord is   by  1  0 which passes through (–3, 0)
3 3

47. C, D
Sol. Let f(x) = x3 – x4 – x2 + 2020
f(x) = 3x2 – 4x3 – 2x = –x(4x2 – 3x + 2)
 f(x) is decreasing  x > 0
n 1
1 r
Sn  lim
n
 n f  n   T
k 0
n

48. B, D

Sol. f(x) = x tan x ; g  x  


x
; g  x  

1  x tan x  x x sec 2 x  tan x 
1  x tan x
 
2
1  x tan2 x

 cos x  x  cos x  x   
= 0  x = ,    0, 
cos2 x 1  x tan x 
2
 2

 g(x) > 0  0 < x <  ; g(x) < 0   < x <
2

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AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 14

SECTION – C

49. 00300.00
n
Sol. Sn  
k 0
nk
Ck  k = 1 n 1Cn  2 n 2
Cn  .....  n 2n
Cn

= coefficient of xn in 1 x  n1


 2 1  x 
n 2
 3 1  x 
n 3
 ..... n 1  x 
2n

 n 1  x 
2n 1 n 1 2n 1 

1  x   1  x  

= coefficient of in xn 
 x x2 
2n 1 2n 1
= n Cn 1  Cn  2
100  201! 201! 201!  1 1 
S100   =   A + B = 300
101! 100! 102! 99! 99!  101! 102! 

50. 00025.00
C
100  x 2 5 B
Sol. cos  
10 –
x 5
50  x 2 100  x 2 x 2  50 
cos         
50 10 50 D 10 A
 25(100 – – x 2) =
= + 2500 – (x2 50)2 x4 100x2
 2
 x  5 3 and    ABC 
3 3

51. 00004.00
 /3 2
    
2
    
Sol. I 
0
log
 2 
 
1  3 tan 3

 x  
     3
 
 x 

 3 3

 x   dx
 
 /3
 
  x  3x 
2
2 4
= log2   dx
0  1  3 tan x 
 /3

  x  3x 
2
2 5
I dx =
810
0

52. 00082.00
k 2
Sol. S1(n) = –64n2, S2 k    k  3k  1
3

53. 00009.00
R
Sol. In radius of DEF = 2R cos A cos B cos C =
4
1
 cos A cos B cos C =  ABC is equilateral
8
a3
R  3 a=3
3 2
4 a
4

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15 AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021

54. 00192.00
 C(0, c, 0)
Sol. OP  a ˆi  bkˆ R(a, c, 0)

PC  a ˆi  cjˆ  bkˆ
 E(0, c, b)
OA  a ˆi Q
Equation of PC, r  a ˆi  bkˆ    a ˆi  cjˆ  bkˆ 
O A(a, 0, b)
Equation of OA, r  aiˆ
 ac  kˆ  bjˆ B(0, 0, b) P(a, 0, b)
Shortest distance =  a ˆi  bkˆ    ackˆ  abjˆ 
a b2  c 2
abc bc ac ab
1    Similarly  2  , 3 
2 2 2 2
a b c b c a  c2
2
a  b2
2

1 1 1  1 1 1   1 1 1 
   2 2  2  2   2   
12  22 23 a b c   ab bc ca 

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