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Progress in Organic Coatings xxx (2014) xxx–xxx

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Progress in Organic Coatings


journal homepage: www.elsevier.com/locate/porgcoat

Powder coating of veneered particle board surfaces by hot pressing


Monica Badila a , Christoph Jocham a , Wenbiao Zhang b , Thomas Schmidt c ,
Günter Wuzella a , Uwe Müller a , Andreas Kandelbauer a,d,∗
a
WOOD Carinthian Competence Centre, Klagenfurterstraße 87-89, A-9300, St. Veit an der Glan, Austria
b
Zhejiang Agricultural & Forestry University, School of Engineering, 88, North Circle Rd., Lin‘an, Zhejiang Province, 311300 China
c
TIGER Coatings GmbH & Co. KG, Negrellistraße 36, A-4600 Wels, Austria
d
School of Applied Chemistry, Reutlingen University, Alteburgstraße 150, D-72762 Reutlingen, Germany

a r t i c l e i n f o a b s t r a c t

Article history: The powder coating of veneered particle boards by the sequence electrostatic powder application –
Received 31 July 2013 powder curing via hot pressing is studied in order to create high gloss surfaces. To obtain an appealing
Received in revised form 20 August 2013 aspect, veneer sheets were glued by heat and pressure on top of particle boards and the resulting surfaces
Accepted 12 September 2013
were used as carrier substrates for powder coat finishing. Prior to the powder coating, the veneered
Available online xxx
particle board surfaces were pre-treated by sanding to obtain good uniformity and the boards were
stored in a climate chamber at controlled temperature and humidity conditions to adjust an appropriate
Keywords:
electrical surface resistance. Characterization of surface texture was done by 3D microscopy. The surface
Powder coating
Veneer
electrical resistance was measured for the six veneers before and after their application on the particle
Particle board board surface. A transparent powder top-coat was applied electrostatically onto the veneered particle
Press board surface. Curing of the powder was done using a heated press at 130 ◦ C for 8 min and a smooth,
Curing glossy coating was obtained on the veneered surfaces. By applying different amounts of powder the
Gloss coating thickness could be varied and the optimum amount of powder was determined for each veneer
type.
© 2014 Elsevier B.V. All rights reserved.

1. Introduction layer that confers the required resistance is usually applied onto
the furniture surface.
Engineered wood panels such as medium density fiber boards Engineered wood is usually coated by melamine formaldehyde
(MDF) or particle boards have since long been used as substitutes resin impregnated papers yielding decorative laminates, which
for native wood products in many applications because of several represent about 70% of all panels [1]. The remainder is surface fin-
advantages. Since they consist of homogenized, refined particles ished by painting, varnishing or veneering [2,3]. Recently, printed
or fibers that are glued together with high-performance resins the surface designs [4] and the powder coating of engineered wood
technical properties of such panels can be tailored within a wide products [5–9] have come into the focus of research and develop-
range and the resultant products are much less influenced by the ment.
natural inhomogeneity that is observed with a natural material In light of the increasingly severe regulations imposed by
such as native wood. In addition, the rather low price contributed European legislation regarding the reduction of volatile organic
to the wide-spread use of such panels in interior design and furni- compounds (VOC) [10], powder coating technology applied to engi-
ture applications. Besides their low price, these engineered wood neered wood has steadily gained in popularity during the past
boards also present specific features that recommend them as years. As compared to wet coating, the absence of solvents and the
building materials: they are flat, rigid, smooth panels that can eas- possibility of practically 100% recycling of the non-adhering pow-
ily be processed and thus, show good mechanical stability towards der material after electrostatic spray application makes powder
compression, torsion or shearing stresses. However, for creating coating an attractive environmentally friendly alternative which in
high-value products for the end-users, typically their surfaces must many applications is already able to compete with solvent-borne
display an appealing design. Other important issues are the sur- and water-borne wet coating systems. Studies have shown [11,12]
face resistance against moisture, scratch, impact or dirt. A coating that some major drawbacks of water-borne coatings applied to
wood are caused by the interaction of water with the wood fiber.
Water produces fiber swelling due to hydration and wet adhesion
∗ Corresponding author. is diminished. The swelling of the wood grain results in a finish that
E-mail address: andreas.kandelbauer@reutlingen-university.de has a rougher feel and appearance. Although with the appropriate
(A. Kandelbauer). combination of coatings, equipment, and sanding the grain size can

0300-9440/$ – see front matter © 2014 Elsevier B.V. All rights reserved.
http://dx.doi.org/10.1016/j.porgcoat.2013.09.018

Please cite this article in press as: M. Badila, et al., Powder coating of veneered particle board surfaces by hot pressing, Prog. Org. Coat.
(2014), http://dx.doi.org/10.1016/j.porgcoat.2013.09.018
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be reduced to an acceptable level, still waterborne coatings should commercial particle boards with dimensions of 320 mm × 280 mm
preferably be used only as topcoats instead of fully waterborne sys- and a thickness of 18.7 mm were used.
tems. Being solvent-free and 100% solid, powder coating eliminates The veneer sheets were glued on top of commercial particle
any such problems caused by solvents or fiber swelling. boards using Placol 4507 urea-formaldehyde resin glue (Geistlich
Among other advantages, powder coating allows freedom in Ligamenta AG, Schlieren, Switzerland). The glue was mixed with
design also with complex shaped three-dimensional objects and water (glue: water = 2:1 by weight) and was evenly distributed
permits the customized coating of consumer items in batch sizes on the entire particle board surface. The veneer sheet was then
of one at economically feasible costs. glued onto the particle board surface by heat and pressure using
One major drawback, however, is that with powder coatings, so a SUT-PUK 1600 heated press (Svoboda Umformtechnik GmbH,
far no high-gloss surfaces have been realized. Wien, Austria) at a temperature of 70 ◦ C for 360 s and a pressure
As such, in the past twenty years powder coating has been of 80 N/cm2 .
applied in the automotive industry in the coating of metal The veneered particle boards were sanded on an industrial
parts thereby producing superior durable and environmentally automated sanding machine (grit size P150) to improve veneer
friendly finishes. In recent years, intense research affords have uniformity and increase absorbability prior to powder coating. The
been undertaken to transfer this technology to engineered wood, boards such prepared were then equilibrated in a climate chamber
mainly MDF panels [13,14]. The difficulties encountered in this (Binder MKF720, BINDER GmbH, Tuttlingen, Germany) at 25 ◦ C/55%
technology transfer arise mainly from the limited electrical con- relative humidity.
ductivity, the bad temperature stability, and the unsatisfactory
surface homogeneity of wood-based panels compared to metal
surfaces. Many of the technological issues in the coating of MDF 2.2. Electrical resistance and moisture content measurements
have been already successfully addressed and the requirements
of MDF powder coating technology is quite well understood The electrical resistance measurements were performed after
with respect to the substrate (residual moisture content, density conditioning of the panels according to DIN EN 61340-4-1 [15]
profiles, etc.) and the process (pre-treatment methods, curing pro- using a teraohmmeter (TO-3, H.-P. FISCHER ELEKTRONIK GmbH &
tocols). Co., Mittenwalde, Germany): two cylindrical electrodes were pos-
However, the powder coating of solid wood materials is not itioned at a distance of 30 cm and the surface electrical resistance
yet far developed and practically no research work has been pub- was determined (absolute value). The test voltage was 250 V.
lished in the international scientific literature so far on this subject. For additional more detailed studies on the influence of panel
The powder coating of solid wood is technologically much more moisture content on the surface electrical resistance of raw veneers
demanding than coating MDF since this substrate material due and veneered particle boards, the electrical resistance measure-
to its more native, “natural” character is even more inhomoge- ments were carried out directly, immediately after the conditioning
neous and of much less favorable surface texture than is engineered process in the climate chamber.
wood. Further complicating the matter is the potential presence of The moisture content of the veneers was determined after con-
volatile compounds or extractives that may interfere with film for- ditioning in accordance with the procedure described by DIN EN
mation and curing of the powder coating film. Such components 322 [16].
have been removed in the case of engineered wood in the course
of homogenization. Wood veneer is a typical example of a solid
wood-based material that still shows some typical characteristics 2.3. Electrostatic powder application on veneered particle boards
of native wood. Wood veneer is frequently applied in the surface
finishing of wood-based panels and, in contrast to paper-based dec- The powder used in the powder coating of veneered particle
orative laminates still needs a subsequent coating step which is boards was transparent Drylac 530 Series from TIGER Coatings
currently performed using solvent or water borne paintings. In the GmbH & Co. KG, Wels, Austria. Drylac Series 530 is a highly reac-
present study, a novel approach to apply powder coatings to wood tive hybrid epoxy/polyester powder coating. Curing is accelerated
veneer surfaces is described. by a mixture of catalysts that allow curing times of 3 min at 150 ◦ C
Typically, special low-temperature curing powder coatings that or 5 min at 135 ◦ C which accounts for savings in energy and time.
were optimized for application onto MDF are either cured in con- Due to its rather low curing temperature Drylac Series 530 pow-
ventional ovens (convective heat transfer) or in infrared ovens der is very much suitable for the coating of temperature-sensitive
(radiative heat transfer); attempts are made also to apply UV-curing substrates such as MDF and wood.
powder coats. In contrast, in the present study, a completely dif- The powder was applied uniformly onto the veneered parti-
ferent approach for the film formation and curing of the powder cle board surface using a laboratory powder coating spray booth
coating is pursued. Here, we describe how to create decorative sur- “Laborkabine Typ 1‘200” with a manual PEM-X1 spray gun with
faces on particle boards using wood veneers whereby the veneer corona charging connected to a Prima Sprint X digital control
surface is finished by a powder coating and the curing of the pow- panel. The powder coating equipment was obtained from J. Wagner
der coating is achieved by using a heated press. The method is GmbH, Markdorf, Germany.
evaluated for its potential to produce high-gloss powder coated
surfaces.
2.4. Hot pressing

2. Materials and methods To avoid powder coating sticking problems, the high gloss press
plate was treated with release agent Frekote 770NC from Henkel,
2.1. Veneering of particle boards using a soft cloth. Three release agent coats were applied on the
high-gloss press plate before pressing. The waiting time between
For the coating of particle boards six different types of treatments was 5 min for the release agent to dry.
wood veneers were used: Maple (Acer platanoides), Bamboo The powder was melted and cured at a temperature of 130 ◦ C
(Phyllostachys pubescens), Beech (Fagus sylvatica), Walnut (Juglans for 8 min and a press force of 64 N/cm2 , using the SUT-PUK 1600
regia), Oak (Quercus robur) and Wenge (Millettia laurentii). Standard heated press from Svoboda Umformtechnik GmbH, Vienna, Austria.

Please cite this article in press as: M. Badila, et al., Powder coating of veneered particle board surfaces by hot pressing, Prog. Org. Coat.
(2014), http://dx.doi.org/10.1016/j.porgcoat.2013.09.018
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2.5. Polishing process throughout the growth ring instead of being collected in a band or
row. The types of wood veneers used in the present study were
Polishing was done in order to improve surface uniformity selected as to represent a wide range of different morphologies to
and to test if gloss can be further improved. Fine polishing paper gain a representative overview about the principle powder coata-
was used with grit P1500 and P2000 “Super Assilex, Orange” bility of solid wood-based materials. Table 1 summarizes some
from Kovax. Final polishing was done with the polishing paste relevant information on the various wood species used. It is seen
“Polyshine” from Argotec GmbH (Esslingen, Germany) which was that the density of the used veneers and, in turn, their porosity var-
applied using a lamb fur. The surface was cleaned with soap water ied within a wide range from 0.3 to close to 1 g cm−3 . Also, the fine
then dried. structure of the pores varied from very tiny and almost invisible
pores (e.g., beech wood) to very large ones (e.g., wenge).
2.6. Gloss Surface roughness of the coating substrate is very important and,
in case of solid wood surfaces, can strongly be influenced by var-
Gloss measurements were performed with a Novo Gloss Trio ious factors such as cross grain, annual ring width, ratio of early
device from Rhopoint Instruments Limited, UK, at an angle of 20◦ , wood and late wood, rays, knots, juvenile and mature wood and
before and after polishing. The final gloss value was calculated as specific cell structures. Tight grained woods include maple and
an average from five individual measurements. beech; hence, for instance, these woods are smooth to the touch
and, therefore, should allow for an even finishing with powder
2.7. Surface topography and roughness measurements coating films.
The evaluation of surface roughness plays an important role in
The three-dimensional morphology of the samples was mea- predicting surface performance and in monitoring the manufactur-
sured before and after powder coating using the 3D - optical ing process. Literature studies showed that the strength of glued
microscope Infinite Focus (Alicona Imaging GmbH, Graz, Austria) wooden materials and other mechanical properties of wood prod-
at five-fold magnification, with a vertical resolution of 1 ␮m and ucts depend on surface roughness [19]. Rough veneer can reduce
a measurement area of 10 × 10 mm2 . The surface morphology was bond quality by as much as one-third compared to smooth veneer
than examined using the software IFM 2.0-1 from Alicona Imaging [20]. Also, studies show that smooth surfaces need relatively little
GmbH (Graz, Austria). As texture indicators, the amplitude parame- paint for coverage, and paint performance is improved [21]. There-
ters Sa (average roughness), Sv (max valley depth), Sz (max height) fore, in the present study, before powder coating experiments were
and the functional parameter Svk (reduced valley depth) were con- carried out, the surface smoothness of the veneer substrates was
sidered (primary profile). determined using 3D microscopy. Analysis of the surface topogra-
phy by 3D microscopy offers important information regarding the
2.8. Adhesion roughness, primary profile, waviness and porosity of a substrate
and is a useful tool in the analysis of surfaces before coating. To
Cross-cut tests were done to evaluate the surface stability study the influence of surface topography and surface roughness
against mechanical damage. The degree of exterior layer delamina- of the coating substrate on the final coating quality, the surface
tion is assessed using the European Standard ISO 2409:2007 [17], textures of both the raw veneer sheets and the veneered particle
on a scale from 0 to 5. When the edges of the cut are completely boards after lamination were compared to the surface topogra-
smooth without any detachment of the coating, the cross-cut test phy of the powder coated veneered particle boards. Besides the
scored a value of 0. For a high extent of flaking and delamination, frequently used roughness parameters of a surface the arithmetic
the cross-cut test yielded a value of 5, which represents the worst average deviation (Sa) of the vertical irregularities and the maxi-
rating. mum height of the characterized area (Sz) additional parameters
which characterize the wood pores, in addition, the maximum val-
2.9. Coating thickness measurements ley height (Sv) and the mean depth of the valleys below the core
material (Svk) were also considered for each veneer surface. The
Coating thickness was measured in cross-section for each surface topographic descriptors obtained from 3D microscopy for
sample, using a stereomicroscope (Zeiss Stemi 2000-C). The cross- the various types of wood veneer used are summarized in Table 1.
section was produced by cutting the sample vertically with a The corresponding values describing the surface texture of the
circular saw in order to expose all the layers: particle board, veneer powder coated samples are summarized in Table 4.
and powder coating. Before the powder coating is applied there is a high variation
among the different coating substrates within the different surface
3. Results and discussion parameters when comparing the different wood species due to dif-
ferent proportion and distribution of the pores. For example, the
3.1. Characterization of wood-veneer coating substrate oak veneer surface is characterized by dominant long deep pores
reflected by the high surface parameter values whereas the low
3.1.1. Wood veneer surface structure values recorded for maple veneer surface indicate a smooth surface.
Wood is a heterogeneous, cellular, anisotropic, and hygroscopic
material that easily adsorbs and desorbs water to eventually stabi- 3.1.2. Wood veneer electrical resistance
lize a dynamic moisture exchange equilibrium. Wood is composed In the powder coating of non-metal substrates, one crucial
of cells, and the cell walls are composed of micro-fibrils of cellulose parameter of the coating substrate is its surface electrical resis-
(40–60%) and hemicellulose (6–27%) that confer wood its strength. tance. From literature it is known that besides the moisture content
The fibers are impregnated with and held together by lignin as the at the moment of powder application, the electrical properties of
natural binder (18–41%) [18]. wood can be strongly influenced by the wood type. For instance, it
Every wood type has a distinctive grain structure. Wood species was empirically shown that pine wood has a lower electrical resis-
such as oak, and walnut have “open-pores”. These wood types are tance than fir [22]. Further, oak was found to have a lower electrical
characterized by small holes in their surface that result in a three- resistance than both of these coniferous woods analyzed. The lower
dimensionally textured surface. In diffuse-porous woods the pores electrical resistance was attributed to the lower pH, higher density
are evenly sized so that the water conducting capability is scattered and different wood structure of oak.

Please cite this article in press as: M. Badila, et al., Powder coating of veneered particle board surfaces by hot pressing, Prog. Org. Coat.
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Table 1
Characteristics of the wood types used in our study.

Wood type Pore size Density Surface texture parameters Practical features
(g/cm3 ) (air
dried)

Sa (␮m) Sv (␮m) Sz (␮m) Svk (␮m)

Maple Diffuse, evenly sized, fine texture 0.6–0.75 6.7 70.2 119.8 13.3 Hard, resistant to shock
Beech Tiny, almost invisible, very fine texture 0.7–0.9 7.3 103.4 211.5 11.8 Hard, strong, heavy, flexible
Oak Large open-pore, coarse texture 0.6–0.9 16.8 282.3 405.3 107.5 Heavy, strong, prominent grain
Walnut Medium-sized pores 0.65–0.7 9.0 158.8 211.2 45.6 Strong, hard and durable
Wenge Very large pores, very coarse texture 0.8–0.9 17.2 261.7 301.6 125.3 Moderate hardness and resistance
Bamboo Open-pore, coarse texture 0.3–0.4 9.5 145.2 241.0 40.5 Sturdy, strong, hard, great tensile strength

Table 2
Moisture values (U) for different types of veneers at varying relative humidity (RH).

Veneer type

Climate UMaple (%) UBamboo (%) UBeech (%) UOak (%) UWalnut (%) UWenge (%)
(◦ C/% RH)

25/30 7.3 5.7 7.0 8.0 8.7 7.2


25/40 8.3 6.9 8.1 9.6 9.8 8.3
25/50 8.8 7.1 8.8 9.9 10.4 8.6
25/60 95 7.9 9.2 10.7 10.7 9.6

Table 3
Surface electrical resistance (R) at 25 ◦ C and varying relative humidity for raw veneers and veneered particle boards.

Veneer type

Climate RMaple () RBamboo () RBeech () ROak () RWalnut () RWenge ()
(◦ C/%RH)

25/30 5.61 × 1011 1.66 × 1011 5.83 × 1011 1.073 × 1011 5.33 × 1011 1.41 × 1011
25/40 1.85 × 1011 2.70 × 1011 1.99 × 1011 2.90 × 1011 2.69 × 1011 2.80 × 1011
25/50 1.01 × 1011 1.45 × 1010 8.43 × 1010 2.033 × 1010 1.39 × 1011 1.86 × 1010
25/60 5.46 × 1010 5.83 × 109 6.16 × 1010 1.60 × 1010 9.16 × 1010 6.50 × 109
Veneered particle board
25/30 6.53 × 1010 7.40 × 1010 4.76 × 1010 4.00 × 1010 6.00 × 1010 4.13 × 1010
25/40 2.13 × 1010 1.76 × 1010 2.06 × 1010 1.86 × 1010 2.20 × 1010 1.70 × 1010
25/50 1.59 × 1010 1.36 × 1010 1.31 × 1010 1.26 × 1010 1.86 × 1010 1.29 × 1010
25/60 6.86 × 109 4.83 × 109 6.29 × 109 6.06 × 109 7.90 × 109 5.66 × 109

Studies that were mainly performed on medium density fiber- coating step. Therefore, in the next step, the values for the sur-
boards (MDF) have shown that for the successful electrostatic face electrical resistance of the raw veneers were compared to the
powder application onto wood-based substrates an electrical sur- surface electrical resistance of veneered particle boards. The val-
face resistance below 1011  is required [23–26]. Since moisture ues for electrical resistance of veneers and laminated veneers are
content and electrical resistance need carefully be controlled, these presented in Table 3.
parameters were measured at 25 ◦ C and varying relative humid- Upon comparison of the surface electrical resistance values at
ity (30, 40, 50 and 60%) [27,28]. The moisture content values are 25 ◦ C/50% relative humidity for the raw veneers before laminating
summarized in Table 2. to those of the veneer surfaces that were laminated onto the par-
As expected, for all wood species studied, the moisture content ticle boards (Fig. 2) it can be observed that in general the electrical
is increasing with relative humidity and the desired moisture con-
tent can be adjusted by tuning the relative humidity under defined
climatization conditions. Since for powder deposition the electrical
resistance is of immediate importance, the influence of the mois-
ture content on the electrical resistance has been investigated in
more detail. Fig. 1 shows the dependence of veneer surface electri-
cal resistance on moisture content and veneer type.
It was observed that for all veneer types the surface electrical
resistance decreases with increasing moisture content. This is in
agreement with the work of Dunky and Niemz [29] who found that
the electrical resistance of pine wood decreases with increasing rel-
ative humidity. It can also be observed that the electrical resistance
is strongly influenced by the wood species. The findings are also in
agreement with similar results obtained for MDF panels [25].
However, since the laminating step in which the raw veneer
sheets are glued on top of the carrier boards may significantly
change the surface properties of the raw veneers due to the expo-
sure to heat and pressure during hot pressing, these values may not Fig. 1. Dependence of surface electrical resistance on veneer moisture content and
be suitable for discussing the efficiency of the subsequent powder veneer type.

Please cite this article in press as: M. Badila, et al., Powder coating of veneered particle board surfaces by hot pressing, Prog. Org. Coat.
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Table 4
Coating parameters and results of the tests (Code: . . . 1 L → “one-coat low”; . . . 1 H → “one-coat high”; . . . 2 → “2-coat”).

Code Wood Nr. of Coating Coating Coating Adhesion Surface texture parameters Gloss
species coating Layer 1 Layer 2 thickness ISO2409
layers (g/m2 ) (g/m2 ) (␮m)

Sa (␮m) Sv (␮m) Sz (␮m) Svk (␮m) Gloss after Gloss after


hot press polish

A1L Maple 1 100 – 75 1 6.7 89.6 119.9 11.0 62.4 55.7


A1H Maple 1 176 – 123 0 5.3 110.3 131.5 4.1 57.3 21
A2 Maple 2 185 179 286 0 8.0 25.6 55.5 4.3 30.8 43.1
B1L Bamboo 1 103 – 64 1 7.3 78.8 109.9 4.6 52.6 42.7
B1H Bamboo 1 184 – 136 0 6.7 88.2 120.4 5.7 69.1 47.8
B2 Bamboo 2 183 179 285 0 5.6 20.9 47.5 4.8 33.8 49.1
Bu1L Beech 1 105 – 37 0 9.6 83.4 135.8 6.4 59.9 24.1
Bu1H Beech 1 177 – 102 0 7.5 107.9 133.2 5.9 77.4 38.4
Bu2 Beech 2 184 73 186 0 5.9 21.6 50.6 5.2 27.5 51.4
E1L Oak 1 106 – 79 0 6.0 99.3 172.9 11.2 56 36,2
E1H Oak 1 174 – 132 0 5.2 84.5 104.2 2.9 64.8 48.3
E2 Oak 2 185 173 263 0 5.3 21.5 44.9 4.4 28.1 49.7
N1L Walnut 1 106 – 79 1 7.3 89.8 113.3 6.5 59.2 43.9
N1H Walnut 1 184 – 136 1 6.6 110.0 140.2 5.8 74.7 29.7
N2 Walnut 2 187 83 186 0 7.9 22.0 58.0 3.7 27.9 31.5
W1L Wenge 1 102 – 56 1 6.2 82.3 105.4 5.5 63.8 38.5
W1H Wenge 1 184 –- 124 1 6.4 135.9 154.7 5.0 69.4 27.9
W2 Wenge 2 176 179 240 1 8.2 26.7 55.1 3.5 25.7 43.9
N1Hp Walnut Polished 7.8 25.6 51.8 5.7
sample (for
compari-
son with
N 1 H)

resistance is higher for the raw veneers than that of the correspond- 1010 . This observation is considered to be technologically of
ing veneered particle boards. One reason might be that the particle interest because it points towards the possibility of powder coat-
board influences the electrical surface resistance of the veneered ing veneered particleboards in general since all values were less
panels by representing a moisture sink. However, it seems more than the critical value of 1011  and, furthermore, that because
likely that under the applied pressing conditions, water is being of lamination, this principle powder coatability is more or less
evaporated and the drier veneer surface in turn suffers a loss in independent of the wood type. Hence, it should be much less prob-
electrical conductivity. This effect is pronounced differently for dif- lematic in general to apply powder coating technology to veneered
ferent kinds of wood. From Table 3 it can be seen that the electrical particle boards or even plywood, since a similar gluing and press-
resistance values are significantly higher for the raw veneers of ing step is involved in the fusion of stacks of several layers of wood
maple, beech and walnut around 1011  than those for bamboo, veneer to form plywood, than it should be when it is attempted to
oak and wenge. This corresponds to some extent to the morpho- powder coat native wood pieces.
logical features and moisture absorption values measured. The
latter two veneer types (wenge and oak) possess comparatively
rather large pores which allows for greater initial water absorp- 3.2. Characterization of powder coated veneered boards
tion and water holding capacity [30] which should, in turn, yield
greater initial electrical conductivity. Upon lamination, it is most In the coating experiments, a transparent top coat powder was
likely that this conductivity-conferring water content is removed used. The powder was applied electrostatically on the veneered
under hot-pressing conditions. However, this explanation may be particle board surfaces and melting and curing of the powder was
too simplified since bamboo with its rather open-porous structure done in the heated press, creating thus the coating layer.
displays the comparatively lowest water absorption values in the Three different amounts of powder were used on each type of
present set of veneers. Hence, other factors like composition of wood veneer in order to evaluate the efficiency of coating layer
wood species will certainly play a role as well. build-up in dependence on the used veneer type. The thicknesses
The laminating press exerts some kind of leveling effect on the and quality of the achieved coating films were used as an indicator
surface resistance of particle boards veneered with sheets from dif- for the powder coatability of the veneer: the coatability was judged
ferent wood species since all values of electrical resistance for the as being the better the less powder had to be applied in order to
veneered particle boards are in the order of magnitude of about achieve a defect-free, smooth surface film.

Fig. 2. Microscope photo: different layer thicknesses on powder coated walnut veneered particle boards.

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Fig. 3. Coating results of different coated veneered particle boards; (1). . .Maple; (2). . .Bamboo; (3). . .Beech; (4). . .Oak; (5). . .Walnut; (6). . .Wenge.

The coating experiments resulted in largely varying coating surfaces [31] were obtained, with gloss values around 65–75 gloss
thicknesses for each veneer type. Fig. 2 shows the example of pow- units.
der coated walnut veneered particle board with varying coating Polishing of the coated boards was done in an attempt to
thicknesses: “one-coat low” - where a powder amount of 106 g/m2 improve uniformity and increase surface gloss. It was, however,
was applied resulting in a coating thickness of 79 ␮m upon hot observed that due to the polishing process gloss was decreased
pressing, one coat with higher powder amount named “one-coat for all the surfaces treated. Instead, a soft-feel surface effect was
high” where 184 g/m2 powder was applied resulting in a final cured obtained.
coating thickness of 136 ␮m and a third case “2-coat”, where the Adhesion of the coating to the substrate was tested using the
application of a powder amount double as compared to “one-coat cross-cut method. In the coating thickness range investigated here
low” was intended. In the case of walnut the amount of powder that from 37–286 ␮m, adhesion was very good for all coating thick-
was electrostatically applied in the 2-coat system was of 270 g/m2 nesses and for all six veneer types.
and the coating thickness obtained was 186 ␮m.
Due to the powder coating process the veneer pores are filled
by the powder coating, reducing to a minimum the variation of the 4. Conclusion
surface texture parameter values, as smooth surfaces are obtained
after powder coating and curing for all veneer types. Powder coating was successfully carried out on veneered par-
In the case of the one-coat low system for oak, walnut and espe- ticle boards using six types of wood veneers: maple, bamboo,
cially wenge the finished surface was not completely homogenous beech, oak, walnut and wenge. Moisture content of the wood sub-
and smooth. The powder coating layer used in the one-coat-low strates could be tuned by varying relative humidity using a climate
system was, indeed, too thin and the larger pores of these veneers chamber. The substrates were tested to determine surface electri-
still appeared as small valleys in the coating surface. The results of cal resistance and moisture content at 25 ◦ C and varying relative
coating tests for the analyzed substrates as well as surface quality humidity conditions. It was found that electrical resistance val-
results such as gloss and adhesion are accumulated in Table 4. ues are influenced by moisture content and by wood type. As such,
Gloss values were influenced by the coating thickness. The two- the surface electrical resistance values are significantly higher for
coat tests resulted in coating thicknesses above 180–200 ␮m and maple, beech and walnut raw veneers, around 1011 , while for
a significantly reduced gloss for all six types of veneered particle bamboo, oak, wenge, as well as for the veneered particle boards the
boards. A foggy appearance was observed with all two-coat tests. values are around 1010 , indicating suitable substrates for electro-
The highest gloss (after press) was obtained with “one-coat static powder application. The limiting surface resistance of 1011 
high” systems that led to medium coating thickness in the range required for the successful powder-coating that was documented
100–140 ␮m, for all six veneer types (Fig. 3). Comparatively glossy in earlier studies performed on MDF substrates was found to apply

Please cite this article in press as: M. Badila, et al., Powder coating of veneered particle board surfaces by hot pressing, Prog. Org. Coat.
(2014), http://dx.doi.org/10.1016/j.porgcoat.2013.09.018
G Model
POC-3302; No. of Pages 7 ARTICLE IN PRESS
M. Badila et al. / Progress in Organic Coatings xxx (2014) xxx–xxx 7

also as good measure to predict the powder coatability of wood References


veneers.
The appealing glossy and mechanically resistant surfaces on [1] C. O’Carroll, European market update Proceedings of the European Laminates
Conference and Workshop, Berlin, Germany, April 19–22, 2004, pp. 1–12, P1.
wood veneers were created by melting and curing of the electro- [2] A. Kandelbauer, A. Teischinger, Eur. J. Wood Wood Prod. 68 (2) (2010) 179–187.
statically applied Drylac 530 transparent powder layer at 130 ◦ C [3] A. Kandelbauer, P. Petek, S. Medved, A. Pizzi, A. Teischinger, Eur. J. Wood Wood
and 8 minutes, in hot pressing. Veneer surface was thoroughly char- Prod. 68 (2010) 63–75.
[4] M. Badila, E. Dolezel-Horwath, E.M. Zikulnig-Rusch, T. Schmidt, A. Kandelbauer,
acterized by Alicona 3D microscopy. The different veneer types Eur. J. Wood Wood Prod. 70 (2012) 639–649.
showed different topography characteristics regarding roughness, [5] D. Kleber, R. Emmler, D. Krug, M. Mäbert, B. Brendler, F. Schäfer, Pulverlack-
porosity and absorbability that were reflected in the powder coat- direktbeschichtung auf Holzwerkstoffe, DFO Tag der Holzbeschichtung, Bad
Salzuflen, 2012.
ing results. Results show that glossy surfaces with gloss values [6] TIGER (2009), Tiger Coatings. Retrieved Sept. 1, 2009, from Tiger Coatings:
measured at 20◦ in the range 65–75 gloss units can be achieved http://www.tigercoatings
by powder coating of veneered particle board surfaces followed [7] M.C. Barbu, T.W. Schmidt, Holztechnologie 50 (1) (2006) 32.
[8] G. Wuzella, A.R. Mahendran, T. Bätge, C. Jocham, A. Kandelbauer, Holztechnolo-
by hot press curing. The optimum amount of powder specific for
gie 51 (4) (2010) 34–38.
each wood type in order to create glossy high quality surface [9] G. Wuzella, A.R. Mahendran, T. Bätge, C. Jocham, A. Kandelbauer, Holztechnolo-
was identified. Surface quality tests showed that optimal results gie 51 (5) (2010) 39–43.
were obtained with one coat and a coating thicknesses around [10] Solvents Emissions Directive, 1999/13/EC on the limitation of emissions of
volatile organic compounds (VOC) due to the use of organic solvents in certain
100–140 ␮m for all six veneer types. The approach used in the activities and installations (1999).
present study involved appropriate conditioning of the coating sub- [11] M. De Meijer, H. Militz, Holz als Roh-und Werkstoff 58 (2001) 467–475.
strate prior to the powder coating and hot pressing steps. This [12] M. De Meijer, H. Militz, Prog. Org. Coat. 38 (2000) 223–240.
[13] C. Jocham, J. Sinic, T.W. Schmidt, U. Müller, A. Kandelbauer, J. Adhes. Sci. Tech-
procedure seems industrially feasible to implement and similar nol. (2013), accepted.
approaches have been tested successfully already in the case of [14] G. Wuzella, A. Kandelbauer, A.R. Mahendran, A. Teischinger, Prog. Org. Coat. 70
MDF panel substrates. Although the surface finished panels pro- (2011) 186–191.
[15] D IN EN 61340-4-1 (2004): Electrostatics - Part 4-1: Standard test methods
duced in the present study were rather small test panels of size for specific applications - Electrical resistance of floor coverings and installed
320 × 280 mm, the described approach is, in principle, not limited floors (IEC 61340-4-1:2003); German version EN 61340-4-1:2004.
to any specific pressing format. The maximum pressing format with [16] D IN EN 322 (02/1993) Holzwerkstoffe - Bestimmung des Feuchtegehaltes.
[17] European Standard EN ISO 2409:2007, Paints and varnishes – Cross-cut test.
the laboratory scale press would be 550 × 450 mm and it should be [18] P. Niemz, Holz - Anatomie, chemie, physik, Physik des Holzes und der Holzw-
possible to apply the process also to panels on an industrial scale, erkstoffe, DRW-Verlag, Leinfelden-Echterdingen, 1993.
where a typical pressing format of 2800 × 1850 mm is used. [19] J.E. Marian, D.A. Stumbo, C.W. Maxey, Forest Prod. J. 12 (1958) 345–351.
[20] T.D. Faust, Forest Prod. J. 37 (6) (1987) 34–40.
By using three-dimensionally shaped tools during the hot press-
[21] K. Richter, W.C. Feist, M.T. Knabe, Forest Prod J. 45 (7/8) (1995) 91–97, Part 1.
ing step, composite materials of other geometries than flat surfaces [22] Q.P. Du, A. Geissen, D. Noack, Holz als Roh- und Werkstoff 49 (1991) 305–311.
can, in principle, be produced. In the case of the veneer coated par- [23] M. Bayer, Proceedings of the 6th European Wood-based Panels Symposium,
ticle boards described in the present study, however, one is limited Hannover, Germany, 2008, pp. 1.
[24] E. Uittenbrock, D. Ondratschek, Besser lackieren — Jahrbuch, Vincentz Network
to flat surface profiles since no complex geometries may be formed GmbH und Co., Hannover, Germany, 2008, pp. 510–521.
from this substrate geometry. The present study demonstrates that [25] C. Jocham, T.W. Schmidt, G. Wuzella, A. Teischinger, A. Kandelbauer, J. Adhes.
the solid wood-based materials like wood veneers can successfully Sci. Technol. 25 (2011) 1937–1946.
[26] H. Bauch, R. Emmler, D. Krug, I. Fuchs, Proceedings of the interior surface con-
be powder coated to yield surfaces of satisfactory property profile. ference 2007, Technical Conference Management, Vienna, Austria, 2007, pp.
It can be assumed, that similar surfaces based on plywood might as 159.
well be accessible to powder coating technology. Plywood-based [27] D IN EN 322: Wood-based panels – determination of moisture content
(1993–08).
materials could, to some extent, even be produced in geometri- [28] C. Jocham, U. Müller, C. Mayer, A. Blatter, T. Schwarz, T. Schmidt, P. Hauber, M.
cal shapes that deviate from plain flat surfaces. Using appropriate Himmelreich, A. Kandelbauer, Holztechnologie 54 (2) (2013) 43–48.
pressing tools, in principle, with such substrates, hence, even more [29] M. Dunky, P. Niemz, Holzwerkstoffe und Leime: Technologie und Einflussfak-
toren, Springer, Berlin Heidelberg, 2002.
complex three-dimensionally shaped materials could be surface [30] J. Zhang, C. You, Energy Fuels 27 (2013) 2643–2648.
finished by powder coats using the technology presented in this [31] A. Kandelbauer, H. Burger-Scheidlin, B. Hölbling, K. Fischer, Proceedings of
study. Consequently, future studies will focus on the process adap- the European Laminates Conference and Workshop, April–10 (2008), Vienna,
Austria, 2008, pp. 17–22, Paper 3.
tation of powder technology to plywood.

Please cite this article in press as: M. Badila, et al., Powder coating of veneered particle board surfaces by hot pressing, Prog. Org. Coat.
(2014), http://dx.doi.org/10.1016/j.porgcoat.2013.09.018

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