QUIZ II

Which of the following statements about resonance structures is not true?

Resonance structures are in equilibrium with each other
Resonance structures differ only in the arrangement of electrons.
There is no movement of electrons from one form to another
Resonance structures are not isomers

Identify the Lewis base in the following reaction.

Which reaction is slowest?

m
er as
co
eH w
o.
rs e A
ou urc
Which of the following statements is not true?
Carbanions are nucleophiles.
o

In polar reactions, a nucleophile reacts with an electrophile.

aC s

Carbocations are electrophiles.

vi y re

A half-headed curved arrow shows the movement of an electron pair

ed d

Which of the following statements explain why HBr is a stronger acid than HF?
ar stu

Br- is less stable than F- because Br- is less electronegative than F

Br- is less stable than F- because Br- is larger than F-.
Br- is more stable than F- because Br- is less electronegative than F-.
Br- is more stable than F- because Br- is larger than F
is
Th

What is the formal charge of the carbon in carbon dioxide (CO2) when drawn with two double bonds? 0
sh

Which of the following statements about Lewis bases is true?

Lewis bases are electron pair donors
Lewis bases are electron pair acceptors.
Lewis bases are proton donors.
Lewis bases are proton acceptors.

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 What kind of reaction does the conversion of A to B represent?

Substitution reaction
Addition reaction
Oxidation-reduction reaction
Elimination reaction

Which of the following statements about equilibrium is true?

Equilibrium favors the products when the energy of the products is higher than the energy of the
reactants.
Equilibrium favors the products when they are less stable than the starting material of a reaction.

m
er as
Equilibrium favors the products when they are more stable than the starting material of a reaction.
Equilibrium favors the reactants when the energy of the product is lower than the energy of the reactants

co
eH w
o.
What is the direction of equilibrium when acetylene (C2H2) reacts with ethoxide (CH3CH2O-) in an acid-base
reaction? rs e
ou urc
o
aC s

Cannot be determined
vi y re

Right
Neither
Left
ed d

In which of the following ions does carbon have a formal charge?

ar stu
is

II
Th

What is the nucleophilic site in the following compounds?

sh

I = Oxygen; II = carbon; III = nitrogen.

I = Oxygen; II = π electrons in bond; III = nitrogen
I = Hydrogen; II = carbon; III = carbon.
I = Hydrogen; II = π electrons in bond; III = nitrogen.

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 In which structure is the hybridization incorrect?

II

Which of the Keq corresponds to the highest value of DG°?

Keq = 10-3
Keq = 10-2
Keq = 10-5
Keq = 10-1

Which reaction is fast and has Keq = 1?

m
er as
co
eH w
o.
rs e
ou urc
B
o
aC s

Identify the compounds that can be deprotonated by −OH (pKa of water = 15.7).
vi y re
ed d
ar stu
is
Th
sh

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 Which of the following expressions summarizes the correct relationship between the free energy change, DG°,
and the equilibrium constant, Keq?
Keq > 1 when DG° > 0

m
er as
Keq > 1 when DG° < 0

co
Keq < 1 when DG° < 0

eH w
Keq < 1 when DG° = 0

o.
rs e
ou urc
Which of the following species is the conjugate base of the hydronium ion, H3O+?
H3O
o
aC s

HO-
vi y re

H2O
H2O-
ed d
ar stu

Consider the following energy diagram from the conversion of A → G. Which points on the graph correspond
to transition states?
is
Th
sh

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 Which is the conjugate acid in the following reaction?

III

m
er as
co
eH w
o.
rs e
ou urc
o
aC s
vi y re
ed d
ar stu
is
Th
sh

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