Professional Documents
Culture Documents
shihab@iittp.ac.in
1 1
Wastewater generation In India
• Wastewater generation in major cities - 38354 MLD
• Our municipal wastewater treatment capacity- 11786 (CPCB, 2009)
• more than 75% water bodies have contaminated due to discharge of untreated or
partially treated sewage into water bodies (CPHEEO, 2012)
Water Wastewater
availability Generation
2
Reduce
solids
Reduce
toxic Objectives Reduce
substanc of WWT BOD
es
Reduce
pathogen
s
• To meet regulatory limits that are protective of public health and the environment
3
Types of WW
• Infiltration and inflow: water that eventually enters the sewer foundation
drains, leaking pipes, groundwater infiltration, etc.
4
Source of images: Google images
Municipal wastewater composition
Municipal WW
Pathogenic
organisms
Typical contaminants in wastewater and their
Environmental impacts
• Suspended solids - sludge deposit, scum layer formation
• Biodegradable organics – dissolved oxygen depletion, anaerobic conditions,
affects aquatic life
• Pathogens- Transmission of diseases
• Nutrients – Eutrophication and impairment of water quality
• Refractory organics – may be toxic or carcinogenic
• Heavy metals – toxic to aquatic life
• Endocrine disrupting substance – Feminization of fish, and other possible impacts
Source of images: Google
images
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Endocrine disrupting compounds
Dioxin
PCBs
7
Source of images: Google images
Typical parameters involved in Sewage Analysis (
Adapted from Metcalf and Eddy, 2003
Total Suspended Solids (TSS) Portion of TS retained on filter paper with pore size
1.5 micrometers
10
Levels of wastewater treatment
• Preliminary treatment: Involves the physical removal of substances like rags,
plastic bags, sand particles, etc. – e.g. Screen, grit chamber, floatation unit
• Primary treatment: involves the physical removal of a portion of the SS from WW,
typically by sedimentation – e.g. primary clarifiers – Primary treatment often
includes preliminary as well as primary operations.
• Enhanced primary treatment: this involves addition of chemicals (coagulants) to
obtain additional solid removal in primary clarifiers.
• Conventional secondary treatment: this involves biological treatment for
degradation of organic matter – e.g. activated sludge process
• Secondary treatment with nutrients: secondary treatment with nutrient removal
(N, P)
• Tertiary treatment: this involves treatment process used after secondary
treatment- e.g. granular filtration media, chlorination
• Advanced treatment: Special treatment process used for toxic compounds that
warrant additional removal, or for potential water reuse application – e.g.
activated carbon adsorption for removal of VOC, ion exchange for removal of
specific ions
1 11
Biosolids removal
• The term bio-solids refers to treated sludge
• The sludge generated from primary and secondary clarifiers has a
significant amount of organic matter and requires treatment before
disposal
• The cost of the treatment is typically 40-50% of the WW treatment
• Objectives of sludge treatment : 1. to reduce the organic content; 2.
to reduce pathogens; 3. to reduce the liquid fraction – First two
objectives are achieved through digestion (aerobic, anaerobic),
composting, pasteurization, etc. – Third objective can be achieved
by gravity thickening , centrifugation, etc.
12
Typical process flow diagram of STP
or -Balancing
Grit tank
By-pass
Raw water
Screens Grit PST
Balancing
Chamber tank
Screenings
Land/Stream
Disposal
Recycle bio-solids
Drinking/other reuse Methane gas
bio-solids
Waste
Return flow
Solids for Centrifuge Sludge from
Sludge Thickener thickener
Land Disposal digester
Effluent
14
Onsite Vs centralised
15
Section of Appropriate Sewage Treatment Technology
– important criteria
• No dilution of high strength wastewater with clean water
• The technology must consistently meet the treated sewage
standards as required
• The power requirement should be minimum
• Technologies selected should be cost-effective (in construction,
operation, and maintenance) and environmentally sound
• Should have long life-time and are simple in operation and
maintenance.
• Should able to withstand organic and hydraulic load
fluctuations.
• Technology adopted should be acceptable for local population
• Land requirement should be minimum
• Maximum of recovery and re-use of treated water and by-
products obtained from the pollution substances. (i.e. irrigation,
fertilization)
• Should be self sufficient in all respect
1 16
Decision Matrix
Decision Matrix for Secondary Treatment Processes
Ease of
nEase of
Coliform
Nitrificat
Process
Electrica
Capacity
Operatio
Denitrifi
Phospho
Reliabili
Demand
Mainten
Recover
Effluent
removal
removal
Process
Typical
Quality
Energy
Record
Capital
Range,
cation
Track
MLD
Land
Cost
ance
rous
ion-
Use
ty
y
s
l
Activated Sludge Good Good Poor Poor Very Good Good Good Very Avg Avg Very All flows
Process Good Good Good
Aerated Lagoon Good Good Poor Poor Avg Poor Avg Avg Poor Poor Good Poor Smaller
Extended Aeration Very Good Poor Poor Very Avg Very Very Poor Poor Good Good Smaller
Good Good Good Good
Membrane Bio Very Very Good Poor Poor Good Very Poor Poor Poor Poor Poor Poor Smaller
Reactor Good Good
Moving Bed Bio Very Very Good Poor Poor Good Very Poor Avg Poor Avg Good Poor Smaller
Reactor Good Good
Sequencing Batch Very Very Good Very Very Good Good Very Good Good Poor Avg Avg Good All Flows
Reactor Good Good Good
1 20
Microbial metabolism
1 21
Growth kinetics
dX
X 1
dt
max S
Monods Model
Ks S
1 22
Enzyme reaction
ES
ES
( I ) n
EP
E P......(1)
E S
k2
ES
k3
E P......( 2)
dp dS
k3 [ ES ]
dt dt
Eo [ E ] [ ES ] Mass conservation principle
d ( ES )
k1[ E ][ S ] k 2 [ ES ] k3 [ ES ]
dt
0 k1[ E ][ S ] k 2 [ ES ] k3 [ ES ] Assume steady state condition
ES ( k 2 k3 ) k1[ E ][ S ]
( k 2 k3 ) [ E ][ S ]
k1 ES
[ E ][ S ] [ Eo ] [ ES ] [ S ]
km
ES ES
23
(k 2 k3 ) [ E ][ S ]
Enzymes are saturated with substarte
k1 ES d[S ]
k[ E ] Zero order
[ E ][ S ] [ Eo ] [ ES ][ S ]
dt
km
ES ES
E – constant ( eq-2)
[ Eo ] [ ES ][ S ]
-d[s]/dt
km
d[S ]
dt
k[ E ][ S ]
ES
k m [ ES ][ S ] [ ES ] [ E0 ][ S ] First order
[ E0 ][ S ] S, mg/L
ES
km [ S ] km Michaelis constant
d[S ]
k3 [ ES ]
dt
d[S ] [ E0 ][ S ]
k3
dt km [ S ]
d[S ] rmax [ S ]
k3
km [ S ]
When all enzymes are saturated
dt with substrate (E
24
Monod model
max S
μmax
Ks S
S K s S Ks
μ, 1/t
μmax/2
dX
dt
max S / Ks max / 2
S K s
dX KS S, mg/L
max X
dt
S - is the concentration of limiting food, mg/L
Ks= half saturation constant, mg/L- concentration of limiting food
when max / 2
1 25
Biomass growth and substrate utilization
dX max S
X
dt Ks S
Y = yield of biomass – fraction of food mass
converted to biomass
dX
Y dt dS max S
dS X
dt Y (K s S )
dt
1 26
Endogenous metabolism
dX
K d X
dt
rnet rg rd
dX max S
X kd X
dt net (K s S )
dX
dt net
Ynet
dS
dt
1 27
Activated sludge process (ASP)
• Demerits
• High energy consumption
• Skilled operators needed
• Uninterrupted power supply is required
• Requires elaborate sludge digestion, drying and disposal arrangement
• No energy production
• No nutrient removal
1 29
Design and operational parameters
• F/M ratio
BOD removed in the reactor
F/M
biomass in the reactor
F QS o S
M VX 1 30
• Volumetric loading rate ((kg/m3-d)
Q, Xo, So Qw, Xw
Q, X, S
Waste sludge
Assumption
1. Reactor is in steady state condition, accumulation = 0.0
2. Complete mixing is achieved
3. Concentration of biomass in the influent and effluent is negligible
0 QX o QX V dX / dt net
max S dX max S
Q /V kd net X kd X
(K s S ) dt (K s S )
1 max S
kd V/Q = HRT (θ)
(K s S )
1 max S VX/Q X= SRT (θc)
kd
c (K s S ) ASP with no recycle
SRT= HRT
1 max S Or
kd (1)
(K s S ) θ = θc
1 36
Mass balance for substarte around the system,
dS / dt V QS o QS V dS / dt
V max S
0 Q( S o S ) X
Y (K s S )
max S Y
( S o S ) (2)
( K s S ) X
Equating eqn. 1 and 2
1 Y
kd (S o S )
X
Y (S o S )
X
1 k d
1 37
• Expression for substrate S
max S Y
(K S )
X ( S o S )
s
max S Y (S o S ) 1
(K S )
Y (S S ) k d
s o
1 k d
max S 1
(K S ) kd
s
1
max S k d ( K s S )
K S 1 k d
S
( max k d ) 1 1 38
ASP (CSTR with recycle)
Primary
(Q+Qr), X, S Secondary
Effluent Effluent
Q, Xo, So
Aeration Tank
Secondary (Q-Qw), Xe, S
Clarifier
V, X, S
QR, Xu
Qu , X u
Qw, Xu, S
Waste sludge
Schematic of ASP with recycle
1 39
• Mass balance for biomass around the system,
1 41
• Mass balance for substrate S
dS / dt V QS o (Qe S Qw S ) V dS / dt su
0 QS o S (Qe Qw ) V dS / dt su
QS o S (Q ) V
dX / dt
.....................................Y
dX / dt
Y ds / dt
X
QS o S (Q ) V
Y
max S
Q( S0 S ) V X
Y ( K s S )
Y (S0 S ) Q max S
X V ( K s S )
Y (S0 S ) max S
( 4)
X (K s S )
Y (S0 S ) 1
kd
X
C
Equating eq. 3 and 4
Y ( S 0 S ) C
X
(1 k d C ) 1
• Expression for S
Y (S 0 S ) 1
kd
X C
Y (S 0 S ) 1
kd
Y ( S 0 S ) C C
(1 k d C )
K S 1 k d C
S
C ( max k d ) 1
43
Useful relationships
V X VX
HRT ..or.. ( A) MCRT ..or.. C ( B )
Qo X / t Qw X u
1 Y (S o S ) 1
k d (C )..or..
( C ) ( ) X ( C )
Y ( S 0 S ) C
X ( D )
(1 k d C )
HRT = hydraulic retention time
( C )QY ( S o S ) MCRT = mean-cell-residence time
V (E)
X 1 k d ( C ) X= mixed-liquor suspended solids
(MLSS) or simply biomass conc.
K S 1 k d C
S (F )
C ( max k d ) 1
1
Very important
V X VX
HRT MCRT
Qo X / t Qw X u
1 Y
(S o S ) k d 6
( MCRT ) ( HRT ) X
( MCRT )Y ( S o S ) m (S o S )
X 7
( HRT )1 k d ( MCRT ) 1 k d ( MCRT )
46
ASP – Empirical Design Parameters
• Volumetric loading rate or BOD loading rate, VL = QSo/V ( 0.4 -0.6 kg of
BOD5/ m3. d).
Note: Typical value of parameters for the conventional ASP are given in
parenthesis
1 47
• Why these parameters are important?
MCRT - effect efficiency of treatment, satiability of the
sludge, oxygen requirement, quantity of waste activated
sludge.
50
ASP – Oxygen requirements
The ultimate BOD for one mole of cell requires 1.42 moles of oxygen
Mass of O2/d = total mass of BODu used – 1.42 x mass of organism wasted
Q( So S )
kgO2 / day 1.42( Px)
1000 g / kg
Px = mass of the microorganism wasted
1 51
C s ,T , H C L T 20
AORT SORT
C s , 20
F
AOTR – actual oxygen transfer rate under filed condition, kgO2/h or
kgO2/kWh
SORT – standard oxygen transfer rate in clean water at 20 degree
Celsius and zero DO
β= salinity- surface tension correction factor (0.95-0.98)
Cs,T,H=oxygen transfer concentration in clean water at WW temperature
T, and diffuser dept H ( mg/L)
CL= DO conc. in wastewater (mg/L)
Cs,20=DO saturation conc. in clean water at 20 degree Celsius and 1
atm presuure ( 9.17 mg/L)
ϴ = temperature correction factor ( 1.024)
T = WW temp.
F = Fouling factor = 0.65 – 1
Α = oxygen transfer correction factor = 0.3 to 0.4
1 52
Diffused aeration system
1 53
1 54
ASP - Modifications
Refer Table 8-15: Description of activated sludge process for BOD removal ( Metcalf
and Eddy, 4 th edition)
1 55
CNV
HR-ASP EAS
Aerobic digestion
Aeration
Q Tank Second effluent
Primary ary
Clarifier clarifier
Q-Qw
QR
Oxygen utilization rate
Qw
Supply
Demand
inlet outlet
Advantage: Protect against hydraulic and organic shock load; toxicity materials are
diluted below their threshold conc. ; suitable for general application 57
Design Criteria
R 0.25 – 0.50
Dry solids, % 1
58
ASP (Plug flow reactor)
Primary
Effluent Secondary
Q, Xo, So S, X
Effluent
Aeration Tank (Q+Qr), X, Se
Qe, Xe, Se
Secondary
Clarifier
QR, Xu, Se
Qu, Xu, Se
Qw, Xu, Se
Second effluent
Primary Q ary
Aeration Tank
Clarifier clarifier
Q-Qw
Width = 6-10 m; length = 30 -100 m
QR
Demand
inlet
outlet
Drawback: high oxygen demand at the head of the tank; more susceptible upset for shock load
and toxic material; used for low strength wastewaters.
60
• The concentration of microorganism in the influent to the aeration
tank is approx. the same as that in the effluent from the aeration
tank. This holds true when SRT/HRT >=5 . The avg. concentration
of biomass is Xavg
• The rate of soluble substrate utilization as the wastewater passes
through the reactor is:
ds max SX avg
.rsu
dt Y ( K s S )
1 max S o S
kd
c S
So S K (1 R ) ln i
S
S o RS e
S i
1 R
R 0.25 – 0.50
BOD loading rate
62
• Tapered Aeration ( Plug flow)
45% - first third
30% - next third
25% - last third
Second effluent
Primary Q ary
Aeration Tank
Clarifier clarifier
Q-Qw
QR
Qw
Oxygen rate
R 0.25 – 0.50
64
• Extended aeration
Aeration
Primary Q Second effluent
Tank
Clarifier ary
clarifier
( optional) Q-Qw
QR
Qw
inlet outlet
65
Oxidation ditch – first extended aeration system
Oxidation ditch
Sludge pump A B
Mixed liquid
feed
SST
Returned Depth 1- 3.5 m
Sludge
66
Design Criteria
HRT, hours 18 - 24
R 0.75 – 1.5
67
Contact stabilization process
Compared to conventional activated sludge process, oxygen requirement are lower but
waste sludge quantities are higher
68
Design Criteria
R 0.25 – 1.0
69
• Step-Feed Aeration ( Alternate configuration)
Primary Q
Aeration Tank
Clarifier
effluent
Second
ary
clarifier
Q-Qw
recirculation QR
Qw
1 71
• High rate ASP (CM)
Aeration
Q Tank Second effluent
Primary ary
Clarifier clarifier
Q-Qw
QR
Oxygen utilization rate
Qw
Supply
Demand
inlet outlet
Partial treatment for medium to strong waste – widely used in food and dairy industry 72
Design Criteria
High rate ASP
R 1.0 – 5.0
73
• Pure oxygen ASP (CM)
Pure Oxygen ASP Aeration basins are covered to avoid
escape of oxygen
SRT or MCRT, days 8 - 20 Supplement mixing is done to keep
the MLSS in suspension
F/M (kg BOD5/kg MLSS) 0.2 – 1.0 Some provision should be done for
the escape of CO2
VLR (kg BOD5/m3.d) 1.6 – 4 Buffering may be required with
alkaline agents
HRT, hours 1-3
R 0.25 – 0.5
1 74
Kraus process
Primary Secondary effluent
Aeration tank
Clarifier clarifier
(optional)
aeration
tank
supernatant
Anaerobic
digester
1 75