Safety Data Sheet

according to 29CFR1910/1200 and GHS Rev. 3

Effective date : 10.24.2014 Page 1 of 7
Vinegar

SECTION 1 : Identification of the substance/mixture and of the supplier

Product name : Vinegar
Manufacturer/Supplier Trade name:
Manufacturer/Supplier Article number: S25623
Recommended uses of the product and restrictions on use:
Manufacturer Details:
AquaPhoenix Scientific, Inc
9 Barnhart Drive, Hanover, PA 17331
(717) 632-1291
Supplier Details:
Fisher Science Education
6771 Silver Crest Road, Nazareth, PA 18064
(724)517-1954
Emergency telephone number:
Fisher Science Education Emergency Telephone No.: 800-535-5053

SECTION 2 : Hazards identification

Classification of the substance or mixture:

Irritant
Skin irritation, category 2
Eye irritation, category 2A

Skin Irritation 2
Eye Irritation 2

Signal word :Warning

Hazard statements:
Causes skin irritation
Causes serious eye irritation
Precautionary statements:
If medical advice is needed, have product container or label at hand
Keep out of reach of children
Read label before use
Do not eat, drink or smoke when using this product
Wear protective gloves/protective clothing/eye protection/face protection
Wash skin thoroughly after handling
Take off contaminated clothing and wash before reuse
IF ON SKIN: Wash with soap and water
If skin irritation occurs: Get medical advice/attention
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do –
continue rinsing
If eye irritation persists get medical advice/attention
Specific treatment (see supplemental first aid instructions on this label)

Flammability:
The mixture is being classified on the basis of the classification of the flammable ingredient at or equal to 50%

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 Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 10.24.2014 Page 2 of 7
Vinegar

.(Source: CRC Handbook of Chemistry and Physics, 63rd Edition)

Other Non-GHS Classification:

WHMIS

B3 E

NFPA/HMIS

NFPA SCALE (0-4) HMIS RATINGS (0-4)

SECTION 3 : Composition/information on ingredients

Ingredients:

CAS 64-19-7 Acetic Acid 5%

CAS 7732-18-5 Deionized Water 95 %

Percentages are by weight

SECTION 4 : First aid measures

Description of first aid measures
After inhalation: Move exposed individual to fresh air. Loosen clothing as necessary and position individual in
a comfortable position.Seek medical advice if discomfort or irritation persists.Give artificial respiration if
necessary. If breathing persists give oxygen.
After skin contact: Wash affected area with soap and water. Rinse thoroughly. Seek medical attention if
irritation, discomfort or vomiting persists.Flush with water for 15 minutes.
After eye contact: Protect unexposed eye. Rinse/flush exposed eye(s) gently using water for 15-20 minutes.
Remove contact lens(es) if able to do so during rinsing. Immediately get medical assistance if irritation persists
or if concerned.
After swallowing: Rinse mouth thoroughly. Do not induce vomiting. Have exposed individual drink sips of
water. Seek medical attention if irritation, discomfort or vomiting persists.

Most important symptoms and effects, both acute and delayed:

Irritation, Nausea,Headache, Shortness of breath.;
Indication of any immediate medical attention and special treatment needed:
If seeking medical attention, provide SDS document to physician.Notes to Physician: Treat symptomatically.

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 Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 10.24.2014 Page 3 of 7
Vinegar

SECTION 5 : Firefighting measures

Extinguishing media
Suitable extinguishing agents: If in laboratory setting, follow laboratory fire suppression procedures. Use
appropriate fire suppression agents for adjacent combustible materials or sources of ignition
For safety reasons unsuitable extinguishing agents:
Special hazards arising from the substance or mixture:
Combustion products may include carbon oxides or other toxic vapors.
Advice for firefighters:
Protective equipment:
Additional information (precautions): Move product containers away from fire or keep cool with water
spray as a protective measure, where feasible.

SECTION 6 : Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Wear protective equipment. Avoid contact with skin, eyes and clothing.Remove from all sources of ignition.Use
respiratory protective device against the effects of fumes/dust/aerosol. Keep unprotected persons away. Ensure
adequate ventilation.Keep away from ignition sources. Protect from heat.Stop the spill, if possible. Contain
spilled material by diking or using inert absorbent. Transfer to a disposal or recovery container.
Environmental precautions:
Prevent from reaching drains, sewer or waterway. Collect contaminated soil for characterization per Section 13
Methods and material for containment and cleaning up:
If in a laboratory setting, follow Chemical Hygiene Plan procedures.Collect liquids using vacuum or by use of
absorbents. Place into properly labeled containers for recovery or disposal. If necessary, use trained response
staff/contractor.Remove from all sources of ignition.Soak with inert material.Use spark-proof tools and
explosion-proof equipment.Always obey local regulations.
Reference to other sections:

SECTION 7 : Handling and storage

Precautions for safe handling:
Prevent formation of aerosols. Follow good hygiene procedures when handling chemical materials. Do not eat,
drink, smoke, or use personal products when handling chemical substances. If in a laboratory setting, follow
Chemical Hygiene Plan.Use only in well ventilated areas.Avoid splashes or spray in enclosed areas.Wash hands
after handling.Avoid contact with skin and eyes.
Conditions for safe storage, including any incompatibilities:
Store in a cool location. Provide ventilation for containers. Avoid storage near extreme heat, ignition sources or
open flame. Store away from foodstuffs. Store away from oxidizing agents.Store in cool, dry conditions in well
sealed containers. Keep container tightly sealed.Protect from freezing.

SECTION 8 : Exposure controls/personal protection

Control Parameters: 64-19-7, Acetic Acid, ACGIH TLV: 25mg/m3, OSHA PEL: 25mg/m3

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 Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 10.24.2014 Page 4 of 7
Vinegar

Appropriate Engineering controls: Emergency eye wash fountains and safety showers should be available in
the immediate vicinity of use/handling.Provide exhaust ventilation or
other engineering controls to keep the airborne concentrations of vapor
or mists below the applicable workplace exposure limits (Occupational
Exposure Limits-OELs) indicated above.
Respiratory protection: Not required under normal conditions of use. Use suitable respiratory
protective device when high concentrations are present. Use suitable
respiratory protective device when aerosol or mist is formed. For spills,
respiratory protection may be advisable.
Protection of skin: The glove material has to be impermeable and resistant to the product/
the substance/ the preparation being used/handled.Selection of the glove
material on consideration of the penetration times, rates of diffusion and
the degradation.
Eye protection: Safety glasses with side shields or goggles.
General hygienic measures: The usual precautionary measures are to be adhered to when handling
chemicals. Keep away from food, beverages and feed sources.
Immediately remove all soiled and contaminated clothing. Wash hands
before breaks and at the end of work. Do not inhale
gases/fumes/dust/mist/vapor/aerosols. Avoid contact with the eyes and
skin.

SECTION 9 : Physical and chemical properties

Appearance (physical Explosion limit lower: 0 Vol %

Clear, colorless liquid
state,color): Explosion limit upper: 0 Vol %

2.3 kPa (@ 20°C) or 23 hPa (17

Odor: Vinegar-like Vapor pressure:
mm Hg) at 20 °C (68 °F)

Odor threshold: Not determined Vapor density: 0.62 (Air = 1)

pH-value: Not determined Relative density: 1 (Water = 1)

Melting/Freezing point: 0 °C (32 °F) Solubilities: Soluble in Water

Boiling point/Boiling Partition coefficient (n-

100°C (212°F) Not determined
range: octanol/water):

Flash point (closed Auto/Self-ignition

Not applicable Not determined
cup): temperature:

Decomposition
Evaporation rate: Not determined Not determined
temperature:

a. Kinematic:Not determined
Flammability
Not applicable Viscosity: b. Dynamic: 0.952 mPas at 20
(solid,gaseous):
°C (68 °F)

Density: 1 g/cm³ (8.345 lbs/gal) at 20 °C (68 °F)

SECTION 10 : Stability and reactivity

Reactivity:
Chemical stability:No decomposition if used and stored according to specifications.
Possible hazardous reactions:
Conditions to avoid:Store away from oxidizing agents, strong acids or bases.
Incompatible materials:Strong acids.Strong bases.Oxidizers. Metals

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 Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 10.24.2014 Page 5 of 7
Vinegar

Hazardous decomposition products:Carbon oxides (CO, CO2).Irritating fumes

SECTION 11 : Toxicological information

Acute Toxicity:

Oral: LD50 orl-rat: 3310 mg/kg (Acetic Acid)

LC50 inhalation-rat: 5620 ppm/ 1hr. (Acetic

Dermal:
Acid)

Chronic Toxicity: No additional information.

Corrosion Irritation:

Dermal: Section 2 Classified as a skin irritant

Ocular: Section 2 Classified as an eye irritant

Sensitization: No additional information.

Single Target Organ (STOT): No additional information.

Numerical Measures: No additional information.

Carcinogenicity: No additional information.

Mutagenicity: No additional information.

Reproductive Toxicity: No additional information.

SECTION 12 : Ecological information

Ecotoxicity
Ecotoxicity: Acetic Acid has high biochemical oxygen demand, and a potential to cause oxygen depletion in
aquatic systems.
Persistence and degradability: Readily degradable in the environment.
Bioaccumulative potential:
Mobility in soil: Aqueous solution has high mobility in soil.
Other adverse effects:

SECTION 13 : Disposal considerations

Waste disposal recommendations:

Product/containers must not be disposed together with household garbage. Do not allow product to reach
sewage system or open water.It is the responsibility of the waste generator to properly characterize all waste
materials according to applicable regulatory entities (US 40CFR262.11). Consult federal state/ provincial and
local regulations regarding the proper disposal of waste material that may incorporate some amount of this
product.Classify as a hazardous waste.

SECTION 14 : Transport information

UN-Number
UN2790
UN proper shipping name

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 Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 10.24.2014 Page 6 of 7
Vinegar

Acetic Acid Solution

Transport hazard class(es)
Class:
8 Corrosive substances
Packing group:III
Environmental hazard:
Transport in bulk:
Special precautions for user:

SECTION 15 : Regulatory information

United States (USA)

SARA Section 311/312 (Specific toxic chemical listings):
Acute
SARA Section 313 (Specific toxic chemical listings):
None of the ingredients is listed
RCRA (hazardous waste code):
None of the ingredients is listed
TSCA (Toxic Substances Control Act):
All ingredients are listed.
CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act):
64-19-7 Acetic Acid 5000 lb

Proposition 65 (California):

Chemicals known to cause cancer:

None of the ingredients is listed
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed
Chemicals known to cause developmental toxicity:
None of the ingredients is listed

Canada

Canadian Domestic Substances List (DSL):

All ingredients are listed.
Canadian NPRI Ingredient Disclosure list (limit 0.1%):
None of the ingredients is listed
Canadian NPRI Ingredient Disclosure list (limit 1%):
None of the ingredients is listed

SECTION 16 : Other information

This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the
SDS contains all the information required by the Controlled Products Regulations.Note:. The responsibility to

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 Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 10.24.2014 Page 7 of 7
Vinegar

provide a safe workplace remains with the user.The user should consider the health hazards and safety information
contained herein as a guide and should take those precautions required in an individual operation to instruct
employees and develop work practice procedures for a safe work environment.The information contained herein is,
to the best of our knowledge and belief, accurate.However, since the conditions of handling and use are beyond
our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this
material.It is the responsibility of the user to comply with all applicable laws and regulations applicable to this
material.
GHS Full Text Phrases:

Abbreviations and acronyms:

IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
CFR: Code of Federal Regulations (USA)
SARA: Superfund Amendments and Reauthorization Act (USA)
RCRA: Resource Conservation and Recovery Act (USA)
TSCA: Toxic Substances Control Act (USA)
NPRI: National Pollutant Release Inventory (Canada)
DOT: US Department of Transportation

Effective date : 10.24.2014

Last updated : 05.27.2015

Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com