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∂Ψ p2 Ψ
ih̄ = +VΨ
∂t 2m
where h̄, k, and m are constants and
∂
p = −ih̄ (momentum operator)
∂x
1
V = kx2 (potential energy operator)
2
1
x is self adjoint because, for f, g ∈ D(x) ⊂ L2 (R),
∫
⟨xf, g⟩ = xf (x)g(x)dx
∫
= f (x)xg(x)dx
= ⟨f, xg⟩.
Then a+ and a− are adjoints of each other. Using the fact that [x, p] = ih̄,
it is straightforward to show that
[a− , a+ ] = 1 (1)
h̄ω
H= (2a+ a− + 1) (2)
2
[H, a+ ] = h̄ωa+
2
Proof: Use the raising and lowering operators. See the last page of this
document or [3], page 594.
so E0 = h̄ω
2
. An eigenfunction with eigenvalue En = (n + 12 )h̄ω is given by
a+ ψ0 (if a+ ψ0 ̸= 0). Let ψn be a corresponding normalized eigenfunction
n n
so
Cn+1 = (n + 1)−1/2 .
It follows that √
a+ ψn = n + 1ψn+1 . (4)
Similarly, √
a− ψn = nψn−1 . (5)
3
Therefore
1
ψn = √ an+ ψ0 . (6)
n!
This is sufficient for computing expectation values of powers of x and p
of the eigenfunctions because
√
h̄
x= (a+ + a− )
√2mω
h̄mω
p=i (a+ − a− )
2
For example, since eigenfunctions of a self-adjoint operator corresponding
to different eigenvalues are orthogonal and [a− , a+ ] = 1, the expectation value
of x2 on the state ψn is given by
( )
h̄
⟨ψn , x ψn ⟩ = ⟨ψn ,
2
(a+ + a− )(a+ + a− )ψn ⟩
2mω
h̄
= ⟨ψn , (a2+ + a2− + a+ a− + a− a+ )ψn ⟩
2mω
h̄
= ⟨ψn , (a2+ + a2− + a+ a− + (a+ a− − a+ a− ) + a− a+ )ψn ⟩
2mω
h̄
= ⟨ψn , (a2+ + a2− + 2a+ a− + 1)ψn ⟩
2mω
h̄
= ⟨ψn , (2n + 1)ψn ⟩
2mω
h̄
= (2n + 1)
2mω
ψ0 (y) = N0 e−y
2 /2
.
i.e.
ψ0 (x) = N0 e−α
2 x2 /2
.
4
By (6),
( )1/2
α
e−α
2 x2 /2
ψn (x) = √ n Hn (αx)
π2 n!
where Hn is the Hermite polynomial of order n. By separation of variables,
Since the position distribution |Ψn |2 doesn’t depend on time, these are called
stationary states.
References
[1] Agnolet, G. Physics 412 Lecture Notes.
5
Proof of Lemma 1: As derived earlier,
[a− , a+ ] = 1 (7)
h̄ω
H= (2a+ a− + 1) (8)
2
[H, a+ ] = h̄ωa+
By (7), a− a+ = a+ a− + 1, so
⟨aj+1
− ψ, a− ψ⟩ = ⟨a+ a− (a− ψ), a− ψ⟩
j+1 j j
i.e.
∥aj+1
− ψ∥
2
Ẽ − j = ≥0 (11)
∥aj− ψ∥2
− ψ = 0. By (11), Ẽ −n = 0.
for all j. Thus ∃n ∈ N such that an− ψ ̸= 0 but an+1
By (9), ( )
1
E = h̄ω n + for some n ∈ {0, 1, 2, 3, ...}.
2