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Managing operational risks along the oil supply chain


Roberto Cigolini a; Tommaso Rossi b
a
Department of Management, Economics and Industrial Engineering, Politecnico di Milano, Milan,
Italy b Institute of Technology, Università Carlo Cattaneo - LIUC, Castellanza, VA, Italy

First published on: 11 March 2010

To cite this Article Cigolini, Roberto and Rossi, Tommaso(2010) 'Managing operational risks along the oil supply chain',
Production Planning & Control,, First published on: 11 March 2010 (iFirst)
To link to this Article: DOI: 10.1080/09537280903453695
URL: http://dx.doi.org/10.1080/09537280903453695

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Production Planning & Control
2010, 1–16, iFirst

Managing operational risks along the oil supply chain


Roberto Cigolinia* and Tommaso Rossib
a
Department of Management, Economics and Industrial Engineering, Politecnico di Milano, Milan, Italy;
b
Institute of Technology, Università Carlo Cattaneo – LIUC, Castellanza, VA, Italy
(Received 8 September 2008; final version received 20 October 2009)

Operational risk in the oil industry may lead to environmental disasters and to heavy loss of human lives.
However, the relationship between operational risk and oil supply chain management is poorly studied. This
article proposes a model (derived from the Eni’s supply chain) to analyse and to assess the operational risk at the
drilling, primary transport and refining stage of the oil supply chain. For the drilling stage, the model suggests
three sub-methods, one for each period of the plant life cycle (design, construction and production). For the
primary transport stage, two different risk management processes are proposed: the former one allows the risks
resulting from processes, procedures and physical components (other than oil-pipelines) to be identified, assessed
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and controlled, whereas the latter one allows risks arising from the pipeline breakdowns to be faced. Finally, for
the refining stage, a preliminary phase is recommended to prioritise each equipment of the refinery, and several
techniques and tools are suggested.
Keywords: supply chain; operational risk; oil industry

1. Introduction significant efficiency losses (Blackhurst et al. 2005)


In the recent years, supply chain risk has become a and, ultimately, to unpredictably high costs (Riddalls
major research subject, pushed to the fore by the and Bennett 2002). A company studied by Rice and
impacts on logistic networks of various events (Peck Caniato (2003) projected an increased cost by $ 50–100
2004): 11 September, war in the Middle East, millen- million per day due to supply network disruptions.
nium bug, bovine spongiform encephalopathy (BSE) Radjou (2002) stated that (in 1996) General Motors
outbreak, etc., have urged both academicians and did not receive components from a brake supplier
practitioners to investigate supply chain vulnerability, factory for 18 days, which idled workers at 26 assembly
and to assess risks in logistic networks. plants and the estimated reduction in quarterly earn-
Supply chain vulnerability is due to the supply ings was around $0.9 billion. Boeing (in 1997) experi-
chain nature (Chapman et al. 2002, Rice and Caniato enced supplier delivery failure of two critical parts,
2003). Dynamic networks of interconnected firms and which caused an estimated loss of $2.6 billion.
In the oil industry, operational risk is ‘bull-
industries – driven towards efficiency over the last
whipped’, in which it goes beyond the classical
decades – are more and more reliant on efficient and
effectiveness and efficiency reduction of either a
reliable production, transport and communications.
single firm or a group of production plants.
So, in addition to terrorist attacks, natural disasters
Operational risk may lead to environmental disasters
and/or industrial disputes, day-by-day (operational) and heavy loss of human lives: in the Mediterranean
risks may result in disruptions of the logistic network sea, on 10 April 1991 the Moby-Prince ferry rammed
operations (Tapiero and Grando 2006). According to the Agip-Abruzzo motor vessel causing 140 deaths and
Tapiero (2004), supply chain operational risks can be 25,000 tons of oil was poured into the sea. One day
defined as the risks connected to the daily disturbances later, a blaze on board the Haven oil-tanker resulted in
that materials and information flows can suffer from. 6 deaths and 50,000 tons of oil was poured, and 17
Such disturbances can be either internal (failures in years later the environment reclamation operations are
operations and service management) or external (an still in progress. In Texas City (TX), on 25 March 2005
uncontrollable event the supply chain is not ready for). an explosion within the refining plant of the British
In the end, operational risks lead to the supply group BP (the third refining plant in the US) killed 15
chain inability to satisfy customers’ needs as well as to people and caused serious environmental damage to

*Corresponding author. Email: roberto.cigolini@polimi.it

ISSN 0953–7287 print/ISSN 1366–5871 online


ß 2010 Taylor & Francis
DOI: 10.1080/09537280903453695
http://www.informaworld.com
2 R. Cigolini and T. Rossi

the surrounding area. In Lagos (Nigeria), on 26 transport from offshore fields to oil tankers and from
December 2006 a damaged oil-pipeline was burst: the onshore fields to oil-pipelines.
shock-wave caused the fire of the neighbouring houses The primary transport stage refers to the oil
and the International Red Cross counted 269 deaths. transfer to refining plants and it involves – depending
Indeed, several authors state that the relationship on the oil field – either pipelines only or pipelines and
between operational risk and oil supply chain man- tankers. As a matter of fact, the global oil transport
agement requires further investigation (Brandsaeter system also involves either continent crossing pipelines
2002, Cigolini et al. 2004, Dey et al. 2004, Cigolini and or super tankers and, since oil is often used far from
Rossi 2006, Proth 2007). the extraction place, several combinations of transport
This article proposes a model to analyse and to means can be used along the way. However, the
assess the operational risk within the oil supply chain. primary transport activity ends when the crude oil is
The model has been derived by the Eni’s (see within the refining area and the responsibility of the
www.eni.it) supply chain and it is based on an active refining stage starts.
involvement of the Exploration & Production division Refining is devoted to transform crude oil into
and of the Refining & Marketing division, which are, finished products and it can be summarised as follows:
respectively, responsible for identifying and exploiting after the removal of salts and other impurities, crude
oil-fields and for transporting and refining crude oil. oil is fractioned via primary distillation; then finished
The methodologies applied here refer to the case products quality and mix is improved through the
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study research and the action research (Westbrook reduction of the average molecular weight, the
1995, Yin 2003). The case study methodology allowed upgrading, the blending and the finishing activities
to understand the oil supply chain, its peculiarities and (Castellano and Cigolini 2002, Nguyen et al. 2005).
problems by means of inspections to drilling and Each of the three above-mentioned oil supply chain
refining plants as well to oil-pipelines and interviews. stages is plagued by different operational risks
The action research methodology allowed to build the (Brandsaeter 2002, Khan et al. 2002, Novelli 2004,
model through team-working with people responsible Ross 2004, Nguyen et al. 2005), as outlined in Table 1.
for the risk management process at each stage of the oil Regardless of the differences among the stages of the oil
supply chain. The action research has been performed supply chain in terms of operational risks, processes,
through a recurrent approach involving critical reflec- plants and safety equipments, no specific risk manage-
tion (at the beginning, on the current risk management ment approach has been conceived for the drilling,
process, and then, on the modified risk management primary transport and refining stage, respectively.
process) and action (changes to iteratively improve Oil industry adopts a traditional undifferentiated
how to manage risks at each stage of the oil supply risk management approach (Culp 2001, Omole et al.
chain). 2004; see also Figure 1) that can be divided into three
This article is arranged as follows: Section 2 main consecutive phases so that the output of each
presents the background; Section 3 illustrates phase is the input of the following one: (i) risk analysis,
approaches and tools to assess the operational risks made up from the definition of the system’s bounds as
along the oil supply chain; and finally, Section 4 well of the incidents it can suffer from and risky events
provides some concluding remarks and future research identification; (ii) risk assessment, in terms of the
paths. frequency of each event previously identified and of the
severity of its consequences and (iii) risk control, where
appropriate procedures to manage risk are selected.
2. Background
The oil supply chain can be divided into three main
stages: drilling, primary transport and refining. 2.2. Risk analysis
Within the risk analysis, risk identification can be
performed by means of either forward or backward or
2.1. The risks along the oil supply chain even hybrid techniques (Vesely et al. 1981, Crawley et
In the drilling stage the activities that follow the al. 2000, Clifton and Ericson 2005). In particular, the
exploration (new oil fields identification) take place; most popular forward techniques in the oil industry
these activities deal with (Nguyen 1996): (i) oil and are: (i) the hazard checklist, which consists of the plant
natural gas extraction from onshore and offshore analysis to verify if risky events identified in previous
fields; (ii) oil and gas leaching (with water and sand) risk analyses or in similar plants can occur (Lees 1996);
and elimination of any unwanted materials; and (iii) oil (ii) the Events Tree Analysis (ETA) that allows to
Production Planning & Control 3

Table 1. Taxonomy of the main operational risks at the different stages of the oil supply chain.

Drilling stage Primary transport stage Refining stage

Risk 1: Pouring and outflows of crude Risk 1: Collisions between tankers and Risk 1: Process blazes (flash-fire,
oil which can result in serious other ships, and between tankers jet-fire, fireball, tank-fire)
damages (spill or blowout) and docks, coastal terminals, rocks
Risk 2: Leaks from the tubing that Risk 2: Blazes and explosions on board Risk 2: Refining plant (or components)
links the field to the oil-pipeline tankers explosion (distillation column,
heat-cracking and catalytic cracking
equipments) due to the status
modifications of treated elements
Risk 3: Tubing and/or casing corrosion Risk 3: Oil-pipelines damages Risk 3: Fast combustions which can
result in high pressures and boiling
liquid expanding vapour explosion
(the so-called Bleve)
Risk 4: Erosion or malfunctioning of Risk 4: Outflow of process and
plant components (motors, gears, auxiliary elements (hydrofluoric
mud circuit, safety and lifting acid, sulphured hydrogen, sulphur-
equipments) and of the auxiliary ous anhydride, ozone)
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plants to treat mud and oil


Risk 5: Blazes and explosions of oil
and other elements not directly
connected to the drilling process

System bounds
Start
identification

Critical events
identification
identification

Risky events
Risk analysis identification

Risk Risk
control assessment Valuation of risky events
End
likelihood and
likelihood impact
and impact

Give the users


Appropriate No Is the risk Yes
notice of the
procedures acceptable ?
residual risk

Figure 1. The risk management process.

determine the damages a potential risky event can With reference to the backward-oriented
result in, due to the safety equipment and procedures approaches, the most common technique is the
which the plant is characterised by. Faults Tree Analysis (FTA), which allows to identify
Figure 2 outlines an events tree referring to an risks by linking the final events (damages) to the risky
unstoppable oil leak, which is a typical risky event of events through logical connectors.
the refining stage. By means of the risky event Figure 3 outlines a faults tree of a furnace of a
frequency (and of the middle events), ETA allows the refinery vacuum plant: the considered damage (usually
damages occurrence probability to be estimated. In this called top-event) is a too high furnace temperature.
way the first step of the risk assessment phase can be Also the hazard review belongs to the backward
anticipated. techniques category – it consists in a qualitative
4 R. Cigolini and T. Rossi

Legend Yes Water Yes Jet/pool-fire


Bleve: instantaneous outflow of expanding cooling not
vapour or boiling liquid, which causes an Impact on 25% 2% + Bleve
available
explosion caulked
Pool-fire: blaze of an oil pool sphere No 98%
Jet-fire: blaze of a high-speed gas or vapour jet
Flash-fire: blaze of a low speed Yes 2% No 75%
outflow of gas or vapour Water not
Jet/pool-fire
available No 98%
Yes 5%
Yes Water Yes Flash-fire +
Instantaneous cooling not jet/pool-fire
burning Impact on 25% 2%
available + Bleve
caulked
No 95% No 98%
sphere
Unstoppable Yes 2% No 75%
oil leak Water not Flash-fire +
available No 98% jet/pool-fire
Yes 30%
Delayed
Dispersion
burning No 70%
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Figure 2. Events tree example.

Too high furnace


temperature

And

Ineffective temperature High furnace Ineffective furnace


control equipment temperature stop equipment

Or Or

Temperature Temperature Alarm Ineffective Safety Ineffective


sensors out threshold out of operators equipment stop
of order incorrect order intervention out of order actions

Figure 3. Faults tree example.

check of the plant to define, on the basis of the an element of the primary transport system is outlined
reviewer’s experience and personal judgement, the risks in Table 2. The considered node is given by the booster
it can suffer from. pumps of an oil-pipeline and the main process
Finally, the most popular techniques in the oil parameters for which a deviation from the standard
industry are the hybrid ones: the Hazard and values can occur are ‘flow’ and ‘containment’, while the
Operability (HazOp) study, the procedural HazOp possible deviations, expressed by couples of keywords
and the emergency systems survivability analysis. and process parameters are: no-flow, reverse-flow and
HazOp consists in verifying, in a systematic way, the loss-of-containment.
plant and its design to detect causes and effects of
the deviations from the plant normal operating. The
procedural HazOp is the HazOp applied to critical
systems from the safety point of view (drilling plant, 2.3. Risk assessment
lifting equipments and mud circuit). The third technique The risk assessment is performed (for each previously
allows to identify the ability of an emergency system to identified risky event) by estimating the magnitude of
resist incident statuses. An example of HazOp study for the corresponding damages and the damages
Production Planning & Control 5

Table 2. Example of HazOp analysis assuming the booster pumps as HazOp node.

Protections and/or
# Deviation Causes Consequences indications Recommendation

1 No-Flow Closed valves on the Lines overpressure and Valves on the delivery Inhibit the booster
delivery lines pumps overheating lines provided with pumps start or, during
limit blocks. Operator the use, stop pumps
always present when when the delivery lines
pumps start. Lines are intercepted
designed to resist
booster pumps shut
off pressure
2 No-Flow Valves on the delivery Closed valves condition Install limit blocks and
lines not provided not detected alarms on the valves
with limit blocks
3 Reverse-Flow Valves not closed Due to gravity, the Operational procedures Install limit blocks and
when needed; liquid flows from the to open & close valves alarms on the transfer
the two cisterns higher level cistern to before and after the lines (between cisterns
become connected the lower level cistern product transfer and booster pumps)
with product
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contamination
4 Loss-of- Booster pumps seal Oil or gasoline leaks Install booster pumps
Containment damaged or (which can result in provided with a
broken blazes) double seal

occurrence probability (or frequency) on condition both actions (maintenance activities, safety equipments
that the risky event occurs, so that the risk is measured and operators training) and financial tools (insurance
as the product between magnitude and probability. and not insurance transfers).
The two most popular approaches to estimate the Actions, which represent the so-called technologi-
frequency in the oil industry are based on historical cal instruments, aim at reducing risks according to a
data and qualitative judgements: historical time-series prevention or an avoidance approach. An oil company
can be obtained from ad hoc plant-related or can decide to completely eliminate a risk by harvesting
sector-related databases, while qualitative judgements the business activities or (more often) the geographical
of experts can be converted into synthetic values of areas where the risk can rise from.
probability occurrence by means of linguistic variables The financial tools aim at reducing risks according
and corresponding fuzzy sets (see, among others, to a protection approach. An effective risk analysis and
Cigolini and Rossi (2007)). risk assessment activity is very important since insur-
The magnitude estimation can be performed by ance companies are more and more reluctant to ensure
means of (Molak 1997): (i) plant-related or full cover when dealing with oil plants (Pizzurno and
industry-related databases that report the damages Rossi 2007). The not insurance transfer allows the oil
occurred in the past to the considered plant or to company to transfer risks to companies different from
similar ones; (ii) experts’ judgements to be converted insurance companies and it takes place by outsourcing
into synthetic magnitude values (through fuzzy theory) the business activities that originate risks, typically the
and (iii) simulation techniques to test on a model the transport by tankers.
damages caused by each risky event under different
environmental conditions (wind speed, air temperature
and other weather conditions). 2.5. Need for action
Due to the differences (outlined in Section 2.1) among
plants, processes and operational risks within each
2.4. Risk control stage of the oil supply chain and due to that the risk
With reference to risk control, the oil industry is management process is undifferentiated along the oil
characterised by prevention practices to reduce the supply chain, a need for action arises in order to
probability of damage occurrence and by protection identify specific approaches and tools to be used
practices to limit the damage magnitude. Such for risk management at the drilling, transport and
practices, popular as loss control techniques, involve refining levels.
6 R. Cigolini and T. Rossi

A more accurate risk management processes spe- management process and methods for the transport
cifically conceived for each stage of the oil supply chain and refining stages, respectively: risk analysis, risk
allows: (i) to identify all the risky events a drilling plant assessment and risk control are treated with reference
or a transport system or a refining plant can suffer to the production phase only and the object of the risk
from; (ii) to better evaluate the probability and the management process at the transport stage is given by
magnitude of each risky event and (iii) to activate the oil-pipelines, which represent the transport resources
most appropriate control actions for the highest under the direct responsibility of the oil company.
priority risks. A careful risk management is particu-
larly relevant in the oil industry where underrated risks
can lead to environmental disasters and to heavy loss 3.1. The drilling stage
of human lives. The construction of new production plants is quite
Section 3 is devoted to present approaches and tools common at the drilling stage, so the risk management
specific for each stage of the oil supply chain. Such process has to be conceived for the plant life cycle up
approaches and tools have been identified through to production. Since various criticalities characterise
team-working with Eni Corporation managers of the each plant life-cycle phase, specific risk analysis, risk
divisions Exploration & Production (for the drilling assessment and risk control techniques have to be
stage) and Refining & Marketing (for the transport and proposed for each stage (Figure 4). The risk manage-
the refining stages). For this reason, the items related to
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ment process during the design phase depends on the


risks and activities the oil company is responsible for are design type: if the drilling plant is a standard one (the
mainly considered in the following. plant is similar to others formerly designed and built in
terms of functional and dimensional features as well of
context where the plant will operate), risk analysis and
3. The proposed model risk assessment should not be executed since the design
As stated above, this section is aimed at presenting will be performed according to the best practices
specific approaches and tools to manage risks at each established over the years (as a result of the risk
stage of the oil supply chain. Such a section is analysis and risk assessment performed with reference
structured according to the matrix depicted in to the first plants of the series). In other words, risk
Table 3. Section 3.1 is devoted to provide some insights management is limited to risk control.
on the risk management process and methods at the If the drilling plant to be designed is significantly
drilling stage and it treats risk analysis, risk assessment different from the ones previously designed (e.g. an
and risk control with reference to the whole drilling off-shore plant aimed at drilling a deeper field than the
plant life cycle. In particular, the risk management ones currently exploited), risky events identification
process during the design and construction phases is (risk analysis) and the estimation of the damages
focused on the drilling plants designed by the oil magnitude and occurrence probability (risk assess-
company and by an outsourcer, respectively. Sections ment) are needed. The hazard checklist technique is
3.2 and 3.3 aim at identifying the most proper risk suggested, since neither the ETA nor a backward

Table 3. Scheme of Section 3.

Stage Object Risk analysis Risk assessment Risk control

Drilling Design of drilling plant Hazard checklists, Judgements, ETA Databases


(Section 3.1) (designed by the oil HazOp
company)
Construction of drilling HazOp ETA, simulation Standards, equipments
plant (designed by an
outsourcer)
Production at drilling Judgements ETA, Simulation Operational procedures
plant
Transport Transport resources Judgements, HazOp Judgements, HazOp, HazOp, Costs/benefits,
(Section 3.2) belonging to the oil Costs/benefits, Equipments
company simulation
(oil-pipelines)
Refining Refining plant Literature, Field Databases, ETA, Equipments, Insurances
(Section 3.3) experience, Simulation
HazOp, Databases
Production Planning & Control 7

technique nor a hybrid one is suitable, given that the additional prevention and/or protection equipment.
drilling plant has not been designed yet. Within the risk Such precautionary check is always carried out not-
assessment phase, the magnitude and the occurrence withstanding the oil company transfers risks resulting
probability of the damages corresponding to the risky from incorrect design decisions to the outsourcer
events can be estimated in a qualitative way, by having (Section 2.4) and notwithstanding the outsourcers
to resort to experts’ judgements (to be translated into analysis, assess and control risks when they design
synthetic values of magnitude and probability through the drilling plant. The check pattern is the same as the
fuzzy sets). one to be used for non standard plants.
Once the design is finished, the plant has to be During plant production, risk management follows
verified from the risk point of view. Through a HazOp two paths. The former one concerns the drilling
analysis, the risky events can be identified and, starting activity: risk management (analysis, assessment and
from the reliability data of each component, the control) is aimed at preventing and at facing blowout,
frequency of each risk event is estimated. Then, by which is the most relevant damage that can be
means of ETA, the different damages and the corre- triggered. Risk management has to be performed
sponding probabilities can be figured out. Finally, periodically and is composed of four steps: (i) identi-
simulation techniques help to outline the magnitude of fication (on the basis of experts’ opinions) of risky
each damage. If the design is unsatisfactory under events which can result in blowout; (ii) for each risky
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given combinations of probability and magnitude, it event, by means of historical data and/or data obtained
will be modified to reduce damages effects and/or from industry data bases, the corresponding events tree
frequency and new checks will be done until the is drawn and the damages which the risk event can
impacts of all damages are acceptable. actually result in are detected (the events tree allows
The risk management process during the drilling also the damages occurrence probability to be esti-
plant construction depends on the designer: if the mated); (iii) the magnitude of each damage is deter-
designer is the oil company, risk analysis and risk mined through simulation; (iv) loss control measures
assessment should not be executed since the plant will are taken to prevent blowout (through the substitu-
be built according to the best practices established over tion of components and by increasing maintenance
many years. Risk management is limited to risk control frequency) and/or to reduce its consequences (by
and the plant is built according to good construction defining and implementing safety procedures and
practices that derive from the oil company experience insurances).
and/or they are suggested by third parties (e.g. the Det The latter path of the risk management concerns
Norske Veritas foundation). If an outsourcer designed the production and/or the plant itself, which represent
the plant, the design is checked by the oil company to the other activities that can cause damages to the
verify whether to install (during construction) operators. The risk management is limited to risk

Project Standard Production phase


specifications project ? Design
Yes phase Risk analysis and
No Plant design risk assessment
(experts’ judgements,
according to
Risk analysis Constru- ETA & simulation)
standards
ction
(hazard checklists) and
risk assessment phase
Drilling
(experts’
(experts’ judgements)
judgments)
Plant Plant
design construction
Risk analysis
(HazOp) and Other
risk assessment activities
(ETA &
simulation) Operative
Risk analysis
procedures
Plant design (made (HazOp) and
definition
by an outsourcer) risk assessment
(ETA & simulation)

Figure 4. Overall view of the risk management activities and tools (in grey) for the drilling stage.
8 R. Cigolini and T. Rossi

control. Detailed operative procedures (such as how to into tanks depend on oil-pipeline elevation profile and
execute maintenance in high sulphur concentration on safety and control equipments positioning; the
environments) are defined to minimise the possible analyses are done through ad hoc simulation software
harmful consequences for operators during the pro- tools.
duction and/or the plant maintenance. For the primary transport stage, the risk manage-
ment process has been faced with reference to the
production phase only, while both design and con-
3.2. The transport stage struction are not taken into account. This is due to that
oil companies are used to establish a new drilling plant
Within the transport stage, pipelines represent the for exploiting an oil-field, while seldom oil companies
main transportation resources which directly involve start to exploit completely new fields and/or to build
oil companies, given that the transport by tankers is new refining plants. For this reason, the management
usually performed by third parties (responsible for the of risks in designing and building oil-pipelines has been
damages such as loss of human lives, tankers founder- overlooked.
ing and oil pouring). According to this perspective, the
risk management is divided into two areas: on the one
hand, risks resulting from processes, procedures and
physical components (other than piping but connected 3.3. The refining stage
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with it) of the transport system; on the other hand, A refinery is composed of several plants, areas and
risks arising from pipeline breakdowns – this area is equipments, so that an early identification of the most
devoted to quantify oil leaks and to identify actions to relevant risk sources should be advisable. First of all,
minimise consequences. practitioners figure out (for each refinery component)
With reference to the former area, risk analysis and the main risk factors: operative procedures and/or
risk assessment are completely overlapped and they plant physical parts, which often originate critical
consist of the following steps: (i) identification of the situations, according to literature and field experience.
so-called HazOp nodes (booster pumps, retaining Then, the risk of each previously identified factor is
valves, etc.), which divide the transport system into estimated, according to industry databases and acci-
sub-systems to be analysed separately; (ii) execution of dents that both occurred and were avoided over a
HazOp analysis on each sub-system to figure out relevant time horizon (10 years). Finally, risk levels are
criticalities, possible causes (hazards) and effects adjusted to take into account safety and control
(damages), recommendations (from the plant and/or equipments, and each plant, area and equipment of
process viewpoint) to reduce or to eliminate the above the refinery is prioritised (according to the risk
mentioned criticalities; then the risk value of each management perspective) on the basis of the adjusted
criticality (and of the corresponding recommendations) risk levels of the factors it is characterised by.
is given by the product between hazard frequency and With reference to the risk management process at
damage magnitude – both of them can be expressed by the refining stage, risk analysis consists of a HazOp
means of indexes drawn by experts from a Likert scale analysis which studies the behaviour of each plant,
and (iii) costs-benefits evaluation of each recommen- area and equipment due to the risk factors it is
dation – before versus after evaluation costs and characterised by and under various process parameters
damages related to the implementation of the recom- settings (temperature, pressure and flow). Such an
mendation. Risk control consists of defining the analysis allows both the causes or ‘primary events’
recommendations to be implemented according to the (typically concatenation of failures, operational errors,
priorities expressed by the criticalities risk values process anomalies, leaks) and the effects of the risk
(obtained after the HazOp analysis) and by the factors to be identified.
outcomes of the costs-benefits analysis. Risk assessment is composed of three sub-phases:
With reference to the area linked to pipeline (i) estimate of the primary events frequency on the
breakdowns, risk management is composed of risk basis of literature (Health and Safety Executive 1978,
assessment and risk control only. In particular, in this Rijnmond Public Authority 1982, Lees 1996) and/or
case, the risk management process is aimed at industry databases (the Center for Chemical Process
estimating leaks due to oil-pipeline possible breaks, Safety data base, among others); (ii) outline of the
defining activities to keep down environmental con- consequences of each significant (characterised by a
sequences of such leaks and reducing the probability of rate greater than 106 times per year) primary event
explosive atmospheres into the tanks. The leaks and of the related frequency. ETA is used and only the
estimation and the valuation of explosive atmospheres significant (characterised by a frequency higher than
Production Planning & Control 9

108 times per year) damages are used as inputs of the 4. Applications
subsequent sub-phase and (iii) assessing the magnitude The model proposed here has been applied to the
of the previously identified significant damages – three stages of the Eni’s supply chain. In particular,
ad hoc simulation tools are suggested to evaluate the the application has dealt with one of the oil-fields
damages severity in terms of operational variables in Kazakhstan (at the production stage), the
(toxic substance concentration and heat density); by Sannazzaro refinery (at the refining stage) and
combining the damages occurrence frequency and the oil-pipeline connecting the Livorno refinery to the
magnitude, the highest priority risks are identified. Cadenzano depot (at the transport stage).
The remaining risks are faced in the risk control Unfortunately, intellectual property constraints have
step by means of both actions aimed at preventing the prevented from providing in-depth details about the
damages occurrence (maintenance activities, control production stage.
equipments installation and operational procedures With reference to the refining stage, the model has
definition) and technological and/or financial instru- been applied to the vacuum plant which allows to
ments aimed at reducing the damages consequences produce light, middle and heavy distillates. This plant
(safety equipments and insurances). is composed of three units: the preheat exchanger train,
Similarly, as for the transport stage, also for the the furnace and the vacuum column. The first step of
refining stage the risk management process has been the risk analysis requests to identify the risk factors of
Downloaded By: [roberto.cigolini@polimi.it] At: 16:53 11 March 2010

faced with reference to the production only, while each unit: according to the field experience of the
design and construction have been overlooked. This is refinery staff, such factors are represented by hydro-
due to that oil companies seldom build new refining carbon fractions for the exchanger and for the furnace,
plants, which does not make a priority the investiga- and gas oil for the column.
tion of risks in designing and building refining plants. For the preliminary identification of the most
Appendix 1 synthesises the suggested pattern to critical areas of the plant, the so-called compensated
perform the risk management process in the oil general risk index (G0 ) has been used. Such index,
supply chain. defined by the Italian law,1 takes into account both the
inherent risk of the substance and factors that can
either increase or decrease such risk (e.g. plant layout,
prevention and protection measures). In this way, G0
index allows the second and the third sub-phases of the
Table 4. Compensated general risk indexes (G0 ) for the
risk analysis to be fused. Table 4 reports the G0 s for the
vacuum plant units.
three units of the vacuum plant, while Appendix 2
Unit G0 Corresponding risk level highlights the calculation algorithm.
According to Table 4, different vacuum plant units
Preheat exchanger 34.41 Low are ranked to perform the primary events identification
Furnace 33.45 Low (the last sub-phase of the risk analysis). Table 5
Vacuum column 206.78 Medium
reports the HazOp referred to the part of the

Table 5. HazOp analysis on the in parallel-flow heat exchangers and the feeding line of the preheat exchanger train under the
following conditions: 8/4 bar pressure; 170/250/290 C temperature; 3  105 kg/h flow rate.

Key word Causes Effects Protection measures

No/less Failure in closing the inflow The pressure of the inflow line You should add a device to
valve of the furnace leads to equals pump prevent the valve form the
shut-off complete closing
Failure in locking the inflow The pressure of the line You should add a controller
valve of the furnace decreases that closes the auxiliary line,
thus allowing the flow to be
incremented as needed
More Failure in opening the inflow The valve has to be closed to You should provide the valve
valve of the furnace keep adequate pressure with a system preventing it
from complete opening
Leaking Leaking through the flange of Outflow of hot substances; You should section the line and
the exchanger (primary maybe vapours cloud and take measures against fire
event #1, see Table 6) fire
10 R. Cigolini and T. Rossi

Table 6. Primary events together with their frequencies and sources.

ID Primary event Frequency (times/year) Source

1 The exchanger leaks 2  104 Industry database


2 The heating coil of the furnace cracks 1  102 Industry database
3 The outflow line of the furnace overheats 2  109 FTA
4 Superheated hydrocarbon outflows at the end of 2  102 Industry database
the vacuum column
5 The vacuum column is over-pressured 4  109 FTA

Maximum pressure value exceeded

And

The column is over pressured Lock valve


016 broken Lock valve 020
down broken down
Or
λ = 2.1 x 10–4 λ = 2.1 x 10–4
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The XV-007 Incorrect locking of waste Incorrect locking of the manual


valve is locked gas line not detected valve on the gas outflow line
λ = 9.3 x 10–6 λ = 2.8 x 10–8
Or

Incorrect locking Warning failed


of waste gas line
λ = 3.4 x 10–7 And

Prevention device 163 ineffective Prevention device 164 ineffective

Or Or

Detector 163 Alarm out The operator does Detector 164 Alarm out The operator does
not properly not properly
out of order of order operate out of order of order operate
λ = 8.3 x 10–6 λ = 2 x 10–6 λ = 0.01 λ = 2.5 x 10–5 λ = 2 x 10–6 λ = 0.01
TT = 3.5 x 104 TT = 720 TT = 3.5 x 104 TT = 720

Figure 5. Fault tree for the primary event #5 (see Table 6) ‘the vacuum column is over-pressured’.

preheat exchanger train composed of the in Reliability Database (PERD) of the Centre for
parallel-flow heat exchangers and the feeding line, Chemical Process Safety.2
while the first column of Table 6 shows the results of Now, the last two steps of the proposed risk
the HazOp for all the three units the vacuum plant is assessment methodology are to be applied to all the
composed of. primary events whose occurrence frequency is higher
Now, the calculation of the primary events than the threshold value (1  106 times per year), i.e.
frequency (the first step of the risk assessment #1, #2 and #4 (see also Table 6). For the sake of
phase) can be performed through either literature or simplicity, the remainder of the paragraph is focused
industry databases or FTA. Table 6 reports the on the primary event #1 only.
primary events together with their frequencies and As for the identification of the effects for
sources, while Figure 5 highlights the fault tree the considered primary event and the valuation of the
corresponding to the primary event #5 (Table 6). The corresponding frequencies, the suggested tool is
failure rates of the base faults () and the interval (in the ETA. Figure 6 depicts the event tree concerning
hours) between two consecutive tests (test time, TT) the primary event #1 (Table 6). By multiplying the
are drawn from the Performance Equipment conditional occurrence probabilities of the effects
Production Planning & Control 11

Pool-fire oil and it is characterised by a 175 m3/h flow rate. For


Instantaneous Yes 5%
burning the sake of simplicity, the remainder is focused on the
No white pipeline only.
The 95% Yes 15% Flash-fire According to the proposed methodology, the risk
exchanger + pool-fire analysis is unnecessary, given that the only risky event
Delayed
Delayed
leaks
burning
burning No 85% is represented by oil leaking from the pipelines. As
Dispersion
suggested in Section 3.2, the risk assessment phase has
Figure 6. Event tree for the primary event #1 (see Table 6). been carried on by means of simulation techniques to
verify if and where along the pipeline the possible
petrol outflow could be greater than the maximum
Table 7. Effects frequencies for the primary event #1 admissible value for Eni (150 m3). By setting the proper
(Table 6). input data (pipeline lay-out and profile, pressure and
flow rate, positions of the valves, etc.) on the simula-
A. B. tion software package Pipeline SimulatorTM,4 the
Primary Occurrence outflows of petrol in the case of a break can be
event #1 probability AB calculated in each point of the pipeline.
frequency (according to Frequency
Effect (times/year) the ETA) (times/year) Figure 7 shows the simulation output. Notice that
Downloaded By: [roberto.cigolini@polimi.it] At: 16:53 11 March 2010

only in one point of the white pipeline, the petrol


Pool-fire 2.00  104 0.05 1.00  105 outflow exceeds the maximum threshold value. Such a
Flash-fire þ Pool-fire 0.95  0.15 2.85  105 point belongs to the final part of the white pipeline
where the course is descending and the simulation
software estimates 190 m3 petrol outflow in the case of
a pipeline break. As a consequence, in this point
Table 8. Effects magnitude.
prevention measures (e.g. periodical checks of the
Effect Threshold Wind: 5 m/s Wind: 2 m/s pipeline status and preventive maintenance actions) as
well as protection measures (such as the installation of
Pool-fire 12.5 kW/m2 7m 7m both equipments for detecting the outflow occurrence
7.0 kW/m2 8m 9m and motorised valves upstream the considered point)
5.0 kW/m2 10 m 10 m
3.0 kW/m2 11 m 12 m must be adopted, while neither prevention nor protec-
Flash-fire þ LFL 51 m 51 m tion measures are needed elsewhere along the white
Pool fire pipeline.
LFL/2 51 m 51 m

5. Concluding remarks
(calculated on the basis of the event tree) by the
frequency of the primary event, the frequency of each The study of risk management processes along the oil
effect is obtained, as shown in Table 7. supply chain highlights that nowadays risk analysis,
The latter step refers to the valuation of the effects risk assessment and risk control at the drilling, primary
magnitude by means of simulation techniques. In transport and refining stage do not show significant
particular, by setting the proper input data (wind differences in terms of neither approaches, nor
speed, outflow rate, temperature, pressure, etc.) on the techniques and tools. However, the different stages
simulation software package PHASTTM Professional,3 are affected by various operational risks, basically
the severity of the effects of the considered primary according to the differences in plants and, as a
event can be calculated. These effects are expressed in consequence, each plant should be provided with a
terms of the distance reached by the thermal radiation specifically conceived risk management process.
and in terms of the concentration of the vapours cloud For the drilling stage, the model proposed here
at the Lower Flammability Level (LFL, see Table 8). suggests three sub-methods, one for each period of the
At the transport stage, the oil-pipeline connecting drilling plant life cycle (design, construction and
the Livorno refinery to the Cadenzano depot is production). Different patterns of risk management
composed of two pipelines: the former one (called sub-methods are proposed to take into account the
white pipeline) is devoted to transport petrol and it is type of the drilling plant to be designed, who designs
characterised by 220 m3/h flow rate, while the latter the plant and the operative activities performed within
one (called black pipeline) is devoted to transport gas the plant.
12 R. Cigolini and T. Rossi

200

Petrol outflow in m3
150

100

50

0
0 10 20 30 40 50 60 70 80 90
Point of the pipeline (distance from the origin, in km)

Figure 7. Outflow level along the white pipeline.

For the primary transport stage, two different risk plants and oil-pipelines the activities which refer to the
management processes are proposed. The former one risks connected to the end of their life cycle, that is
allows the risks resulting from processes, procedures referred to the drilling plant tapping out, the refining
Downloaded By: [roberto.cigolini@polimi.it] At: 16:53 11 March 2010

and physical components (other than oil-pipelines) to plant shut down and the oil-pipeline dismantling.
be identified, assessed and controlled, whereas the
latter one allows risks arising from the pipeline
breakdowns to be faced. Acknowledgements
Finally, for the refining stage, a preliminary phase The authors wish to acknowledge Dr E. Pizzurno of Eni
is recommended to identify the priority according to Corporate University for his contribution and Fondazione
which each plant, area and equipment of the refinery Cariplo for the financial support. The authors also express
their gratitude to the anonymous referees and to the Editor
has to be submitted to the risk management process,
of Production Planning & Control for their suggestions.
and several techniques and tools (HazOp, historical
data analysis, ETA and simulation) are suggested.
The effectiveness of the methodology presented Notes
here has been tested by directly applying it in field. In 1. DPCM 31.3.89, i.e. Prime Minister Decree dated 31
particular, three case studies involving, respectively, March 1989
one of the Eni oil-fields in Kazakhstan (not reported 2. See: http://www.aiche.org/ccps
3. See Det Norske Veritas (DNV) and the related website:
here in depth for intellectual-property-related con- http://www.dnv.com/services/software
straints), the Eni Sannazzaro refinery and the Eni 4. See Pipeline Systems Incorporated (PSI) and the website:
oil-pipeline connecting the Livorno refinery to the http://www.pipesys.com/app_simulator.html
Cadenzano depot have been carried on. This applica-
tion has proved the model’s usefulness in field to
support the risk management process at different levels Notes on contributors
of the oil supply chain. Roberto Cigolini is Professor of
In particular, the main strength connected to more ‘Quality Facility Management’ and
of ‘Operations Management’ at the
effective (able to take into account the specificities of School of Management of Politecnico
each stage) risk analysis and assessment phases lies in di Milano. His main interests are
the possibility to pinpoint the actual high-priority primarily related to business planning
risks. This is crucial for the subsequent risk control and control, supply chain manage-
phase, in which it allows to focus the control effort ment, facility management contracts
negotiation and real estate manage-
only on the most prominent risks. ment. He graduated cum laude in
Finally, future research steps will deal with: (i) Management Engineering at Politecnico di Milano in 1994.
investigating the risk management process performed From 1999 to 2002 he has been co-Director of the MBA
by outsourcers in the drilling plants design phase as program at the MIP – Politecnico di Milano Business
well as by third parties with reference to the transport School and now he is co-Director of the Facility, Property
& Asset Management Master Course. He is also founding
by tankers; (ii) including into the risk management member (2001) of the Technical Committee on
process of the transport and refining stages also the Semiconductor Factory Automation (IEEE Robotics and
unusual design and construction phases; and (iii) Automation Society) and member of the McKinsey executive
highlighting in the design of drilling and refining panel.
Production Planning & Control 13
Tommaso Rossi graduated in Khan, F., Sadiq, R., and Husain, T., 2002. Risk-based
Management Engineering at
process safety assessment and control measures design for
Politecnico di Milano in 2000. Since
2001 to 2004 he attended the PhD off-shore process facilities. Journal of Hazardous
course in Industrial Engineering at the Materials, 94 (1), 1–36.
Politecnico di Milano, spending his Lees, F.P., 1996. Loss prevention in process industries. Hazard
abroad period at the MIT (Boston, identification, assessment and control. Heinemann, Oxford:
MA). Since 2002 he is Researcher Butterworth.
at the Institute of Technology of Molak, V., 1997. Fundamentals of risk analysis and risk
Università Cattaneo – LIUC (Castellanza, Italy), where he management. Boca Raton, FL: Lewis Publishers.
holds the courses of Operations Management and Supply Nguyen, J.P., 1996. Drilling: oil and gas field development
Chain Management. He is member of the National
techniques. Paris, France: Editions Technip.
Association for Industrial Plants and the National
Nguyen, J.P., et al., 2005. Variety and the evolution of the
Association for Quality. His research interests concern
production planning, network design, simulation, hybrid refinery processing. Industrial and Corporate Change, 14
production systems and risk assessment. (3), 469–500.
Novelli, L., 2004. Oil and natural gas: exploration and
production. Rome, Italy: Eni internal publication (in
Italian).
Omole, O., Borisade, T.A., and Muhammad, A., 2004. Risk
References impact on the economic performance of oil and gas
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projects in Nigeria. OPEC Review, 24 (4), 247–274.


Blackhurst, J., et al., 2005. An empirically derived agenda of Peck, H., 2004. Interesting times. Freight Transport Review,
critical research issues for managing supply-chain disrup- Spring (2), 1–3.
tions. International Journal of Production Research, 43 Pizzurno, E. and Rossi, T., 2007. Introduction to the
(19), 4067–4081. operational risks in the oil supply chain. Working Paper
Brandsaeter, A., 2002. Risk assessment in off-shore industry. No. 5. Eni Corporate University, Rome, Italy (in Italian).
Safety Science, 40 (1), 231–269. Proth, J.M., 2007. Supply chains: measure, evaluation and
Castellano, A. and Cigolini, R., 2002. Using modularization specific risks. International Journal of Business
to manage construction projects of onshore process plants: Performance Management, 9 (2), 127–144.
a theoretical approach and a case study. Project Radjou, N., 2002. Adapting to supply network change.
Management Journal, 33 (2), 29–40. March 2002 Forrester Research Technology Strategy
Chapman, P., et al., 2002. Identifying and managing supply Report, Forrester Research, Cambridge, MA.
chain vulnerability. Logistics and Transport Focus, 4 (4), Rice, J. and Caniato, F., 2003. Building a secure and resilient
59–64. supply chain. Supply Chain Management Review, 7 (5),
Cigolini, R., Cozzi, M., and Perona, M., 2004. A new 22–30.
framework for supply chain strategies: conceptual models Riddalls, C. and Bennett, S., 2002. Production – inventory
and empirical test. International Journal of Operations and system controller design and supply chain dynamics.
Production Management, 24 (1), 7–41. International Journal of Systems Science, 33 (3), 181–196.
Cigolini, R. and Rossi, T., 2006. A note on supply risk and Rijnmond Public Authority, 1982. Risk analysis of six
inventory outsourcing. Production Planning and Control, potentially hazardous industrial objects in the Rijnmond
17 (4), 424–437. area; a pilot study. Dordrecht, The Netherlands: Kluwer,
Cigolini, R. and Rossi, T., 2007. Evaluating supply chain Reidel.
integration: a case study using fuzzy logic. Production Ross, J.G., 2004. Risk and uncertainty in portfolio char-
Planning and Control, 19 (3), 242–255. acterization. Journal of Petroleum Science and Engineering,
Clifton, A. and Ericson, I.I., 2005. Hazard analysis techniques 44 (1–2), 41–53.
for system safety. New York: Wiley. Tapiero C.S., 2004. Risk measurement and supply chains. In:
Crawley, F., Preston, M., and Tyler, B., 2000. HAZOP: International Workshop on Performance and Risk
guide to best practice: guidelines to best practice for the Measurement, Milan, Italy, 113–129.
process and chemical industries, Railway Terrace. Rugby, Tapiero, C.S. and Grando, A., 2006. Supply risk and
UK: IChemE. inventory outsourcing. Production Planning and Control,
Culp, C.L., 2001. The risk management process: business 17 (5), 534–539.
strategy and tactics. New York: Wiley. Vesely, W.E., et al., 1981. Fault tree handbook. Washington,
Dey, P.K., Ogunlana, S.O., and Naksuksakul, S., 2004. Risk- DC: US Nuclear Regulatory Commission.
based maintenance model for off-shore oil and gas Westbrook, R., 1995. Action research: a new paradigm for
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Island – Thurrock area. London: HMSO. Thousand Oaks, CA: Sage.
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14

Appendix 1
Table A1. Taxonomy of techniques and tools to manage risk along the oil supply chain.

Risk analysis Risk assessment Risk control

Sub-phases Tools Sub-phases Tools Sub-phases Tools

Drilling Design Standard project Standard project Standard project


– – Plant design according to Data base of
standards (best practices) similar
projects
Non standard project Non standard project Non standard project
Risky events identifica- Hazard checklist Damages severity and Experts’ Plant design for reducing
tion (before the frequency valuation judgements the damages severity
design) (before the design) and/or frequency
Risky events identifica- HazOp analysis Damages severity and ETA and Plant re-design for reducing
tion (after the design) frequency valuation simulation the damages severity
(after the design) techniques and/or frequency
Construction Design made by the oil Design made by the oil Design made by the oil
company company company
R. Cigolini and T. Rossi

– – Plant construction Constructive


according to the standards
standards (best practices)
Design made by an Design made by an Design made by an
outsourcer outsourcer outsourcer
Risky events HazOp analysis Damages severity and ETA and simula- Damages severity and/or Control and/or
identification frequency valuation tion frequency reduction by safety
techniques means of the installation equipments
prevention and/or
protection equipments
Production Drilling activities Drilling activities Drilling activities
Risky events Experts’ Damage (blow-out) severity ETA and Actions for reducing the Substitution of
identification judgements and frequency valuation simulation blow-out occurrence components,
probability as well as the maintenance,
blow-out consequences safety
equipments,
insurances
Other activities Other activities Other activities
– – Definition of detailed
operative procedures
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Transport Processes, procedures Processes, procedures and Processes, procedures and


and physical compo- physical components physical components
nents (other than (other than pipelines) (other than pipelines)
pipelines)
HazOp nodes Experts’ Damages identification, HazOp analysis Recommendation Outcomes of the
identification judgements valuation of their mag- and experts’ implementation HazOp and
nitude and frequency judgements cost/ benefit
and recommendation analysis
definition
Risky events HazOp analysis Damages and correspond- Cost/ benefit
identification ing risky events analysis
prioritisation
Oil-pipeline Oil-pipeline Oil-pipeline
– Leaks and explosive atmo- Simulation Installation of physical Control and
sphere in tanks valuation components for reducing safety
leaks equipments
Refining Risk factors Literature & field Primary events frequency Literature, Actions for preventing Maintenance,
identification for experience valuation industry data damages control
each refinery area bases and equipments
FTA
Valuation of the risk Literature & his- Identification of the ETA Technological and financial Safety
level of each factor torical data primary events instruments for reducing equipments,
consequences and their damages magnitude insurances
frequency valuation
Risk level adjustment Adjusted risk Consequences magnitude Simulation
due to the presence of levels valuation
control and safety
equipments
Refinery areas
prioritisation
Primary events HazOp analysis
Production Planning & Control

identification
15
16 R. Cigolini and T. Rossi

Appendix 2. Calculation algorithm of the into account the conditions of pressure, tempera-
compensated general risk index (G0 ) ture, etc. at which the process takes place;
. Q is the quantity risk index. It is given by literature
The compensated general risk index G0 is calculated and it is a function of the quantity of substance
according to Equation (1): treated during the process;
G 0 ¼ G  k1  k2  k3  k4  k5  k6 , ð1Þ . L is the lay-out risk index. It is obtained by
summing up the plant’s height (h), the plant’s
where G is the general risk index and k1. . .6 are coefficients surface (N) and five other sub-indexes, which refer
(whose values range from 0 to 1) that allow to take into to other characteristics of the area where the
account prevention and protection measures, e.g. to retain process takes place (e.g. the presence of tunnels
substances, to control the process, to train operators, to and/or catch basins under the plant); the values to
isolate the substances in case of outflow occurs, etc.; the more the five sub-indexes are assigned from pre-defined
intense the actions, the closer to 0 k1. . .6 are. scales and on the basis of how the area performs
The general risk index G is given by Equation (2), where with reference to the corresponding characteristics;
A, C, D and F are indexes . s is the health risk index. It ranges from 0 to 100. In
pffiffiffiffiffiffiffiffiffiffi the case of accident, if operators can lose their lives,
G ¼ D  ð1 þ 0:2  C  A  FÞ ð2Þ
s ¼ 100; otherwise, if the accident cannot have any
D index is the Dow equivalent index and it is calculated consequence for the operators’ health, s ¼ 0.
according to Equation (3)
C index is the explosion in a bordered environment index and
     
M P SþQþLþs it is given by Equation (4)
D¼B 1þ  1þ  1þ
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ð3Þ
100 100 100 mþpþs
C¼1þ ð4Þ
where 100
. B is the substance factor, that is a measure of the where
potential energy that can be released when an . m is the sub-index of M that expresses the mixing
outflow of the considered substance occurs; and dispersion characteristics of the substance; its
. M is the substance specific risk index. It is value ranges from 60 to þ100;
composed of 10 sub-indexes that refer to 10 . p is the sub-index of S that expresses whether the
substance characteristics (e.g. oxidising or non- process takes place at a high pressure or not. Its
oxidising substance). Each sub-index is assigned a value ranges from 0 to 160.
value drawn from a pre-defined scale on the basis of
how the substance performs with reference to the A index is the explosion in an open environment index and it
corresponding characteristic; is calculated according to Equation (5)
. P is the process general risk index and it is  
composed of six sub-indexes that refer to how the M Q  h  C t þ 273
A¼B 1þ  ð1 þ pÞ   ð5Þ
substance is manipulated and behaves along the 100 1000 300
process. Each sub-index is assigned a value drawn
from a certain range. Such a value is determined on where t is the temperature at which the process takes place.
the basis of qualitative judgements about the Finally, F is the fire index and it is given by Equation (6)
procedures according to which the substance is
manipulated or on the behaviour of the substance K
F ¼B ð6Þ
during the production process; N
. S is the process specific risk index and it is
composed of 14 sub-indexes that allow to take where K is the quantity (in tons) of the processed substance.

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