GUIDED SEE (Main + Advanced) 2021 REVISION LEADER + ENTHUSIAST COURSE CHEMISTRY GRS-2 ISOMERISM (STEREO) Paragraph Type question (answer as integer form) : 1. Options required to fill the blank space (P), (Q), (R), (S), (T) are your answer (for example if: P = 2, Q = 3, R =8,S =9, T =1 then your answer is 23891 for OMR Consider following options to fill the blank space in given paragraph (1) Linkage (2) Optical (3) Geometrical_-—_(4) Stereo (5) Facial (6) Meridional (7) Square planar (8) Tetfahedral (9) cis @) isomerism arisesin heteroleptic complexes due to different possible relative position arrangements of the ligands, Important examples of this behaviour aré found with coordination numbers 4.and 6. Ina square planer complex of formula [MX,L,] (X and L are unidentate), the two ligands X may be arranged adjacent to each other or opposite to each other: Other square planer complex of the type MABXL (where A, B, X, L are unidentates) shows three isomers Such isomerism is not two__(Q)_< andone___- You may attempt to draw these structures possible fora__(R)_geometry but similar behaviour is possible in octahedral complexesof formula IMX,L,]ittwhich the two ligands X may be oriented in two different possibility to each other This type of isomerism also arises when didentate ligands L-L [e.g. NH, CH, CH, NH, (en)] are present in complexes of formula [MX,(L=L)}] The isomerism occurs inoctahedral coordination tities of the type [Ma,b,] like [Co(NH,),(NO,),]. If three donor atoms of the same ligands occupy adjacent position at the comers of an octahedral, we have the___(S)__&_ isomer) When the positions are around the meridian of the octahedron, we get the. isomer. Complex : [MX,(L-L),] and [Co(NH,),(NO, ),] have total three and two _(T)__isomers.Guided Revision Plan Matching list type 1 x 3 Q. (Three list type Question) The following column I, I, Ill represent the different type of stereoisomersin complex compounds. Answer the questions that follow Column- Column-II- Number of optical active isomers Column-IIt - Pairs of Enantiomers - Number of Geometrical isomers Column -T Column - IT Column - IIT |Number of Geometrical | Number of optical | Pairs of Enantiomers isomers active isomers am 2 @O6 (Py a 6 3 @2 ay 3 Gil) 4 Rs ay iy 2 1 2. For[CrCl,(en)(NH,),]° complex the only CORRECT combination is (A) AID. Gi), () BAP) —_ C/A. (iv(S) (D) (MD, Civ), (Q 3. For[PICl(NH.),(py),1” complex the only CORRECT combination is - (A), (8) (B) A, (ii),(S)_— OV), (D) (IV). (iv),(S) 4. For[Co(gly),|" complex the only CORRECT combination is - (A), Gili), (R) (B) (0), ii), (Q O@,tiv),(Q (D) (ID, Gili), (Q) Match the column - 5. Column-T Column-IT (Complex compound) (Characteristics) (A) [CoCL,Br,]* (P) No Geometrical isomer (B) [Rh(en),* (Q)No Optical isomer (© [Cren),Br* (R) Two optically active form ) [Pi(gly)CIBrt (S) Chelating complex (1) +2 ON. of metal 6. Column-T Column-I (Chemical species) (Characteristics) (A) [PqNH,),CL] (P) Follows Sidgwick rule (B) [Co(H,0),F,] (Q) EAN value is 36 © Co Cl. CN. NO(NH,)gh (R) Have wo geometrical isomers ©) [Fe(aly),] (S) Shows optical isomerism (D)_ Shows inkage isomerism 7. Column-I Column-I ‘Type of complex The change in number of stereoisomer by the associated process with the given complex (A) [M(AB), ab] (P) 2 (B) [Mab] Q6 © [M(AA),a,)" ® 3 (D) [M(AB) ab] =alsb (5 (1) 0 2 —— ng iJEE-Chemistry ALLEN One or more than one correct type 8. Whichof the following compounds are resolvable into d or £-forms? (A) [ZnCl (en)] (B) [Be(acac),} (© [Cotgly),] (D) [CxC,0),- 9. Which of the following molecule(s)/ion(s) can show optical isomerism - (A) [Pt(bn),P* (B)[PtCL(NH,),] (C)[Fe(EDTA)]} (D) [Fe(en),* 10. Which of the following complxe(s) is/are not optically inactive 5 ns b, M (a) e a a (B) [M(EDTA)}> Where M?* = Ca*, Hg”* or Pb? CH, of GC bet sth el 11. _ Select complex (es) in whichall geometrical isomers of the complex are optically active (A) [Co(gly),P (B) [Co(en)(NH,\(p, (Br)(C))]* (©) [PUNH pp BoD? (D) [PUCO,)(NO2)9° 12. Outof given three complexes [Mn(CO), (HD [CrfCO),] (ID [V(CO),} (A) IID has maximum-O length (B) (II) has lowestO.N, of metal (©) @ has minimum number of electrons (D) (II) hasmaximum x-character in metal-carbon bond Single Correct Type 13. Whichof the following complex/ion can show only linkage isomerism. (A) [Co(NH,) (H,O)CIICN (B) [(Co(NH,) SCN] (©)[CoH,O) CI, (D) [Co(NH,),$0, [Br 14, Which of the following complex shows optical isomerism - (A)cis[CrCl(ox),F (B) trans [CrC1x), (C) [Fe(NH,), (CN),F (D) both (B) and (C) ny 3Guided Revision Plan 15. ALLEN Find the correct statements regarding these two complex - NH, NH, Nu, Bro Bs cl Me and 4 cl cl 1 a NH, © a (A) () and (I) are G.1. of each other and both are optically active (B) () and (II) are G.L. of each other and I is optically active while Il is optically inactive (©)C) and (IP are G.L. of each other and both are optically inactive (D) (1) and (ID) are identical and both are optically inactive. Paragraph type questions : 16. 17. 18. 19. 20. 2. Integer (Single Digit Type) 22. 23. 24, 4 Paragraph for Q. No. 16. to Q. No. 18 ‘The complex compounds which have the same lignads ii the co-ordination sphere but the relative position of the ligands around the central atom is different aré Galled as geometrical isomers and this phenomenon iscalled geometrical isomerism (G.L) Find the number of complexes having zero dipole moment forthe complex formula [MCI,(NH,),] (where M?* have 4d or Sd configuration) (A2 (B)0 ©L (D)3 Total number of triangular faces in mer [Ma,b,] complex which have éither two aatom or two batoms (A8 (B)6 (two (D) four Select incorrect about fae(Ma,b;] complex (A) Itisone of the G.1 of complex which is given in above question (B) Itis an optically inactive complex (©) Ithas one triangle face which has three a atoms’ (D) None Paragraph for Q. No. 19 to Q. No. 21 When the solutions of certain complex compounds are placed in the path of a plane polarised light, they rotate its plane through acertain angle, which may be either to the leftor to the right. Complex having this property (rotating the plane of polatised light) is said to be optically active and this isomerism is called as optical isomerism Number of optical isomers for Ma,b,c, complex ~ (A3 (B)2 @o (D)1 Number of optical isomers for M(AA), complex - “I (B)3 ©2 0 Number of optical isomers for Mab, complex ~ (a2 (BL oo (D) 03 Find out the total number of stereoisomer of [Pt(bn), ]°* Find the total number of geometrical isomers of [M(AB) (CD) (EF)|"* 5 Find the number of optically active isomers for the complex [Ni(gly).(H,O),} i —____. E1. 25 3 era eS 10. i. 12. 13. 14, 16. 2 eeee Peer sor oe JEE-Chemistry Ans, (39854) Ans.(C) Ans.(D) Ans.(B) Ans. (A) -P,Q, T; (B)-P,R,S ; (C)- R, SD) - QS,T Ans. (A)-R 5 (B)-P,Q,R ; (C)-P,Q, S,T ; (D)-R,S Ans. (A)-R 5 (B)-P 5 (C)-T ; (D)-P Ans. (C,D) [Co(gly),] and [Cr(C,O,),* both are octaheadral complex. Ans. (A,C,D) Ans. (B,C,D) Ans. (A, B) Ans. (A, D) Ans. (B) SCN act as ambidentate ligand. Ans. (A) Ans. (C) Ans. (C) ‘Ans. (A) ‘Ans. (D) Ans, (B) Ans. (C) Ans. (C)Guided Revision Plan 22. Ans. (7) cH, cH, ba pe NH, NHL “ nt »< e OL. H Sc NH,’ NH, ~cé cat Nou cn cH ba at 1 Nie (B) el MN ‘Nu OA Hal 7 Nuno ™ CNH, Ni cut Non, cH cH, QO en © W HN OR p ena cH, OL OA, 23. Ans. (8) cB CB 7B B Nic) SylePpSih-8) Ale) RAND ER te Ne NE Se c c Ko Cp Cin ir ie) Sie?) Sic ®) Ae") RCTS RING SFY NE Qe F Np D 24. Ans. (6) ALLEN