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  • Guided Revision Sheet - Liquid Solution - English

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    46 views5 pages

    Guided Revision Sheet - Liquid Solution - English

    Uploaded by

    Yash Dhoke

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    GUIDED JE (Main + Advanced) 2021 REVISION LEADER + ENTHUSIAST COURSE| CHEMISTRY, GRS-22 LIQUID SOLUTION SECTION-I : (i) Only One option correct Type This section contains 9 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. 3D 1. 3 8. The solubility of common salt is 36.0 gm in 100 gmof water at 20°C. Ifsystems I, Il and III contain 20.0, 18.0 and 15.0 g of the salt added to 50.0 gm of water in each case, the vapour pressures would be in the order. (A)I 11> 11 (l=I> ml (D) T= P,, , which relation between X,, (mole fraction of A in liquid phase) and Y ,(mole fraction of A in vapour phase) is correct? (AY, X, JEE-Chemistry 1 ideal binary mixtu mole fraction of 'B' in liquid phase). mole fraction of 'A’ in vapour phase) ing plots repre (A) Plot of Pygy W/S UX, is linear (X, (B) Plot of P.,., WS Y, is linear (Y, (©) Plotof 1 (D) Plotof p — v/s Y,,is non linear vis Y,, is linear Paragraph Type This section contains 2 paragraphs , describing theory, experiment, data etc. 5 questions relate to one paragraphs with two questions, Each question of a paragraph has only one correct answer among the four choices (A), (B), (C) and (D). 30) 14, 15. 16. Paragraph for question no. 14 to 16 The lowering of vapour pressure on adding a non-volatile solute may bémeasured by Ostwald- Walker method, In this method, dry airis fist passed through a series of vessels having the solution, then through series of vessels having pure solvent and finally through a vessel (normally U-tube) having the absorbent of the solvent, The masses of solution and pure solvent decreases due to removal of vapours of solvent in the flow of airand the massof absorbent increases due to absorption of the vapour of solvent, in order to make the airdry. By measuring the changes in mass, we may detefmine the lowering of vapour pressure and hence, the composition f solution, formRaoultf's law. If the mass of absorbent increased by 0.24 gm/and the massof pure solvent (water) decreased by 0.02 gm, then the mass percent of solute (glucose) in its@quedte solution is, 1000 100 1000 100 yd ® O3%* O77 % (A) If the experiment ispetformed with ag, AICI, solution (c.=0.8) prepared by dissolving I mole AICI, in 17 mole water and the decrease in mass of solution is found to be 0.18 gm, then the increase in mass of absorbent should be ; (A) 0.216 gm (B) 0.225 gm (C) 0.191 gm (D) 1.08 gm If the arrangement of vessels is changed in the experiment as : Dry air eS ett Dry air. then, whichOf the following must be incorrect? (A) the massof pure solvent will decrease, (B) the mass of solution will decrease. © then (D) The experiment will obey the law of conservation of mass. of absorbent will increase. Guided Revision Plan ALLI mM Paragraph for Q.17 to Q.19 One mole of liquid *A’ and two moles of liquid ‘B’ are mixed 27°C to form an ideal binary solution. (In2 = 0.7, In3 = 1.1) 17. The value of AH, is Ao (B)+ve ©-ve (D) any of these 18. The value of AG, , is (AO (B)+ 1140 cal/K (C)- 1140 cal /K (D)-380 cal /K - mol 19. The value of AS,,,. is (AO (B) + 3.8 cal/K (C)-3.8 cal/K (D) +3.8 cal /K- mol SECTION-III : (Integer Value Correct Type) This section contains 4 questions. The answer to each question is a single digit Integer, ranging from 0 to 9 (both inclusive) 4-1) 20. In how many of the following, the elevation in boiling point of the final solution is more than that of initially taken solution (No limiting reagent) (Assume: = 1 where ever needed) (i) BaCl(aq.) + Na,SO,(ag.) (added)—> BaSO, + 2NaCl(ag.) (ii) K FFe(CN),(aq.) + 2CuSO (ag. (added) > Cu,Fe(CN), +2K,SO, Gii) AL,(SO,),(ag,) + 3BaCl, (aq) (added) -> 3BaSO, +2AICI(2q,), (iv) AgNO, (ag.) + 2KCN (added) > K[Ag(CN,)(ag.) + KNOKaq.) 21. If | gmof solute dimerise upto 75% in 100gm of H,O & show depression in freezing point 0,093°C. Find average molecular weight of solute & dimer in the solution (K,j1,o, = 1.86). Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer. 22. 4ml of a gas at | atm pressure and 300 K is dissolved in 1L of solution. Calculate the volume of the 1 coe gas dissolved at 4 atm pressure and 300 K in > L of solution in ml. 23. When the mixture of two immicible liquids (water and nitrobenzene) boils at 372 K and the vapour pressure at this temperature are 98.4 kPa (H,O) and 3.6 kPa (C,H,NO,). If the weight ratio of nitrobenzene and water in the vapour is | : x, then the value of *x’ is. 4 9 ALLEN JEE-Chemistry Epa LIQUID SOLUTION SECTION-I : (i) Only One option correct Type : 3-1) 1. Ans(D) 2 3. Ans. (A) 4. Ans.(D) 5 6. 7. Ans.(A) 8 Ans.C) 9. Gi) One or more options correct Type : 4(-1) 10. Ans. (A,C,D) ll. Ans.(B,C,D) 12. Ans. (C) 13. Ans. (C) Paragraph Type : 3(0) 14. Ans.(A) 15. (A) 16. Ans. (B) 17. Ans.(A) 18. Ans

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