lay ALLEN ° GUIDED SEE (Main + Advanced) 2021 ‘CAREER INSTITUTE Pate est ENGELS REVISION LEADER + ENTHUSIAST COURSE CHEMISTRY GRS-15 MOLE CONCEPT & REDOX REACTION SECTION-I : (i) Only One option correct Type This section contains 9 multiple choice questions. Hach question has four choices (A), (B), © and (P) out of which ONLY ONE is correct 3CD 1. 4 6. For the estimation of nitrogen, 1.4 g of an organie compound was digested by Kjeldahl method and the M evolved ammonia was absorbed in 60 mL of 7 sulphuric acid. The unreacted acid required 20 mL. of M Jo Sodium hydroxide for complete neutralizaton. The peréentage of nitrogen inthe compound is (A) 3% (B) 5% (©) 6% (D) 10% 3.0 gm silver salt of an organic acid exactly produce 2.16 gm silver of strong ignition. The basicity of the acid is (‘The molar mass of acid is 172 gm/ mol) (Ag= 108) @. 2 (3 (4 An aqueous solution contain’ 2M-AICI, and 8m-SnCl,. If the molarity and molality of Cl-ion in the solution is same, the density of Solution is (Al =27, Sn = 119) (A) 1.05 gm/ ml (B) 1.15 gm/ mb (©) 195m / ml (D) 2.05 gm/ ml A150 mL of solution of I, is divided into two unequal pars. I part reacts with hypo solution in acidic medium. 15 mL of 0.4M hypo was consumed. Tl part was added with 100 mL of 0.3 M NaOH solution. Residualbase required 10 mL of 0.3 MH,SO, sOlution for complete neutralization, What was the initial concentration of I, ? (A) 0.08 M. (B)0.1M (©()02M (D) none of these A458 g sample containing Mn,O, was dissolved and all manganese was converted to Mn?*. In the presence of fluoride ion, Mn?* is itrated with 3 litof KMnO, solution (which was 1.25 N against oxalate in acidic medium), both reactants being converted to acomplex of Mn(IIT) , What was the % of Mn,O, in the sample? (A) 50% (B) 75% (C)25% (D) 40% 20 ml of a solution of H,O, is diluted to 100 ml and 50 ml of this solution is titrated with 0.02 M KMnO, solution in acidic medium and required 50 ml. The volume strength of original H,O, (A) 0.285 V (B) L.12V (C) 2.80 V (D) 2.28 V ‘A mixture of NaHC,O, and KHC,, . HCO, required equal volumes of 0.2 N KMnO, and 0.12 N NaOH separately. What is the molar ratio of NaHC,O, and KHC,O,. HC,O, in the mixture ? (A621 (B)3:1 © solution is ~ 3 (D) noneGuided Revision Plan 8. ALLEN 10 ml of 0.10 M solution of a compound (Na,CO,.NaHCO, . 2H,0) is titrated against 0.05 M HCI. X ml of HC1 is used when phenolphthalein is the indicator and Y ml of HCI is used when methyl orange is the indicator in two separate titration, hence (Y - X) is (A) 20 ml (B) 40 ml (©) 60 ml (D) None of these Calculate the mass of anhydrous oxalic acid, which ean be oxidised to CO, (g) by 100 ml of an MnO>, solution, 10 ml of which is capable of oxidising 50 ml of INF to 1. (A) 45 gm (B) 22.5 gm (©) 30 gm (D) 12.25 gm Gi) One or more options correct Type This section contains 2 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE or MORE are correéh, 41) 10. ud. ‘A definite volume of pure ammonia (NH,) gas is passed through a series of electric sparks by which the volume becomes 90 ml. The increase in volume is due to formation of nitrogen (N,) and hydrogen (H) gases. All the gases finally present are washed with dilute sulphuricacid solution, by which the volume of gases becomes 80 mi. Al the volume are measured at the same temperature and pressure. Which of the following statement(s) is/are correct regarding the original ammonia sample? (A) The volume of NH, gas taken was 40 mi (B) The volume of NH, gas taken was 50 ml (©) Only 80% of NH, gas decomposed jinto N, and H, gases, (D) Only 20% of NH, gas decomposed into Ny and H, gases, When N,(g) and H,() afé mixed N,H, (g) ,NHL(g) or both may form , depending upon the relative amount of N, and H, taken, If initial moles of N,, Hare x,¥y and final moles of N,H,, NH, are, v, then the correct options from the following in order of (, y, 2)v) isare - (22,10) (B)3,8,1,4) ©4940) ()(05,3,0,1) (ii) Paragraph Type ‘This section contains 1 paragraphs cach describing theory, experiment, data ete. 8 questions relate to two paragraphs with two questions on each paragraph. Each question of a paragraph has only. one correct answer among the four choices (A), (B), (C) and (0). 30) Paragraph for Q.12 & Q.14 Analysis of dissolved oxygen in river water is very essential to ensure that aquatic life is safe. As per european standards dissolved oxygen should never be less than 6.4 mg / lit and preferably should be greater than 9.6 mg /lit, A water body having value less than 6.4:mg /lit iseonsidered "heavily polluted” and a water body having value greater than 9.6 mg /lit, is considered optimum fit for aquatic life. One method to measure dissolved oxygen is through Winkler titration, The method involves three stages. Stage-1 : The water sample is treated with excess of a solution of Mn™* (aq) along with a base to cause the following reaction Mn’™* (ag) + 20H” (aq) > Mn(OH), (s) @ —— 912. 13. 14, JEE-Chemistry The precipitate then reacts with dissolved oxygen as shown, 1 2Mn(OH), (8) + 5 O, (aq) + H,O (4) > 2Mn(OH), (s) oii) Stage-2 : The solution is added with excess of acidified solution of KI to cause following reaction, 2Mn(OH), (s) + 2KI + 3H,SO, > 2MnSO, + K,SO, + 1, (ag) + 6H,0 Stage-3 : The 1, produced is calculated by the following reaction by calculating amount of Na,S,O, ii) consumed. I, + 2Na,$,0, > 2Nal + Na,S,O, a Civ) Using the above information answer the questions, If | litre of water sample is taken then calcula the sample is considered "heavily polluted’ (A)80ml (B) 80 litre (© 120ml (D) 120 titre maximum volume of 0.01 M Na,S,O, solution required if, If | litre of water sample is taken, then calculate minimum volume of 0.1 M Na,S,O, solution required if the sample is considered "optimum fit" for aquatic life (A) 8 ml (B) 80 ml (©) 12m1 (D) 120 mi Which of the statements is correct w:rst, above method ? (A) Greater the amount of dissolved oxygen lesser will be moles of Na,$,O, required. (B) Exces solution in stage- 1 ensures all dissolved oxygen teacts. (©) Moles of Mn(OH),(s) reacted and moles of Mn(QH)y formed will be different. (D) | mole of dissolved oxygen will require 2 moles 6f Na,$,, for estimation. SECTION-II: (Integer Value Correct Type) This section GOntains 3 questions. Thélanswer to each question is a single digit Integer, ranging from 0 to 9 (both inclusive) 4-1) 15. 16. 17. 2ml Tetrahedral lead, (CjH,), Pb, is mixed per litre of gasoline to prevent knocking in engine. How many moles of ethyl chloride, C,H,Cl, is needed to produce sufficient tetraethyl lead needed to be mixed with 25 L gasoline ? Density of tetraethyl lead is 6.48 gm /ml, (Pb = 208) 4CH,Cl + 4Na=Pb > (C;H,), Pb + 4NaCl + 3Pb A sample of K,8O, AL(SO,),.24H,0 contains 5 kg oxygen then calculate mass of sulphur (in kg) in same sample? Equivalent weight of Br, is 96 in the following disproportionation reaction: Br, + OH- > Br + H,O + ? (oxidized product) The oxidation state of Br in the oxidized product is (Br= 80)Guided Revision Plan SECTION-IV : Matrix-Match Type This Section contains 1 question. Question has four statements (A, B, C and D) given in Column I and five statements (P, Q, R, and 'T) in Column IL. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column IL, For example, if for a given question, statement B matches with the statements given in Q and R, then for the particular question, against statement B, darken the bubbles corresponding to Q and R in the ORS. 800) ALLEN 18. To find molarity of 2 separate solutions of KMnO, and ©,(0, > 0), a student titrate 20 ml of KMnO, (in neutral medium ) and 10 ml of O, separately using 3 reagents A, B & C , performing 3 different experiments for KMnO, and O, each, He found solarity of KMnO, and O 1 30 M 1 and 3g M respectively. A,B & Care FeCr,0, , CuFeS,, FeS respectively and their reactions are: (A) FeCr,0, > K,CrO, + Fe,0, (B) CuFeS, > Cut + Fe + SO, (C) FeS + Fe* + SO, Column-I represents solution of A, B, C used for titration Column-II represents mili moles of A, B.C consumed with KMnO, or with O,. Column I Column I ~ 3 (A) FeCr,O, Og 3 (B) CuFeS, QF (©) FeS R) 4 4 OTALLEN JEE-Chemistry ANSWER-KEY : Topic # Mole C SECTION-I : (i) Only One option correct Type: 3(-1) 1. Ans.(D) 2, Ans.(D) 3. Ans. (D) 4. Ans. (B) 5. Ans.(A) 6. Ans.(C) 7. Ans.(B) 8. Ans.(B) 9. Ans. QR; B) >PS3() QR