JEE (Main + Advanced) 2021 LEADER + ENTHUSIAST COURSE| CHEMISTRY, GRS-4 ‘SALT ANALYSIS. Matching List Type 1 x 3 Q. (Three list type questions) The following column I, Il, III represent the reactions between salt solutions and reagents which gives different colour of precipitate. Answer the questions that follow Column: - Salt in aqueous solution Column-II - Reagents Column-III - Colour of precipitate Column 1 Column = I Column 11 Salt in aqueous sol Reagen Colour of precipitate (NaS, (i) Cuso, (P) White precipitate (i) Na,S Gi) AgNO, (Q) Reddish Brown am Ka (ii) K.Cr,0, (R) Chocolate Brown (IV) K,{Fe(CN),] {iy) ZnSO, (S) Black precipitate Observe the following reaetions= AgCl(s) + NH, => [Ag(NH).}g + Chg fas a) Which of the following set of codéis CORRECT about the ‘X” ? (A) On mixing of aqueous solution of (1) and (ii) and followed by heating gives (X) (B) Mixture of (I) and (iv) gives (S) which is identical with (X) (C) Mixture of (IV) and (i) gives (S) which is identical with (X) (D) On mixing of aquéous solution of (II) and (ii) and followed by heating gives (X) CORRECT set of combination is- (AAD, Gi, Q (B) dM), (i),(R)—- (CVAD, Gv), P) (D) (IV), @), ) Which of the following set of combination is INCORRECT? (A) CD, Gi), (S) (B) 0, @), (S) (©) AV), Giv), (P) (D) ID), (iv), (P) Only Single Correct : 4 Which of the following reaction cannot take place in reality ? (A) 5F + FO, + 6H* —> 3F, +3H,O (B) SCI + ClO, + 6H* —> 3C1, + 3H,0 (©) SBI + BrO, + 6Ht —> 3Br, + 3H,O (D) SI +10, + 6H* —> 31, + 3H,0 ——______—. 1Guided Revision Plan ALLEN In which of the following reaction, on standing violet colour produet disappears = (A) [Ni(en),]*? + $,0,> ——> (B) Fe** + 28,0 ——> (C) $*+ [Fe(CN),NOP > (D) Nal(ag,) + Cl, water — Identify the correct statement . (A) The ppt of BaCO, is insoluble in dil HCL (B) Hg(NO,), + Na,S > white ppt of HzS (C) Na,SO, + Hg(NO,), > yellow ppt of HgSO,.2Hz0 (D)H,S tums ime water milky 7. Anion which is protonated by dil. H,SO, but produce volatile product only with cone.H,SO, (not with diLH,SO,) (A) C,0, (B) PO, («© coe (D) SO> More than one may be correct : 8. Which of the following metal sulphides are insolublein yellow ammonium sulphide (VAS) ;- (A) HgS (B) CuS (Bis, (D) Su Which of the following reagent(s) can show eolour change when SO, gas ispassed through it. (A) Bromine water (B) Acidic potassium dichromate solution (© Acidic ferric chloride solution (D) Chlorine water 10. Methylene blue isan indicator widely used in acid-base titration , itis forined on mixing NH in ‘Mey (A) NaSO, (B)Nas (C) FeSO), (D) FeSO, 11, In which reaction(s) blood red eolorationis observed in product : (A) FeSO, 82... 5 Product (B) Na,$,0, 85... ®" Product (©) NISCN "="! Phoduot ©) No, —* Fe", Product Paragraph for Q.12 & Q.13 Chromy! chlorideis a deep red / brown coloured compound which is formed during qualitative analysis of chloride radical, Chloride salts (with some exceptions) produces chromyl chloride gas when reacted with K,Cr,0,(s) and cone. H,$0, 12, During chromyl chloride formation when chlorides salt is heated with cone, H,SO, + K,Cr,O, oxidation number of each Cr atom is : (A) Reduced to +3 (B) Reduced to +2 (C) Increased to +7 (D) Does not change 13. Bromide salt when heated with cone.H,SO, + K,Cr,O, (A) Brown vapour of CrO,Br, is produced (B) Brown vapour of Br, is produced (©) Brown vapour of SO,Br, (sulphuryl bromide) is produced (D) Br” salt does not react with K,Cr,O, 2 neJEE-Chemistry Paragraph Q.14 to Q.16 (A) HED, (a) Excess KL, (soluble complex) Ton pot ©) React with (x) reagent (Dy —Hxatolysed_, (5) Orange turbidity Black ppt. ByH.O 14, Identify (A) ion - ccr wr ©Br (D) Cu” 15. Whatis the hybridisation of central atom of (C) - (A) dsp? (B) spr Ospw (Dy sp* 16. When X reagent undergoes hydrolysis then - (A) White turbidity of SbOCL is formed. (B) White turbidity of BiO1 is formed (© White turbidity of BiOCI isformed (D) None of these MATCHING LIST TYPE 17. Match the followingllist:= List - I (Reaction) List I (Characteristic odour/product) (P) NOS. HCH (1) Coloured odd electron species (Q $,0,2 hte, (2) Vinegar stnell (R) HCo,2 AES (3) Yellowish-white turbidly (S) CH,COO® _ild1Ch, (4) Colourless gas comes out with brisk effervescence Code : ® Q@ B® A 4 °°3 1 2 28 24 1 3 @ tt Bee) oO 3 1 a2Guided Revision Plan ALLEN MATRIX MATCH 18. Match the column - Column-I (radical) Column-II (Correct characteristics) (A) Fe** (P) Produces white ppt with K [Fe(CN),] (B) Zn (Q Produces soluble complex in exce: NaOH solution ©cr (R) Gives redox reaction with Na,S,O, solution, (D) Ar (S) Produces corresponding hydroxide with Na,S solution, (T) Produces brownish—red ppt. with CH,COONa solution, 19. Column-I (Acidie/basic radical) Column-II (characteristics) (A) NO (P) Gives brown ring test (B) NOS (Q)Gives brown ppt. with Nessler's reagent (©) NHP (R) Gives black ppt. with (NH.),S (D) Fe (S) Gives red colouration with CH,COONa (T) Reduced to ammonia with Zn + conc.NaQH Integer Type : 20, How many of the following salton heating in bunsen burner flame gives characteristic green flame:~ BaCl, , CaCl, , “LiCl , NaCl , MgCl, 21, Find the total number of change in) which acidic medium is required : @ CO? —> Cr,0,* (i) MnO; + 10+ Mn, (i) Cr,0,°+H,S —>S+Cr" (iy) H,O,+ MnO, —> 0, + Mn** (%) CO; —> CO, 22, Chromate solution +H,0, 42% BES=€°" > permanent deep blue coloured compound. Find the change in,oxidation state of Cr-atom in the reactant and product. 4 ——————ALLEN JEE-Chemistry 13. 17. 18. 19. 20. Ans.(A) 2. Ans.(C) 3. Ans.(B) Ans.(A) F maximum show one covale! reality. so FO}-is not possible hence this reaction can not take place in Ans.(B) 6. Ans.(C) 7. Ans.(A) 8. Ans.(A,B,C) Ans.(A,B,C) 10. Ans.(B,C) 11. Ans(A,B,C,D) 12. Ans.(D) Ans.(B) 14. Ans.(B) 15. Ans.(D) 16. Ans.(C) Ans.(C) Ans.(A) - R, T ; (B) - P,Q; (C)- Q, S53 (D)-Q,S Ans.(A) - P, T; (B)- P, T;(C)-Q3(D)-R,S Ans.(1) 21. Ans.(4) 22. Ans.(0)