Feo ALLEN ° GUIDED SEE (Main + Advanced) 2021 [Peo oes EOUNGENERETUN CAREER INSTITUTE REVISION LEADER + ENTHUSIAST COURSE| CHEMISTRY, GRS-6 CARBOXYLIC ACID & AROMATIC SECTION-I : (i) Only One option correct Type This section contains 8 multiple choice questions. ach question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct 3-1) ‘The relative yield of the following alkenes produced by the reaction of I-chloro-(Z)-1, 2-dimethyleyclohexane with KOH/heat is ® Cy Gi) cy Gi er (A) i> ii > ili (B) ii > ih >i © i> itt> ii (D) iti >i i (@) NaOCH2CHg, Ethanol i) Nal , Ethanol ci o cron, locn , — eS Kem, ti Which of the following is the final product, of the séries of reactions shwon above : ) ° il i (a) Operon ott i @) Cyrano eigen, q © Opie rie ton 3 qk (D) CHy—C—CH—C—OHGuided Revision Plan_(For Advanced) ALLEN An organic compound on reaction with 2,4 — dinitrophenyl hydrazene (2,4 -DNP) gives a yellow ppt. It also gives silver mirror with ammonical AgNO,. It gives an alcohol and sodium salt of carboxylic acid on reaction with concentrated NaOH. It yields benzene =1,2 — dicarboxylic acid on heating with alkaline KMnO,. ‘The structure of the compound among the following is @ @) CL ‘CHO oF 1 o OC oO (oH coors b Nou 1 wt \ — Dea, Major product ofthe, reaction is NO NO» ns es (A) HO- {\ (B) MeO {\ ©) Noy No NO» Nos aN ON cy (Ho <\ (©) Meo c\ HyJEE-Chemistry ‘The relative acidity of the indicated H in each of the following is g es, 0 heroes 6 4, Son! Xe HC (A) i> i> iii (B) ii > ii >i (i> iti>ii () iti >i >i ‘The correct statement for the given reaction is choot yy ae (A) Y is optically inactive due to external compensation’ (B) Y is optically inactive due to internal, compensation (© X is predominantly cis-alkene (D) ¥ does not have chiral centres CH, CH, -CH-CH,-CH, when X undergoes monochlorination and then thé products fromed undergo fractional distillation, the number of fractions obtained is: @l Bz 3 (D4 Oo + CHCl, + AIC], —>>& (excess) X+NBS——> sy Hurolysis, 7 Correct option regarding X, Y, (A) Z when reacts with lucas reagent, white turbidity is formed within 5-10 minutes. (B) Maximum number of benzonoid structures X ean have is two. © 4% when reacts with PCC, benzophenone is formed as product. (D) ¥ when reacts with silver nitrate, white precipitate is formed instant.Guided Revision Plan_(For Advanced) SECTION-IGii) : One or More than one ALLEN This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE or MORE are correct. 4-1) 10. Identify correct reaction set(s) ? oot Br + Oy 0 “Nor Hs. Av be a) + Base s. a cr MeOH Boaz ——> eo 3 ° HgC. OH OHAg’ H3C, CO3H © Ye a Br oe ©, @) ATE Base ple cl —— 3° Oo Consider following sequence of factions ‘OMe Solid NOP) SalH@1_, NaNOwiHICl Ke (DH0*, i Ne 4 le WHC, y KEN g mi in Which of the following statement(s) is/are correct. ? (A) Formation of product P involves electrophilic aromatic substitution, 0 (B) Product. T may be ) (©) Compound R is unstable at temperature > 25°C. (D) Compound Q can give positive carbyl amine Test. —— 9ALLEN, JEE-Chemistry ad 12. Predict correct orders among the following ? “ o > me > Cd » (resonance energy). ° | H (B) B-D-glucopyranose > a—D-glycopyranose > open chain form of D-glucose (stability), a ol a a No, © > > > (©) Aromatic Nucleophilic substitution), No, NO, NO, (D) GF, >CH, (% p character in orbital having unpaired electron). Consider the reaction given below :- oO ao (Major product (9) Select, the correct statement(s) (A) The major product gives efférveseénce with NaHGO, solution (B) (X) decolourises, Br, © Formation of major product involves nugleophilic attack water (D) The given reaetion ihyolves nucleophilic Substitution.Guided Revision Plan_(For Advanced) SECTION-I (iv) Table Type s 3 questions of matching type. This section contains One tables (cach having 3 columns and 4 rows) Based on each table, there are THREE questions Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct For each question, darken the bubble corresponding to the correct option in the ORS. ALLEN This section contai For each question, marks will be awarded in one of the following categories Full Marks : +3. If only the bubble corresponding to the correct option is darkened. Zero Marks 0. If none of the bubbles is darkened. Negative Marks _: -1_Inall other cases Answer Q.13, Q.14 and Q.15 by appropriately matching the information given in the three columns of the following table. Column I Column IT Column II Me MeCH,CH,CH,Cl ao aay cae (A) Only one organic (P)_Carboeation is formed . product is formed a8 intermediate NO, (@) NaOH wo eorae (B) Product. is optically @ Carbanion is formed active as intermediate } Red P (limited) (UD CH,CH,COOK: (C) This process involves (R) Free radical is, Br, dea) nucleophite substitution formed as reaction at one of the intermediate carbon COOH av) cHy Nig SSCAEC, —(D) This process involves (S)_Nitrene is formed as u electrophle substitioun intermediate reaction at one of the carbon 13. Which of the following option is correctly matched A) 0,O).) (8) QD, D), @ (© dy, &,® — ) AV), ®, 6) 14, Select incorrect match A) @, ©), ®) ®) a), A), @ (©) (UD, @B), RB) (D) None of these 15. Product of (III) can be converted into product. of (IV) by : (A) NaNO, + HCI (B) aq. KOH followed by H (©) NH, (D) AgNO, 6 —_—_—_—_——sJEE-Chemistry SECTION-II : Integer Type This section contains 2 questions. The answer to each question is a single digit Integer, ranging from 0 to 9 (both inclusive). 4D 2 Br /FeBr 3 > products. 4 16. S G major organie product will have Bromine at position. 3 17. Consider following sequence of reactions 6 0 H,O* c oi D pH, 5 ‘Total sum of degree of unsaturations of product,.D_& 1 will be.Guided Revision Plan_(For Advanced) ALLEN ANSWER-KEY_ CARBOXYLIC ACID & AROMATIC COMPOUND SECTION-I : i) Only One option correct Type : 3-1) 1. Ans.(D) 2. Ans.(C) 3. Ans.(C) 4. Ans.(D) 5. Ans.(D) 6 AnsiA) 7. Ans.(D) 8. Ans.iC) SECTION-I(i) : One or More than one: 4(-1) 9. Ans.(A,B.D) 10. Ans.(A,B,C,D) 11, Ans.(A,B,C) nen oH g 2. ansiawo-sa.0 “ OH SECTIONAL (iv) Table Type : 3-1) 13. Ans.(A) 14. Ans.C) 15. _Ans.(B) SECTION-II : Integer Type : 4(-1) 16. Ans.(4) 17. Ans.)