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The following example from the textbook shows how you can solve such problems without having
to use anything other than the Ideal Gas Law in its normal form.
Example: A sample of gas was placed in a sealed container at 300 K. The pressure of the
gas was found to be 1.00 atm. If this container was then heated to a temperature of 400 K,
what would be the pressure exerted by the gas in the container at this new temperature?
First, note that the same container is used at both temperatures and it contains the same
sample of gas. Thus V2 =
Let’s make a list of the data we know for each set of conditions, (which I will refer to
as Expt. 1 and 2):
T1 = 300 K T2 = 400 K
P1 = 1.0 atm P2 = ?
V1 = ? V2 = ?
n1 = ? n2 = ?
P1V1 = n1RT1 P2V2 = n2RT2
Let’s assume the volume of the container that was used was exactly 1 L. This means
that only one unknown remains for Expt. 1 – the number of moles present in our 1 L
container. Solving for the number of moles gives
n
1 atm 1 L 0.0406 moles
0.0821 L-atm/mol-K 300K
Note that the same sample was used in the same container under the conditions given
for the 2nd experiment. Thus, n2 = n1 = n = 0.0406 moles. The only unknown left for
Expt. 2 is the pressure when the temperature is raised to 400 K:
PV nRT P2 1 L 0.0406 moles 0.0821 L-atm/mol-K 400K
The example below shows a case where we cannot make any assumptions, because only one
unknown exists for one of the sets of conditions. It is actually a straight-forward use of the
Ideal Gas Law. The only “wrinkle” is that you must realize that the same sample of gas is
used with both sets of conditions.
– 10 – Raynor: 7/30/2021
RT RT RT
PA nA , PB nB , PC nC , (29)
V V V
Note that the factor given by (RT/V) will be the same for all the gases. We need only calculate it
once. Then, the partial pressures of each gas can simply be found by multiplying that factor by the
number of moles of that particular gas.
Example: A 0.13 g sample of an unknown gas is collected over water at 30 C. It is found that
this gas occupied 85 mL at an atmospheric pressure of 750 mmHg. Calculate the molar mass of
this gas.
First, we need to look up the vapor pressure of water at 30 C. It is discovered that its vapor
pressure is 31.82 mmHg at that temperature. We can now use this information to determine
the partial pressure exerted by the unknown gas:
PTOT = Punk + Pwater
750 mmHg = Punk + 31.82 mmHg
Punk = 718 mmHg × (1 atm / 760 mmHg) = 0.945 atm
Now we can use the Ideal Gas Law to determine the number of moles of unknown gas that is
present:
n = PV / RT = (0.945 atm) (0.085 L) / (0.0821 L-atm/mol-K) (303 K)
n = 3.2 × 10–3 mol
Since we were given the mass of this sample, 0.13 g, and we now know how many moles of
molecules are within that sample, we can determine its molecular weight:
MW = 0.13 g / 3.2 × 10–3 mol = 41 g/mol
The next example demonstrates Dalton’s Law when combined with a chemical reaction.
Example: Initially a flask contains N2 and H2 with partial pressures of 0.300 atm and 0.850 atm,
respectively. What will be the total pressure and the partial pressures of N2, H2 and NH3 after the
following reaction is complete: N2 + 3 H2 → 2 NH3. [Assume the temperature remains constant.]
Since all gases are in the same container, at the same temperature, we can note that the
partial pressures of each gas will be proportional to the number of moles of that gas:
PA = nA (RT / V) = nA × c [where c is the same constant for all gases]
We can therefore use the stoichiometry in terms of the partial pressures – i.e., if 1.0 atm of
N2 reacts with 3.0 atm of H2, they will form 2.0 atm of NH3.
First, we need to determine the limiting reagent by calculating the amount of NH3 that would
form if all of each gas was consumed:
– 11 – Raynor: 7/30/2021
If all the N2 reacts, then we get 0.300 atm N2 × (2 atm NH3 / 1 atm N2) = 0.600 atm
NH3 formed
If all the H2 reacts, then we get 0.850 atm H2 × (2 atm NH3 / 3 atm H2) = 0.567 atm
NH3 formed
Thus, H2 will be the limiting reagent – it will form the least amount of product. We can now
immediately conclude the following final values for the partial pressures of H 2, (which will
be all used up), and of NH3:
PH2 = 0 atm
PNH3 = 0.567 atm
Before we can determine the partial pressure due to excess N2 that is present, we first need to
determine how much of it will react, (using the stoichiomety):
PN2 reacted = 0.850 atm H2 × (1 atm N2 / 3 atm H2) = 0.283 atm N2 reacted
The amount of N2 remaining will be the difference between the amount we started with and
the amount that reated:
PN2 remaining = 0.300 atm – 0.283 atm = 0.017 atm
PTOT = PN2 + PH2 + PNH3 = 0.017 + 0.000 + 0.567 atm = 0.584 atm
An alternative approach would be to choose any values you like for the temperature and
volume and then convert all the partial pressures into moles, using
nA = PA (V / RT)
Then use moles to find the limiting reagent, determine the amount of NH3 formed and the
moles N2 remaining. Finally, using the same values of T and V, convert the moles back into
partial pressures:
PA = nA (RT / V)
This route requires far more calculations, but will ultimately lead to the same final results.
[Try it on your own using V = 1 L and T = 100 K, or any values you like.]
– 12 – Raynor: 7/30/2021
Example: [Example 5.4 in textbook]
Calculate the volume in L that is occupied by 7.40 g of NH3 at STP.
For either method, the 1st step, (as always!), is to convert the mass of NH3 into moles NH3,
using its molar mass:
7.40 g NH3 × 1 mol NH3 / 17.03 g NH3 = 0.434 mol NH3
If you use the fact that 1mol occupies 22.4 L at STP as a conversion factor, you get
0.434 mol NH3 × 22.4 L / 1 mol = 9.73 L
Alternatively, we can use the Ideal Gas Law directly, using T = 273 K and P = 1 atm:
(1 atm) V = 0.434 mol × 0.0821 L-atm/mol-K × 273 K
V = 9.73 L
Notice that we get the same result, without memorizing that 1 mol of gas occupies 22.4 L at
STP. This relationship is true ONLY at STP – not at other temperatures or pressures. [If we
ask the same question, but at room temperature, (298 K), then we get V = 10.6 L instead!
Try it on your own!]
– 13 – Raynor: 7/30/2021