PH V - Sankalp022 PCM - 23-6-2021-Adv-P2

(PANINI-eSANKALP022AP1A, AP1-AP8, CP1-DP1, PH1)
IIT – JEE, 2022

PAPER II (PHASE – V)
Time: 3 Hours Maximum Marks: 216
INSTRUCTIONS
A. Question Paper Format

The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of two sections.
1. Section 1 contains 6 Integer Answer Type Questions ranging from 0 – 9.
2. Section 2: contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which One
Or More Than One are correct.
3. Section 3 contains 6 Numerical answer type questions with answer XXXXX.XX and each question carries +4 marks
for correct answer. There is no negative marking
B. Marking Scheme
4. For each questions in Section 1 and 3 : you will be awarded +4 marks for correct answer and no negative marking.
5. For each question Section 2: marks will be awarded in one of the following categories:
Full Marks : + 4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened.
Partial Marks : + 1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : – 2 In all other cases.
For example, if [A], [C] and [D] are all the correct options for a question, darkening all these three will get +4 marks;
darkening only [A] and [D] will get +2 marks; and darkening [A] and [B] will get -2 marks, as a wrong option is also
darkened.
Enrolment No. :
Name : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
IT-2022- eSANKALP022AP1A, AP1-AP8, CP1-DP1, PH1–PH-V -PCM-P2--2
PART I: PHYSICS
SECTION – 1: (Only Integer Value Correct Type)
This section contains 6 questions. Each question, when worked out will result in one integer
from 0 to 9 (both inclusive).
1. A disk of radius a/4 having a uniformly distributed charge 6C is y
placed in the x-y plane with its centre at (a/2, 0, 0). A rod of
length a carrying a uniformly distributed charge 8C is placed on
x
the x-axis from x = a/4 to x = 5a/4. Two point charges 7C and
3C are placed at (a/4, a/4, 0) and (3a/4, 3a/4, 0), respectively.
Consider a cubical surface formed by six surfaces x =  a/2, y = 
a/2, z =  a/2. The |electric flux| through this cubical surface is
NC
. The value of N is
0
2. There is a non-conducting sphere of uniformly distributed charge +

+ +
density  insulated from surrounding. There is a cavity inside the sphere
B
as shown in figure. P is the centre of sphere and C is centre of cavity. + + A
+ P C
2
a +
Value of  VA  VC  is of the form , where k 0 is constant. Then value +
k 0 0 +
of k 0 will be? VA and VC are the electrostatic potential A and C. It is given
that PC  a, AB  a , BC  a , AB is parallel to PC and BC is

2 2
perpendicular to PC.
3. In the network of capacitors and resistances as shown in the d

figure, steady current I enters at junction ‘a’ and same current C1=C – + C3=C
C2=2C –
+
leaves junction b. Charge on capacitor C3 with shown polarity is b
+
KRC  a 
. Find K.
4 R 2R
c
4. The figure shows a RC circuit with a parallel plate capacitor. Before -Q0
switching on the circuit, plate A of the capacitor was given a charge A B
–Q0 while plate B had no net charge. a
Now, at t = 0, the circuit is switched on. How much time (in R
seconds) will elapse before the net charge on plate A becomes
2  106
zero. Take C = 1 F, Q0 = 1 mC,  = 1000 V and R = 
n  3  
5. The figure shows a circular ring of radius R = 0.5 m and mass A

y
0.5 kg. Part ABC and ADC carries uniform charge +C and
D B
C. When uniform electric field of 1 N/C î is applied and ring
x
is slightly rotated about its axis and released. Find the angular
C
frequency (in rad/sec) of small oscillation.
6. Two uniformly charged large plane sheets S1 and S2 having charge densities 1 and 2
 1   2  are placed at a distance d parallel to each other. A charge q is moved along a line of
length a (a < d) at an angle 45° with the normal to S1. Calculate the work done (in Joule) by the
electric field. (take  1   2  4 2 , a = 1m and q0 =  0 )

SECTION – 2: (One or More Than One Options Correct Type)
This section contains 6 multiple choice type questions. Each question has four choices (A), (B),
(C) and (D) out of which ONE or MORE THAN ONE are correct.
7. There is a system of four large parallel plates A, B, C, and

D. Plates A and C are connected to each other with the
d d d
help of metallic wire and plates B and D are connected to
the ground with the help of open switches S1 and S2.  2Q0
Q0
Q0
Distance between consecutive plates is d. Initially plates A
and B are having a charge of Q0 each and plate D is
having charge +2Q0 (See figure). At t = 0 switches S1 and
S2 are closed simultaneously. Then the magnitude of A B C D
charge flown through switch S1
(A) S1 is 5Q0 / 3 S2
(B) S1 is Q0
(C) S2 is 7Q0 / 3
(D) S2 is 2Q0
8. Figure shows an electric circuit contain four resistors of equal E E1 5A H

resistances 4. Cells E1, E2, E3 are ideal of unknown emf
7A 6A
where as cell E4 has some unknown internal resistance and A D
R
emf 4V. It is found that current through EA, DH, FB and HE are
7A, 6A, 2A and 5A respectively. R R E4
E2
(A) Internal resistance of E4 is 2
R
B C
(B) Current through DC is 0.5 A.
2A
(C) Current through AD is 5.5 A.
F E3 G
(D) E2 = 6V.
9. In the figure shown resistance of each

resistor are same. If current in AG is 5A A
B C D E F
then
(A) current in FL is 5 A
(B) current in BA is 15 A G H I J K L
(C) Current in AF is 10 A
(D) current in BH is 20 A
10. In the circuit shown in the figure C1 = C2 = C and capacitor C1 is having R

initial charge Q. The switch is closed at t = 0. Which of the following
options are correct. +
C1 C2

 Q  2t / RC
(A) The current at time t through the circuit will be  e
 RC 
Q
(B) The charge on capacitor C1 at time t will be
2

1  e 2t / RC 
Q
(C) The charge on the capacitor C2 at time t will be (1  e 2t / RC )
2
Q2
(D) Total heat loss in the process of charge transfer will be
8C
11. The figure shows, a graph of current in a discharging circuit of a i

capacitor through a resistor of resistance 10 . Choose the correct 10A
option(s)
(A) The initial potential difference across the capacitor is 100 Volts 2.5A
1 2s t
(B) The capacitance of the capacitor is F
10 ln 2
1000
(C) The total heat produced in the circuit is J
ln 2
500
(D) The total heat produced in the circuit is J
ln 2
12. Three capacitors each having capacitance C  2  F are S

connected to battery of emf 30 V as shown in the figure. When
the switch is closed.
(a) the amount of charge flow through the battery is 20  C
C
(b) heat generated in the circuit is 0.6 mJ C
C
(c) work done by the battery is 0.6 mJ
(d) the charge flow through the switch is 60  C
30V
SECTION – 3: (Numerical Value Type)

This section contains 6 questions. The answer of each question is a numerical value in a decimal
notation, truncated/rounding off to the second decimal place e.g.
1. The kinetic energy of charged particle decreases by 10 J as it moves from a point at potential 100 V
to a point at potential 200 V. Find the charge on the particle (in coulomb)
2. Each of the plates shown in figure has surface area (96 /  0 )  1012 F–m on one side and the
separation between the consecutive plats is 4.0 mm. The emf of the battery connected is 10 volts.
Find the magnitude of the charge (in C) supplied by the battery to each of the plates connected to
it.
3. A 5.0 µF capacitor is charged to 12 V. The positive plate of this capacitor is now connected to the
negative terminal of a 12 V battery and vice versa. Calculate the heat developed in the connecting
wires (in mJ).
2
4. A current of 1.0 A exists in a copper wire of cross-section 1.0 mm . Assuming one free electron per
atom calculate the drift speed (in mm/s) of the free electrons in the wire. The density of copper is
3
9000 kg/m .
5. Find the charge (in C) on each of the capacitors 0.20 ms after the switch S is closed in figure.
6. A voltmeter coil has resistance 50.0  and a resistor of 1.15 k  is connected in series. It can read
potential differences upto 12 volts. If this same coil is used to construct an ammeter which can
measure currents upto 2. 0 A, what should be the resistance (in ) of the shunt used?
PART II: CHEMISTRY

SECTION – 1: (Only Integer Value Correct Type)
This section contains 6 questions. Each question, when worked out will result in one integer
from 0 to 9 (both inclusive).
AlCl3 SeO2 Conc KOH/ 

1. Benzene + acetic anhydride  (A)  (B)   (P)
Degree of unsaturation present in P is ______
2. 0.344 gm of acetyl derivative of a polyhydric alcohol (Molecular Wt. of Alcohol = 92) require 0.336
gm KOH for complete hydrolysis. Calculate the number of hydroxyl groups in the alcohol.
3.
HCl Br2 /CCl4

R number of products     P number of achiral products
D D
Cold alkaline dil KMnO 4
Q number of products
Then the value of half of sum of P, Q and R is _____
+
4. Identify the most favourable site for the attack of H .
1 O
2
3
4 N
CH3
5. The molecular formula of an amine is C5H13N. How many C–N bond(s) is/are present in its most
basic isomer(in gas phase)?
6. How many following alcohols show positive iodoform test?

HO
CH2OH OH OH
OH
, , , , ,
CH 3-CH 2OH
OH
OH
, , ,
OH CH CH3
OH

7. The given compound by definition is
O
O
(A) Acetal
(B) Hemi-acetal
(C) Ether
(D) Ester
O O
|| * ||  
Br2  OH
8. R  C NH2  CH3CHD  C NH2  
 Mixture of 1o amines
(enantiomerically pure)
Which of the following statement(s) is/are correct for above reaction?
(A) A mixture of four different amines are formed confirming that a free carbonylnitrene
intermediate is formed
(B) A mixture of two amines are formed confirming that rearrangement is strictly
intramolecular
(C) If R is chiral, it migrates with retention of configuration
O
(D) A free carbonylnitrene H3C C N intermediate is formed and only two amines are
formed.
9. Which of the following process(es) will not produce 2° amine?

(A) Gabriel’s synthesis
(B) Hoffmann’s brom-amide reaction
(C) reduction of carbylamine
(D) Isopropyl nitrile +Sn/HCl
NH  CO , 
10.
4 2
Butan-1, 4-dial 
3
P  , then
(a) P is aromatic in nature
(b) P is antiaromatic in nature
O
N CH
(c) P on reaction with chloroform and sodium hydroxide gives H
Cl
(d) P on reaction with chloroform and sodium hydroxide gives N
11. Choose the correct statement(s) among following
O
(a) Ph C CH2 Br will react more readily by S 2 than S 1 reaction
N N
H3C H3C
CH3
CH3
- CH3
(b) O +
will react more readily than -
when heated to form an alkene.
N O +
N CH
H3C H3C 3
Br Br
(c) will react more readily than for SN1 reaction
Br
(d) Br will react more readily than for E2 reaction
12. Which of the following will not be hydrolysed in basic medium
CH3  CN
(a) (b)
O O
O O O
|| ||
(c) (d)
H3C C O CH2 CH3 CH3  C  O  C  CH3

1. Ratio of the total number of carbon atoms to that of the total number of nitrogen atoms
present in a molecule of “BRADY’S REAGENT” is ________
2. Consider the following compound(s):
CHO O O
CHO
O
; ; H2C C CH2 CH3 ; ;
OH O O
O
; H3C CHO ; ;
O OH
Let, the total number of compound(s) which gives positive silver mirror test be x, and the
total number of compounds that gives positive Fehling’s test be ‘y’ then the value of (x/y)
is _______
3. Consider the following reactions:

conc. H2SO4 conc. H2SO4
(i) Acetone (ii) Ethanal
O
conc. HCl (1 eqvt)

(NH4)2CO3
(iii) Hexan-2, 5-dione (iv)
O
OH
dil.KOH conc. H2SO4

(v) CH 3CHO +HCHO
(vi) OH
(excess) HO
OH KHSO4
conc. H2SO4
(vii) (viii) CH2OH
CH-OH
OH
CH2-OH
O
CH2-OH oxalic acid (x) HCl

(ix)
CH-OH 110C
CH2-OH
Let, the number of reaction(s) giving aromatic product(s) be ‘x’ and the number of
reaction(s) giving aliphatic product(s) be ‘y’, then the value of (x/y) is ______
4. Benzaldehyde on heating with ethanolic KCN forms a product which on oxidation with
PCC/CH2Cl2 followed by heating with conc, KOH solution gives a major product (x).
Ratio of degree of unsaturation to the number of rings in a molecule of ‘x’ is ______
5. Consider the following Reaction

O
CH3 anhyd. MCPBA (excess)

major product (A)
[where MCPBA is meta chloroperoxybenzoic acid]

Ratio of degree of unsaturation of (A) to the total number of carbon atoms present in a
molecule of A; is________
6. Formalin” is 40% aqueous solution of a compound (x). Find the mass percentage of
oxygen in a molecule of ‘x’. [Round-off the answer upto the 2nd place of decimal]
PART III: MATHEMATICS


11. If f(x) = |x  a| (x), where (x) is continuous function, then

+ +
(A) f(a ) = (a) (B) f(a) = (a) (C) f(a ) = f(a) (D) None of these
 
1/ 3 x2
12.  2
If lim p tan qx  3cos x  4
2
  e5 / 3 ; p, q  R then :
x 0
1 1
(A) p  2, q  (B) p , q  2 2 (C) p = 1, q = 2 (D) p = 2, q = 4
2 2 2

xf 2   2f x 
1. If f(2) = 2 and f (2) = 1, then the value of Lim is equal to __________
x 2 x2
2. The number of points where f(x) = [sinx + cos x] (where [ ] denotes the greatest integer function),
x  ( 0, 2) is not continuous is __________
2 3
3. A function f(x) is defined for x > 0 and satisfies f(x ) = x  x > 0, then find the value of f(4).
a b  2
4. If a, b, c, x > 0 tan1  tan1  , then find the value of x – ab.
x x 2
 x 
5. Let f(x) = nx + n  [nx + n] + tan   where [x] is the greatest integer  x and n  N. Find the
 2 
period of f(x).
6. If f(x) be a continuous function defined for 1  x  3. If f(x) attains only rational values for all x  [1,
3] and f(2) = 5, then find the value of f(1.8).
(PANINI-eSANKALP022AP1A, AP1-AP8, CP1-DP1, PH1)
IIT – JEE, 2022

PAPER II (PHASE – V)
ANSWERS
PHYSICS (PART-I)
SECTION – 1
1. 7
2. 2
3. 4
4. 2
5. 6
6. 2
SECTION – 2
7. A, C
8. A, B, C, D
9. A, B, C, D
10. A, B, C
11. A, B, D
12. A, C, D
SECTION – 3
1. 0.1
2. 0.14 to 0.18
3. 1.40 to 1.50
4. 0.074 to 0.076
5. 9.0 to 9.30
6. 0.24 to 0.26
CHEMISTRY (PART-II)
SECTION – 1
1. 5
2. 6
3. 5
4. 1
5. 3
6. 6
SECTION – 2
1. A, C
2. B, C
3. A, B, D
4. A, C, D
5. A
6. B
SECTION – 3
1. 1.50
2. 1.25
3. 1.50
4. 4.50
5. 0.50
6. 53.33
MATHEMATICS (PART-III)
SECTION – 1
1. 3
2. 4
3. 2
4. 1
5. 1
6. 1
SECTION – 2
7. A, B, C, D
8. A, B, C, D
9. A, B, C, D
10. A, B, C
11. A, B
12. B, C
SECTION – 3
1. 0.00
2. 5.00
3. 3.00
4. 0.00
5. 2.00
6. 5.00

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(PANINI-eSANKALP022AP1A, AP1-AP8, CP1-DP1, PH1)

IIT – JEE, 2022

A. Question Paper Format

Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .

1. A disk of radius a/4 having a uniformly distributed charge 6C is y

2. There is a non-conducting sphere of uniformly distributed charge +

that PC  a, AB  a , BC  a , AB is parallel to PC and BC is

3. In the network of capacitors and resistances as shown in the d

5. The figure shows a circular ring of radius R = 0.5 m and mass A

electric field. (take  1   2  4 2 , a = 1m and q0 =  0 )

7. There is a system of four large parallel plates A, B, C, and

8. Figure shows an electric circuit contain four resistors of equal E E1 5A H

9. In the figure shown resistance of each

10. In the circuit shown in the figure C1 = C2 = C and capacitor C1 is having R

11. The figure shows, a graph of current in a discharging circuit of a i

12. Three capacitors each having capacitance C  2  F are S

SECTION – 3: (Numerical Value Type)

PART II: CHEMISTRY

AlCl3 SeO2 Conc KOH/ 

HCl Br2 /CCl4

6. How many following alcohols show positive iodoform test?

SECTION – 2: (One or More Than One Options Correct Type)

7. The given compound by definition is

9. Which of the following process(es) will not produce 2° amine?

(d) P on reaction with chloroform and sodium hydroxide gives N

11. Choose the correct statement(s) among following

12. Which of the following will not be hydrolysed in basic medium

SECTION – 3: (Numerical Value Type)

2. Consider the following compound(s):

3. Consider the following reactions:

conc. HCl (1 eqvt)

dil.KOH conc. H2SO4

CH2-OH oxalic acid (x) HCl

5. Consider the following Reaction

CH3 anhyd. MCPBA (excess)

[where MCPBA is meta chloroperoxybenzoic acid]

PART III: MATHEMATICS

SECTION – 3: (Numerical Value Type)

11. If f(x) = |x  a| (x), where (x) is continuous function, then

SECTION – 3: (Numerical Value Type)

(PANINI-eSANKALP022AP1A, AP1-AP8, CP1-DP1, PH1)

IIT – JEE, 2022

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