Cp Constant DHvap DHf

Component Tb (K) Tc (K)

A B C D (kJ/kmol) (kJ/kmol)
NH3 27.315 2.38E-02 1.71E-05 ### 239.65 405.6 23362 -45900
N2 31.150 ### 2.68E-05 ### 63.25 126.2 5581 0
H2 27.143 9.27E-03 ### 7.65E-09 20.35 33.2 904 0
B.2.1 Energy Balance around Mixer, M-1

Stream 18

Stream 1 Stream 3
Stream 2

M-1

Operating condition :

Temperature Temperature Pressure 4

Stream 3 Phase
(°C) 2 (K)1 M-1 (atm)
1 25.00 298.15 60.00 Vapor
2 25.00 298.15 60.00 Vapor
3 -22.81 250.34 59.97 Vapor
18 -41.86 231.30 59.97 Vapor

Assumption :
1. Adiabatic compressing (no heat loss in process of compressing)
2. Reference temperature : 25 °C
3. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= ΣΔHk(out) - ΣΔHk(in)
where Q = Heat duty
ΣΔHk(out) = Σnk(out)Hf,k(out) + Σnk(out) ∫Cp,kdT
ΣΔHk(in) = Σnk(in)Hf,k(in) + Σnk(in) ∫Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference

Stream Flowrate òCpdT DHf DHV

Component
(inlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
1 N2 380.1200 0.0000 0 0.0000
2 H2 1140.3000 0.0000 0 0.0000
18 NH3 46.0400 -2313.3687 -45900 -2219743.4957
N2 849.6100 -1954.0110 0 -1660147.3229
H2 2572.0000 -1923.3943 0 -4946970.2288
Total -8826861.0474
Stream Flowrate òCpdT DHf DHV
Component
(outlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
3 NH3 46.0400 -1668.1522 -45900 -2190037.7270
N2 1230.5000 -1396.4576 0 -1718341.0159
H2 3712.4000 -1377.1397 0 -5112493.2706
Total -9020872.0135

Heat duty (kJ/hr) = -194010.97 kJ/hr

 A B C D T (K)
31.150 -1.356E-02 2.679E-05 -1.168E-08 298.1500
27.143 9.27E-03 -1.38E-05 7.65E-09 298.1500
27.315 2.38E-02 1.71E-05 -1.18E-08 231.2950
31.150 -1.36E-02 2.68E-05 -1.17E-08 231.2950
27.143 9.27E-03 -1.38E-05 7.65E-09 231.2950
 A B C D T (K)
27.315 2.38E-02 1.71E-05 -1.18E-08 250.3400
31.150 -1.36E-02 2.68E-05 -1.17E-08 250.3400
27.143 9.27E-03 -1.38E-05 7.65E-09 250.3400
To (K)

298.15
298.15
298.15
298.15
298.15
To (K)

298.15
298.15
298.15
B.2.2 Balance around Compressor, C-2

Stream 3 Stream 4

C-2
Operating condition :

Temperature Temperature Pressure

Stream Phase
(°C) (K) 2 (atm)
1 E-1
3 -22.81 250.34 59.97 Vapor
4 108.15 381.30 172.74 Vapor

Assumption :
1. Adiabatic compressing (no heat loss in process of compressing)
2. Reference temperature : 25 °C
3. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= ΣΔHk(out) - ΣΔHk(in)
where Q = Heat duty
ΣΔHk(out) = Σnk(out)Hf,k(out) + Σnk(out) ∫Cp,kdT
ΣΔHk(in) = Σnk(in)Hf,k(in) + Σnk(in) ∫Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference

Stream Flowrate òCpdT DHf DHV

Component
(inlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
3 NH3 46.0400 -1668.1522 -45900 -2190037.7270
N2 1230.5000 -1396.4576 0 -1718341.0159
H2 3712.4000 -1377.1397 0 -5112493.2706
Total -9020872.0135

Stream Flowrate òCpdT DHf DHV

Component
(outlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
4 NH3 46.0400 3069.8481 -45900 -1971900.1954
N2 1230.5000 2426.8046 0 2986183.0846
H2 3712.4000 2411.0888 0 8950925.9232
Total 9965208.8123

Heat duty (kJ/hr) = 18986080.83 kJ/hr

 A B C D T (K)
27.315 2.38E-02 1.71E-05 -1.18E-08 250.3400
31.150 -1.36E-02 2.68E-05 -1.17E-08 250.3400
27.143 9.27E-03 -1.38E-05 7.65E-09 250.3400

A B C D T (K)
27.315 2.38E-02 1.71E-05 -1.18E-08 381.3000
31.150 -1.36E-02 2.68E-05 -1.17E-08 381.3000
27.143 9.27E-03 -1.38E-05 7.65E-09 381.3000
To (K)

298.15
298.15
298.15

To (K)

298.15
298.15
298.15
B.2.3 Balance around Exchanger, X-3

Stream 4 Stream 5

X-3

Operating condition :
1
2
Temperature Temperature Pressure
Stream
(°C) X-1
(K) (atm)
Phase

4 108.15 381.30 172.74 Vapor

5 450.00 723.15 172.71 Vapor

Assumption :
1. Reference temperature : 25 °C
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= ΣΔHk(out) - ΣΔHk(in)
where Q = Heat duty
ΣΔHk(out) = Σnk(out)Hf,k(out) + Σnk(out) ∫Cp,kdT
ΣΔHk(in) = Σnk(in)Hf,k(in) + Σnk(in) ∫Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference

Stream Flowrate òCpdT DHf DHV

Component
(inlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
4 NH3 46.0400 3069.8481 -45900 -1971900.1954
N2 1230.5000 2426.8046 0 2986183.0846
H2 3712.4000 2411.0888 0 8950925.9232
Total 9965208.8123

Stream Flowrate òCpdT DHf DHV

Component
(outlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
5 NH3 46.0400 17995.4947 -45900 -1284723.4239
N2 1230.5000 12660.7749 0 15579083.4965
H2 3712.4000 12438.1729 0 46175473.0605
Total 60469833.1331

Heat duty (kJ/hr) = 50504624.32 kJ/hr

 A B C D T (K)
27.315 2.38E-02 1.71E-05 -1.18E-08 381.3000
31.150 -1.36E-02 2.68E-05 -1.17E-08 381.3000
27.143 9.27E-03 -1.38E-05 7.65E-09 381.3000

A B C D T (K)
27.315 2.38E-02 1.71E-05 -1.18E-08 723.1500
31.150 -1.36E-02 2.68E-05 -1.17E-08 723.1500
27.143 9.27E-03 -1.38E-05 7.65E-09 723.1500
To (K)

298.15
298.15
298.15

To (K)

298.15
298.15
298.15
B.2.4 Balance around Reactor, R-4

Stream 5 Stream 6

R-4
Operating condition :

Temperature Temperature Pressure

Stream 1 2 Phase
(°C) (K)
R-1 (atm)
5 450.00 723.15 172.71 Vapor
6 450.00 723.15 172.68 Vapor

Note that the heat of reaction is automatically incuded in calculating the stream enthalpy
Assumption :
1. Reference temperature : 25 °C
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= ΣΔHk(out) - ΣΔHk(in)
where Q = Heat duty
ΣΔHk(out) = Σnk(out)Hf,k(out) + Σnk(out) ∫Cp,kdT
ΣΔHk(in) = Σnk(in)Hf,k(in) + Σnk(in) ∫Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference

Stream Flowrate òCpdT DHf DHV

Component
(inlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
5 NH3 46.0400 17995.4947 -45900 -1284723.4239
N2 1230.5000 12660.7749 0 15579083.4965
H2 3712.4000 12438.1729 0 46175473.0605
Total 60469833.1331

Stream Flowrate òCpdT DHf DHV

Component
(outlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
6 NH3 788.5100 17995.4947 -45900 -22002981.4722
N2 859.2200 12660.7749 0 10878390.9971
H2 2598.7000 12438.1729 0 32323079.9058
Total 21198489.4307
Heat duty (kJ/hr) = -39271343.7 kJ/hr
lculating the stream enthalpy

A B C D T (K)
27.315 2.38E-02 1.71E-05 -1.18E-08 723.1500
31.150 -1.36E-02 2.68E-05 -1.17E-08 723.1500
27.143 9.27E-03 -1.38E-05 7.65E-09 723.1500

A B C D T (K)
27.315 2.38E-02 1.71E-05 -1.18E-08 723.1500
31.150 -1.36E-02 2.68E-05 -1.17E-08 723.1500
27.143 9.27E-03 -1.38E-05 7.65E-09 723.1500
To (K)

298.15
298.15
298.15

To (K)

298.15
298.15
298.15
B.2.5 Balance around Expander, E-5

Stream 6 Stream 7

E-5
Operating condition :

Temperature Temperature Pressure

Stream Phase
(°C) (K) (atm)
1
6 450.00 723.15 172.68 Vapor
2
7 372.22 645.37
E-1 90.00 Vapor

Assumption :
1. Adiabatic expending (no heat loss in process of expanding)
2. Reference temperature : 25 °C
3. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= ΣΔHk(out) - ΣΔHk(in)
where Q = Heat duty
ΣΔHk(out) = Σnk(out)Hf,k(out) + Σnk(out) ∫Cp,kdT
ΣΔHk(in) = Σnk(in)Hf,k(in) + Σnk(in) ∫Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference

Stream Flowrate òCpdT DHf DHV

Component
(inlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
6 NH3 788.5100 17995.4947 -45900 -22002981.4722
N2 859.2200 12660.7749 0 10878390.9971
H2 2598.7000 12438.1729 0 32323079.9058
Total 21198489.4307

Stream Flowrate òCpdT DHf DHV

Component
(outlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
7 NH3 788.5100 14276.3382 -45900 -24935573.5868
N2 859.2200 10274.9338 0 8828428.5811
H2 2598.7000 10145.4464 0 26364971.6126
Total 10257826.6070

Heat duty (kJ/hr) = -10940662.8 kJ/hr

 A B C D T (K)
27.315 2.38E-02 1.71E-05 -1.18E-08 723.1500
31.150 -1.36E-02 2.68E-05 -1.17E-08 723.1500
27.143 9.27E-03 -1.38E-05 7.65E-09 723.1500

A B C D T (K)
27.315 2.38E-02 1.71E-05 -1.18E-08 645.3700
31.150 -1.36E-02 2.68E-05 -1.17E-08 645.3700
27.143 9.27E-03 -1.38E-05 7.65E-09 645.3700
To (K)

298.15
298.15
298.15

To (K)

298.15
298.15
298.15
B.2.6 Balance around Exchanger, X-6

Stream 7 Stream 8

X-6
Operating condition :
1
2
Temperature Temperature Pressure
Stream Phase
(°C) (K) (atm)
7 372.22 X-1
645.37 90.00 Vapor
8 -23.00 250.15 89.97 Mixture

Assumption :
1. Reference temperature : 25 °C
2. Estimated η = 0.38
3. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= ΣΔHk(out) - ΣΔHk(in)
where Q = Heat duty
ΣΔHk(out) = Σnk(out)Hf,k(out) + Σnk(out) ∫Cp,kdT
ΣΔHk(in) = Σnk(in)Hf,k(in) + Σnk(in) ∫Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
4. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc

Stream Flowrate òCpdT DHf DHV

Component
(inlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
7 NH3 788.5100 14276.3382 -45900 -24935574
N2 859.2200 10274.9338 0 8828429
H2 2598.7000 10145.4464 0 26364972
Total 10257827

Stream Flowrate (kmole/hr) òCpdT DHf

Component
(outlet) Liquid Vapor (kJ/kmole) (kJ/kmole)
8 NH3 701.4600 87.0520 -1674.643 -45900
N2 0.9983 858.2200 -1402.015 0
 H2 0.6424 2598.0000 -1382.596 0

DHvap(Tb) DHvap(T) DHL DHV

Component
(kJ/kmole) (kJ/kmole) (kJ/hr) (kJ/hr)
NH3 23362 22788.8882 -49357203 -4141468
N2 5581 0.0000 -1399.576 -1203238
H2 904 0.0000 -888.1384 -3591985
Total -49359490 -8936691

Heat duty (kJ/hr) = -68554007.4 kJ/hr

 A B C D T (K) To (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 645.3700 298.15

31.150 -1.36E-02 2.68E-05 -1.17E-08 645.3700 298.15
27.143 9.27E-03 -1.38E-05 7.65E-09 645.3700 298.15

A B C D T (K) To (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 250.1500 298.15

31.150 -1.36E-02 2.68E-05 -1.17E-08 250.1500 298.15
27.143 9.27E-03 -1.38E-05 7.65E-09 250.1500 298.15

flowrate
Tb (K) Tc (K) T (K) liquid vapor ∫Cp ΔHf
239.65 405.6 250.1500 701.4600 87.052 -1674.643 -45900
63.25 126.2 250.1500 0.9983 858.22 -1402.015 0
20.35 33.2 250.1500 0.6424 2598 -1382.596 0
B.2.7 Balance around Flash, F-7

Stream 9

Stream 8 F-7

Stream 10

Operating condition :
1
F-1 2
Temperature Temperature3 Pressure
Stream Phase
(°C) (K) (atm)
8 -23.00 250.15 89.97 Mixture
9 -23.00 250.15 89.94 Vapor
10 -23.00 250.15 89.94 Liquid

Assumption :
1. Reference temperature : 25 °C
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= ΣΔHk(out) - ΣΔHk(in)
where Q = Heat duty
ΣΔHk(out) = Σnk(out)Hf,k(out) + Σnk(out) ∫Cp,kdT
ΣΔHk(in) = Σnk(in)Hf,k(in) + Σnk(in) ∫Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
4. Estimated η = 0.38
5. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc

Stream Flowrate (kmole/hr) òCpdT DHf

Component
(inlet) Liquid Vapor (kJ/kmole) (kJ/kmole)
8 NH3 701.4600 87.0520 -1674.643 -45900
N2 0.9983 858.2200 -1402.015 0
H2 0.6424 2598.0000 -1382.596 0
 DHvap(Tb) DHvap(T) DHL DHV
Component
(kJ/kmole) (kJ/kmole) (kJ/hr) (kJ/hr)
NH3 23362 22788.8882 -49357203 -4141468
N2 5581 0.0000 -1399.576 -1203238
H2 904 0.0000 -888.1384 -3591985
Total -49359490 -8936691

Stream Flowrate òCpdT DHf DHV

Component
(outlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
9 NH3 87.0520 -1674.7112 -45900 -4141474
N2 858.2200 -1402.0738 0 -1203288
H2 2598.0000 -1382.6537 0 -3592134
Total -8936896

Stream Flowrate òCpdT DHf DHvap(Tb) DHvap(T) DHL

Component
(outlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/kmole) (kJ/kmole) (kJ/hr)
10 NH3 701.4600 -1674.7112 -45900 23362 22789 -49357328.63
N2 0.9983 -1402.0738 0 5581 0 -1399.6342
H2 0.6424 -1382.6537 0 904 0 -888.1753
Total -49359616.44

Heat duty (kJ/hr) = -331.549142 kJ/hr

 A B C D T (K) To (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 250.1500 298.15

31.150 -1.36E-02 2.68E-05 -1.17E-08 250.1500 298.15
27.143 9.27E-03 -1.38E-05 7.65E-09 250.1500 298.15
 flowrate
Tb (K) Tc (K) T (K) liquid vapor ∫Cp ΔHf
239.65 405.6 250.1500 701.4600 87.052 -1674.643 -45900
63.25 126.2 250.1500 0.9983 858.22 -1402.015 0
20.35 33.2 250.1500 0.6424 2598 -1382.596 0

A B C D T (K) To (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 250.1480 298.15

31.150 -1.36E-02 2.68E-05 -1.17E-08 250.1480 298.15
27.143 9.27E-03 -1.38E-05 7.65E-09 250.1480 298.15

A B C D T (K) To (K) Tb (K) Tc (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 250.1480 298.15 239.65 405.6
31.150 -1.36E-02 2.68E-05 -1.17E-08 250.1480 298.15 63.25 126.2
27.143 9.27E-03 -1.38E-05 7.65E-09 250.1480 298.15 20.35 33.2
B.2.8 Balance around Exchanger, X-8

Stream 9 Stream 11

X-8

Operating condition :
1
2
Temperature Temperature Pressure
Stream Phase
(°C) (K) X-1(atm)
9 -23.0020 250.1480 89.9400 Vapor
11 -27.5000 245.6500 89.9100 Mixture

Assumption :
1. Reference temperature : 25 °C
2. Estimated η = 0.38
3. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= ΣΔHk(out) - ΣΔHk(in)
where Q = Heat duty
ΣΔHk(out) = Σnk(out)Hf,k(out) + Σnk(out) ∫Cp,kdT
ΣΔHk(in) = Σnk(in)Hf,k(in) + Σnk(in) ∫Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
4. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc

Stream Flowrate òCpdT DHf DHV

Component
(inlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
9 NH3 87.0520 -1674.7112 -45900 -4141474
N2 858.2200 -1402.0738 0 -1203288
H2 2598.0000 -1382.6537 0 -3592134
Total -8936896

Stream Flowrate (kmole/hr) òCpdT DHf

Component
(outlet) Liquid Vapor (kJ/kmole) (kJ/kmole)
11 NH3 16.1813 70.8707 -1828.053 -45900
N2 0.0210 858.1990 -1533.671 0
 H2 0.0129 2597.9871 -1511.792 0

DHvap(Tb) DHvap(T) DHL DHV

Component
(kJ/kmole) (kJ/kmole) (kJ/hr) (kJ/hr)
NH3 23362 23037.3582 -1145076 -3382521
N2 5581 0.0000 -32.25465 -1316195
H2 904 0.0000 -19.5384 -3927616
Total -1145128 -8626332

Heat duty (kJ/hr) = -834564.134 kJ/hr

 A B C D T (K) To (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 250.1480 298.15

31.150 -1.36E-02 2.68E-05 -1.17E-08 250.1480 298.15
27.143 9.27E-03 -1.38E-05 7.65E-09 250.1480 298.15

A B C D T (K) To (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 245.6500 298.15

31.150 -1.36E-02 2.68E-05 -1.17E-08 245.6500 298.15
27.143 9.27E-03 -1.38E-05 7.65E-09 245.6500 298.15

flowrate
Tb (K) Tc (K) T (K) liquid vapor ∫Cp
239.65 405.6 245.6500 16.1813 70.8707 -1828.053
63.25 126.2 245.6500 0.0210 858.199 -1533.671
20.35 33.2 245.6500 0.0129 2597.987 -1511.792
 ΔHf
-45900
0
0
B.2.9 Balance around Expander, E-9

Stream 11 Stream 12

E-9
Operating condition :

Temperature Temperature Pressure

Stream Phase
(°C) (K) (atm)
11 -27.50 1 245.65 89.91 Mixture
12 -41.85 231.30 60.00 Mixture
2
E-1
Assumption :
1. Adiabatic expending (no heat loss in process of expanding)
2. Reference temperature : 25 °C
3. Estimated η = 0.38
4. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= ΣΔHk(out) - ΣΔHk(in)
where Q = Heat duty
ΣΔHk(out) = Σnk(out)Hf,k(out) + Σnk(out) ∫Cp,kdT
ΣΔHk(in) = Σnk(in)Hf,k(in) + Σnk(in) ∫Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
5. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc

Stream Flowrate (kmole/hr) òCpdT DHf

Component
(inlet) Liquid Vapor (kJ/kmole) (kJ/kmole)
11 NH3 16.1813 70.8707 -1828.053 -45900
N2 0.0210 858.1990 -1533.671 0
H2 0.0129 2597.9871 -1511.792 0

DHvap(Tb) DHvap(T) DHL DHV

Component
(kJ/kmole) (kJ/kmole) (kJ/hr) (kJ/hr)
NH3 23362 23037.3582 -1145076 -3382521
N2 5581 0.0000 -32.25465 -1316195
H2 904 0.0000 -19.5384 -3927616
Total -1145128 -8626332
Stream Flowrate (kmole/hr) òCpdT DHf
Component
(outlet) Liquid Vapor (kJ/kmole) (kJ/kmole)
12 NH3 40.5610 46.4920 -2313.302 -45900
N2 0.0272 858.1900 -1953.952 0
H2 0.0138 2598.0000 -1923.337 0

DHvap(Tb) DHvap(T) DHL DHV

Component
(kJ/kmole) (kJ/kmole) (kJ/hr) (kJ/hr)
NH3 23362 23802.0580 -2921015 -2241533
N2 5581 0.0000 -53.1944 -1676862
H2 904 0.0000 -26.50166 -4996830
Total -2921095 -8915225

Heat duty (kJ/hr) = -2064859.53 kJ/hr

 A B C D T (K) To (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 245.6500 298.15

31.150 -1.36E-02 2.68E-05 -1.17E-08 245.6500 298.15
27.143 9.27E-03 -1.38E-05 7.65E-09 245.6500 298.15

flowrate
Tb (K) Tc (K) T (K) liquid vapor ∫Cp ΔHf
239.65 405.6 245.6500 16.1813 70.8707 -1828.053 -45900
63.25 126.2 245.6500 0.0210 858.199 -1533.671 0
20.35 33.2 245.6500 0.0129 2597.987 -1511.792 0
 A B C D T (K) To (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 231.2970 298.15

31.150 -1.36E-02 2.68E-05 -1.17E-08 231.2970 298.15
27.143 9.27E-03 -1.38E-05 7.65E-09 231.2970 298.15

flowrate
Tb (K) Tc (K) T (K) liquid vapor ∫Cp ΔHf
239.65 405.6 231.2970 40.5610 46.492 -2313.302 -45900
63.25 126.2 231.2970 0.0272 858.19 -1953.952 0
20.35 33.2 231.2970 0.0138 2598 -1923.337 0
B.2.10 Balance around Flash, F-10

Stream 13

Stream 12 F-10

Stream 14
Operating condition :
1
F-1 2
Temperature Temperature 3Pressure
Stream Phase
(°C) (K) (atm)
12 -41.85 231.30 60.00 Mixture
13 -41.86 231.30 59.97 Vapor
14 -41.86 231.30 59.97 Liquid

Assumption :
1. Reference temperature : 25 °C
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= ΣΔHk(out) - ΣΔHk(in)
where Q = Heat duty
ΣΔHk(out) = Σnk(out)Hf,k(out) + Σnk(out) ∫Cp,kdT
ΣΔHk(in) = Σnk(in)Hf,k(in) + Σnk(in) ∫Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
4. Estimated η = 0.38
5. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc

Stream Flowrate (kmole/hr) òCpdT DHf

Component
(inlet) Liquid Vapor (kJ/kmole) (kJ/kmole)
12 NH3 40.5610 46.4920 -2313.302 -45900
N2 0.0272 858.1900 -1953.952 0
H2 0.0138 2598.0000 -1923.337 0
 DHvap(Tb) DHvap(T) DHL DHV
Component
(kJ/kmole) (kJ/kmole) (kJ/hr) (kJ/hr)
NH3 23362 22788.8882 -2879920 -2241533
N2 5581 0.0000 -53.1944 -1676862
H2 904 0.0000 -26.50166 -4996830
Total -2880000 -8915225

Stream Flowrate òCpdT DHf DHV

Component
(outlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
13 NH3 46.4920 -2313.3687 -45900 -2241536
N2 858.1900 -1954.011 0 -1676913
H2 2598.0000 -1923.3943 0 -4996978
Total -8915427

Stream Flowrate òCpdT DHf DHvap(Tb) DHvap(T)

Component DHL (kJ/hr)
(outlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/kmole) (kJ/kmole)
14 NH3 40.5610 -2313.3687 -45900 23362 23802.162 -2921021.934
N2 0.0272 -1954.011 0 5581 0.000 -53.1960
H2 0.0138 -1923.3943 0 904 0.000 -26.5025
Total -2921101.632

Heat duty (kJ/hr) = -41304.3703 kJ/hr

 A B C D T (K) To (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 231.2970 298.15

31.150 -1.36E-02 2.68E-05 -1.17E-08 231.2970 298.15
27.143 9.27E-03 -1.38E-05 7.65E-09 231.2970 298.15
 flowrate
Tb (K) Tc (K) T (K) liquid vapor ∫Cp ΔHf
239.65 405.6 231.2970 40.5610 46.492 -2313.302 -45900
63.25 126.2 231.2970 0.0272 858.19 -1953.952 0
20.35 33.2 231.2970 0.0138 2598 -1923.337 0

A B C D T (K) To (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 231.2950 298.15

31.150 -1.36E-02 2.68E-05 -1.17E-08 231.2950 298.15
27.143 9.27E-03 -1.38E-05 7.65E-09 231.2950 298.15

A B C D T (K) To (K) Tb (K) Tc (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 231.2950 298.15 239.65 405.6
31.150 -1.36E-02 2.68E-05 -1.17E-08 231.2950 298.15 63.25 126.2
27.143 9.27E-03 -1.38E-05 7.65E-09 231.2950 298.15 20.35 33.2
B.2.11 Balance around Mixer, M-11

Stream 14
Stream 15
Stream 10

M-11

Operating condition :
1 3
Stream 2
Temperature Temperature Pressure
Phase
(°C) (K) (atm)
10 -23.00 M-1
250.15 89.94 Liquid
14 -41.86 231.30 59.97 Liquid
15 -23.29 249.86 59.97 Mixture

Assumption :
1. Reference temperature : 25 °C
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= ΣΔHk(out) - ΣΔHk(in)
where Q = Heat duty
ΣΔHk(out) = Σnk(out)Hf,k(out) + Σnk(out) ∫Cp,kdT
ΣΔHk(in) = Σnk(in)Hf,k(in) + Σnk(in) ∫Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
4. Estimated η = 0.38
5. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc

Stream Flowrate òCpdT DHf DHvap(Tb) DHvap(T)

Component DHL (kJ/hr)
(inlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/kmole) (kJ/kmole)
10 NH3 701.4600 -1674.7112 -45900 23362 22789 -49357328.63
N2 0.9983 -1402.0738 0 5581 0 -1399.6342
H2 0.6424 -1382.6537 0 904 0 -888.1753
Total -49359616.44
Stream Flowrate òCpdT DHf DHvap(Tb) DHvap(T)
Component DHL (kJ/hr)
(inlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/kmole) (kJ/kmole)
14 NH3 40.5610 -2313.3687 -45900 23362 23802.162 -2921021.93
N2 0.0272 -1954.011 0 5581 0.000 -53.1960
H2 0.0138 -1923.3943 0 904 0.000 -26.5025
Total -2921101.632

Stream Flowrate (kmole/hr) òCpdT DHf

Component
(outlet) Liquid Vapor (kJ/kmole) (kJ/kmole)
15 NH3 742.0100 0.0122 -1684.548 -45900
N2 0.9160 0.1095 -1410.498 0
H2 0.4163 0.2398 -1390.925 0

DHvap(Tb) DHvap(T) DHL DHV

Component
(kJ/kmole) (kJ/kmole) (kJ/hr) (kJ/hr)
NH3 23362 22788.8882 -52217793 -578.5805
N2 5581 0.0000 -1292.045 -154.3931
H2 904 0.0000 -579.0558 -333.5994
Total -52219664 -1066.573

Heat duty (kJ/hr) = 59987.18565 kJ/hr

 A B C D T (K) To (K) Tb (K) Tc (K)
27.315 2.38E-02 1.71E-05 -1.18E-08 250.1480 298.15 239.65 405.6
31.150 -1.36E-02 2.68E-05 -1.17E-08 250.1480 298.15 63.25 126.2
27.143 9.27E-03 -1.38E-05 7.65E-09 250.1480 298.15 20.35 33.2
 A B C D T (K) To (K) Tb (K) Tc (K)
27.315 2.38E-02 1.71E-05 -1.18E-08 231.2950 298.15 239.65 405.6
31.150 -1.36E-02 2.68E-05 -1.17E-08 231.2950 298.15 63.25 126.2
27.143 9.27E-03 -1.38E-05 7.65E-09 231.2950 298.15 20.35 33.2

A B C D T (K) To (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 249.8600 298.15

31.150 -1.36E-02 2.68E-05 -1.17E-08 249.8600 298.15
27.143 9.27E-03 -1.38E-05 7.65E-09 249.8600 298.15

flowrate
Tb (K) Tc (K) T (K) liquid vapor ∫Cp ΔHf
239.65 405.6 249.8600 742.0100 0.012159 -1684.548 -45900
63.25 126.2 249.8600 0.9160 0.10946 -1410.498 0
20.35 33.2 249.8600 0.4163 0.23984 -1390.925 0
B.2.12 Balance around Flash, F-12

Stream 16

Stream 15 F-12

Stream 17
Operating condition :

1 Temperature
Temperature Pressure
Stream F-1 Phase
3 59.972
(°C) (K) (atm)
15 -23.29 249.86 Mixture
16 -23.29 249.86 59.94 Vapor
17 -23.29 249.86 59.94 Liquid

Assumption :
1. Reference temperature : 25 °C
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= ΣΔHk(out) - ΣΔHk(in)
where Q = Heat duty
ΣΔHk(out) = Σnk(out)Hf,k(out) + Σnk(out) ∫Cp,kdT
ΣΔHk(in) = Σnk(in)Hf,k(in) + Σnk(in) ∫Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
4. Estimated η = 0.38
5. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc

Stream Flowrate (kmole/hr) òCpdT DHf

Component
(inlet) Liquid Vapor (kJ/kmole) (kJ/kmole)
15 NH3 742.0100 0.0122 -1684.548 -45900
N2 0.9160 0.1095 -1410.498 0
H2 0.4163 0.2398 -1390.925 0
 DHvap(Tb) DHvap(T) DHL DHV
Component
(kJ/kmole) (kJ/kmole) (kJ/hr) (kJ/hr)
NH3 23362 22788.8882 -52217793 -578.5805
N2 5581 0.0000 -1292.045 -154.3931
H2 904 0.0000 -579.0558 -333.5994
Total -52219664 -1066.573

Stream Flowrate òCpdT DHf DHV

Component
(outlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
16 NH3 0.0122 -1684.5136 -45900 -578.5801
N2 0.1095 -1410.4691 0 -154.3899
H2 0.2398 -1390.8959 0 -333.5925
Total -1066.563

Stream Flowrate òCpdT DHf DHvap(Tb) DHvap(T) DHL

Component
(outlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/kmole) (kJ/kmole) (kJ/hr)
17 NH3 742.0100 -1684.5136 -45900 23362 22804.978 -52229707.03
N2 0.9160 -1410.4691 0 5581 0.000 -1292.0179
H2 0.4163 -1390.8959 0 904 0.000 -579.0439
Total -52231578.09

Heat duty (kJ/hr) = -11913.7633 kJ/hr

 A B C D T (K) To (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 249.8600 298.15

31.150 -1.36E-02 2.68E-05 -1.17E-08 249.8600 298.15
27.143 9.27E-03 -1.38E-05 7.65E-09 249.8600 298.15
 flowrate
Tb (K) Tc (K) T (K) liquid vapor ∫Cp ΔHf
239.65 405.6 249.8600 742.0100 0.012159 -1684.548 -45900
63.25 126.2 249.8600 0.9160 0.10946 -1410.498 0
20.35 33.2 249.8600 0.4163 0.23984 -1390.925 0

A B C D T (K) To (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 249.8610 298.15

31.150 -1.36E-02 2.68E-05 -1.17E-08 249.8610 298.15
27.143 9.27E-03 -1.38E-05 7.65E-09 249.8610 298.15

A B C D T (K) To (K) Tb (K) Tc (K)

27.315 2.38E-02 1.71E-05 -1.18E-08 249.8610 298.15 239.65 405.6
31.150 -1.36E-02 2.68E-05 -1.17E-08 249.8610 298.15 63.25 126.2
27.143 9.27E-03 -1.38E-05 7.65E-09 249.8610 298.15 20.35 33.2
B.2.13 Balance around Exchanger, X-14

Stream 17 Stream 20

X-14

1
2
Operating condition :
X-1
Temperature Temperature Pressure
Stream Phase
(°C) (K) (atm)
17 -23.29 249.86 59.94 Liquid
20 -15.00 258.15 59.91 Liquid

Assumption :
1. Reference temperature : 25 °C
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= ΣΔHk(out) - ΣΔHk(in)
where Q = Heat duty
ΣΔHk(out) = Σnk(out)Hf,k(out) + Σnk(out) ∫Cp,kdT
ΣΔHk(in) = Σnk(in)Hf,k(in) + Σnk(in) ∫Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
4. Estimated η = 0.38
5. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc

Stream Flowrate òCpdT DHf DHvap(Tb) DHvap(T) DHV

Component
(inlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/kmole) (kJ/kmole) (kJ/hr)
17 NH3 742.0100 -1684.5136 -45900 23362 22804.978 -52229707.03
N2 0.9160 -1410.4691 0 5581 0.000 -1292.0179
H2 0.4163 -1390.8959 0 904 0.000 -579.0439
Total -52231578.087
Stream Flowrate òCpdT DHf DHvap(Tb) DHvap(T) DHV
Component
(inlet) (kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/kmole) (kJ/kmole) (kJ/hr)
20 NH3 742.0100 -1400.4057 -45900 23362 22335.911 -51670843.577
N2 0.9160 -1168.0752 0 5581 0.000 -1069.9803
H2 0.4163 -1152.7257 0 904 0.000 -479.8913
Total -51672393.449

Heat duty (kJ/hr) = 559184.6386 kJ/hr

 A B C D T (K) To (K) Tb (K) Tc (K)
27.315 2.38E-02 1.71E-05 -1.18E-08 249.8610 298.15 239.65 405.6
31.150 -1.36E-02 2.68E-05 -1.17E-08 249.8610 298.15 63.25 126.2
27.143 9.27E-03 -1.38E-05 7.65E-09 249.8610 298.15 20.35 33.2
 A B C D T (K) To (K) Tb (K) Tc (K)
27.315 2.38E-02 1.71E-05 -1.18E-08 258.1500 298.15 239.65 405.6
31.150 -1.36E-02 2.68E-05 -1.17E-08 258.1500 298.15 63.25 126.2
27.143 9.27E-03 -1.38E-05 7.65E-09 258.1500 298.15 20.35 33.2
B.2.14 Stream 19

Operating condition :

Temperature Temperature Pressure

Stream Phase
(°C) (K) (atm)
19 -41.86 231.30 59.97 Vapor

Flowrate òCpdT DHf DHV

Stream Component
(kmole/hr) (kJ/kmole) (kJ/kmole) (kJ/hr)
19 NH3 0.46492 -2313.3687 -45900 -22415.3594
N2 8.5819 -1954.011 0 -16769.1274
H2 25.98 -1923.3943 0 -49969.7848
Total -89154.2716

Total Entalphy = -89154.2716 kJ/hr

 A B C D T (K)
27.315 2.38E-02 1.71E-05 -1.18E-08 231.2950
31.150 -1.36E-02 2.68E-05 -1.17E-08 231.2950
27.143 9.27E-03 -1.38E-05 7.65E-09 231.2950
To (K)

298.15
298.15
298.15
Equipment Energy Balance

Heat duty
Proses Equipment
(kJ/hr)
Mixer, M-1 -194010.9661 -53.89194
Compressor, C-2 18986080.8258 5273.9113
Exchanger, X-3 50504624.3208 14029.062
Reactor, R-4 -39271343.7024 -10908.71
Expander, E-5 -10940662.8237 -3039.073
Exchanger, X-6 -68554007.4352 -19042.78
Flash, F-7 -331.5491 -0.092097
Exchanger, X-8 -834564.1342 -231.8234
Expander, E-9 -2064859.5287 -573.5721
Flash, F-10 -41304.3703 -11.47344
Mixer, M-11 59987.1856 16.663107
Flash, F-12 -11913.7633 -3.309379
Exchanger, X-14 559184.6386 155.32907
Summary of Energy Balance Calculation

Temperature Pressure Enthalpy

Stream Phase
(°C) (atm) (kJ/hr)
1 Vapor 25.00 60.00 0 0
2 Vapor 25.00 60.00 0 0
3 Vapor -22.81 59.97 -9020872 -2505.798
4 Vapor 108.15 172.74 9965208.8 2768.114
5 Vapor 450.00 172.71 60469833 16797.18
6 Vapor 450.00 172.68 21198489 5888.469
7 Vapor 372.22 90.00 10257827 2849.396
8 Mixture -23.00 89.97 -58296181 -16193.38
9 Vapor -23.00 89.94 -8936896 -2482.471
10 Liquid -23.00 89.94 -49359616 -13711
11 Mixture -27.50 89.91 -9771460 -2714.294
12 Mixture -41.85 60.00 -11836320 -3287.867
13 Vapor -41.86 59.97 -8915427 -2476.508
14 Liquid -41.86 59.97 -2921102 -811.4171
15 Mixture -23.29 59.97 -52220731 -14505.76
16 Vapor -23.29 59.94 -1066.5625 -0.296267
17 Liquid -23.29 59.94 -52231578 -14508.77
18 Vapor -41.86 59.97 -8826861 -2451.906
19 Vapor -41.86 59.97 -89154.27 -24.76508
20 Liquid -15.00 59.91 -51672393 -14353.44
 Manual Simulation
Stream Error (%)
(kJ/hr) (kJ/hr)
1 0 178430 100
2 0 1128300 100
3 -9020872.01350509 -2649300 -240.50021
4 9965208.8123242 17961000 44.5175168
5 60469833.1331124 68530000 11.7615159
6 21198489.4306884 62200000 65.9188273
7 10257826.6069629 50548000 79.7067607
8 -58296180.8282047 -19635000 -196.89932
9 -8936895.93711825 -2472700 -261.42257
10 -49359616.4402279 -17162000 -187.60993
11 -9771460.07128815 -3326900 -193.71066
12 -11836319.6000099 -5461400 -116.72684
13 -8915427.15754258 -4395500 -102.83079
14 -2921101.6320001 -1065900 -174.05025
15 -52220730.8865799 -18228000 -186.48634
16 -1066.56251029496 -269.06 -296.40322
17 -52231578.0873595 -18228000 -186.54585
18 -3956000
19 -439550
20