JEE-MAIN 2021-22

Time: 90 Mins Physics, Chemistry and Mathematics 360

PHYSICS
01) The correct curve between the stopping
potential (V) and intensity of incident light (I) is

D)

03) Consider an electron in a hydrogen atom,

A) revolving in its second excited state (having radius
0
4.65 A ). What is the de-Broglie wavelength of this
electron?
0
B) A) 12.9 A
0
B) 6.6 A
0
C) 3.5 A
0
D) 9.7 A
C)
04) In a historical experiment to determine Planck's
constant, a metal surface was irradiated with light
of different wavelength. The emitted photoelectron
energies were measured by applying a stopping
potential. The relevant data for the wavelength   
D)
of incident light and the corresponding stopping
02) The following curves show the variation potential  V0  are given below:
between the applied potential difference (V) and the
photoelectric current (i), at two different intensities
of light (I1 > I2). In which figure is the correct
variation shown?

Given that c  3  108 ms1 and e  1.6  1019 C,

estimate the Planck's constant (in units of J-s)
found from such an experiment.
A) 6.6  1034
A) B) 6.4  1034
C) 6.0  1034
D) 6.8  1034

05) For a photoelectric cell, the graph showing the

variation of cut of voltage (Vo) with frequency (v) of
B) incident light is best represented by

A)
C)

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B) B)

C)
C)

D)
D)
06) Photoelectric effect experiments are performed
using three different metal plates p,q and r having 09) A material particle with a rest mass is moving
work functions p  2.0 eV, q  2.5eV and with a velocity of light c. Then, what is the
wavelength of the de Broglie wave associated with
r  3.0 eV, respectively. A light beam containing it?
wavelengths of 550 nm, 450 nm and 350 nm with A) (h / m0c)
equal intensities illuminates each of the plates. B) Zero
Identify the correct I-V graph for the experiment. C) (m0c / h)
D) 
10) Identify a photon of frequency v has
momentum associated with it is(c is the velocity of
A) photon)
v
A)
c
hv
B) 2
B) c
hv
C)
c
D) hvc

C) 11) The maximum velocity of electrons emitted

from a metal surface is v. The maximum velocity if
the frequency of incident light is increased by a
factor of 4 would be
A) < 2v
D) B) > 2v
C) 2v
07) In a photoelectric experiment, the wavelength D) between 2v and 4v
of the light incident on a metal is changed from
300 nm to 400 nm. The decrease in the stopping 12) The threshold frequency for certain metal is
v0 . When light of frequency 2 v0 is incident on it,
 hc 
potential is neearly equal to   1240 nmV  the maximum velocity of photoelectrons is
 e 
A) 0.5 V 4  106 m s-1 . If the frequency of incident radiation
B) 2.0 V is increased to 5 v0 , then what will be the
C) 1.5 V maximum velocity of photoelectrons?
D) 1.0 V A) 2  107 m s-1
08) Which of the following figure represents the B) 2  106 m s-1
variation of particle momentum and the associated
de-Broglie wavelength? C) 8  106 m s-1
D) 4 /5  106 m s-1

13) Monochromatic light incident on a metal

surface emits electrons with kinetic energies from
zero to 2.6 eV . The least energy of the incident
A)
photon if the tightly bound electron needs 4.2 eV

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to remove is
A) From 1.6 eV to 6.8 eV 19) When green light is incident on the surface of
metal, it emits photo-electrons but there is no such
B) 1.6 eV emission with yellow colored light. The color, that
C) 6.8 eV can produce emission of photo-electrons, is
D) More than 6.8 eV A) indigo.
B) orange.
14) Electrons are accelerated in television tubes C) red.
through potential difference of about 10 kV. What D) none of the above.
is the highest frequency of the electromagnetic
waves emitted when these electrons strike the 20) The frequency of incident light falling on a
screen of the tube? photosensitive metal plate is doubled, what is the
A) 2.4  1018 Hz KE of the emitted photoelectrons?
A) Unchanged
B) 2.2  1017 Hz B) Double the earlier value
C) 3.6  1018 Hz C) More than doubled
D) 3.2  1016 Hz D) Less than doubled

15) In the experiment on photoelectric effect, the 21) The work function of a substance is 4.0 eV .
graph between EK(max) and v is found to be a What is the longest wavelength of light that can
cause photoelectron emission from this substance?
straight line as shown in figure. A) 540 nm
B) 220 nm
C) 310 nm
D) 400 nm

22) With respect to electromagnetic theory of light,

the photoelectric effect is best explained by which
of the following statement?
A) Light waves carry energy and when light is
What are the threshold frequency and Plank’s incident on the metallic surface, the energy
constant according to this graph? absorbed by the metal may somehow concentrate
A) 3.33  1018 s1,6  1034 J  s on individual electrons and reappear as their
kinetic energy when ejected
B) 6  1018 s1, 6  10-34 J-s B) When light waves fall on a metallic surface, the
C) 4  1018 s1,3  1034 J  s stability of atoms is disturbed and the electrons
come out to make the system stable
D) 2.66  1018 s1,4  1034 J  s
C) Particles of light (photons) collide with the metal
16) The work functions of a metal is W and is the and the electron take this energy and may eject.
wavelength of the incident radiation. When______, D) None of above
there is no emission of photoelectrons. 23) An electron is accelerated through a potential
A)   hc / W difference of V volt. It has a wavelength 
B)   hc / W associated with it. Through _____ potential
C)   hc / W difference an electron must be accelerated so that
its de Broglie wavelength is the same as that of a
D)   hc / W
proton Take mass of proton to be 1837 times larger
0 than the mass of electron.
17) A photon of wavelength 0.1 A is emitted by a A) 1837 V volt
helium atom as a consequence of the emission of B) 1837 V volt
photon. What is the KE gained by helium atom? C) V/1837 volt
A) 3.05 eV D) V volt
B) 1.05 eV
24) If 10000 V is applied across an X-ray tube,
C) 2.05 eV then the ratio of de-Broglie wavelength of the
D) 0.05 eV incident electrons to the shortest wavelength of
e
18) If the kinetic energy of a free electron doubles, X-ray produced, will be ( for electron is
m
by which factor its de Broglie wavelength changes?
1 1.8  1011 c kg 1 )
A) A) 0.3
2
B) 0.2
1 C) 0.1
B)
2 D) 1
C) 2
25) The work function of a metallic surface is
D) 2
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5.01 eV The photoelectrons are emitted when light C) 6.6  1034 J-s
0 D) None of these
of wavelength 2000 A falls on it. What is the
potential difference applied to stop the fastest MATHEMATICS
photoelectrons? [h  4.14  1015 eVs]
 2  sin x  dy 
A) 1.2 V 31) If     cos x, y(0)  1, then y  
B) 4.8 V  1  y  dx 2
C) 3.6 V =
D) 2.24 V 1
A)
4
26) A charged oil drop is suspended in a uniform
1
field of 3  104 V / m so that it neither falls nor B)
3
rises. What will be the charge on the drop? (take
1
the mass of the charge as 9.9  1015 kg and C)
2
g  10 m/s2 ) D) 1
A) 3.3  1018 C 32) What is the solution of the differential equation
B) 3.2  1018 C y
 
C) 408  1018 C dy y x
    ?
D) 1.6  1018 C dx x y
  
x
27) According to Einstein's photoelectric equation,
the plot of the kinetic energy of the emitted photo y
A)     kx
electrons from a metal versus the frequency, of the x
incident radiation gives a straight line whose slope
y
A) depends on the nature of the metals used. B)     ky
B) depends both on the intensity of the radiation x
and the metal used. y
C) depends on the intensity of the radiation. C) x    k
x
D) is the same for all metals and independent of
the intensity of the radiation. y
D) y    k
x
28) The equation E  pc, is valid for _____, out of a
photon and an electron. 33) The solution of the differential equation
A) neither dy xy
B) both  2 is
dx x  y 2
C) photon only 2
D) electron only A) y  ex  y 2  c
2 2
29) If a photocell is illuminated with a radiation of B) y  ex  e y  c
0
1240 A then stopping potential is found to be 8 V. C) ay  ex/y
2
What are the work function of the emitter and the /y 2
D) ay 2  ex
threshold wavelength?
0
A) 4 eV,4200 A  7
34) The equation of a curve passing through  2, 
0  2
B) 2. eV, 6200 A 1
0 and having gradient 1  2 at (x, y) is
C) 3 eV, 7200 A x
0 A) xy  x  1
D) 1. eV, 5200 A B) y  x2  x  1
30) In the following graph, if the slope is C) xy  x2  x  1
4.12  1015 V-s, then value of 'h' should be D) None of these
35) The differential equation
3 4
 d2 y   dy  2
x 2      y  x is of
 dx   dx 
 
A) degree 4 and order 4
B) degree 4 and order 3
A) 9.1  1031 J-s C) degree 1 and order 1
D) degree 3 and order 2
B) 6.6  1031 J-s

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36) What is the particular solution of the 1

A)  (ln x)2  ln x
 y  2
differential equation  x sin2    y  dx  xdy  0 ,
 x  1
B)  (ln x)2  ln x
 2
satisfying the condition y  , when x=1?
4 1
C) (ln x)2  ln x
x 2
A) tan    log  ex  1
y D) (ln x)2  ln x
2
y
B) tan    log  ex 
x 3
42) The solution of ydx  xdy  3x2 y2ex dx  0 is
y e x
C) cot    log   A)
3
 ex  0
x x y
y x
D) cot    log  ex 
3
B)  ex  c
x y
x 3
d2 y C)  ex  0
37) The solution of  cos x  sin x is y
dx 2
D) None of these
A) y  cos x  sin x  c1x2  c2 x
43) What is the solution of differential equation
B) y  cos x  sin x  c1x2  c2 x
dy  ty   dy 
2 2
C) y   cos x  sin x  c1x  c2 t  1   ty    ... ?
D) y   cos x  sin x  c1x  c2 dt 2 !  dt 

dy
A) y    log t 2  C
38) If  2  sin x    y  1 cos x  0 and y  0   1,
B) y   log t   C
2
dx
 C) y  log t  C
then what is y   ?
2 D) ty  t y  C
1
A) 44) The solution of the equation
3
dy
B)
4 (x  2y 3 )  y  0 is
3 dx
(Where A is any arbitrary constant)
1
C)  A) x(1  xy)  Ay
3
B) x(1  xy)  Ay
2
D)  C) y3  x  Ay
3
D) y(1  xy)  Ax
39) Let y(x) be the solution of the differential
dy 45) The general solution of the differential equation
equation  x log x   y  2x log x,  x  1 . Then,
dx (2x  y  1)dx  (2y  x  1)dy  0 is
what is y(e)? A) x2  y2  2xy  x  y  c
A) 2e
B) e B) x2  y2  2xy  x  y  c
C) 2 C) x2  y2  xy  x  y  c
D) 0
D) x2  y2  xy  x  y  c
40) A solution of the differential equation
2 46) Evaluate the solution of differential equation
 dy  dy
 dx   x dx  y  0 is  d 
 
dt
t
dx
g  x   t2
A) y  2x2  4   
dx g x
B) y = 2x - 4
g x
C) y = 2x A) t  C
D) y = 2 x
g x  C
d2 y B) t 
41) The solution of the equation x 2  ln x, x
2
dx g x
dy C) t 
when x = 1, y = 0 and  1 is xC
dx

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D) t  g  x   x  C x2  y2
passing through a point (2, 1) is , then the
2xy
d  dx
47) The function f     
d 0 1  cos  cos x
equation of the curve is
A) x(x2  y 2 )  10
satisfies which of the following differential
equation? B) x(x2  y 2 )  6
df C) 2(x2  y 2 )  6y
A)  2f     0
d D) 2(x2  y 2 )  3x
df
B)  2f     0
d 53) The differential equation of all circles passing
df through the origin and having their centres on the
C)  2f     tan  x-axis is
d
dy
df A) y 2  x 2  2xy
D)  2f    cot   0 dx
d
dy
B) y 2  x 2  2xy
48) The differential equation of the family of curves dx
represented by the equation x 2 y  a , is dy
C) x 2  y 2  xy
dy 2x dx
A)  0
dx y dy
D) x 2  y 2  xy
dy 2y dx
B)  0
dx x 54) The solution of the differential equation
dy 2x sec2 x tan y dx  sec2 y tan x dy  0 is
C)  0
dx y A) tan x sec y = c
dy 2y B) tan x = c cot y
D)  0 C) tan x = c tan y
dx x
D) tan x = c tan (x + y)
49) If y(t) is a solution of
dy dy
1  t   ty  1 and y 0   1 , then what is the 55) The solution of the equation x  3y  x is
dt dx
value of y(1)? x4
A) x 3 y  c
A) -1 4
B) 1 x4
1 B) x 3 y  c 0
C)  4
2
x4
D) 0 C) x 3 y  0
4
50) The order and degree of the differential D) None of these
3 2
 dy   d2 y  56) Solution of the differential equation
equation x    2  2   3y  x  0 are
 dx   dx  dy y
  sin x is
respectively dx x
A) 2, 1 A) x(y  cos x)  cos x  c
B) 2, 2 B) x(y·cos x)  sin x  c
C) 2, 3
C) x(y  cos x)  sin x  c
D) 3, 2
D) x(y  cos x)  sin x  c
51) The differential equation of all the lines in the
xy-plane is 57) The solution of the differential equation,
d2 y y dx  (x  x2 y)dy  0 is
A) 0
dx 2 A) log y  cx
d2 y 1
B) 2
x0 B)  logy  c
dx xy
dy 1
C) x0 C)   log y  c
dx xy
d2 y dy 1
D) 2
x 0 D)  logy  c
dx dx xy
52) The slope of the tangent at (x, y) to a curve 58) The equation of the curve that passes through

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the point (1, 2) and satisfies the differential D) 1.3  105 ms1
dy 2xy
equation  is 64) The instantaneous rate of disappearance of the
dx (x 2  1)
MnO4 ion in the following reaction is
A) y(x2  1)  4  0
4.56  103 ms1. Then fnd the rate of appearance
2
B) y(x  1)  4
of I2 . 2MnO4  10I  10H  2Mn2  5I2  8H2 O
2
C) y(x  1)  4
A) 5.7  103 ms1
D) None of these
B) 1.14  103 ms1
59) What is the solution of the equation C) 4.56  104 ms1
2
x2
d y
 log x when x =1, y=0 and
dy
 1 ? D) 1.14  102 ms1
dx 2 dx
65) In a catalytic conversion of N2 to NH3 by
Haber's process, the rate of reaction was expressed
1 as change in the concentration of ammonia per
A) y   log x 2  log x
2 time is 40  103 mol litre1s1 . If there are no side
1 reaction, the rate of the reaction as expressed in
B) y   log x   log x
2
2 terms of hydrogen is (in mol litre1s1 )
1 A) 10.3  103
C) y    log x   log x
2
2 B) 20  103
1 C) 60  103
D) y    log x   log x
2
2 D) 1.200
60) Find a solution of the differential equation 66) The rate constant for a second order reaction is
2
 dy  dy 8  105 M1 min1 . How long will it take a 1 M
 dx   x dx  y  0 .
  solution to be reduced to 0.5 M?
A) y  2x A) 1.25  104 min
B) y  2 B) 8.665  103 min
C) y  2x  4 C) 4  105 min
D) y  2x2  4 D) 8  105 min

CHEMISTRY 67) t 1 can be taken as the time taken for the

4
61) Rate equation for autocatalytic reaction 3
dCA concentration of a reactant to drop to of its
A  R  k

 R  R is   kCA .CR find when the 4
dt initial value. If the rate constant for a first order
rate of disappearance of A is maximum. reaction is K , then t 1 can be written as
A) CA  CR 4

B) CA  2CR A) 0.75 /K
C) 2CA  CR B) 0.69 /K
C) 0.29 /K
D) CA   CR 
1/2

D) 0.10 /K
62) For the reaction: aA  bB;
68) In a first order reaction the concentration of
 dA   dB 
log    log  dt   0.6020, then find a:b. reactant decreases from 800 mol /dm3 to
 dt   
50 mol /dm3 is 2  102 s . The rate constant of
A) 4 reaction in s 1 is
B) 0
C) 1.5 A) 1.386  102
D) 2 B) 2  104
C) 3.45  105
63) For the reaction 2N2O5(g)  4NO2(g)  O2(g) , if
D) 2  104
concentration of NO2 in 100 seconds is increased
69) The reaction
by 5.2  103 m . Then rate of reaction will be
1
A) 2  103 ms1 N2O5 (in CCl4 soln )  2NO2 (soln )  O2 (g) is of
4 1
2
B) 7.6  10 ms first order in N2O5 with rate constant
C) 5  104 ms1
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6.2  101s1. What is the value of rate of reaction C) 50

1 D) 34
when [N2O5 ]  1.25 mole l
A) 3.85  101 mole l1 s 1 77) Temperature dependent equation can be
written as
B) 5.15  105 mole l1s 1
A) ln k  ln A  eRT/Ea
C) 6.35  103 mole l1s 1
B) ln k  ln A  eEa /RT
1 1 1
D) 7.75  10 mole l s
C) ln k  ln A  eEa /RT
70) The decomposition of N2O5 occurs as, D) All of these
2N2O5  4NO2  O2 , and follows Ist order kinetics, 78) The minimum energy a molecule should
hence possess in order to enter into a fruitful collision is
A) T1/2  a 0 known as
A) threshold energy.
B) the reaction is unimolecular. B) activation energy.
C) the reaction is bimolecular. C) collision energy.
D) none of these. D) reaction energy.
71) The reaction 2FeCl3  SnCl2  2FeCl2  SnCl4 79) The activation energy for a simple chemical
is an example of reaction A  B is Ea in forward direction. The
A) third order reaction. activation energy for reverse reaction
B) second order reaction. A) can be less than or more than Ea .
C) first order reaction.
D) none of these. B) is always less than Ea .
C) is negative of Ea .
72) If initial concentration is reduced to its 1/4th
D) is always double of Ea .
in a zero order reaction, the time taken for half of
the reaction to complete
80) An endothermic reaction A  B has an
A) doubles.
activation energy 15 kcal/mole and energy of
B) becomes one-fourth.
reaction 5 kcal/mole. The activation energy of the
C) remains same.
reaction B  A is
D) becomes 4 times.
A) 10 kcal/mole.
73) An example of a pseudo - unimolecular B) 20 kcal/mole.
reaction is C) 15 kcal/mole.
A) decomposition of hydrogen peroxide. D) None of these.
B) dissociation of phosphorus pentachloride.
81) The activation energy for a reaction is
C) hydrolysis of methyl acetate in dilute solution.
D) dissociation of hydrogen iodide. 9.0 K cal / mol. The increase in the rate constant
when its temperature is increased from 298 K to
74) A reaction 2 A  products is found to follow 308 K is
zero order kinetics, then A) 10%
dx B) 50%
A)  k[2 A] C) 63%
dt
D) 100%
dx
B)  k[A]
dt 82) Find the order of a chemical reaction
K
dx A  2B  
 C, if the rate of formation of 'C'
C)  k[A]0
dt increases by a factor of 2.82 on doubling the
dx concentration of 'A' and increases by a factor of 9
D)  k[A]2 on tripling the concentration of 'B'
dt A) 7/2
75) If a substance with half life 3 days is taken at B) 7/4
other place in 12 days. What amount of substance C) 5/4
is left now? D) 5/2
A) 1/32 83) For zeroth order reaction, variation of x with
B) 1/16 time is shown as
C) 1/8
D) 1/4
76) The rate constant is doubled, when
temperature increases from 27°C to 37°C.
Activation energy in kJ is
A) 100
B) 54
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 dx 
 rate  k  A 
n
88) For nth order reaction,  
 dt 
Graphs between log (rate) and log A0  are of the
type A0 is the initial concentration
At initial concentration of the reactant as
17.32mol dm1, what is half-life period?
A) 10.0 min
B) 15.0 min
C) 8.66 min
D) 5.0 min
Lines P, Q, R and S are for which of the following
84) The mechanism for the reaction is given below the order.
2P  Q  S  T
P  Q  R  S (slow) A)
P  R  T (fast)
The rate law expression for the reaction is
A) r  k[P]2 B)
B) r  k[A][R]
C) r  k[P][Q] C)
D) r  k[P]2[Q]
D)
85) If 3 A  2B, then the rate of reaction of
d(B) 89) The acid catalyzed ionization of   hydroxy
 is equal to butyric acid proceeds as a reversible reaction.
dt
Which is I order in both the forward and backward
3 d(A)
A)  steps:
2 dt k1
A B
2 d(A)  Acid  k2 Lactose 
B) 
3 dt d A
1 d(A) The rate  is
C)  dt
3 dt A) k 2 B
d(A)
D) 2 B) k1  A 
dt
C) k1  A   k2 B
86) For the decomposition of HI at 1000 K
k1  A 
2HI  H2  I2  , the following dater were obtained D)
k 2  B
[HI] (M) Rate of decomposition of HI  mol L1 1
s 
90) Two reactions R1 and R2 have identical
0.1 2.75  108
pre-exponential factors. Activation energy of R1
0.2 11  108
exceeds that of R 2 by 10 kJ mol1. If k1 and k2
0.3 24.75  108
are rate constants for reactions R1 and R2
What is the order of reaction?
A) 1 respectively at 300 K, then In  k2 / k1  is _____.
B) 2
C) 1.5 R  8.314 J mol 1
K 1

D) 0 A) 12
B) 8
87) The rate equation for the reaction 2A  B  C C) 6
is rate  k  A B . Find the correct statement D) 4
about this.
A) K is independent of [A] and [B]
B) t1/2 is constant
C) Rate of formation of C is twice the rate of
disappearance of A
D) Unit of K is sec 1

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