Part Test-Iv - P1 - Key & Solutions - 12.06.20

FIITJEE
HYD SENIORS
PART TEST-IV
IIT(2012)_P1
ANSWERS
PHYSICS
1. C 2. C 3. B 4. D
5. C 6. A 7. D 8. A
9. D 10. A 11. B, C 12. A, B, C, D
13. A, C 14. A, C 15. B, C, D 16. 1
17. 2 18. 2 19. 1 20. 3
CHEMISTRY
21. C 22. A 23. D 24. B
25. C 26. B 27. D 28. A
29. C 30. B 31. A, B, C, D 32. A, D
33. A, C, D 34. A, B, C, D 35. B, D 36. 5
37. 6 38. 6 39. 3 40. 1
MATHEMATICS
41. D 42. A 43. B 44. C

45. C 46. D 47. D 48. D
49. C 50. B 51. A, B, C 52. C, D
53. A, C, D 54. A,B,C,D 55. A,B 56. 3
57. 0 58. 3 59. 6 60. 4
FIITJEE (Hyderabad Classes) Limited. 5-9-14/B, Saifabad, (Opp. Secretariat) Hyderabad. 500 063. Ph: 040-66777000 – 03 Fax: 04066777004
FIITJEE Limited. 22–97, Plot No.1, (Opp. Patel Kunta) Huda Park, Vijaynagar Colony, Kukatpally, Hyderabad. 500 072. Ph : 040–64601123
FIITJEE Limited. Plot No. 39A, (Opp. Sashi Hospital), Gaddiannaram, Dilsukhnagar, Hyderabad, 5000036. Ph: 040–64569509.
ANSWERS AND SOLUTIONS
PHYSICS SOLUTIONS
1. C
1 2 2
Sol. E m A
2
2 A2
v   A  A / 4  3
2
1 2 2 3 3 
KE  m   A    E 
2 4 4 
2. C
Sol. V  A
3. B

Sol. E x
3 0

F   q  x
3 0
4. D
Sol.
5. C
 1
Sol. K 
 
6. A
dT
Sol.  b  T  Ta 
dt
7. D
Sol. Both rods are in parallel
8. A
Sol. Pv = nRT
9. D
Sol. Q  Q1  Q2
10. A
Sol. Principle of thermometry
11. B, C
12. A, B, C, D
13. A, C
14. A, C
15. B, C, D
5
Sol.
PV  C
3
16. 1
2
ml
Sol. I
3
T 1
,S  a  t 
2
 t 
4 2
17. 2

Sol. T  2
g
18. 2
Sol.
kx
N

acom
(N/2) f
N
 f  macom
2
1
f  macom
2
kx  4macom
19. 1
Sol. Points on isotherm are at same temperature.
20. 3
Sol. Heat supplied = nc(T)
CHEMISTRY SOLUTIONS
21. C
Sol. Diphenyl benzene -1, 3-dicarboxylate
22. A
Sol.
CH3 CH3 CH3
CH3
23. D
Sol. E.N. of 0 > N > S
No aromatic in 4th structure
24. B
Sol. It will form more stable structure
O H H
D C CH C Ph
CH2 CH3 CH CH2
25. C
Sol.
COOH
H OH
optiion C is HO H
COOH
COOH
H OH
mesotartaric acid is H OH
COOH
26. B
Sol. Acidic strength of H3 C  COOH
27. D
Sol. The basicity order will be inversely proportional to resonance stability of lone pair
28. A
Sol.
CH3 CH3
CH3 H H
(i) B 2H6 THF TsCl
H H
ii) H 2O 2 / NaOH
OH OTS
(X) (X)
t- BuO
CH3
H
(Anti elimination)
t-BuOK
TsOH
29. C
Sol.
H3C CH CH CH CH
4
2  16
30. B
Sol.
C 2H 5 CH2 Cl CH3
H Cl H CH3 H Cl
H Cl H CH3 (CH2)2
C 2H 5 CH2 Cl H Cl
CH3
31. A, B, C, D
CH3
H C 2H 5
N
N (Racemic mixture)
A) H C2 H5
CH3
CH3 CH3
DCl N N
B) H C2 H5 D H D H
CH3 C 2H 5 C 2H 5
(C) Two gauche form of butane are chiral and have equal energy
H3C CH3
C C C (optical active)
(D) H H
32. A, D
Sol. Phenol and aliphatic alcohol are considered as different functional groups
33. A, C, D
Sol. (A) Due to steric hindrance to salvation of conjugated acid
(C) acidity  stability of conjugate base
(D) In period left to right, Kb decreases
34. A, B, C, D
Sol. (A) Pyrolysis of esters syn 1, 2-elimination
(B) Cope elimination trialkyl amine oxides
(C) Hofmann elimination of 4 ammonium hydroxide
(D) Hofmann elimination of sulphonium hydroxide
35. B, D
Sol.
Ph C CHCl 2 Ph C C H
1) 2)
O O O
H
Ph C C OH
3) internal OH O
cannizaro reaction
36. 5
*
Sol. Cl  CH2  CH  CH3   CH2  CH3
10  6 hydrogens (chiral) 6 x 1 = 6
2  1 = 5 x 1 = 5
3  1 = 5 x 1 = 5
Other 1  3 = 3 x 1 = 3 total = 6 + 6 + 5 + 3 = 20
6
x   100  30
20
30
5
6
37. 6
Sol. 1) C-C-C-C-OCH3
2) C-C-C(C)-O-CH3
3) C-C(C)-C-O-CH3
4) C-2C-OCH3
5) C-C-C-O-C2H5
6) C-C(C)-OC2H5
38. 6
Sol.
O O O H C O
 d    d  
39. 3
Sol.
Br Br Br
C C C C , C C
,
Br Cl OH
40. 1
Sol. X is Br-Mg –C = C-Mg-Br
Y is Br-Mg-COO-C C-COOH
Z is HOOC-C = C-COOH
P is HOOC-C(H)=C(H)-COOH
HOOC COOH
C C D
Q is H
D D
Maths solutions
41. D
Sol: x8  x5  x 4  x  1  0  x  R
42. A
Sol: x  x  3  x  0
(x  3)  x  0
x ( ,3)  Z
43. B
Sol: S  12  22 x  32 x 2  4 2 x 3  5 2 x 4 ....
SX  12  22 x 2  3x 3  4x 4 ....
-------------------------------------------
 1  x  5  1  3x  5x2  7x3  9x 4  ..
  1  x  x5   x  3x  5x  7x  ...
2 3 4
-------------------------------------------------
 1 x
2 2 3 4
s  1  2x  2x  2x  2x  ....
2x
= 1
1 x
2x  1  x
 1 x
2
s
1 x
1 x
s  f  x
 1 x
3
3
 
1
f    2  3  4  12
2 1
8
1
 1  4
f    2 3 
 2 3 27
2
 
44. C
x  tan1 x x 2  sin x x  t  x
Sol : , , is finite.
x3 x4 x2
45. C
Sol : f(x)  x 2020  x 2019  x 3  x 2  0
f(1) =0 = f(0) = f(-1)
Hence at least one root in (-1 , 0) and (0,1)
46. D
f I (x)   x  2020   t  1
2020 2019
Sol :
47. D
Sol : f(2)  2, f(x)  1  x   1,3   2
48. D
Sol : f I (x)  9x8  9  x  1
 a  8   a  8   0  a   , 8    8,  
49. C
Sol : hI (x)  (1  2f(x)  3 f(x)2 f I (x)  
h (x)  0 at x  0
I
50. B
x 2  sin x 2
Sol : x 0  2 lowest degree
x 4  sin x 2
51. A, B, C
Sol : f  5m  5   8f(5m)  5  5m  1
f(x)  x,  x  0, 1,2,5
52. C, D
Sol : f(x  1)  f(x  7)
Period is 8
53. A, C, D
Sol :
54. A,B,C,D
Sol : Apply L’ Hospital Rule.
55. A,B
2
Sol: f(x)  1 
x 4  x 2  2x  4
2
= 1
x 
 1   x  1  2
2 2 2
 f(x)  (1,2]
56. 3
Sol : ab  a  b , a,b  0, a  1
x 4

 9 (x 2  3)  0
x4  9  x2  3
x2  3  1
x  ( , 2]  [2,  )
57. 0
2
Sol : 2sec x  cos ec 2 x  16
1  sin2 x  2
58. 3
Sol : f I (x)  5x 4  3ax 2  a
f I (x)  0 x  R if D<0
 20 
9a2  20a  0 a   0, 
 a 
 20 
a   ,0    ,  
Or  a 
    0,   0
3a
  0 a   0,  
5
a=0
a=0,1,2
59. 6
Sol: f(x) has 5 roots
f I (x) has 4 roots
f II (x) has 3 roots
f I (x) f II (x) 7 roots
 f (x) f (x)
I II
6 roots
60. 4
Sol: h' (x)  2f(x)f I (x)  2g(x)gI (x)
=0
 h(x) is constant function.

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FIITJEE

41. D 42. A 43. B 44. C

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