FACULTY OF AGRICULTURE AND FOOD SCIENCE

CHM2000 General Chemistry

Group Work 03

Acid and Base

1. Complete the following table
[H+] [OH-] pH pOH
a) 3.98
b) 6.92x10-9
c) 9.77 x10-10
d) 7.08 x10-12
e) 2.69 x10-6
f) 2.34 x10-7
g) 8.99
h) 11.17

2. Determine:
a) A sample of rainwater has a pH of 5.5. What is the [H3O+] and pOH for the sample?
b) What volume of 0.120 M NaOH would be required to neutralize 25.0 mL of 0.160 M HCl?
c) A 2.50 g sample of Ba(OH)2 is dissolved in water. This solution requires 41.50 mL of HNO 3 for
neutralization. What is the molarity of the HNO3?
d) A 0.025 M solution of formic acid, HCOOH, has a pH of 2.75. Calculate the Ka for formic acid.
1.36 x 10-4
e) What is the pH of a solution of a 0.085 M solution of NH3? [Kb = 1.8 x 10-5]. NH3 + H20 → NH4 +
OH- pH=11.09

Organic Chemistry: Introduction and Conventions

1. Give the Lewis diagrams for ethene (C2H4), ethyne (C2H2) and methyl iodide (CH3I).
2. Determine the correct line structures for the following condensed structural formulae
a) CH3CH2CH(CH3)2
b) CH3CHBrCH2CH3
c) CH3CH(OH)CH(CH3)CH3
d) CH3C CCHO
e) 2,2,4-trimethylhexane
f) 3-ethyl-2,4,5-trimethyloctane
g) 2-bromo-2,4,6-trimethyloctane
3. The naming and structure of some simple haloalkanes
Name Structure
a) fluoroethane
b) CH3 – CH = CHCl
c) CH3 – CI = CH2
d) 3-chloropropene
4. Give the correct name for the structures given below:

5. Complete the following reactions

a) CH3CH2CH=CH2 + HCl → ______________
b) CH3C CCH3 + Br2 (excess) → ______________

c) _____________

d) _______________

e) _______________
6. Name the organic compound formed when 1,2-dibromoethane is heated with aqueous potassium
hydroxide. Show the chemical equation for the reaction.
7. What is meant by Grignard reagent? By using Grignard reagent, write an equation to show how
phenylmethanol, C6H5–CH2OH is synthesized.

I II III IV V VI VII VIII

1 2
1 H He
1.008 4.0026
3 4 5 6 7 8 9 10
2 Li Be B C N O F Ne
6.941 9.0122 10.81 12.011 14.007 15.999 18.998 20.179
11 12 13 14 15 16 17 18
3 Na Mg Al Si P S Cl Ar
22.990 24.305 26.982 28.086 30.974 32.06 35.453 39.948
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.098 40.078 44.956 47.88 50.942 51.996 54.938 55.847 58.933 58.69 63.546 65.38 69.72 72.59 74.922 78.96 79.904 83.80
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.468 87.62 88.906 91.22 92.906 95.94 (98) 101.07 102.91 106.4 107.87 112.41 114.82 118.69 121.75 127.60 126.90 131.29
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
6 Cs Ba « La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.91 137.33 138.91 178.49 180.95 183.85 186.21 190.2 192.22 195.08 196.97 200.59 204.38 207.2 208.98 (209) (210) (222)
87 88 89 104 105 106 107 108 109 110 111 112
7 Fr Ra § Ac Rf Db Sg Bh Hs Mt Uun Uuu Uub
(223) 226.03 227.03 (261) (262) (263) (262) (265) (266) (269) (272) (277)

58 59 60 61 62 63 64 65 66 67 68 69 70 71
« lanthanides Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140.12 140.91 144.24 (145) 150.36 151.96 157.25 158.93 162.50 164.93 167.26 168.93 173.04 174.97
90 91 92 93 94 95 96 97 98 99 100 101 102 103
§ actinides Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232.04 231.04 238.03 237.05 (244) (243) (247) (247) (251) (252) (257) (258) (259) (260)