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2- The hygroscopicity
The ability of a substance to remove moisture from the air. It is commonly expressed by
the relative humidity of the air with which the substance is in equilibrium
Degree of hygroscopicity of honey depends upon
a. Its specific composition
b. Its sugar composition
c. Its moisture content
Honey with 17.4% moisture content is in equilibrium with air at 58% relative humidity
The surface layer of honey takes up moisture rapidly. This water diffuses more slowly
into the depths of the container which can allow fermentation caused by yeast
50 15,9%
60 16,8%
70 24,8%
80 33,1%
When honey is exposed to dry air, it loses moisture more slowly because of the
formation of a relatively dry surface “skin”
Excessive moisture content of honey can be reduced by exposing it to air of relative
humidity lower than its equilibrium value
Even when packed in a screw-cap jar, honey can take up moisture
It influences the texture and color (become lighter in color) of the honey which
Crystallized honey is frequently more liable for the fermentation, if the yeast
spores exist
Forms of granulation of honey
1. Complete granulation
2. Partial granulation (occurs commonly in honey with high moisture content)
the lower layer is granulated
the upper one is in liquid status
1,58 None
1,99 ¼ granulated
Deterioration in color, flavor, and enzyme content occurs rapidly by storage at high
temperatures
All of these deteriorative changes can be avoided by storing honey at temperature of
15 C, but this low temperature causes honey to granulate
How to maintain the quality and flavor of honey?
Honey should be well-ripe and contain a proper moisture content
Honey must be free of foreign particles such as pollen grains, dust, wax particles
Honey shouldn’t be fermented
Honey must be free of odor, whatever their origin
simple sugars
2. Used in cooking and baking and confectionery industry
Give breads the flavor and soft texture because laevulose of honey is able to
absorb and keep moisture
Give breads the flavor and soft texture because laevulose of honey is able to
absorb and keep moisture
3) Used in the feeding of infants and children, especially children who suffer from
inflammation of intestines, bronchitis, constipation.ally children who suffer f
Compensate for the lack of iron in breast milk and cow milk
Promote appetite
Relieves anxiety
Added to many medicinal preparations to give them a flavor and sweet taste
Helps to sleep
Relieves cough
Against infertility
Reduces the time required to recover from the flu and the common cold
Increases appetite
Treatment of some eye diseases such as rheumatoid eyelids and sore iris and
keratitis
Does not cause erosion of tooth enamel compared with orange juice
Against diarrhea
Lowers the level of cholesterol in blood, which leads to the reduction of heart
disease and blood vessel diseases
Note: When honey is used for treatment, it should be taken at rate of 50-80
g/day for adult for at least 1.5-2 months
Honey adulteration
Adulteration is the introduction of any foreign
substance to honey either by feeding the
bees on it or in the store.
Adulteration could be by:
1- Colors
2- Flavors
3- Sugars
4- Mixing floral honey of different origin
5- Mixing floral honey with honeydew honey.
Honey
Honey
Honey is sweet-tasting viscous liquid, manufactured from nectar and/or honeydew
by honey bee workers
Worker bees store the honey in honeycomb inside the hive to be used in feeding of
brood and adult bees
b. Comb honey
It is honey contained in the cells of the comb in which is produced.
It may appear on the market in several forms;
Section comb honey
Individual section of comb honey
Bulk comb honey
Cut comb honey
Chunk honey
Chunk honey Section comb honey Liquid honey
The hygroscopicity
The ability of a substance to remove moisture from the air. It is commonly expressed
by the relative humidity of the air with which the substance is in equilibrium
Degree of hygroscopicity of honey depends upon
a. Its specific composition
b. Its sugar composition
c. Its moisture content
Honey with 17.4% moisture content is in equilibrium with air at 58% relative
humidity
The surface layer of honey takes up moisture rapidly. This water diffuses more
slowly into the depths of the container which can allow fermentation caused by
yeast
When honey is exposed to dry air, it loses moisture more slowly because of the
formation of a relatively dry surface “skin”
Excessive moisture content of honey can be reduced by exposing it to air of relative
humidity lower than its equilibrium value
Even when packed in a screw-cap jar, honey can take up moisture
Specific gravity
The ratio of the weight of a volume of a substance to the weight of the same volume
of water
The minimum density for top-grade honey corresponds to a specific gravity of
1.4129
The refractive index
The ratio of the velocity of light in the substrate to that in air
Used to determine the water content of honey
Dextrose (glucose) of the honey granulates more rapidly than laevulose (fructose)
due to its low solubility in water
Gluconic acid is one of the most important organic acids of honey, which is
produced from glucose by means of glucose oxidase enzyme
B. Inorganic acids of honey, such as
- Phosphoric acid - Hydrochloric acids
Amino acids are present in honey in very small quantity, so they do not have a
nutritional value in daily diet
Amino acids cause the honey to become darker in color over the time as a result of
their slow reaction with honey sugars, which is accelerated by heating
The average proportion of nitrogen of honey is 0.04% , reaching sometimes 0.1%
40%-65% of nitrogenous materials of honey is proteins and some amino acids
Honey may contain 8-11 proteins depending upon a kind of honey. It is believed
that the source of these proteins is worker bees, not the nectar
An increase the proportion of proteins reduces the surface tension of honey which
increases the possibility of formation of foam and small air bubbles
Diastase (amylase)
• Converts starch to simple substances
• Breaks down during honey storage
• Nectar doesn’t contain starch, therefore, its role in honey is still unknown
Phosphatase
Glucose oxidase; produced by worker bees and converts the glucose as follows
glucose oxidase
Glucose Gluconic acid (dominant in honey) + Hydrogen
peroxide (H2O2) (bacterial inhibitor)
Sources of enzymes of honey
1. Worker beed
- Invertase - Glucose oxidase - Diastase (amylase)
bees
small amount
7. Antibiotic activity of honey
Not the least of the many ancient uses for honey was in medicine as a dressing for
wounds and inflammations
Today medicinal use of honey is largely confined to folk medicine
Although modern medical literature describe its value in treatment of wounds,
burns, infections and other disorders
Anti-bacterial effect of honeys is referred to;
1. Glucose oxidase present in honey and produced by worker bees. This enzyme
converts glucose with end product of H2O2 (called inhibine or Dold) which inhibit
the growth of microorganisms
Amount of inhibine in honey depends on type of flowers, age of honey and
storage temperature
2. Density and acidity (pH 3.2-4.5) of honey
acidity of honey prevents the growth of bacteria
Density of honey suppresses the growth of normal yeasts
Aroma and flavor of honey
Volatile organic compounds are responsible for the flavor of honey, including;
Benzaldehyde
Furfural
Isovaleraldehyede
Phenylacetaldehyde
It influences the texture and color (become lighter in color) of the honey which
Crystallized honey is frequently more liable for the fermentation, if the yeast
spores exist
Forms of granulation of honey
1. Complete granulation
2. Partial granulation (occurs commonly in honey with high moisture content)
the lower layer is granulated
the upper one is in liquid status
Honey should not be exposed to direct fire flame because it adversely affect flavor
and color of the honey
How to avoid granulation of honey?
Clarify the honey from pollen, wax pieces and air bubbles by means of a strainer
or nylon cloth
Clean the supers off the honey thoroughly before reuse in the hive or storage in
winter
In USA, liquid honey is heated prior to packing at 63 ºC for 30 minutes,
or at 71 C for one minute followed by rapid cooling at 49-52 ºC
The degree of damage due to the fermentation of honey and its impact on the quality
and flavor of honey depends on:
Moisture content of the honey (fermentation doesn't occur when honey moisture
is 17.1% or below)
Soil of apiary
Honey inside the wax cells that isn’t capped yet is more liable to fermentation
than that is closed with wax capping
Deterioration in color, flavor, and enzyme content occurs rapidly by storage at high
temperatures
All of these deteriorative changes can be avoided by storing honey at temperature of
15 C, but this low temperature causes honey to granulate
How to maintain the quality and flavor of honey?
Honey must be free of foreign particles such as pollen grains, dust, wax particles
Compensate for the lack of iron in breast milk and cow milk
Promote appetite
Relieves anxiety
But because the body absorbs the fructose of honey more slowly than glucose,
as well as honey is more able to sweeten food than table sugar, it may be
introduced in the daily diet of diabetes patients in proper amount (related to
the composition of honey) after consulting the doctor
6. Medical uses of honey
Treatment of severe burns, cleaning and healing of superficial
wounds and wounds dressing
Treatment of asthma, blood pressure, arthritis, premature aging, heartburn
and stomach ulcers, acne, inflammation of intestines
Added to many medicinal preparations to give them a flavor and sweet taste
Helps to sleep
Relieves cough
Against infertility
Reduces the time required to recover from the flu and the common cold
Increases appetite
Treatment of some eye diseases such as rheumatoid eyelids and sore iris and
keratitis
Does not cause erosion of tooth enamel compared with orange juice
Against diarrhea
Lowers the level of cholesterol in blood, which leads to the reduction of heart
disease and blood vessel diseases
Note: When honey is used for treatment, it should be taken at rate of 50-80
g/day for adult for at least 1.5-2 months