Professional Documents
Culture Documents
JEE (Main)-2019
TEST DATE: 16-12-2018
SECTION – A
1. B
Sol. At higher temperatures, specific heat is also higher. Therefore, block with higher initial
temperature will suffer less change in temperature.
2. B
h y
Sol. 1/v vy
mv
v v 2y v 20 E0j
v0
v y uy a y t
qE0
vy 0 t
m x
(3v 0) = v 2y v 02
qE0
v 2y 8v 02 t 2 2v 0
m
2 2m
t v 0 t 1/E0
qE0
3. A
Sol. When switch is closed 2I I
Initially circuit is in steady state current through each
L2 L1
resistor as all are identical and are in parallel
combination. When switch is off current through L1 I I I
and L2 just after unchanged. So flow of current
remain same.
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AITS-FT-I –PCM(Sol.)-JEE(Main)/19 2
2I I
4. A
2
Sol. Icm + m(R + y) = I3 …(i)
2
Icm + m(R y) = I1 …(ii)
from (i) and (ii)
I1 I3 = m[(R y)2 (R + y)2]
I1 I3 = m(2R) (2y) …(iii)
Icm m(R x)2 I4 …(iv)
Icm m(R x)2 I2 …(v)
From (iv) and (v)
(I2 I4) = m[(R x)2 (R + x)2]
(I2 I4) = m[(2R) (2x)] …(vi)
from (iii) and (vi)
distance from CM from O
= x2 y 2
1
= (I1 I3 )2 (I2 I4 )2 , putting values d = 5 m
4MR
5. A
Sol. Velocity after time t, v = v0 gt mg
v 0 > 2g …(i) v0
Displacement in time ‘t’ a = g d = 1m
1
S v 0 t gt 2
2
1 1
1 = 2v 0 g(2)2 v 0 g …(ii)
2 2
From (i) and (ii)
1
g 2g
2
< 1/2g
< 0.05
6. A
Sol. 45 + r > C …(i) R
45 r > C …(ii)
r
90 > 2C
45 > C
r
sin 45 > sin C 45 r
1 1 45 r 45
2 45 +r 45 +r
> 2 r
taking equation 2 only 45
Q P
45 C > r , sin (45 C) > sin r
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3 AITS-FT-I –PCM(Sol.)-JEE(Main)/19
1 1 sin 45
cos C sin C
2 2
2
1 1 1
2 1 2 5
7. A
Sol. cos cos2
2 2
C1
cos = 1/3
/2
/2
C2
8. D
T 2v 2 v 2 v1
Sol. v and A t A i and A r Ai
v 2 v1 v 2 v1
9. C
Sol. r = 3R/8
2
m v 3R 3mv 2 2r
F 3N
2 R 8 16R
C.M.
10. C
11. B
vd
Sol. Use, N
12. C
Sol. In steady state,
AT4 = 2 A(300)4
4 4
and P + A(300) = 2 AT
4
P = 3A(300) = 3 kW
13. D
Sol. Wave speed v gx
dv 1 g
g gx
dt 2 x 2
g
A(2f )2 X
2
i.e., 82f 2A = g
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AITS-FT-I –PCM(Sol.)-JEE(Main)/19 4
14. C
v0 D 11
Sol. M 1
u0 fe 2
0.22
Smin 0.04 mm
11/ 2
15. A
1 T 1 1 Y
Sol. f
2 2 2
16. C
Sol. P = Ei i2r
E
and i for Pmax
2r
17. D
Pn
Sol. Cn , n : no of strokes
P0
18. B
Sol. Using conservation of energy A
2 +3C/2 3C/2
1 1 1 3 1 2
C(2)2 C 2 (C C) Limax C
2 2 2 2 2
C2 9C2 1 2
2C 2 Limax
2 4 2
imax
2 2
5C 9C 1 2
Limax
2 4 2 +3C/2 3C/2
C 2 1 2
Limax C B
4 2
C
imax
2L
19. A
3
1 h
Sol. In equilibrium (m + m) = tan2 g ( : semi-vertical angle of the cone)
3 2
When displaced slightly by y
3
1 h
fr (m m)g y tan2 g
3 2
6gy
a
h
1 6g
f
2 h
20. C
Sol. m1 m2 g KL
1 2
KL m1g 2L
2
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5 AITS-FT-I –PCM(Sol.)-JEE(Main)/19
21. D
Sol. Consider a pyramid of square base of side 2a .
22. B
Sol. L1di1i1 L 2di2i2 (Mdi1i2 Mdi2i1 )
1 2 1 2
L1di1i1 L 2 di2i2 Md(i1i2 ) L1i1 L 2i2 Mi1i2
2 2
23. B
Sol. M.S. reading 35 mm
X + 4V = nM
5
X = nM 4 M
8
X < 1 mm for n = 3 only
5 1
So, X 3 mm
2 2
reading = 35 + 0.5 mm
= 3.55 cm
24. B
Sol. Maximum number of particles will be emitted when dn/dE = 0
E
i.e. at E = max
5
4
Thus, maximum number of neutrinos would come out energy Emax .
5
25. D
Sol. Maximum p.d. can be 18 V 12 V 6V
9 4 36
Req
9 4 13
9V 9V
Pmax = 117 W
26. A
Sol. In equilibrium T = mg and RT = R2BI
27. A
Sol. For central maxima P
( 1)t dsin , t
S1 y
( 1)t (1.5 1)1 105 1
sin 3
d 1 10 200 d O
for small
S2
1 y 1
tan ,
200 D 200
y = 0.5 cm
D=1m
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AITS-FT-I –PCM(Sol.)-JEE(Main)/19 6
28. D
A max A min
Sol. Modulation index =
A max A min
29. B
Sol. Basic Concept
30. A
PV P(atm)
T
Sol. R
T will be maximum when PV is maximum
curve
PV (4 2sin )(4 2cos )
T
R R Isothermal curve
As sin and cos both can not be equal to 1 for same temperature 24/R
value of
T can not be 36/R V(lit)
Tmax should be less than 36R
Curve is above isothermal curve
temperature is more than 24/R on the given process
So Tmax lie between 24/R and 36/R
Only one option is present.
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7 AITS-FT-I –PCM(Sol.)-JEE(Main)/19
Chemistry PART – II
SECTION – A
31. B
Sol. In ccp number of O2- ions per unit cell = 4
Total negative charge per unit cell = 4 × 2 = 8
Number of tetrahedral voids = 4 × 2 = 8
Number of octahedral voids = 4 × 1 = 4
12.5
Number of tetrahedral voids occupied 8 1
100
Number of negative charges left unneutralized = 8 – 2 = 6
3+ 6
Number of Y ions required to occupy octahedral voids 2
3
2
Fraction of octahedral voids occupied 0.5
4
32. D
Sol. Cl
O
H
Cl ,h KOH O / Zn
2
1 eqv.
C H OH
3
CS
H
2 5 2
X Y Z O
33. B
34. A
Sol. (A) XeF4 O 2F2
XeF6 O2
(B) XeF4 H2
Xe HF
(C) XeF4 KI
KF Xe I2
(D) XeF4 SF4
SF6 Xe
35. B
Sol. (A) Al OH 4 aq NH4 aq Al OH 3 NH3 H2 O
White
(B) Pb2 aq 2Br aq PbBr2 White
(C) BiI3 black precipitate H2 O BiOI orange
(D) S2 Na2 Fe CN5 NO Na 4 Fe CN5 NOS
Purple colouration
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AITS-FT-I –PCM(Sol.)-JEE(Main)/19 8
36. B
Sol.
InOH
In OH
In OH
Kb
InOH
In
Also pOH pK b log
InOH
At pH = 3.3, pOH = 14 – 3.3 = 10.7, the indicator will be sufficiently ionized to give the colour
solely due to In ion.
Hence,
In
10.7 pK b log
InOH
In
14 pk a log
InOH
14
3.3 4.7 log In
2 InOH
In
log 0.7 log5
InOH
In
5
InOH
37. B
200
Sol. Amount of H2C2O4 in 200 cm3 of original solution 0.5 90 9.0 g
1000
32 0.25
Molarity of filterate 0.4 M
2 10
Amount of the acid left out after adsorption = 0.4 × 0.2 × 90 = 7.2 g
Amount of the acid adsorbed = 9.0 – 7.2 = 1.8 g
1.8
Amount of the acid adsorbed (x/m) per gram 0.2
9
38. A
Sol. EoFe3 /Fe2 3EFe
o
3
/Fe
o
2EFe2
/Fe
= 3 × (- 0.04) – 2 × (- 0.44) V
= 0.76 V
Fe3 e Fe2
2.303RT Fe2
o
EFe3 /Fe2 EFe3
/Fe 2
log 3
F Fe
Fe2
0.718 0.76 0.06log 3
Fe
Fe2 0.042 Fe2
log 0.7 log5 5
Fe3 0.06 Fe3
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9 AITS-FT-I –PCM(Sol.)-JEE(Main)/19
39. A
Sol. Meq. of H2SO4 taken to absorb NH3 = 50 × 0.2 = 10
Meq. of H2SO4 left after NH3 absorption = Meq. of NaOH used for H2SO4 = 25 × 0.19 = 4.75
Meq. of H2SO4 used for NH3 = 10 – 4.75 = 5.25
1.4 NV 1.4 5.25
%N 4.2%
wt. of Fertilizer 1.731
40. C
Sol. Meq. of H2SO4 (original) = 30 × 1 = 30 meq.
Meq. of H2SO4 after passing NH3 = 30 × 0.2 = 6
Meq. of H2SO4 reacted = Meq. of NH3 = 30 – 6 = 24
WNH3
1000 24 WNH3 0.408 g
17
0.408
Volume of NH3 at STP 22.4 0.5376lit
17
= 537.6 ml.
41. D
Sol. Diborane forms adduct at low temperature
B2H6 2NH3 B2H6 .2NH3
B2H6 .2NH3 on heating to 200oC gives borazole
o
200 C
3B2H6 .2NH3 2B3N3H6 12H2
24
Moles of addition product = moles of diborane
28
2 24
Moles of borazole
3 28
2 24
Weight of borazole 81 46.29 g
3 28
42. C
Sol. [Ni(CN)4]2– is square planar and coloured.
[NiCl4]2– is tetrahedral and contains Ni(II) which is coloured.
K2[Zn(CN)4] is tetrahedral and colourless.
43. C
Sol. The colloidal solution has positively charged particles.
44. A
1
Sol. NH4NO3 N 2 O 2H2O
0
NH4 2 Cr2O7 N2 4H2 O Cr2 O3
4
Hg NO3 2 Hg 2NO2 O2
3
Na NH4 HPO 4 .4H2O NaPO3 NH3 5H2 O
+1 + 0 + 4 – 3 = (+ 2)
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AITS-FT-I –PCM(Sol.)-JEE(Main)/19 10
45. B
Sol. NaBr aq Na aq Br aq
0.01 0.01
K sp
AgBr s
Ag aq Br aq
0.01
K sp Ag Br
K sp 0.01 0.01 0.01
1010 0.01 108
Solubility in pure water is K sp 10 5 M
10 8
Factor by which solubility changes = 103
10 5
x 3
46. C
Sol. SO 2 PCl5 SOCl2 POCl3
X
SOCl2 H2 O
SO2 2HCl
Pungent smell
47. C
Sol. Polystyrene, Teflon and Polyacrylonitrile are addition homopolymer, whereas melamine is
copolymer.
48. D
Sol. -Ketoacid, - - unsaturated acid and 1-3 diacid decarboxylates on heating, where as 1-4 diacid
dehydrates on heating.
O O
H 2C C OH H 2C C
H 2 O
O
H 2C C OH H 2C C
O O
49. D
Sol. Siderite → FeCO3
Anglesite → PbSO4
50. B
Sol. Vitamin C is water soluble, but Vitamin D is fat soluble.
Morphine is used as analgesic.
Vitamin E is known as lactoflavin.
51. A
Sol. MnO2, is a selective and specific oxidizing agent which oxidizes allylic or benzylic hydroxyl group
o o
to carbonyl group (C = O) where as PCC is a mild oxidant which oxidizes 1 and 2 ROH to
aldehyde and ketones respectively.
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11 AITS-FT-I –PCM(Sol.)-JEE(Main)/19
52. C
Sol. Radius (x1) of nth orbit for H-atom = r1 × n2
If n is lower orbit, the next orbit = n + 1
2 2
and x2 = r1 (n + 1) = r1(n + 2n + 1)
x2 – x1 = r1 (2n + 1)
If n is higher orbit, then consecutive lower orbit = n – 1
2
and x 2 r1 n 1 r1 n2 2n 1
x1 x 2 r1 n2 r1 n2 2n 1 r1 2n 1
53. A
Sol. OEt OEt
NH2 NH2
C O
O
EtOH
C O
NH2 O
NH2
OEt OEt
H
H
N O
N O
EtOH
NH2 O
OEt N O
H
54. A
Sol. Cl2 2NaOH
NaCl NaOCl H2O
3Cl2 6NaOH 5NaCl NaClO3 3H2 O
55. B
A B C D
Sol. At t 0 400mm
After 2 hrs 400 x x x x
As per question 400 – x + x + x + x = 800
x = 200
2.303 Po
k log A
2 PA
2.303 400
log
2 200
-1
= 0.346 hr
56. D
Sol. D-Glucose and D-Fructose are reducing sugar.
Glycogen and dextrin are non-reducing sugars.
-D-(+) glucopyranose is an example of hemiacetal.
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AITS-FT-I –PCM(Sol.)-JEE(Main)/19 12
57. D
Sol. H2C OH CHO CH2OH
H O /FeSO /
HC OH
2 2 4
CHOH C O
58. B
T2 V
Sol. S nCV n nRn 2
T1 V1
600
= 2.303 × 5 × 3 × log
300
= 10.39 cal/K
59. B
Sol. German silver, Gun-metal and Bronze are alloys of copper but magnelium is alloy of aluminium
and magnesium.
60. B
HCl
Cl MgCl COOH
Peroxide Mg/ether i) CO 2
+
ii) H 3O
(E) (F)
(D)
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13 AITS-FT-I –PCM(Sol.)-JEE(Main)/19
SECTION – A
61. C
Sol. (9 – x1) + (9 – x2) + (9 – x3) + (9 – x4) + (9 – x5) + (9 – x6) = 49
x1 + x2 + x3 + x4 + x5 + x6 = 5
Number of solution is
62. D
Sol. A3 = A2·A = (2I – A)A = 2A – A2 = 2A – (2I – A) = 3A – 2I
A4 = A3·A = (3A – 2I)A = 3A2 – 2A = 3(2I – A) – 2A = 6I – 5A
5 2
A = (6I – 5A)A = 6A – 5A = 6A – 5(2I – A) = 11A – 10I
P = 11 and K = –10
63. B
1 cos x x sin x 1 1 cos x x sin x
Sol. x sin x 2 cos2 x dx = 2
dx
cos x
1
x sin x 2
x sin x
cos x 1 1 cos x
Let t 1 t2 dt tan t c tan1 c
x sin x x sin x
64. D
Sol. Around x = 4 f(x) = 3 – sin(x – 2)
It continuous and differentiable f(x) = –cos(x – 2)
65. B
sin cos2 cos 2 sin2 cos3
Sol. cot
cos sin cos sin cos cos2 cos sin
cos 6 sin6 cos7
Similarly,
cos sin cos cos 6 sin
5 6
66. B
1
dy
Sol. y k (where k f x dx )
dx 0
y = cex – k if f(0) = 1 c – k = 1
1 1
e 1 2 e 1
ce
x
k f x dx k k dx 2k = c(e – 1) k c c and k
0 0 2 3e 3e
67. D
2
cos A cosB cosC a2 b2 c 2 a b c 2 ab bc ca 144 94 5
Sol. = =
a b c 2abc 2abc 120 12
68. A
Sol. C1C2 = |r1 + r2| or C1C2 = |r1 – r2|
10 = |(5 + 0.2t) + (3 + 0.3t)| or 10 = |5 + 0.2t – 3 – 0.3t|
t = 4 sec or t = 120 sec
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AITS-FT-I –PCM(Sol.)-JEE(Main)/19 14
69. B
2 2
Sol. 4cot x 4 or 4cot x 16
cot2 x = 1 or cot2 x = 2
Number of solution 2 + 2 = 4
70. D
Sol. B is fixed x my n 0 passes and we know 2m n 0 point B is (1, –2)
Side length = 52
3 3
Area of equilateral triangle = a2 = 52 13 3
4 4
71. C
1 1 1
Sol. Domain , a = and b = 1
2 3 3 2
5 1
Range 0, c = 0 and d =
6 6
72. B
n n
1 1 1
Sol. fk 4k sin2 2k 1 cos2 2k = 4k sin2 2k 4 sin2 2k 1
k 0 k 0
n
1 1 1
= 4k sin2 2k 4k 1 sin2 2k 1 1
k 0
= sin2
4n1
sin2 2n1
3 3 1 3
f4 sin sin2 32 1 f 5() = 0
2 2 1024 2
73. C
Sol. Let f(x) = x2 – 2ax + a2 – 4
A B = {x : –2 < x 1} 4
b –2 1
graph of f(x) must be i.e. 1 and f(4) 0
2a
a 2
1 and 16 – 8a + a – 4 0
2
a > 2 and a a is 3 Least value of a is 3
74. D
Sol.
a / b r5
1
r = –2
7
a / b r 4
75. C
2 2 2
Sol. As x + 3x + 5 + 0 has non-real roots so the equations x + 3x + 5 = 0 and 3x + px + r = 0 have
3 p r
both roots common i.e., p = 9 and r = 15
1 3 5
pr
q q = 12
2
PQR is right angled triangle therefore circumradius is half of length of hypotenuse
15 54
Circumradius = and = rs r 3
2 s 18
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15 AITS-FT-I –PCM(Sol.)-JEE(Main)/19
76. C
1 n 1
1 1
Sol. f n cot 1 k tan1 k cot 1 k tan1 k = tan1 k tan1 k 0 = n
k n k 1 k n
10 10
n n 1 2n 1 99
n2 n 2
77. B
n
n
r 2 n
r 1 1 n n n
C n
1 n 1 2n 1
Sol. r 1 nCr Cr = n Cr r 1r = 2n Cr 1 = 2n
r 0 r 0 r 1 r 0 r 0 r 0 n 1 n 1
n
2 n 3 1
= n = 13
n1
78. C
4 n2 4
n2 n2
Sol. L 1 2 2 =
n 3 n n3 n n 3 n n3 n
1 2 3 n2 5 6 7 n 1 n 2
L ..... .....
3 4 5 n 3 4 5 n 1 n
L
1 2
n 1 n 2
; lim
2 n2 3n 2
1
n n 1 34 n 2
12 n n 6
2
n 1 n n 1 1 2 3 4 n 2 n 1 7 13 21 n2 n 1
M 2 = ..... .....
n 2 n 1 n n 1 3 4 5 6 n n 1 3 7 3 n2 n 1
2 n2 n 1 2 2
= n2 M
n n 1 3 3 3
n 12
n1
n1 2 n 1
N = n 2 = 2 N=2
n 1 n n 2 n 1 n 1 n n2
3 1
L–1 + M–1 + N1– = 6 8
2 2
79. B
Sol. (z1 + 2)(z2 + 2)(z3 + 2) = z1z2z3 + 2(z1z2 + z2z3 = z3z1) + 4(z1 + z2 + z3) + 8
= 1 + 2(z1z2 + z2z3 + z3z1) + 4 + 8 = 13 + 2(z1z2 + z2z3 + z3z1)
1 1 1 1 1 1
Now z1z2 + z2z3 + z3z1 = z1z2 z3 =
z
1 z 2 z 3 z1 z 2 z 3
z1 z2 z3
= 2
2
2
= z1 z2 z3 = z1 + z2 + z3 = 1
z1 z2 z3
80. B
4
Sol. Total ways in which 4 customers can order is 5 = 625
th 5
Now for the 4 person, number of ways is C1 = 5 and for the other three persons, number of
ways = 4 4 4
Total number of ways 4th person orders unordered item = 5 43
th 5 43 64
Probability that 4 person orders an unordered item = 4
55 125
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AITS-FT-I –PCM(Sol.)-JEE(Main)/19 16
81. D
2 2
Sol. C1: (x + 2) + y = 16
2 2
C2 : (x – 1) + y = 100
CC1 = r + r1 and CC2 = r2 – r CC1 + CC2 = r1 + R2 = 14
Locus of C is an ellipse whose focus is at C1 and C2 and length of major axis = 14
3
2a = 14 and 2ae = 3 e
14
82. B
Sol. Put x = 0, y = 0, we get f(0) = –4
f x h f x f x f h 3xh x h 8xh 4 f x
f x lim = lim
h 0 h h 0 h
f h 3xh x h 8xh f 0
= lim (as f(0) = –4)
h 0 h
2 2 3 2
= f(0) + 3x + 8x = 3x + 8x f(x) = x + 4x + c
as f(1) = 1 c = –4
f(x) = x3 + 4x2 – 4 f(x) = x3 + 4ex x2 – 1= ex which has one solution
83. C
D(0, 0, 0)
Sol. Given b a 12 ; c 6
Equation of CD is r c 6
Equation of AB is r a b a
A a C c
Shortest distance between AB and CD
a c ba
a c b
= 8 8 12
c ba c ba
a c b 8 c b a
B b
1
6 volume of tetrahedron = 8 c b a
2
v = 48
84. D
x
Sol. f(x) = –((x2 – x + 1)ex + ex(2x – 1)) + ex·e–x·f(x) + ex e y f y dy
0
x
f x f x e x y f y dy e x x 2 x
0
0 = f(x) + (x2 – x + 1)ex – ex(x2 + x)
f(x) = ex(x2 + x – x2 + x – 1)
f(x) = ex(2x – 1)
f(x) = ex2 + (2x – 1)ex
f(1) = e; f(1) = 3e
85. A
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17 AITS-FT-I –PCM(Sol.)-JEE(Main)/19
86. A
Sol. Any point on the parabola y2 = 4ax is (at2, 2at)
x2 y2
Equation of the chord of the ellipse 1
2a2 a2
Whose mid-point is (at2, 2at) is T = S1
at 2 2at a2 t 4 4a2 t 2
x 2 y 2 tx + 4y + at3 + 8at
2a a 2a2 a2
a2 a2
As it passes through 20a, 20at 4 at 3 8at
2 2
3 2 3
at – 12at + 2a = 0 t – 12t + 2a = 0 (a 0)
Now three should be 3 distinct values of t for three distinct chords
Let f(t) = t3 – 12t + 2a; f(t) = 3t2 – 12 = 0 t = 2
So f(2) f(–2) < 0 (a + 8)(a – 8) < 0
14 values of a are possible (a 0)
87. D
x
x f x
Sol. f t dt x f x . Differentiating w.r.t. to x, we get f x 2 f x f x
0
2 2 3/2 1 2 1/2 2
2f(x)3/2 = xf(x) + 2f(x); f x f x f x ; 3/2
f x f x
x x f x x x
1/2 dt 1 3/2 dt 2t 2 dt 1 1
Let f x f x
t f x 2 t
dx 2 dx x x dx x x
1
Solving, we get t = 1 + cx; i.e., 1 cx
f x
1 1 1
f 1 c=1 f x f x
4 1 x 1 x 2
1 1
Now f(x) = cosec x 2
(1 + x)2 = sin x; No solutions
1 x sin x
88. B
2 2
Sol. Radius of director circle = a2 b2 8 a + b = 64
36 3 2
50 + b2 = 64 b2 = 14 ; b2 = a2(1 – e2) 14 = 50(1 – e2) e2 e
50 5
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AITS-FT-I –PCM(Sol.)-JEE(Main)/19 18
50
Slope of line joining centre and vertex = 1 foci lies on this line
83
3 2 1 3 2 1
Foci (x, y) can be (x, y) = 8 5 2
5
2
, 05 2
5
= 8 3 2, 3 2
2
3 2 1 3 2 1
or (x, y) = 8 5 2 , 05 2
5 2 5 2
89. B
Sol. 1 + cosec4 1 2
4
2 + cot 2 2 and 4 + sin 43 3
L.H.S. 12
2 4
Only possibility is sin 1 = 1, cot 2 = 0 and sin 43 = –1
3 5 3 5 3 7 11 18
1 , , ; 2 , , ; 3 , , ,
2 2 2 2 2 2 8 8 8 8
Number of triplets are 3 3 4 = 36
90. A
2019
dx
Sol. I1 ..... (1)
2017 5 2x x 1 e
2 3x 3
b b
Using the property f x dx f a b x dx , we get
a a
2019
dx
I1 ..... (2)
2017 5 2x x 1 e
2 3 3 x
2019
dx
Adding equation (1) and (2), we get 2I1
2017 5 2x x
2
I1 1
2I1 = I2
I2 2
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