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COM } ON GOOGE
Options:
(a) 3,2,4
(b) 0,2,3
(c) 4,0,4
(d) 0,2,2
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Ans. Option (c) is correct
Explanation:
Before solving the or guessing the options, you should check either the given molecule is
symmetrical or unsymmetrical
The given molecule is unsymmetrical as it has group X at one end and group Y at other end
Then after you need to find out the number of chiral carbon
Now come to formula to calculate the number of enantiomer, meso isomer and total number of
optical isomers
Note:
A meso compound is one which is optically inactive although have more than one chiral carbons.
Chiral carbon, n= 2
So Number of enantiomer = 2n = 22 = 4
(b) 12
(c) 4
(d) 9
Explanation:
Here in Glucose molecule the number of chiral carbon is = 4, as shown in the figure
Note:
• The stereoisomers which are non superimposable mirror images of each other is known as
enantiomer
Options:
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(a) Enzymes
(c) Chemisorption
(d) Rotation
Explanation:
Enantiomer has different biological properties and hence can be separated by enzymes
Q4. Select the correct stability order of the conformation /Rotamers/ Rotational isomers of Ethane
Molecule
Options:
(a) Partially Eclipsed > Fully Eclipsed > Anti-staggered > Skew or Gouche
(b) Skew or Gouche > Partially Eclipsed > Fully Eclipsed > Anti-staggered
(c) Anti-staggered > Skew or Gouche > Partially Eclipsed > Fully Eclipsed
(d) Fully Eclipsed > Anti-staggered > Skew or Gouche > Partially Eclipsed >
Explanation:
• The isomers which can be produced by the free rotation about single bond are known as
conformation /Rotamers/ Rotational isomers and this phenomenon is called as conformational
analysis
1. sawhorse projection
3. A staggered conformer is more stable than an eclipsed conformer as the latter involves
unfavourable energy interactions between atoms.
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4. In conformational analysis (energetics study of different rotational conformers or rotamers),
structures are represented by *Newman projection * (atoms and bonds are viewed along the axis of
rotation).
Options:
(a) H2SO4
(b) P2O5
(c) BF3
(d) NaOH
Explanation:
Beckmann rearrangement is only catalysed by Acid catalyst and used to determined the
configuration of ketoximes
n
r3 8
Q 6. Solve lim
r 3 r 8
n 3
Options:
2
(a)
3
2
(b)
5
2
(c)
7
1
(d)
7
3 2 32 4 2 3 4 2 42 4 2 4
lim . .
n 3 2 32 4 2 3 4 2 4 2 4 2 4
n 2 n2 4 2 n
........................................... . 2
n 2 n 4 2 n
3 2 4 2 5 2 n 2
lim . . ...............
n 3 2 4 2 5 2 n 2
32 4 2 3 42 4 2 4 n 2 4 2 n
2 . ...............
3 4 2 3 4 4 2 4 n 2 4 2 n
2
1.2.3.4.5.6....... 19.28.39.52.63.........
lim
n
5.6.7.8....... 7.12.19.28.39.52.63..............
1 2
lim 1.2.3.4.
n
7.12 7
1
1
Q 7. The value of lim by a 1 y dy is where b > a.
x
x
x 0
0
Options:
1
1 bb b a
(a) a
ea
1
bb b a
(b) a
a
1
1 ab ba
(c) a
eb
1
1 bb a b
(d) a
ea JOIN @iitwale on Telegram
Ans. Option (a) is correct
Explanation:
1
1 x
Let L lim by a 1 y dy
x
x 0
0
1
Let I by a 1 y dy
x
Let by a 1 y t , b a dy dt
tx t x 1
I dt
b a x 1 b a
by a 1 y x 1
I [Computed at y = 1 and y = 0]
x 1 b a
b x 1 a x 1
I
x 1 b a
1
b x 1 a x 1 x
L lim
x 0 x 1 b a
b x 1 a x 1
In
x 1 b a
In L lim
x 0 x
b x 1 In b a a 1In a 1
In L lim
x 0
x 1 b a x 1
1 bb
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ba a
1
1 bb b a
L a
ea
Q 8. lim x x x x is equal to
x
Options:
(a) 0
(b) 1/2
(c) log2
(d) e2
Explanation:
lim x x x x
x
x x x x
lim
x
x x x x
1 x 1/2 1
lim
x 2
1 x 1 x 3/2 1
Q 9. Find lim
x 9 2 e x 28
x 0 x
Options:
(a) 0
(b) DNE
Explanation:
3
We have f x x 9 2 e x 28
f x f 0
Now, we can write the limit as lim which is the definition of f ' 0 .
x 0 x0
Now,
1
3
f ' x x 9 2 ex
2
1
3
f ' 0 0 9 2 e0
2
9
1
2
11
2
x 1
Q 10. Find lim
x 1 x 1
ln x
Options:
(a) 0
(b) DNE
(c) 1/2
(d) 0
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Explanation:
x 1 x ln x x 1
lim lim
x 1 x 1
ln x x1 x 1 ln x
ln x 1 1 x ln x
lim lim
x 1
ln x
x 1
x 1
x ln x x 1
x
ln x 1 ln1 1 1
lim
x 1 ln x 1 1
ln1 1 1 2
Q 11. Four particles, each of mass M and equidistant from each other, move along a circle of
radius R under the action of their mutual gravitational attraction. The speed of each particle is:
Options:
(a)
GM
R
1 2 2
(b)
1 GM
2 R
1 2 2
GM
(c)
R
GM
(d) 2 2
R
Options:
(a) 96 N
(b) 108 N
(c) 120 N
(d) 150 N JOIN @iitwale on Telegram
Explanation:
Rearth
Rplanet …(i)
10
earth planet
M earth M planet
4 3 4 3
Rearth Rplanet
3 3
M
M planet earth
103
Now,
M earth
GM planet G
g planet 103 GM earth
2 2 2
Rplanet Rearth 10 Rearth
10
x
gdepth of planet gsurface of planet
R
where, x = distance from centre of planet
Total force on the wire,
R
x g x
2
R
F dx g
4 R /5
R R 2 4 R /5
Substituting the given values we get F = 108 N
Q 13. Two bodies, each of mass M, are kept fixed with a separation 2L. A particle of mass m is
projected from the midpoint of the line joining their centres, perpendicular to the line. The
gravitational constant is G. The correct statement is
Options:
(a) The minimum initial velocity of the mass m to escape the gravitational field of the two
GM
bodies is 4
L
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(b) The minimum initial velocity of the mass m to escape the gravitational field of on Telegram
the two
GM
bodies is 2
L
(c) The minimum initial velocity of the mass m to escape the gravitational field of the two
2GM
bodies is
L
(d) The energy of the mass m is not constant.
Explanation:
Options:
Explanation:
Given,
1 GM e m
= mV2 +
2 Re
At highest point h,
V= 0
GM e m GM e m GM e m
And, Potential energy = = 0+ =
Re h Re h Re h
Total energy of the rocket at the Earth`s surface= Total energy at height h
1 GM e m GM e m
mV 2
2 Re Re h
1 1 1 R h Re
mV 2 GM e = GM e e
2 e
R R e h e e
R ( R h )
1 2 GM e h R
V e
2 R e ( R e h) R e
1 2 gRe h
V
2 ( R e h)
GM
Where, g= 2
9.8m / s 2 (Acceleration due to gravity on the Earth`s surface.)
Re
Therefore, V2(Re+h) =2gReh
V2Re = h(2gRe – V2)
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ReV 2 6.4 10 6 (5 10 3 ) 2
h= =
2 gRe V 2 2 9.8 6.4 10 6 (5 10 3 ) 2
6.4 25 1012
h= 1.6 10 6 m
100.44 10 6
Height achieved by rocket with respect to the centre of the Earth= Re+ h = 6.4× 106 + 1.6 10 6 m
= 8.0 ×106 m
Q 15. What is the minimum energy required to launch a satellite of mass m from the surface of a
planet of mass M and radius R in a circular orbit at an altitude of 2R?
Options:
5GmM
(a)
6R
2GmM
(b)
3R
GmM
(c)
2R
GmM
(d)
3R
Ans. Option (a) is correct
Explanation:
Q 16. Which of the following statements is not correct about order of a reaction?
Options:
Explanation:
Order of reaction is equal to the sum of powers of concentration of the reactants in rate law
expression.
For any chemical reaction
x A + yB Product
Rate = k [A]x [B]y
Order = x + y
Order of reaction can be a fraction also. Order of reaction is not always equal to sum of the
stoichiometric coefficients of reactants in the balanced chemical equation. For a reaction it may or
may not be equal to sum of stoichiometric coefficient of reactants.
Q 17. In a reaction if the concentration of reactant A is doubled, the rate of reaction becomes eight
times. What is the order of the reaction?
Options:
(a) 2
(b) 3
(c) 8
(d) 4
Ans. Option (a) is correct
Explanation:
n 3 n
1 1 1 1
8 2
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Hence, n = 2
Q 18. The expression to calculate time required for completion of zero order reaction is
Options:
k
(a) t
0
R
R 0
(b) t
k
k
(c) t
2 R 0
R 0
(d) t
2k
Explanation:
Options:
(a) 3.8%
(b) 65.4%
(c) 39.5%
(d) 48.5%
Options:
Explanation:
Explanation:
Q 22. The function f x 2 x x 2 x 2 2 x has a local minimum
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x is equal to on Telegram
Options:
(a) – 2
(b) 2
(c) 3
(d) – 2/3
Ans. Option (a) is correct
Explanation:
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x2 y 2
Q 23. If the straight line x cos + y sin = p touches the curve 1 , then
a 2 b2
Options:
Explanation:
x2 y 2
We have, if a line y = mx + c touches ellipse 2 2 1, , then the required condition is
a b
c2 = a2 m2 + b2
The equation of given line is x cos + y sin = p
p x cos
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y
sin
p
y x cot
sin
p
Now, c and m = cot
sin
p
a ( cot ) b
2 2 2
sin
p 2
cos 2
2 a2 b2
sin sin 2
p 2 a 2 cos2 b2 sin 2
Q 24. Two men A and B start with velocities v at the same time from the junction of two roads
inclined at 45° to each other. If they travel by different roads, then find the rate at which they are
being separated.
Options:
(a) 2 2 v unit/s
(b) 2 2 v unit/s
(c) 2 2 v unit/s
(d) 2 2 v unit/s
Explanation:
Let two men start from the point C with velocity v each at the same time.
Also, BCA = 45
Since, A and B are moving with same velocity v, so they will cover same distance in same time.
Therefore, ∆ABC is an isosceles triangle with AC = BC.
Now, draw CD AB.
Let at any instant f, the distance between them is AB.
Let AC = BC = x and AB = y
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In ∆ACD and ADCB,
CAD = CBD [ AC = BC]
22 π 22
2v sin
2 8 2
2 2 v unit/s
which is the rate at which A and B are being separated.
Q 25. The approximate volume of metal in a hollow spherical shell whose internal and external
radii are 3 cm and 3.0005 cm, respectively is
Options: JOIN @iitwale on Telegram
(a) 0.1807
(b) 0.01807
(c) 0.01087
(d) 0.01807
Explanation:
Options:
(a) 110.15
(b) 107.15
(c) 117.15
(d) 120.15
Explanation:
a = 4.07 × 10−8 cm
d = 10.5 g cm−3
zM
d
a3 N A
da 3 N A 10.5 4.077 108 6.022 1023
m 107.15 g / mol
z 4
Q 27. CsCl crystallises in body centered cubic lattice. If 'a' is its edge length, then which of the
following expressions is correct?
Options:
3a
(b) rCs rCl
2
3
(c) rCs rCl a
2
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(d) rCs rCl 3a
Explanation:
In CsCl, CI– lies at corners of simple cube and Cs+ at the body centre. Hence, along the body diagonal, Cs+
and Cl– touch each other so
rCs rCl 2r
3a
r
4
3 3
Hence, rCs rCl 2r 2 a a
4 2
Q 28. A cubic solid is made of two elements P and Q. Atoms of Q are at the corners of the cube
and P at the body-centre. What is the formula of the compound?
Options:
(a) PQ
(b) P2Q3
(c) PQ2
(d) P2Q
Explanation:
1
No. of atoms of Q in one unit cell 8 1
8
Therefore, the formula of the compound & coordination number of both P and Q is PQ.
Q 29. Gold (atomic radius = 0.144 nm) crystallises in a face-centred unit cell. What is the length of
a side of the cell?
Options:
(a) 0.107 nm
(b) 0.207 nm
(c) 0.307 nm
(d) 0.407 nm
Explanation:
r 0.144 nm
Q 30. The total number of tetrahedral voids in the face centred unit cell is ………. .
Options:
(a) 6
(b) 8
(c) 10
(d) 12
Fcc unit cell contains 8 tetrahedral voids at centre of each 8 smaller cube of an unit cell as shown
below:
dy
Q 31. The solution of the differential equation 1 e x y is
dx
Options:
(a) (x + C) ex − y + 1 = 0
(b) (x − C) ex − y + 1 = 0
(c) (x − C) ex − y − 1 = 0
(d) (x − C) ex − y + 1 = 0
Explanation:
dy
Given differential equation is 1 e x y …(1)
dx
On substituting x − y = t, we get
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dy dt
1
dx dx
dt
Eq. (1) becomes et
dx
et dt dx
e t x C
1
xC
e x y
1 = (x + C) ex − y
(x + C) ex − y + 1 = 0
Q 32. The differential equation of all circles which pass through origin and whose centres lie on Y-
axis is
Options:
(a) x 2 y 2 dy
dx
2 xy 0
(b) y 2 x 2 dy
dx
2 xy 0
(c) x 2 y 2 dy
dx
2 xy 0
(d) x 2 y 2 dy
dx
2 xy 0
Explanation:
We have, circles pass through origin and their centres lie on Y-axis. Let (0, k) be the centre of the
circle and radius is k.
The general equation of the circle is (x a)2 + (y b)2 = r2 , where (a, b) is the centre and r is the
radius of the circle.
Now, the equation of circle is (x 0)2 + (y k)2 = k2
x2 + y2 2ky = 0
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x2 y 2
k …(1)
2y
On differentiating Eq. (1), w.r.t. x, we get
y
2 y 2x 2 y x2 y 2
dx
2dy
dx
2
0
4y
dy
4 y x y 2 x2 y 2
dx
dy
dx
0
4 xy 4 y 2
dy
dx
2 x2 y 2
dy
dx
0
dy
[4 y 2 2( x 2 y 2 )] 4 xy 0
dx
dy
(2 y 2 2 x 2 ) 4 xy 0
dx
x 2
y2 dy
dx
2 xy 0
Q 33. Find the equation of a curve passing through the point (2, 1), if the tangent drawn at any
point P(x, y) on the curve meets the coordinate axes at A and B such that P is the mid-point of AB.
Options:
(a) xy = 2
(b) y = x
(c) x = 2
(d) xy = 1
Explanation:
Let the coordinate of the point P is (x, y). It is given that, P is mid-point of AB.
So, the coordinates of points A and B are (2x, 0) and (0, 2y), respectively.
0 2y y
Therefore, slope of AB =
2x 0 x
Since the segment AB is a tangent to the curve at P.
dy y
dx x
dy dx
y x
Now, integrating both sides, we get
log y = log x + log C
C
log y log ...(1)
x
Since, the given curve passes through (2, 1)
C
log1 log
2
C
0 = log
2
c=2
2
log y log
x
2
y
x
xy = 2
Q 34. A curve passes through the point 1, . Let the slope of the curve at each point x, y be
3
y y
csc , x 0 . Then the equation of the curve is
x x
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Options:
y 1
(a) cos log x
x 2
y 1
(b) cos log x
x 2
y 1
(c) cos log x
x 2
y 1
(d) csc log x
x 2
Explanation:
dy
Q 35. Let y(x) be the solution of the differential equation x ln x y 2 x ln x, x 1 . Then y(e)
dx
is equals to:
Options:
(a) e
(b) 0
(c) 2
(d) 2e
Explanation:
We have,
dy
x ln x y 2 x ln x, x 1
dx
On putting x = 1 we get y = 0
On dividing the above equation by x logx it can be written as:
dy y
2
dx x ln x
1
IF = e x ln x ln x
dx
At x = 1, y = 0
0 = c + 2(−1)
c=2
y ln x 2 x ln x x 2
Put x = e
y 2 e ln e e
y2
Options:
Explanation:
First of all, the compound has complex positive part [Co(H2O)4(NH3)2]3+ therefore, according to
IUPAC conventions, positive part will be named first. Secondly, in writing name of complex,
ligands are named first in alphabetical order, irrespective of its charge, hence "ammine" will be
written prior to "aqua".
NOTE: In alphabetical order, original name of ligands are considered not the initials of prefixes.
Also, special precaution should be taken in spelling name of NH3 ligand as it is ammine.
Therefore, name of the complex is [Co(H2O)4(NH3)2]Cl3 is Diamminetetraaqua cobalt (III)
chloride.
Q 37. The number of geometric isomers that can exist for square planar [Pt (Cl) (py) (NH3)
(NH2OH)]+ is (py = pyridine).
Options:
(a) 2
(b) 3
(c) 4
(d) 6
Ans. Option (b) is correct
Explanation:
So, the number of geometric isomers that exist for this compound is 3.
Q 38. The correct increasing order of conductivity of the given complexes in their solution is
[Co(NH3)3Cl3], [Co(NH3)4Cl2] Cl, [Co(NH3)6]Cl3 and [Cr(NH3)5Cl]Cl2
Options:
(a) Co NH3 3 Cl3 Cr NH3 5 Cl Cl2 Co NH3 4 Cl2 Cl Co NH3 6 Cl3
(b) Co NH3 4 Cl2 Cl Co NH3 3 Cl3 Cr NH3 5 Cl Cl2 Co NH3 6 Cl3
(c) Co NH3 3 Cl3 Cr NH3 5 Cl Cl2 Co NH3 4 Cl2 Cl Co NH3 6 Cl3
(d) Co NH3 3 Cl3 Co NH3 4 Cl2 Cl Cr NH3 5 Cl Cl2 Co NH3 6 Cl3
Explanation:
Ions or molecules present outside the coordination sphere are ionisable. A complex which gives
more ions on dissolution, is more conducting.
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Co NH3 3 Cl3 Co NH3 4 Cl2 Cl Cr NH3 5 Cl Cl 2 Co NH3 @iitwale
Cl3
6
on Telegram
1 ion 2 ions 3 ions 4 ions
Q 39. Due to the presence of ambidentate ligands coordination compounds show isomerism.
Palladium complexes of the type [Pd(C6H5)2(SCN)2] and [Pd(C6H5)2(NCS)2] are
Options:
Explanation:
The ligand(s) which has two different bonding sites are known as ambident ligands e.g., NCS,NO2
etc
Here, NCS has two binding sites at N and S.
Hence, NCS (thiocyanate) can bind to the metal ion in two ways
M NCS or M → SNC
Thus, coordination compounds containing NCS as a ligand can show linkage isomerism
i.e.,[Pd(C6h5)2(SCN) and [Pd(C6H5)2(NCS)2] are linkage isomers.
Q 40. The oxidation state of Fe in the brown ring complex [Fe(H2O)5NO]SO4 is:
Options:
(a) + 1
(b) + 2
(c) + 3
(d) + 4
Charge on Fe + (+1) = +2
Charge on Fe = +1
Options:
(b) 0 A
3
X
23
X 0 3
0.13 A
Current through 1 resistor is 1 23
Q 42. A wire of resistance 2 is stretched to thrice of its original length. The resistance of
stretched wire would be
Options:
(a) 8
(b) 18
(c) 2
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(d) 4
Explanation:
Resistance of a wire,
l
R 2 ...1
A
lA l ' A '
l l A
A' A A
l' 3l 3
Resistance of the stretched wire is
l' 3l l
R' 9
A' A / 3 A
9 2 18
Q 43. The circuit in figure shows two cells connected in opposition to each other. Cell E1is of emf
12V and internal resistance 4Ω. the cell E2 is of emf 8V and internal resistance 16Ω. Find the
potential difference between the points A and B.
Options:
(a) 11.2 V
(b) 12.1 V
(c) 12.3 V
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(d) 12.1 V
Explanation:
Effective resistance = 4Ω + 16Ω = 20Ω and effective emf of two cells = 12 8 = 4V, so the
12 8
I 0.2 A
electric current is given by 4 16
The direction of flow of current is always from high potential to low potential. Therefore
VB > VA
VB 8V (0.2) 16 = VA
Therefore, VB VA = 11.2 V
Q 44. The supply voltage to room is 120 V. The resistance of the lead wires is 6 Ω. A 60 W bulb is
already switched on. What is the decrease of voltage across the bulb, when a 240 W heater is
switched on in parallel to the bulb?
Options:
(a) 0 Volt
Explanation:
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We know that,
V2
P
R
Resistance of 60 W bulb is
120 120
R 240
60
120 120
R 60
240
Since 240 Ω and 60 Ω resistor are in parallel, so the resultant resistance is:
1 1 1
R 240 60
R 48
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Req 48 6 54
48
V2 120 106.66V
54
Options:
(a) 0.8×10−8 Ωm
(b) 0.8×10−7 Ωm
(c) 0.8×10−6 Ωm
(d) 0.8×10−5 Ωm
Explanation:
J ne vd
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ne vd
A
I neAvd
vd
where, is the drift speed
l
R
and A
By Ohm’s law
V
neAvd
l
A
V
nelvd
10
0.8 105 m
8 10 1.6 10-19 0.2 5 10-4
28
sin x
Q 46. 0
2
sin x cos x
dx ?
Options:
(a)
4
(b)
3
(c)
2
(d)
Explanation:
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sin x
Let I 2 dx …(1)
0 sin x cos x
sin x
and I 2 2 dx
0
sin x cos x
2 2
sin x
I 2 dx …(2)
0 sin x cos x
On adding Eqs. (1) and (2),we get
2 I 2 1 dx
0
I
4
/2 dx
Q 47. 0 (a cos x b2 sin 2 x)2
2 2
Options:
a 2 b2
(a)
2 a3b3
a 2 b2
(b)
4 a3b3
a 2 b2
(c)
3 a3b3
a 2 b2
(d)
4 a3b3
/2 dx
Let I
0 (a cos x b2 sin 2 x)2
2 2
/2 sec4 x dx
I
0 (a 2 b2 tan 2 x)2
/2 (1 tan 2 x)sec2 x dx
0 (a 2 b 2 tan 2 x)2
Put tan x = t
sec2 x dx dt
As x 0, then t 0
(1 t 2 )
and x then t I
2 0 (a 2 b 2 t 2 ) 2
1 t2
Now, [Let t 2 u ]
(a 2 b 2 t 2 ) 2
1 u A B
2 2
(a b u )
2 2 2
( a b u ) ( a b 2u ) 2
2
1 u A(a 2 b2u) B
a2 A B 1 (1)
and b2 A 1 (2)
1
A
b2
a2
Now, B 1
b2
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a 2 b2 a 2
B 1 2
b b2
(1 t 2 )
I
0 (a 2 b 2 t 2 )2
1 dt b2 a 2 dt
2
b
0 a 2 b 2t 2
b2
0 ( a b 2t 2 ) 2
2
1 dt b2 a 2 dt
b2
0
2a
2
2
b2 0 ( a b 2t 2 ) 2
2
b 2 t
b
1 tb b a 1
2 2
3 tan 1
ab a 0 b2 4 a3b
1 b2 a 2
tan 1
tan 1
0
4 a3b3
ab3
b2 a 2
2ab3 4 a b
3 3
2a 2 b 2 a 2 a 2 b 2
3 3
4a3b3 4 a b
x
Q 48. 0 1 sin x
Options:
(a) 0
(b)
3
(c)
(d)
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Ans. Option (d) is correct
Explanation:
x
Let I …(1)
0 1 sin x
x x
and I dx dx …(2)
0 1 sin( x) 0 1 sin x
1
2I dx
0 1 sin x
(1 sin x) dx
0 (1 sin x) (1 sin x)
(1 sin x) dx
0 cos 2 x
(sec2 x tan x sec x)dx
0
tan x sec x
0
0 1 0 1
2I 2
I
x x
Q 49. The integral
0
2
1 4sin 2
2
4sin dx is equal to
2
Options:
(a) 4
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(b) 2 2 4
2
(c) 2 2 4
2
(d) 4 3 4
3
Explanation:
2
x x x x
1 4sin 4sin dx 1 2sin dx 2 1 2sin dx
2 2 2
0 2 2 0
2 0
2
x 2
x 4 cos
2 0
2 2 4
2
Q 50. Let f : 0, 2 R be a function which is continuous on 0, 2 and is differentiable on (0, 2)
F 2 equals to
Options:
(a) e2 1
(b) e 1
(c) e4 1
(d) e 4
Given,
t dt
x2
F x f
0
F ' x 2 xf x
Also,
F ' x f ' x
f ' x 2 xf x
f ' x
2x
f x
Integrating both sides we get,
f ' x
f x 2 xdx
ln f x x 2 c
f x ex c
2
On putting ec k
f x ke x
2
Given,
f 0 1
k 1
f x ex
2
F 2 et dt et e4 1
4 4
0 0
Q 51. On addition of 1 mL solution of 10% NaCl to 10mL of gold sol in the presence of 0.25 g of
starch, the coagulation is just prevented. The gold number of starch is:
Options:
(a) 0.25
(b) 2.5
Explanation:
Gold number of a protective colloid is the minimum mass of it in milligrams which must be added
to 10 mL of gold sol so that no coagulation of the gold sol takes place when 1 mL of 10% NaCl
solution is added to it.
Now given, starch added to 10 mL of gold soil to completely prevent its coagulation by 10 mL of
10% NaCl solution = 0.25 g = 250 mg
Options:
Explanation:
Lyophobic (liquid hating) sols are obtained from inorganic materials such as metals, sulphides,
metal oxides etc.
Options:
Explanation:
Physical adsorption being an exothermic process, occurs more readily at lower temperature and
decreases with increase in temperature.
Q 54. A colloidal system having a gas as a dispersed phase and a solid substance as a dispersion
medium is classified as
Options:
(a) Foam
(b) Emulsion
(c) Solid Foam
(d) Sol
A colloidal system having a gas as a dispersed phase and a solid substance as a dispersion medium
is classified as Solid Foam.
Q 55. The coagulating power of electrolytes having ions Na+, Al3+ and Ba2+ for arsenic sulphide
solution increases in the order
Options:
1 3
Q 56. If P 1 3 3 is the adjoint of a 3 × 3 matrix A and A 4 , then is equals to
2 4 4
Options:
(a) 4
(b) 11
(c) 5
(d) 0
Explanation:
We have,
1 3
P 1 3 3
2 4 4
P 112 12 4 6 3 4 6 2 6
Given,
P = adj(A)
P adjA A 16
2
adjA A
n 1
2 6 16
11
1 f 2 1 f 3 1 f 4
(a)
1
(b)
(c) 1
(d) −1
Explanation:
We have,
f n n n
f 1
f 2 2 2
f 3 3 3
f 4 4 4
Now,
111 1 1 2 2
1 1 2 2 1 3 3
1 2 2 1 3 3 1 4 4
2
1 1 1
1
1 2 2
On expanding, we get
1 1
2 2 2
1 1 K 1 1
2 2 2 2 2 2
K 1
0 xy 2 xz 2
Q 58. Solve x 2 y 0 yz 2 ?
x2 z zy 2 0
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Options:
(a) 2x3 y3 z3
(b) x3 y3 z3
(c) 2x2 y3 z3
(d) 2x2 y2 z2
Ans. Option (a) is correct
Explanation:
0 xy 2 xz 2 0 x x
We have, x 2 y 0 yz 2 x 2 y 2 z 2 y 0 y
x2 z zy 2 0 z z 0
[taking x2, y2, and z2 common from C1, C2 and C3, respectively]
0 0 x
x y z y y
2 2 2
y [ C2 C2 C3]
z z 0
= x2 y2 z2 [x (yz + yz)]
= x2 y2 z22xyz = 2x3 y3 z3
x 1 1
Q 59. The least value of the product xyz for which the determinant 1 y 1 is non negative is
1 1 z
Options:
(a) −8
(b) −1
(c) 2 2
(d) 16 2
Explanation:
t 2
t 3 8
xyz 8
1 3
Q 60. If P 1 3 3 is the adjoint of a 3 × 3 matrix A and A 4 , then is equals to
2 4 4
Options:
(a) 4
(b) 11
(c) 5
(d) 0
Explanation:
We have,
1 3
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P 1 3 3
2 4 4
P 112 12 4 6 3 4 6 2 6
Given,
P = adj(A)
P adjA A 16
2
adjA A n 1
2 6 16
11
Q 61. The vapour pressure of acetone at 20°C is 185 torr. When 1.2g of a non-volatile substance
was dissolved in 100g of acetone at 20°C, its vapour pressure was 183 torr. The molar mass of the
substance is
Options:
(a) 32
(b) 64
(c) 128
(d) 488
Ans. Option (b) is correct
Explanation:
Given,
vapour pressure of acetone (p°) = 185 torr at 20°C
vapour pressure of solution (ps)= 183 torr at 20°C
Mass of non-volatile substance, m = 1.2 g
Mass of acetone = 100 g
Molar mass of acetone = 58 g
We have,
p ps n
ps N
Putting the values, we get,
1.2
185 183 M 2 1.2 58 JOIN @iitwale on Telegram
183 100 183 100 M
58
183 1.2 58
M = 63.684 = 64 g/mol
2 100
Q 62. Consider separate solution of 0.500 M C2H5OH (aq), 0.100 M Mg3(PO4)2(aq), 0.250 M
KBr(aq) and 0.125 M Na3PO4(aq) at 25°C. Which statement is true about these solutions,
assuming all salts to be strong electrolytes?
Options:
Explanation:
For strong electrolyte Van’t Hoff factor is number of ions per formula unit of electrolyte.
Effective molarity = Van't Hoff factor Molarity
Options:
Explanation:
3
Since, K3 Fe CN 6 ionizes as 3K and Fe CN 6
K f 1000 w2
T f i
M 2 w1
1.86 1000 0.1
4 2.23 102
329 100
Tf 2.23 102 C
Q 64. For a dilute solution containing 2.5 g of a non-volatile non-electrolyte solute in 100 g of
water, the elevation in boiling point at 1 atm is 2°C. Assuming concentration of solute is much
lower than the concentration of solvent, the vapour pressure (mm of Hg) of the solution is
Kb 0.76 K kg mol 1
Options:
(a) 740
(b) 724
(c) 736
(d) 718
Ans. Option (b) is correct
Explanation:
Now,
w2
n2
M2
Kb 1000 n2
Tb
w1
0.76 1000 n2
2
100
5
n2
19
According to Raults law,
p10 p1 n2 n
2
p10
n1 n2 n1
Q 65. In comparison to, a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M
MgCl2 solution is …………. .
Options:
Explanation:
As we know depression in freezing point is directly related to van't Hoff factor (i) according to
which greater the value of i greater will be the depression in freezing point.
Solution i
0.01 M glucose 1
0.01 M MgCl2 3
(a) Alkylation of benzene with an alkyl chloride requires only a catalytic amount of a Lewis acid
such as aluminum chloride.
(b) Alkylation of benzene with an alcohol requires only a catalytic amount of a Bronsted acid
such as phosphoric acid.
(c) Acetylation of benzene with acetyl chloride requires only a catalytic amount of a Lewis acid.
(d) Acetylation of benzene with acetic anhydride requires more than one equivalent of a Lewis
acid.
Explanation:
Acetylation of benzene with acetyl chloride requires only a catalytic amount of a Lewis acid.
Friedel-Crafts acylation reaction
Options:
Explanation:
The Reimer–Tiemann reaction is a chemical reaction used for the ortho-formylation of phenols.
On treating phenol with chloroform in presence of sodium hydroxide, a −CHO group is introduced
at ortho position of benzene ring.
Q 68. Which of the following reactions will not result in the formation of carbon–carbon bonds?
Options:
Explanation:
Wurtz reaction, Reimer-Tiemann reaction and Friedel-Crafts acylation result in the formation of C-
C bond while Cannizaro reaction do not form Carbon-Carbon bond.
Q 69. The synthesis of alkyl fluorides is best accomplished by
Options:
Explanation:
Option (a)
Free radical fluorination is highly explosive reaction therefore it is not preferred for the preferred
for the synthesis of alkyl fluorides.
Option (b)
Sandmeyer’s reaction is used to synthesize aryl halides from aryl diazonium salts.
Option (c)
Finkelstein reaction is used mainly for the preparation of alkyl iodides.
Option (d)
The synthesis of alkyl fluoride is best accompanied by Swarts Reaction. Alkyl fluoride is
synthesized by heating alkyl bromide and alkyl chloride in the presence of AgF, SbF3, Hg2F2 etc.
CH3Br+AgF
heat
CH3F+AgBr
Options:
Explanation:
sin 6 x cos6 x
Q 71. Solve
sin 2 x cos 2 x
Options:
Explanation:
sin 2 x cos 2 x
3 3
sin 6 x cos6 x
Let I dx dx
sin 2 x cos 2 x sin 2 x cos 2 x
I tan x cot x 3x C
sin x a
Q 72. Evaluate: sin x a dx
Options:
Let x a t
dx dt
sin t 2a
dt
sin t
sin t cos 2a cos t sin 2a
dt
sin t
sin t cos 2a cos t sin 2a
dt dt
sin t sin t
cos 2a dt sin 2a cot t.dt
t cos 2a sin 2a log sin t c
x a cos 2a sin 2a log sin x a c
1 x2
Q 73. Evaluate: x4
dx
Options:
32
1 1
(a) 1 2 C
3 x
32
1 1
(b) 1 2 C
3 x
32
1 1
(c) 1 2 C
3 x
32
1 1
(d) 1 2 C
3 x
1 x2 1 x2 1
Let I dx x x3 dx
x4
1 x2 1 1 1
2
3 dx 2 1 3 dx
x x x x
1 2
Put 1 2
t 2 3 dx 2t dt
x x
1
t dt
x3
32
t3 1 1
I t 2 dt C 1 2 C
3 3 x
1 x 1
Q 74. The integral 1 x e x dx is equal to
x
Options:
1
x
(a) x 1 e x
C
1
x
(b) xe x
C
1
x
(c) x 1 e x
C
1
x
(d) xe x
C
Explanation:
Let,
1 x 1
I = 1 x e x dx
x
1 x 1
1
x
= e dx x 1 2 e x dx
x
x
On integrating the second function by parts, we get
x
1
1 x 1 d 1 x 1
= e x
dx x 1 2 e x dx x 1 2 e x dx dx JOIN @iitwale on Telegram
x dx x
Let,
1 x 1x
I1 = 1 2 e dx
x
On putting,
1
x t
x
1
1 2 dx dt
x
So,
1
x
I1 = et dt e x
Now,
1 1 1
x x x
I = e x
dx xe x
e x
dx C
1
x
I = xe x
C
x x3 x 2 x3 dx C
1 3
(a)
3
Explanation:
Let,
I x5 f x3 dx JOIN @iitwale on Telegram
On putting,
x3 t
3x2 dx dt
dt
x 2 dx
3
1
tf t dt
3
I
x3 x3 3 x 2 x3 dx C
1
3
x3 x3 x 2 x3 dx C
1
3
Q 76. The forward biased diode connection is
Options:
(a)
(b)
(c)
Explanation:
For forward bias diode, p-side must be at higher potential and n-side must be at lower potential.
9
Q 78. If the ratio of the concentration of electrons to that of holes in a semiconductor is and the
7
5
ratio of currents is Then, the ratio of their drift velocities is
3
Options:
9
(a)
7
7
(b)
15
5
(c)
8
15
(d)
7
Explanation:
As, I = neAvd
I e ene Ave ne ve
I h enh Avh nh vh
Q 79. Two identical capacitors each of capacitance C are charged to the same potential V and are
connected in two circuits (i) and (ii) at t = 0 as shown. The charged on the capacitor at t =CR are
CV CV
(a) ,
e e
(b) CV, CV
VC
(c) , VC
e
VC
(d) VC ,
e
Options:
Explanation:
In Fig. (i) the p-n junction diode is forward biased and represents a very low resistance, the
capacitor, therefore discharges itself through resistor R according to relation.
q q0et CR
and q0 = CV at t = CR
q q0e1
CV
e
In Fig. (ii), the p-n junction diode is reverse biased, the capacitor, therefore holds the charge intact.
q = q0 = CV
Q 80. The anode voltage of a photocell is kept fixed. The wavelength of the light falling on the
cathode is gradually changed. The plate current I of the photocell varies as follows:
(a)
(b)
(c)
(d)
As is increased, there will be a value of above which photoelectrons will cease to come out.
So photocurrent will become zero.
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Options:
(a) [LT3]
(b) [ML3T1]
(c) [M2LT3]
(d) [MT2]
Explanation:
a t2 a t2
Given equation P
bx bx bx
a 1
or ML1T 2
b L
a
b MT
2
or
Q 82. A student measures the thickness of a hanuman hair by looking at it through a microscope of
magnification 200. He makes 20 observations and finds that the average width of the hair in the
field of view of the microscope is 4 mm. What is the estimate on the thickness of hair?
Options:
(a) 0.02 mm
(b) 0.2 mm
(c) 0.002 mm
(d) 2.0 mm
Ans. Option (a) is correct
Explanation:
Magnification of the microscope = 200
Average width of the hair in the field of view of the microscope = 4 mm
4
Actual thickness of the hair is = 0.02 mm.
200
Q 83. Let E0 denote the dimensional formula of the permittivity of vacuum. If
M = mass , L = length, T = Time and A = electric , then
Options:
Explanation:
1 q1q2
From Coulomb’s law, F =
4 E0 R 2
q1q2
E0 =
4 FR 2
Substituting the units we have,
AT
2
C2
E0 M 1L3T 4 A2
N m 2
MLT L
2 2
Options:
(a) 3.2 %
(b) 3.1 %
(c) 3.3 %
(d) 4.2 %
Explanation:
0.4
Least count of the pitch = 0.01
40
Diameter (D) of the ball = [2.4 + 20(0.01)] mm = 2.6 mm
Mass
Volume
M
3
4 D
3 2
The relative percentage error in the density is given as:
m D 0.01 JOIN @iitwale on Telegram
3 =3+ 3 100 = 4.2%
m D 2.6
Options:
(a) 5.211 cm
(b) 5.122 cm
(c) 5.222 cm
(d) 5.111 cm
Explanation:
Options:
1 3
Q 87. If P 1 3 3 is the adjoint of a 3 × 3 matrix A and A 6 , then is equals to
2 4 4
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Options:
(a) 36
(b) 15
(c) 30
(d) 42
Explanation:
We have,
1 3
P 1 3 3
2 4 4
P 112 12 4 6 3 4 6 2 6
Given,
P = adj(A)
P adjA A 36
2
adjA A n 1
2 6 36
21
Options:
(a) 7A + I
(b) 8A + I
(c) 5A + I
(d) 6A + I
Ans. Option (a) is correct
Explanation:
Q 89. If A is a 3 × 3 non-singular matrix such that AAT AT A and B A1 AT , then BBT is equal
to
Options:
(a) I B
(b) I
(c) B 1
(d) B 1
T
Ans. Option (b) is correct
Explanation:
Given,
AAT AT A and B A1 AT
BBT A1 AT A1 AT
T
A1 AT A A1 AB T BT AT
T
A1 AAT A1
T
A1 A
T
IT I
Q 90. Let be a complex root of unity with 1 and P pij be a n n matrix with pij i j
.Then, P 2 0 , when n is equals to
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Options:
(a) 61
(b) 55
(c) 58
(d) 57
Explanation:
Here,
P pij
nn
and pij i j
When n = 1
P pij
nn
= 2
2
P 2 2 4
When n = 2
2 1 2 1
P2 = 0
1 1
When n = 3
2 3 4 2 1 2 1
P 3 4 5 6 3 2 3 2
4 5 6 4 2 3 4 2 3
2 1 2 1
P 2 3 2 3 2 0
4 2 3 4 2 3
Q 91. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom us [a0 is Bohr
radius]
Options:
h2
(a)
4 2 ma02
h2
(b)
16 2 ma02
h2
(c)
32 2 ma02
h2
(d)
64 2 ma02
Explanation:
nh
mvr …(i)
2
n2 h2
mv
2
4 2 r 2
Q 92. If the shortest wavelength of H atom in Lyman series is x, then longest wavelength in
Balmer series of He+ is
Options:
9x
(a)
5
36 x
(b)
5
x
(c)
4
5x
(d)
9
Explanation:
1 1 1
RH Z 2 2 2
n1 n2
For H – atom Z = 1
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1 1 1 1
RH 2 2
RH
x 1 x
For He, Z = 2
1 1 2 1 1
2 2 2
max x 2 3
9x
max
5
Q 93. The ratio of the energy of the electron in ground state of hydrogen to the electron in first
excited state of Be3+ is
Options:
(a) 1 : 4
(b) 1 : 8
(c) 1 : 16
(d) 16 : 1
Explanation:
Z2 V
En 13.6 2 e
n
For H – atom, Z = 1
For Be, Z = 4
13.6 4
2
E2 Be 3
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2
2
E1 : E2 1: 4
Z2
Q 94. Energy of an electron is given by E 2.178 1018 J 2 wave length of light required to
n
excite an electron in a hydrogen atom from level n = 1 to n = 2 will be
h 6.62 10 34
Js and c 3.0 108 ms 1
Options:
We have,
Z2
E 2.178 1018 J 2
n
For hydrogen Z = 1,
1
So, E1 2.178 1018 J 2
1
1
E2 2.178 1018 J 2
2
So, energy required to excite an electron in a hydrogen atom from level
n = 1 to n = 2 is,
hc
E
So,
hc 1 1
= 2.178 1018 2 2
1 2
1.21107 m
Q 95. If Azimuthal quantum number could have value of n also (in addition of normal value), then
electronic configuration of V (Z = 23) would have been
Options:
(a) 1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d3
Explanation:
By Aufbau rule, electron will be filled in increasing order of energy, i.e., (n + 1) rule. Minimum
the value of (n + 1), smaller is the energy of orbital.
Q 96. If eye is kept at a depth h inside the water of refractive index and viewed outside, then the
diameter of circle through which the outer objects become visible, will be
Options:
h
(a)
2 1
2h
(b)
2 1
h
(c)
2 1
h
(d)
2 2 1
Explanation:
Let r be the radius of the cncle through whichother objects become visible. The ray of light must
be incident at critical angle C.
1 r
sin C
r h2
2
2 r2 = r2 + h2 (2 1)r2 = h
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h
r
2 1
2h
Diameter = 2r
2 1
Options:
(a) 45°
(b) 75°
(c) 30
(d) 60
cos
ˆi+ 3jˆ . ˆi 3jˆ
2.2
Options:
(a) 30
(b) 45
(c) 60
(d) 75
Ans. Option (a) is correct
Explanation:
Let i be the incident ray and r be the reflected ray.
The angle made by i with horizontal is .
1
1
tan 2
3 3
2
30
Q 99. The image of an object, formed by a plano-convex lens at a distance of 8m behind the lens,
is real and is one third the size of the object. The wavelength of light inside the lens is 2/3 times
the wavelength in free space. The radius of the curved surface of the lens is
Options:
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(a) 1 m
(b) 6 m
(c) 5 m
(d) 3 m
Explanation:
Given that
Positive of image, v = +8
1
Magnification, m =
3
Now,
1 v
m= =
3 u
u
v
3
u
8
3
u 24
Now, the refractive index of medium is given by,
1 3
air
medium 2 2
3
1 1 1 1 1
1
v u f R
1 1 3 1
1
8 24 2 R
R 3m
Q 100. For a glass prism 3 , the angle of minimum deviation is equal to the angle of the
prism. The angle of the prism is
Options:
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(a) 45°
(b) 75°
(c) 30
(d) 60
Explanation:
The relationship between refractive index, prism angle A and angle of minimum deviation is given
by
A Dm
sin
2
A
sin
2
Here, Dm = A
sin A
Substituting the value, we get
A
sin
2
A A
2sin cos
2 2 2 cos A
A 2
sin
2
A 3
For the given value of refractive index, we have cos
2 2
A
or 30
2
A = 60
Q 101. The area enclosed by the curves y = sinx + cosx and y cos x sin x over the interval
0, 2 is
(a) 4 2 1
(b) 2 2 2 1
(c) 2 2 1
(d) 2 2 2 1
Ans. Option (b) is correct
Explanation:
Let,
y1 sin x cos x 2 sin x
4
y2 sin x cos x 2 sin x
4
Area = 4
sin x cos x cos x sin x dx 2 sin x cos x sin x cos x dx
0
4
= 42 2
=2 2 2 1
Q 102. The common tangents to the circle x 2 y 2 2 and the parabola y 2 8 x touch the circle at
the points P, Q and the parabola at the points R, S. Then, the area of the quadrilateral PQRS is
Options:
(a) 3
(b) 6
(c) 9
(d) 15
Explanation:
Coordinates of P, Q, R, S are
P(–1, 1) Q(–1, –1) R(2, – 4) & S(2, 4)
2 8 3 15 sq unit JOIN @iitwale on Telegram
Area of PQRS =
2
Q 103. The area of the region bounded by the curve y = x3, y = x + 6 and x = 0 is
Options:
(a) 10 sq units
(b) 11 sq units
(c) 12 sq units
(d) 9 sq units
Explanation:
x 6 x dx
2
Required area of shaded region = 3
0
4 16
12 0
2 4
= [2 + 12 4] = 10sq units
Options:
(a) 14 sq units
(b) 12 sq units
(c) 16 sq units
(d) 17 sq units
x if x < 1
We have, y
x 2, if x 1
1
x 2 dx
3
Now, Area of shaded region, A x dx JOIN @iitwale on Telegram
3 1
1 3
x2 x2
2x
2 2 1
1 9 9 1
6 2
2 2 2 2
= [4] + [8 + 4] = 12 + 4 = 16 sq units
Q 105. The area of the region bounded by y2 = 9x, x = 2, x = 4 and the x-axis in the first quadrant
Options:
(a) 16 - 2 units
(b) 14 - 4 2 units
(c) 16 - 4 2 units
(d) 16 4 2 units
Ans. Option (c) is correct
Explanation:
4
ydx
2
4
3 xdx
2
4
32
3
2x
3
2
3 3
2 4 2 2 2
2 82 2
16 4 2 units
Q 106. Decomposition of H2O2 is a first order reaction. Initially, solution of H2O2 having half-life
time 15 min is 16 volumes. When solution becomes 1 volume
Options:
(a) 4 min
(b) 15 mm
(c) 30 min
(d) 60 min
Ans. Option (d) is correct
Explanation:
n
We have, Nt N where, Nt = after n half-lives times volume concentration of H2O2 = 1
1
2
volume
N0 = initial concentration of H2O2 = 16 volume
n
1 16
1
2
4 n JOIN @iitwale on Telegram
1 1 1
16 2 2
n=4
Therefore, after 4 half-life times, volume of H2O2 solution becomes 1 volume. Time used in this
procedure
= 415 min
= 60 min
Q 107. A radioactive isotope having a half-life of 3 days was received after 12 days. It was found
that there were 3 g of the isotope in the container. Find the initial weight of the isotope, when it
was packed (antilog 1.203 = 16)
Options:
(a) 48 g
(b) 24g
(c) 36 g
(d) 12 g
Ans. Option (a) is correct
Explanation:
Given:
Half-life of the isotope = 3days
12
No. of half-lives, n 4
3
A0
Amount left after n half-lives
2n
Amount of isotope left in the container after 12 days = 3g
A0
3
24
or, A0 = 48g
Q 108. During nuclear explosion one of the productsis 90Sr with half-life of 28.1 yr. If 1 g of 90Sr
was absorbed in the bones of a newly born body instead of calcium, howJOINmuch@iitwale
of it will remain
on Telegram
after 60 yr, if it is not lost metabolically?
Options:
(b) 0.228 g
(c) 0.262 g
(d) 0.025 g
Explanation:
Half life
t 1/2 = 28.1 yr
0.693 0.693 1
k yr
t1/ 2 28.1
2.303 a
60yr log
0.693 / 28.1 a x
log
a
60yr 0.693 / 28.1yr 1
06.42
a x 2.303
a
antilog 0.642 4.385
a x
a 1 g 02280 g
a x
4.385 4.385
Q 109. A first order reaction is 50% completed in 2.12 1012 s. HowJOIN @iitwale
much time would iton
takeTelegram
for
100% completion?
Options:
Explanation:
The time taken for half the reaction to complete, i.e., the time in which the concentration of a
reactant is reduced to half of its original value is called half-life period of the reaction.
But it is impossible to perform 100% of the reaction. Whole of the substance never reacts because
in every half-life, 50% of the substance reacts. Hence, time taken for 100% completion of a
reaction is infinite.
Q 110. For the first order reaction, 2N2O5(g) 4NO2(g) + O2(g)
Options:
(a) The concentration of the reactant increases with time
(b) The half-life of the reaction increases with increasing temperature
(c) The half-life of the reaction is independent of initial concentration of the reactant
(d) The reaction proceeds of 99.6% completion in eight half-life duration
Explanation:
Option (a)
For a first order reaction,
A ] [ A0 e kt …(i)
where,
[A] = concentration of reactant remaining after time t
[A0] = initial concentration
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From equation (i) we can conclude that concentration of reactant decreases exponentially with
time.
Option (b)
Half-life of the reaction can be given as:
In 2
t1 2
k
where,
k = Rate constant
t1/ 2 = Half-life
Also rise in temperature increases with rate constant (k).
So, rise in temperature increases rate constant (k) and therefore decreases half-life.
Option (c)
Half-life of first order reaction is independent of initial concentration.
Option (d)
Let initially the reactant is 100 moles.
For a first order reaction,
n
1
% A 100
2
where, n = number of half lives
After 8 half lives amount of A remaining is
8
1
% A 100 0.3906
8
So, the amount of A reacted is 100 − 0.3906 = 99.6%
Q 111. A ball of mass (m) 1 kg is attached to the end of a string having length (L) 1 m. The ball is
rotated on a horizontal circular path about vertical axis. The maximum tension that the string
can bear is 289 N. The maximum possible value of angular velocity of ball (in radian/s) is
Options:
(a) 9
(b) 18
(c) 17
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(d) 18
Ans. Option (c) is correct
Explanation:
Q 112. A small block of mass of 0.1 kg lies on a fixed inclined plane PQ which makes
an angle θ with the horizontal. A horizontal force of 1 N acts on the block through its centre of
mass as shown in the figure. The block remains stationary if (take g = 10 m/s2)
Options:
(a) 45
(b) 45 and a frictional force acts on the block towards P
(c) 45 and a frictional force acts on the block towards Q
(d) None of these
Explanation:
Q 113. In the figure, a ladder of mass m is shown leaning against a wall. It is in static equilibrium
making an angle with the horizontal floor. The coefficient of friction between the wall and the
ladder is 1 and that between the floor and the ladder is 2 . The normal reaction of the wall on the
ladder is N1 and that of the floor is N2. If the ladder is about to slip, then
Options:
mg
(a) 1 0, 2 0 and N 2 tan
2
mg
(b) 1 0, 2 0 and N1 tan
2
mg
(c) 1 0, 2 0 and N 2
1 12
(d) 1 0, 2 0 and N1 tan mg
Q 114. Given in the figure are two blocks A and B of weight 20 N and 100 N, respectively. These
are being pressed against a wall by a force F as shown. If the coefficient of friction
between the blocks is 0.1 and between block B and the wall is 0.15, the frictional force applied
by the wall on block B is :
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Options:
(a) 100 N
(b) 80 N
(c) 120 N
(d) 150 N
Explanation:
For block A,
m1 g 1F
20 0.1 F
20
F 200
0.1
Frictional force on block A will be in upward direction and it will be equals to 20N.
So, block A will exert a frictional force of 20 N on block B in downward direction.
So, for block B
2 F m2 g 1F
100 20 120 N
x3
Q 115. A block of mass m is placed on a surface with a vertical cross section given by y . If
6
the coefficient of friction is 0.5, the maximum height above the ground at which the block can be
placed without slipping is
Options:
1
(a) m
6
2
(b) m
3 JOIN @iitwale on Telegram
1
(c) m
3
1
(d) m
2
Explanation:
r r
Q 116. The range of values of r, for which the point 5 , 3 is an interior point of the
2 2
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major segment of the circle x2 + y2 = 16 cut-off by the line x + y = 2, is
Options:
(a) (, 5 2 )
(b) 4 2 14,5 2
(c) 4 2 14, 4 2 14
(d) None of the above
Ans. Option (b) is correct
Explanation:
We have,
x2 + y2 = 16
Since, the given point is an interior point.
2 2
r r
then, 5 3 16 0
2 2
r 2 8 2r 18 0
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4 2 14 r 4 2 14
r r
5 3 0
2 2 2
r 5 2,
so 4 2 14 r 5 2
Q 117. Tangents drawn from point P (1, 8) to the circle x2 y 2 6 x 4 y 11 0 touch the circle
at the points A and B. The equation of the circumcircle of the triangle PAB is
Options:
(a) x2 y 2 4 x 6 y 19 0
(b) x2 y 2 4 x 10 y 19 0
(c) x2 y 2 2 x 6 y 29 0
(d) x2 y 2 6 x 4 y 19 0
Explanation:
We have,
x2 y 2 6 x 4 y 11 0
x2 6 x 9 y 2 4 y 4 11 13 0
x 3 y 2 24
2 2
Let C be the centre of the circle. So, the coordinates of the centre of the circle is C (3, 2).
Since CA and CB are perpendicular to PA and PB, CP is the diameter of the circumcircle of
triangle PAB.
So, the equation of the circle with the end points of the diameter as (1, 8) and (3, 2) is
x 1 x 3 y 8 y 2 0
x2 y 2 4 x 10 y 19 0 JOIN @iitwale on Telegram
Q 118. The locus of the centre of a circle, which touches externally the circle x2 + y2 6x 6y +
14 = 0 and also touches the y-axis, is given by the equation
Options:
(a) x2 6x 10y + 14 = 0
(b) x2 10x 6y + 14 = 0
(c) y2 6 x 10y + 14 = 0
(d) y2 10x 6y + 14 = 0
Explanation:
We have x2 + y2 6x 6y + 14 = 0
x2 6 x 9 y 2 6 y 9 4 0
x2 6 x 9 y 2 6 y 9 4
x 32 y 32 22
So, the centre and the radius of the given circle are:
Centre: (3, 3)
Radius: 2 units
Let the centre of the circle which touches externally the given circle be g , f
The distance between centres of two circles is sum of radii of two circles i.e. g + 2
g 2 g 3 f 3
2 2
g 3 f 3 g 2
2 2 2
g 2 f 2 6 g 6 f 18 2 g
2
f2 10g – 6f + 14 = 0
y2 10x 6y + 14 = 0
Q 119. The circle passing through the point 1, 0 and touching the y-axis at 0, 2 also passes
through the point
Options:
3
(a) , 0
2
5
(b) , 2
2
3 5
(c) ,
2 2
(d) 4, 0
Explanation:
x x1 y y1 L 0
2 2
Equation of a circle passing through a point (0, 2) and touching line x = 0 is:
x 0 y 2 x 0
2 2
…(i)
The circle also passes through (−1, 0)
1 4 0
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5
Putting the value of in equation (i), we get
x 0 y 2 5x 0
2 2
x2 y 2 5x 4 y 4 0
Put y = 0 for x-intercept
x2 5x 4 0
x 1, 4
So, circle passes through (−4, 0)
Q 120. Let C be the circle with centre at (1, 1) and radius 1. If T is the circle centred at (0, y),
passing through origin and touching the circle C externally, then the radius of T is equal to
Options:
3
(a)
2
3
(b)
2
1
(c)
2
1
(d)
4
Explanation:
Explanation:
Moles of Solute
Molarity
Volume of Solution L
120
Moles of urea 2
60
Weight of solution = Weight of solvent + weight of solute
= 1000 + 120 = 1120 g
1120 g 1
Volume 0.973 L
1.15 g / mL 1000 mL / L
2.000
Molarity 2.05 m
0.973 JOIN @iitwale on Telegram
Q 122. The molarity of a solution in which 2.5 g Na2CO3 is dissolved in 400 mL will be
Options:
(a) 0.05 M
(b) 0.5 M
(c) 0.20 M
(d) 0.2 M
Explanation:
Molecular mass of Na2CO3 =106 g mol−1
2.5
2.5 g Na2CO3 has 0.02 mol
106
Now, it is given that,
0.02 mol are dissolved in 400 mL
Number of moles dissolved in 1000 mL (1 L)
0.02
Molarity of the solution 1000 0.05 M
400
Q 123. The molarity of a solution obtained by mixing 650 mL of 0.25 M HCl with 350 mL of 1.5
M HCl will be
Options:
(a) 0.6875 M
(b) 1.00 M
(c) 1.75 M
(d) 0.0975 M
Explanation:
M1V1 M 2V2
M
V1 V2
Given,
V1 = 650 mL
M1 = 0.25 M
V2 = 350 mL
M2 = 1.5 M
Q 124. Density of a 2.00 M solution of acetic acid in water is 1.00 g/mL. The molality of the
solution is:
Options:
(a) 3.258 mol kg-1
Explanation:
Thus, Mass of acetic acid in 1L solution = Number of moles of solute × Molar mass of solute
= 2.00 × 60 = 120 g
Now, given density of the solution = 1.00 g mL−1 JOIN @iitwale on Telegram
Thus mass of solvent = Mass of solution – mass of solute = 1000 – 120 = 880 g = 0.880 Kg
Q 125. How many grams of concentrated nitric acid should be used to prepare 350 mL of 4.0 M
HNO3? (The concentrated acid contains 60% HNO3.)
Options:
(a) 150 g
(b) 148 g
(c) 147 g
(d) 146 g
Ans. Option (c) is correct
Explanation:
w 1000
Molarity
M B V in mL
4 63 350 441
w g
1000 5
Q 126. A particle of mass 0.5 kg is moving in one dimension under a force that
delivers a constant power 1 W to the particle. If the initial speed (in m/s) of the
particle is zero, the speed (in m/s) after 9 s is
(a) 8
(b) 7
(c) 6
(d) 5
Explanation:
dW
Power =
dt
Total work done in 9 s is
W 1 9 9 KE f KEi
Since initial speed of the particle is zero so its initial kinetic energy will also be zero.
M
9 (v 2f vi2 )
2
M
9 (v 2f 0)
2
9 2
v 2f 36
0.5
vf 6
(a) 1 : 5
(b) 5 : 1
(c) 1 : 4
(d) 4 : 1
The minimum velocity required to complete a full circle in the vertical plane by a
bob of mass m, suspended by a string of length l = 5gl
Also, the speed at highest point is given as gl
The initial speed of 1st bob (suspended by a string of length l1 ) is 5gl1 .
The speed of this bob at highest point will be gl1
When this bob collides with the other bob there speeds will be interchanged.
l 5
gl1 5gl2 1
l2 1
Explanation:
Since the particle is taken along a circular path of radius a about the origin so,
x2 y 2 a2 …(i)
Now,
dw F dr F (dxiˆ dyjˆ) JOIN @iitwale on Telegram
xdx ydy
W K
(x y )
2 2
( x2 y 2 )
From (i)
xdx ydy
W K
(a 2 ) (a 2 )
K a 2 a 2
0 a
K
W xdx ydy 0
a a 0
a 2 2
L is
(a) L2 L3
(b)
2
1 2 3
L L
(c)
3
1 2 3
L L
(d) L L2
Ans. Option (a) is correct
Explanation:
We have,
F 2 x 3x 2
W Fdx
The work done in stretching the unstretched rubber-band by L is
2 x 3x dx
L
W 2
0
L
x 2 x3
0
L2 L3
Q 130. A block is moving with speed v towards a system of two blocks system as shown in figure.
The first block hits the second block elastically. If the maximum compression is x = 1 m. What
will be the common velocity by which two blocks system will move together after some time? (m
= l kg, k = 2Nm-1,v = 2 ms-1) JOIN @iitwale on Telegram
Options:
(a) 1 m/s
(b) 2 m/s
(c) 3 m/s
(d) 4 m/s
Explanation:
As the collision is elastic the first block will transfer its speed completely to second block. So,
initial scenario will be like this
At maximum compression is x.
1 2 1 1
mv 2 mv02 kx 2
2 2 2
mv 2 2mv02 kx 2 mv 2 kx 2 2mv02
mv 2 kx 2 1 4 2 1
v0 1ms 1 JOIN @iitwale on Telegram
2m 2 1
Q 131. Three positive numbers form an increasing GP. If the middle term of the GP is tripled, then
new numbers are in AP. Then, the common ratio of the GP is
Options:
(a) 2 2 3
(b) 3 2 2
(c) 3 2 2
(d) 3 2 2
Explanation:
Q 132. The sum of the first 10 term of the sequence 0.6, 0.66, 0.666,…, is
Options:
2
10
1
(a) 89
27 10
1
10
1
(b) 89
27 10
2
10
1
(c) 89
27 10
2
10
1
(d) 89
3 10 JOIN @iitwale on Telegram
Explanation:
We have,
0.6 0.66 0.666 ...upto10 terms
6 0.1 0.11 0.111 ...upto10 terms
1 11 111
6 2 3 ...upto10 terms
10 10 10
6 9 99 999
2 3 ...upto10 terms
9 10 10 10
2 1 1 1
1 1 1 ...upto10 terms
3 10 100 1000
2 1 1 1
10 ...upto10 terms
3 10 100 1000
1 10
1
10
2 1 10
3 10 1
10
1
2 1 1
10
10 1
3 9 10
2
10
1
89
27 10
Q 133. Let a1, a2, a3,.... be in harmonic progression with a1 = 10 and a20 = 50. The least positive
integer n for which an < 0 is
Options:
(a) 25
(b) 23
(c) 24
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(d) 21
Explanation:
1 1 1
If a1, a2, a3,.... are in harmonic progression, then , , .... are in AP.
a1 a2 a3
1 1
First term of AP,
a1 10
1 1
20th term of AP,
a20 50
1 1
19d
10 50
4
d
19 50
We have to find the least positive integer n for which an < 0
1
n 1 d 0
10
1 4
n 1 0
10 19 50
95
n 1
4
n 24.75
Q 134. If a2.a2 a3,... are terms of AP such that a1 + a5 + a10 + a15 + a20 + a24 = 225, then the sum of
first 24 terms is
Options:
(a) 9 103
(b) 9 102
(c) 10 92
(d) 10 93
Ans. Option (b) is correct
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Explanation:
We know that the sum of terms of AP equidistant from the beginning and end is always same and
it is always equal to the sum of first and last terms.
Sn 2 a1 an
24 n
S24
2
a1 a24
(a) 3n1 + 2
(b) 3 + 3n1
(c) 4 + 3n1
(d) None of these
Ans. Option (c) is correct
Explanation:
5
2 3n1 1
Sn
a rn 1
.r 1
3 1 r 1
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= 5 + 3n 1 = 4 + 3n 1
Options:
Ans. Option (a) is correct
Explanation:
(a) ONCl = 8 + 7 + 17 = 32 e–
ONO– = 8 + 7 + 8 + 1 = 24 e–
Therefore, ONCl and ONO– are isoelectronic
(b)
Central O-atom is sp2-hybridised with 1 lone pair, so bent shape. Hence, (b) is incorrect.
(c) In solid state, ozone is violet-black. Ozone does not exist in solid state, thus incorrect.
Options:
(c) The oxygen-oxygen bond length in ozone is identical with that of molecular oxygen
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(d) Ozone is used as a germicide and disinfectant for the purification of air.
Explanation:
The oxygen–oxygen bond length in ozone is identical with that of molecular oxygen.
Options:
Explanation:
The mountaineers have to carry oxygen cylinder and fighter pilots have to bear oxygen mask
because ozone is not useful for breathing.
Options:
(a) I and II
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(b) I, II and III
Explanation:
Ozone is formed by the interaction of fluorine. It turns tetramethyl base paper and benzidine paper
as violet and brown respectively.
Q 140. Which of the following statements about the depletion of ozone layer is correct?
Options:
(a) The problem of depletion is less serious at poles because NO2 solidifies and is not available for
consuming CIO° radicals
(b) The problem of depletion is more serious at poles because ice crystals in the clouds over poles
act as catalyst for photochemical reactions involving the decomposition of ozone by CI° and CIO°
radicals.
(c) Freons, chlorofluorocarbons, are inert chemically; they do not react with ozone in stratosphere
Explanation:
Freons, chlorofluorocarbons, are inert chemically; they do not react with ozone in stratosphere.
Q 141. A disc of mass 4 kg and radius 0.4 m is rotating with angular velocity 60 rads1. What is
angular velocity, if a mass of 0.5 kg is put on periphery of the disc?
Options:
Explanation:
2 2
1
2 = 48 rad s
Q 142. A circular disc rolls down an inclined plane. The ratio of the total kinetic energy to the
rotational kinetic energy is
Options:
(a) 1 : 3
(b) 3 : 1
(c) 2 : 3
(d) 3 : 2
Explanation:
1
Rotational kinetic energy, kR l 2
2
1 MR 2 2 1 2
kR Mv v R
2 2 2 JOIN @iitwale on Telegram
Translational kinetic energy
1
kT Mv 2
2
3
Mv 2
4
3
Mv 2
Total kinetic energy 4 3
Rotational kinetic energy 1
Mv 2 1
4
Q 143. A solid spherical ball of mass M and radius R rolls without slipping down on inclined plane
of length L and height h. What is the speed of its centre of mass, when the cylinder reaches its
bottom?
4
(a) gh
3
10
(b) gh
7
7
(c) gh
10
3
(d) gh
4
Explanation:
Let a be the acceleration of the rolling body and θ be the angle of the inclined plane.
g sin θ
Then, a ... 1
k2
1 2
R
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Moment of Inertia for a solid spherical ball
2MR 2
I MK 2
5
k2 2
... 2
R2 5
g sin θ 5
a g sin θ
2 7
1
5
5
0 2 g sin θ L
2
10 h 10
g L gh
7 L 7
10
v gh
7
Q 144. A diatomic molecule is formed by two atoms which may be treated as mass points m1 and
m2 joined by a mass less rod of length r. Then, the moment of inertia of the molecule about an axis
passing through the centre of mass and perpendicular to rod is
Options:
(a) Zero
(b) m1 m2 r 2
(c)
m1 m2 r 2
m1m2
mm
(d) 1 2 r 2
m1 m2
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Ans. Option (d) is correct
Explanation:
Let the centre of mass situated at distance x from atom of mass m1 and at distance (r − x) from
mass m2.
By definition, we have,
m1x = m2 (r − x)
m2
x r ... 1
m1 m2
Now, moment of inertia about the centre of mass is
l m1 x 2 m2 r x
2
2 2
m2 r m1r
I m1 m2
m1 m2 m1 m2
2 2
m2 r m1r
I m1 m2
m1 m2 m1 m2
2 1 2
m m 2 r 2 m2 m12 r 2
1
I
m1 m2
m1m2 r 2
I m2 m1
m1 m2
2
m1m2 r 2
I
m1 m2
Q 145. A thin rod of mass M and length L is bent in the middle so that the two halves make an
JOIN
angle of 70°. The moment of inertia of the bent rod about an axis passing @iitwale
through on Telegram
the bending
point and perpendicular to the plane defined by the two halves of the rod is
Options:
ML2
(a)
48
ML2
(b)
12
ML2
(c)
24
ML2
(d)
8 3
Explanation:
Rod is bent from the middle.
L
Length of each part =
2
M
Mass of each part =
2
1 2
Moment of inertia of a rod about an axispassing through its one end is ml
3
where,
m = mass of the rod
l = length of the rod
2
1 M L
Moment of inertia of each part of the rod about an axis passing through its one end
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2Telegram
Hence, net moment of inertia about an axispassing through its middle point O is
1 M L 1 M L 1 ML2 ML2 ML
2 2 2
I
3 2 2 3 2 2 3 8 8 12
Q 146. Two numbers are chosen from 1, 3, 5, 7,… 147, 149 and 151 and multiplied together in all
possible ways. The number of ways which will give us the product a multiple of 5, is
Options:
(a) 75
(b) 1030
(c) 95
(d) 1020
Explanation:
In the given numbers 1, 3,5,7,…, 147, 148, 151the numbers which are multiple of 5 are 5, 15, 25,
35,…, 145 which are an arithmetic sequence
Tn a (n 1) d
145 = 5 + (n – 1) 10
n = 15
and if total number of terms in the given sequence is m, then
151 = 1 + (m – 1) 2
m = 76
So, the number of ways in which product is a multiple of 5 = ( both two numbers from 5, 15, 25,
… , 145) or ( one number from 5, 15, 25, …, 145 and one from remaining numbers)
15C2 15C1 76 15C1
15 14
15 61
2
= 105 + 915
= 1020
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Q 147. A coin is tossed 5 times and the outcomes are recorded. How many outcomes are there?
Options:
(a) 32
(b) 2
(c) 16
(d) 8
Explanation:
In tossing a coin, there are 2 possible outcomes (head and tail). In tossing the coin second time
again, there are 2 possible outcomes and in third time, there are again 2 possible outcomes.
Q 148. From a committee of 10 persons, in how many ways can we choose a chairman and a vice-
chairman assuming one person cannot hold more than one position?
Options:
(a) 72
(b) 100
(c) 81
(d) 90
Out of 10 persons, one person can be chosen for chairman in 10 ways. Now, a person cannot hold
more than one position, i.e., out of 9 persons, one person can be chosen for vice-chairman in 9
ways.
Q 149. How many 6 digit telephone numbers can be constructed using the digits 0 to 9, if each
number starts with 54 and no digit appears more than once?
Explanation:
Explanation:
2n (n C0 n C1 n Cn 1 n Cn )
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2n 2(1 n) 2n 2n 2
Q 151. For one mole of a Van der Waals' gas when b = 0 and T = 300 K, the pV vs 1/V plot is
shown below. The value of the van der Waals' constant a (atm L mol −2)
(a) 0.5
(b) 0.7
(c) 0.6
(d) 0.8
Ans. Option (c) is correct
Explanation:
n2 a
p V nb nRT
V2
Given,
n 1and b 0
a
p 2 V RT
V
a
pV RT … (i)
V
18.2 19.4
a 0.6
42
a = 0.6
Q 152. Calculate the osmotic pressure of 0.02 M solution of cane sugar at 600 K (R= 0.08212 atm
degree1 mol1)
Options:
(a) 0.9852 atm
(b) 0.9582 atm
(c) 0.9825 atm
(d) 0.9528 atm
Q 153. If the value of Avogadro number is 6.023 1023 mol−1 and the value of Boltzmann constant
is 1.380 10−23 JK−1, then the number of significant digits in the calculated value of the universal
gas constant is
Options:
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(a) 5
(b) 2
(c) 4
(d) 3
Ans. Option (c) is correct
Explanation:
We have,
Universal gas constant, R = kNA
where, k = Boltzmann constant
and NA = Avogadro's number
R = 1.380 1023 6.023 1023J/Kmol
= 8.31174 8.312
Since, k and NA both have four significant figures, so the value of R is also rounded off up to 4
significant figures.
When number is rounded off, the number of significant figure is reduced.
So, the number of significant figure is 4.
Options:
(a) Heavier molecules transfer more momentum to the wall of the container
(b) Only a small number of molecules have very high velocity
(c) Between collisions, the molecules move in straight lines with constant velocities
(d) Between collisions, the molecules move in straight lines with constant velocities
Explanation:
According to a postulate of kinetic theory of gases, collision between the molecules as well as
with the wall of container is perfectly elastic in nature.
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Hence, option (a) is correct.
All other statements are incorrect.
Options:
Explanation:
A gas can be liquefied when T < TC and pressure P > PC
Q 156. In Carnot engine, efficiency is 30% at hot reservoir temperature T. For efficiency 40%,
what will be the temperature of hot reservoir?
Options:
6T
(a)
7
(b) 6T
7T
(c)
6
T
(d)
5
Explanation:
work done W
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The efficiency, =
heat input Q
T2
1
T1
T2
0.7
T1
T2 0.7T1
40 T T
NOW, 1 2' 2' 0.6
100 T1 T1
0.7T1
0.6
T1'
0.7
T1' T1
0.6
7
T1' T1
6
7
T1' T [ T1 = T]
6
Q 157. When an ideal gas at pressure p, temperature T and volume V is isothermally compressed to
V
V/n, its pressure becomes pi .If the gas is compressed adiabatically to , its pressure becomes pa.
n
Cp
The ratio pi/pa is
C
V
Options:
(a) 1
(b) n
Explanation:
or pi np ,..(i)
pa Va pV
V
or pa a pV
n
or pa n p
Q 158. If a gas has ‘n’ degrees of freedom, the ratio of the specific heats of the gas is
Options:
1 n
(a)
2
n
(b) 1
2
1
(c) 1
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2
(d) 1
n
Explanation:
Let us consider 1 mole of an ideal gas at kelvin temperature T. It has N molecules (Avogadro's
number). The internal energy of an ideal gas is entirely kinetic. The average KE per molecule of an
1
ideal gas is nkT (k is boltzman constant), where n is degree of freedom. Therefore the internal
2
energy of one mole of an gas would be
1 1 R
E N nkT nRT k
2 2 N
dE n
Now, Cv R
dT 2
n n
and Cp R R 1 R
2 2
n
1 R
2
Cp 2
1
Cv n n
2
Q 159. The work of 175 kJ is performed in order to compress one kilomole of a gas adiabatically
and in this process the temperature of the gas increases by 6°C. The gas is[R = 8.3 Jmol1K1]
Options:
(a) Triatomic
(b) Diatomic
(c) A mixture of monoatomic and diatomic
(d) None of the above
Explanation:
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For adiabatic process,
dQ = 0
According to first law of thermodynamics during adiabatic process all the change in internal
energy is in the form of work done
dU = W
where,
f is degree of freedom
n is number of mole of gas
103 f 8.3 6
175 103 J
2
f =7.03 7
(a) 3 T
(b) T 1/ 2
(c) T 2
(d) T 2
Here it is given that Vp2 = constant It (say). Hence, we may write the gas equation as,
pV = nRT
k
V nRT
V
nR
V T
k
V1 T1
So,
V2 T2
V2
T2 T1
V1
2V
T T 2
V
Q 161. Tangent are drawn from the points on the line x − y 5 = 0 to x2 + 4y2 = 4, then all the
chords of contact pass through a fixed point, whose coordinate are
Options:
4 1
(a) ,
5 5
4 1
(b) ,
5 5
4 1
(c) ,
5 5
Explanation:
We have,
Equation of line: x − y 5 = 0
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Equation of ellipse: x2 + 4y2 = 4
Let A(x1, x1 5) be a point on x y = 5, then the chord of contact of x2 + 4y2 = 4 with respect to
A is
x x1 + 4y (x1 5) = 4
xx1 4 yx1 20 y 4
(x + 4y) x1 (20y + 4) = 0
Since, it passes through a fixed point.
x + 4y = 0 and 20y + 4 = 0
1 4
y and x
5 5
4 1
So, the coordinates of fixed point is ,
5 5
Q 162. The normal at a point P on the ellipse x2 + 4y2 = 16 meets the x- axis at Q. If M is the
midpoint of the line segment PQ, then the locus of M intersects the latus rectums of the given
ellipse at the points
Options:
3 5 2
(a) ,
2 7
3 5 19
(b) ,
2 4
1
(c) 2 3,
7
4 3
(d) 2 3,
7
Ans. Option (c) is correct
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Explanation:
Equation of ellipse: x 2 4 y 2 16
x2 4 y 2
1
16 16
x2 y 2
1
16 4
a 4 and b 2
Equation of the normal to the given ellipse
4 x sec 2 y cos ec =12
Let,
7 cos
M ,sin h, k
2
7 cos
h
2
2h
cos
7
k sin
We know that,
cos2 sin 2 1
2
2h
k2 1
7
4h 2
k2 1
49
4 x2
y2 1 …(i)
49
For the given ellipse
4 3
e2 1
16 4
3
e
2
3
x 4 2 3
2
Putting the value of x in equation (i)
2
4 2 3
y2 1 JOIN @iitwale on Telegram
49
1
y
7
1
So, the coordinates of the required point are 2 3,
7
Q 163. The equation of tangents to the ellipse 3x2 + 4y2 = 5, which are inclined at 30° to the X-
axis, are
Options:
5
(a) y 3 X
2
1 5
(b) y X
3 2
1
(c) y X 1
3
5 2 5
y mx m
3 4
1 1
Slope of tangents are or
3 3
1 5 5
y x
3 9 4
1 65
y x
3 6
Options:
(a) t 2]
(b) t 1
(c) t 1
Explanation:
x2 y 2
Putting x at 2in 1, we get
a 2 b2
y2
t4 1
b2
x2 y 2
Q 165. The slopes of the common tangents of the ellipse 1 and the circle x2 + y2 = 3are
9 2
Options:
1
(a)
3
1
(b)
6
1
(c)
6
r 1 m2 a 2 m 2 b 2
3 1 m2 9m2 2
3 + 3m2 = 9m2 + 2
6m2 = 1
1
m2
6
1
m
6
Q 166. Two Faraday of electricity is passed through a solution of CuSO4. The mass of copper
deposited at the cathode is (at. mass of Cu = 63.5 u)
Options:
(a) 0 g
(b) 63.5 g
(c) 2 g
(d) 127 g
Explanation:
Given, Q = 2F
Atomic mass of Cu = 63.5u
Valency of copper = 2
We have,
Cu 2 SO24
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Cu 2 2e
Cu
1mol 2 mol 1mol=63.5
2F
Q 167. Given, ECr 3
Cr
0.74 V ; EMnO
Mn2
1.51 V and ECr
O 2 Cr 3
1.33 V ; ECl Cl 1.36 V
4 2 7
Explanation:
Higher the standard reduction potential better is oxidizing agent. Among the given EMnO
Mn2
is
4
Q 169. Resistance of 0.2 M solution of an electrolyte is 50. The specific conductance of the
solution of 0.5 M solution of same electrolyte is 1.4 Sm–1 and resistance of same solution of the
same electrolyte is 280. The molar conductivity of 0.5 M solution of the electrolyte in Sm 2mol–1
is
Options:
(a) 5 10–4
(b) 5 10–3
(c) 5 103
(d) 5 102
Ans. Option (a) is correct
Explanation:
Q 170. The equivalent conductance of NaCl at concentration C and at infinite dilution are c and
respectively. The correct relationship between c and is given as (where, the constant B is
positive)
Options:
(a) c = + (B)C
(b) c = – (B)C
(c) c = – (B) C
(d) c = + (B) C
Ans. Option (c) is correct
Explanation:
Q 171. The resistance of a wire at room temperature 20°C is found to be 20. Now to increase the
resistance by 20%, the temperature of the wire must be [The temperature coefficient of resistance
of the material of the wire is 0.002 per °C].
Options:
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(a) 142°C
(b) 124°C
(c) 150°C
(d) 122°C
Ans. Option (b) is correct
Explanation:
We have R1 R0 1 t
Finally, R0 1 t 24
6 1 t
Now,
5 1 20
Q 172. Three very large plates of same area are kept parallel and close to each other. They are
considered as ideal black surfaces and have very high thermal conductivity. The first and third
plates are maintained at temperatures 4T and 5T respectively. The temperature of the middle (i.e.
second) plate under steady state condition is
Options:
1
881 4
(a) T
2
1
2 4
(b) T
881
1
(c) 881 4 T
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(d) 880 4 T
Explanation:
5T 4T T0 4 T0 4
4 4
881T 4 2T0 4
1
881 4
T0 T
2
Q 173. Two gases, carbon monoxide (CO) and nitrogen (N2) at the same temperature have kinetic
energies E1 and E2 respectively. Then,
Options:
(a) E1 > E2
(b) E1 < E2
(c) E1 = E2
(d) E1 and E2 cannot be compared
Explanation:
The gases carbon monoxide (CO) and nitrogen (N2) are diatomic, so both have equal kinetic
5
energy kT . i.e., E1 E2
2
Q 174. During an experiment, an ideal gas is found to obey an additional law Vp2 = constant. The
gas is initially at temperature T and volume V. What will be the temperature of the gas when it
expands to a volume 3V?
Options:
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(a) 2 T
(b) T 1/ 2
(c) 2 T 2
(d) T 3
Explanation:
Here it is given that Vp2 = constant It (say). Hence, we may write the gas equation as,
pV = nRT
k
V nRT
V
nR
V T
k
V1 T1
So,
V2 T2
V2
T2 T1
V1
3V
T T 3
V
Q 175. If a piece of metal is heated to temperature and then allowed to cool in a room which is
at temperature 0 , the graph between the temperature T of the metal and time t will be closest to
Options:
(a)
(b)
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(c)
(d)
Since y2 16x 4y 57 = 0
y 2 2 16 x
61
16
Put y 2 Y
61
Y 2 16 x
16
Q 177. The slope of the line touching both the parabolas y 2 2 x and x 2 16 y is
Options:
1
(a)
2
3
(b)
2
1
(c)
4
1
(d) 3
4
Explanation:
m
1
m3
4
1
m 3
4
Q 178. A line L passing through the focus of the parabola y2 = 4(x 1), intersects the parabola in
two distinct points. If ’m’ be the slope of the line ‘L’ then
Options:
(a) 1 < m < 1
(b) m< 1or m> 1
(c) m R
(d) None of the above
Let y = Y, x 1 = X
Then, the equation becomes Y2 = 4X.
So, the focus = (2, 0)
m R {0}
Q 179. The tangent at (1, 7) to the curve x2 = y – 6 touches the circle x2 + y2 + 16x+12y + c = 0 at
Options:
(a) (6, 7)
(b) (– 6, 7)
(c) (6, –7)
(d) (–6, –7)
Explanation:
The tangent at (1, 7) to the parabola x2 = y − 6 is
1
x y 7 6
2
2x = y + 7 − 12
y = 2x + 5
which is also a tangent to the circle
x2 + y2 + 16x + 12y + c =0
Then, + β = − 12 = − 6 ( = β)
x = − 6 and y = 2x + 5 = −7
Point of contact is (− 6, − 7)
Q 180. Find the length of the line segment joining the vertex of the parabola y2 = 4ax and a point
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on the parabola, where the line segment makes an angle θ to the X-axis.
Options:
2a cos θ
(a)
sin 2 θ
4a cos θ
(b)
sin 2 θ
4a cos θ
(c)
3sin 2 θ
Explanation:
k
sin θ
l
k l sin θ
OA
and cos θ
OP
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h
cosθ h l cos θ
l
Q 181. Which of the following represents the correct order of increasing first ionisation enthalpy
for Ca, Ba, S, Se and Ar?
Options:
Explanation:
Ionisation energy increase along a period from left to right and decreases down a group. The
position of given elements in the periodic table is as
Group No. 16 8
2
Ca S Ar
Ba Se
Q 182. Ionisation energy in group 1A varies in thedecreasing order as JOIN @iitwale on Telegram
(a) Li > Na > K > Cs
(b) Na > Li > K >Cs
(c) Li > Cs > K > Na
(d) K > Cs > Na > Li
Explanation:
Atomic size inereases as we move from top todown in a group, therefore, the amount of
energyrequired for ejection of an electron from atom decreases i.e., ionisation energy decreases.
Hence,the correct order of IE1 is
Li > Na > K > Cs
Options:
(a) Li+
(b) C-
(c) B-
(d) Be-
Explanation:
Be- is the least stable ion, Be (1S22s2) has stable electronic configuration, addition of electron
decreases stability.
Explanation:
In general, the ionic radius increases on moving from top to bottom in group and decreases
onmoving fiom left te right in period So, the correctorder is
Na Li Mg 2 Be2
0.98Å 0.68Å 0.65Å 0.62 Å
Q 185. Which one of the following arrangements represents the correct order of electron gain
enthalpy (with negative sign) of the given atomic species?
Options:
(a) CI < F < S < CO
(b) O < S < F < CI
(c) S < O < CI < F
(d) F < CI < O < S
Explanation:
Generally electron gain enthalpy increases in a period from left to right but decreases in a group on
moving down. Therefore, halogens have very high electron affinities.
Fluorine due to its smaller size has unexpectedly low electron gain enthalpy than CI. Similar is
shown in case of O and S. Thus, the order of electron gain enthalpy is
O < S < F < CI
Q 186. If y sin tan 1 x , then
dy
dx
at x = 1 is equal to
Options:
1
(a)
2
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(b)
2 2
(c) 1
(d) 2
Explanation:
We have,
y sin tan 1 x
Using chain rule of differentiation
cos tan 1 x
dy 1
dx 1 x2
cos tan 1 1 .
dy 1
dx at x 1 1 12
1 π
cos
2 4
1 1
2 2
1
2 2
1
Q 187. If g is the inverse of a function f and f ' x , then g ' x is equal to
1 x3
Options:
(a) 1 x3
(b) 3x 2
1
(c)
1 g x
3
Explanation:
Since g is inverse of f
f g x x …(i)
On differentiating (i) with respect to x using chain rule, we get
f ' g x g ' x 1
1
g ' x
f ' g x
1
g ' x
1
1 g x
3
g ' x 1 g x
3
dy
Q 188. If x m y n = x y
m+n
, then calculate
dx
Options:
dy y
(a) =
dx x
dy x
(b) =
dx y
dy y
(c) =
dx x
Explanation:
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xm y n x y
m n
On differentiation
m n dy 1 dy
. m n . 1
x y dx x y dx
m n dy m n m n dy
. .
x y dx x y x y dx
n m n dy m n m
y x y dx x y x
nx ny my ny dy mx nx mx my
y x y dx x x y
dy y
dx x
dy
Q 189. If y x = e y x , calculate
dx
Options:
dy 1+ log y
2
(a) =
dx log y
dy 1 log y
2
(b) =
dx log y
dy 1+ log y
2
(c) =
dx log xy
dy 1+ log y
(d) =
dx log y
yx eyx
Taking log both sides
x log y y x log e
x log y y x
y x log y x................................ equation 1
On differentiation
dy 1 dy
x. . log y 1
dx y dx
dy x dy
. log y 1
dx y dx
x dy
1 1 log y
y dx
y x dy
1 log y
y dx
dy y 1 log y
dx yx
Put value of y from equation 1
dy x log y x 1 log y
dx x log y x x
dy x log y 11 log y
dx x log y
dy 1 log y
2
dx log y
2 x+1.3x
sin 1
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Options:
dy 2 x+1 .3x
(a) =
dx 1+ 36 x
dy 2 x .3x
(b) = log 6
dx 1+ 36 x
dy 2 x .3x
(c) = log 3
dx 1+ 6 x
dy 2 x 1 .3x
(d) = log 6
dx 1+ 36 x
Explanation:
2 x 1.3x
1
Let y sin
1 36 x
2.2 x.3x
1
sin
1 4 9x
1
2 6x 1 2 x 1
sin sin 1 x 2 2 tan x
x 2
1 6
2 tan 1 6 x
Now,
y 2 tan 1 6 x
On differentiation
6 x log 6
dy 2
dx 1 6
x 2
dy 6 log 6
x
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dx 1 36 x
dy 2 x 1.3x
log 6
dx 1 36 x
Explanation:
SO3 is planar (S is sp2 hybridised), BrF3 is T-shaped and SiO32 is planar (Si is sp2 hybridised).
Options:
(a) Tetrahedral
(c) Octahedral
1
H V Y C A
2
1
8 6 0 0 7
2
Hybridisation = sp3d2
Due to the presence of one lone pair of electron, XeF6 has distorted octahedral geometry.
Explanation:
Q 194. What is the correct order of hybridization of the central atom in the following compounds?
Options:
Explanation:
From the table given in the article we can see that, the correct matches are:
Options:
1
(a) sp2 and 3
1
(b) sp and 2
Explanation:
The hybridization state of each carbon atom and the -bond order of each
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1
sp2 and 3 respectively.
Q 196. An aluminium ring B faces an electromagnet A. The current / through A can be altered,
Options:
Explanation:
If current is passed through solenoid A as shown. Current entering at end A is clockwise. When
seen from the side of A, so it develops south polarity at A and north polarity at B. When current /
through A increase, it is like north of the magnet approaching the ring B and due to Lenz's law face
of ring B facing B develops north polarity and hence there is repulsion between the two.
Q 197. The current in the winding on a torpid is 4.0 A. There are 200 turns and the mean
circumferential length is 20 cm. If the inside magnetic field is 2.0 T, the relative permeability is
near to
Options:
(a) 1000
(b) 2500
(c) 2000
(d) 4000 JOIN @iitwale on Telegram
Explanation:
We have
μ 0 μ r Ni
B
2 r
4 107 μ r 200 4
2
2 20 102
80 102
μr
4 107 800
80 105
2500
4 800
Q 198. A metallic rod of length ‘l’is tied to a string of length ‘2l’ and made to rotate with angular
speed on a horizontal table with one of the string fixed. If there is a vertical magnetic field B in
the region, the emf induced across the ends of the rod is
Options:
2 Bl 3
(a)
2
3Bl 3
(b)
2
4 Bl 2
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2
5 Bl 2
(d)
2
Explanation:
The emf induced across the ends of the rod is given by:
x Bdx
3l
e
2l
3l
x2
B
2 2l
3l 2 2l 2
B
2
5 2
Bl
2
Q 199. A circular loop of radius 0.4 cm lies parallel to a much bigger circular loop of radius 40
cm. The centre of the smaller loop is on the axis of the bigger loop. The distance between their
centres is 25 cm. If a current of 4.0 A flows through the bigger loop, then the flux linked with
smaller loop is
Options:
(a) 10.11011 Wb
(b) 10 1011 Wb
(c) 10.911010 Wb
(d) 10.911011 Wb
4 107 4 40 102
2
B
3
2 0.4 0.25
2 2 2
4 107 4 40 102
2
0.4 102
2
Flux through the smaller loop = BS
3
2 0.4 0.25
2 2 2
= 10.911011 Wb
Q 200. A current carrying infinitely long wire is kept along the diameter of a circular wire loop,
without touching it. The correct statement (s) is / (are)
Options:
(a) The emf induced in the loop is zero if the current is constant
(b) The emf induced in the loop is finite if the current is constant
(c) The emf induced in the loop is zero if the current decreases at a steady rate
(d) The emf induced in the loop is finite if the current decreases at a steady rate
Explanation:
Due to current in the straight wire, net magnetic flux from the circular loop is zero. This is
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half of the circle.
Therefore, change in current will not cause any change in magnetic flux from the loop. Therefore,
induced emf under all condition through the circular loop is zero.
Options:
Explanation:
1
Let z 1 i
i log 2 ei 4
1
i log 2 log ei 4
2
1 i i
i log 2 log 2
2 4 2 4
Q 202. If xn cos i sin n , then x1 x2 x3 is
4 n
4
Options:
1 i 3
(a)
2
1 i 3
(b)
2
1 i 3
(c)
2
1 i 3
(d)
2
Explanation:
We have x1 x2 x3....
cos i sin cos 2 i sin 2
4 4 4 4
cos 3 i sin 3
4 4
1 i i
i log 2 log 2
2 4 2 4
cos 2 3
4 4 4
i sin 2 3
4 4 4
4 4
cos i sin
1 1 4 1 1 4
1 3i
cos i sin
3 3 2
π π
(a) 4 cos i sin
6 6
π π
(b) 2 cos i sin
6 6
π π
(c) 4 cos i sin
6 6
π π
(d) 2 cos i sin
6 6
Explanation:
Let z 3 i
r cos 3 ... i
3 1
2
r 2 cos 2 r 2 sin 2
2
r 2 cos 2 sin 2 3 1 4
r2 4 cos sin
2 2
1
r2
Since, the real and imaginary parts of z are both positive, so point lies in the first quadrant.
π
arg z
6
π π
z 3 i 2 cos i sin
6 6
Q 204. Let z be a complex number such that the imaginary part of z is non zero and
Options:
(a) 1
1
(b)
3
1
(c)
3
1
(d)
2
Explanation:
We have,
z2 z 1 a
1 1 4 1 a
z
2
1 4 1 a
1 4 4a
3
a
4
Q 205. Let be a complex cube root of unity and (1 + )10 = X + Y , then X and Y are
respectively equal to
(a) 0, 1
(b) 1, 1
(c) 1, 0
(d) 1, −1
Ans. Option (b) is correct
Explanation:
1 ω = ω2 ... 1
Now,
It is given that,
(1 + )10 = X + Y
ω2
10
= X + Y
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ω = X + Y
20
.ω2 = X + Y
6
ω3
We know that,
ω3 1
1 .ω2 = X + Y
6
ω 2 = X + Y
From (1) we can say that,
1 ω = X + Y
X 1, Y 1
Explanation:
Pext = l atm.
V1 =5L and V2 =20L
As work is done against constant external pressure, the process is ineversible.
W = Pext V
Q 207. Benzene and naphthalene form an ideal solution at room temperature. For this process,
the true statement(s) is (are)
Options:
(a) G is positive
(b) S system is negative
(c) S surroundings = 0
(d) H ≠ 0
Explanation:
Explanation:
H = H°f (H2O) Hof (H+) H°f (OH) 57.3 = 424.45 0 H°f (OH)
Q 209. The species which by definition has zero standard molar enthalpy of formation at 298 K is
Options:
(a) Br2(g)
(b) Cl2(g)
(c) H2O(g)
(d) CH4(g)
Ans. Option (b) is correct
Explanation:
Elements in its standard state have zero enthalpy of formation. Cl2 is gas at room temperature,
therefore H° of Cl2(g) is zero.
Q 210. The standard enthalpies of formation of CO2(g), H2O(l) and glucose(s) at 25°C are – 200
kJ/mol, – 150 kJ/mol – 650 kJ/mol, respectively. The standard enthalpy combustion per gram of
glucose at 25°C is
Options:
(a) + 1450 kJ
(b) – 1450 kJ
(c) +8.05 kJ
(d) – 8.05 kJ
Explanation:
We have,
HCO2
f H CO2 200 kJ mol1
H H 2O f H H 2O 150kJ mol1
H glocose f H glocose 650kJ mol1
H O 2 f H O2 0.00
C6 H12O6 s 6O2 g
6CO2 g 6H 2O l
1450
8.05kJ g 1
180
Q 211. Let A and B be two sets containing 3 and 2 elements respectively. Then the number of
subsets of the set A B, each having at least three elements is :
Options:
(a) 64
(b) 42
(c) 57
(d) 63
Explanation:
f: R → R defined by f(x) = 2 − 5x
Options:
(a) Onto
(b) Bijective
Explanation:
f(x) = 2 − 5x
Let x1 , x2 R
Such that f x1 f x2
2 5 x1 2 5 x2
x1 x2
2 y
f
5
2 y
2 5
5
y
Hence, f is onto
Thus, f is bijective
Q 213. Let f: {1, 3, 4} → {1, 2, 5} and g: {1, 2, 5} → {1, 3} be given by f = {(1, 2), (3, 5), (4, 1)}
and g = {(1, 3), (2, 3), (5, 1)}. What will be the value of gof.
Options:
(a) gof = 1,3 , 3,1 , 4,3
f = {(1, 2), (3, 5), (4, 1)} and g = {(1, 3), (2, 3), (5, 1)}.
3x+ 2 3
Q 214. If f x = , x , what is true about f?
4x 3 4
Options:
(b) f is invertible
Explanation:
3x+ 2 3
f x , x
4x 3 4
fof x f f x
3x + 2
f
4x 3
3x + 2
3 + 2
4x 3
3x + 2
4 3
4x 3
9x 6 8x 6
12 x 8 12 x 9
x
fof 1
Options:
Explanation:
Given,
f : 0,3 1, 29
f x 2 x3 15x 2 36 x 1
If the function is strictly increasing or decreasing in its domain, then the function is one-one.
f ' x 6 x 2 30 x 36
6 x 2 x 3
So, for given domain f(x) is increasing as well as decreasing. So, the given function is many one.
Now, put
f ' x 0
x 2,3
Thus, for range
f 0 1, f 2 29, f 3 28
The maximum and minimum value lies in the range 1, 29
So, the function is onto.