Jharkhand University of Technology

First Year UG Courses

CHEMISTRY-I (From 2020-21) Module1 (12 of 12-Question)-MKM
Model Question
Module 1: Atomic and molecular structure [10 Lectures]
Schrodinger equation. Particle in a box solutions and their applications for conjugated molecules.
Molecular orbitals of diatomic molecules and plots of the multicentre orbitals. Equations for atomic
and molecular orbitals. Energy level diagrams of diatomics. Pi-molecular orbitals of butadiene and
benzene and aromaticity. Crystal field theory and the energy level diagrams for transition metal
ions and their magnetic properties. Band structure of solids and the role of doping on band
structures.

Q.1. (A)Using Schrodinger Wave Equation derive expression for Wave Function, ψ and the
Energy, E for the Particle in 1-D box.
(B) What is ψ? What information is conveyed by ψ and ψ2?
Q.2. (A) Derive Schrodinger wave equation for the wave mechanical model of an atom
and discuss its application to hydrogen atom.
(B) What is Difference between Bohr atom and the Quantum mechanical model?
Q.3 (A) What do you know about the dual character of matter? Derive de-Broglie
Equation.
(B) Write a note on Heisenberg Uncertainty Principle. How this Principle goes against
Bohr’s theory.
(C) Describe application of Schrodinger wave equation for conjugated molecule.
Q.4 (A) With the help of Molecular Orbital theory, explain the paramagnetic character of
Oxygen and diamagnetic character of nitrogen.
(B) Calculate the bond order of N2- , CO, NO and O2+? Explain the bond order in N2
molecule
Q.5. (A) Write the decreasing order of stability for the following: H2 , H2+, H2- and justify.
(B) Write down the electronic configuration, bond order and magnetic behaviour of NO,
NO+ and NO- . Draw the molecular Orbital diagram of NO molecule.
Q.6. (A) Write Molecular Orbital Electronic Configuration, bond order, magnetic properties
of HF and HCl.
(B) Draw the molecular orbital diagram of HF and HCl.
Q.7 (A) What do you understand by LCAO? Discuss condition for combination of atomic
Orbitals to form Molecular Orbital (M.O)
(B) Write note on (4n+2) rule.
Q.8. (A) Draw Pi (π) molecular orbitals of butadiene.
(B) Draw Pi (π) molecular orbitals of benzene.
Q.9 (A) Discuss the concept of aromaticity and mention which important cyclic Compounds
exhibit it and why?
(B) Write down the three important conditions for formation of metallic bond.
Q.10 (A) Describe and compare the splitting of d-orbitals under the influence of Octahedral
and tetrahedral ligand fields. Draw energy level diagram.
(B) Explain the magnetic properties of transition metal ions.

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Q.11 (A)Discuss the main points of Crystal Field Theory (CFT). Show through a diagram, the
splitting of d-orbitals in Octahedral and tetrahedral crystal fields.
(B) Explain the splitting of d-orbitals under the influence of Square Planar ligand
Field with the help of energy level diagram
Q.12. (A) On the basis of VBT find the geometry and types of hybridization in the following
complexes (i) [Fe(CN)6]4- (ii) [Cu(CN)4]2-
(B) [Co (H2O)6]2+ is more stable than [Co(H2O)6]3+ . Explain on the basis of CFT.
Q.13 (A)Explain the terms conductors, semiconductors and insulators on the basis of Band
Theory/Molecular orbital theory.
(B)Explain Intrinsic and extrinsic semiconductor with examples.
(C) Discuss the electrical conductivity in n-type and p-type semiconductors.
MCQs

Q1 .Which of the following set of ΔH and ΔS values will lead to spontaneous reaction?
(a) ΔH is positive and ΔS is negative
(b) ΔH is positive and ΔS is positive (at low temperature)
(c) ΔH is negative and ΔS is positive
(d) ΔH is negative and ΔS is negative (at high temperature)
Q.2 which of the following have smallest ionic radius?
(a) F- (b) O2- (c) H (d) Cl-
Q.3. With the help of molecular orbital theory, predict which of the following species is
Diamagnetic (a) H2+ (b) H2- (c) O2 (d) O2+2
Q.4 which of the following is not a spontaneous process?
(a) Diffusion of a gas from higher pressure to lower pressure
(b) Flow of heat from lower to higher temperature
(c) Precipitation of AgCl in the reaction of silver nitrate with sodium chloride
(d) The conversion of water from liquid to vapour at 25°C
Q.5 Which of the following has largest de-Broglie wavelength, provided all have
Equal velocity? (a) CO2 molecule (b) Electron (c) Ammonia molecule (d) Proton
Q.6. The species having bond order different from that in CO is
(a) N2 (b) NO+ (c) CN- (d) NO-
Q.7 which of the following has largest de-Broglie wavelength, provided all have equal
velocity? (a) CO2 molecule (b) Electron (c) Ammonia molecule (d) Proton
Q.8. Which of the following species doesn’t exist under normal condition?
(a) Li2 (b) Be2+ (c) Be2 (d)B2
Q.9. To get an n-type semiconductor from silicon, it should be doped with a substance
with valence------------ (a) 2 (b)1 (c) 3 (d) 5

Q.10. The species having bond order different from that in CO is

(a) N2 (b) NO+ (c) CN- (d) NO-
Q.11. ψ2 =0 represents
(a) a node (b) an orbital (c) angular wave function (d) wave function
Q.12 The species having bond order different from that in CO is
(a) NO- (b) NO+ (c) CN- (d)N2

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Q.13. which of the following shall form an octahedral complex?
(a) d4 (low spin) (b) d8 (high spin) (c) d6 (low spin) (d) all of these
Q.14. Silicon doped with electron-rich impurity forms------------.
(a) p-type semiconductor (b) n-type semiconductor (c) intrinsic semiconductor
(d) insulator
Q.15. Silicon doped with Galium forms-
(a) p-type semiconductor (b) n-type semiconductor
(c) Intrinsic semiconductor (d) Insulator

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