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Chapter 9
Coagulation and Flocculation
Note: If any errors are noted in this solution manual or in the textbook, please notify
Kerry Howe at howe@unm.edu
PROBLEM 9-1
Solution
1. Calculate electrophoretic mobility (see Eq. 9-3).
v E 12.5 µm / s
v=
o
= = 0.125 ( µm / s ) / ( V / cm )
E 100 V / cm
2. Calculate zeta potential using Eq. 9-3.
(0.125 µmcm / s V)(4 π)(0.890 x 10 −3 Ns / m2 )(1 m /106 µm)(1 m /102 cm)
Z=
(78.54)(8.854188 x 10-12 C2 /Jm)
= 0.0201
= V 20.1 mV
PROBLEM 9-2
Problem Statement - Particles are present in a water with the following chemical
characteristics. Estimate the thickness of the particle electrical double layer.
Concentration, Concentration,
Cation Anion
mg/L mg/L
Ca2 + 40.0 HCO3– 91.5
Mg2 + 12.2 SO42– 72
+ –
Na 15.1 Cl 22.9
+
K 5.1 NO3– 5.0
Solution
1. Determine the ionic strength of the sample water.
a. Convert the concentration of each ion to molar concentration.
For example:
1. Estimate the thickness of the particle electrical double layer using Eq. 9-4.
1
−
(2)(1000)e NA I 2 2
κ −1 =
1010
εεo k T
1
−
10 A (2)(1000L/m3 )(1.60219×10 −19 C) 2 (6.02205×10 23 /mole)(0.012mole/L) 2
κ −1
10= −12 −23 27.7 A
m (78.54)(8.854188 ×10 C 2
/Jm)(1.38066 ×10 J/K)(273 + 25K)
PROBLEM 9-3
Problem Statement - Determine the thickness of the particle electrical double layer if
the ionic strength is 0.0025 mole/L.
Solution
Problem Statement - Prepare a plot of the thickness of the electrical double layer
versus the ionic strength.
Solution
1. Calculate the thickness of the electrical double layer at a given I using Eq. 9-4.
For example, when I = 0.001 mole/L, the thickness of the electrical double layer is
calculated as follows:
1
−
A (2)(1000L/m3 )(1.60219×10 −19 C) 2 (6.02205×10 23 /mole)(0.001mole/L) 2
κ −1 (10=
10
) 96.2 A
m (78.54)(8.854188×10 −12 C 2 /Jm)(1.38066×10 −23 J/K)(273 + 25K)
Calculate the thickness at other ionic strengths following the same procedure.
2. Plot the thickness of the electrical double layer versus the ionic strength.
The thickness of the electrical double layer shrinks dramatically with increasing
ionic strength when ionic strength is less than 0.03 mole/L.
PROBLEM 9-5
Problem Statement - Calculate the amount of Fe(OH)3 precipitate formed and amount
of alkalinity consumed (expressed as CaCO3) by 25 mg/L dose of ferric sulfate
Fe2(SO4)3.
PROBLEM 9-6
Problem Statement - A natural water with a flow of 3800 L/d is to be treated with an
alum dosage of 60 mg/L. Determine the chemical feed rate for the alum, the
amount of alkalinity consumed by the reaction, and the precipitate produced in
mg/L and kg/day.
Solution
1. Determine the chemical feed rate for the alum.
L mg 1g
Amount of alum=3800 ×60 × 3 =228 g/d
d L 10 mg
2. Calculate the amount of alkalinity consumed by the reaction. Write the applicable
stoichiometric equation (see Eq. 9-11).
PROBLEM 9-7
Problem Statement - Determine the amount of Fe(OH)3 produced and the amount of
alkalinity consumed when 60 mg/L of ferric chloride [FeCl3 · 6H2O] is reacted with
a natural water. Assume enough alkalinity is present.
Solution
1. Write the applicable stoichiometric equation (see Eq. 9-12).
FeCl3 6H2O → Fe ( OH)3↓ + 3H+ + 3Cl− + 3H2O
Solution
a. Determine the basicity of Al4(OH)6(Cl2)2.
1. Determine the molar ratio of the hydroxide bound to the metal ion.
[OH]/[M] = 6/4 = 3/2
2. Calculate the basicity using Eq. 9-16.
[OH] 3 1
Basicity =(100% ) =× (100% ) =
50%
[M] ZM 2 3
PROBLEM 9-9
Problem Statement - The following data were obtained from a bench-scale coagulation
flocculation test. Using these data, estimate the alum dosage for turbidity removal
and for NOM removal.
Solution
1. Plot turbidity and DOC concentration versus alum dose.
PROBLEM 9-10
Problem Statement - Estimate the DOC removal using alum as a function of dose for a
concentration range varying from 10 to 90 mg/L for the following conditions: initial
DOC = 5 mg/L, initial UV254 absorbance = 0.138 cm-1, and pH = 7.
Solution
mg 2mmolAl3+
Al =
3+
10 alum × =0.0337mmol / L Al3+
L 594mgalum
cm 0.138 cm−1
(SUVA)i =
100 × =2.76 L / mg.m
m 5 mg / L
3. Calculate the non-adsorbable DOC using Eq.9-19 and model parameter from
Table 9-8.
mg DOC
Q m= 4.91 × 73 − 74.2 × 72 + 284 × 7= 36.33
mmol Al3+
mg mmol 1 mg mg mg
=B 36.33 × 0.0337 + −5 + 1.765= 4.79
mmol L 0.147 L / mg L L L
Comment
When the alum dose increases from 10 mg/L to 90 mg/L, DOC removal efficiency
increases from 7.3 percent to 37.1 percent.
PROBLEM 9-11
Problem Statement - Estimate the DOC removal using ferric chloride as a function of
dose varying from 5 to 50 mg/L for the following conditions: initial DOC = 5 mg/L,
initial UV254 absorbance = 0.138 cm-1, and pH = 7.
Solution
mg 1mmolFe3+
Al =
3+
5 alum × =0.031mmol / LFe3+
L 162.2mgalum
2. Calculate the specific UV absorbance using Eq.9-18.
cm 0.138 cm−1
(SUVA)i =
(100 ) × =2.76 L / mg.m
m 5 mg / L
3. Calculate the nonadsorbable DOC using Eq.9-19 and model parameter from
Table 9-8.
mg L
DOCna = 5 −0.028 × 2.76 + 0.23 = 0.764 mg / L
L mg.m
mg DOC
Q m= 4.96 × 73 − 73.9 × 72 + 280 × 7= 40.18
mmol Fe3+
mg mmol 1 mg mg mg
=B 40.18 × 0.0308 + −5 + 0.764
= 11.7
mmol L 0.068 L / mg L L L
Comment
When the iron dose increases from 5 mg/L to 50 mg/L, DOC removal efficiency
increases from 5.3 percent to 35.5 percent.
PROBLEM 9-12
Solution
1. Collision frequency function for dj = 100 A.
a. Calculate the collision frequency function for macroscale flocculation using
Eq. 9-30.
G ( di + d j )
1 3
=
βM
6
3
1 1 1m 1m −16
βM = × 100 2µm × 6 + 100A × 10 = 1.35 × 10
6 s 10 µm 10 µm
Log(βM ) =−15.87
b. Calculate the collision frequency function for microscale flocculation using Eq.
9-42.
2kT 1 1
=βµ + ( di + d j )
3µ di d j
1m 1m −16
2µm × 6 + 100A × 10 = 4.70 × 10
10 µ m 10 µm
Log(βµ ) =−15.33
c. Calculate the collision frequency function for differential settling using Eq. 9-
50.
π(ρp − ρl )g
( di + d j ) ( di − d j )
3
=βDS
72µ
βDS
( )
π 1100 mkg3 − 999.1 mkg3 × 9.81 sm2 1m 1m
3
2µm × 6 + 100A × 10
72 × 1.139 × 10 −3 Nm2s 10 µm 10 µm
1m 1m −19
2µm × 6 − 100A × 10 = 6.13 × 10
10 µm 10 µm
Log(βDS ) =
−18.21
2. Calculate collision frequency function for other dj and plot the Log collision
frequency function versus dj.
Problem Statement - Based on your reading of this chapter, provide a brief answer to
the following questions: (a) Who first came up with the principal idea behind
flocculation theory? When? (b) Who were the first people to put flocculation into
practice? When? (c) Who proposed the concept of RMS velocity gradient? When?
Solution
a. Smolochoski first came up with the microscale flocculation mechanism in 1917.
Langlier came up with the macroscale flocculation mechanism in 1921 and
O’Melia came up with the differential settling mechanism in 1978.
b. Langlier was the first person to put flocculation into practice in 1921.
c. Camp and Stein proposed the concept of RMS velocity gradient in 1943.
PROBLEM 9-14
Problem Statement - Based on your reading of this chapter, provide a brief answer to
the following questions: (a) Flocculation installations can be divided into what two
groups? (b) Which type of flocculator produces very large and fluffy floc? (c) What
are two advantages of vertical turbines versus horizontal-shaft paddles for
flocculation? (d) What are the two principal impeller types used for flocculation? (e)
What is the principal disadvantage of hydraulic flocculators?
Solution
a. Flocculation installations can be divided into mechanical flocculation and hydraulic
flocculation.
b. Hydraulic flocculation produces very large and fluffy floc.
c. Advantages of vertical turbines versus horizontal shaft paddles:
1. Flocculators can be maintained or replaced without basin shutdown.
2. Highest energy input potential.
d. The impellers used for mixing can be placed in two broad classifications:
1. radial flow impellers
2. axial flow impeller
e. The principal disadvantage of hydraulic flocculators is little flexibility.
Homework Solution Manual Page 15 of 20
MWH’s Water Treatment: Principles and Design, 3rd ed. Version 1
Chapter 9 - Coagulation and Flocculation
PROBLEM 9-15
Solution
Down-pumping axial flow impellers help keep the particles in the tank in suspension.
PROBLEM 9-16
Solution
1. Determine the Reynolds number using Eq. 9-57.
=
Re
D2Nρ
=
( 22 m2 )( 25min−1 )( 999.7Kg / m=
3
) 1.27 × 106
µ s
(1.31× 10 kg /(ms) )
−3
60
min
2. Determine the power applied to the shaft to rotate it.
a. Obtain the power number, NP from Table 9-12.
The power number for a Rushton turbine ranges from 4.5 – 5.5. Use NP = 5
b. Calculate the power required using Eq. 9-58.
3
min
5 ( 998kg / m ) 25min−1× ( 2m )
5
P =ρ
NP N D = 3 5 3
60 s
=
1.16 × 10 4 W = 11.6kW
3. The impeller pumps radial flow and creates substantial trailing vortices.
Solution
1. Determine the tank turnover time.
a. Calculate the volume of tank.
V = (4m)2 x 4m = 64 m3
b. Obtain the pumping number, NQ from Table 9-12.
The pumping number for a Rushton turbine is 0.72.
c. Calculate the flow rate be rearranging Eq. 9-46.
min
( 2m ) =
3
Q= 0.72 25min−1×
NQND3 = 2.4m3 / s
60 s
d. Calculate the tank turnover time.
t = V/Q = 64 m3/(2.4 m3/s) = 26.7 s
b. Calculate the G value using Eq. 9-35. (See Appendix C for values of the
absolute viscosity of water.)
P 1.16 × 10 4 W
=G = = 371 s −1
µV 1.31 × 10 −3 kg / (m ⋅ s) × 64m3
Problem Statement - What is the largest paddle wheel that meets the design criteria in
Table 9-14? How many paddle boards may be used on such a wheel?
Solution
1. The largest paddle wheel that meets the design criteria in Table 9-14 is the 4 m
diameter wheel.
2. Determine the number of boards that may be used.
a. Estimate the basin area.
1. Calculate the basin length.
length of the basin = dia of the paddle wheel + 2 x wall clearance
length of the basin = (4 m) + 2(0.7 m) = 5.4 m
2. Calculate the basin width.
The paddle board length is selected from Table 9-14. Use the longest
available board (3.5 m) to maximize construction efficiency.
width of the basin = (3.5 m) + 2(0.7 m) = 4.9 m
3. Calculate the basin area from the length and width determined in steps
2aii and 2aiii.
area of the basin = 5.4 m x 4.9 m = 26.5 m2
a. Estimate the total area of boards.
According to Table 9-14, the area of the boards should be smaller than 20
percent of tank section area.
Apaddle boards = 0.2 x 26.5 = 5.3 m2
c. Estimate the number of boards.
area of one board = 3.5 m x 0.15 m = 0.525 m2
n = 5.3 m2 / 0.525 m2 = 10
Conclusion
Ten boards may be used on a 4 m diameter wheel. If the paddle wheel flocculators
have the same design as Example 9-9, 12 boards may be used on a wheel.
Homework Solution Manual Page 18 of 20
MWH’s Water Treatment: Principles and Design, 3rd ed. Version 1
Chapter 9 - Coagulation and Flocculation
PROBLEM 9-19
Solution
G
1. Determine the water power input required to achieve a value of 30 s-1 using Eq
9-35.
= G2µV
P
( 30 s−1 ) 1.31× 10 −3 kg /(ms) ( 208.3 m3=
) 245.6 kg ⋅ m2 / s=3 245.6 J / s
2
=
P
2. Determine the power required by the paddles by rearranging Eq. 9-61, and noting
that the area and shape of first, second, and third boards is the same, therefore:
ρ CD A p
=P ( Vinside
3
paddles ) + ( Vmiddle paddles ) + ( Voutside paddles )
3 3
2
a. Determine area of boards at each position (inside, middle, and outside):
Ap = (2 wheel)(4 boards/wheel)(0.15 m)(2.97 m) = 3.56 m2
b. Check length to width ratio and select drag coefficient, CD.
Paddle L/W = 2.97/0.15 = 19.8
From Table 9-14, CD ~ 1.5
b. Develop parameters needed to determine paddle power requirements.
The velocity of the paddles = r 2π N/(60 s/min)(0.75)
Where r = distance to centerline of paddle from center of rotation
N = shaft rotational speed, rev/min
0.75 = relative velocity of paddle with respect to fluid
The diameter of the paddle wheel is 4 m, rwheel = 2 m
rinside = r1 = 0.67 – 0.15/2 = 0.595 m
rmiddle = r2 = 1.33 – 0.15/2 = 1.255 m
routside = r3 = 2.0 – 0.15/2 = 1.925 m
436.7
3=
N 2.73 rev / min
(2,664.7)(4.85 x10 −4 )(9.321)
PROBLEM 9-20
Problem Statement - What is the minimum water depth for a hydraulic flocculator?
Solution
The minimum water depth for a hydraulic flocculator is 1 m.
PROBLEM 9-21
Solution
1. The principal advantages of an Alabama flocculator are that the flow arrangement
is simple and the entrance pipe can create the jet.
2. The principal advantage of a variable-gate flocculator is that the flexible design
enables hydraulic flocculation to achieve constant mixing at variable flow.
Homework Solution Manual Page 20 of 20
MWH’s Water Treatment: Principles and Design, 3rd ed. Version 1
Chapter 9 - Coagulation and Flocculation