1771434JEE - Main - Examination - 06!04!2014 - Code-F (PCM)

CAREER POINT
JEE Main Exam 2014 (Solution)

Code – F Date : 06-04-2014
Part A – CHEMISTRY Q.2 Which one of the following bases is not

present in DNA ?
Q.1 Consider separate solutions of 0.500M (1) Adenine (2) Cytosine
C2H5OH(aq), 0.100 M Mg3(PO4)2(aq), 0.250M
KBr(aq) and 0.125M Na3PO4(aq) at 25ºC. (3) Thymine (4) Quinoline
Which statement is true about these solutions,
assuming all salts to be strong electrolytes ? Ans. [4]
(1) 0.100 M Mg3(PO4)2(aq) has the highest Sol. CP Students may find this question in CP
osmotic pressure
Exercise Sheet: [Chapter: Biomolecule,
(2) 0.125 M Na3PO4(aq) has the highest
osmotic pressure Level # 2, Page No. 57, Q.27]
(3) 0.500 M C2H5OH(aq) has the highest D.N.A contain four bases
osmotic pressure.
(4) They all have the same osmotic pressure → Adenine
Ans. [4] → Guanine
Sol. CP Students may find similar question in CP
Exercise Sheet: [Chapter : Solution & → Cytosine
Colligative property, Level # 1, Page No. 71,
Q. 58] → Thymine
Q α = 100%
So that quinoline is not present in D.N.A.
∴ i = no. of particles given by an electrolyte
0.500 M C2H5OH (aq.) ; i=1
0.100 M Mg3(PO4)2 (aq.) ; i = 5 Q.3 Considering the basic strength of amines in
0.250 M KBr (aq.) ; i=2 aqueous solution, which one has the smallest
0.125 M Na3PO4 (aq.) ; i=4 pKb value ?
according to formula of osmotic pressure,
(1) CH3NH2 (2) (CH3)3N
π ∝ (i × C)
π( C2H5OH ) ∝ 1 × 0.5 (3) C6H5NH2 (4) (CH3)2NH
π( Mg3 ( PO4 )2 ) ∝ 5 × 0.1 Ans. [4]
π(KBr) ∝ 2 × 0.25 Sol. CP Students may find this question in CP

π( Na 3PO4 ) ∝ 4 × 0.125 Exercise Sheet: [Chapter: GOC, Level # 2, Q.37]
All have same osmotic pressure In aqueous solution
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CAREER POINT [ CODE – F ]
If alkyl group (R) =CH3 Q.5 On heating an aliphatic primary amine with
chloroform and ethanolic potassium
then basic strength order is
hydroxide, the organic compound formed is:
2ºamine > 1ºamine > 3ºamine > Anilene (1) an alkane diol (2) an alkyl cyanide
(CH3)2NH > CH3–NH2 > (CH3)3N > C6H5NH2 (3) an alkyl isocyanide (4) an alkanol
basic strength ↑ Kb ↑ pKb ↓ Ans. [3]
so that (CH3)2NH have smallest pKb Sol. CP Students may find this question in CP
Exercise Sheet: [Chapter: Nitrogen containing
compound, Level # 1, Q.59]
Q.4 The metal that cannot be obtained by Carbylamine reaction [isocyanide test]
electrolysis of an aqueous solution of its salts is
R – NH2 + CHCl3 Ethanolic
 KOH
→
(1) Ca (2) Cu (3) Cr (4) Ag
R–N C + KCl + H2O
Alkyl isocyanide (Pungent smell)
Ans. [1]
Sol. CP Students may find question based on

1
similar concepts in theory sheet of Metallurgy Q.6 For the reaction SO2(g) +
O2(g) SO3(g)
2
Highly electropositive metals can not be if KP = KC(RT)x where the symbols have
obtained by electrolysis of an aqueous
solution of it's salt. usual meaning then the value of x is:
(assuming ideality)
Ca is s-block metal which is highly
electropositive. 1 1
(1) − (2) (3) 1 (4) – 1
2 2

Ans. [1] 2Mn+2 → 2Mn+3 + 2e– Eºred. = 1.51 V
Sol. CP Students may find Similar Question in Overall reaction

CP Exercise Sheet: [Chapter: Chemical
3Mn+2 → 2Mn+3 + Mn
Equilibrium, Level # 2, Q. 8]
Eº = Eºcathode – Eºanode
1
SO2(g) + O2(g) SO3(g)
2 = –1.18 – 1.51
∆n = Σ moles of products – Σ moles of = –2.69 V
reactants Since value of Eº is negative therefore the

 1 reaction will not occur.
= (1) – 1 + 
 2
1 Q.8 If Z is a compressibility factor, Vander Waals
= −
2 equation at low pressure can be written as :
We know that, KP = KC (RT)∆n a Pb
(1) Z = 1 – (2) Z = 1 –
1 VRT RT
∴ ∆n = − =x
2 Pb RT
(3) Z = 1 + (4) Z = 1 +
RT Pb
Q.7 Given below are the half-cell reactions : Ans. [1]
Mn2+ + 2e– → Mn; Eº = –1.18 V Sol. CP Students may find this question in CP
Exercise Sheet: [Chapter: Gaseous state,
2(Mn3+ + e– → Mn2+); Eº = +1.51 V
Level #3, Page No. 29, Q. 9]
The Eº for 3Mn2+ → Mn + 2Mn3+ will be : We know that,
(1) – 2.69 V; the reaction will occur
 a 
 P + 2  (V – b) = RT
(2) – 0.33 V; the reaction will not occur  V 
(3) – 0.33 V; the reaction will occur At low pressure

V >> b or V – b ~_ V
(4) – 2.69 V; the reaction will not occur
 a 
Ans. [4]  P + 2  V = RT
 V 
Exercise Sheet: [Chapter: Electrochemistry, a
PV + = RT
Level # 2, Page No. 31, Q. 37] V
Reaction at cathode : a
PV = RT –
V
Mn+2 + 2e– → Mn Eºred. = –1.18 V
PV a  a 
Reaction at anode :
RT
=1–
VRT  Z = 1 − VRT 
 

Q.9 In the reaction Q.11 The ratio of masses of oxygen and nitrogen
in a particular gaseous mixture is 1 : 4. The
CH3COOH LiAlH
 4 → A PCl
5 → B Alc
. KOH
→ C
ratio of number of their molecule is -
the product C is -
(1) Acetylene (2) Ethylene (1) 7 : 32 (2) 1 : 8
(3) Acetyl chloride (4) Acetaldehyde
(3) 3 : 16 (4) 1 : 4
Ans. [2]
Ans. [1]
Exercise Sheet: [Chapter: Oxygen Containing Sol. Let mass of O2 = x g
Sub III, Ex. 20 Page No. 107 + Oxygen
N2 = 4x g
Containing Sub I Ex. 13 Page No. 21]
x
CH3COOH LiAlH4
 → CH3–CH2–OH No. of moles of O2 =
Reduction 32
PCl5
CH3–CH2–Cl 4x
No. of moles of N2 =
β-elimination Alc. KOH
28
CH2 = CH2 x
Ethylene
∴ no. of molecules of O2 = NA
32
Q.10 Among the following oxoacids, the correct
decreasing order of acid strength is - 4x
no. of molecules of N2 = NA
28
(1) HClO4 > HOCl > HClO2 > HClO3
(2) HClO4 > HClO3 > HClO2 > HOCl ∴ Ratio of number of molecules of O2 and N2
(3) HClO2 > HClO4 > HClO3 > HOCl xN A

7
(4) HOCl > HClO2 > HClO3 > HClO4 = 32 =
4 xN A 32
Ans. [2] 28
Sol. CP Students may find this question in CP
Exercise Sheet: [Chapter: p-block elements,
Level # 1, Page No. 32, Q. 75] Q.12 Which one of the following properties is not
General form of an oxyacid is (HO)mZOn shown by NO ?
m = basicity (1) It is a neutral oxide
Z = central atom
(2) It combines with oxygen to form nitrogen
n = no. of remaining O-atoms
dioxide
As value of n increases, acidic strength also
increases. (3) It’s bond order is 2.5
HClO4 > HClO3 > HClO2 > HOCl
(4) It is diamagnetic in gaseous state
n=3 n=2 n=1 n=0

Ans. [4] Q.14 For which of the following molecule
Sol. CP Students may find this question in CP significant µ ≠ 0 ?

Level # 1, Page No. 29, Q. 26] Cl CN
NO is paramagnetic in gaseous state because
(a) (b)
it has one unpaired e–
N=O Cl CN
Q.13 Which series of reactions correctly represents

OH SH
chemical relations related to iron and its
compound ? (c) (d)
(1) Fe O
2 , heat
→ FeO dil
H 2SO 4
→ OH SH
FeSO4 heat
→
 Fe (1) (a) and (b) (2) Only (c)
(2) Fe Cl
2 ,
heat
→ FeCl3 heat
 , ari
→
(3) (c) and (d) (4) Only (a)
Zn
FeCl2 → Fe
Ans. [3]
(3) Fe O
2 , heat
→ Fe3O4 CO
,600 º C
→
Sol.
CO , 700 º C
FeO  → Fe
x y
H H
(4) Fe dil
H 2SO 4
→ FeSO4 H
2SO 4 , O 2
→ O S
Fe2(SO4)3 heat
→
 Fe Net dipole Net dipole
moment is moment is
Ans. [3] present present
O S
x H y H
Sol. CP Students may find similar Question in
CP Exercise Sheet: [Chapter: Metallurgy,
µ≠0 µ≠0
Level # 3, Page No. 134, Q. 7]
O 2 , heat

Fe → Fe3O 4 CO
,( R .A.)
→ FeO (about O-atoms (about S-atoms
600 º C
(FeO + Fe2O3 )
700ºC CO, (R.A)
shape is angular/ shape is angular/
Fe
not planar) not planar)
CO acts as reducing agent in this reaction.

Q.15 CsCl crystallises in body centred cubic Ans. [4]

lattice. If ‘a’ is its edge length then which of Sol. CP Students may find this question in CP
Exercise Sheet: [Chapter: Polymer, Level # 3,
the following expressions is correct ? Page No. 34, Q. 14]
3a
(1) rCs+ + rCl– = Removal of small molecule like H2O during
2
polymerisation known as condensation
3
(2) rCs+ + rCl– = a
2 polymer.
(3) rCs+ + rCl– = 3a nHO–CH2–CH2–O–H + nHO–C C–OH

|| ||
ethylene glycol
O O
(4) rCs+ + rCl– = 3a terpthalic acid
–H2O
Ans. [2]
–O–CH2–CH2–O–C C––
Sol. CP Students may find this question in CP || ||
O O n
Exercise Sheet: [Chapter: Solid State, Level # 1, Dacron [TERELENE]
Q. 29, Similar Question Ex # 44, Ex # 53, Theory
Q.17 For the estimation of nitrogen, 1.4 g of an
Page No. 97, Point - 7] organic compound was digested by Kjeldhal
method and the evolved ammonia was
Cs M
absorbed in 60 mL of sulphuric acid. The
10
Cl M
unreacted acid required 20 mL of sodium
10
hydroxide for complete neutralization. The
percentage of nitrogen in the compound is -
(1) 10% (2) 3% (3) 5% (4) 6%
a
Ans. [1]
rCl− + 2rCs+ + rCl− = 3a Sol. CP Students may find similar Question in
CP Exercise Sheet: [Chapter: Purification of
Characterisation of Organic Compound
3a Level # 4 Page No. 18
∴ rCs + + rCl – =
2 1.4 × N × V
%N =
W
N → Normality of Acid
Q.16 Which one is classified as a condensation N × V = equivalent of acid consumed for NH3
polymer ? N=n×M
1
(1) Neoprene (2) Teflon N= 2×
10
(3) Acrylonitrile (4) Dacron n → basicity of acid

n=2 Ans. [4]

1 Sol. CP Students may find similar question in CP
eq. of acid = 60 × × 2 = 12
10 Exercise Sheet: [Chapter: Chemical
excess eq. of acid ≡ eq. of NaOH Energetics, Page No. 155, Q. 24]
1
= 20 × =2
10 C2H5OH(l) + 3O2(g) → 2CO2(g) + 3H2O(l)
eq. of acid used = 12 – 2 = 10

∆H = ∆E + ∆nRT
1.4 × 10
Q %N = = 10%
1. 4 ∆n = 2 – 3 = –1
Q.18 For complete combustion of ethanol, We know that heat produced in bomb
C2H5OH(l) + 3O2(g) → 2CO2(g) + 3H2O(l), calorimeter is ∆E
the amount of heat produced as measured in 8.314 × 298

bomb calorimeter, is 1364.47 kJ mol–1 at = –1364.47 – 1 ×
1000
25ºC.. Assuming ideality the Enthalpy of
combustion, ∆CH, for the reaction will be : = –1364.47 – 8.314 × 298 × 10–3
(R = 8.314 kJ mol–1) = –1364.47 – 2476.38 × 10–3
(1) – 1361.95 kJ mol–1 = –1366.9 kJ
(2) – 1460.50 kJ mol–1 Note:-Value of R given is wrong, standard

–1 value of R = 8.314 JK–1 mol–1
(3) – 1350.50 kJ mol
(4) – 1366.95 kJ mol–1

Q.19 The octahedral complex of a metal ion M3+ R–CH2–OH → R–CH=O

with four monodentate ligands L1, L2, L3 and
PCC(Pyridinum chloro chromate) is specific
L4 absorb wavelengths in the region of red,
oxidising reagent which oxidised only
green, yellow and blue, respectively. The
increasing order of ligand strength of the four alcohol to carbonyl substances.
ligands is:
(1) L1 < L3 < L2 < L4 (2) L3 < L2 < L4 < L1 Q.21 In which of the following reactions H2O2 acts
(3) L1 < L2 < L4 < L3 (4) L4 < L3 < L2 < L1 as a reducing agent ?
Ans. [1] (a) H2O2 + 2H+ + 2e– → 2H2O
Sol. CP Students may find similar concept in (b) H2O2 – 2e–→ O2 + 2H+
CP Theory Sheet & Similar question in CP
(c) H2O2 + 2e– → 2OH–
Exercise Sheet: [Chapter: Co-Ordination
Compounds, Level # 3, Page No. 108, Q. 8] (d) H2O2 + 2OH– – 2e– → O2 + 2H2O
V I B G Y O R (1) (c), (d) (2) (a), (c)
Violet Indigo Blue Green Yellow Orange Re d
             →
Order of increasing wavelength (3) (b), (d) (4) (a), (b)
1 Ans. [3]
∆(CFSE) ∝
λ( wavelength)
Sol. Loss of electron is oxidation. In (b) and (d)
[∆ or CFSE ∝ strength of ligands] reactions H2O2 loose electrons. Hence, it
behaves as reducing agent.
Hence, order of strength of ligand is :
(b) H2O2 – 2e–→ O2 + 2H+
L1 < L3 < L 2 < L 4
(Re d ) ( Yellow ) ( Green ) ( Blue )
or, H2O2 → O2 + 2H+ + 2e–
(d) H2O2 + 2OH– – 2e– → O2 + 2H2O

Q.20 The most suitable reagent for the conversion
or, H2O2 + 2OH– → O2 + 2H2O + 2e–
of R–CH2–OH→ R–CHO is-
(1) K2Cr2O7
Q.22 The correct statement for the molecule CsI3,
(2) CrO3
is-
(3) PCC (Pyridinium Chlorochromate)
(1) it contains Cs+ and I3− ions
(4) KMnO4
Ans. [3] (2) it contains Cs3+ and I– ions
Sol. CP Students may find similar Question in (3) it contains Cs+, I– and lattice I2 molecule
CP Exercise Sheet: [Chapter: Carbonyl (4) it is a covalent molecule
Compound, Level # 3, Page No. 79, Q. 2]

Ans. [1] Debye and Huckel equation for strong electrolyte
Sol. CP Students may find similar Question in CP λm = λm∞ – b C

∴ for NaCl that is strong electrolyte
Level # 4 (Section-B), Page No. 42, Q. 8]
In CsI3, cation is Cs+ and anion is I3– λC = λ∞ – B C
Q.23 The major organic compound formed by the Q.25 Resistance of 0.2M solution of an electrolyte
reaction of 1, 1, 1– trichloroethane with is 50Ω. The specific conductance of the
silver powder is: solution is 1.4 Sm–. The resistance of 0.5M
(1) Ethene (2) 2-Butyne solution of the same electrolyte is 280 Ω. The
molar conductivity of 0.5M solution of the
(3) 2-Butene (4) Acetylene
electrolyte in Sm2 mol–1 is:
Ans. [2]
(1) 5 × 10–3 (2) 5 × 103
Sol. CP Students may find similar Question in
(3) 5 × 102 (4) 5 × 10–4
CP Exercise Sheet: [Chapter: Hydrocarbon
(Alkyne), Ex-35, Page No. 82] Ans. [4]
Cl Sol. CP Students may find similar question in CP

CH3–C–Cl Ag ∆
CH3–C≡C–CH3 Exercise Sheet: [Chapter: Electrochemistry,
Cl 2-butyne
Ex. # 53, Page No. 22]
1,1,1-trichloro ethane
I-Case C = 0.2 M; R = 50Ω; kV = 1.4 s/m
1 1
KV = ×
R a
Q.24 The equivalent conductance of NaCl at
concentration C and at infinite dilution are l
= KV × R = 1.4 × 50 = 70 m–1
a
λC and λ∞, respectively. The correct
relationship between λΧ and λ∞ is given as: because cell is similar so cell constant (
l
) also
a
(where the constant B is positive)
remain constant
(1) λC = λ∞ – (B)C (2) λC = λ∞ – (B) C II-Case
(3) λC = λ∞ + (B) C (4) λC = λ∞ + (B)C l

= 70 m–1 ; R = 280 Ω ; C = 0.5 M
a
Ans. [2]
1000
Sol. CP Students may find similar question in CP λM = kV ×
C
Exercise Sheet: [Chapter: Electrochemistry,
Level # 2, Page No. 33, Q. 61] But when length is given in 'm'

So, COONa
λM = kV ×
10 −3
O–Na + CO2 125
º → OH
C 5 Atm
Kolbe reaction
l 1 10 −3 H⊕ Acidification
(Ar. SE reaction)
= × ×
a R C
COOH
1 10 −3
λM = 70 × × OH
280 0.5
1
= × 10–3 Acetylation Ac2O
2
= 5 × 10–4 s m2 mole–1 O
O–C–CH3
COOH
Q.26 Sodium phenoxide when heated with CO2
O-Acetoxy benzoic acid
under pressure at 125º yields a product which
on acetylation produces C. Q.27 The equation which is balanced and

represents the correct product(s) is -
H+
ONa + CO2 125
º → B → C (1) [CoCl(NH3)5]+ + 5H+ → Co2+ + 5NH4+ + Cl–
5 Atm Ac2O
(2) [Mg(H2O)6]2+ + (EDTA)4–

The major product C would be: excess
 NaOH→ [Mg(EDTA)]2+ + 6H2O

OH OH (3) CuSO4 + 4KCN → K2[Cu(CN)4] + K2SO4
(1) COCH3 (2) COCH3 (4) Li2O + 2KCl → 2LiCl + K2O
Ans. [1]
COCH3
Sol. [CoCl(NH3)5]+ + 5H+ → Co2+ + 5NH4+ + Cl–
OCOCH3 OCOCH3 Base Acid Salt
COOH Q.28 The correct set of four quantum numbers for

(3) (4)
COOH the valence electrons of rubidium atom
(Z = 37) is -
Ans. [4] 1 1
(1) 5, 1, 0 + (2) 5, 1, 1 +
Sol. CP Students may find similar question in CP 2 2
Exercise Sheet: [Chapter: Phenol, Level # 1, 1 1
(3) 5, 0, 1 + (4) 5, 0, 0 +
Page No. 126, Q. 39] 2 2

Ans. [4] r = k[A]x [B]y (Rate law expression)
Sol. CP Students may find this question in CP 1.2 × 10–3 = k[0.1]x[0.1]y ….(1)
Exercise Sheet: [Chapter: Atomic structure,
1.2 × 10–3 = k[0.1]x[0.2]y ….(2)
Level # 2, Page No. 44, Q. 46]
2.4 × 10–3 = k[0.2]x[0.1]y ….(3)
Z = 37
Dividing equation(1) by (2) we get y = 0
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 5s1
Dividing equation (1) by (3) we get x = 1
1
∴ n = 5 l = 0 m = 0 ms = +
2 ∴ rate law = k[A]
Q.29 For the non – stoichiometre reaction Q.30 In SN2 reactions, the correct order of
reactivity for the following compounds :
2A + B → C + D, the following kinetic data
were obtained in three separate experiments CH3Cl,CH3CH2Cl, (CH3)2CHCl and (CH3)3CCl is
all at 298 K. (1) CH3Cl > CH3CH2Cl > (CH3)2CHCl > (CH3)3CCl
Initial Initial Initial rate of (2) CH3CH2Cl > CH3Cl > (CH3)2CHCl > (CH3)3CCl
Concentration Concentration formation of C
(3) (CH3)2CHCl > CH3CH2Cl > CH3Cl > (CH3)3CCl
(A) (B) (mol L–S–)
(4) CH3Cl > (CH3)2CHCl > CH3CH2Cl > (CH3)3CCl
0.1 M 0.1 M 1.2 × 10–3
Ans. [1]
–3
0.1 M 0.2 M 1.2 × 10
0.2 M 0.1 M 2.4 × 10–3
Exercise Sheet: [Chapter: Haloalkane, Level
The rate law for the formation of C is - # 4, Page No. 157, Q. 5]
dc dc 1
(1) = k[A]2 [B] (2) = k[A] [B]2 Reactivity of SN2 ∝
dt dt Steric hindrance
dc dc So that
(3) = k[A] (4) = k[A] [B]
dt dt
CH3 – Cl > CH3– CH2 – Cl >
Ans. [3]
CH3—CHCl > (CH3)3CCl
2
Exercise Sheet: [Chapter: Chemical
Kinetics, Ex. # 12, Page No. 16]

Q.32 Let the population of rabbits surviving at a time

Part B – MATHEMATICS t be governed by the differential equation
dp( t ) 1
sin( π cos 2 x ) = p(t) – 200. If p(0) = 100, then p(t)
Q.31 lim is equal to dt 2
x →0 x2 equals :
π (1) 400 – 300 e–t/2 (2) 400 – 300 et/2

(1) π (2)
2 (3) 300 – 200 e–t/2 (4) 600 – 500 et/2
(3) 1 (4) –π Ans. [2]
Ans. [1] Sol. CP Students may find similar question in CP
Exercise Sheet: [Chapter : Differential
Equation, Level # 4(B); Page No. 128; Q.18]
Exercise Sheet: [Chapter : Limit, Level #
4(B), Page No. 71, Q. 12] d 1
(p(t)) = (p(t)) – 200
dt 2
sin( π cos 2 x ) sin( π(1 − sin 2 x ))
lim = lim
x →0 x2 x →0 x2 2 dp(t) = (p(t) – 400) dt
dp( t )
= lim
sin(π − π sin 2 x ) ⇒ 2 ∫ p(t ) − 400 = ∫ dt
x →0 x2
2 ln |p(t) – 400 | = t + c ...(1)
sin( π sin 2 x )
= lim at t = 0
x →0 x2
⇒ 2 ln | 100 – 400 | = c
sin( π sin 2 x ) π sin 2 x
= lim 2
× hence from equation (1)
x →0 π sin x x2
2 ln |p(t) – 400 | – 2 ln| – 300 | = t
=1×π×1=π
p( t ) − 400
⇒ t = 2 ln
− 300

p( t ) − 400 Ans. [1]

⇒ ln = et/2
− 300 q r
Sol. α+β=– ; αβ =
p p
400 − p( t )
⇒ = et/2
300 2q = p + r ...(1) (given)
⇒ 300 et/2 = 400 – p(t) α+β

= 4 (given)
αβ
⇒ p(t) = 400 – 300 et/2
−q
So, =4
r
Q.33 The statement ~ (p ↔ ~ q) is
⇒ 2(–4r) = p + r ⇒ p = –9r (from eq. (1))
(1) a fallacy
Since
(2) equivalent to p ↔ q
D q 2 − 4pr 16r 2 − 4pr
(3) equivalent to ~p ↔ q |α – β| = = =
|p| |p| |p|
(4) a tautology
52r 2 2 | r | 13 2 13
Ans. [2] = = =
|p| 9|r| 9
Exercise Sheet : [Chapter : Mathematical Q.35 Let PS be the median of the triangle with
Reasoning; Level # 1; Page No. 224; Q.46] vertices P(2, 2), Q(6, –1) and R(7, 3). The
equation of the line passing through (1, –1) and
p q ~q p ↔ ~ q ~ (p ↔ ~ q) p ↔q parallel to PS is
(1) 2x – 9y – 11 = 0 (2) 4x – 7y – 11 = 0
T T F F T T
(3) 2x + 9y + 7 = 0 (4) 4x + 7y + 3 = 0
T F T T F F
Ans. [3]
F T F T F F
F F T F T T Exercise Sheet : [Chapter : Straight line;
∴ ~ (p ↔ ~ q) = p ↔ q Level # 4(B); Q.4]
P(2, 2)
Q.34 Let α and β be the roots of equation
px2 + qx + r = 0, p ≠ 0. If p, q, r are in A.P. and
1 1
+ = 4, then the value of |α – β| is
α β
(6, –1)Q R(7, 3)
S
2 13 61
(1) (2)
9 9 Q S is the mid point of QR
2 17 34  7 + 6 − 1 + 3   13 
(3) (4) ∴ S ,  =  , 1
9 9  2 2  2 

M = slope of PS 1
1
( 2 − 1) 1 2
=
2
× π × 1+ 2 ∫
0
1 − x dx
= = =–
 13  (− 9 / 2) 9
2 − 
 2  =
π
2
2
[
– 2× (1 − x ) 3 / 2
3
] 1
0
= slope of the line parallel to PS

π 4
= – [0 – (1)]
∴ Equation of the line which is parallel to line 2 3
PS & passing through the point (1, –1) is
π 4
= +
2 2 3
⇒ y – (–1) = – (x – 1)
9
⇒ 9y + 9 = –2x + 2
⇒ 2x + 9y + 7 = 0 Q.37 If A is an 3 × 3 non-singular matrix such that

AA′ = A′A and B = A–1A′, then BB′ equals :
(1) (B–1)′ (2) I + B
Q.36 The area of the region described by (3) I (4) B–1

A = {(x, y) : x2 + y2 ≤ 1 and y2 ≤ 1 – x} is : Ans. [3]
π 2 π 4 Sol. |A| ≠ 0
(1) + (2) +
2 3 2 3
A.A′ = A′.A; (given)
π 4 π 2
(3) − (4) −
2 3 2 3 B = A–1.A′
Ans. [2] ⇒ B′ = ((A–1) . A′)′
Sol. ⇒ B′ = (A′)′ . (A–1)′
C ⇒ B′ = A . (A–1)′
1
⇒ B.B′ = (A–1.A′) A . (A–1)′
D O 1
= A–1.(A A′) (A–1)′
B
= I.A′(A–1)′
A –1
= A′ . (A–1)′
Area of ABCDA
= (A–1.A)′
= area of semi circle + 2 × area of OBCO
= I′ = I

x −1 y−3 z−4 Q.39 If x = –1 and x = 2 are extreme points of

Q.38 The image of the line = =
3 1 −5 f(x) = α log |x| + βx2 + x then :
in the plane 2x – y + z + 3 = 0 is the line :
1 1
(1) α = 2, β = (2) α = –6, β =
x −3 y+5 z−2 2 2
(1) = =
−3 −1 5
1 1
(3) α = –6, β = – (4) α = 2, β = –
x +3 y−5 z−2 2 2
(2) = =
3 1 −5
Ans. [4]
x +3 y−5 z+2
(3) = = Sol. CP Students may find this question in CP
−3 −1 5
Exercise Sheet : [Chapter : Maxima-Minima;
x −3 y+5 z−2 Level # 4(B); Page No. 205; Q. 11]
(4) = =
3 1 −5
f(x) = α ln|x| + βx2 + x
Ans. [2]
α
Sol. f ′(x) = + 2βx + 1
x
A(1,3,4)
given line at point of extreme f ′(x) = 0
so f ′(2) = 0 & f ′(–1) = 0
B(4,4,–1) α
⇒ + 4β + 1 = 0 & –α – 2β + 1 = 0
2
Image of line in ⇒ α + 8β + 2 = 0 & α + 2β – 1 = 0

B′ given plane ⇒ α + 8β = – 2 ...(1) & α + 2β = 1 ...(2)
A′
by solving equation (1) & (2)
x −1 y − 3 z − 4
Given line is = = =λ 1
3 1 −5 β=– and α = 2
2
by taking λ = 0 and 1 we will have the points
A(1, 3, 4) and B(4, 4, –1) on the line.
Q.40 If a ∈ R and the equation
Image of A in the plane mirror
2x – y + z + 3 = 0 is –3(x –[x])2 + 2(x – [x]) + a2 = 0 (where [x]
denotes the greatest integer ≤ x) has no integral
x −1 y − 3 z − 4 − 2(2 − 3 + 4 + 3)
= = = solution, then all possible values of a lie in the
2 −1 1 4 +1+1
interval :
hence image of A is A′ (–3, 5, 2)
(1) (– ∞, –2) ∪ (2, ∞)
similarly image of B is B′(0, 6, –3)
(2) (–1, 0) ∪ (0, 1)
So the line joining A′, B′ is
(3) (1, 2)
x +3 y−5 z−2
= =
3 1 −5 (4) (–2, –1)

Ans. [2] r2 = y = ?
Sol. –3(x – [x])2 + 2(x – [x]) + a2 = 0 Q Both circles touches each other, externally
2
⇒ 3{x} – 2{x} – a = 0 2 then
C1C2 = (r1 + r2)

let {x} = t ∀ t ∈ (0, 1)
since x cannot be integer. ⇒ (1 − 0) 2 + (1 − y) 2 = y + 1
Let f(t) = 3t2 – 2t – a2 ⇒ 1 + 1 + y2 – 2y = y2 + 1 + 2y

since equation has at least one solution in ⇒ 4y = 1
(0, 1)
1
So, f(0) f(1) < 0 ⇒y= = r2
4
–a2(1 – a2) < 0
a2(a2 – 1) < 0
Q.42 If the coefficients of x3 and x4 in the expansion
⇒ –1 < a < 1 and a ≠ 0 of (1 + ax + bx2) (1 – 2x)18 in powers of x are
both zero, then (a, b) is equal to :
⇒ a ∈ (–1, 0) ∪ (0, 1)
 272   251 
(1) 16,  (2) 16, 
 3   3 
Q.41 Let C be the circle with centre at (1, 1) and
radius = 1. If T is the circle centred at (0, y),  251   272 
(3) 14,  (4) 14, 
passing through origin and touching the circle  3   3 
C externally, then the radius of T is equal to
Ans. [1]
1 3 3 1 Sol. (1 + ax + bx2) (1 – 2x)18
(1) (2) (3) (4)
4 2 2 2
coefficient of x3
Ans. [1]
= –18C3 (2)3 + a. 18C2(2)2 – b . 18
C1 (2) = 0
Sol.
18 18
C3 C1
y ⇒– 18
.8 + 4a – b. 18
(2) = 0
C2 C2
 16  2
⇒ –   .4 + 2a – b . =0
 3 17
C1(1, 1)
⇒ 51a – 3b = 544 ...(1)
r1=1
C2 coefficient of x4
x
O(0,0) = 18C4(2)4 – 18C3(2)3. a + 18C2 (2)2b = 0
18 18
C4 C2
C2(0, y) ⇒ 18
.(2)2 – (2)a + 18
.b=0
C3 C3

3
⇒ 15 – 2a + b=0
16 1
 1  x+
⇒ 32a – 3b = 240 ...(2)
Q.44 The integral ∫ 1 + x − e x dx is equal to
 x
from equation (1) & (2) 1 1
x+ x+
(1) –x e x +c (2) (x – 1) e x +c
a = 16
1 1
x+ x+
272 (3) x e x +c (4) (x + 1) e x +c
b=
3
Ans. [3]
1
If z is a complex number such that |z| ≥ 2, then
x+  1
Q.43 Sol. ∫ e x
1 + x −  dx
 x
1
the minimum value of z + :
2 1 1
x+  1  x+
3 5
= ∫ e x
 x ∫
dx +  x −  e x dx
(1) is strictly greater than but less than
2 2 1 1
x+  1  x+
5
= ∫ e
I
x .1 dx +  x −  e x dx
II  x ∫
(2) is equal to
2
1 1 1
x+ x+  1   1  x+
(3) lies in the interval (1, 2) = xe x − e ∫ x . x 1 − 2  dx +
 x  ∫  x −  e x dx + c
 x
5 1 1 1
(4) is strictly greater than x+ x+  1 x+  1
2 = xe x − e ∫ x
 x −  dx +
 x ∫ e x
 x −  dx + c
 x
Ans. [3]
1
x+
Sol. |z| ≥ 2 = xe x +c
It represents exterior of a circle having radius 2

and centre (0, 0)
Q.45 The slope of the line touching both the
1  1 parabolas y2 = 4x and x2 = – 32y is
z+ = z −  −  = minimum distance
2 min  2  min 2 1
(1) (2)
1 3 3 2
between z and – = AB =
2 2 3 1
(3) (4)
lies between (1, 2) 2 8
Ans. [2]

A B
–2 O Exercise Sheet : [Chapter : Parabola; Level
−
1 2
2 # 1; Page No. 101; Q. 61]
Equation of tangent to the parabola y2 = 4x is

1 Ans. [1]
y = mx + .... (i)
m Sol. f4(x) – f6(x)
1 1
Equation of tangent to the parabola = (sin4x + cos4x) – (sin6x + cos6x)
4 6
x2 = – 32y is 1
= [(sin2x + cos2x)2 – 2sin2x cos2x]
4
y = mx + 8m2 ...(ii) 1
– [(sin2x + cos2x)3 – 3sin2x cos2x
6
Comparing (i) & (ii)
(sin2x + cos2x)]
1 1 1 1 1
8m2 = ⇒ m3 = ⇒m= = [1 – 2sin2x cos2x] – [1– 3sin2x cos2x]
m 8 2 4 6
1 1 1
= – =
4 6 12
1
Q.46 Let fk(x) = (sink x + cosk x) where x ∈ R and
k
k ≥ 1. Then f4(x) – f6(x) equals : Q.47 A bird is sitting on the top of a vertical pole 20
m high and its elevation from a point O on the
ground is 45º. It flies off horizontally straight
1 1 away from the point O. After one second, the
(1) (2)
12 6 elevation of the bird from O is reduced to 30º.
Then the speed (in m/s) of the bird is :
1 1
(3) (4)
3 4 (1) 20( 3 – 1) (2) 40( 2 – 1)
(3) 40( 3 – 2 ) (4) 20 2

Ans. [1] → → → → → →
⇒ [ p q r ] = p .( q × r )
Sol.
→ → → →
A = p .{ q ×( c × a )}
x P
→ → → → → → →
= p .{ c ( q . a ) – a ( q . c )}
20 2 20
20 → → → → → → → →
= ( p . c )( q . a ) – ( p . a ) ( q . c )
45º 30º
O Q → → → → → →
B x = {( a × b ). c }{( b × c ). a }
20
→ → → → → →
20 – {( a × b ). a }{( b × c ). c }
tan 30º =
20 + x
→→→  → → → 
1 20 = [ a b c ]2 ⇒ λ = 1 as  a b a  = 0
=    
3 20 + x
x = 20( 3 – 1)
Q.49 Let A and B be two events such that P( A ∪ B )
x 1 1 1
Velocity = m/sec = 20( 3 – 1) m/sec = , P(A∩B) = and P( A ) = , where A
1 6 4 4
stands for the complement of the event A. Then
2
the events A and B are :
→ → → → → →  → → → 
Q.48 If  a × b b × c c × a  = λ  a b c  then λ is (1) independent and equally likely
   
equal to : (2) mutually exclusive and independent
(1) 1 (2) 2 (3) equally likely but not independent
(3) 3 (4) 0 (4) independent but not equally likely
Ans. [1] Ans. [4]
Sol. CP Students may find Question based on Sol. From given information
similar concept in Class Notes : [Chapter :
Vector] 5
P(A∪B) =
6
→ → → → → → 
 a × b b× c c × a  1
  P(A∩B) =
4
→ → →
Let a ×b =p 3
P(A) =
4
→ → →
b×c =q
Since
→ → →
c ×a =r P(A∪B) = P(A) + P(B) – P(A∩B)

5 3 1 y
= + P(B) –
6 4 4 (h,k)
BM
5 1 3 10 + 3 − 9 4 1 P
P(B) = + – = = =
6 4 4 12 12 3 A
x
C
1 (0, 0)
P(A∩B) = Tangent at point P
4
3 1 1 k
P(A).P(B) = . = Q m1 = slope of line CM =
4 3 4 h
⇒ P(A∩B) = P(A) × P(B) −1 − h

m2 = slope of line PM = =
m1 k
P(A) ≠ P(B)
Equation of line PM is
∴ Independent but not equally likely.
−h
y–k= (x – h)
k
2
−h h
Q.50 The locus of the foot of perpendicular drawn y = x + +k …(2)
 k  k
from the centre of the ellipse x2 + 3y2 = 6 on
any tangent to it is : Now, line (2) touches the ellipse (1),
(1) (x2 + y2)2 = 6x2 – 2y2 then c2 = a2 m 22 + b2

(2) (x2 – y2)2 = 6x2 + 2y2 2 2
 h2 + k2 
  = 6  − h  + 2
(3) (x2 – y2)2 = 6x2 – 2y2  k   k 
 
(4) (x2 + y2)2 = 6x2 + 2y2
Q a2 = 6, b2 = 2
Ans. [4]
∴ Locus of point M is
Sol. CP Students may find Question based on
similar concept in Class Notes : [Chapter : (x2 + y2)2 = 6x2 + 2y2
Ellipse]
x 2 y2
+ =1 …(1)
6 2
Q.51 If f and g are differentiable functions in
Point M is the foot of the perpendicular which [0, 1] satisfying f(0) = 2 = g(1), g(0) = 0 and
is drawn from the centre of the ellipse on any f(1) = 6, then for some c∈]0, 1[ :
tangent.
(1) f ′(c) = 2g′(c) (2) 2f ′(c) = g′(c)
(3) 2f ′(c) = 3g′(c) (4) f ′(c) = g′(c)
Ans. [1]

Sol. CP Students may find this question in CP Ans. [1]

Exercise Sheet: [Chapter : Tangent &
Sol. Let the three numbers are
normal, Level # 2, Page No. 157, Q. 19]
a, ar, ar2 are in G.P. where a > 0 and r > 1
Let f ′(x) = k g′(x) …(1)
(Q no.'s are positive and in increasing G.P.)
Integrate it f(x) = k g(x) + c …(2)
Now a, 2ar, ar2 are in A.P. (given)
at x = 0, f(0) = 2 and g(0) = 0
So 4ar = a + ar2
from (2) f(0) = k g(0) + c
⇒ r2 – 4r + 1 = 0
2=0+c ⇒ c=2
from (2) f(x) = k g(x) + 2 4 ± 12
⇒ r=
2
at x = 1, f(1) = k g(1) + 2
6 = k. 2 + 2 ⇒ 2k = 4 ⇒ r=2± 3
k=2 Since r > 1
Now from equation (1), f ′(x) = 2 g′(x) So r=2+ 3

Correct answer is (1)
Note : This question can be solved by the Q.53 If g is the inverse of a function f and
application of LMVT.
1
f ′(x) = , then g′(x) is equal to :
Consider the function 1 + x5
φ(x) = f(x) – 2g(x), for x ∈ [0, 1] (1) 1 + {g(x)}5 (2) 1 + x5
since f and g are differentiable functions in 1
[0, 1], hence φ(x) is also differentiable. (3) 5x4 (4)
1 + {g ( x )}5
According to LMVT
Ans. [1]
φ(1) − φ(0)
φ′(c) = Sol. CP Students may find this question in CP
1− 0
Exercise Sheet: [Chapter : Differentiation,
(f (1) − 2g (1)) − (f (0) − 2g(0)) Level # 2, Page No. 128, Q. 1]
f ′(c) – 2g′(c) =
1− 0 g(x) = f –1(x)
(6 − 2 × 2) − (2 − 0) f{g(x)} = x
f ′(c) – 2g′(c) =
1− 0
f ′{g(x)} g′(x) = 1
f ′(c) – 2g′(c) = 0
1
g′(x) =
f ′(c) = 2g′(c) f '{g( x )}
Q.52 Three positive numbers form an increasing 1

as f ′(x) =
G.P. If the middle term in this G.P. is doubled, 1 + x5
the new numbers are in A.P. Then the common
ratio of the G.P. is : So g ′(x) = 1 + {g(x)}5
(1) 2 + 3 (2) 2+ 3
(3) 3 + 2 (4) 2 – 3

Q.54 Let a, b, c and d be non-zero numbers. 1 1 1 1 1 1

If the point of intersection of the lines 1 α β . 1 α α2
4ax + 2ay + c = 0 and 5bx + 2by + d = 0 lies in
1 α2 β2 1 β β2
the fourth quadrant and is equidistant from the
two axes then : = K(1 – α)2 (1 – β)2 (α – β)2
(1) 3bc + 2ad = 0 (2) 2bc – 3ad = 0 2
0 0 1
(3) 2bc + 3ad = 0 (4) 3bc – 2ad = 0 1− α α −β β
Ans. [4] 1 − α2 α 2 − β2 β2
Sol. 4ax + 2ay + c = 0 = K(1 – α)2 (1 – β)2 (α – β)2
5bx + 2by + d = 0 2
2 2 1 1
(1 – α) (α – β)
Point of intersection of these lines is 1+ α α + β
 2(ad − bc) 5bc − 4ad)  = K(1 – α)2 (1 – β)2 (α – β)2
(x, y) ≡  , 
 − 2ab − 2ab 
(β – 1)2 = K(1 – β)2 ⇒K=1
th
Since point lies in 4 quadrant and also
equidistant from both the axes. So
Q.56 The integral
x=–y
π
ad − bc 5bc − 4ad x x
− ab
=
2ab
∫
0
1 + 4 sin 2
2
− 4 sin dx equals :
2
⇒ 2ad – 2bc = – 5bc + 4ad π

(1) 4 3 – 4 – (2) π – 4
⇒ 3bc – 2ad = 0 3
Q.55 If α, β ≠ 0, and f(n) = αn + βn and 2π

(3) –4–4 3 (4) 4 3 – 4
3
3 1 + f (1) 1 + f (2)
1 + f (1) 1 + f (2) 1 + f (3) Ans. [1]
1 + f (2) 1 + f (3) 1 + f (4) π
x x
2 2 2
= K(1 – α) (1 – β) (α – β) , then K is equal to
Sol. I= ∫
0
1 + 4 sin 2
2
− 4 sin dx
2
-
π 2 π
 x  x
(1) – 1 (2) αβ = ∫
0
 2 sin − 1 dx =
 2  ∫ 2 sin 2 − 1 dx
0
1
(3) (4) 1
αβ x
Let =t
2
Ans. [4]
∴ dx = 2dt
Sol. f(n) = αn + βn
π/ 2
3 1 + α + β 1 + α 2 + β2 So I=2 ∫ 2 sin t − 1 dt
1+ α + β 1 + α 2 + β 2 1 + α 3 + β3 0
2 2 3 3 4 4
1+ α + β 1+ α + β 1+ α + β
= K(1 – α)2 (1 – β)2 (α – β)2

π/ 6 π/ 2 
 0 ∫ π/6
∫
= 2  (1 − 2 sin t )dt + (2 sin t − 1)dt 
 Q.58 The angle between the lines whose direction
cosines satisfy the equations l + m + n = 0 and
[
= 2 ( t + 2 cos t ) 0π / 6 + (−2 cos t − t ) ππ // 62 ] l2 = m2 + n2 is -
π π π π π π π
= 2 + 3 −0−2+0− + 3 + (1) (2) (3) (4)
 6 2 6  2 3 4 6
Ans. [2]
 π
= 2 2 3 − 2 −  Sol. Given
 6
π l+m+n=0 …(1)
=4 3–4–
3 l2 = m2 + n2 …(2)
Using (1) in (2), we get
9 1 8 2 7
Q.57 If (10) + 2(11) (10) + 3(11) (10) + … (m + n)2 = m2 + n2
… + 10 (11)9 = k(10)9, then k is equal to :
2mn = 0
121
(1) 110 (2) ⇒ mn = 0
10
If m = 0, l+n=0 ⇒l=–n
441
(3) (4) 100
100 DRs be < 1, 0, –1>
Ans. [4] Again if n = 0, l + m = 0 ⇒ l = – m

s
Sol. S = 109 + 2(11)(10)8 + 3.(11)2(10)7 + DR be <1, –1, 0>
9
….. + 10(11) 1
Required angle, cos θ =
11 2
S= (11)(10)8 + 2(11)2(10)7 +
10 π
θ=
….. + 9(11)9 + (11)10 3
–
Q.59 The variance of first 50 even natural numbers is:
–
S
10
[
= 10 9 + (11)(10)8 + (11) 2 (10) 7 + ... + (11) 9 – (11)10 ] 437 833
(1) (2)
G.P. (10 terms) 4 4
(3) 833 (4) 437
  11 10 
9
10 1 −    Ans. [3]
S   10  
– = – (11)10 Sol. CP Students may find similar question in CP
10 11
1− Exercise Sheet: [Chapter : Measurement of
10
Central tendency, Level # 4, Page No. 155,
S Q. 12]
– = [– (10)10 + (11)10] – (11)10
10
2 + 4 + 6 + ..... + 100 2 × 50 × 51
x= = = 51
S = 1011 = k . 109 50 2 × 50
⇒ k = 100

www.ecareerpoint.com Email: info@cpil.in 23/ 40
1 X = {(1 + 3n + nC2 (3)2 + nC3 (3)3 + …..)

σ2 =
n ∑x 2
i − (x) 2
– 3n – 1 : n ∈ N}
1 2 X = {9.k : k is some natural no.}
σ2 = (2 + 42 + 62 + ….. + 1002) – (51)2
50
X is set of multiple of 9 (but not all)
1
σ2 = × 4(12 + 22 + ….. + 502) – (51)2 Y = {9(n – 1) : n ∈ N}
50
Y = {0, 9, 18, …..}
1 50 × 51 × 101
σ2 = ×4× – (51)2 Y is set of whole no. multiple of 9
50 6
σ2 = 17 × 202 – 2601 ⇒ X∪Y = Y (Q X is subset of Y)
= 833
Q.60 If X = {4n – 3n – 1 : n ∈ N} and

Y = {9(n – 1) : n ∈ N}, where N is the set of
natural numbers, then X∪Y is equal to :
(1) Y (2) N
(3) Y – X (4) X
Ans. [1]
Sol. X = {4n – 3n – 1 : n ∈ N}
X = {(1 + 3)n – 3n – 1 : n ∈ N}

Q.62 In the circuit shown here, the point C is kept

Part C - PHYSICS connected to point a till the current flowing
through the circuit becomes constant.
Q.61 The pressure that has to be applied to the ends
Afterward, suddenly, point C is disconnected
of a steel wire of length 10 cm to keep its
from point A and connected to point B at time
length constant when its temperature is raised t = 0. Ratio of the voltage across resistance and
by 100ºC is : (For steel Youngs's modules is the inductor at t = L/R will be equal to -
2 × 1011 Nm–2 and coefficient of thermal R
A C
expansion is 1.1 × 10–5 K–1)
(1) 2.2 × 109 Pa B L
(2) 2.2 × 107 Pa

1− e e
(3) 2.2 × 106 Pa (1) 1 (2) –1 (3) (4)
e 1− e
(4) 2.2 × 108 Pa
Ans. [2]
Ans. [4]
Sol. CP students may be find this question in CP
Sol. CP students may be find similar question in Exercise Sheet: [Chapter : E.M.I. similar to
CP Exercise Sheet: [Chapter : Elasticity, Q.71, Level # 1, Page No. 116]
Level # 4, Page No. 110, Q.5]
VL + VR = 0 (By Kirchoff's law)
Given l = 10 cm
VL = – VR
∆T = 100ºC
VR
= −1
Y = 2 × 1011 N/m2 VL
α = 1.1 × 10–5 K–1

Q.63 The radiation corresponding to 3 → 2 transition
So stress developed in steel wire is thermal stress
of hydrogen atom falls on a metal surface to
= Yα∆T produce photoelectrons. These electrons are
made to enter a magnetic field of 3 × 10–4 T. If
= 2 × 1011 × 1.1 × 10–5 × 100
the radius of the largest circular path followed
= 2.2 × 1013 × 10–5 = 2.2 × 108 N/m2 by these electrons is 10.0 mm, the work
function of he metal is close to -
Since pressure developed in wire is equal to
(1) 1.1 eV (2) 0.8 eV
thermal stress developed
(3) 1.6 eV (4) 1.8 eV
Pressure applied = 2.2 × 108 N/m2

Ans. [1]
Sol. Ephoton = E3 – E2 = – 1.51 – (–3.4)
= 1.89 eV ≈ 1.9 eV
d2
2mKE α
Using r =
qB
For max radius KE is KEmax

d1
2mKE max 1 + cos α 1 + tan α

∴ rmax = (1) (2)
qB 1 − cos α 1 − tan α
(qBrmax ) 2 1 + sin α 1 + sin α

KEmax = (3) (4)
2m 1 − cos α 1 − sin α
Ans. [2]
(1.6 ×10−19 × 3 × 10−4 × 10 ×10 −3 ) 2
KEmax = J Sol.
2 × 9.1× 10−31
(1.6 × 10−19 ) × (30 × 10−7 ) 2

KEmax = eV
2 × 9.1× 1031
1.6 × 10−19 × 900 × 10 −14 90º

KEmax = eV d2
2 × 9.1× 10−31 (90 – α) α R
KEmax = 0.8 eV
Ephoton = KEmax + φ
d1 A
1.9 = 0.8 + φ
Pressure at A point from both side will be
φ = 1.1 eV equal.
(R – R sin α) d1g = (R – R cos α) d1g
Q.64 There is a circular tube in a vertical plane. Two + (R sin α) d2g + R cos α d2g
liquids which do not mix and of densities d1
(cos α – sin α) d1 = (sinα + cos α) d2
and d2 are filled in the tube. Each liquid
subtends 90º angle at centre. Radius joining d1 sin α + cos α
=
their interface makes an angel α with vertical. d 2 cos α − sin α
d1 1 + tan α
Ratio is - =
d2 1 − tan α

r r
Q.65 A bob of mass m attached to an inextensible Since | r | and | v | and angle between them are
string of length l is suspended from a vertical r
support. The bob rotates in a horizontal circle constant therefore, magnitude of L will
with an angular speed ω rad/s about the constant.
vertical. About the point of suspension - r r
Q Direction of r × v is changing hence
(1) angular momentum changes in magnitude r
but not in direction direction of L will change.
(2) angular momentum changes in direction
but not in magnitude
(3) angular momentum changes in both Q.66 A thin convex lens made from crown glass
direction and magnitude  3
 µ =  has focal length f. When it is
(4) angular momentum is conserved  2
Ans. [2] measured in two different liquids having
Sol. CP students may be find this question in CP

4 5
refractive indices and , it has the focal
3 3
Exercise Sheet: [Chapter : Rotation,
lengths f1 and f2 respectively. The correct
IIT-2012, Page No. 243, Q.31]
relation between the focal lengths is -
(1) f1 > f and f2 becomes negative

r r (2) f2 > f and f1 becomes negative
r r
L ω L
(3) f1 and f2 becomes negative
r
⊗v (4) f1 = f2 < f
r r r
L = r ×p Ans. [1]
1  1 1 
Sol. = (µ – 1)  −  lens formula
f  R1 R 2 

Case (i) (2) The spectrum of visible light whose

frequency is more than that of green light
3
  will come out to the air medium
2
µrel =  
1 R1 R2 (3) The entire spectrum of visible light will
come out of the water at various angles to
the normal
1  3  1 1   1  1 1  (4) The entire spectrum of visible light will

=  − 1 −  =   − 
f  2  R 1 R 2   2  R 1 R 2  come out of the water at an angle of 90º to
the normal
Case (ii)
Ans. [1] For English medium
3 [2] For Hindi medium
 
2 9
µrel =   =
4 8 Sol. CP students may be find similar question in
 
3 CP Exercise Sheet: [Chapter : Refraction at
plane surface & Prism, Level # 4, Page No.
1 9   1 1  1  1 1  Q.13]
=  − 1  −  =    − 
f1  8  R
 1 R 2  8 R
 1 R 2  According to snell's law
Case (iii) 1
sin θC =
µ
3
 
2 9 B
µrel =   = Qµ= A+ +… (Cauchy equation)
 5  10 λ2
 
3
⇒ λ ↓ µ ↑ θC ↓ f ↑
1 9  1 1   − 1  1 1  ⇒ So freq. is greater, critical angle will be

=  − 1 −  =   − 
f 2  10  R1 R 2   10  R1 R 2  lesser.
⇒ f2 = negative Note : fgUnh ek/;e esa Nis gq, iz'u dk gy fuEu

izdkj gksxkA
and f1 > f
pwafd rjaxnS/;Z] vkofrZ ds O;qRØekuqikrh gksrh gS
rFkk ;gk¡ gjs izdk'k ls de vkofrZ dk izdk'k
Q.67 A green light is incident from the water to the ek/;e ls ckgj fudy jgk gS tks ;g iznf'kZr
air- water interface at the critical angle (θ). djrk gS fd gjs izdk'k ls vf/kd rjaxnS/;Z dk
Select the correct statement - izdk'k ikuh ls ok;q ds ek/;e esa ckgj fudysxkA
(1) The spectrum of visible light whose mÙkj [2]
frequency is less than that of green light
will come out to the air medium

Q.68 A block of mass m is placed on a surface with a So, from equation (1)
3
x 1
vertical cross section given by y = . If the y= m
6 6
coefficient of friction is 0.5, then maximum
height above the ground at which the block can
be placed without slipping is - Q.69 The coercivity of a small magnet where the
ferromagnet gets demagnetized is 3 × 103 Am–1.
2 1 1 1
(1) m (2) m (3) m (4) m The current required to be passed in a solenoid
3 3 2 6
of length 10 cm and number of turns 100, so
Ans. [4] that the magnet gets demagnetized when inside
Sol. CP students may be find similar question in the solenoid, is -
CP Exercise Sheet: [Chapter : Laws of (1) 60 mA (2) 3 A (3) 6 A (4) 30 mA
Motion, Similar Ex.20 Page No. 116] Ans. [2]
f Sol. H = 3 × 103 A/m
N
θ B µ 0 ni
H= =
µ0 µ0
mg cos θ mg sin θ
N
mg H = ni = i
l
N = mg cos θ Hl 3 × 103 × 10 × 10 −2
i= = = 3A
N 100
fmax = µ Mg cos θ
for limiting equilibrium,

Q.70 A conductor lies along the z-axis at –1.5 ≤ z < 1.5 m
µmgcosθ = mgsinθ and carries a fixed current of 10.0 A in
–az direction (see figure). For a field
µ = tanθ r
B = 3.0 × 10–4 e–0.2x â y T, find the power
x3 required to move the conductor at constant
as y = (given) …(1)
6 speed to x = 2.0 m, y = 0 m in 5 × 10–3s.
Assume parallel motion along the x-axis -
dy 1
= (3x 2 )
dx 6 z
1.5
I
x2
tan θ =
2 y
B
µ = tanθ 2.0 –1.5
x2 x
0.5 =
2 (1) 2.97 W (2) 14.85 W
(3) 29.7 W (4) 1.57 W
x=±1

Ans. [1] W 14.83 ×10−3

r r r P= =−
t 5 ×10−3
Sol. F = i ( l × B)
≈ 2.97 W
= 10 [3 (− k̂ ) × 3 × 10–4 e– 0.2 x ĵ ]
= 10 × 3 × 3 × 10–4 e– 0.2 x î
= 9 × 10–3 e– 0.2 x î Q.71 Two beams, A and B, of plane polarized light

By work-energy theorem with mutually perpendicular planes of
polarization are seen through a Polaroid. From
WB + Wext = ∆K = 0 the position when the beam A and has
∴ Wext = – WB maximum intensity (and beam B has zero
intensity), a rotation of polaroid through 30º
x =2
makes the two beams appear equally bright. If
=– ∫ F.dx
x =0 the initial intensities of the two beams are IA
IA
x =2 and IB respectively, then equals -
∫e IB
–3 −0.2 x
= – 9 × 10 dx
x =0
3
−3 (1) (2) 1
− 9 ×10 2
= [e −0.2 x ]02
− 0.2
1
–3 –0.2 × 2 – 0.2 × 0 (3) (4) 3
= 45 × 10 [e –e ] 3
= 45 × 10–3 [e – 0.4 – 1]
= 45 × 10–3 (0.67 – 1) [e – 0.4 = 0.67]
= – 14.83 × 10–3

Ans. [3]
r
Q.73 Assume that an electric field E = 30 x 2 î exists
in space. Then the potential difference
Sol. Plane of polarization of A is along the
VA – VO, where VO is the potential at the
transmission axis of Polaroid. original and VA the potential at x = 2 m is -
Polaroid is rotated through angle 30º so. (1) –120 J (2) – 80 J
Intensity of A and B after passing through the (3) 80 J (4) 120 J
Polaroid is IA cos2 30º and IB cos2 60º Ans. [2]

Sol. CP students may be find similar question in
Which is equal IA cos2 30º = IB cos2 60º
CP Exercise Sheet: [Chapter : Electrostatic,
Level # 3, Page No. 41, Q.28]
 I A  cos 2 60º
  = 2 rA
 I B  cos 30º r r
VA – V0 = – ∫
r0
E.d r
 IA  1
  =
 IB  3 r =2 2
 x3 
∫
2
= − 30 x dx = – 30  
x =0  3 0
= – 10[23 – 03] = – 80 V
Q.72 The forward biased diode connection is -
[Note : Unit of potential is given wrong in this
–3V –3V question. Its unit should be volt not the joule.]
(1)
4V
(2) 2V Q.74 Match List-I (Electromagnetic wave type) with
List-II (Its association/application) and select
+2V the correct option from the choices given below
(3) –2V
the list:
–2V List-I List-II

(4) +2V
(a) Infrared waves (i) To treat muscular
Ans. [4] strain
Sol. CP students may be find this question in CP (b) Radio waves (ii) For broadcasting
Exercise Sheet: [Chapter : Semi conductor (c) X-rays (iii) To detect fracture
and devices, Level # 2, Page No. 153 Q.19] of bones
Forward bias. (d) Ultraviolet rays (iv) Absorbed by the

ozone layer of the
+2V –2V
atmosphere

(a) (b) (c) (d)  1000 

dI = (I + 1)   (dV)
(1) (i) (ii) (iv) (iii)  T 
(2) (iii) (ii) (i) (iv)  1000 

dI = (5 + 1)   × (0.01)
 300 
(3) (i) (ii) (iii) (iv)
10
(4) (iv) (iii) (ii) (i) dI = 6 × × 0.01 = 0.2 mA
3
Ans. [3]
Sol. a → (i)
b → (ii)
Q.76 One mole of diatomic ideal gas undergoes a
c → (iii) cyclic process ABC as shown in figure. The
process BC is adiabatic. The temperatures at A,
d → (iv)
B and C are 400 K, 800 K and 600 K
respectively. Choose the correct statement -
B
Q.75 The current voltage relation of diode is given 800 K
by I = (e1000V/T – 1) mA, where the applied
P
voltage V is in volts and the temperature T is in
600 K
degree Kelvin. If a student makes an error
A C
measuring ± 0.01 V while measuring the 400 K
current of 5 mA at 300 K, what will be the V
error in the value of current in mA ?
(1) The change in internal energy in the
(1) 0.02 mA (2) 0.5 mA process CA is 700 R
(3) 0.05 mA (4) 0.2 mA (2) The change in internal energy in the
process AB is – 350 R
Ans. [4]
(3) The change in internal energy in the
Sol. I = [e1000V/T – 1] mA
process BC is – 500 R
differentiating on both sides
(4) The change in internal energy in whole
1000  cyclic process is 250 R
dI = [e1000V/T ]   dV
 T 

Ans. [3] Sol. CP students may be find this question in CP
Sol. CP students may be find this question in CP Exercise Sheet: [Chapter : Waves (Sound)
Exercise Sheet: [Chapter : Heat and similar Question in Theory portion,
Thermodynamics, similar Question at Page No. 39]
Solved Example-7, Page No. 124]
B l = 85 cm
800 K
600 K Velocity of sound = 340 m/s

A C
400 K ( 2n + 1) v
f=
V 4l
n = 0, 1, ……….
n=1
4f × l 4 × 1250 × 0.85
5 2n + 1 = = = 12.5
CV = R v 340 × 100
2
2n = 11.5
7
CP = R
2 11.5
n= = 5.7
2
BC – Adiabatic
Hence maximum value of n = 5
5
∆UCA = nCV∆T = R × (–200) = –500R
2 hence total no. of oscillation = 6
5
∆UBC = nCV∆T = 1 × R (600 – 800) Q.78 In a large building, there are 15 bulbs of 40 W,
2
5 bulbs of 100 W, 5 fans of 80 W and 1 heater
∆UBC = – 500R of 1 kW. The voltage of the electric mains is
220 V. The minimum capacity of the main fuse
of the building will be -
(1) 10 A (2) 12 A (3) 14 A (4) 8 A

Q.77 A pipe length 85 cm is closed from one end.
Ans. [2]
Find the number of possible natural oscillations
of air column in the pipe whose frequencies lie Sol. CP Students may be find similar question in
below 1250 Hz. The velocity of sound in air is CP Exercise Sheet: [Chapter : Current
340 m/s - Elasticity, Similar to Q.32, Level-2, Page No.
139]
(1) 8 (2) 6 (3) 4 (4) 12
Ans. [2] P
Using i =
V

Total current passing through mains Sol. CP Students may be find this question in CP
Exercise Sheet: [Chapter : Gravitation,
40 100 80 1000 Page No. 17, Ex.3]
i= ×15 + ×5+ ×5 + ×1
220 220 220 220
v
600 + 500 + 400 + 1000 F
= M M
220 F1
v F v
2500
= R
220
M M
= 11.36 A
v
∴ min current capacity of fuse = 12 A
Resultant force on any one
GM 2 GM 2
FR = 2 F + F1 = 2 × +
Q.79 Four particles, each of mass M and equidistant ( 2R ) 2 ( 2R ) 2
from each other, move along a circle of radius
GM 2 GM 2
R under the action of their mutual gravitational FR = +
2R 2 4R 2
attraction. The speed of each particle is -
If they are moving is circle then
GM GM Mv 2 GM 2  1 1
(1) 2 2 (2) (1 + 2 2 =  + 
R R R R2  2 4
1 GM GM GM  1 1 1 GM
(3) (1 + 2 2 ) (4) v=  +  = ( 2 2 + 1)
2 R R R  2 4 2 R
Ans. [3]

Q.80 From a tower of height H, a particle is thrown

u + u 2 + 2gH u
vertically upwards with a speed u. The time =n
g g
taken by the particle, to hit the ground, is n
times that taken by it to reach the highest point u2 + 2gH = (n – 1)2u2
of its path. The relation between H, u and n is -
or 2gH = nu2(n – 2)
(1) gH = (n – 2)2u2 (2) 2 gH = nu2(n – 2)
(3) gH = (n – 2)u2 (4) 2 gH = n2u2

Q.81 A student measured the length of a rod and
Ans. [2] wrote its as 3.50 cm. Which instrument did he
use to measure it ?
Sol. CP students may be find similar question
based on Concept in CP Class notes : (1) A vernier calliper where the 10 divisions in
vernier scale matches with 9 division in
[Chapter : Kinematics]
main scale and main scale has 10 divisions
in 1 cm
(2) A screw gauge having 100 divisions in the

circular scale and pitch as 1 mm
t1 • v=0 (3) A screw gauge having 50 divisions in the
u + circular scale and pitch as 1 mm
(4) A meter scale

–
t2
Ans. [1]
H Sol. CP Students may be find similar question in
CP Exercise Sheet: [Chapter : Practical Phy,
Easy, As per Theory, Page No. 7]
Let time taken upto maximum height and when Vernier caliper
it hit ground is t2 10 divisions is vernier scale
u = 9 divisions in main scale
So t1 = …(i)
g
⇒ 10 V = 9 S
1 2
by using S = ut + at 9
2 ⇒V= S
10
1 2
– H = ut2 – gt 2 1
2 ⇒ Least count = S – V =   (S)
 10 
u + (u 2 + 2gH)
t2 = 1
g ⇒ Least count =   (0.1 cm) = 0.01 cm
 10 
Given t2 = nt1

Q.82 A parallel plate capacitor is made of two Ans. [4]

circular plates separated by a distance of 5 mm
and with a dielectric of dielectric constant 2.2 Sol. Initially,
between them. When the electric field in the
dielectric is 3 × 104 V/m, the charge density of l1 = 8 cm
the positive plate will be close to -
P1 = 76 cm of Hg
(1) 3 × 10–7 C/m2 (2) 3 × 104 C/m2
(3) 6 × 104 C/m2 (4) 6 × 10–7 C/m2

8cm
Ans. [4]
Sol.. CP students may be find similar question in

CP Exercise Sheet: [Chapter : Capacitance,
Level-1, Q. No. 34, Page No. 82]
x 46 + 8 = 54 cm
∆V
E= + –
d E
∆V = Ed
q = C ∆V K
Let length of air column = x cm
∈0 KA
= Ed cross sectional area of tube = A
d
d
q Pressure above mercury when tube closed and
σ= =∈0 KE
A
raised
−12 4
= 8.85 ×10 × 2.2 × 3 ×10
P2 = 76 – (54 – x) = (x + 22) cm of Hg
= 6 × 10–7 C/m2
Apply P1V1 = P2V2 (T = constant)

Q.83 An open glass tube is immersed in mercury in
such a way that a length of 8 cm extends above 76 × 8 × A = (x + 22) × (x × A)
he mercury level. The open end of the tube is
then closed and sealed and tube is raised x2 + 22x – 608 = 0
vertically up by additional 46 cm. What will be
length of the air column above mercury in the
tube now ? x = 16 cm
(Atmospheric pressure = 76 cm of Hg)
(1) 22 cm (2) 38 cm
(3) 6 cm (4) 16 cm

Q.84 A particle moves with simple harmonic motion

in a straight line. In first τ s, after starting from
rest it travels a distance a and in next τ s it R
travels 2a, in same direction, then -
2r
(1) time period of oscillations is 8τ
(2) amplitude of motion is 4a ρwg ρw g

(1) R2 (2) R2
6T T
(3) time period of oscillations is 6τ
(4) amplitude of motion is 3a 3ρ w g ρw g

(3) R2 (4) R2
T 3T
Ans. [3]
Ans. [Bonus]
Sol. Starting from rest so equation of S.H.M
Sol. When it detatch
 2π 
x = A cos (ωt) = A cos  t
 T 
 2π  B
So (A – a) = A cos  τ ….(i)
 T 
R
θ
 2π 
(A – 3a) = A cos  ( 2 τ)  ….(ii) r
 T  θ
From equation (i) & (ii)

T T
  2π  
A – 3a = A 2 cos 2  τ  − 1 r
  T   So, B = T (2πr) sin θ (sin θ = )
R
By solving A = 2a
4 3 r
From equation (i) gt A = 2a ⇒ T = 6τ πR ρWg = T(2πr) ×
3 R
2T
= (πr2)
Q.85 On heating water, bubbles being formed at the R
bottom of the vessel detatch and rise. Take the
bubbles to be spheres of radius R and making a 2ρ w g
r = R2 (None)
circular contact of radius r with the bottom of 3T
the vessel. If r << R, and the surface tension of
water is T, value of r just before bubbles
detatch is -
(density of water is ρw)

Q.86 A mass ‘m’ is supported by a massless string Q.87 During the propagation of electromagnetic
wound around a uniform hollow cylinder of waves in a medium -
mass m and radius R. If the string does not slip
on the cylinder, with what acceleration will the (1) Electric energy density is half of the
mass fall on release ? magnetic energy density
(2) Electric energy density is equal to the

magnetic energy density
m R
(3) Both electric and magnetic energy densities
m are zero
g 5g 2g (4) Electric energy density is double of the

(1) (2) (3) g (4)
2 6 3
magnetic energy density
Ans. [1]
Ans. [2]
Sol. CP Students may be find this question in CP
Exercise Sheet: [Chapter : Rotation, Avg, Sol. CP Students may be find this question in CP
Similar as Q.24, (Level-4A), Page No. 238] Exercise Sheet: [Chapter : Electromagnetic
Wave, Level # 1, Q.18, Page No. 179]
R 1
UE = ∈0 E 2
2
T
B2
UB =
m 2µ 0
a
mg
1
∈ E2 2
For translatory motion of block UE 2 0 E
= = ∈0 µ0  
UB B2  B
mg – T = ma ….(i)
2µ 0
for cylinder
τ = T.R = I α ….(ii)  1 
=  2 (C ) 2 = 1
a C 
TR = (mR2) or T = ma ….(iii)
R
∴ UE = UB
By adding equation (i) & (iii)
g
mg = 2ma a =
2

Q.88 Three rods of Copper, Brass and Steel are k Cu A ( t A − t ) k A( t − t B ) k S A( t − t C )

= B +
welded together to form a Y-shaped structure. l Cu lB lS
Area of cross-section of each rod
= 4 cm2. End of copper rod is maintained at 0.92(100 − t ) 0.26( t − 0) 0.12( t − 0)
= +
100ºC where as ends of brass and steel are kept 46 13 12
at 0ºC. Lengths of the copper, brass and steel 0.02 (100 – t) = 0.02 (t) + 0.01 t
rods are 46, 13 and 12 cms respectively. The
2 = 0.05 t
rods are thermally insulated from surrounding
except at ends. Thermal conductivities of 200
t= = 40ºC
copper, brass and steel are 0.92, 0.26 and 0.12 0.05
CGS units respectively. Rate of heat flow
k Cu A(100 − 40) 0.92 × 4 × 60
through copper rod is - HCu = =
l Cu 46
(1) 2.4 cal/s (2) 4.8 cal/s
HCu = 4.80 cal/s
(3) 6.0 cal/s (4) 1.2 cal/s
Ans. [2]
Sol. CP students may be find similar question in

Q.89 Hydrogen (1H1). Deuterium (1H2), singly
CP Exercise Sheet: [Chapter : Heat transfer
ionised Helium (2He4)+ and doubly ionised
in Level-4B, Q.no. 3, Page No. 176] lithium (3Li6)++ all have one electron around the
nucleus. Consider and electron transition from
0ºC
A 100ºC B n = 2 to n = 1. If the wavelengths of emitted
Cu
Brass radiation are λ1, λ2, λ3 and λ4 respectively then
HCu HB approximately which one of the following is
O correct ?
Steel
HS (1) λ1 = 2 λ2 = 2λ3 = λ4
0ºC (2) λ1 = λ2 = 4λ3 = 9λ4

C
(3) λ1 = 2 λ2 = 3λ3 = 4λ4
AO → copper rod; BO → Brass rod
(4) 4λ1 = 2 λ2 = 2λ3 = λ4
OC → Steel rod
Ans. [2]
Area of cross section A = 4 cm2 = 4 × 10–4 m2
1  1 1 
tA = 100ºC, tB = 0ºC, tC = 0ºC Sol. = Rz2  2 − 2 
λ  nL nH 
lCu = 46 cm, lB = 13 cm, lS = 12 cm
1  1 1 
kCu = 0.92, kB = 0.26, kS = 0.12 2
= R 2 − 2 
λz  nL nH 
Let temperature of junction point = t
For all atoms RHS is same
HCu = HB + HS

So λz2 = constant W= ∫ F dx
2 2 2 2
λ1(1) = λ2(1) = λ3(2) = λ4(3)
L
∫ (ax + bx
2
λ1 = λ2 = 4λ3 = 9λ4 = ) dx
0
aL2 bL3
Q.90 When a rubber-band is stretched by a distance = +
2 3
x, it exerts a restoring force of magnitude
F = ax + bx2 where a and b are constants. The
work done in stretching the unstretched rubber-
band by L is -
1 aL2 bL3
(1) (aL2 + bL3) (2) +
2 2 3
1  aL2 bL3 
  (4) aL2 + bL3
(3)
2  2 + 3 
 
Ans. [2]
Sol. CP Students may be find similar question in

CP Exercise Sheet: [Chapter : Work, Power
& Energy, Level-1, Page no. 159]


1771434JEE - Main - Examination - 06!04!2014 - Code-F (PCM)

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CAREER POINT

JEE Main Exam 2014 (Solution)

Part A – CHEMISTRY Q.2 Which one of the following bases is not

π( Mg3 ( PO4 )2 ) ∝ 5 × 0.1 Ans. [4]

π(KBr) ∝ 2 × 0.25 Sol. CP Students may find this question in CP

All have same osmotic pressure In aqueous solution

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Sol. CP Students may find question based on

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Ans. [1] 2Mn+2 → 2Mn+3 + 2e– Eºred. = 1.51 V

Sol. CP Students may find Similar Question in Overall reaction

∆n = Σ moles of products – Σ moles of = –2.69 V

reactants Since value of Eº is negative therefore the

(3) – 0.33 V; the reaction will occur At low pressure

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(3) HClO2 > HClO4 > HClO3 > HOCl xN A

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Ans. [4] Q.14 For which of the following molecule

Sol. CP Students may find this question in CP significant µ ≠ 0 ?

Q.13 Which series of reactions correctly represents

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Q.15 CsCl crystallises in body centred cubic Ans. [4]

(3) rCs+ + rCl– = 3a nHO–CH2–CH2–O–H + nHO–C C–OH

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n=2 Ans. [4]

eq. of acid used = 12 – 2 = 10

the amount of heat produced as measured in 8.314 × 298

(R = 8.314 kJ mol–1) = –1364.47 – 2476.38 × 10–3

(1) – 1361.95 kJ mol–1 = –1366.9 kJ

(2) – 1460.50 kJ mol–1 Note:-Value of R given is wrong, standard

(4) – 1366.95 kJ mol–1

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Q.19 The octahedral complex of a metal ion M3+ R–CH2–OH → R–CH=O

(d) H2O2 + 2OH– – 2e– → O2 + 2H2O

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Ans. [1] Debye and Huckel equation for strong electrolyte

Sol. CP Students may find similar Question in CP λm = λm∞ – b C

In CsI3, cation is Cs+ and anion is I3– λC = λ∞ – B C

Cl Sol. CP Students may find similar question in CP

(3) λC = λ∞ + (B) C (4) λC = λ∞ + (B)C l

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on acetylation produces C. Q.27 The equation which is balanced and

(2) [Mg(H2O)6]2+ + (EDTA)4–

OH OH (3) CuSO4 + 4KCN → K2[Cu(CN)4] + K2SO4

(1) COCH3 (2) COCH3 (4) Li2O + 2KCl → 2LiCl + K2O

COOH Q.28 The correct set of four quantum numbers for

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Ans. [4] r = k[A]x [B]y (Rate law expression)

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Q.32 Let the population of rabbits surviving at a time

π (1) 400 – 300 e–t/2 (2) 400 – 300 et/2

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p( t ) − 400 Ans. [1]

⇒ 300 et/2 = 400 – p(t) α+β

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= slope of the line parallel to PS

⇒ 2x + 9y + 7 = 0 Q.37 If A is an 3 × 3 non-singular matrix such that

(1) (B–1)′ (2) I + B

Q.36 The area of the region described by (3) I (4) B–1

Ans. [2] ⇒ B′ = ((A–1) . A′)′

Sol. ⇒ B′ = (A′)′ . (A–1)′

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x −1 y−3 z−4 Q.39 If x = –1 and x = 2 are extreme points of