Chem Jeem Sept

Final JEE - Main Exam September, 2020/02-09-2020/Morning Session
FINAL JEE–MAIN EXAMINATION – SEPTEMBER, 2020

(Held On Wednesday 02nd SEPTEMBER, 2020) TIME : 9 AM to 12 PM
CHEMISTRY TEST PAPER WITH ANSWER & SOLUTION
1. The IUPAC name for the following compound is: Sol. Photoelectric effect (option 2), atomic spectrum
CHO (option 3) and Black body radiations (option 4)
CH3 may be explained by quantum theory.
H3 C As on increasing temperature, all the values of
COOH internal energy becomes possible, it is not directly
(1) 2, 5-dimethyl-6-carboxy-hex-3-enal explained from quantum theory.
(2) 6-formyl-2-methyl-hex-3-enoic acid 3. For the following Assertion and Reason, the
(3) 2, 5-dimethyl-5-carboxy-hex-3-enal correct option is
(4) 2, 5-dimethyl-6-oxo-hex-3-enoic acid Assertion (A) : When Cu (II) and sulphide ions
Official Ans. by NTA (4) are mixed, they react together
6
CHO extremely quickly to give a solid.
Soll. H3C
5
4
3
2
COOH
1
CH3
IUPAC name
2, 5-dimethyl-6-oxo-hex-3-enoic acid
EN Reason (R) : The equilibrium constant of
Cu2+ (aq) + S2– (aq) CuS(s)
is high because the solubility
product is low.
2. The figure that is not a direct manifestation of the (1) Both (A) and (R) are true and (R) is the
quantum nature of atoms is : explanation for (A)
LL
(2) Both (A) and (R) are false
Internal
energy of (3) (A) is false and (R) is true
(1) Ar 300 400 500 600
(4) Both (A) and (R) are true but (R) is not the
Temperature (K)
explanation for (A)
Rb K Na Official Ans. by NTA (4)
Kinetic
A
energy of Sol. Slow or fast process is kinetic parameter but extent

less or more is thermodynamic parameter.
(2) photoelectrons
Frequency of incident 4. If AB4 molecule is a polar molecule, a possible
radiation
geometry of AB4 is :
Increasing wavelength
(1) Square pyramidal
(2) Tetrahedral
(3)
(3) Square planar
Absorption spectrum
(4) Rectangular planar
Intensity T2 > T1 Official Ans. by NTA (1)
of black body
(4) radiation T1
Wavelength
Official Ans. by NTA (1)
1
Sol. (1) If AB4 molecule is a square pyramidal then
it has one lone pair and their structure should be D
Sol. A B
B Compound Gas
+ H2
B catalyst (Haber's process)
A :
B C
B Basic gas
and it should be polar because dipole moment of Basic gas (C) must be ammonia (NH3).
lone pair of 'A' never be cancelled by others. It means (B) gas should be N2 which is
formed by heating of compound (A).
(2) If AB4 molecule is a tetrahedral then it has
no lone pair and their structure should be (1) (NH4)2Cr2O7 ¾¾
D
® N2 + Cr2O3 + 4H2O
B D 1
(2) Pb(NO3)2 ¾¾
® PbO + 2NO2 + O
2 2
A
B B D
B (3) 2NaN3 ¾¾ ® 2Na + 3N2
EN
and it should be non polar due to perfect symmetry.
(3) If AB4 molecule is a square planar then
B B
6.
(4) NH4NO2 ¾¾
D
® N2 + 2H2O
So, (A) should not be Pb(NO3)2
In general, the property (magnitudes only) that
shows an opposite trend in comparison to other
A
properties across a period is
B B
(1) Electronegativity
it should be non polar because vector sum of dipole
LL
moment is zero. (2) Electron gain enthalpy
(3) Ionization enthalpy
(4) If AB4 molecule is a rectangular planar then
(4) Atomic radius
B B
A
Sol. In general across a period atomic radius decreases
B B
A
while ionisation enthalpy, electron gain enthalpy

and electronegativity increases because effective
it should be non polar because vector sum of dipole
nuclear charge (Zeff) increases.
moment is zero.
7. The statement that is not true about ozone is :
5. On heating compound (A) gives a gas (B) which
is constituent of air. This gas when treated with (1) in the stratosphere, it forms a protective shield
against UV radiation.
H2 in the presence of a catalyst gives another gas
(C) which is basic in nature. (A) should not be: (2) it is a toxic gas and its reaction with NO gives
NO2.
(1) (NH4)2Cr2O7
(3) in the atmosphere, it is depleted by CFCs.
(2) Pb(NO3)2
(4) in the stratophere, CFCs release chlorine free
(3) NaN3
& which reacts with O3 to give
radicals (Cl)
(4) NH4NO2 chlorine dioxide radicals.
Official Ans. by NTA (2) Official Ans. by NTA (4)
2
Sol. In the stratosphere, CFCs release chlorine free While with weak field ligands Mn(II)
&
radical (Cl) complexes can be high spin because they have
more number of unpaired electron (unpaired
UV
CF2Cl2(g) ¾¾¾ ® Cl& (g) + CF
& Cl(g)
2
electron = 5)
(IV) Aqueous solution of Mn(II) ions is pink in
&
which react with O3 to give chlorine oxide (ClO) colour.
& ) radical.
radical not chlorine dioxide (ClO 10. Consider that a d 6 metal ion (M 2+) forms a
2
complex with aqua ligands, and the spin only
& + O (g) ® ClO(g)
Cl(g) & + O2 (g) magnetic moment of the complex is 4.90 BM. The
3
8. The metal mainly used in devising photoelectric geometry and the crystal field stabilization energy
cells is: of the complex is :
(1) Na (2) Rb (1) tetrahedral and –1.6 Dt + 1P

(3) Li (4) Cs (2) tetrahedral and –0.6 Dt
Official Ans. by NTA (4) (3) octahedral and –1.6 D0
Sol. Cs used in photoelectric cell as it has least
(4) octahedral and –2.4 D0 + 2P
9.
ionisation energy. EN
For octahedral Mn(II) and tetrahedral Ni(II)
complexes, consider the following statements :
Sol. If spin only magnetic moment of the complex is
4.90 BM, it means number of unpaired electrons
should be 4.
(I) both the complexes can be high spin
(II) Ni(II) complex can very rarely be low spin. (A) In octahedral complex : [M(H 2O)6 ]2+
(III) with strong field ligands, Mn(II) complexes d6
LL
can be low spin.
eg.
(IV) aqueous solution of Mn(II) ions is yellow in
color. 0.6 D0
The correct statements are : Bary centre

–0.4 D0
(1) (I), (III) and (IV) only 't2g'
A
(2) (II), (III) and (IV) only

C.F.S.E. = (–0.4 D0) × 4 + (+0.6 D0) × 2 + 0 × P
(3) (I), (II) and (III) only = –0.4 D0
(4) (I) and (II) only (B) In tetrahedral complex : [M(H 2O)4 ]2+
Official Ans. by NTA (3) d6
Sol. (I) Under weak field ligand, octahedral Mn(II)
and tetrahedral Ni(II) both the complexes are 't2'
high spin complex.
(II) Tetrahedral Ni(II) complex can very rarely be 0.4 Dt
low spin because square planar (under strong Bary centre
ligand) complexes of Ni(II) are low spin
–0.6 Dt
complexes. 'e'
(III) With strong field ligands Mn (II) complexes
can be low spin because they have less number C.F.S.E. = (–0.6 Dt) × 3 + (+0.4 Dt) × 3 + 0 × P
of unpaired electron (unpaired electron = 1) = –0.6 Dt
3
11. In Carius method of estimation of halogen, 0.172g OH OH

of an organic compound showed presence of 0.08g (1) CO2H (2)
CHO
of bromine. Which of these is the correct structure
Br Br
of the compound :
(3) (4)
NH2 CO2H
CHO
(1) (2) H3C–CH2–Br O OH

HBr
Sol. (excess),
¾¾¾¾ ®
Br D
Br Br
NH2
Br OH
(i) KOH (Alc.) O
¾¾¾¾¾¾ ® ¾¾¾¾ 3
Zn/H O+
®
(3) (4) H3C–Br (ii)H + 3
Br OH O
CHO ||
Official Ans. by NTA (1) + | + H–CH
Sol. In Carius method
mass of organic compound = 0.172 gm
mass of Bromine = 0.08 gm
EN 13.
CHO CHO
An open beaker of water in equilibrium with water
vapour is in a sealed container. When a few grams
of glucose are added to the beaker of water, the
0.08 rate at which water molecules :
Hence % of Bromine = ´ 100
0.172 (1) leaves the vapour increases
= 46.51% (2) leaves the solution increases
LL
(3) leaves the solution decreases
NH2 (4) leaves the vapour decreases
é 80 ù Official Ans. by NTA (1)
(1) C6H6NBr ê%Br = ´ 100 ú = 46.51%
Official Ans. by ALLEN (3)
ë 172 û
Sol. With addition of solute in solvent, surface area
Br for vapourisation decreases causes lowering in
vapour pressure
A
80 14. Which one of the following graphs is not correct

(2) CH3CH2Br C2H5Br %Br = ´ 100 = 73.33%
109 for ideal gas ?
NH2
(3) C6H5NBr2 d d
Br Br
T T
(4) CH3Br (I) (II)
12. The major aromatic product C in the following
reaction sequence will be :
O d d
HBr
(excess), (i) KOH(Alc.)
¾¾¾¾D
® (A) ¾¾¾¾¾¾
(ii)H +
®B
1/T P
(III) (IV)
O
¾¾¾¾ 3
Zn/H O +
®C d = Density, P = Pressure, T = Temperature
3
4
(1) II (2) III (1) (iii) < (iv) < (ii) < (i)
(3) I (4) IV (2) (iii) < (iv) < (i) < (ii)
Official Ans. by NTA (1) (3) (iii) < (i) < (iv) < (ii)
1 (4) (i) < (iii) < (iv) < (ii)
Sol. PM = dRT Þ d µ
T Sol. Increasing order of reactivity towards HCN
15. Which of the following compounds will show addition
retention in configuration on nucleophic
–
O
substitution by OH ion ? ||
Greater the electrophilicity on –C– group greater
(1) CH3–CH–CH2Br (2) CH 3–CH–Br the reactivity in nucleophilic addition.
C2H 5 C6H5
O O
|| ||
Br CH CH
OCH3
(3) CH 3–CH–Br (4) CH3–C–H
+R < <
+I OCH3
CH3 C6H 13
*
Sol. (1) CH3–CH–CH2–Br
OH *
CH3–CH–CH 2OH
SN 2
EN CHO
(–I)
O
||
CH
Et Et
* (NCERT) <
NO2 NO2
OH (–I) (–R)
LL
(2) CH3–CH–Br Ph–CH–OH only (–I)
SN2
Ph CH3
(iii) < (i) < (iv) < (ii)
OH 17. While titrating dilute HCl solution with aqueous
(3) Br OH
SN 2
NaOH, which of the following will not be
required?
A
OH
CH3–CH–Br CH3–CH–OH
(4) SN 2 (1) Clamp and phenolphthalein
C6H 13 C6 H 3
(2) Pipette and distilled water
As language given, we have to go with option (1)
as stereochemistry of chiral centre is not distortet. (3) Burette and porcelain tile
16. The increasing order of the following compounds (4) Bunsen burner and measuring cylinder
towards HCN addition is : Official Ans. by NTA (4)
H 3CO CHO CHO Sol. Lab manual
18. Consider the following reactions :
NO2
(i) (ii) (i) Glucose + ROH dry HCl
¾¾¾¾ ® Acetal
CHO O2 N CHO
x eq.of
¾¾¾¾¾
(CH 3CO)2 O
® acetyl derivative
OCH3
(iii) (iv)
5
Ni/H 2 y eq.of CH=O CH2–OH

(ii) Glucose ¾¾¾® A ¾¾¾¾¾ ® acetyl | |
(CH CO) O 3 2 Ni 6 Eq.
(CH–OH)4 (CH–OH)4
derivative (ii) | H2 | Ac2O
CH2–OH CH2–OH
z eq.of
(iii) Glucose ¾¾¾¾¾
(CH 3CO)2 O
® acetyl derivative
CH2–OAc
|
'x', 'y' and 'z' in these reactions are respectively. (CH2–OAc) 4
(1) 5, 6, & 5 (2) 4, 5 & 5 |
CH2–OAc
(3) 5, 4 & 5 (4) 4, 6 & 5
OH
Official Ans. by NTA (4) O
Sol. Ac2O
OH 5 Eq.
(i) Glucose + dry HCl ¾¾¾ (iii)
ROH
® Acetal HO
x Eq
¾¾¾¾¾ ® acetyl derivative OH
(CH 3CO)2 O
OAc
O
(ii) Glucose
(iii) Glucose
Ni/H 2
z Eq
¾¾¾¾¾
y Eq
¾¾¾® A ¾¾¾¾¾
(CH 3CO)2 O
(CH 3CO)2 O
®
® EN Acetyl
derivative
Acetyl derivative
Glucose pentacetase
OAc
OAc
OAc
OAc
due to presence of –OH group in Glucose the 19. The major product in the following reaction is :
reaction is H 3C CH=CH2
LL
H O+
O O O ¾¾¾
3
Heat
®
|| || ||
R–OH + CH 3–C—O–C–CH 3 R–O–C–CH 3
OH
H3 C CH3
H3C
Acetyl derivative CH3
(1) (2)
so for (i)
A
CH3 CH3
CH2OH CH2OH
O O (3) (4)
H dil. H CH3 CH3
H HCl H
OH OR
OH H ROH OH H
OH HO Official Ans. by NTA (3)
H OH H OH Å
H 3C CH=CH2 CH3 CH–CH3
Ac2O (4 Eq)
H3O+
Sol.
Heat
OAc
O
OR
OAc H ring expansion
AcO
H OAc
CH3
D Å
+
–H
CH3
major
6
20. Which of the following is used for the preparation Official Ans. by NTA (5.00)
of colloids ? Sol. No. of chiral centres
(1) Ostwald Process (2) Van Arkel Method *

*
(3) Bredig's Arc Method (4) Mond Process N
Official Ans. by NTA (3) OH O
*
Sol. Bredig's Arc method is used to from metal colloids. *
CH
21. The Gibbs energy change (in J) for the given H3 C * CH3
reaction at [Cu2+] = [Sn2+] = 1 M and 298K is: N
Cu(s) + Sn2+ (aq.) ® Cu2+ (aq.) + Sn(s) ;
24. The oxidation states of iron atoms in compounds
0 0
(E Sn 2+
|Sn
= -0.16V, E Cu 2+
|Cu
= 0.34V, (A), (B) and (C), respectively, are x, y and z. The
Take F = 96500 C mol–1) sum of x,y and z is ____.
Official Ans. by NTA (96500.00) Na 4 [Fe(CN)5 NOS)] Na 4 [FeO 4 ] [Fe 2 (CO) 9 ]
é Sn +2 ù (A) (B) (C)
Sol. DG = DGº + RT ln ê +2 ú
ë Cu û
22.
= 96500 J
æ1ö
= –2 × 96500 [(–0.16) – 0.34] + RT ln ç ÷
è1ø
EN
The mass of gas adsorbed, x, per unit mass of
x
Sol. (A) Na 4 [Fe(CN)5 (NOS)]
(+1)4 + x + (–1)5 + (–1) 1 = 0
x = +2
adsorbate, m, was measured at various pressures,
y
x (B) Na 4 [Fe O 4 ]
p. A graph between log and log p gives a
m
(+1)4 + y + (–2)4 = 0
straight line with slope equal to 2 and the intercept
LL
x y = +4
equal to 0.4771. The value of at a pressure
m z
of 4 atm is : (Given log 3 = 0.4771) (C) [Fe 2 (CO)9 ]
Official Ans. by NTA (6.00) 2z + 0 × 9 = 0
Official Ans. by ALLEN (48.00)
x
z=0
A
Sol. = k p x ...(1) so (x + y + z) = +2 + 4 + 0
m
x = 6
log = log k + x log p
Þ E55F m E55F E55F 25. The internal energy change (in J) when 90g of
x
y c + m water undergoes complete evaporation at 100ºC
Given c = log k = 0.4771 or k = 3 is ____ .
slope x = 2
(Given : DHvap for water at 373 K = 41 kJ/mol,
x
put in eq. (1) = 3 × (4)2 Þ 48 R = 8.314 JK–1 mol–1)
m
23. The number of chiral carbons present in the Official Ans. by NTA (189494.00)
molecule given below is _____ . Official Ans. by ALLEN (189494.39)
Sol. H2O(l) H2O(g) 90 gm of H2O
N
H O DH = DU + DngRT Þ 5 moles of H2O
C 5 × 41000 J = DU + 1 × 8.314 × 373 × 5
H3 C CH3
HO DU = 189494.39 Joule
N
7
Final JEE - Main Exam September, 2020/02-09-2020/Evening Session

(Held On Wednesday 02nd SEPTEMBER, 2020) TIME : 3 PM to 6 PM
CHEMISTRY TEST PAPER WITH ANSWER & SOLUTIONS
1. The major product of the following reaction is: 3. Arrange the following labelled hydrogens in
OH decreasing order of acidity :
CH3 conc. HNO3 + conc. H2SO4
NO2 C C H
NO2 a
OH OH
H3 C H3 C NO2 H O COO H b
d
(1) (2) O H
c
O2 N NO2 NO2
(1) b > c > d > a
OH OH
H3 C (2) c > b > a > d
H3 C NO2
(3) b > a > c > d
(3) NO2 (4) NO2
Sol.
NO2
More donating group

EN NO 2 (4) c > b > d > a
Sol. Acidic strength order :
OH OH O
CH3 CH3 R C OH > R OH > R C CH
Conc. HNO3 / H2SO4
Nitration
NO2 NO2
LL
O
NO2
(Major) Reason : R C O stable by equivalent resonance.
OH Stable :
CH3 NO2
+
NO2 –R NO 2 C CH –I NO2 C CH
A
[Minor due to crowding]

>
2. If you spill a chemical toilet cleaning liquid on HO COOH O COOH
your hand, your first aid would be : O OH
(1) aqueous NH 3 (2) vinegar
So answer is b > c > d > a.
(3) aqueous NaHCO3 (4) aqueous NaOH
4. Cast iron is used for the manufacture of :
Sol. Toilet cleaning liquid has about 10.5% w/v (1) wrought iron and pig iron
HCl; to neutralise its affect aqueous NaHCO3 (2) wrought iron and steel
is used while NaOH is avoid for this purpose
(3) wrought iron, pig iron and steel
because its highly corosive in nature and can
(4) pig iron, scrap iron and steel
burn body.
Aliter : Official Ans. by NTA (2)
Dil HCl is generally used as toilet cleaner Sol. Cast iron is used for manufacturing of wrought
\ NaHCO3 is used to neutralize it iron and steel.
1
5. Two compounds A and B with same molecular 6. The shape/structure of [XeF5]– and XeO 3F2,
formula (C3H6O) undergo Grignard's reaction
respectively, are :
with methylmagnesium bromide to give
products C and D. products C and D show (1) pentagonal planar and trigonal bipyramidal
following chemical tests.
(2) trigonal bipyramidal and pentagonal planar
Test C D (3) octahedral and square pyramidal
Ceric Positive Positive
(4) trigonal bipyramidal and trigonal
ammonium
nitrate Test bipyramidal
Lucas Test Turbidity Turbidity Official Ans. by NTA (1)

obtained after obtained
7. The major product obtained from
five minutes immediately
E 2 -elimination of 3-bromo-2-fluoropentane
Iodoform Test Positive Negative
is:
C and D respectively are :
Br
CH3
(1) CH3CH2 CH CH CH2
(1) C H3C C OH ;
CH3
D H3C CH2 CH CH3
OH
(2) C H3C CH2 CH2 CH2 OH ;
EN Br
(2) CH3 CH2 C CH CH3
F
CH3 (3) CH3 CH CH CH CH3
D H3C C OH
CH3 (4) CH3CH2CH C F
LL
OH CH3
(3) C H3C CH2 CH CH3 ;
CH3
Sol.
D H3C C OH
CH3 H more acidic H
(4) C H3C CH2 CH2 CH2 OH ; E2
CH3 CH2 CH C CH3
A
D H3C CH2 CH CH3

Br F
OH
Official Ans. by NTA (3) Better leaving group
Sol. CH3 CH2 CH C CH3
O OH F
CH3MgBr Stable alkene
CH3 CH2 C H CH3 CH2 CH CH3
having 5 aH
(A) 2° Alcohol
(C) 8. Three elements X, Y and Z are in the 3rd period
CAN test for alcohol : ü of the periodic table. The oxides of X, Y and
Iodoform test : ü Z, respectively, are basic, amphoteric and
O OH acidic. The correct order of the atomic numbers
CH3MgBr
CH3 C CH3 CH3 C CH3 of X, Y and Z is :
(B) CH3 (1) Z < Y < X (2) X < Z < Y
3° Alcohol (3) X < Y < Z (4) Y < X < Z
CAN test for alcohol : ü
Lucas test : Immediately Official Ans. by NTA (3)
Iodoform test : û
2
Sol. When we are moving from left to right in a Sol. Reaction 1 : SN1
periodic table acidic character of oxides increases Reaction 2 : E2
(as well as atomic number of atom increases) SN 1 is independent of concentration of
\ X<Y<Z (acidic character) nucleophile/base
X<Y<Z (atomic number) 12. The results given in the below table were
9. The number of subshells associated with n = 4 obtained during kinetic studies of the following
and m = –2 quantum numbers is :
reaction:
(1) 4 (2) 8 (3) 16 (4) 2
2A + B ¾® C + D
10. Simplified absorption spectra of three complexes Initial
((i), (ii) and (iii)) of M n + ion are provided below; Experiment [A]/molL–1 [B]/molL–1 rate/molL–1
their l max values are marked as A, B and C min–1
respectively. The correct match between the I 0.1 0.1 6.00 × 10–3
complexes and their lmax values is :
II 0.1 0.2 2.40 × 10–2
III 0.2 0.1 1.20 × 10–2
C
A IV X 0.2 7.20 × 10–2
B
Absorption V 0.3 Y 2.88 × 10–1
lmax lmax
Wavelength (nm)
lmax
EN X and Y in the given table are respectively :
(1) 0.3, 0.4
(3) 0.4, 0.4
(2) 0.4, 0.3
(4) 0.3, 0.3
Sol. From rate law
(i) [M(NCS)6](–6+n) (ii) [MF6](–6+n)
(iii) [M(NH3)6]n+ 1 d[A] -d[B]
r=- =
(1) A-(ii), B-(i), C-(iii) (2) A-(iii), B-(i), C-(ii) 2 dt dt
LL
(3) A-(ii), B-(iii), C-(i) (4) A-(i), B-(ii), C-(iii) = K[A] [B]
x y
Official Ans. by NTA (2) 6 × 10–3 = K(0.1)x (0.1)y ……(1)

11. Consider the reaction sequence given below : 2.4 × 10 = K(0.1) (0.2) ……(2)
–2 x y
1.2 × 10–2 = K(0.2)x (0.1)y ……(3)

OH (3) ÷ (1) Þ x = 1
Br H2O OH + Br ……(1)
rate = k[t-BuBr] (2) ÷ (3) Þ x = 2
A
So, other with respect to A = 1

CH3 Order with respect to B = 2
OH (4) ÷ (3)
C2H5OH
+ HOH + Br ……(2)
2 -2
H2C CH3 æ x ö æ 0.2 ö 7.2 ´ 10
ç ´
÷ ç ÷ =
rate = k[t-BuBr] [OH ] è 0.2 ø è 0.1 ø 1.2 ´ 10 -2
Which of the following statements is true : 6 ´ 0.2
(1) Changing the concentration of base will x=
4
have no effect on reaction (1)
x = 0.3 M
(2) Changing the concentration of base will
(5) ÷ (4)
have no effect on reaction (2)
2 -1
(3) Changing the base from OH to OR will æ y ö 2.88 ´ 10
ç ÷ = -2
have no effect on reaction (2) è 0.2 ø 7.2 ´ 10
(4) Doubling the concentration of base will y2 = 4 × 0.22
double the rate of both the reactions. y = 0.4 M
3
13. An organic compound 'A' (C 9 H 10 O) when 15. Two elements A and B have similar chemical
treated with conc. HI undergoes cleavage to properties. They don't form solid
yield compounds 'B' and 'C'. 'B' gives yellow hydrogencarbonates, but react with nitrogen to
precipitate with AgNO 3 where as 'C' form nitrides. A and B, respectively, are :
tautomerizes to 'D'. 'D' gives positive idoform (1) Na and C (2) Li and Mg
test. 'A' could be :
(3) Cs and Ba (4) Na and Rb
(1) O CH CH CH3 Official Ans. by NTA (2)

16. The one that is not expected to show isomerism
CH2 O CH CH2 is :
(2)
(1) [Ni(NH3)4(H2O)2]2+ (2) [Ni(NH3)2Cl2]
(3) [Pt(NH3)2Cl2] (4) [Ni(en)3]2+
(3) O CH2 CH CH2
17. Amongst the following statements regarding
(4) H3C O CH CH2
adsorption, those that are valid are :
Sol
. CH2 O CH CH2
C9H 10O
Conc. HI
EN (a) DH becomes less negative as adsorption
proceeds.
(b) On a given adsorbent, ammonia is
adsorbed more than nitrogen gas.
[A] H (c) On adsorption, the residual force acting
CH2 O CH CH2 along the surface of the adsorbent
increases.
LL
Cleavage of
ether by SN1 (d) With increase in temperature, the
equilibrium concentration of adsorbate
CH2 + HO CH CH2 increases.
(1) (b) and (c) (2) (a) and (b)
I Tauto
(3) (d) and (a) (4) (c) and (d)
O
A
AgNO3
AgI ¯ CH2 I H C CH3 Official Ans. by NTA (2)
Yellow
ppt [B] [D] Sol.(a) Since adsorption is exothermic process, as
Iodoform : ü adsorption proceeds number of active sites
test
present over adsorbent decreases, so less heat
14. The size of a raw mango shrinks to a much
is evolved.
smaller size when kept in a concentrated salt
(b) Since NH 3 has higher force of attraction on
solution. Which one of the following processes
adsorbent due to its polar nature (high value of
can explain this ?
(1) Diffusion (2) Dialysis 'a').
(3) Osmosis (4) Reverse osmosis (c) As the adsorption increases, residual forces
Official Ans. by NTA (3) over surface decreases.
Sol. Raw mango shrink in salt solution due to net (d) Since process is exothermic, on increasing
transfer of water molecules from mango to salt temperature it shift to backward direction, so
solution due to phenomenon of osmosis. concentration of adsorbate particle decreases.
4
18. Match the type of interaction in Column A with Sol. Seliwanoff's test is used to distinguish between
the distance dependence of their interaction aldose and ketone sugars; when added to a
energy in Column B : solution containing ketose, red colour is formed
A B rapidly.
Hydrolysis Seliwanoff 's
Sucrose Glucose Red
1 +
reagent
(I) iron - ion (a) colour
r Fructose
20. The molecular geometry of SF6 is octahedral.
1
(II) dipole - dipole (b) 2 What is the geometry of SF4 (including lone
r
pair(s) of electrons, if any) ?
1
(III) London dispersion (c) 3 (1) Trigonal bipyramidal
r
1 (2) Square planar
(d) 6
r (3) Tetrahedral
(1) (I)-(a), (II)-(b), (III)-(c) (4) Pyramidal
(2) (I)-(a), (II)-(c), (III)-(d)
(3) (I)-(a), (II)-(b), (III)-(d)
(4) (I)-(b), (II)-(d), (III)-(c)
EN Sol.
F
F
F
S
Official Ans. by NTA (3) F
Official Ans. by ALLEN (2) 4s bonds +1 lone pair
Sol. Type of interaction µ Interaction Energy \ Shape (including lone pair of electrons) is
LL
1 Trigonal bipyramidal
ion - ion
r 21. The heat of combustion of ethanol into carbon
dioxides and water is –327 kcal at constant
1 pressure. The heat evolved (in cal) at constant
dipole - dipole
r3 volume and 27°C (if all gases behave ideally)
is (R = 2 cal mol–1 K–1)
A
1
London dispersion
r6 Official Ans. by NTA (–326400.00)
19. The correct observation in the following Official Ans. by ALLEN (326400.00)
reactions is : Sol. C2H5OH(l) + 3O2(g) ¾® 2CO2(g) + 3H2O(l)
Dng = 2 – 3 = –1
Glycosidic bond Seliwanoff 's
Sucrose Cleavage
A+B reagent
? DcH = DcU + (Dng) RT
(Hydrolysis)
DcH = DcU – RT
(1) Formation of blue colour DcU = DcH + RT
(2) Formation of violet colour = –327 × 103 + 2 × 300

= –326400 cal.
(3) Formation of red colour
\ Heat evolved
(4) Gives no colour
= 326400 cal.
5
22. For the disproportionation reaction So, x=6

2Cu + (aq) Cu(s) + Cu 2+(aq)
at 298 K, y=7
ln K (where K is the equilibrium constant) z=6
is _____ × 10–1 .
x + y + z = 19
Given
24. The ratio of the mass percentages of 'C & H'
(E
0
Cu 2+ /Cu +
= 0.16V and 'C & O' of a saturated acyclic organic
compound 'X' are 4 : 1 and 3 : 4 respectively.
E 0Cu + /Cu = 0.52V Then, the moles of oxygen gas required for
RT complete combustion of two moles of organic
= 0.025) compound 'X' is _______ .
F
Official Ans. by NTA (144.00) Official Ans. by NTA (5.00)
Sol. Cu+ ¾® Cu + e– Sol. C : H = 4 : 1
Cu+ + e– ¾® Cu(s) C:O=3:4
Mass ratio
2Cu+ ¾® Cu2+ + Cu
C : H : O = 12 : 3 : 16
E ocell = E Cu
o
+
/Cu
- E Cu
= 0.52 – 0.16
= 0.36 V
o
At equilibrium ® Ecell = 0
2+
/Cu + EN Mole ratio
C:H:O=1:3:1
Empirical formula = CH3O
Molecular formula = C2H6O2
(saturated acyclic organic compound)
RT
E ocell = ln K 5
nF C2H 6O 2 + O ¾® 2CO2 + 3H2O
2 2
LL
E ocell ´ nF 2 mole 5 mol
ln K =
RT Moles of O2 required = 5 moles
25. The work function of sodium metal is
0.36 ´ 1
ln K = 4.41 × 10 –19 J. If the photons of wavelength
0.025
300 nm are incident on the metal, the kinetic
A
= 14.4 = 144 × 10–1

energy of the ejected electrons will be
23. The oxidation states of transition metal atoms
(h = 6.63 × 10 –34 Js; c = 3 × 10 8 m/s)
in K2Cr2O7, KMnO4 and K2FeO4, respectively,
________ × 10–21 J.
are x, y and z. The sum of x, y and z is ____. Official Ans. by NTA (222.00)
Official Ans. by NTA (19.00) Sol. E = W + K·Emax
Sol. K2Cr2O7
K·Emax = E – W
2 (+1) + 2X + 7(–2) = 0
X=6 hc
= – 4.41 × 10–19
Transition metal chromium is present in +6 l
oxidation state.
6.63 ´ 10 -34 ´ 3 ´ 108
In KMnO 4 transition metal molar mass is = – 4.41 × 10–19
300 ´ 10 -9
present in +7 oxidation state
In K2FeO4 transion metal Fe is present in +6 = 2.22 × 10–19 J
oxidation state = 222 × 10–21 J
6

(Held On Thursday 03rd SEPTEMBER, 2020) TIME : 9 AM to 12 PM
1. The complex that can show optical activity is:
(1) trans-[Fe(NH3)2(CN)4]– O O
me me (B)
(2) cis-[Fe(NH3)2(CN)4]– H+/H2O
Sol. (1) me C C O CH2 C me C OH
(3) cis-[CrCl2(ox)2]3– (ox = oxalate) me me
(A)
(4) trans-[Cr(Cl2)(ox)2]3– + KMnO4
Official Ans. by NTA (3) HO CH2
(C)
NH3 1
NC CN
Fe
Sol. (1) optically inactive O
NC CN
NH3 (2)
C O CH2 CH2 CH3
NH3 1
NC NH3 Total 8 'C' ® so molecular formula not
(2) Fe optically inactive
NC CN matched.
(3)
OX Cr
CN
Cl
Cl
3–
EN
optically active (3) me CH2 CH O C CH2 CH
O me
Et
OX me H + /H2O O me
Cl 3– me CH2 CH OH + C CH2 CH
me HO
(4) OX Cr OX optically inactive Et
LL
not inter convertible
Cl by oxidation
2. An organic compound [A], molecular formula
C10H20O2 was hydrolyzed with dilute sulphuric
acid to give a carboxylic acid [B] and alcohol O
[C]. Oxidation of [C] with CrO 3 – H 2 SO 4 (4) me CH2 CH C O CH2 CH Et (A)
A
produced [B]. Which of the following structures me +

H /H2O O me
are not possible for [A] ? me CH2 CH C OH + HO CH2 CH Et
(B) me (C)
(1) (CH3)3–C–COOCH2C(CH3)3 KMnO4
(2) CH3CH2CH2COOCH2CH2CH2CH3
3. If the boiling point of H2O is 373 K, the boiling
CH3
| point of H2S will be :
CH3–CH2–CH–OCOCH2CH–CH2CH3
(3) | (1) Greater than 300 K but less than 373 K
CH3
(2) Less than 300 K
CH3 (3) Equal to 373 K
|
CH3–CH2–CH–COOCH2–CH–CH2CH3 (4) More than 373 K
(4) |
CH3 Official Ans. by NTA (2)
Official Ans. by NTA (3) Sol. Boiling point of H2S < Boiling point of H2O
Official Ans. by ALLEN (2 & 3) (213 K) (373 K)
1
4. In a molecule of pyrophosphoric acid, the 7. Henry's constant (in kbar) for four gases a, b,
number of P–OH, P=O and P–O–P bonds/ g and d in water at 298 K is given below :
moiety(ies) respectivey are :
a b g d
(1) 3, 3 and 3 (2) 2, 4 and 1
KH 50 2 2 ´ 10 -5 0.5
(3) 4, 2 and 0 (4) 4, 2 and 1
Official Ans. by NTA (4) (density of water = 10 3 kg m–3 at 298 K)
Sol. Pyrophosphoric acid. This table implies that :
(1) The pressure of a 55.5 molal solution of g
O O is 1 bar
P P (2) The pressure of a 55.5 molal solution of d
HO O OH is 250 bar
OH OH
(3) Solubility of g at 308 K is lower than at 298 K
P – OH linkages = 4 (4) a has the highest solubility in water at a
P = O linkages = 2 given pressure
P–O–P linkages = 1 Official Ans. by NTA (2)
5. It is true that :
(2) A second order reaction is always a

multistep reaction
EN
(1) A zero order reaction is a single step reaction
Sol. (1) Pg = KHXY
Pg = 2 ´ 10 -15 ´
55.5
55.5 +
1000
18
= 2 ´ 10 -5 K bar
(3) A first order reaction is always a single step = 2 × 10–2 bar

reaction (2) Pd = KH Xd
(4) A zero order reaction is a multistep reaction
LL
55.5
Official Ans. by NTA (4) Pd = 0.5 ´ = .249 K bar = 249 bar
1000
Sol. Zero order reaction is multiple step reaction. 55.5 +
18
6. Which of the following compounds produces
(3) On increasing temperature solubility of
an optically inactive compound on
gases decreases
hydrogenation ?
(4) KH ¯ solubility and lowest KH is for g.
A
CH3 H CH3 8. Tyndall effect of observed when :

H
(1) (2)
(1) The diameter of dispersed particles is much
smaller than the wavelength of light used
H CH3 (2) The diameter of dispersed particles is much

H CH3
(3) (4) larger than the wavelength of light used
(3) The diameter of dispersed particles is similar

Official Ans. by NTA (2) to the wavelength of light used
(4) The refractive index of dispersed phase is

me me
greater than that of the dispersion medium
H 2/Ni
Sol.
Optically Optically Sol. The diameter of disperseed particles is similar
active inactive to wavelength of light used.
2
9. Thermal power plants can lead to : 12. The Kjeldahl method of Nitrogen estimation fails
for which of the following reaction products ?
(1) Ozone layer depletion
(2) Eutrophication NO 2 CN
(3) Acid rain
(a) Sn/HCl (b) LiAlH4
(4) Blue baby syndrome
Sol. Thermal power plants lead to acid rain.

CH2CN
10. The electronic spectrum of [Ti(H2O)6]3+ shows a
single broad peak with a maximum at (c) (i) SnCl2 + HCl
20,300 cm–1. The crystal field stabilization energy (ii) H2O
(CFSE) of the complex ion, in kJ mol–1, is :
(1) 242.5
(2) 83.7
(3) 145.5
EN (d)
NH2
NaNO2
HCl
(1) a and d (2) c and d

(4) 97
(3) a, c and d (4) b and c
LL
Sol. CFSE = 0.4 D0
Sol. Kjeldahl method is used for N estimation But
20300 not given by 'Diazo' compounds
= 0.4 ×
83.7
A
= 97 kJ/mol
O
11. Aqua regia is used for dissolving noble metals
CH2 C N C H
(Au, Pt, etc). The gas evolved in this process
is : (i) SnCl2 + HCl NO
+
(ii) H2O give

(1) N2
(2) N2O3 Å
N N
(3) NO NH2
NaNO2 NO
+
(4) N2O5 + HCl give

Sol. Au + HNO3 + 4HCl ® HAuCl4 + NO + 2H2O
3
13. The mechanism of SN1 reaction is given as : 15. Glycerol is separated in soap industries by :
(1) Steam distillation
Y1 R – Y + X 1
R – X ® R X ® R ||X ®
Å 1 Å 1
(2) Differential extraction
Ion Solvent
pair separated ion (3) Distillation under reduced pressure
pair
(4) Fractional distillation
A student writes general characteristics based Official Ans. by NTA (3)

Sol. Glycerol is separated by reduced pressure
on the given mechanism as :
distillation in soap industries.
(a) The reaction is favoured by weak nucleophiles 16. Of the species, NO, NO+, NO2+, NO–, the one
(b) RÅ would be easily formed if the substituents with minimum bond strength is :
are bulky (1) NO2+ (2) NO + (3) NO (4) NO–
(c) The reaction is accompained by recemization Official Ans. by NTA (4)
(d) The reaction is favoured by non-polar Sol. Bond order of NO2+ = 2.5
solvents. Bond order of NO+ = 3
Which observations are correct ?
(1) b and d
(3) a, b and c
EN
(2) a and c
(4) a and b 17.
Bond order of NO = 2.5
Bond order of NO– = 2
Bond order a bond strength.
The atomic number of the element unnilennium
Official Ans. by NTA (2) is :
Sol. SN1 favours
(1) 119 (2) 108 (3) 102 (4) 109
(a) The reaction is favoured by weak nucleophiles
LL
(b) RÅ would be easily formed if the substituents
are bulky Sol. 1 0 9
(c) The reaction is accompained by recemization un nil enn
14. Which one of the following compounds Hence correct name ® unnilennium
possesses the most acidic hydrogen ? 18. An acidic buffer is obtained on mixing :
NºC CºN (1) 100 mL of 0.1 M CH3COOH and 200 mL

A
(1) (2) H3C–CºC–H of 0.1 M NaOH

H H
(2) 100 mL of 0.1 M CH3COOH and 100 mL
O O of 0.1 M NaOH
O
(3) (4) MeO H OMe (3) 100 mL of 0.1 M HCl and 200 mL of
H3C CH3 OMe
O 0.1 M CH3COONa
Official Ans. by NTA (4) (4) 100 mL of 0.1 M HCl and 200 mL of
0.1 M NaCl
Most acidic H
O O Official Ans. by NTA (3)
Sol.
H
m eO C C Ome HCl + CH 3COONa ® CH 3COOH + NaCl
C Sol.
10 mili mol
—
20 mili mol — —
10 mili mol 10 mili mol 10 mili mol

C Ome
O So finaly we get mixture of
CH3COOH + CH3COONa that will work like
Due to presence of 3 (–R) groups acidic buffer solution.
4
19. Let CNaCl and CBaSO be the conductances (in S) 22. The mole fraction of glucose (C6H12O6) in an
4
measured for saturated aqueous solutions of aqueous binary solution is 0.1. The mass
NaCl and BaSO4, respectively, at a temperature percentage of water in it, to the nearest integer,
T. Which of the following is false ? is ______.
(1) Ionic mobilities of ions from both salts Official Ans. by NTA (47)
increase with T Sol. XC H O = 0.1
6 12 6
(2) CNaCl >> CBaSO at a given T Let total mole is 1 mol then mole of glucose
4
will be 0.1 and mole of water will be 0.9
(3) CNaCl(T2) > CNaCl(T1) for T2 > T1
(4) CBaSO (T2) > CBaSO (T1) for T2 > T1 0.9 ´ 18
4 4 so mass % of water = ´ 100
Official Ans. by NTA (3) 0.1 ´ 180 + 0.9 ´ 18
Official Ans. by ALLEN (Bonus) = 47.36
Sol. Dissolution of BaSO 4 is an endothermic Ans : 47
reaction 50 on increasing temperature number 23. The photoelectric current from Na (work
of ions of BaSO4 decrease so it's conduction function, w0 = 2.3 eV) is stopped by the output
also decrease. voltage of the cell
20.
(2) Alcoholic HCN; NaOCl; ZnCl 2/HCl

(3) Br2/water; ZnCl2/HCl; NaOCl
EN
The antifertility drug 'Novestrol" can react with :
(1) Br2/water; ZnCl2/HCl; FeCl3
Pt(s)|H2(g, 1bar)|HCl(aq., pH = 1)|AgCl(s)|Ag(s)
The pH of aq. HCl required to stop the
photoelectric current from K(w0 = 2.25eV), all
other conditions remaining the same, is_____
(4) ZnCl2/HCl; FeCl3; Alcoholic HCN × 10–2 (to the nearest integer).
Official Ans. by NTA (1) RT
Given, 2.303 = 0.06V; E 0AgCl|Ag|Cl- = 0.22V
F
LL
H3C
C CH Official Ans. by ALLEN (142)
H
Sol. 1
H 2 ® H + + e1
H H 2
Sol.
HO e1 + AgCl (s) ® Ag(s) + Cl 1
A
1
Ethynylestradiol (novestrol) H 2 + AgCl(s) ® H (+aq ) + Ag(s) + Cl1( aq )
2
gives (1) Br2 + H2O test

(2) Lucas test with ZnCl2 + HCl é H + ù éCl1 ù
.06
(3) FeCl 3 test of phenolic group. E=e - 0
log ë û ë1 û
1
PH22
21. The volume strength of 8.9 M H2O2 solution
calculated at 273 K and 1 atm is _____.
(R=0.0821 L atm K–1 mol–1) (rounded off to the
E = 0.22 - .06 log
(10 )(10 )
-1 -1
nearest integer) 1
Official Ans. by NTA (100) 12

Sol. Volume strength of H2O2 at 1 atm E = 0.22 + .12 = .34 volt
273 kelvin = M × 11.2 = 8.9 × 11.2 = 99.68 Þ total energy of photon will be (for Na)
Ans : 100 = 2.3 + 0.34 = 2.64 eV
5
Þ stopping potential required for K

a
= 2.64 – 2.25 = 0.39 volt = 2r
2
.06 é H + ù é Cl - ù
E = e0 - log ë û 1ë û
r=
a
=
2a 1.414 ´ 405 ´ 10 -12
=
1 4 4
PH22 2 2
r = 143.16 × 10–12
as [H+] = [Cl!] so
25. The total number of monohalogenated organic
2 products in the following (including
éH+ ù
ë û stereoisomers) reaction is ______.
0.39 = 0.22 – .06 log 1
12 A (i)H 2 /Ni/ D
(simplest optically ¾¾¾¾¾
(ii) X / D
®
active alkene) 2
0.17 = + .12 pH
pH = 1.4166 Þ 1.42
24. An element with molar mass 2.7 × 10–2 kgmol–1
forms a cubic unit cell with edge length 405 pm.
If its density is 2.7 × 103 kgm–3,
element is approximately ____ × 10–12 m (to the
EN
the radius of the
Sol.
me
Simplest
O.A. Alkene
Ni/H2
me
Cl2
hv
nearest integer).
Cl *
Official Ans. by NTA (143) 2
LL
æ M ö
zç ÷ Cl
Sol. è NA ø *
d= 4
a3 *
1
æ 2.7 ´ 10 -2 ö
A
Cl
ç ÷
3 è 6 ´ 10 23 ø
2.7 ´ 10 = z
( ) 1
3
405 ´ 10 -12
Cl
Alter
2.7 ´ 10 3
=z
( 2.7 ´ 10 ) -2
Str. of Tri peptide
6 ´ 10 ( 4.05 ´ 10 )
3
23 -10
O O O
H 2N CH C NH CH C NH CH C OH
2.7 ´ 10 3 = z
( 2.7 ´ 10 ) -2 CH2 CH2 (CH2)4
6 ´ 10 23 ´ 66.43 ´ 10 -30 O C CH2 NH2
3.98 = z OH C O
z » 4 structure is fcc OH
6

(Held On Thursday 03rd SEPTEMBER, 2020) TIME : 3 PM to 6 PM
1. Among the statements (I – IV), the correct ones 3. Consider the hypothetical situation where the
are: azimuthal quantum number, l, takes values 0,
(I) Be has smaller atomic radius compared to 1, 2, …… n + 1, where n is the principal
Mg. quantum number. Then, the element with
(II) Be has higher ionization enthalpy than Al. atomic number :
(III) Charge/radius ratio of Be is greater than (1) 13 has a half-filled valence subshell
that of Al. (2) 9 is the first alkali metal
(IV) Both Be and Al form mainly covalent (3) 8 is the first noble gas
compounds. (4) 6 has a 2p-valence subshell
(1) (I), (II) and (IV) Official Ans. by NTA (1)
(2) (II), (III) and (IV) Official Ans. by ALLEN (2,3)
(3) (I), (II) and (III)
(4) (I), (III) and (IV
Sol. I, AN : Be < Mg
EN Sol. l = 0 to (n + 1)
n=1
l = 0, 1, 2
n=2
l = 0, 1, 2, 3
II IE : Be > Al 1s 1p 1d 2s 2p 2d 2f
(n + l) Þ
III Charge/radius ratio of Be w less than that of Al 1 2 3 2 3 4 5
IV Be, Al mainly form covalent compounds
n=3
LL
2. The strengths of 5.6 volume hydrogen peroxide
l = 0, 1, 2, 3, 4
(of density 1 g/mL) in terms of mass percentage
and molarity (M), respectively, are: 3s 3p 3d 3f 3g
(Take molar mass of hydrogen peroxide as 3 4 5 6 7
34 g/mol)
Now, in order to write electronic configuration,
(1) 1.7 and 0.25 (2) 1.7 and 0.5
A
we need to apply (n + l) rule

(3) 0.85 and 0.5 (4) 0.85 and 0.25
Energy order : 1s < 1p < 2s < 1d < 2p < 3s < 2d…
Sol. Volume strength = 11.2 × molarity Option 1) 13 : 1s21p62s21d3 is not half filled
Option 2) 9 : 1s21p62s1 is the first alkali
5.6
Þ molarity = = 0.5 metal because after losing
11.2
one electron, it will achieve
Assuming 1 litre solution;
mass of solution = 1000 ml × 1 g/ml = 1000 g first noble gas configuration
mass of solute = moles × molar mass Option 3) 8 : 1s21p6 is the first noble gas
= 0.5 mol × 34 g/mol because after 1p6 e– will
= 17 gm. enter 2s hence new period
17 Option 4) 6 : 1s2 1p4 has 1p valence

Þ mass% = ´ 100 = 1.7%
1000 subshell.
1
4. Three isomers A, B and C (mol. formula 5. 100 mL of 0.1 M HCl is taken in a beaker and
C8H11N) give the following results : to it 100 mL of 0.1 M NaOH is added in steps
of 2 mL and the pH is continuously measured.
R(product of A)
Which of the following graphs correctly depicts
A and C ¾¾¾¾¾ ® P + Q ¾¾¾¾¾¾ ®+
Diazotization (i) Hydrolysis
(ii) oxidation
(KMnO 4 + H + ) S(product of C) the change in pH?
R has lower boiling point than S

7
B ¾¾¾¾®
C 6 H 5SO 2 Cl alkali-insoluble product pH pH 7
(1) (2)
A, B and C, respectively are :
vol. of NaOH vol. of NaOH
NH2 CH2CH3 NH2
(1)
CH2CH3 7
CH3 CH2CH3
pH 7 pH
(3) (4)
NH2 CH2NHCH3 CH2CH3
(2) vol. of NaOH vol. of NaOH
CH2CH3 H2 N
(3)
H 2N
CH2CH3 NHCH2CH3
EN NH2
CH2CH3
6.
Sol. Steep rise in pH around the equivalence point
for titration of strong acid with strong base.
The incorrect statement(s) among (a) – (d)
CH2CH3 CH2NHCH3 NH2 regarding acid rain is (are) :
(4)
CH2CH3 (a) It can corrode water pipes.
NH2
(b) It can damage structures made up of stone.
LL
(c) It cannot cause respiratory ailments in animals.
Intramolecular (d) It is not harmful for trees

Å (1) H-Bonding
NH 2 NaNO N2 +
H /H2O OH (1) (c) and (d)
2
Sol. (2) KmnO 4 COOH
P (R)
(2) (a), (b) and (d)
(A)
A
(3) (c) only

(4) (a), (c) and (d)
Å
NH2 N2 OH Official Ans. by NTA (2)
Sol. (1) Acid rain corrodes water pipes resulting in the
COOH
Q (S) leaching of heavy of heavy metals such as iron,
(C) Intermolecular
H-Bonding lead and copper into the drinking water.
(2) Acid rain damages buildings and other
structures made of stone or metal.
Me
Ph–SO2Cl Ph–S–N (3) It causes respiratory aliments in human
Ph–CH2–NH–Me
CH2–Ph beings and animals.
Solid sulphonamicle
(not soluble is Aq.)
NaOH
(4) It is harmful for agriculture, trees and plants
as it wasshes down the nutrients needed for
its growth.
2
7. The five successive ionization enthalpies of an 9. The d-electron configuration of [Ru(en)3]Cl2

element are 800, 2427, 3658, 25024 and 32824 and [Fe(H2O)6]Cl2, respectively are :
4 2 6 0
kJ mol–1. The number of valence electrons in (1) t 2g e g and t2g eg
the element is : 6 0 6 0
(2) t 2 g e g and t 2 g e g
(1) 2 (2) 3 6 0 4 2
(3) 4 (4) 5
4 2 4 2
Sol. Let suppose element X Þ Sol. [Ru(en)3]Cl2 Ru Þ 4d series
en Þ chelating ligand
+ +2
IE1
X(g) ¾¾¾ IE 2 IE3 CN = 6, octahedral splitting hence laye splitting
800 ® X(g) ¾¾¾
2427 ® X(g) ¾¾¾
3658 ®
of d-subshell
+3
IE 4
+4
IE 5
+5 tg0
X(g) ¾¾¾® X(g) ¾¾¾
32824 ® X(g)
25024 Ru+2 Þ [Kr]4d65s0
8.
is high jump after IE3
So valence electrons are 3
EN
X+3 has stable inert gas configuration as there
A mixture of one mole each of H2, He and O2

[Fe(H2O)6]Cl2 Þ H2O Þ Weak filled ligand
Fe+2 Þ [Ar] 3d64s0
t2g6
less plitting
each are enclosed in a cylinder of volume V at CN = 6 octahedral splitting
temperature T. If the partial pressure of H2 is
LL
2 atm, the total pressure of the gases in the tg2
cylinder is :
(1) 14 atm (2) 22 atm
t2g4
(3) 6 atm (4) 38 atm
10. An ionic micelle is formed on the addition of :
A
excess water to liquid

Sol. According to Dalton's law of partial pressure
pi = x i × PT (1) Å
N N PF6
pi = partial pressure of the ith component H3 C CH3
xi = mole fraction of the ith component

pT = total pressure of mixture excess water to liquid
–
æ nH ö (2)
N N
Å SO 4
Þ 2 atm = ç n n
2
n ÷ ´ pT
è H2 + H e + O2 ø H 3C CH3
(3) liquid diethyl ether to aqueous NaCl solution

3 (4) sodium stearate to pure toluene
Þ pT = 2 atm × = 6 atm Official Ans. by NTA (2)
1
Sol. Correct Ans. is (2)
3
11. The decreasing order of reactivity of the Polar protic Bond
I
following compounds towards nucleophilic Å
Sol. t-BuOH 1, 2H! Å 1, 2H!
substitution (SN2) is : D H Shift Shift
CH2Cl CH2Cl D Å
NO2 7
H
more subtituted
NO2 Alkene (major)
(I) (II) 13. The increasing order of the reactivity of the

following compound in nucleophilic addition
CH2Cl CH2Cl reaction is :
Propanal, Benzaldehyde, Propanone, Butanone
NO2 O2 N NO2 (1) Butanone < Propanone < Benzaldehyde <

NO2 Propanal
(III) (IV) (2) Benzaldehyde < Butanone < Propanone <
(1) (IV) > (II) > (III) > (I)

(2) (II) > (III) > (IV) > (I)
EN Propanal
(3) Propanal < Propanone < Butanone <
Benzaldehyde
(3) (II) > (III) > (I) > (IV) (4) Benzaldehyde < Propanal < Propanone <
(4) (III) > (II) > (IV) > (I) Butanone
LL
Sol. Reactivity order of various carbonyl
Cl Cl Cl Cl
NO2
compounds ® Aldehydes > Ketones
Sol. > > >
NO2 NO2 NO2 O O
O2N O O
NO2
–I & –R less –I & –R Only 2 – I C–H Ph–C–H
A
2
rate of SN reaction
14. The incorrect statement is :
12. The major product in the following reaction is :
(1) In manganate and permanganate ions, the
I p-bonding takes place by overlap of p-orbitals
t-BuOH of oxygen and d-orbitals of manganese
Heat
(2) Manganate ion is green in colour and
permanganate ion in purple in colour
Ot-Bu
(1) (2) (3) Manganate and permanganate ions are
paramagnetic
(4) Manganate and permanganate ions are
(3) (4) tetrahedral
4
Sol. Option 1) Manganate Þ MnO24- , 15. The compound A in the following reaction is :
Permanganate Þ MnO-4 A ¾¾¾¾¾¾

(i) CH 3 MgBr / H 2 O
(ii) Conc. H 2 SO 4 / D
®
B ¾¾¾¾®(i) O3
(ii) Zn / H 2 O
C+D
O O
(i) Conc.KOH +
Mn Mn C COO K +
– – (ii) D
O –
O O O
O O
hybridisation hybridisation CH2OH
of Mn Þ d s of Mn Þ d s
3 3
CH3 O
Ba(OH) 2
Mn Þ D D
H3C–C=CH–C–CH3
5 2
3d 4s
O
After excitation CH3
(1) C6H5–C–CH
CH3
Mn Þ
p p
4p
EN MnO4
2–
O
(2) C6H 5–C–CH 2CH 3
O
– –
O OO O (3) C6H 5–CH2–C–CH 3
2p 2p
O
LL
2 × 2pp – 3dps (4) C6H 5–C–CH 3

2–
MnO4
p p p 4P
O
A
OH
2P 2P Sol.
(1) CH3MgBr/H2O H2SO4/D
Ph Ph Ph
(A) (B)
2 × 2Pp – 3dp O
O + Ph–C–H
1 × 2Pp – 4Pp O3/Zn
(D) (C)
(2) MnO42– Þ green
MnO4– Þ purple/violet
(3) Manganate contains 1 unpaired electron O
hence it is paramagnetic Ph–C–H Conc. Ph–COOK + Ph–CH2OH
NaOH
(cannizaro)
where as permanganetic contains no unpaired
electrons hence it is diamagnetic.
O
(4) Both have d3s hybridisation hence both have OH /D
!
O
tetrahedral geometry. Aldol
5
16. Consider the following molecules and 17. Consider the following reaction :
statements related to them :
O H O H c
(A) O H d H O CH3
C
O Hb O H a
O
H O H
Chromic
(B) O 'P'
C anhydride
O
The product 'P' gives positive ceric ammonium
(a) (B) is more likely to be crystalline than (A) nitrate test. This is because of the presence of
(b) (B) has higher boiling point than (A) which of these –OH group(s) ?
(c) (B) dissolves more readily than (A) in water (1) (c) and (d)
Identify the correct option from below : (2) (b) only

(3) (d) only
(1) only (a) is true (2) (a) and (c) are true
(4) (b) and (d)
(3) (b) and (c) are true (4) (a) and (b) are true
Official Ans. by ALLEN (2, 3 & 4)
EN Official Ans. by NTA (2)
Sol. Compound ¾¾¾¾

® Chromic
O
O
OH
anhydride O
H H O O
O O C H due to pressure of b
O
LL
C 18. Match the following drugs with their
O H
Sol. therapeutic actions :
O-salicylic acid (i) Ranitidine (a) Antidepressant
intra molecular H C O
H-bonding O O H (ii) Nardil (b) Antibiotic
p-salicylic acid (Phenelzine)
inter molecular H-bonding
A
(iii)Chloramphenicol (c) Antihistamine

(iv)Dimetane (d) Antacid
(a) B will be more crystalline due to more inter (Brompheniramine)
molecular interactions hence more efficient (e) Analgesic
packing. (1) (i)-(a); (ii)-(c); (iii)-(b); (iv)-(e)
(2) (i)-(e); (ii)-(a); (iii)-(c); (iv)-(d)
(b) B will have higher boiling point due to
(3) (i)-(d); (ii)-(a); (iii)-(b); (iv)-(c)
higher intermolecular interactions.
(4) (i)-(d); (ii)-(c); (iii)-(a); (iv)-(e)
(c) B will be more soluble in water than A as
B will have more extent of H-bonding in water
Sol. Raniticline ® Antacid
So all three statements are correct Nard1 ® Antidepressant
{Solubility date Þ O-salicylic acid = 2g/L Chloramphenicol ® Antibiotic
P-salicylic acid = 5g/L} Dimetane ® Antihistamine
6
3 21. An acidic solution of dichromate is electrolyzed

19. For the reaction 2A + 3B + C ® 3P, which
2 for 8 minutes using 2A current. As per the
statement is correct ? following equation
dn A dn B dn C Cr2 O27- + 14H + + 6e - ® 2Cr 3+ + 7H 2 O
(1) = =
dt dt dt The amount of Cr3+ obtained was 0.104 g. The
efficiency of the process(in%) is
dn A 2 dn B 3 dn C (Take : F = 96000 C, At. mass of chromium = 52)
(2) = =
dt 3 dt 4 dt ______.
dn A 3 dn B 3 dn C
(3) = =
dt 2 dt 4 dt ! æ 8 ´ 60 ´ 2 ö
Sol. Moles of e = ç ÷
è 96000 ø
dn A 2 dn B 4 dn C
(4) = = Using stoichiometry; theoritically
dt 3 dt 3 dt
n e! used n cr +3 produced
Official Ans. by NTA (4) =
6 2
Sol. For aA + bB ® cC;
2 8 ´ 60 ´ 2
-1 d[A] -1 d[B] 1 d[C]
a dt
=
b dt
=
c dt
-1 d[A] -1 d[B] -2 d[C] 1 d[p]

EN Þ n cr +3 produced =
=
´
6 96000
0.02
6
\ = = =
2 dt 3 dt 3 dt 3 dt Þ wt cr +3 theoritically produced
20. Complex A has a composition of H12O6Cl3Cr. æ 0.02 ö

´ 52 ÷ g
LL
= ç
If the complex on treatment with conc. H2SO4 è 6 ø
loses 13.5% of its original mass, the correct
molecular formula of A is : 0.104g
Þ % efficiency = ´ 100
æ 0.02 ´ 52 ö
[Given : atomic mass of Cr = 52 amu and ç 6 ÷g
è ø
Cl = 35 amu]
= 60%
A
(1) [Cr(H2O)5Cl]Cl2 · H2O 22. 6.023 × 1022

molecules are present in 10 g of
a substance 'x'. The molarity of a solution
(2) [Cr(H2O)3Cl3] · 3H2O
containing 5 g of substance 'x' in 2 L solution
(3) [Cr(H2O)4Cl2]Cl · 2H2O is _______ × 10 –3.
(4) [Cr(H2O)6]Cl3
number of molecules given mass
Official Ans. by NTA (3) moles = =
6 ´ 10 23 molar mass
Sol. % mass of water
10 ´ 6.023 ´ 10 23
x ´ 18 Þ molar mas = = 100g / mol
= ´ 100 = 13.5 6.023 ´ 10 22
(12 + 6 ´ 16 + 35 ´ 3 + 52)
moles of solute (5 / 100)
Þ molarity = =
265 ´ 13.5 volume of sol (l)
n
2
Þ x= ;2
18 ´ 100 = 0.025
7
23. The volume (in mL) of 0.1 N NaOH required Sol. Let molar mass of protein A = x g/mol
Let molar mass of protein B = y g/mol
to neutralise 10 mL of 0.1 N phosphinic acid
is _________ . æ 0.73 ö
ç ÷
pA = osmotic pressure of protein A = è x ø RT
Official Ans. by NTA (10) 0.25
Sol. H3PO2 + NaOH ® NaH2PO2 + H2O æ 1.65 ö

ç ÷
è y ø RT
pB = osmotic pressure of protein B =
n H3 PO2 reacted n NaOH reacted 1
=
1 1 pA = p B
æ 0.73 ö æ 1.65 ö
Þ ç ÷ RT = ç ÷ RT
è x ´ 0.25 ø è y ø
0.1 ´ 10
Þ = 0.1 ´ VNaOH
1 æxö 0.73
Þ ç ÷= = 1.769 @ 1.77
è y ø 0.25 ´ 1.65
Þ VNaOH = 10 ml.
25. The number of C = O groups present in a
24.
EN
If 250 cm3 of an aqueous solution containing
0.73 g of a protein A is isotonic with one litre of
another aqueous solution containing 1.65 g of a
tripeptide Asp – Glu – Lys is _________ .
Sol. Structure of Tri peptide Asp – Glu – Lys
O O O
protein B, at 298 K, the ratio of the molecular
H2N–CH–C–NH–Ch–C–Nh–Ch–C–OH
mases of A and B is _________ × 10–2 (to the nearest
CH2 CH2 (CH2)4
integer).
LL
O=C CH2 NH2
Official Ans. by NTA (177) OH C=O
OH
A
8

(Held On Friday 04th SEPTEMBER, 2020) TIME : 9 AM to 12 PM
1. On heating, lead(II) nitrate gives a brown gas 3. When neopentyl alcohol is heated with an acid,
(A). The gas (A) on cooling changes to a it slowly converted into an 85 : 15 mixture of
colourless solid/liquid (B). (B) on heating with alkenes A and B, respectively. What are these
NO changes to a blue solid (C). The oxidation alkenes ?
number of nitrogen in solid (C) is :
H3C
CH3 H3C CH2
(1) +5 (2) +2
(1) and
(3) +4 (4) +3
H3C H3C
D CH3
Sol. Pb (NO3)2 PbO + 2NO2 + 1 O2(g) CH3 CH2
Brown 2 CH3
gas (2) and
(A)
NO2 (g)
Cooling
N2O4 + NO
D
N2O4
(B)
N2O3
Blue Solid
EN (3)
CH2
H3C CH2
and
CH3
H3C CH3
(C) H3C CH2

O.S. of nitrogen in N2O3 is + 3
CH3
N2O3 2x + 3 (–2) = 0 H3C CH3
LL
H3C
x=+3 (4) and
H3C CH2
2. Which of the following will react with
CHCl3 + alc. KOH ? Official Ans. by NTA (4)
(1) Adenine and lysine
(2) Adenine and thymine
A
.. H+
(3) Adenine and proline OH
Sol. Å
(4) Thymine and proline
Sol. Adenine and lysine Both have primary amine
react with CHCl3 + alc. KOH
NH2 Å
O
H2N C –H+
N H
(A) H
C N
NH2 HC
C CH –H
+
Lysine
N N
H
Adenine (B)
1
4. Among statements (a) -(d), the correct ones

Sol. E ocell = 0.34 - ( -0.76)
are :
(a) Lime stone is decomposed to CaO during = 1.10 volt
the extraction of iron from its oxides.
(b) In the extraction of silver, silver is extracted If Eext > 1.10 volt
as an anionic complex.
Cu ® Anode
(c) Nickel is purified by Mond's process.
(d) Zr and Ti are purified by Van Arkel method. Zn ® Cathode
(1) (c) and (d) only
(2) (a), (c) and (d) only If Eext = 1.10 volt
(3) (b), (c) and (d) only
(4) (a), (b), (c) and (d) Zn ® Anode
D
Cu ® Cathode
Sol. (a) CaCO3 ¾¾ ® CaO + CO 2 {In Blast furnace}
lime stone 6. The IUPAC name of the following compound
(b) Ag form cyanide complex [Ag(CN) 2 ]– is :
during cyaride process
!
Ag / Ag2 S + CN ® [Ag(CN)2 ]
(c) Ni is purified by mond's process
-
EN CH3 O
C – OH
(d) Zr and Ti are purified by van arkel method

Br
All (a), (b), (c), (d) are correct statements
Thus correct option is (4) (1) 4-Bromo-2-methylcyclopentane carboxylic
LL
Eext acid
(2) 5-Bromo-3-methylcyclopentanoic acid
Zn rod Cu rod (3) 3-Bromo-5-methylcyclopentane carboxylic

5. –ve +ve acid
1M Salt 1M
A
ZnSO4 Bridge CuSo4

soln. soln. (4) 3-Bromo-5-methylcyclopentanoic acid
E o Cu 2 + |Cu = +0.34V Official Ans. by NTA (1)

E o Zn 2 + |Zn = -0.76V
Identify the incorrect statement from the CH3 O
Sol.
options below for the above cell : 2 C – OH
(1) If Eext > 1.1 V, Zn dissolves at Zn 3 1
electrode and Cu deposits at Cu electrode
4 5
(2) If Eext > 1.1 V, e– flows from Cu to Zn Br
(3) If Eext = 1.1 V, no flow of e – or current
occurs
(4) If Eext < 1.1 V, Zn dissolves at anode and 4-bromo-2-methyl cyclopentane carboxylic
Cu deposits at cathode Acid
2
7. For the equilibrium A B , the variation of the Sol.

rate of the forward (a) and reverse (b) reaction Cl Cl
(A) (B) (C) CH3–CH–CH3 (D) CH3–CH–CH2–NO2
with time is given by
Cl Cl
OMe
Rate of reaction Rate of reaction Rate of reaction Rate of reaction
AgNO3 AgNO3 AgNO3

a AgNO3
Å Å
equilibrium Å Å
CH3–CH–CH3 CH3–CH–CH2–NO2
(1) b
OMe (2° Cation) 2° Cation and
Time (–I of NO2)
Aromatic Aromatic + OMe
increase stability
\ Stability Cation B > A > C > D
a
equilibrium 9. An organic compound (A) (molecular formula
(2) b
Time C6H12O2) was hydrolysed with dil. H2SO4 to
give a carboxylic acid (B) and an alcohol (C).
'C' give white turbidity immediately when
a
treated with anhydrous ZnCl2 and conc. HCl.
equilibrium
(3) b The organic compound (A) is :
(4)
a
b
Time
equilibrium
EN (1)
O
O
O
Time (2)
O
Sol. at equilibrium O
LL
(3)
ra = rb O
8. The decreasing order of reactivity of the O
following organic molecules towards AgNO3
(4) O
solution is :
A
Cl Cl Official Ans. by NTA (1)
(A) (A) OMe

Sol. O
CH3CHCH3 CH3CHCH2NO2 OH
O
Cl Cl dil OH +
(C) (D) H2SO4
Hydrolysis
(A) (B) (C)
(1) (A) > (B) > (D) > (C)
Cl
,H
(2) (A) > (B) > (C) > (D)

2
Cl
Zn
(3) (C) > (D) > (A) > (B)

(4) (B) > (A) > (C) > (D) Cl
White turbidity
immediately
3
10. Match the following : 13. [P] on treatment with Br 2 /FeBr 3 in CCl 4
produced a single isomer C 8 H 7 O 2 Br while
(i) Foam (a) smoke
heating [P] with sodalime gave toluene.
(ii) Gel (b) cell fluid
The compound [P] is :
(iii) Aerosol (c) jellies
COOH
CH2COOH
(iv) Emulsion (d) rubber
(e) froth (1) (2)
(f) milk CH3
(1) (i)-(b), (ii)-(c), (iii)-(e), (iv)-(d) COOH
(2) (i)-(d), (ii)-(b), (iii)-(e), (iv)-(f) COOH
CH3
(3) (i)-(e), (ii)-(c), (iii)-(a), (iv)-(f)
(3) (4)
(4) (i)-(d), (ii)-(b), (iii)-(a), (iv)-(e)
Official Ans. by NTA (3) CH3
Sol. Foam - Froth Official Ans. by NTA (4)
Gel ® Jellies CH3 CH3
Br
Aerosol ® Smoke
Sol ® Cell fluids
Solid sol ® rubber
EN Sol.
COOH
Br2
Br2/FeBr3
COOH
(Only single product)
11. The elements with atomic numbers 101 and
104 belong to, respectively : Sodalime CH3
(1) Group 11 and Group 4 D
LL
(2) Actinoids and Group 4
(3) Actinoids and Group 6
(4) Group 6 and Actinoids 14. The number of isomers possible for
Official Ans. by NTA (2) [Pt(en)(NO2)2] is :
Sol. Element with atomic no. 101 is an Actinoid (1) 3 (2) 2
element.
(3) 1 (4) 4
A
12. On combustion Li, Na and K in excess of air,

the major oxides formed, respectively, are : Sol. [Pt (en) (NO2)2] Þ does not show G.I. as well
(1) Li2O, Na2O and K2O2 as optical isomerism.
(2) Li2O, Na2O2 and K2O
NO2– 2+ N
(3) Li2O, Na2O2 and KO2
Pt
(4) Li2O2, Na2O2 and K2O2 NO2– N
Sol. Li + O2 ® Li2O (Major Oxides) This complex will have three linkage isomers
excess as follows :-
Na + '' ® Na2O2 ('') [Pt (en) (NO2)2] I
K + '' ® KO2 ('') [Pt (en) (NO2)(ONO)] II

[Pt (en) (ONO)2] III
4
15. The ionic radii of O2–, F–, Na+ and Mg2+ are in the Sol. From the given graph, potential energy of A-B
order : molecule is minimum.
(1) F– > O2– > Na+ > Mg2+ Thus A-B bond is most stable and have
(2) Mg2+ > Na+ > F– > O2– strongest bond amongst these.
(3) O2– > F– > Mg2+ > Na+ B ® Most electronegative
(4) O2– > F– > Na+ > Mg2+
Official Ans. by NTA (4) D ® Least electronegative
A-B ® Shortest bond length
A-B ® Largest bond enthalpy
-2 - + 2+
Sol. O F Na Mg Therefore correct option is (3).
z 8 9 11 12
18. What are the functional groups present in the
-
e 10 10 10 10 structure of maltose ?
z
0.8 0.9 1.1 1.2 (1) One ketal and one hemiketal
e
z (2) One acetal and one hemiacetal
as ratio increases size decreases.
e
Thus correct ionic radii order is
O–2 > F– > Na+ > Mg2+
Therefore correct option is (4)
16. The region in the electromagnetic spectrum
EN Sol.
(3) Two acetals
(4) One acetal and one ketal
where the Balmer series lines appear is CH2OH

CH2OH
(1) Visible H O H O H
H H
(2) Microwave H
LL
OH H O OH H
(3) Ultraviolet HO OH
(4) Infrared H OH Maltose H OH
Hemiacetal
Sol. Balmer series give visible lines For H-atom 19. For one mole of an ideal gas, which of these
17. The intermolecular potential energy for the statements must be true ?
molecules A, B, C and D given below suggests
A
(a) U and H each depends only on temperature

that :
(b) Compressibility factor z is not equal to 1
Interatomic distance (pm)
(c) CP,m – CV,m = R
50 100 150
0 ××
–100 × (d) dU = CVdT for any process
× ×
×
Potential –200 × ×
× × (1) (a), (c) and (d) (2) (b), (c) and (d)
Energy –300 × ××
–1
(kJ mol ) –400 A–D (3) (c) and (d) (4) (a) and (c)
–500 A – A A – C
A–B Official Ans. by NTA (1)
–600
Sol. For ideal Gas
# U = f(T), H = f(T)
(1) D is more electronegative than other atoms
(2) A-D has the shortest bond length #Z=1
(3) A-B has the stiffest bone # CP – C V = R
(4) A–A has the largest bond enthalpy
Official Ans. by NTA (3) # dU = CV dT
5
20. The pair in which both the species have the same 22. The number of chiral centres present in [B] is
magnetic moment (spin only) is : _______.
(1) [Mn(H2O)6]2+ and [Cr(H2O)]2+
(2) [Cr(H2O)6]2+ and [CoCl4]2– CH–C º N (i) C2H5MgBr
+
[A]
(3) [Cr(H2O)6]2+ and [Fe(H2O)6]2+ CH3 (ii) H3O
(4) [Co(OH)4]2– and [Fe(NH3)6]2+
Official Ans. by NTA (3) (i) CH MgBr
¾¾¾¾¾ 3
(ii) H O
®[B]
2

Sol. Complex e– configuration no. of unpaired e–
2+ Sol.
[Mn(H2O)6] eg 5
WFL t2g
[Cr(H2O)6]2+ eg 4 O
WFL (i) C2H5MgBr
CH–CºN ¾¾¾¾
+ ® CH–C–C2H 5
(ii) H3O
[COCl4] 2–
Tetrahedral
[Fe(H2O)6]
WFL
2+
e
eg
t2
t 2g
EN 3
4
CH3 CH3
(i) CH 3MgBr
(ii) H 2O
OH
[Co(OH)4]2– t2
3 CH–C–C2H 5
WFL e
CH3 CH3
Tetrahedral 4
LL
[Fe(NH3 )6 ]2+
23. A 20.0 mL solution containing 0.2 g impure

Thus complex [Cr(H2O)6]2+ and [Fe(H2O)6]2+ H2O2 reacts completely with 0.316 g of KMnO4
have same no. of unpaired e– and hence same in acid solution. The purity of H2O2 (in %) is
magnetic moment (spin only). ______ (mol. wt. of H2O 2 = 34; mol. wt. of
A
21. The mass of ammonia in grams produced when KMnO4 = 158)

2.8 kg of dinitrogen quantitatively reacts with
1 kg of dihydrogen is ________.
Official Ans. by NTA (3400) Sol. Eq of H2O2 = Eq of KMnO4
Sol. N2 + 3H2 ® 2NH3
0.316
2.8 1 x×2= ´5
K mol K mol 158
28 2
x = 5 × 10–3 mol
= 0.1 K mol 0.5 K mol —
0 0.2 K mol 0.2 K mol m H 2O2 = 5 ´ 10 -3 ´ 34 = 0.17gm
mass (NH3) = 0.2 × 17 Kg
0.17
= 3.4 Kg %H 2 O2 = ´ 100 = 85
0.2
= 3400 gm
6
24. If 75% of a first order reaction was completed in 25. At 300 K, the vapour pressure of a solution
90 minutes, 60% of the same reaction would be containing 1 mole of n-hexane and 3 moles of
completed in approximately (in minutes) n-heptane is 550 mm of Hg. At the same
________. temperature, if one more mole of n-heptane is
added to this solution, the vapour pressure of
(Take : log 2 = 0.30; log 2.5 = 0.40)
the solution increases by 10 mm of Hg. What
Official Ans. by NTA (60) is the vapour pressure in mm Hg of n-heptane
in its pure state _________ ?
ln 2
Sol. t 0.75 = 2 ´ = 90
k Official Ans. by NTA (600)
1 3
k=
ln 2
min -1 Sol. 550 = PAo ´ + PBo ´
45 4 4
1 2200 = PAo + 3PBo .....(i)

kt = ln = ln 2.5
1 - 0.6
2800 = PAo + 4PBo ....(ii)
ln 2
45
´ t = ln 2.5
log 2.5 0.4

EN 1
560 = PAo ´ + PBo ´
5
4
5
t = 45 ´ = 45 ´ = 60 min PBo = 600, PAo = 400

log 2 0.3
LL
A
7

(Held On Friday 04th SEPTEMBER, 2020) TIME : 3 PM to 6 PM
1. If the equilibrium constant for A B + C is 4. The crystal Field stabilization Energy (CFSE)
of [CoF3(H2O)3](D0 < P) is :-
K (1) and that of B + C P is K eq , the
(2)
eq
equilibrium constant for A P is :- (1) –0.8 D0 (2) –0.4 D0 + P

(3) –0.8 D0 + 2P (4) –0.4 D0
(2) (1) (1) (2)
(1) K eq – K eq (2) K eq K eq
(1) (2)
(3) K eq / K eq (4) K eq + K eq
(1) (2) Official Ans. by ALLEN (2, 4)
Sol. [CoF3(H2O)3] D0 < P
Means all ligands behaves as weak field ligands
[B][C]
Sol. A B+C K (1)
eq = .....(1) eg
[A] 3+ +0.6D0
Co
[P] –0.4D0
B + C P K (2)
For
A P K eq =
eq =
[P]
[B][C] EN .....(2)
= [ –0.4 ´ 4 + 0.6 ´ 2 ] D 0
= [ –1.6 + 1.2 ] D 0
t2g
[A]
= [ –0.4 D 0 ]
Multiplying equation (1) & (2)
5. The mechanism of action of "Terfenadine"
LL
[P] (Seldane) is :-
K ´K
(1)
eq
(2)
eq = = K eq
[A]
(1) Activates the histamine receptor
2. Five moles of an ideal gas at 1 bar and 298 K
(2) Inhibits the secretion of histamine
is expanded into vacuum to double the volume.
The work done is :- (3) Inhibits the action of histamine receptor
(4) Helps in the secretion of histamine
(1) CV (T2 – T1 ) (2) –RT ln V2/V1
A

(3) –RT(V2 – V1) (4) zero
Sol. Seldane is an antihistamine drugs it inhibits the
Official Ans. by NTA (4) action of histamine receptor.
Sol. As the expansion is done in vaccum that is in
absence of p ext so 6. An alkaline earth metal 'M' readily forms water
soluble sulphate and water insoluble
W = zero
hydroxide. Its oxide MO is very stable to heat
3. The process that is NOT endothermic in nature
is :- and does not have rock-salt structure. M is :-
(1) Ca (2) Be (3) Mg (4) Sr
(1) Ar(g) + e ® Ar(g) (2) H (g) + e ® H (g)
– – – –

(3) Na (g) ® Na
+
(g) +e –
(4) O
–
(g) +e ®O
– 2–
(g)
Sol. [Be]
BeSO4 is water soluble
Sol. H(g) + e– ® H– is exothermic Be(OH)2 is water insoluble
rest of all endothermic process. BeO is stable to heat
1
7. The reaction in which the hybridisation of the NH 2 Cl Cl
underlined atom is affected is :-
(i) NaNO2 + HCl Cl2/hn
+ Sol.
(1) NH3 ¾¾
H
® (ii) Cu2Cl2 + HCl
(2) XeF4 + SbF5 ® CH3 CH3 CH2–Cl
(3) H 2 SO4 + NaCl ¾¾¾

420 K
®
Cl CH2–CH2 Cl
(4) H 3 PO2 ¾¾¾¾¾¾
Disproportionation
® Na-Dry
ether
10. A sample of red ink (a colloidal suspension) is
XeF4 + SbF5 ® [ XeF3 ] [SbF6 ]
+ –
Sol. prepared by mixing eosin dye, egg white,
sp3d2 sp3d sp3d sp3d2 HCHO and water. The component which
8. The one that can exhibit highest paramagnetic ensures stability of the ink sample is :-
behaviour among the following is :- (1) HCHO (2) Eosin dye
gly = glycinato; bpy = 2, 2'-bipyridine (3) Egg white (4) Water
(1) [Pd(gly)2] Official Ans. by NTA (3)
(2) [Ti(NH3)6]3+
(3) [Co(OX)2(OH)2]– (D0 > P)
(4) [Fe(en)(bpy)(NH3)2]2+
Sol. [Co(OX)2(OH)2]–
7
D0 > P [S.F.L]
2
EN 11. The processes of calcination and roasting in
metallurgical industries, respectively, can lead
to :-
(1) Global warming and acid rain
Co = 3d 4s (2) Photochemical smog and ozone layer
+5 4 0
Co = 3d 4s depletion
(3) Global warming and photochemical smog
It has highest number of unpaired e–s. so it is
LL
(4) Photochemical smog and global warming
most paramagnetic.
9. In the following reaction sequence, [C] is :-
Sol. Due to industrial process SO2 gas is released
NH2 which is responsible for acid rain & global
(i) NaNO2 + HCl, 0-5 °C
warming.
[A]
(ii) Cu2Cl 2 + HCl 12. Which of the following compounds will form
A
the precipitate with aq. AgNO3 solution most

CH3
readily ?
Cl2 Na+dry ether
hn
[B] [C] Br
(Major Product)
N
CH2 CH2 (1) O Br (2)
(1)
Cl Cl
(2) CH3 CH3 Br

N
N Br
(3) Cl CH2–CH2 Cl (3) (4)
OCH3
(4) Cl CH2 CH2–Cl
2
Sol. R – x + aq.AgNO3 ¾¾¾

R.D.S
® R Å + Agx (1) 15. The major product [R] in the following sequence
(PPT)
of reactions is :-
So rate of P.P.T formation of Agx depend's
on stability of carbocation (R+)
(i) LiNH2/ether
In given question formed carbocation will be HC ºCH (ii) H3C
[P]
CH–Br
Å N Å (CH3)2CH
N Å
N
Å
O (i) HgSO4/H2SO4 Conc.H2SO4
Ph [Q] [R]
O–CH3 (ii) NaBH4 D
(a) (b) (c) (d)

H3 C
Most stable carbocation is (b) so C=CH–CH3
(1)
Br (CH3)2CH
N
give fastest P.P.T of AgBr with aq AgNO3 H3C
(2) C=C(CH3)2
H3CCH2
13. The molecule in which hybrid MOs involve
only one d-orbital of the central atom is :-
(1) [Ni(CN)4
(3) BrF5
]2– (2) [CrF6
(4) XeF4
EN
]3– (3)
H2C
C–CH2–CH3
CH(CH3)2
Official Ans. by NTA (1) H3C

Sol. [Ni(CN)4]2– (4) CH–CH=CH2
(CH3)2CH
LL
dsp2
hybridisation.
14. Among the following compounds, which one
has the shortest C—Cl bond ?
(i) LiNH2/ether
Sol. CHºCH CH3–CH–CºCH
(ii) Br
H3C
Cl
(1) H3C–Cl (2) H3C (i) HgSO4/H2SO4
CH3
A
(ii) NaBH4
OH
CH3
Cl CH
CH HC Cl
(3) (4)
CH 2 CH 2 H /D
+
Official Ans. by NTA (3) CH3 CH2–CH3

Cl
C
Sol.
CH
CH2
} CH3 CH3
(major)
In option (3) C—Cl bond is shortest due to Now :- (i) HgSO4/dil.H2SO4
resonance of lone pair of –Cl.
(ii) NaBH4
Due to resonance C—Cl bond acquire partial
is convert triple bond into ketone and formed
double bond character. ketone is reduced by NaBH4 and convert into
Hence C—Cl bond length is least. Alcohol.
3
16. The incorrect statement(s) among (a) - (c) is CH3
(are) :-
Sol. CH3–CH2–CH–CH 2–OCH 2–CH3
(a) W(VI) is more stable than Cr(VI).
HI/D
(b) in the presence of HCl, permanganate
titrations provide satisfactory results. CH3
Å
(c) some lanthanoid oxides can be used as CH3–CH2–CH–CH 2—O—CH2–CH 3
phosphors. SN2 H
(1) (a) and (b) only (2) (a) only SN2
I
–
Prefer to
(3) (b) and (c) only (4) (b) only less hindrance
Official Ans. by NTA (4) CH3
Sol. KMnO4 will not give satisfactory result when CH3–CH2–CH–CH 2–OH + CH3–CH2–I
it is titrated by HCl. [A] H2SO4/ D
17. 250 mL of a waste solution obtained from the CH3
workshop of a goldsmith contains 0.1 M AgNO3
CH3–CH=C
and 0.1 M AuCl. The solution was electrolyzed
at 2 V by passing a current of 1 A for 15 minutes. CH3
(major)
The metal/metals electrodeposited will be :-
19. The major product [C] of the following reaction
(E 0
Ag + /Ag
= 0.80V, E 0Au + /Au = 1.69V ) EN sequence will be :-
(1) only silver
(i) NaBH4
(2) only gold CH2=CH–CHO [A] [B]
(ii) SOCl2 Anhy.
(3) silver and gold in equal mass proportion AlCl3
(4) silver and gold in proportion to their atomic DBr
[C]
weights
Official Ans. by NTA (4) (1) D
Sol. As voltage is '2V' so both Ag + & Au + will Br
LL
reduce and their equal gm equivalent will
(2) Br
reduce so D
gmeq Ag = gmeq of Au Br
Wt Ag Wt Au
= (3) D
E qwt E qwt
Ag Au
Br
A
wt Ag E qwt At wt Ag
So = = Ag
wt Au E qwt Au Atwt Au (4)

18. The major product [B] in the following reactions D
is :- Official Ans. by NTA (3)
CH3
O
CH3–CH2–CH–CH 2–OCH2–CH3 (i) NaBH 4
Sol. CH2=CH–C–H (ii) SOCl2 CH2=CH–CH2–Cl
HI H2SO4
Heat
[A] alcohol D
[B] (A)
CH3 + AlCl3
(1) CH3–CH 2–C=CH2
(2) CH 3–CH2–CH=CH–CH3 CH2–CH=CH2
(3) CH2=CH2
Br D
CH3 DBr
CH–CH2–CH2
(4) CH3–CH=C–CH 3
4
20. The shortest wavelength of H atom is the Lyman 21. A 100 mL solution was made by adding 1.43 g of
series is l 1 . The longest wavelength in the Na2CO3·xH2O. The normality of the solution is 0.1
Balmer series of He+ is :- N. The value of x is _______.
(The atomic mass of Na is 23g/mol) :-

5l1 27l1
(1) (2)
9 5 Official Ans. by NTA (10)
Sol. Molar mass of Na2CO3·xH2O

9l1 36l1
(3) (4)
5 5 Þ 23 × 2 + 12 + 48 + 18x
Official Ans. by NTA (3) Þ 46 + 12 + 48 + 18x
hc Þ (106 + 18x)
Sol. As we know DE =
l
M
Eqwt = = (53 + 9x)
hc 2
So l= for l minimum i.e.
DE
shortest; DE = maximum
for Lyman series n = 1 & for DEmax
Transition must be form n = ¥ to n = 1
EN As nfactor in dissolution will be determined from net
cationic or anionic charge; which is 2 so
Eqwt =
M
= 53 + 9x
2
1 æ 1 1 ö
So = R H Z2 ç 2 – 2 ÷
l è n1 n 2 ø wt 1.43
=
LL
Gmeq =
Eqwt 53 + 9x
1
= R H Z 2 (1 – 0 )
l
Gmeq
1 1 Normality = V
= R ´ (1)2 Þl1 = litre
l R
A
For longest wavelength DE = minimum for

1.43
Balmer series n = 3 to n = 2 will have DE Normality = 0.1 =
53 + 9x
minimum 0.1
for He+ Z = 2
As volume = 100 ml
1 2æ 1 1 ö
So l = R H ´ Z ç n 2 – n 2 ÷
2 è 1 2 ø = 0.1 Litre
1 æ1 1ö
= RH ´ 4 ç – ÷ 1.43
l2 è4 9ø So 10–2 =
53 + 9x
1 5 53 + 9x = 143
= RH ´
l2 9
9x = 90
9
l 2 = l1 ´ x = 10.00
5
5
22. The osmotic pressure of a solution of NaCl is 0.10 23. The number of chiral centres present in
atm and that of a glucose solution is 0.20 atm. The threonine is _________.
osmotic pressure of a solution formed by mixing
1 L of the sodium chloride solution with 2 L of the Official Ans. by NTA (2)
glucose solution is x × 10–3 atm. x is _____. Sol. Structure of Threonine is :
(nearest integer) :-
Official Ans. by NTA (167) COOH
NH2 * H
Sol. Osmotic pressure = p = i × C × RT
For NaCl i = 2 so *
CH –OH S. 2-chiral center is present
pNaCl = i × CNaCl × RT CNaCl = conc. of NaCl CH3
0.1 = 2 × CNaCl × RT
24. Consider the following equations :
0.05
CNaCl = Cglucose= conc. of glucose 2 Fe2+ + H2O2 ® x A + y B
RT
For glucose i = 1 so (in basic medium)
pGlucose = i × Cglucose × RT
2MnO4– + 6H + + 5H 2O2 ® x' C + y' D + z' E
0.2 = 1 × Cglucose × RT
CGlucose =
0.2
RT
hNaCl = No. of moles NaCl
hNaCl in 1 L = CNaCl× VLitre
0.05
EN (in acidic medium)
The sum of the stoichiometric coefficients
x, y, x', y' and z' for products A, B, C, D and
E, respectively, is ___________.
= hglucose= No. of moles glucose
RT Official Ans. by NTA (19)
hglucose in 2 L = Cglucose × VLitre
Sol. éë Fe 2+ ® Fe 3+ + e – ùû ´ 2
LL
0.4
=
RT H 2 O 2 + 2e – ® 2HO !
!
VTotal = 1 + 2 = 3L 2Fe 2+ + H 2 O 2 ® 2Fe 3+ + 2HO (q w)
0.05 x=2 y=2

so Final conc. NaCl =
3RT
éë8H + + MnO 4– + 5e – ® Mn 2+ + 4H 2O ùû ´ 2
A
0.4
Final conc. glucose =
3RT
éë H 2 O2 ® O2(g) + 2H + + 2e – ùû ´ 5
pTotal = pNaCl + pglucose
Þ 16H + + 2MnO4– + 5H 2O2
= éë i ´ C NaCl + C glu cos e ùû ´ RT
® 2Mn 2+ + 8H 2 O + 5O 2(g) + 10H +
æ 2 ´ 0.05 0.4 ö
= ç + ´ RT
è 3RT 3RT ÷ø Þ 6H + + 2MnO4– + 5H 2O2
0.5 ® 2Mn 2+ + 8H 2 O + 5O 2(g)

= atm
3
= 0.1666 atm So x' = 2 y' = 8 z' = 5
= 166.6 × 10–3 atm so x + y + x' + y' + z'

Þ 167.00 × 10–3 atm Þ 2+2+2+8+5
so x = 167.00 Þ 19
6
25. The number of molecules with energy greater

than the threshold energy for a reaction
increases five fold by a rise of temperature from
27 °C to 42 °C. Its energy of activation in
J/mol is _________. (Take ln 5 = 1.6094;
R = 8.314 J mol–1K–1)
Official Ans. by ALLEN
(84297.47 or 84297.48)
Sol. T1 = 300K T2 = 315K
As per question K T2 = 5K T1 as molecules

activated are increased five times so k will
increases 5 times
Now
æ KT
ln ç 2
ç KT
è 1
ö Ea æ 1 1 ö
÷=
ø
–
÷ R çè T1 T2 ÷ø
EN
Ea æ 15 ö
ln 5 =
R çè 300 ´ 315 ÷ø
LL
1.6094 ´ 8.314 ´ 300 ´ 315
So Ea =
15
Ea = 84297.47 Joules/mole
A
7

(Held On Saturday 05th SEPTEMBER, 2020) TIME : 9 AM to 12 PM
1. The equation that represents the water-gas shift 3. The values of the crystal field stabilization
reaction is : energies for a high spin d 6 metal ion in
octahedral and tetrahedral fields, respectively,
(1) CO(g) + H2O(g) ¾¾¾®
673K
Catalyst CO2(g) + H2(g)
are :
(2) CH4(g) + H2O(g) ¾¾¾
1270 K
Ni
® CO(g) + 3 H2(g) (1) –0.4 D0 and –0.27 Dt
(3) C(s) + H2O(g) ¾¾¾® CO(g) + H2(g)

1270K
(2) –1.6 D0 and –0.4 Dt
(4) 2C(s) + O2(g) + 4N2(g) ¾¾¾

1273K
® 2CO(g) + 4 N2(g) (3) –0.4 D0 and –0.6 Dt
(4) –2.4 D0 and –0.6 Dt
Sol. (1) Water gas shift reaction
CO(g) + H 2 O(g) ¾¾¾
673K
® CO 2(g) + H 2(g)
catalyst
1270 K
Ni
EN
(2) Water gas is produced by this reaction.
CH 4(g) + H 2 O (g) ¾¾¾ ® CO (g) + 3H 2(g)

Sol. For high spin octahedral field
d6
+0.6D0
D0
(3) Water gas is produced by this reaction –0.4D0
C (s) + H 2 O (g) ¾¾ ¾® CO (g) + H 2(g)

1270 K
LL
CFSE = (4) (–0.4D0) + 2(0.6 D0) = – 0.4 D0
(4) producer gas is produced by this reaction.
For high spin tetrahedral field
2C(s) + O2(g) + 4N2(g) ¾¾¾
1270K
® 2CO(g) + 4N2(g)
2. Consider the following reaction

+0.4Dt
N2O4(g) 2NO2(g) ; DH0 = +58 kJ d6 Dt
–0.6Dt
A
For each of the following cases (a, b), the

direction in which the equilibrium shifts is:
(a) Temperature is decreased CFSE = 3(–0.6Dt) + 3(0.4 Dt) = – 0.6 Dt
(b) Pressure is increased by adding N 2 at 4. Which of the following is not an essential
constant T
amino acid :
(1) (a) towards reactant, (b) no change
(1) Valine
(2) (a) towards product, (b) towards reactant
(3) (a) towards product, (b) no change (2) Leucine
(4) (a) towards reactant, (b) towards product (3) Lysine
(4) Tyrosine
Sol. DHo > 0 T¯ equation shifts back ward.
N2 is treated as inert gas in this case hence no
effect on equilibrium. Sol. Tyrosine is not an essential amino acid.
1
5. In the following reaction sequence the major 6. The increasing order of the acidity of the
products A and B are : a-hydrogen of the following compounds is :
O O O O O O
anhydrous 1. Zn – Hg/HCl Ph Ph OMe NMe2
+ O A B
AlCl 3 2. H3PO4 (A) (B) (C) (D)
O (1) (C) < (A) < (B) < (D)
O (2) (B) < (C) < (A) < (D)
(3) (A) < (C) < (D) < (B)
A= ;B= (4) (D) < (C) < (A) < (B)
(1)
CO2H Official Ans. by NTA (4)
O
O Sol. D<C<A<B
More cross
(2) A = ;B=
O Cross conjugation
O conjugation
CO2H !
Me 1
H2 C N H2C O Me
O Me
H H
O
(3)
A=
CO2H
O
;B= EN
O
least
stable
anion
ß
(Least Acidic)
!
CH2
H
Ph–C–CH–C–Ph
O
!
most
ß
O
stable Anion
(more Acidic)
A= ;B= 7. An Ellingham diagram provides information
(4)
CO2H about :
O
Official Ans. by NTA (1) (1) the pressure dependence of the standard
LL
O O electrode potentials of reduction reactions
Sol. !
O + AlCl3
+
O AlCl3 involved in the extraction of metals.
(2) the kinetics of the reduction process.
O O
O (3) the temperature dependence of the standard
H O
+ Gibbs energies of formation of some metal
!
+ OAlCl 3 oxides.
A
+
! O
AlCl3 O O (4) the conditions of pH and potential under
H + O which a species is thermodynamically
Zn-Hg / HCl stable.
(Clemension reduction) Official Ans. by NTA (3)
HO
O Sol. Ellingham diagram provides information about
(A)
temperature dependence of the standard gibbs
H3PO4
Å energies of formation of some metal oxides.
H +
HO 8. Which of the following derivatives of alcohols
O O
is unstable in an aqueous base ?
+
O
(1) RO – CMe3 (2)
H RO Me
O
–H
+
RO
(3) (4)
RO O
O Official Ans. by NTA (2)
2
! OH 12. A flask contains a mixture of compounds A and

OH/H2O
Sol. R–O–C–CH3 R–O–C–CH3 B. Both compounds decompose by first-order
O O kinetics. The half-lives for A and B are 300 s
(ester) !
and 180 s, respectively. If the concentrations
!
CH3–C–OH+OR of A and B are equal initially, the time required
O for the concentration of A to be four times that
(Acid) (Base)
of B(in s) : (Use ln 2 = 0.693)
!
CH3–C–O + R–OH (1) 180 (2) 120
O (3) 300 (4) 900
It is a hydrolysis of ester in basic medium. Official Ans. by NTA (4)
9. The structure of PCl5 in the solid state is
Sol. [A]t = 4[B]t
(1) square pyramidal
(2) tetrahedral [PCl4]+ and octahedral [PCl6]– [A]0 e - (ln
2
/300)t
= 4[B]0 e( - ln 2/180)t
(3) square planar [PCl4]+ and octahedral [PCl6]–
(4) trigonal bipyramidal æ ln 2 ln 2 ö
çç - ÷÷
Official Ans. by NTA (2) e è 180 300 ø
=4
Sol. PCl5(s) exist as [PCl4]+ and [PCl6]–
[PCl4] Þ P
+
Cl
+
Cl Cl Cl
Tetrahedral
EN
(sp3 hybridisation)
æ ln 2 ln 2 ö
ç -
è 180 300 ø
÷ t = ln 4
Cl æ 1 1 ö 2 ´ 180 ´ 300
Cl ! Cl
[PCl6] Þ
–
P ç 180 - 300 ÷ t = 2 Þ t = 120
= 900 sec.
è ø
Cl Cl
Cl
LL
octahedral 13. The increasing order of basicity of the following
sp3d2 hybridization compounds is
10. The most appropriate reagent for conversion of N
C2H5CN into CH3CH2CH2NH2 is :
N N N N
(1) Na(CN)BH3 (2) LiAlH4
(3) NaBH4 (4) CaH2 H H H
A
(A) (B) (C) (D)

(1) (A) < (B) < (C) < (D)
Sol. CH 3–CH2–CºN
? CH3–CH2–CH 2–NH 2 (2) (B) < (A) < (C) < (D)
CH 3–CH2–CºN
LiAlH4
CH3–CH2–CH2–NH2
(3) (D) < (A) < (B) < (C)
(4) (B) < (A) < (D) < (C)
11. The difference between the radii of 3rd and 4th
orbits of Li2+ is DR1. The difference between the
radii of 3rd and 4th orbits of He+ is DR2. Ratio Sol. (A) (B) (C) (D)
N
DR1 : DR2 is :
(1) 8 : 3 (2) 3 : 2 N N N N
(3) 3 : 8 (4) 2 : 3 H H H
sp2
Official Ans. by NTA (4) (Localised
lone pair sp3 less Basic
involve in then(c)
4 32 2 conepair)
- aromaticity most due to !I
DR1 (r4 - r3 ) 42+ 7/3 2 ß
= = 32 3 2 = = Weakest base
basic effect of IInd
Sol. DR 2 (r4 - r3 ) He+ 4 3 7/2 3 Nitrogen
- (least Basic)
2 2
3
14. Identify the correct molecular picture showing 17. The condition that indicates a polluted environment
that happens at the critical micellar is
concentration (CMC) of an aqueous solution of (1) BOD value of 5 ppm
a surfactant ( polar head; non-polar tail; (2) eutrophication
water). (3) 0.03% of CO2 in the atmosphere
(4) pH of rain water to be 5.6
Sol. In Eutrophication nutrient enriched water
(A) (B) (C) (D)
bodies support a dense plant population, which
(1) (B) (2) (A) (3) (D) (4) (C) kills animal life by depriving it of oxygen and
Official Ans. by NTA (3) results in subsequent loss of biodiversity. If
Sol. indicates polluted environment.
Polar head 18. In the sixth period, the orbitals that are filled
more compatible
with polar aq. solution are
(1) 6s, 5f, 6d, 6p (2) 6s, 6p, 6d, 6f
EN
Micelles formed at CMC.
15. If a person is suffering from the deficiency of
nor-adrenaline, what kind of drug can be
(3) 6s, 5d, 5f, 6p
(4) 6s, 4f, 5d, 6p
Sol. As per (n + l) rule in 6th period, order of orbitals

filling is 6s, 4f, 5d, 6p.
suggested ? 19. The potential energy curve for the H2 molecule
(1) Anti-inflammatory (2) Analgesic as a function of internuclear distance is :
(3) Antihistamine (4) Antidepressant
LL
Energy
Sol. Anti depressant ® drug which enhance the Energy

mood. Non adrenaline is neurotransmitter and
its level is low in body due to some reason then (1) (2)
Internuclear Internuclear
person suffers from depression and in that distance distance
situation anti depressant drug is required.
A
16. The correct electronic configuration and spin-

only magnetic moment (BM) of Gd3+ (Z = 64),
Energy
Energy
respectively, are
(1) [Xe]5f7 and 8.9 (2) [Xe]4f7 and 7.9
(3) [Xe]5f7 and 7.9 (4) [Xe]4f7 and 8.9 (3) (4)
Internuclear Internuclear
Official Ans. by NTA (2) distance distance
Sol. Electronic configuration of Gd3+ is
64Gd
3+ = [Xe]4f7 Official Ans. by NTA (2)
[Xe] Sol. Potential energy curve for H2 molecule is.
Gd3+ having 7 unpaired electrons.

Energy
Magnetic moment (µ) = n(n + 2)B.M.

µ = 7(7 + 2)B.M.
= 7.9 B.M. Internuclear
n Þ Number of unpaired electrons. distance
4
20. A diatomic molecule X2 has a body-centred cubic 23. The total number of coordination sites in
(bcc) structure with a cell edge of 300 pm. The ethyl enedi ami netetraacetate (EDTA 4– ) is
density of the molecule is 6.17 g cm–3. The number _______.
of molecules present in 200 g of X2 is
(Avogadro constant (NA) = 6 × 1023 mol–1)
(1) 8 NA Sol. EDTA4– is hexadentate ligand, so its donation
(2) 40 NA sites are six.
(3) 4 NA
(4) 2 NA O
Official Ans. by NTA (3) CH2–C–O–
N
CH2–C–O–
M M
2´ 2´ H 2C O
Sol. NA NA
p= Þ 6.17 =
a 3
(3 ´ 10 cm)3
–8
H 2C CH2–C–O–
N O
Þ M ; 50 gm / mol CH2–C–O–
O
21.
No =
w
M
´ NA =
200
50
´ N A = 4N A
EN
an oxidation-reduction reaction in which 3
electrons are transferred has a DGo of 17.37 kJ
24. The number of chiral carbon(s) present in
peptide, Ile-Arg-Pro, is _____.

o
mol –1 at 25 o C. The value of E (in V) is
cell 25. A soft drink was bottled with a partial pressure
_____ × 10–2 of CO 2 of 3 bar over the liquid at room
LL
(1 F = 96,500 C mol–1) temperature. The partial pressure of CO2 over
Official Ans. by NTA (6) the solution approaches a value of 30 bar when
Sol. DG ° = –AFE ° = –3 ´ 96500 ´ E ° 44 g of CO2 is dissolved in 1 kg of water at room
temperature. The approximate pH of the soft
Þ E° = –6 ´ 10 –2 V
drink is __________ × 10 –1.
22. The minimum number of moles of O2 required
A
for complete combustion of 1 mole of propane (First dissociation constant of H2CO3 = 4.0 × 10–7;
and 2 moles of butane is ______. log 2 = 0.3; density of the soft drink = 1 g mL–1)
Sol. C3 H8 + SO2 ® 3Co2 + 4H 2O

1mole 5mole Sol. PCO2 = K H ´ CO2
For 1 mole propane combustion 5 mole
O2 required 3 K H .n CO2
= Þ n CO2 = 0.1mol
13 30 KH1
C4 H10 + O2 ® 4Co2 + 5H2O
2
1 mole 6.5 mole 1 1
2 mole 13 mole
pH = ( pka1 - log c ) = ( 6.4 ´ 1) = 3.7
2 2
For 2 moles of butane 13 mole of O2 is required
total moles = 13 + 5 = 18 pH = 37 × 10–1
5

(Held On Saturday 05th SEPTEMBER, 2020) TIME : 3 PM to 6 PM
1. The rate constant (k) of a reaction is measured H
at different temperatures (T), and the data are CH2CH3 ÅO–H CH2CH3
Sol. HO
plotted in the given figure. The activation H
Å
energy of the reaction in kJ mol–1 is :

O from O
(R is gas constant)
(H2SO4)
10 –H2O
CH2–CH3 CH2CH3
ln k
5 + H
HSO4
–H2SO4 O
O
0 3. The following molecule acts as an :
1 2 3 4 5
(1) 2R
(3) 1/R
(2) R
10
T
(4) 2/R
3 EN N
(CH2)2
N
(Brompheniramine)
Sol. Official Ans. by NTA (1)
Ea
Slope = - Br
R
LL
(1) Antiseptic (2) Anti-bacterial
10 E (3) Anti-histamine (4) Anti-depressant
- =- a
5 R Official Ans. by NTA (3)
4. An element crystallises in a face-centred cubic
Ea = 2R
(fcc) unit cell with cell edge a. The distance
2. The major product of the following reaction is:
between the centres of two nearest octahedral
A
HO CH2CH3 voids in the crystal lattice is

H2SO4
¾¾¾¾
® a a
(1) a (2) 2a (3) (4)
2 2
O
O.V.
CHCH 3 CH2CH3 Sol.
O.V.
(1) (2)
a/2
O O
O.V.
CH2CH3 CH=CH2 a/2
distance between nearest octahedral
(3) (4) voids(O.V.)
O O 2
æaö æaö
2
a
= ç ÷ +ç ÷ Þ =
Official Ans. by NTA (2) è2ø è2ø 2
1
5. The variation of molar conductivity with 8. The increasing order of boiling points of the
concentration of an electrolyte (X) in aqueous following compounds is :
solution is shown in the given figure. OH OH OH OH
Molar
conductivity
CH3 NO 2 NH 2 OCH3
I II III IV
(1) I < IV < III < II
c (2) IV < I < II < III
The electrolyte X is : (3) I < III < IV < II
(4) III < I < II < IV
(1) CH3COOH (2) KNO3
(3) HCl (4) NaCl
Sol. OH OH OH OH
Sol. Its a weak electrolyte hence : CH3COOH
6.
of permanent hardness of water is :
(1) Treatment with sodium carbonate
EN
The one that is NOT suitable for the removal
CH3
I
O
N
II
O
NH2
III
OCH3
IV
(2) Calgon's method BP value 202°C 279° 284°C 243°C

from net
(3) Clark's method
BP µ dipolemoment (µ)
(4) Ion-exchange method
Alter
LL
Increasing order of boiling point is :
Sol. Temporary hardness of water is removed by OH
clark method and boiling. While permanent
hardness of water is removed by treatment with I.
sodium carbonate (Na2CO3), calgons method
and ion-exchange method CH3
A
7. The correct statement about probability density Þ Shows hydrogen bonding from –O–H group
(except at infinite distance from nucleus) is : only
(1) It cn be negative for 2p orbital OH
(2) It can be zero for 3p orbital

II.
(3) It can be zero for 1s orbital
(4) It can never be zero for 2s orbital
NO2
Official Ans. by NTA (2) Þ Shows strongest hydrogen bonding from
both sides of –OH group as well as –NO2 group.
2 OH
Sol. [R(r)]
3p
III.
r
NH2
2
Þ Shows stronger hydrogen from both side of CH2

–OH group as well as –NH 2 group.
OH Sol. (1) Not show GI
Cl
IV.
H
(2) C Show GI
OCH3 Cl
Þ Shows stronger hydrogen bonding from one CH3
H
side –OH–group and another side of –OCH3
(3) C Not show GI
group shows only dipole-dipole interaction.
Cl
Þ Hence correct order of boiling point is: H3C
H
(I) < (IV) < (III) < (II) (4) Show GI
C
9. The compound that has the largest H–M–H Cl
bond angle (M=N, O, S, C), is : H3C
11. Which one of the following polymers is not
(1) H2O
(3) NH3
(2) CH4
(4) H2S
EN obtained by condensation polymerisation?
(1) Buna - N
(3) Nylon 6
(2) Bakelite
(4) Nylon 6, 6
H
Sol. BuNa–N is an addition polymer
O C
Sol. (1) H H (2) H H Buta-1, 3-diene + Acrylonitrile
H
LL
3
sp , 104°5' sp3, 109°28' CH2=CH–CH=CH2 CH2=CH–CºN
Na
N
H H S [BuNa-N]
(3) H (4) H H
sp3, 107° 92° 12. The final major product of the following
A
reaction is :
10. Among the following compounds, geometrical
Me
isomerism is exhibited by : (i) Ac2O/Pyridine
CH 2 (ii) Br2, FeCl3

CHCl –
(iii) OH /D
NH 2
(1) (2) Br
Me
CH3 Me
Cl (1) (2)
Br
CHCl CHCl NH2
NH2
Me Me Br
(3) (4)
H3C CH3 (3) Br (4)
Official Ans. by NTA (2) NH2 NH2
Official Ans. by ALLEN (2 & 4) Official Ans. by NTA (1)
3
H 3C
15. Lattice enthalpy and enthalpy of solution of
Sol. Me
Acetylation NaCl are 788 kJ mol –1 and 4 kJ mol –1 ,
respectively. The hydration enthalpy of NaCl
CH3–C–O–C–CH3
H 2N NH–C–CH3 is :
O O
O
(1) –780 kJ mol–1 (2) –784 kJ mol–1
(Bromination) Br2/FeCl3
(3) 780 kJ mol–1 (4) 784 kJ mol–1
Br Br
H 3C H 3C
OH
D DH = 4
NaCl(s) ¾¾¾¾® NaCl(aq)
–ACOH
NH2 NH–C–CH3
Sol. H = +788 DH = ?
O + –
H––OH Na (g) + Cl (g)
13. Hydrogen peroxide, in the pure state, is : 4 = 788 + DH

(1) non-planar and almost colorless DH = –784 kJ
(2) linear and almost colorless
16. Reaction of ammonia with excess Cl2 gives :
(3) planar and blue in color
(1) NH4Cl and N2
(4) linear and blue in color
H
EN (2) NCl3 and NH4Cl
(3) NH4Cl and HCl
(4) NCl3 and HCl
O Official Ans. by NTA (4)
Sol.
O NH 3 + 3Cl2 ¾¾
® NCl3 + 3HCl
H Sol. excess
LL
17. The correct order of the ionic radii of
hydrogen peroxide, in the pure state, is non-
planar and almost colourless (very pale blue) O2–, N3–, F–, Mg2+, Na+ and Al3+ is :
liquid. (1) Al3+ < Na+ < Mg2+ < O2– < F– < N3–
(2) N3– < O2– < F– < Na+ < Mg2+ < Al3+
14. Boron and silicon of very high purity can be
(3) Al3+ < Mg2+ < Na+ < F– < O2– < N3–
obtained through :
(4) N3– < F– < O2– < Mg2+ < Na+ < Al3+
A
(1) vapour phase refining

(2) electrolytic refining
Sol. Correct order of size for isoelectronic species.
(3) liquation
Al3+ < Mg2+ < Na+ < F– < O2– < N3–
(4) zone refining
18. Consider the complex ions,
trans-[Co(en) 2Cl2]+ (A) and
Sol. "Boron" and "Silicon" of very high purity can
cis-[Co(en)2Cl 2]+ (B). The correct statement
be obtained through :-
regarding them is :
zone refining method only.
(1) both (A) and (B) can be optically active
While other methods are used for other metals/ (2) both (A) and (B) cannot be optically active
elements i.e. (3) (A) can be optically active, but (B) cannot
(i) Vapour phase refining be optically active
(ii) electrolytic refining (4) (A) cannot be optically active, but (B) can
(iii) liquation etc. be optically active
4
Sol. (A) trans-[Co(en)2Cl2]+ x

m T1
Cl (+)
NH2 NH2 x 1/n T2 (T2 > T1)
Sol. m = K.P.
en Co en p
20. The major product formed in the following

NH2 NH2
Cl reaction is :
Þ (A) is trans form and shows plane of
CH 3CH = CHCH(CH 3 )2 ¾¾ ¾
HBr
®
symmetry which is optically inactive (not
optically active) (1) CH3 CH2 CH2 C(Br) (CH3)2
(2) Br(CH2)3 CH(CH3)2
(B) cis-[Co(en)2Cl2]+
(3) CH3 CH2 CH(Br) CH(CH3)2
Cl (4) CH3 CH(Br) CH2 CH(CH3)2
NH2 Cl
en Co Official Ans. by ALLEN (4)
NH2 NH2
Sol. CH3–CH=CH–CH–CH3
19.
NH2
en
symmetry, hence it is optically active.

Adsorption of a gas follows Freundlich
EN
Þ (B) is cis form and does not shows plane of
From Å CH3
HBr H
Å
CH3–CH–CH–CH–CH3
H CH3
adsorption isotherm. If x is the mass of the gas Br

adsorbed on mass m of the adsorbent, the
CH3–CH–CH 2–CH–CH3
LL
x
correct plot of versus p is :
m Br CH3
200 K
x 250 K Addition of HBr according to M.R.
m
270 K 21. The number of chiral carbons present in sucrose
(1)
is_______ .
p
A
270 K
x CH2OH CH2OH O
m 250 K Sol. H O H
200 K H
(2) OH H O
OH H OH CH2OH
p
H OH
OH H
200 K
x 250 K [a-D-Glucose] [b-D-Fructose]
m 270 K Total no. of chiral carbon in sucrose = 9
(3)
22. For a dimerization reaction,
p
2 A(g) ® A2(g)
270 K
x 250 K at 298 K, DU!, = – 20kJ mol–1, DS! = –30 J
m
200 K K–1 mol–1, then the DG! will be _________J.
(4)
Official Ans. by NTA (–13538.00)
p
Official Ans. by ALLEN (–13537.57)
5
Sol. DG° = DH° – TDS° 24. The volume, in mL, of 0.02 M K2Cr2O7 solution
= (DU° + DngRT) – TDS° required to react with 0.288 g of ferrous oxalate
in acidic medium is_______.
é
{
= ê -20 + (-1))
ë
8.314
1000
´ 298 - }298
1000
ù
´ (-30) ú kJ
û
(Molar mass of Fe = 56 g mol–1)
Official Ans. by NTA (50.00)
Sol. K2Cr2O7 + FeC2O4 ¾® Cr+3 + Fe+3 + CO2
= –13.537572 kJ
n=6 n=3
= –13537.57 Joule
23. For a reaction X + Y 2Z, 1.0 mol of X, 1.5 0.02 ´ 6 ´ V(mL) 0.288
= ´3
mol of Y and 0.5 mol of Z were taken in a 1 1000 144
L vessel and allowed to react. At equilibrium, Þ V = 50mL
the concentration of Z was 1.0 mol L–1. The 25. Considering that D0 > P, the magnetic moment
equilibrium constant of the reaction is (in BM) of [Ru(H2O)6]2+ would be________ .
x
______ . The value of x is ________ . Sol. Magnetic moment (in B.M.) of [Ru(H2O)6]2+
15
would be; while considering that D0 > P,
Sol.
t=0 1
X + Y
1.5
=
0.5
2Z
;
EN Ru(44) ; [Kr]4d75s1 (in ground state)
Þ In Ru2+ Þ 4d6 Þ (t2g)6(eg)0
(eg)
D0 > P
0
At eq. 0.75 1.25 1

6
4d (t2g)
6
Þ Here number of unpaired electrons in

12 16
Keq. = =
LL
3 5 15 Ru2+ = (t2g)6 (eg)0 = 0 and Hence
´
4 4 µm = n(n + 2)B.M. = 0 B.M.
A
6

(Held On Sunday 06th SEPTEMBER, 2020) TIME : 9 AM to 12 PM
1. The set that contains atomic number of only 5. A solution of two components containing
transition element is - n1 moles of the 1st component and n2 moles of
(1) 21, 32, 53, 64 the 2nd component is prepared. M1 and M2 are
the molecular weights of component 1 and 2
(2) 21, 25, 42, 72
respectively. If d is the density of the solution
(3) 9, 17, 34, 38 in g mL–1, C2 is the molarity and x2 is the mole
(4) 37, 42, 50, 64 fraction of the 2nd component, then C2 can be
Official Ans. by NTA (2) expressed as :
2. The lanthanoid that does NOT show +4
1000x 2
oxidation state is (1) C2 =
M1 + x 2 (M2 - M1 )
(1) Dy
dx 2
(2) Eu
(3) Ce
(4) Tb
EN (2) C2 =
(3) C2 =
M2 + x 2 (M2 - M1 )
dx1
M2 + x 2 (M2 - M1 )
3. The INCORRECT statement is : 1000dx2
(4) C2 =
M1 + x 2 (M2 - M1 )
(1) bronze is an alloy of copper and tin.
LL
(2) brass is an alloy of copper and nickel Official Ans. by NTA (4)
(3) cast iron is used to manufacture wrought 6. The major products of the following reaction
are :
iron.
CH3
(4) german silver is an alloy of zinc, copper and (i) KOtBu/D
nickel CH3–CH–CH–CH3
(ii) O3/H2O2
A
Official Ans. by NTA (2) OSO2CH3

4. The correct statement with respect to dinitrogen CH3
is : (1) + HCOOH
H3C COOH
(1) liquid dinitrogen is not used in cryosurgery.
CH3
(2) it can be used as an inert diluent for reactive
(2) + HCHO
chemicals. H3C CHO
(3) it can combine with dioxygen at 25°C CH3
(4) N2 is paramagnetic in nature. (3) + CH3CHO
H3C O
CH3
(4) + CH3COOH
H3C O
1
7. Kraft temperature is the temperature 10. The major product obtained from the following
(1) below which the formation of micelles takes reaction is -
place. Hg2+/H+
O2 N C C OCH3
(2) below which the aqueous solution of detergents H2 O
starts freezing. OH
(3) above which the formation of micelles takes

place. (1)
O
(4) above which the aqueous solution of O 2N OCH3
detergents starts boiling. O

(2)
8. Consider the Assertion and Reason given
O2 N
below.
OCH3
Assertion (A) : Ethene polymerized in the
presence of Ziegler Natta Catalyst at high
temperature and pressure is used to make (3)
buckets and dustbins.
EN
Reason (R): High density polymers are closely
packed and are chemically inert. Choose the
O2 N
O
O
OH
correct answer from the following : (4)

O 2N
(1) (A) is correct but (R) is wrong.
(2) (A) and (R) both are wrong.
LL
11. For the reaction :
(3) Both (A) and (R) are correct and (R) is the
correct explanation of (A). 3 2Fe(s) + NH3 (g)
Fe2N(s) + H 2 (g)
2
(4) Both (A) and (R) are correct but (R) is not
the correct explanation of (A). (1) KC = KP(RT) (2) KC = KP(RT)–1/2
A
(3) KC = KP(RT)–3/2 (4) KC = KP(RT)1/2

9. The species that has a spin only magnetic
moment of 5.9 BM, is -
12. Arrange the following solutions is the
(1) Ni(CO)4(Td) decreasing order of pOH :
(2) [MnBr4]2–(Td) (A) 0.01 M HC1

(B) 0.01 M NaOH
(3) [NiCl4]2–(Td)
2– (C) 0.01 M CH3COONa
(4) [Ni(CN) 4] (square planar)
(D) 0.01 M NaCl
(1) (B) > (C) > (D) > (A)
(2) (A) > (C) > (D) > (B)
(3) (B) > (D) > (C) > (A)
(4) (A) > (D) > (Q > (B)
2
13. The presence of soluble fluoride ion upto 1 ppm (3) II < I < III < IV
concentration in drinking water, is : (4) I < II < III < IV
(1) harmful to bones Official Ans. by NTA (1)
(2) harmful for teeth
16. Among the sulphates of alkaline earth metals,
(3) safe for teeth
the solubilities of BeSO4 and MgSO4 in water,
(4) harmful to skin
Official Ans. by NTA (3) respectively, are:
14. Consider the following reactions : (1) high and high (2) poor and poor
'A' is - (3) high and poor (4) poor and high
'A' ozonolysis Official Ans. by NTA (1)
(C7H14) 'B' + 'C'
17. The major product of the following reaction is
(I2 + NaOH)
'B' yellow ppt CH3
D
Ag2O
2HBr
silver mirror
D
(I2 + NaOH)
'C' no yellow ppt
D
LiAlH4
'D'
Anhydrous ZnCl2
conc. HCl
EN
gives white
turbidity
within 5
minutes
(1)
NO2
CH3
Br
(2)
Br CH3
Br
Br NO2
(1)
NO2
LL
CH3
H3C Br
(2) Br
(3) (4)
(3) Br
Br NO2
(4) NO2
A

15. The increasing order of pKb values of the following 18. The variation of equilibrium constant with
compounds is - temperature is given below :
Temperature Equilibrium constant
N(CH3)2 N(CH3)2 NHCH3 NHCH3
T1 = 25ºC K1 = 100
T2 = 100ºC K2 = 100
The values of DHº, DGº at T1 and DGº at T2 (in
CN OH
kJ mol–1) respectively, are close to
OCH3
[Use R = 8.314 JK–1mol–1]
I II III IV
(1) 0.64, –5.71 and –14.29
(1) I < II < IV < III (2) 28.4, –7.14 and –5.71
(2) II < IV < III < I (3) 28.4, –5.71 and –14.29
(4) 0.64, –7.14 and –5.71
3
19. Consider the following reactions : 22. The elevation of boiling point of 0.10 m aqueous
A ® P1 ; B ® P2 ; C ® P3 ; D ® P4 CrCl3.xNH3 solution is two times that of 0.05m
aqueous CaCl2 solution. The value of x is____.
The order of the above reactions are a, b, c, and
d, respectively. The following graph is obtained [Assume 100% ionisation of the complex and
when log [rate] vs. log[conc] are plotted: CaCl2 , coordination number of Cr as 6, and that
all NH 3 molecules are present inside the
[D] [B]
[A] coordination sphere]
[C] Official Ans. by NTA (5.00)
log[rate]
23. A spherical balloon of radius 3 cm containing

–3
helium gas has a pressure of 48 × 10 bar. At
log[conc.] the same temperature, the pressure, of a
Among the following , the correct sequence for spherical balloon of radius 12 cm containing
–6
the order of the reactions is: the same amount of gas will be_____× 10 bar.
(1) a > b > c > d Official Ans. by NTA (750.00)
(2) c > a > b > d 24. The number of CI = O bonds in perchloric acid
20.
(3) d > b > a > c
(4) d > a > b > c
Which of the following compound shows
EN 25.
is, "_________"
Potassium chlorate is prepared by the
electrolysis of KCl in basic solution
geometrical isomerism
(1) 2-methylpent-2-ene 6OH– + Cl– ® ClO3– + 3H2O + 6e–
(2) 4-methylpent-l-ene If only 60% of the current is utilized in the
LL
(3) 4-methylpent-2-ene reaction, the time (rounded to the nearest hour)
(4) 2-methylpent-l-ene required to produce 10 g of KCIO 3 using a
Official Ans. by NTA (3) current of 2 A is_____.
–1
21. In an estimation of bromine by Carius method, (Given : F = 96,500 C mol molar mass of
–1
1.6 g of an organic compound gave 1.88 g of KClO3=122 gmol )
AgBr. The mass percentage of bromine in the
A

compound is _______
(Atomic mass, Ag=108, Br = 80 g mol–1)
4

(Held On Sunday 06th SEPTEMBER, 2020) TIME : 3 PM to 6 PM
1. The value of KC is 64 at 800 K for the reaction
N2(g) + 3H2(g) 2NH3(g)
Sol.(a) nCH 2=C–CH=CH 2 Poly cis-isoprene
The value of KC for the following reaction is : CH3 (Natural rubber)
isoprene CH3 H
1 3 C=C
NH3(g) N2(g) + H2(g) CH2
2 2 CH2 n
1 1 1
(1) (2) (3) 8 (4)
4 8 64
(b) nCH2=C–CH=CH2 (CH2–C=CH–CH2–)n
Official Ans. by NTA (2) Cl Cl
Neoprene
Sol. N2 + 3H2 2NH3 ® KC = 64 Chloroprene
2NH3 N2 + 3H2 ® KC =
NH3
1 3 æ 1 ö
N2 + H2 ® KC = ç ÷
1
64
EN
1
2
=
1
(c) nCH2=CH–CH=CH2+nCH2=CH
1,3 buta diene
CN
Acrylonitrile
Buna-N
2 2 è 64 ø 8 (d) CH2=CH–CH=CH2+CH2=CH –CH2–CH=CH–CH2–CH2 –CH–

1,3-buta diene
2. The element that can be refined by distillation styrene
is :
LL
4. Mischmetal is an alloy consisting mainly of:
(1) nickel (2) zinc (1) lanthanoid metals
(3) gallium (4) tin (2) actinoid metals
(3) actinoid and transition metals
(4) lanthanoid and actinoid metals
Sol. Impure zinc is refined by distillation method.
A
3. The correct match between Item-I and Item-II :

Sol. Alloys of lanthanides with Fe are called Misch
Item-I Item-II metal, which consists of a lanthanoid metal
(a) Natural rubber (I) 1, 3-butadiene + (~95%) and iron (~5%) and traces of S, C, Ca
styrene and Al.
(b) Neoprene (II) 1, 3-butadiene + 5. Reaction of an inorganic sulphite X with dilute
acrylonitrile H2SO4 generates compound Y. Reaction of Y
(c) Buna-N (III) Chloroprene with NaOH gives X. Further, the reaction of X
with Y and water affords compound Z. Y and
(d) Buna-S (IV) Isoprene
Z, respectively, are:
(1) (a) - (III), (b) - (IV), (c) - (I), (d) - (II) (1) S and Na2SO3
(2) (a) - (IV), (b) - (III), (c) - (II), (d) - (I) (2) SO2 and NaHSO3
(3) (a) - (IV), (b) - (III), (c) - (I), (d) - (II) (3) SO3 and NaHSO3
(4) (a) - (III), (b) - (IV), (c) - (II), (d) - (I) (4) SO2 and Na2SO3
1
8. Match the following :

dil. H2SO4 NaOH
Sol. Na2SO3 SO 2 Na2SO 3 Test/Method Reagent
(X) (Y) (X)
(i) Lucas Test (a) C6H5SO2Cl/aq. KOH
SO2
+ (ii) Dumas method (b) HNO3/AgNO3
H2O
(iii) Kjeldahl's method (c) CuO/CO2
NaHSO3
(Z) (iv) Hinsberg Test (d) Conc. HCl and ZnCl2
(e) H2SO4
6. The IUPAC name of the following compound (1) (i)-(d), (ii)-(c), (iii)-(e), (iv)-(a)
is : (2) (i)-(b), (ii)-(d), (iii)-(e), (iv)-(a)
(3) (i)-(d), (ii)-(c), (iii)-(b), (iv)-(e)
OH
(4) (i)-(b), (ii)-(a), (iii)-(c), (iv)-(d)
NH2 Official Ans. by NTA (1)
Sol. Test Correct reagent
O 2N
(i) Lucas test ¾® conc. HCl + ZnCl2
CHO
(ii) Dumas method ¾® CuO / CO 2
(1) 3-amino-4-hydroxymethyl-5-nitrobenzaldehyde (iii) Kjeldahl's method ¾® H2SO4
(2) 2-nitro-4-hydroxymethyl-5-aminobenzaldehyde
(3) 4-amino-2-formyl-5-hydroxymethylnitrobenzene
(4) 5-amino-4-hydroxymethyl-2-nitrobenzaldehyde
EN 9.
(iv) Hinsberg Test ¾® C6H5SO2Cl + aq. KOH
The reaction of NO with N2O4 at 250 K gives :
(1) N2O5
(3) N2O
(2) NO2
(4) N2O3
250K
Sol. 2NO + N2O4 2N2O 3
LL
OH blue solid
4
3 5 NH2 10. For the given cell ;
2 6 Cu(s)|Cu2+ (C1M)||Cu2+ (C2M)|Cu(s) change in
Sol.
O 2N 1
Gibbs energy (DG) is negative, if :
CHO
C1
(1) C1 = 2C2 (2) C 2 =
2
5-amino-4-hydroxymethyl-2-nitrobenzaldehyde
A
7. Dihydrogen of high purity (> 99.95%) is (3) C1 = C2 (4) C 2 = 2C1

obtained through: Official Ans. by NTA (4)
(1) the electrolysis of warm Ba(OH)2 solution Sol. DG = –n F Ecell
using Ni electrodes. DG is negative, if Ecell is positive
Cu(s) ¾® Cu (C1) + 2e : E°
+2 –
(2) the reaction of Zn with dilute HCl Anode :
Cathode : Cu+2(C2) + 2e– ¾® Cu (S) : –E°
(3) the electrolysis of brine solution.
(4) the electrolysis of acidified water using Pt 2.303RT
electrodes. E °cell -
E cell = log Q
nF
Official Ans. by NTA (1) æC ö
2.303RT
Sol. High purity (>99.95%) dihydrogen is obtained E cell =
0- log ç 1 ÷
nF è C2 ø
by electrolysing warm aqueous barium
C1
hydroxide solution between nickel electrodes. E cell > 0 : if < 1 Þ C1 < C2
C2
2
11. A crystal is made up of metal ions 'M1' ana 'M2' 13. Which of the following compounds can be
and oxide ions. Oxide ions form a ccp lattice prepared in good yield by Gabriel phthalimide
structure. The cation 'M 1 ' occupies 50% of synthesis?
octahedral voids and the cation 'M2' occupies
12.5% of tetrahedral voids of oxide lattice. The CH2NH2 NH2
oxidation numbers of 'M 1 ' and 'M 2 ' are, (1) (2)
respectively :
(1) +2, +4 (2) +3, +1
(3) +1, +3 (4) +4, +2 O
Official Ans. by NTA (1) CH2–C–NH2
(3) (4) CH3–CH2–NHCH3
Sol. O–2 ions form ccp. O4
(–8 charge)
Sol. Gabriel phthalimide synthesis is used for
50
M1 = 50% of O.V. Þ ´ 4 = 2 :(M1 )2 preparation of 1° Aliphatic amine
100
M2 = 12.5% of T.V. Þ
12.5
100
EN
´ 8 = 1:(M 2 )1
So formula is : (M1)2 (M2)1O4

O
O
NH
Å 1
KOH
O
O
1 Å
NK
R–Br
–KBr
O
O
N–R
HOH/HÅ
O
This must be neutral. Both metals must have +8 OH
+ R–NH2
OH
charge in total.
O
LL
From given options : O.N. of M1 = +2 CH2–Br
M2 = +4 Here R–Br =
12. For a d4 metal ion in an octahedral field, the correct CH 2–NH 2

R–NH2 =
electronic configuration is :
14. The correct match between Item-I (starting
(1) t 2g eg when D O < P
4 0
A
material) and Item-II (reagent) for the

(2) eg t 2g when D O < P
2 2
preparation of benzaldehyde is :
(3) t 2g eg when D O < P

3 1 Item-I Item-II
(I)Benzene (P) HCl and SnCl2, H3O+
(4) t 2g eg when D O > P
3 1
(II)Benzonitrile (Q) H2, Pd-BaSO4, S

and quinoline
eg
(III)Benzoyl Chloride (R)CO, HCl and AlCl 3
Sol. d4 (1) (I)-(Q), (II)-(R) and (III)-(P)

t2g (2) (I)-(R), (II)-(Q) and (III)-(P)
back pairing is not possible because pairing energy (3) (I)-(R), (II)-(P) and (III)-(Q)
> DO. (4) (I)-(P), (II)-(Q) and (III)-(R)
3
O H CH2–OH
C–H H
O OH Anomeric –OH is present
H
CH2–OH O OH so it give +ve Fehling Test
H
CO, HCl (Gattermann HO O OH
Sol.(i) AlCl3 koch reaction) Sol.
H
OH
H
H
H H b–D -Glucose
H OH (+)
e
O alactos
b–D -G+)
CN CH=NH C–H (
Å It is b-Glycosidic linkage
(ii) (i) SnCl2, HCl H3O
(Stephen
Structure of Lactose
reduction)
Imine
structure of lactose
Cl H
O
O
C C
17. A set of solutions is prepared using 180 g of
H2, Pd
(iii) (Rosenmund water as a solvent and 10 g of different
BaSO4, S,
Quinoline
reduction)
non-volatile solutes A, B and C. The relative
15. The average molar mass of chlorine is 35.5 g lowering of vapour pressure in the presence of
mol –1. The ratio of 35Cl to 37Cl in naturally these solutes are in the order [Given, molar
occurring chlorine is close to : mass of A = 100 g mol –1; B = 200 g mol–1;
(1) 4 : 1
(2) 1 : 1
(3) 2 : 1
(4) 3 : 1
EN C = 10,000 g mol–1]
(1) A > B > C
(3) C > B > A
(2) A > C > B
(4) B > C > A
DP
35
Cl
37
Cl Av. molar Sol. Relative lowering of V.P. = = x solute
P0
mass = 35.5
Sol. let x : 1
LL
mole ratio 10 10
æ DP ö 100 æ DP ö 200
ç P 0 ÷ = 10 180 : ç P 0 ÷ = 10 180
è øA + è ø B +
n1M1 + n 2 M 2 100 18 200 18
Av. molar mass = (n1 + n 2 )
10
x ´ 35 + 1 ´ 37 æ DP ö 10,000 æ DP ö æ DP ö æ DP ö
35.5 = ç P0 ÷ = : ç 0 ÷ >ç 0 ÷ >ç 0 ÷
A
x +1 è øC 10 180 è P ø A è P ø B è P øC
+
10,000 18
x=3
16. Which one of the following statements not 18. For a reaction,
true ? 4M(s) + nO2(g) ® 2M2On(s),
(1) Lactose contains a-glycosidic linkage the free energy change is plotted as a function
between C1 of galactose and C4 of glucose. of temperature. The temperature below which
(2) Lactose (C11H22O11) is a disaccharide and the oxide is stable could be inferred from the
it contains 8 hydroxyl groups. plot as the point at which :
(3) On acid hydrolysis, lactose gives one (1) the slope changes from positive to zero
molecule of D(+)-glucose and one (2) the free energy change shows a change
molecule of D(+)-galactose. from negative to positive value
(4) Lactose is a reducing sugar and it gives (3) the slope changes from negative to positive
Fehling's test. (4) the slope changes from positive to negative
4
19. Match the following compounds (Column-I) with peroxide

102°C
their uses (Column-II) : Sol. (a) HBr
Br
S.No. Column - I S.No. Column - II
(I) Ca(OH)2 (A) casts of statues
(II) NaCl (B) white wash (b) Br 73.3°C
HBr
1
(III) CaSO 4 . H 2O (C) antacid
2
washing soda
(IV) CaCO3 (D) Br
preparation
(c) 91°C
(1) (I)-(D), (II)-(A), (III)-(C), (IV)-(B) HBr
(2) (I)-(B), (II)-(C), (III)-(D), (IV)-(A)

1
(3) (I)-(C), (II)-(D), (III)-(B), (IV)-(A) B.P. µ \ a > c > b (order of B.P.)
Branching
(4) (I)-(B), (II)-(D), (III)-(A), (IV)-(C)
Official Ans. by NTA (4) 21. For Freundlich adsorption isotherm, a plot of
log (x/m) (y-axis) and log p (x-axis) gives a
Sol. (I) Ca(OH)2 is used in white wash
2NH3 + H2O + CO2 ¾® (NH4)2CO3

(NH4)2CO3 + H2O + CO2 ¾® 2NH4HCO3
EN
(II) NaCl is used in preparation of washing soda
straight line. The intercept and slope for the line
is 0.4771 and 2, respectively. The mass of gas,
adsorbed per gram of adsorbent if the initial
pressure is 0.04 atm, is_ _ _ _ _ _ × 10–4g.
NH4HCO3 + NaCl ¾® NH4Cl + NaHCO3(s) (log 3 = 0.4771)
2NaHCO3 ¾¾
D
® Na2CO3 + CO2 + H2O Official Ans. by NTA (48.00)
LL
1 x
= KP n
1
(III) CaSO4. H O (Plaster of Paris) is used for Sol.

2 2 m
making casts of statues

(IV) CaCO 3 is used as an antacid æxö 1
log ç ÷ = log P + log K
èmø n
A
20. The increasing order of the boiling points of the

major products A, B and C of the following
reactions will be : 1
slope = =2
n
O
(C6H5CO) 2
(a) + HBr A
intercept = log K = 0.4771
K=3
(b) + HBr B
x
mass of gas adsorbed per gm of adsorbent =
(c) + HBr C m
(1) C < A < B (2) B < C < A x

= 3 ´ (0.04)2 = 48 ´ 10 -4
(3) A < B < C (4) A < C < B m
5
22. A solution of phenol in chloroform when treated 24. The rate of a reaction decreased by 3.555 times
with aqueous NaOH gives compound P as a major when the temperature was changed from 40°C
product. The mass percentage of carbon in P to 30°C. The activation energy (in kJ mol–1) of
is________. (to the nearest integer) the reaction is_ _ _ _ _ _.
(Atomic mass : C = 12; H = 1; O = 16) Take; R=8.314 J mol–1 K–1 In 3.555 = 1.268
OH OH
(Reimer æ KT ö Ea é 1 1 ù
CHO ln ç 2 ÷= -
CHCl3 Tiemann Sol. ç KT ÷ R êë T1 T2 úû
Sol. è 1 ø
NaOH reaction)
(P)
(C7H6O2) T1 = 303 K ; T2 = 313 K
K T2
Molecular weight of C7H6O2 = 122
%C =
12 ´ 7 ´ 100
122
= 68.85 » 69
EN K T1
= 3.555
Ea é 1 1 ù
ln(3.555) = -
23. If the solubility product of AB2 is 3.20 × 10–11 M3, 8.314 ë 303 313 úû
ê
then the solubility of AB2 in pure water is_ _
_ _ _ × 10–4 mol L–1. [Assuming that neither Ea = 99980.715
LL
kind of ion reacts with water]
Official Ans. by NTA (2.00) kJ
Ea = 99.98
mole
Sol. A(aq.)
AB2 (s) +2 -
+ 2B(aq.) : K sp
S 2S 25. The atomic number of Unnilunium is _____.
A
KSP = S1 × (2s)2 = 4s3 Official Ans. by NTA (101.00)
3.2 × 10–11 = 4 × S3 Sol. Unnilunium Þ 101

S = 2 × 10–4 M/L

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Final JEE - Main Exam September, 2020/02-09-2020/Morning Session

FINAL JEE–MAIN EXAMINATION – SEPTEMBER, 2020

energy of Sol. Slow or fast process is kinetic parameter but extent

while ionisation enthalpy, electron gain enthalpy

(1) Na (2) Rb (1) tetrahedral and –1.6 Dt + 1P

The correct statements are : Bary centre

(2) (II), (III) and (IV) only

11. In Carius method of estimation of halogen, 0.172g OH OH

(1) (2) H3C–CH2–Br O OH

80 14. Which one of the following graphs is not correct

Official Ans. by NTA (1)

Ni/H 2 y eq.of CH=O CH2–OH

(1) Ostwald Process (2) Van Arkel Method *

FINAL JEE–MAIN EXAMINATION – SEPTEMBER, 2020

More donating group

[Minor due to crowding]

Lucas Test Turbidity Turbidity Official Ans. by NTA (1)

D H3C CH2 CH CH3

Official Ans. by NTA (2) 6 × 10–3 = K(0.1)x (0.1)y ……(1)

1.2 × 10–2 = K(0.2)x (0.1)y ……(3)

So, other with respect to A = 1

(1) O CH CH CH3 Official Ans. by NTA (2)

(2) Formation of violet colour = –327 × 103 + 2 × 300

22. For the disproportionation reaction So, x=6

= 14.4 = 144 × 10–1

FINAL JEE–MAIN EXAMINATION – SEPTEMBER, 2020

produced [B]. Which of the following structures me +

(2) A second order reaction is always a

(3) A first order reaction is always a single step = 2 × 10–2 bar

CH3 H CH3 8. Tyndall effect of observed when :

H CH3 (2) The diameter of dispersed particles is much

(3) The diameter of dispersed particles is similar

(4) The refractive index of dispersed phase is

Official Ans. by NTA (3)

Sol. Thermal power plants lead to acid rain.

(1) a and d (2) c and d

(ii) H2O give

(4) N2O5 + HCl give

Sol. Au + HNO3 + 4HCl ® HAuCl4 + NO + 2H2O

A student writes general characteristics based Official Ans. by NTA (3)

NºC CºN (1) 100 mL of 0.1 M CH3COOH and 200 mL

(1) (2) H3C–CºC–H of 0.1 M NaOH

10 mili mol 10 mili mol 10 mili mol

(2) Alcoholic HCN; NaOCl; ZnCl 2/HCl

gives (1) Br2 + H2O test

Official Ans. by NTA (100) 12

Þ stopping potential required for K

FINAL JEE–MAIN EXAMINATION – SEPTEMBER, 2020

we need to apply (n + l) rule

17 Option 4) 6 : 1s2 1p4 has 1p valence

R has lower boiling point than S

Intramolecular (d) It is not harmful for trees

(3) (c) only

7. The five successive ionization enthalpies of an 9. The d-electron configuration of [Ru(en)3]Cl2

A mixture of one mole each of H2, He and O2

excess water to liquid

xi = mole fraction of the ith component

(3) liquid diethyl ether to aqueous NaCl solution

(I) (II) 13. The increasing order of the reactivity of the

NO2 O2 N NO2 (1) Butanone < Propanone < Benzaldehyde <

(1) (IV) > (II) > (III) > (I)

Permanganate Þ MnO-4 A ¾¾¾¾¾¾

Official Ans. by NTA (3)

7. For the equilibrium A B , the variation of the Sol.

equilibrium constant for A P is :- (1) –0.8 D0 (2) –0.4 D0 + P