ADVANCED REVISION SHEET

CHEMISTRY COORDINATION COMPOUNDS

Part – 1 (One Option Correct)

1. 4 – nitrophenyl hydrazine is an example of:
(A) A tridentate ligand (B) A bidentate ligand
(C) A monodentate ligand (D) A tetradentate ligand

2. The correct electronic configuration for CrF6 

4
will be:
(A) t24g eg0 (B) eg2 t 22g (C) t23g e1g (D) eg4 t 20g

3. Which of the following pairs of coordination compound show same type of isomerism?
(A)  Co  NH 3 5 Br  SO4 and  Ni  dmg  2 
(B)  Pt  NH 3 2 Cl2  and Co  en 2 BrCl  Cl .
(C)  Co  NH 3 6  Cr  CN 6  and K  PtCl3  C2 H 4   .
2 2
(D)  Ni  en 3  and  Pt  en 2  .

4. The correct name for the complex  Pt  NH 3 2 Cl4  , which has maximum planes of symmetry is:
(A) cis-platinum tetrachlorodiammine (B) trans-platinum tetrachlorodiammine
(C) trans-Diamminetetrachloroplatinum (IV) (D) cis-Diammine tetrachloroplatinum (IV)

5. The ligand N  CH 2CH 2 NH 2 3 is:

(A) tridentate (B) tetradentate (C) didentate (D) pentadentate

6. The hybridisation and geometry of [Fe(CO)4]2– is

(A) sp3d, TBP (B) sp3, tetrahedral (C) dsp2, square planar (D) sp 3, TBP

7. The E.A.N. of Fe - atom in (CO)3Fe(CO)3 Fe(CO)3 is

(A) 34 (B) 35 (C) 36 (D) 37

8. Which of following statement correct for the complex K4 [Fe(CN)5 O2] having t26g , ego electronic
configuration.
(A) d 2sp3 hybridised and diamagnetic (B) sp3d2 hybridised and paramagnetic
(C) sp d hybridised and diamagnetic
3 2
(D) d2sp3 hybridised and paramagnetic

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9. Choose the correct order of M–C bond order in the following molecule and ions
(A) [Ni(CO)4] > [Co(CO)4] – > [Fe(CO)4]2–
(B) [Ni(CO)4] = [Co(CO)4] – = [Fe(CO)4]2–
(C) [Co(CO)4] – > [Fe(CO)4]2– > [Ni(CO)4]
(D) [Ni(CO)4] < [Co(CO)4] – < [Fe(CO)4]2–

Part – 2 (One or More than One Option Correct)

10. Select the correct statement.
(A) [Co(H2O)6]3+ is Co(III), low spin, 0 unpaired electron, diamagnetic
(B) [CoF6]3– is Co(III), high spin d 6, 4 unpaired electron, paramagnetic
(C) [RhF6]3– is Rh(III), low spin d6, 0 unpaired electrons diamagnetic
(D) [Fe(CN)6]4– is high spin d6, 0 unpaired electron diamagnetic

Part – 3 (Paragraph Type Question)

Paragraph # 01
Answer the questions based on the following reactions:
CuSO4  excess NH 3  X .
Y .
CuSO4  excess KCl 

11. The name of Y is:

(A) Potassium (tetrachloride) disulphate copper (II)
(B) Potassium Tetrachloridocuprate (II)
(C) Potassium tetrachloridocopper (II)
(D) Dipotassiumcuprate (II) chloride

12. To Y, excess KCN is added due to which a highly stable complex results. This complex is:
2 4
(A)  Cu  CN 4  paramagnetic (B) Cu  CN 6  dimagnetic
3 5
(C)  Cu  CN 4  diamagnetic (D) Cu  CN 6  paramagnetic

Part – 4 (Matrix Match Type Question)

13. Column – I Column – II
(A) MnO4 (p) Paramagnetic and colored.
(B) MnO42 (q) Diamagnetic and colored
(C) Cu  CN 4 
3 (r) Diamagnetic and colorless

(D) Ni  dmg 2 (s) Tetrahedral complex.

(t) Square planar complex.

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14. Column – I Column – II
(A) Na3 Co  ox 3  (p) Show geometric isomersim.
(B)  RhCl  CO   PPh3  NH 3  (q) Low spin complex.
(C) K Cr  NH 3 2  CN  4  . (r) Paramagnetic with more than two unpaired electrons.
(D) Ba CoBr2Cl2  . (s) Show colligative property corresponding of two
particles per formula.
(t) Electrically conducting

15. Column – I Column – II

Number of unpaired   B.M .
electron
(A) [Fe(NH3)6]2+ (p) 0 0
(B) [MnO4]¯ (q) 5 5.9
(C) [Mn(NH3)6]2+ (r) 1 1.73
(D) (s) 4 4.90

16. Column – I Column – II

(A) [ M ( AA)b2 cd ]n Four optically active isomer
(B) [ Ma3bcd ]n Four geometrical isomer
(C) [ M ( AB )b2 c2 ]n All geometrical isomers are optically active.
(D) [ M ( AB )3 ]n Two pair of enantiomer
Two optically inactive isomer.
Note : AA , AB , a,b,c,d are not having chiral centre.

Part – 5 (Integer Type Questions)

17. Find the value of x + y where x and y indicate number of H atoms in H x Fe  CO  4 and H y Re  CO 5
respectively. (EAN rule is followed).
18. Find total number of N – Cr – O bond angles in tris (glycinato) chromium (III).
19. The sum of oxidation state of Co and Cr in the following complex is: Co  NH 3 6  Cr  NH 3 2 Cl4  .
3
20. Total number of isomers (including stereoisomers) for the complex  Pd  NH 3   H 2O  NO2 2  are:
21. Number of pair of enantiomer of [Ma2b 2cd] is __________.
ANSWER KEY

Que. 1 2 3 4 5 6 7 8 9 10
Ans. C C B C B B C D D ABC
Que. 11 12 13 14 15 16 17 18 19 20
Ans. B C A– A– A– A– 3 9 6 7
qs,B- qt,B- s,B- pqst,B-
ps,C- pq,C- p,C- q q,C-
rs,D - prst,D pqst,D
qt - rst - prs
Que. 21
Ans. 2
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