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Topic: Capillarity
When we dip three tubes with ne bores but with di erent diameters into a clean water, we observe
that water rises in the tubes but the narrower the bore the higher the height to which the rises.
Capillary action (sometimes capillarity, capillary motion, or wicking) is the ability of a liquid to ow in
narrow spaces without the assistance of, and in opposition to, external forces like gravity. The e ect can
be seen in the drawing up of liquids between the hairs of a paint-brush, in a thin tube, in porous
materials such as paper, in some non-porous materials such as lique ed carbon ber, or in a cell. It
occurs because of inter molecular forces between the liquid and surrounding solid surfaces. If the
diameter of the tube is su ciently small, then the combination of surface tension (which is caused by
cohesion within the liquid) and adhesive forces between the liquid and container act to lift the liquid. In
short, the capillary action is due to the pressure of cohesion and adhesion which cause the liquid to
work against gravity.
Capillarity or capillary action is the tendency of a liquid to rise or fall in a narrow tube.
In both the water and the soap solution, the surface of the liquid or its meniscus curves upwards. But in
mercury the meniscus is curved downwards away from cohesion and adhesion will be required to
explain this capillary action.
Cohesion is the force of attraction between molecules of the same kind, e.g. the molecules of water.
Adhesion is the force of attraction between molecules of di erent kinds, e.g. the molecules of water
and glass.
Cohesion and adhesion explain the di erent action of water and mercury when spilled on a clean glass
surface.
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Because the adhesion of water molecules to glass is stronger than the cohesion between water
molecules, water spreads out on a clean glass surface when sprinkled on it and wets the glass. This is
not so in the case of mercury which does not spread on glass or wet it. The cohesion of mercury
molecules is greater than the adhesion of the mercury molecules to those of glass. As a result the
mercury forms into goblets or spherical beads on the glass surface.
Capillary Action
Key Di erence: In terms of chemistry and physics, adhesion is the tendency of dissimilar particles or
surfaces to cling to one another. Cohesion is the tendency of similar or identical molecules to cling to
each other.
Adhesive and cohesive are two words that sound very similar because of the ‘sive’ at the ends, however
they are completely di erent from each other. They are derived from the words ‘adhesion’ and
‘cohesion’ respectively. Both these words are most commonly associated with chemistry and psychics;
however cohesion is also used in computer programming. Let’s look at the di erence between the two
words.
Adhesive and Adhesion has been listed as an adjective and a noun. As an adjective, adhesive means to
tend to remain in memory or to adhere to something. As a noun, adhesive is described as glue, which is
known to have adhesive properties that help two substances stick together. Merriam Webster de nes,
‘adhesion’ (adjective) as:
1. Steady or rm attachment
3. Agreement to join
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particles or surfaces to cling to
one another. The most commonly known adhesive is glue, which is used to stick two di erent surfaces
together. The intermolecular forces that cause adhesion can be divided into several types: mechanical
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adhesion, chemical adhesion, dispersive adhesion, electrostatic adhesion and di usive adhesion.
In mechanical adhesion, adhesive materials ll the pores of the surfaces and hold surfaces together by
interlocking. Chemical adhesion requires bonding at a molecular level, where two materials join and
form iconic, covalent or hydrogen bonds upon contact and hold together. In dispersive adhesion, two
materials are held together by van der Waals forces: the attraction between two molecules, each of
which has a region of slight positive and negative charge. Dew is an example of dispersive adhesion.
Electrostatic adhesion is when conducting materials pass electrons to form a di erence in electrical
charge at the join. This is similar to a capacitor, which creates electrostatic force in between the
materials. Di usive adhesion is when two materials merge and form a new material at di usion. This
occurs when the molecules of both materials are mobile and soluble in each other.
‘Cohesive’ is de ned as, “exhibiting or producing cohesion or coherence.” While, cohesion is de ned as:
Molecular attraction by which the particles of a body are united throughout the mass
Though, cohesion is more popularly used in chemistry it is also used in computer programming.
Yourdon and Constantine describe cohesion as the degree to which the elements of a module belong
together. Cohesion is a measure of how strongly-related or focused the responsibilities of a single
module are.
In terms of chemistry, cohesion is the tendency of similar or identical molecules to cling to each other. It
is considered as the opposite of adhesion. Cohesive attraction, intramolecular force or cohesive force is
the force that pushes similar molecules to join together and form a strong bond. This force is an intrinsic
property of a substance because of the shape and structure of its molecules, which makes distribution
of orbiting molecules di cult when the molecules get closer to one another, creating an electrical
attraction. Cohesion allows for surface tension, creating a solid-like state upon which low-density
materials can be placed. Water and mercury are strongly cohesive.
Applications of Capillarity
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1. Lubricating oil spread easily on all parts because of their low surface tension.
2. Cotton dresses are preferred in summer because cotton dresses have ne pores which act as
capillaries for sweat.
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3. Dirt gets removed when detergents are added while washing clothes because surface tension of
water is reduced.
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4. The absorption of ink by a blotting paper is due to capillary action, as the blotting paper is porous.
When it is placed over the ink, the ink raises into the pores. Also rise of oil in the wick of a lamp is due to
capillary action.
5. If one end of a towel is dipped into a bucket of water and the other end hangs over the bucket, the
entire towel soon becomes wet due to capillary action.
6. The supply of water to the leaves at the top of even a tall tree is through capillary rise.
7. A fabric can be waterproof, by adding suitable waterproo ng materials to the fabric. This addition
increases the angle of contact, thereby making the fabric waterproof.
ASSESSMENT.
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