Paper_UN-Champ (Chemistry = PC+OC+IOC)00-00-2021

SECTION-I : Single Correct Type

This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct. You will be awarded 3 marks if only the correct option is chosen
and zero mark if none of the option is chosen. (–1) marks will be awarded for incorrect answers in this
section.
Level : Moderate
Topic : Thermodynamics
Concept : 1st law of T.D.
Sub-concept : 1st law of T.D.
1. H for a real gas undergoing a change from (3lit, 5atm) to (5lit, 7atm) is,
 H   H 
Given :   = 5 lit.;  = 2V atm
 P  v  V  P
(A) 16 atm-litre (B) 42 atm-litre (C) 10 atm-litre (D) 26 atm-litre
Ans. (D)
 H   H 
Sol. dH =   dP +   dV
 P V  V P
= 5 dP = 2VdP
= 5(7 – 5) + (25 – 9)
= 26 atm-litre

Level : Tough
Topic : Thermodynamics
Concept : 1st law of T.D.
Sub-concept : 1st law of T.D.
2. 2A(s) + B(g) → 2C(g) + D(l) ; Hreaction= –20 kJ/mole
Calculate change in internal energy when 2 mole of B reacts with excess of A(s) in above reaction
at 1000 K ?
(A) –56.6 kJ (B) –28.3 kJ (C) –100 kJ (D) –14.4 kJ
Ans. (A)
Sol. For 1 mole B
H = U + ngRT
100
–20 = U + (+1) 8.314 ×
1000
U = – 28314
For 2 mol B
U = – 56.628 kJ

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Level : Moderate
Topic : Thermodynamics
Concept : 1st law
Sub-concept : 1st law
3. During vapourisation of H2O(l) at 373 K & 1 atm
(A) Internal energy remain unchanged (B) Kinetic energy remain unchanged
(C) Enthalpy remains unchanged (D) Potential energy remain unchanged
Ans. (B)
Sol. KE = f(T) So vaporisation at const. temperature potential energy charges not kinetic energy.

Level : Moderate
Topic : Thermodynamics
Concept : 1st law
Sub-concept : 1st law
4. ‘’ for NH3 including contribution from vibrational degree’s of freedom is -
(A) 4/3 (B) 10/9 (C) 7/9 (D) 13/12
Ans. (B)
n + n Rot + 2n is
Sol. CV = tr R
2
3 + 3 + 12
= = 9R
2
10
r=
9

Level : Moderate
Topic : Optically Isomerism
Concept : Symmetry
Sub-concept : Symmetry
5. Condition for a compound to be optically active is absence of
(A) Only plane of symmetry (B) Only axis of symmetry
(C) Only centre of symmetry (D) Only alternative axis of symmetry
Ans. (D)
Sol. Plane and centre of symmetry both are subset S1 & S2 respectively of alternative axis of symmetry
(Sn).
Sn (AAOS) absent → S1 absent have POS absent
S2 absent have COS absent

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Level : Moderate
Topic : Optically Isomerism
Concept : Symmetry
Sub-concept : Symmetry

6. Dissymmetric Compound is :-
F
H3 C F Cl
C C=C=C Br
(A) (B) H (C) Cl (D)
Cl Br H Br
I

Ans. (D)

Sol. Dissymmetric compound contains only axis of symmetry

Option (A)  No symmetry present

Option (B)  No symmetry present

Option (C)  Plane & axis of symmetry solution present

Option (D)  Only AOS (C2) is present hence dissymmetric.

Level : Moderate
Topic : Optically Isomerism
Concept : Symmetry
Sub-concept : Symmetry

7. Correct statement regarding following compound is :-

(A) 4 plane of symmetry & 5 axis of symmetry

(B) 5 plane of symmetry & 5 axis of symmetry

(C) 6 plane of symmetry & 6 axis of symmetry

(D) 6 plane of symmetry & 5 axis of symmetry

Ans. (C)
C5

Sol.
C2

1C5 (from centre of tops bottom pentagon faces)

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 5C2 (Each from mid-point of vertical edges to centre of opposite rectangular faces)

5 vertical plane of symmetry passion through one corner of pentagonal & mid-point of opposite

edge same pentagon)

1 horizontal plane of symmetry as shown.

Level : Easy
Topic : Optically Isomerism
Concept : Chiral Centre
Sub-concept : Chiral Centre
8. Compounds having odd number of chiral centre is :-
O H3C CH3 CH
3

Cl Cl
S
(A) (B) (C) (D)
Br CH3 H3C CH3 CH3

Ans. (D)

S
Sol.

Level : Easy
Topic : Optically Isomerism
Concept : Chiral Centre
Sub-concept : Chiral Centre
9. Compound which can show stereoisomers :-
(A) Ethene (B) Propene (C) Butane-2-ol (D) Ethyne
Ans. (C)
Sol. Compound in option C is showing optical isomerism.

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Level : Moderate
Topic : Optically Isomerism
Concept : Symmetry
Sub-concept : Symmetry
10. Correct statement regarding following compound :-
Cl Cl
C=(C)=C
Br x Br
(A) One two fold axis of symmetry for all values of x
(B) Two plane of symmetry for all even values of x
(C) No plane of symmetry for all odd values of x
(D) All of these
Ans. (D)
Sol.

Level : Moderate
Topic : Optically Isomerism
Concept : Optical Activity
Sub-concept : Optical Activity
11. If compounds observed rotation for a compound for plane polarized light is zero with statement
which is always correct.
(A) Compound is optically active
(B) Compound is showing optical isomerism
(C) Compound is not showing optical isomerism
(D) Compound is optically inactive
Ans. (D)
Sol. If obs = 0  optically inactive compound

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Level : Tough
Topic : Optically Isomerism
Concept : Calculation of stereoisomers
Sub-concept : Calculation of stereoisomers
12. Following compound has there type of rings as shown.
R

R R
Q
Q Q

Q Q
Q
R R

If nP, nQ & nR are total number of stereoisomers when all P rings are benezoid, all Q rings are benezoid & R
rings are benezoid respectively. Then,
(A) nP = nQ = nR (B) nR > nP > nQ (C) nP > nQ > nR (D) nQ > nR > nP
Ans. (B)
Sol. When ring P is benzenoid
 Only all Q rings can show geometrical isomerism, hence possible stereoisomers.

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 Z E E E
Z Z Z Z Z E Z Z

Z Z Z Z Z Z Z E
Z Z Z Z
E E E E
Z Z Z E Z E Z Z

Z Z Z E Z Z E E
E Z E Z
Z Z Z Z E
E Z E E E E E E E E

E E E Z E E E E E E
E E Z E E
(np = 13)
When ring Q is bengezoid
 Only all P would show stereoisomers.

Possible stereoisomers
(nQ = 9)
Cl

) Similiar to
Cl

Cl
Cl
Cl

Cl )
When ring R is benzenoid
 Both ring P & Q would show stereoisomers.

It’s very obvious that in this case number of stereoisomers would be very high than previous cases
hence n R  n P  n Q

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Level : Moderate
Topic : Periodic Table
Concept : Periodic Table
Sub-concept : Periodic Table
13. Which of the following electronic configuration is associated with the biggest jump between the
second and third ionization energies?
(A) 1s2 2s2 2p2 (B) 1s2 2s2 2p6 3s1 (C) 1s2 2s2 2p6 3s2 (D) 1s2 2s2 2p1
Ans. (C)
Sol. Elements having valence electrons is equal to two is associated with the biggest jump between the
second and third ionization energies.

Level : Tough
Topic : Salt Analysis
Concept : Salt Analysis
Sub-concept : Salt Analysis
14. CO3–2 + Hg+2 + H2O ⎯→ (x) + H+, (x) is :
(A) Hg2CO3 (B) HgO.HgCO3 (C) 3HgO.HgCO3 (D) HgO.3HgCO3
Ans. (C)
Sol. CO3–2 + Hg+2 + H2O ⎯→ 3HgO·HgCO3 + H+

Level : Easy
Topic : Chemical Bonding
Concept : Chemical Bonding
Sub-concept : Chemical Bonding
15. Which of the following statement(s) is INCORRECT?
As the s-character of a hybrid orbital decreases :
(A) The bond angle decreases (B) The bond strength Increases
(C) The bond length increases (D) Size of orbitals increases
Ans. (B)
Sol. s % character Bond angle, B.L.

Level : Moderate
Topic : Salt Analysis
Concept : Salt Analysis
Sub-concept : Salt Analysis
16. Metal ‘M’ + dil. H2SO4⎯→ H2, metal ‘M’ can NOT be :
(A) Li (B) Cu (C) Al (D) Pb
Ans. (B)
Sol. Metal above H2 produce H2 gas on reaction with non-oxidising acid.

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Level : Moderate
Topic : Metallurgy
Concept : Metallurgy
Sub-concept : Metallurgy
17. The purpose of adding cryoliteis :
(A) to increase the electrical conductivity of pure aluminium
(B) to lower the melting point of Al2O3
(C) to remove the impurities as slag
(D) to increase the Al % in the yield
Ans. (B)
Sol. Na3AlF6 lowers the m.pt. and increases the conductance of melt.

Level : Easy
Topic : Metallurgy
Concept : Metallurgy
Sub-concept : Metallurgy
18. The function of fluorspar (CaF2) is :
(A) to decrease the melting point of electrolyte
(B) to increase electrolyte conductivity power
(C) to remove the impurities as slag
(D) all of the above
Ans. (B)
Sol. Fluorspar increases the electrical conductance.

Level : Moderate
Topic : Periodic Table
Concept : Endothermic
Sub-concept : Endothermic
19. Which of the following is highly endothermic process.
(A) Na → Na+ (B) Ca → Ca+1 (C) Li+→ Li2+ (D) Be+→ Be2+
Ans. (C)
Sol. II Ionisation energy always endothermic process Li+→ Li2+

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Level : Moderate
Topic : P-Block
Concept : P-Block
Sub-concept : P-Block
20. Metallic radii of some transition elements are given below. Which of these elements will have
lowest density?
Element Fe Co Ni Cu
Metallic radii/pm 126 125 125 128
(A) Fe (B) Ni (C) Co (D) Cu
Ans. (A)
Sol. Element Fe Co Ni Cu
Metallic radii/pm 126 125 125 128
Density 7.8 8.7 8.9 8.9

SECTION-II : Integer Value Correct Type

This section contains 10 questions. For each question, enter the correct numerical value (in decimal
notation, truncated / rounded off to the second decimal place; e.g. 6.25, 7.00, –0.33, –0.30, 30.27, –
127.30) using the mouse and the on screen virtual numeric keypad in the place designated to enter the
answer. You will be awarded 3 marks if correct numerical value is entered as answer. No negative
marks will be awarded for incorrect answers in this section.
Level : Easy
Topic : Mole concept
Concept : Application of mole
Sub-concept : Application of mole
1. 1.11 gm of CaCl2 added to water forming 500 ml solution. 20 ml of this solution is taken and
diluted 10 folds. Find moles of Cl– ions in 2 ml of diluted solution –
(Atomic mass of Ca : 40, Cl : 35.5).
If your answer is x × 10–y then the value of x + y ?
Ans. (14)
1.11
Sol. Moles of CaCl2 in 500 ml sample = = 0.01 mol
111
0.01
Moles in 20 ml sample =  20
500
0.01 20
Moles of Cl– in 2 ml diluted sample =   2  2 = 8 × 10–6
500 200

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Level : Easy
Topic : Mole concept
Concept : Application of mole
Sub-concept : Application of mole
2. Cyclohexanol is dehydrated to cyclohexene on heating with conc. H2SO4. If the yield of this
reaction is 75 %. How much cyclohexene will be obtained from 100 g of cyclohexanol ?
Ans. (61.5)
OH

Sol. 75 %

(C 6H12O) (C6H10)
100 g 82 g × 75 = 61.5 g
100

Level : Moderate
Topic : Mole concept
Concept : Application of mole
Sub-concept : Application of mole
3. 3 gm of carbon reacts completely with 5 gm of O2 leaving none of reactant. Mole fraction of CO in
final mixture is :-
Ans. (0.75)
Sol. C + O2 → CO + CO2
3 5
a b
12 32
3 10
a+b= a + 2b =
12 32
10 3 30 − 24 1
b= − = =
32 12 96 16
3 1 12 − 3 9
a= − = =
12 16 48 48
9
3
Mole fraction of CO = 48 =
3 4
12

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Level : Tough
Topic : Thermodynamics
Concept : 1st law
Sub-concept : 1st law
4. Calculate magnitude of net work in following cyclic process for 1 mole of ideal monoatomic gas
(in cal.)
(Given - B → C - isothermal process:
D → A - adiabatic process : TA = 300 K
TD = 75 K, R = 2 cal/mole-K. : ln2 = 0.7

Ans. (1605)
Sol. TA = 300
TB VB 2V
= =
TA VA V
TB = 2TA = 2 × 300 = 600
TC = 600
TD = 75
and volume at D will be
TA VA −1 = TD VD −1
/  −1
 300 
  V = VD
75 
TA VAr −1 = TD VDr −1
1
 300  r −1 3
VD = V    = ( 4 ) 2 V = 8V
 75 

WAB = – 1 × R × 300 = – 300 R = – 600 Cal

WBC = – R × 600 × ln4 = – 840 R = – 1680 Cal

WCD = 0
3
WDA = × R × (225) = 675 Cal
2

Wtotal = – 1605

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Level : Moderate
Topic : Thermodynamics
Concept : 1st law
Sub-concept : 1st law
5. How many times volume of diatomic gas should be expanded reversibly & adiabatically in order to
reduce it's rms velocity to half.
Ans. (32)
3RT
Sol. U rms  T
M
T  U2rms
2
T2  1  1
=  =
T1  2  4
In reversible adiabatic process
 −1 1/  −1
T2  V1  V T
=  2 = 1
T1  V2  V1  T2 

Level : Moderate
Topic : Thermodynamics
Concept : 1st law
Sub-concept : 1st law
6. 1 mole of monoatomic ideal gas subjected to irreversible adiabatic expansion against constant
external pressure of 1 atm starting from initial pressure of 5 atm and initial temperature of 300 K
till the final pressure is 2 atm. What is the magnitude of work done (in cal) in the process.
(Take R = 2 cal/mol K).
Ans. (135)
1  nRT2 nRT1 
Sol. 1 × R (T2 – 300) = – Pext  −
3  P2 P1 
 T 300 
1.5 (T2 – 300) = – 1  2 − 
 2 5 
1.5 T2 – 450 = – 0.5 T2 + 60
2T2 = 510
T2 = 255 K
3 3
W = R (T2 – 300) = (R) (255 – 300)
2 2

−45  3
= × R = – 135 cal
2

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Level : Moderate
Topic : Optically Isomerism
Concept : Symmetry
Sub-concept : Symmetry
7. Total number of three fold axis of symmetry in ethane is :-
Ans. (1)
C3
H H
C H
Sol.
C H
H
H

Level : Moderate
Topic : Optically Isomerism
Concept : Symmetry
Sub-concept : Symmetry
8. Total number of possible dimethyl cyclohexane compounds which are achiral ?
Ans. (5)
H3C CH3
CH3 CH3 CH3
Sol.
CH3
(Achiral) (Achiral) CH3 (Chiral) (Chiral) CH3

CH3 CH3 CH3 CH3 CH3

CH3
(Achiral) CH3 (Chiral) (Chiral) CH3
CH3 CH3
(Achiral) (Achiral)

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Level : Moderate
Topic : Salt Analysis
Concept : Salt Analysis
Sub-concept : Salt Analysis
9. Total number of anions among the following which from volatile product with acids is :
C2O4–2, I–, F–, S–2, NO2–, CrO4–2, PO4–3, SO4–2
Ans. (5.00)
Sol. Anions of class ‘A’ form volatile product with acid

Level : Moderate
Topic : Co-ordination Compound
Concept : Co-ordination Compound
Sub-concept : Co-ordination Compound
10. Consider the complex [Co(NH3)4CO3]ClO4 find sum of co-ordination number, oxidation number
and number of d electrons on metal ion
Ans. (15.00)
0

Sol. [Co(NH3)4CO3]ClO4 :Coordination number = 6

0

Oxidation number = +3
7

Co+3 = 3d6 ⇒ Number of 'd' elements = 6

6

= 6 + 3 + 6 = 15

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